CA1158811A - High temperature resistant compressible sheet material for gasketing and the like - Google Patents
High temperature resistant compressible sheet material for gasketing and the likeInfo
- Publication number
- CA1158811A CA1158811A CA000365914A CA365914A CA1158811A CA 1158811 A CA1158811 A CA 1158811A CA 000365914 A CA000365914 A CA 000365914A CA 365914 A CA365914 A CA 365914A CA 1158811 A CA1158811 A CA 1158811A
- Authority
- CA
- Canada
- Prior art keywords
- weight
- percent
- fibers
- coupling agent
- silane coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title claims abstract description 94
- 238000013023 gasketing Methods 0.000 title abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 40
- 229920001971 elastomer Polymers 0.000 claims abstract description 30
- 239000000806 elastomer Substances 0.000 claims abstract description 30
- 239000011230 binding agent Substances 0.000 claims abstract description 25
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000003431 cross linking reagent Substances 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 8
- 229920001410 Microfiber Polymers 0.000 claims description 7
- 239000003658 microfiber Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- KVBYPTUGEKVEIJ-UHFFFAOYSA-N benzene-1,3-diol;formaldehyde Chemical compound O=C.OC1=CC=CC(O)=C1 KVBYPTUGEKVEIJ-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000178 monomer Substances 0.000 description 14
- 229920000126 latex Polymers 0.000 description 11
- 239000004816 latex Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 125000002091 cationic group Chemical group 0.000 description 7
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 6
- 238000004132 cross linking Methods 0.000 description 6
- -1 ethylene, butylene, propylene Chemical group 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 6
- 229920000867 polyelectrolyte Polymers 0.000 description 5
- 229920003051 synthetic elastomer Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000005061 synthetic rubber Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000010425 asbestos Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910052895 riebeckite Inorganic materials 0.000 description 3
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000569 Gum karaya Polymers 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 2
- 241000934878 Sterculia Species 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229940117913 acrylamide Drugs 0.000 description 2
- 238000012644 addition polymerization Methods 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- OOOBCBJWKXTYAX-UHFFFAOYSA-H chromium(3+);octadecanoate;tetrachloride;hydroxide Chemical compound [OH-].[Cl-].[Cl-].[Cl-].[Cl-].[Cr+3].[Cr+3].CCCCCCCCCCCCCCCCCC([O-])=O OOOBCBJWKXTYAX-UHFFFAOYSA-H 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 230000006854 communication Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000231 karaya gum Substances 0.000 description 2
- 229940039371 karaya gum Drugs 0.000 description 2
- 235000010494 karaya gum Nutrition 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 2
- WPJGWJITSIEFRP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;hydrate Chemical compound O.NC1=NC(N)=NC(N)=N1 WPJGWJITSIEFRP-UHFFFAOYSA-N 0.000 description 1
- MBDUIEKYVPVZJH-UHFFFAOYSA-N 1-ethylsulfonylethane Chemical class CCS(=O)(=O)CC MBDUIEKYVPVZJH-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- UMPSXRYVXUPCOS-UHFFFAOYSA-N 2,3-dichlorophenol Chemical class OC1=CC=CC(Cl)=C1Cl UMPSXRYVXUPCOS-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920003265 Resimene® Polymers 0.000 description 1
- 240000001058 Sterculia urens Species 0.000 description 1
- 235000015125 Sterculia urens Nutrition 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- WVJOGYWFVNTSAU-UHFFFAOYSA-N dimethylol ethylene urea Chemical compound OCN1CCN(CO)C1=O WVJOGYWFVNTSAU-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229960004279 formaldehyde Drugs 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 229940056960 melamin Drugs 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/02—Sealings between relatively-stationary surfaces
- F16J15/06—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces
- F16J15/10—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with non-metallic packing
- F16J15/102—Sealings between relatively-stationary surfaces with solid packing compressed between sealing surfaces with non-metallic packing characterised by material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/12—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2709/00—Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
Abstract
ABSTRACT OF THE DISCLOSURE
A high temperature resistant compressible sheet material has a thickness of 0.001 to 1 inch and includes a crosslinked elastomer as a binder and high temperature staple fibers. A major amount of a particulate filler which has been chemically modified to coreact with the crosslinked elastomer is incorporated into the sheet material. The binder preferably has incorporated therein an addition polymerized silane coupling agent. The sheet material is fabricated according to papermaking techniques. The sheet material is useful in the fabrication of gasketing and in heat shields.
A high temperature resistant compressible sheet material has a thickness of 0.001 to 1 inch and includes a crosslinked elastomer as a binder and high temperature staple fibers. A major amount of a particulate filler which has been chemically modified to coreact with the crosslinked elastomer is incorporated into the sheet material. The binder preferably has incorporated therein an addition polymerized silane coupling agent. The sheet material is fabricated according to papermaking techniques. The sheet material is useful in the fabrication of gasketing and in heat shields.
Description
BACKGROUND OF THE INVENT_ON
This invention relates to high temperatures resistant compressible sheet material useful as gasketing and heat shields and more particularly to high temperature resistant compressible sheet material using a crosslinked elastomer as the binder.
