CA1086844A - Electrophoretic image display device - Google Patents

Electrophoretic image display device

Info

Publication number
CA1086844A
CA1086844A CA292,202A CA292202A CA1086844A CA 1086844 A CA1086844 A CA 1086844A CA 292202 A CA292202 A CA 292202A CA 1086844 A CA1086844 A CA 1086844A
Authority
CA
Canada
Prior art keywords
electrode
transparent
display device
mesh
segmented
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA292,202A
Other languages
French (fr)
Inventor
Richard B. Liebert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Philips North America LLC
Original Assignee
North American Philips Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by North American Philips Corp filed Critical North American Philips Corp
Application granted granted Critical
Publication of CA1086844A publication Critical patent/CA1086844A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis

Abstract

ABSTRACT:
Electrophoretic image display device comprising a transparent front electrode, segmented rear electrode(s), an isolating layer covering the rear electrode(s) and a mesh electrode in the shape of the segmented electrode(s) on said insulating layer. Swit-ching takes place between the rear electrode(s) and the mesh electrode resulting in greatly reduced switching times. The suspension medium may be a clear liquid in which the charged pigment particles are suspended.

Description

L PITA 20.760 CB
1 0 . îl O . 1 9 77 1086~344 E]ec~rophoretic Image D~splay Device.

The invention relates to an electrophoretic image display device comprising: an electrophoret~c suspension comprising a dispersion of pigment particles in a dielectric suspending liquid and a charging material for introducing a charge on the pigment particles;
a fir.st transparent electrode on a first substrate;
at least one segmented electrode on a second substrate having a major surface in opposition to the maJor sur-face of said first transparent electrode, the space - between said substrates forming a cell for containing said electrophoretic suspension.
Electrophoretic image display devices herein-after termed EPID cells, have been described in the art, 15; for example in Evans, United States Patent 3,612,758 and ; Ota, United States Patent 3,668,106.
Generally, an EPID cell comprises firstly a dispersion of pigment particles in a dielectric liquid dispersion medium to which is added a dye to cause the dispersion medium to have a contrasting color to that .
of the pigment particIes and a charging material for introducing a charge on the pigment particles.
; - The dispersion is contained in a cell - formed by two closely spaced electrodes joined together by a thin section of insulating material. One of the electrodes, the front or viewing electrode is trans-,-- ~ ' .

.... . .

L I'~-l~ 20.760 10. 10. 1977 10868~4 parent and tl1e rear electrode, which is made to conform to the desired image or i~na~es desircd to be displayed, may or may not be transparent.
An electroc field is created across the suspension by means of a D.C. voltage applied to the front and rear electrodes.
- Depending upon the charge on the pigment ~particles and the electrodes, the pigment particles are attracted to either the front or rear electrode.
If the pigment particles are ~egative, the front electrode is positive and the rear electrode is negative the pigment particles are attracted to the front electrode in the shape of the rear electrode. The observer sees an image of the color of the pigment against the color of the dispersion medium. Reversal of the polarity between the electrodes causes the pigment to go to the rear electrode where it is hided behind the dispersion medium.
Removal of the electric field does not cause disruption of the image, as the pigment particles remain in the previously acti~ated position for a period of time.
Thus the cell exhibits some memory function.
One problem with the known EPID cells is ~ that they have relatively slow switching times, that is, the time it takes pigment particles to move from the front to the rear electrodes or the reverse. The relationship of the switching time to the applied voltage and distance between the electrodes is determined accarding to the formula t = 6 ~r d2 ~ / V