DESCRIPTION OF T~E PRIOR ART
Flexible compressible sheet material has been extensively used in gasketing applications. Typically, the sheet material has a thickness between 0.001 to 1/4 of an inch for use in the fabrication of gaskets. The sheet material is either used alone or as a component of a composite gasket. For example, a gasket for sealing the base of a carburetor to the inta}ce manifold of an internal combustion engine is formed by placing the sheet material on or between one or two sheets respectively of thin metal to form a composite gasket. Further9 gaskets used in connection with internal combustion engines are sometirnes required to withstand extremely high temperatures, i.e. on the order of greater than 500F and sornetimes as much as 900~F. For example, the exhaust manifold gaskets, the supercharger gaskets, the gaskets for exhaust systems and head gaskets and those required in connection with catalytic conver-ters must have high temperature resistance. Fur-ther, these gaskets must be resistant to oil and water, both of which will contact the gasket when used in connection with an internal combustion engine. With respect to water resistance, this is a particularly important characteristic when used in the fabrication of water pump gaskets.
Further, water resistance becomes an even greater requirement of gasketing material when the gasket is used in connection with marine engines and more particularly in outboard motors.
By far, asbestos has found the most use as the fiberous component in gasketing material primarily because of its high temperature resistance. However, because of the toxicity of asbestos, substitutes have been sought which would effectively eliminate the need to use asbestos in gasketing materials.
Fiberglass in the form of microfibers and ceramic fibers has been utilized in connection with forming compress-ible sheet materials for use in gasketing material. Further, in order to retain structural integrity during conversion of the sheet material to gasketing and in use, it is necessary to provide a binder which possesses these characteristics.
Typically, these binders are elastomeric in nature. Further, the binders should have some degree of heat resistance since they will come in contact with high temperature environments when placed in service. The sheet material must also be compressible and nonporous to form an effective seal between passages which are in fluid communication.
In accordance with the present invention a sheet material formed on standard papermaking apparatus is provided which maintains its integrity under high temperature conditions and is resistant to both water and oil when used as a gasket.
~ -3-l 158~ ~
Further, the sheet material according to the invention may be used as a heat shield to isolate various areas from heat generating sources such as a floor underlay in a car or trunk.
Still further, the sheet material according to the invention has a plurality of uses where high temperature characteristics are required.
STATEMENT OF THE INVENTION
According to a broad aspect, the present invention provides a high temperature resistant compressible water laid sheet material having a fibrous constituent and a thickness of 0.001 to 1 inch. The sheet material comprises 8 to 65 percent by weight of a binder including a cross-linkable elastomer and a silane coupling agent copolymerized within the binder at a level of at least about 2 percent by weight. Also provided is a crosslinking agent for the elastomer. 15 to 70 percent by weight of a inorganic particu-late filler which has been chemically modified to coreact with the crosslinked elastomer is also provided. Further, a 15 to 50 percent by weight of high temperature nonasbestos staple fibers is provided. The material is capable of withstanding service temperatures of 500F and being oil and water resistant.
According to a further broad aspect~ there is provided a high temperature resistant compressible water laid sheet material having a thickness of 0.001 to 1 inch comprising 20 to 30 percent by weight of inorganic nonasbestos staple fibers having a service temperature in excess of 1500F;
up to 8 percent by weight of inorganic staple fibers having a service temperature greater than 900F but not in excess of 1500F, 20 to 30 percent by weight of a crosslinked elasto-meric binder having a silane coupling agent polymerized ~ii -4-therein at a level of at least about 2 percent by weight, and 40 to 50 percent by weight of an inorganic filler which has been modified to coreact with the elastomeric binder. The material is capable of withstanding continous service temperatures in excess of 500F and being oil and water resistant.
BRIEF DESCRIPTION OF THE INVENTION
.
A high temperature resistant compressible sheet material has a thickness of 0.Q01 to 1 inch and includes a crosslinked elastomer as a binder and high temperature staple fibers. A major amount of a particulate filler which has been chemically modified to coreact with the crosslinked elastomer is incorporated into the sheet material.
Preferably, the binder includes a silane coupling agent addition polymerized therein. The sheet material is fabricated according to papermaking techniques. The sheet material is useful in the fabrication of gasketing and in heat shields.
The binder is constituted of a crosslinked elastomer to provide the required compressibility and integrity to the composite sheet material. The term "elastomer", as used herein, is intended to mean and include both synthetic and natural rubber. "Natural rubber" as used herein, is the elastic solid obtained from the sap or latex of the Havea tree, the major constituent being the homopolymer of 2-methyl-1,3-butadiene (isoprene). "Synthetic rubber" as used herein, is meant to encompass polymers based upon at least
This invention relates to high temperatures resistant compressible sheet material useful as gasketing and heat shields and more particularly to high temperature resistant compressible sheet material using a crosslinked elastomer as the binder.
DESCRIPTION OF T~E PRIOR ART
Flexible compressible sheet material has been extensively used in gasketing applications. Typically, the sheet material has a thickness between 0.001 to 1/4 of an inch for use in the fabrication of gaskets. The sheet material is either used alone or as a component of a composite gasket. For example, a gasket for sealing the base of a carburetor to the inta}ce manifold of an internal combustion engine is formed by placing the sheet material on or between one or two sheets respectively of thin metal to form a composite gasket. Further9 gaskets used in connection with internal combustion engines are sometirnes required to withstand extremely high temperatures, i.e. on the order of greater than 500F and sornetimes as much as 900~F. For example, the exhaust manifold gaskets, the supercharger gaskets, the gaskets for exhaust systems and head gaskets and those required in connection with catalytic conver-ters must have high temperature resistance. Fur-ther, these gaskets must be resistant to oil and water, both of which will contact the gasket when used in connection with an internal combustion engine. With respect to water resistance, this is a particularly important characteristic when used in the fabrication of water pump gaskets.
Further, water resistance becomes an even greater requirement of gasketing material when the gasket is used in connection with marine engines and more particularly in outboard motors.
By far, asbestos has found the most use as the fiberous component in gasketing material primarily because of its high temperature resistance. However, because of the toxicity of asbestos, substitutes have been sought which would effectively eliminate the need to use asbestos in gasketing materials.
Fiberglass in the form of microfibers and ceramic fibers has been utilized in connection with forming compress-ible sheet materials for use in gasketing material. Further, in order to retain structural integrity during conversion of the sheet material to gasketing and in use, it is necessary to provide a binder which possesses these characteristics.
Typically, these binders are elastomeric in nature. Further, the binders should have some degree of heat resistance since they will come in contact with high temperature environments when placed in service. The sheet material must also be compressible and nonporous to form an effective seal between passages which are in fluid communication.
In accordance with the present invention a sheet material formed on standard papermaking apparatus is provided which maintains its integrity under high temperature conditions and is resistant to both water and oil when used as a gasket.
~ -3-l 158~ ~
Further, the sheet material according to the invention may be used as a heat shield to isolate various areas from heat generating sources such as a floor underlay in a car or trunk.
Still further, the sheet material according to the invention has a plurality of uses where high temperature characteristics are required.
STATEMENT OF THE INVENTION
According to a broad aspect, the present invention provides a high temperature resistant compressible water laid sheet material having a fibrous constituent and a thickness of 0.001 to 1 inch. The sheet material comprises 8 to 65 percent by weight of a binder including a cross-linkable elastomer and a silane coupling agent copolymerized within the binder at a level of at least about 2 percent by weight. Also provided is a crosslinking agent for the elastomer. 15 to 70 percent by weight of a inorganic particu-late filler which has been chemically modified to coreact with the crosslinked elastomer is also provided. Further, a 15 to 50 percent by weight of high temperature nonasbestos staple fibers is provided. The material is capable of withstanding service temperatures of 500F and being oil and water resistant.
According to a further broad aspect~ there is provided a high temperature resistant compressible water laid sheet material having a thickness of 0.001 to 1 inch comprising 20 to 30 percent by weight of inorganic nonasbestos staple fibers having a service temperature in excess of 1500F;
up to 8 percent by weight of inorganic staple fibers having a service temperature greater than 900F but not in excess of 1500F, 20 to 30 percent by weight of a crosslinked elasto-meric binder having a silane coupling agent polymerized ~ii -4-therein at a level of at least about 2 percent by weight, and 40 to 50 percent by weight of an inorganic filler which has been modified to coreact with the elastomeric binder. The material is capable of withstanding continous service temperatures in excess of 500F and being oil and water resistant.
BRIEF DESCRIPTION OF THE INVENTION
.
A high temperature resistant compressible sheet material has a thickness of 0.Q01 to 1 inch and includes a crosslinked elastomer as a binder and high temperature staple fibers. A major amount of a particulate filler which has been chemically modified to coreact with the crosslinked elastomer is incorporated into the sheet material.
Preferably, the binder includes a silane coupling agent addition polymerized therein. The sheet material is fabricated according to papermaking techniques. The sheet material is useful in the fabrication of gasketing and in heat shields.
The binder is constituted of a crosslinked elastomer to provide the required compressibility and integrity to the composite sheet material. The term "elastomer", as used herein, is intended to mean and include both synthetic and natural rubber. "Natural rubber" as used herein, is the elastic solid obtained from the sap or latex of the Havea tree, the major constituent being the homopolymer of 2-methyl-1,3-butadiene (isoprene). "Synthetic rubber" as used herein, is meant to encompass polymers based upon at least
2 percent of a conjugated unsaturated .. .,,,j ` -4a-~158811 monomer, the conjugation being in the 1, 3 position in the monomer chain and the final polymer in its uncured state having an extensibility of at least 200 percent and a memory of at least 90 percent when stretched within the extensibility limits and released instantaneously. The conjugated unsatu-rated monomers which are used in the preparation of synthetic rubber are, but not limited to, chloroprene, butadiene, isoprene, cyclopentadiene, dicyclopentadiene, and the like.
Other olefins capable of free radical anionic or cationic addition polymerization into the polymer chain with a conjugated unsaturated monomer are useful in forming synthetic rubbers. These olefins are typically monoethylenically unsaturated monomers. "Monoethylenically unsaturated", as used herein, is characterized by the monomer having a~ C =
CH2 group. These monoethylenically unsaturated monomers are but not limited to the acrylic monomers such as methacrylic acid, acrylic acid, acrylonitrile, methacrylonitrile, methyl-acrylate, methylmethacrylate, ethylacrylate, ethylmethacrylate, acrylamide, and the like, olefinic hydrocarbons such as ethylene, butylene, propylene~ styrene, alpha-methylstyrene and the like, and other functional unsaturated monomers such as vinyl pyridine, vinyl pyrollidone and the like.
The elastomers preferred in the practice of the invention are those based upon synthetic rubber and containing preferably butadiene and acrylonitrile. It is also preferred that the elastomer have incorporated therein sites for condensation crosslinking. These sites for condensation .
:, '~:. .,' `~
crosslinking are typically acid groups imparted by acrylic acid, hydroxyl groups imparted by hydroxyethylacrylate, N-methylol groups imparted by N-methylolacrylamide and the like. These condensation crosslinking sites are required S in order to condensation interpolymerize the various polymer chains to form a crosslinked network as a tenacious and compressible binder material.