' ''' ' ''' ~ ' , L PIIA 20.7f,0 10. 10. 1977 108~44 where t is the switching time, d is the distance betwecll the rront and rcar electrodes, ~ is the dielectric constant and ~ is the viscosity of the suspending medium, ~ is the ze-ta potential and V i9 the applied voltage.
As can be seen, the switching time is largely dependent on the distance between the electrodes as it increases with the square of this distance, Due to practical considerations, there is a minimum limit on the distance between the electrodes and thus the minimum switching time for a given potential difference is limited for a particular suspension.
For many purposes a faster switching time then is achieved with the presently known EPID cells is highly desirable.
An additional problem is the need for use of dyes in order to hide the pigment when it is on the rear electrode.
It is an object of the invention to provide an EPID cell having a faster switching time than those EPID cells known from the prior art.
An other ohject of the invention is to provide an EPID cell capable of operating at a reduced voltage.
- Still another object of the invention is to provide an EPID cell wherein the suspension is free of dyes.
These and other objects of the invent~n will be appar~nt from the description that ~ollows :

L PIT~ 20.7~0 10.10.1977 1~86844 According to the ltlvention, an electrophoretic image display device as mentioned in the preamble is charac-terized in that a transparent insulating layer is positioned on the maJor surface of said segmented e~ectrode opposed to 5 said first transparent electrode;
a mesh electrode in the shape of the segmentedelectrode having holes barely visible to the naked eye is positioned on said transparent insulating layer, one of said mesh electrode and said segmented electrode being formed of light reflective metal, the device further comprising . electrical supply means for supplying a reversible voltage between.said mesh electrode and said segmented electrode.
The operation of the EPID cell of the invention . is as follows: .
Emplying a reflective mesh electrode and a black negatively charged pigment suspended in a clear liquid, with the rear and front electrodes negative in relation to the mesh electrode, all the pigment is depo-sited on the mesh electrode and the observer looking through the transparent front electrode sees only black, since the - spaces within the mesh are made to look black.
;~ When the charge on the mesh electrode and the back electrode are reversed, the pigment is deposited in the mesh holes and the observer sees the exposed reflective metal of the mesh.
Due to the fact that the pigment must travel : only between the mesh surface and the holes in the mesh to ~5-:. :
,.: ' . ................ , ' , . .

L Pl-l~ 20.760 10~844 10.10.1977 cause switching ratller than the much longer distancc between the f`ront and rear electrodes, switching time - is greatly reduced in the ~PID cells of the invention.
Similarly the voltage required to operate the cell i9 greatly reduced since the pigment only has to travel a much smaller distance for switching to occur.
The invention will now be described with reference to the drawing, the sole figure of which is a cross-sectional view of an ~PI~ cell of the inventiDn.
Referring to the drawing, front transparent electrode 1 such as indium oxide having a thickness of about 1000 A supported by transparent substrate 2 such as glass or methyl methacrylate resin is opposed by rear transparent electrode 3 such as indium oxide which has a thickness of about 1000 A.
Rear electrode 3 is supported by transparent substrate 4 which may be made of glass or another suitable non-conducting transparent material. The rear surface of substrate 4 is colored black by means of a black paint layer 5.
The front and rear electrode 1 and 3 are "
separated from each other by a 50/um thick epoxy resin seal 6.
On the surface of rear electrode 3, facing front electrode 1, is a thin transparent dielectric layer 7 formed of a photoresist such as AZ 1350J made by Shipley Co. and 5000 ~ thick. The surface of the dielec-- .

~ -6-. ~ ` .

L PHA 20.7Go 10~6844 10.10.1977 tric layer 7 facin~ the front electrode 1 is covered with a thin re~lective metal mesh 8 of reflective aluminium or other metal. The mesh 8 has holes of 8/u diameter on 19/u cent~rs.
An opaque mask 12 formed of a thin black paint layer is present on the surface of the front electrode 1 - opposing rear electrode 3.
The me~al mesh 8 is formed by evaporating a thin layer Or aluminium on the dielectric layer 7 and then etching the aluminium layer with an etch such as phosphoric and nitric acids through a photoresist mask to provide the holes in the aluminium layer and the resultant mesh 8.
An electrophoretic suspension comprising a mix-- ture of perchloroethylene and xylene in a volume ratio of 7 to 3 to which there is added two percent by weight of diarylide yellow pigment and one percent by weight of Chevron OLOA-370 to stabilize the dispersion and negatively charge the pigment, was injected into the cell which was then sealed. D.C. voltages were applied through lead lines 9,-10 and 11 to the rear, front and mesh electrodes respec-tively.
Application of -100 volts to the mesh electrode 8 and the front electrode 1 with respect to ground (rear electrode 3) resulted in the negatively charged pigment being mostly in the mesh holes allowing the reflective surface of the mesh electrode 8 to be visible through front electrode 1. Reversing the polarity between electrodes 8 and .