In incorporating the elastomer into the sheet material it is desired that the elastomer be in latex form by means of an anionic surface active agent or emulsifier.
Typically, these latices are provided as 40 to 60 percent solids in water. Preferably, a typical latex will have an elongation of between 800 to 1200 in the uncured state and 250 to 750 in the cured state.
Although the elastomers useful in the practice of the invention may be provided with sufficient functional groups to self-crosslink, i.e. crosslink without the addition of other materials, crosslinking agents may be added to provide the required crosslinking characteristics.
Crosslinking agents suitable in the practice of the invention include aldehydes such as formaldehyde, glyoxal, acrolien and the like; synthetic resin precondensates obtained by the reaction of an aldehyde generally with compounds con-taining nitrogen like dimethylol urea, dimethylolethylene urea, di- and trimethylol triazon dimethyluron, di- and trimethylol melamine and other cyclic or noncyclic, water soluble or non-water soluble precondensates of urea and melamine formaldehyde.
115881~
The reactive methylol groups may be blocked or partially blocked by alcohols having 1 to 4 carbon atoms. Apart from the above, other known crosslinking agents too may be used such as diepoxides and epichlorin derivatives thereof, dichlorophenols, beta substituted diethyl sulfones, sulfonium salts, N-methylolacrylamide and methylacrylamide and deriva-tives thereof, diisocyanates and the like. Up to 4 percent of the crosslinking agent may be incorporated into the sheet material. Too much crosslinking agent may render the sheet material too brittle or hard and not provide the required compressilibity for the gasket material.
Typically, the elastomeric binder composes about 8 to 65 percent by weight of the sheet material, and more preferably, 8 to 35 percent by weight based on the weight of the sheet material.
In addition to the elastomeric component of the binder a minor amount of non-elastomeric organic addition polymer such as an acrylate may be added to form the binder material, i.e. up to about 30 percent by weight, and more preferably less than 15 percent by weight. It is desirable to limit the amount of non-elastomeric polymer in relation to the elastomer elsewise the final sheet material will not have the required compressibility to be useful in forming gaskets. The non-elastomeric polymer is typically formed by the free radical, anionic or cationic addition poly-merization of unsaturated monomers. The unsaturated monomers are monoethylenically unsaturated monomers and characterized as previously describedO These monomers are typically 8 ~ ~
acrylic acid9 methacrylic acid, acrylonitrile, methacrylo-nitrile, methylmethacrylate, methylacrylate, ethylacrylate7 ethylmethacrylate, acrylamide, N~methylolacrylamide and the like. Preferably, just as in the case of the elastomers, the non-elastomeric polymer contains the crosslinking groups as previously described. Further, the non-elastomeric polymer is incorporated into the sheet material as a latex which is supplied at a solids level of about 40 to 60 percent by weight in water as an aqueous emulsion.
In a most preferred embodiment of the invention a silane coupling agent having a reactive addition polymeriz-able double bond may be copolymerized in the elastomer or in the non-elastomeric polymer. Typically, the addition polymerizable silane coupling agents have acrylate or methacrylate polymerizable groups thereon for incorporation into the binder along with hydrolyzable groups for reaction with the fibrous constituents of the sheet material.
Preferably, the silane coupling agents are vinyl triethoxy silane, 8-rnethacryloxypropyltrimethoxy silane, vinyl tris(betamethoxyethoxy) silane and the like.
The silane coupling agent monomer should be incorporated into the elastonleric or non-elastomeric polymer at a level of 2 to 15 percent by weight based on the weight of the total binder and more preferably 3 to 12 percent by weight.
The fibers useful in the practice are those capable of withstanding elevated service temperature and are of staple length. "Staple" fibers are those having a discrete length of up to 8 inches and more preferably 4 inches in length and adapted to be processed on standard papermaking equipment.
~'`'``~';' 11~8811 Generally the fibers are those capable of continuous service temperatures in excess of 1500F. These fibers are characterized as ceramic fibers and are formed of metal oxides which are resistant to high temperatures. Typically, the high temperatures are composed of alumina, silica, aluminum silicate and combinations thereof along with quartz and the like.
Typically and preferably, the fiber diameters are less than 5 microns as the mean diameter, and preferably less than 4 microns as the mean diameter. The fibrous component constitutes 15 to 50 percent by weight based on the weight of the sheet material and more preferably 20 to 30 percent by weight based on the weight of the sheet material.
In addition to those fibers which are capable of continuous service temperatures in excess of 1500F, lower temperature inorganic fibers may be used, i.e. those which are capable of withstanding 900F continuous service tempe-rature but less than 1500F continuous service temperatures.
Exemplary of these fibers are what is known as the glass microfibers, i.e. those having fiber diameters of beta, A, AA, AAA, AAAA, and AAAAAA diameter. These glass fibers may be of typical glass compositions known as E-glass, T-glass, C-glass, SF-glass and S-glass as is sold by the Owens Corning Corporation.
These glass fibers can be present in the sheet material at a level of up to 8 percent by weight based on the weight of said material and preferably at less than 5 percent by weight based on the total weight of the material.
_ g _ - . ~ .. . ..
If greater than 8 percent of the glass fibers or the like are used, substantial high temperature degradation will be encountered.
The particular fillers useful in the practice of the invention are those which have been modified to coreact with the crosslinked elastomer, Preferably, these particular fillers are inorganic in nature and the chemical modification has been by way of a silane coupling agent or Werner complex coupling agent. Typical particulate fillers are clay which can be kaolinite, halloysite, montmorittonite and illite.
Other fillers such as quartz, calsite, luminite, gypsum, muscavite and the like may also be used. The clays which have been modified with the coupling agent are those modified by the dual functional coupling agents such as silicone containing organic compound or Werner complex which establishes a bond with the inorganic filler through the metal atom and a bond with the organic binder through the organic radicals attached to the metal atom. Typically useful modifiers in the form of silane coupling agents are, but not limited to:
gamma-aminoprolyltriethoxysilane, N-bis(betahydroxyethyl)-gamma-aminopropyltriethoxysilane, N-beta(aminoethyl-gamma-aminopropyl -trimethoxy) silane, (CH30)3 Si(CH2)3 NH(CH2)2 NH(CH )2 COOCH3, gamma-glycidoxypropyltrimethoxysilane, vinyl triacetoxysilane, gamma-methacryloxypropyltrimethoxysilane, vinyl-triethoxysilane, vinyl-tris(beta-methoxyethoxy) silane, beta-3,4-epoxycyclohexyl(ethyltrimethoxy) silane, gamma-thiopropyltrimethoxysilane and the like. Preferably, the coupling agent used to modify the particulate filler is an amino silane or a mercapto silane, and most preferably a mercapto functional silane.
- : .; : . -ll58811 Preferably, the particle size desired in the filler is under 5 microns and preferably a substantial portion thereof under 2 microns, and most preferably under 1 micron.
One particularly useful filler has been found to be Nucap 190 which is a mercapto silane functional modified kaolin clay.
The particulate filler is incorporated into the sheet material at a level of 15 to 70 percent by weight and more preferably at a level of 40 to 60 percent by weight.
In forming the sheet material of the invention most advantageously standard papermaking apparatus is used such as a fourdrinier and inclined fourdrinier, a cylinder machine, a rotoformer and the like. A typical process involves charging the fibrous constituents and the filler to a pulper and dispersing them in water. The fiber dispersion is then charged to the machine chest of a fourdrinier papermaking machine. The fibrous component along with the filler are agitated with a major amount of water and a cationic polyelectrolyte in a minor amount is added to the admixture of the fibers and the filler. Typically, the cationic polyelectrolyte is a polymer having free amine groups such as a polyamine or the like. The cationic polyelectrolyte imparts a heavy charge on the fibers causing them to separate and be homogeneously dispersed in the water. To the dispersion is then charged a mixture of the crosslinking agent, if used, and the elastomeric and non-elastomeric emulsions. If a non-elastomeric latex is used which contains a silane coupling agent reacted therein, it should be charged first in order to provide intimate contact of the silane on the surface of the fibers. The elastomer and crosslinking agent are deposited on the surface of the fibers.
.
~158811 An addition of an annious colloid is charged to redisperse the fibers and to form a homogeneous dispersion of fibers having elastomer and non-elastomer and crosslinking agent coated thereon. From the machine chest the homogeneous mixture is piped towards the papermaking machine. Prior to the time it reaches the head box of the papermaking machine, al!cationic polyelectrolyte is charged in line with the dispersion which causes the coated fibers to flocculate, thus providing a flocculant at the head box. The flocculant is transferred onto the moving wire of the fourdrinier and the water is allowed to drain therefrom. After the draining of the water by gravity, suction is applied to the wet web to further remove water from the web. The web is then pressed between felt rolls and then pressed between a metal roll and a felt roll and dried. The drying temperature required is between 200 and 350F. During the drying cycle the elastomer is crosslinked and the modified filler is chemically integrated into the sheet material. The sheet material is then calendered to a uniform thickness and is taken up on rolls which can be subsequently unwound and cut into gasketing or other high temperature resistant material. In addition to the consti-tuents previously described, other known materials may be added. For example, Werner complexes of hydrophobic acids may be added to the dispersion to impart hydrophobic properties to the fibers.
-:
The following examples will further illustrate the process of practicing the invention along with specific compositions useful in forming the sheet material.
EXAMPLE
A furnish having the following composition was prepared.
Amount Solids InqredientParts bY Weiqht (percentaqe) Water A 32000 --10 Fiberfrax Hl ceramic fiber 244 22.83 Glass microfiber 28 2.62 Mercapto silane3 modified clay 486 45.47 15 Stearato chromic chloride complex 29% solids in isopropanol 28 0.86 Lufax 2904 (3% dispersion) 100 0.28 lFiberfrax H is manufactured by the Carborundum Company and is 62% AL20 and 38% S10 , has a continuous use limit of 1427C, a me~ting point above 1927C, a mean fiber diameter of 2-3 ~, and a fiber length of up to 2".
The glass microfiber was John Mansville Code 112 micro-fiber.
3The mercapto silane modified kaolin clay was Nucap 190 sold by Huber Co. and having a mean particle diameter of 0.3 ~.
4Lufax 290 is a cationic polyelectrolyte sold by Rohm and Haas.
: -1 ~S88~
Amount Solids Inqredient Parts bY Weiqht(Percentaqe) Poly M 100 (48% solids latex) 294 13.19 Melamin~ formaldehyde resin (67% solids in water) 6.7 0.41 Water B 300 Acrylic~acrylonitrile latex (48% solids in water) 294 13.19 Melamine formaldehyde resin 6.7 0.41 Water C 300 Lufax 2904 50 0.19 Deacetylated Karaya gum8 (1% solids in water)60 0.56 5Poly M 100 is a latex sold by Polymerics, Inc. having12% of a hydrolyzable silane acrylate polymerized therein, along with acrylic acid, acrylonitrile, ~-methylol acryl-amide and alkyl acrylates and is non-elastomeric.