7~

L PIIA 20.760 10.10.1977 10~6844 3 so that the front electrode 1 and rear electrode 3 ~Yere at -100 vo].ts and mesh electrode 8 was at ground most of -the pigment particles covered thè aluminium surface of the mesh electrode 8 thus destroying the visibility of this electrode through the front electrode 1. Repeated changes in polarity between electrodes 3 and 8 resulted in repeated changes of reflectivity of the ' mesh electrode 8.
The device operated successfuly with voltagés as low as 20 volts.

.
.

.
' ~ :

Claims (7)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. Electrophoretic image display device com-prising : an electrophoretic suspension comprising a dispersion of pigment particles in a dielectric suspending liquid and a charging material for introducing a charge on the pigment particles; a first transparent electrode on a first substrate; at least one segmented electrode on a second substrate having a major surface in opposition to the major surface of said first transparent electrode, the space between said substrates forming a cell for con-taining said electrophoretic suspension; characterized in that a transparent insulating layer is positioned on the major surface of said segmented electrode opposed to said first transparent electrode; a mesh electrode in the shape of the segmented electrode having holes barely visible to the naked eye is positioned on said transparent insulating layer, one of said mesh electrode and said segmented electrode being formed of light reflective metal, the device further comprising electrical supply means for supplying a reversible voltage between said mesh elec-trode and said segmented electrode.
2. Display device according to Claim 1 characterized.
in that the mesh electrode is formed of a light reflective metal.
3. Display device according to Claim 2, characte-rized in that the first transparent electrode is a thin coating of a transparent electrically conductive material on the surface of a transparent electrically insulating substrate.
4. Display device according to Claim 3, charac-terized in that the segmented electrode is transparent.
5. Display device according to Claim 1, charac-terized in that the segmented electrode is supported by a transparent electrically insulating substrate.
6. Display device according to Claim 3, charac-terized in that the reflective mesh electrode is formed of aluminium.
7. Display device according to Claim 1, charac-terized in that a opaque mask is positioned on the major surface of said first transparent electrode opposed to said segmented electrode, said opaque mask having light transmissive areas in the shape of said segmented elec-trode.
CA292,202A 1976-12-06 1977-12-01 Electrophoretic image display device Expired CA1086844A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/747,559 US4071430A (en) 1976-12-06 1976-12-06 Electrophoretic image display having an improved switching time
US747,559 1976-12-06

Publications (1)

Publication Number Publication Date
CA1086844A true CA1086844A (en) 1980-09-30

Family

ID=25005628

Family Applications (1)

Application Number Title Priority Date Filing Date
CA292,202A Expired CA1086844A (en) 1976-12-06 1977-12-01 Electrophoretic image display device

Country Status (6)

Country Link
US (1) US4071430A (en)
JP (1) JPS5845027B2 (en)
CA (1) CA1086844A (en)
DE (1) DE2752191C2 (en)
FR (1) FR2373115A1 (en)
GB (1) GB1567708A (en)

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US4071430A (en) 1978-01-31
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FR2373115A1 (en) 1978-06-30
FR2373115B1 (en) 1984-09-21
GB1567708A (en) 1980-05-21
DE2752191A1 (en) 1978-06-08
JPS5386594A (en) 1978-07-31

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