6The melamine formaldehyde resin is sold under the trade name Resimene 842 by Monsanto Co.
7The acrylic/acrylonitrile latex is sold by Polymerics~
Inc. under the name Poly M-410. It has a % elongation of 1020 uncured and 440 cured and is self-crosslinking.
8The deacetylated Karaya gum is an anionic colloid.
~ -14-- 115~811 The water A along with the ceramic fiber and glass microfiber were charged to a pulper which was run 5 minutes and then pumped into the machine chest which was in communi-cation with a fourdrinier papermaking machine. The mercapto silane modified clay was added to the machine chest and the mixture was agitated for 10 minutes. Agitation was continued in the machine chest for the remaining portion of the charging.
The following ingredients were added in sequence: the stearato chromic chloride complex; the Lufax, a mixture of the Poly M 100, melamine formaldehyde and the water B; a mixture of the acrylic/acrylonitrile latex, melamine formal-dehyde and water C, and the addition of deacetylated karaya gum dispersion.
After a uniform dispersion in the machine chest had been achieved the dispersion was pumped towards the head box of the fourdrinier. Prior to entry into the head box the Lufax solution was metered through the fan pump in order to flocculate the fiber dispersion. The flocculant was fed onto the moving screen of the fourdrinier, water was allowed to drain by gravity, and then suction was applied. The wet web was then passed through two felt to felt presses and one roll to felt press and passed through the driers which were at approximately 280F. The process was carried out to produce a final sheet having a thickness of .0087 inches.
After drying the sheet had the following characteristics;
, Gauge in inches .0087 Basis weight, lbs./480 ft. 21.3 Basis weight, grms./dcm 2.17 Density, lbs./ft3 61.2 Tensile~ psi (1) Machine direction 1102 (2) Cross direction 709 % compression, 5000 psi 52 % initial recovery 59 The compressibility and recovery of the sheet material were measured in accordance with ASTM designation F36-66 (1973).
The gasket material was then tested in accordance with ASTM designation F39-59(1974) at 150C for 5 hours in No. 3 oil. The results of the tests were as follows:
% gauge change -1.75 % weight increase +21 % compression 5000 psi 51 /O initial recovery 30 % tensile change (1) Machine direction ~3.9 (2) Cross direction +15 Example 1 was repeated using the identical composi-tion thereof except that the process was carried out to produce a number of desired thicknesses. Table I reports the test results of the gasketing material obtained in accordance with Examples 2 - 9.
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Other olefins capable of free radical anionic or cationic addition polymerization into the polymer chain with a conjugated unsaturated monomer are useful in forming synthetic rubbers. These olefins are typically monoethylenically unsaturated monomers. "Monoethylenically unsaturated", as used herein, is characterized by the monomer having a~ C =
CH2 group. These monoethylenically unsaturated monomers are but not limited to the acrylic monomers such as methacrylic acid, acrylic acid, acrylonitrile, methacrylonitrile, methyl-acrylate, methylmethacrylate, ethylacrylate, ethylmethacrylate, acrylamide, and the like, olefinic hydrocarbons such as ethylene, butylene, propylene~ styrene, alpha-methylstyrene and the like, and other functional unsaturated monomers such as vinyl pyridine, vinyl pyrollidone and the like.
The elastomers preferred in the practice of the invention are those based upon synthetic rubber and containing preferably butadiene and acrylonitrile. It is also preferred that the elastomer have incorporated therein sites for condensation crosslinking. These sites for condensation .
:, '~:. .,' `~
crosslinking are typically acid groups imparted by acrylic acid, hydroxyl groups imparted by hydroxyethylacrylate, N-methylol groups imparted by N-methylolacrylamide and the like. These condensation crosslinking sites are required S in order to condensation interpolymerize the various polymer chains to form a crosslinked network as a tenacious and compressible binder material.
In incorporating the elastomer into the sheet material it is desired that the elastomer be in latex form by means of an anionic surface active agent or emulsifier.
Typically, these latices are provided as 40 to 60 percent solids in water. Preferably, a typical latex will have an elongation of between 800 to 1200 in the uncured state and 250 to 750 in the cured state.
Although the elastomers useful in the practice of the invention may be provided with sufficient functional groups to self-crosslink, i.e. crosslink without the addition of other materials, crosslinking agents may be added to provide the required crosslinking characteristics.
Crosslinking agents suitable in the practice of the invention include aldehydes such as formaldehyde, glyoxal, acrolien and the like; synthetic resin precondensates obtained by the reaction of an aldehyde generally with compounds con-taining nitrogen like dimethylol urea, dimethylolethylene urea, di- and trimethylol triazon dimethyluron, di- and trimethylol melamine and other cyclic or noncyclic, water soluble or non-water soluble precondensates of urea and melamine formaldehyde.
115881~
The reactive methylol groups may be blocked or partially blocked by alcohols having 1 to 4 carbon atoms. Apart from the above, other known crosslinking agents too may be used such as diepoxides and epichlorin derivatives thereof, dichlorophenols, beta substituted diethyl sulfones, sulfonium salts, N-methylolacrylamide and methylacrylamide and deriva-tives thereof, diisocyanates and the like. Up to 4 percent of the crosslinking agent may be incorporated into the sheet material. Too much crosslinking agent may render the sheet material too brittle or hard and not provide the required compressilibity for the gasket material.
Typically, the elastomeric binder composes about 8 to 65 percent by weight of the sheet material, and more preferably, 8 to 35 percent by weight based on the weight of the sheet material.
In addition to the elastomeric component of the binder a minor amount of non-elastomeric organic addition polymer such as an acrylate may be added to form the binder material, i.e. up to about 30 percent by weight, and more preferably less than 15 percent by weight. It is desirable to limit the amount of non-elastomeric polymer in relation to the elastomer elsewise the final sheet material will not have the required compressibility to be useful in forming gaskets. The non-elastomeric polymer is typically formed by the free radical, anionic or cationic addition poly-merization of unsaturated monomers. The unsaturated monomers are monoethylenically unsaturated monomers and characterized as previously describedO These monomers are typically 8 ~ ~
acrylic acid9 methacrylic acid, acrylonitrile, methacrylo-nitrile, methylmethacrylate, methylacrylate, ethylacrylate7 ethylmethacrylate, acrylamide, N~methylolacrylamide and the like. Preferably, just as in the case of the elastomers, the non-elastomeric polymer contains the crosslinking groups as previously described. Further, the non-elastomeric polymer is incorporated into the sheet material as a latex which is supplied at a solids level of about 40 to 60 percent by weight in water as an aqueous emulsion.
In a most preferred embodiment of the invention a silane coupling agent having a reactive addition polymeriz-able double bond may be copolymerized in the elastomer or in the non-elastomeric polymer. Typically, the addition polymerizable silane coupling agents have acrylate or methacrylate polymerizable groups thereon for incorporation into the binder along with hydrolyzable groups for reaction with the fibrous constituents of the sheet material.
Preferably, the silane coupling agents are vinyl triethoxy silane, 8-rnethacryloxypropyltrimethoxy silane, vinyl tris(betamethoxyethoxy) silane and the like.
The silane coupling agent monomer should be incorporated into the elastonleric or non-elastomeric polymer at a level of 2 to 15 percent by weight based on the weight of the total binder and more preferably 3 to 12 percent by weight.
The fibers useful in the practice are those capable of withstanding elevated service temperature and are of staple length. "Staple" fibers are those having a discrete length of up to 8 inches and more preferably 4 inches in length and adapted to be processed on standard papermaking equipment.
~'`'``~';' 11~8811 Generally the fibers are those capable of continuous service temperatures in excess of 1500F. These fibers are characterized as ceramic fibers and are formed of metal oxides which are resistant to high temperatures. Typically, the high temperatures are composed of alumina, silica, aluminum silicate and combinations thereof along with quartz and the like.
Typically and preferably, the fiber diameters are less than 5 microns as the mean diameter, and preferably less than 4 microns as the mean diameter. The fibrous component constitutes 15 to 50 percent by weight based on the weight of the sheet material and more preferably 20 to 30 percent by weight based on the weight of the sheet material.
In addition to those fibers which are capable of continuous service temperatures in excess of 1500F, lower temperature inorganic fibers may be used, i.e. those which are capable of withstanding 900F continuous service tempe-rature but less than 1500F continuous service temperatures.
Exemplary of these fibers are what is known as the glass microfibers, i.e. those having fiber diameters of beta, A, AA, AAA, AAAA, and AAAAAA diameter. These glass fibers may be of typical glass compositions known as E-glass, T-glass, C-glass, SF-glass and S-glass as is sold by the Owens Corning Corporation.
These glass fibers can be present in the sheet material at a level of up to 8 percent by weight based on the weight of said material and preferably at less than 5 percent by weight based on the total weight of the material.
_ g _ - . ~ .. . ..
If greater than 8 percent of the glass fibers or the like are used, substantial high temperature degradation will be encountered.
The particular fillers useful in the practice of the invention are those which have been modified to coreact with the crosslinked elastomer, Preferably, these particular fillers are inorganic in nature and the chemical modification has been by way of a silane coupling agent or Werner complex coupling agent. Typical particulate fillers are clay which can be kaolinite, halloysite, montmorittonite and illite.
Other fillers such as quartz, calsite, luminite, gypsum, muscavite and the like may also be used. The clays which have been modified with the coupling agent are those modified by the dual functional coupling agents such as silicone containing organic compound or Werner complex which establishes a bond with the inorganic filler through the metal atom and a bond with the organic binder through the organic radicals attached to the metal atom. Typically useful modifiers in the form of silane coupling agents are, but not limited to:
gamma-aminoprolyltriethoxysilane, N-bis(betahydroxyethyl)-gamma-aminopropyltriethoxysilane, N-beta(aminoethyl-gamma-aminopropyl -trimethoxy) silane, (CH30)3 Si(CH2)3 NH(CH2)2 NH(CH )2 COOCH3, gamma-glycidoxypropyltrimethoxysilane, vinyl triacetoxysilane, gamma-methacryloxypropyltrimethoxysilane, vinyl-triethoxysilane, vinyl-tris(beta-methoxyethoxy) silane, beta-3,4-epoxycyclohexyl(ethyltrimethoxy) silane, gamma-thiopropyltrimethoxysilane and the like. Preferably, the coupling agent used to modify the particulate filler is an amino silane or a mercapto silane, and most preferably a mercapto functional silane.
- : .; : . -ll58811 Preferably, the particle size desired in the filler is under 5 microns and preferably a substantial portion thereof under 2 microns, and most preferably under 1 micron.
One particularly useful filler has been found to be Nucap 190 which is a mercapto silane functional modified kaolin clay.
The particulate filler is incorporated into the sheet material at a level of 15 to 70 percent by weight and more preferably at a level of 40 to 60 percent by weight.
In forming the sheet material of the invention most advantageously standard papermaking apparatus is used such as a fourdrinier and inclined fourdrinier, a cylinder machine, a rotoformer and the like. A typical process involves charging the fibrous constituents and the filler to a pulper and dispersing them in water. The fiber dispersion is then charged to the machine chest of a fourdrinier papermaking machine. The fibrous component along with the filler are agitated with a major amount of water and a cationic polyelectrolyte in a minor amount is added to the admixture of the fibers and the filler. Typically, the cationic polyelectrolyte is a polymer having free amine groups such as a polyamine or the like. The cationic polyelectrolyte imparts a heavy charge on the fibers causing them to separate and be homogeneously dispersed in the water. To the dispersion is then charged a mixture of the crosslinking agent, if used, and the elastomeric and non-elastomeric emulsions. If a non-elastomeric latex is used which contains a silane coupling agent reacted therein, it should be charged first in order to provide intimate contact of the silane on the surface of the fibers. The elastomer and crosslinking agent are deposited on the surface of the fibers.
.
~158811 An addition of an annious colloid is charged to redisperse the fibers and to form a homogeneous dispersion of fibers having elastomer and non-elastomer and crosslinking agent coated thereon. From the machine chest the homogeneous mixture is piped towards the papermaking machine. Prior to the time it reaches the head box of the papermaking machine, al!cationic polyelectrolyte is charged in line with the dispersion which causes the coated fibers to flocculate, thus providing a flocculant at the head box. The flocculant is transferred onto the moving wire of the fourdrinier and the water is allowed to drain therefrom. After the draining of the water by gravity, suction is applied to the wet web to further remove water from the web. The web is then pressed between felt rolls and then pressed between a metal roll and a felt roll and dried. The drying temperature required is between 200 and 350F. During the drying cycle the elastomer is crosslinked and the modified filler is chemically integrated into the sheet material. The sheet material is then calendered to a uniform thickness and is taken up on rolls which can be subsequently unwound and cut into gasketing or other high temperature resistant material. In addition to the consti-tuents previously described, other known materials may be added. For example, Werner complexes of hydrophobic acids may be added to the dispersion to impart hydrophobic properties to the fibers.
-:
The following examples will further illustrate the process of practicing the invention along with specific compositions useful in forming the sheet material.
EXAMPLE
A furnish having the following composition was prepared.
Amount Solids InqredientParts bY Weiqht (percentaqe) Water A 32000 --10 Fiberfrax Hl ceramic fiber 244 22.83 Glass microfiber 28 2.62 Mercapto silane3 modified clay 486 45.47 15 Stearato chromic chloride complex 29% solids in isopropanol 28 0.86 Lufax 2904 (3% dispersion) 100 0.28 lFiberfrax H is manufactured by the Carborundum Company and is 62% AL20 and 38% S10 , has a continuous use limit of 1427C, a me~ting point above 1927C, a mean fiber diameter of 2-3 ~, and a fiber length of up to 2".
The glass microfiber was John Mansville Code 112 micro-fiber.
3The mercapto silane modified kaolin clay was Nucap 190 sold by Huber Co. and having a mean particle diameter of 0.3 ~.
4Lufax 290 is a cationic polyelectrolyte sold by Rohm and Haas.
: -1 ~S88~
Amount Solids Inqredient Parts bY Weiqht(Percentaqe) Poly M 100 (48% solids latex) 294 13.19 Melamin~ formaldehyde resin (67% solids in water) 6.7 0.41 Water B 300 Acrylic~acrylonitrile latex (48% solids in water) 294 13.19 Melamine formaldehyde resin 6.7 0.41 Water C 300 Lufax 2904 50 0.19 Deacetylated Karaya gum8 (1% solids in water)60 0.56 5Poly M 100 is a latex sold by Polymerics, Inc. having12% of a hydrolyzable silane acrylate polymerized therein, along with acrylic acid, acrylonitrile, ~-methylol acryl-amide and alkyl acrylates and is non-elastomeric.
6The melamine formaldehyde resin is sold under the trade name Resimene 842 by Monsanto Co.
7The acrylic/acrylonitrile latex is sold by Polymerics~
Inc. under the name Poly M-410. It has a % elongation of 1020 uncured and 440 cured and is self-crosslinking.
8The deacetylated Karaya gum is an anionic colloid.
~ -14-- 115~811 The water A along with the ceramic fiber and glass microfiber were charged to a pulper which was run 5 minutes and then pumped into the machine chest which was in communi-cation with a fourdrinier papermaking machine. The mercapto silane modified clay was added to the machine chest and the mixture was agitated for 10 minutes. Agitation was continued in the machine chest for the remaining portion of the charging.
The following ingredients were added in sequence: the stearato chromic chloride complex; the Lufax, a mixture of the Poly M 100, melamine formaldehyde and the water B; a mixture of the acrylic/acrylonitrile latex, melamine formal-dehyde and water C, and the addition of deacetylated karaya gum dispersion.
After a uniform dispersion in the machine chest had been achieved the dispersion was pumped towards the head box of the fourdrinier. Prior to entry into the head box the Lufax solution was metered through the fan pump in order to flocculate the fiber dispersion. The flocculant was fed onto the moving screen of the fourdrinier, water was allowed to drain by gravity, and then suction was applied. The wet web was then passed through two felt to felt presses and one roll to felt press and passed through the driers which were at approximately 280F. The process was carried out to produce a final sheet having a thickness of .0087 inches.
After drying the sheet had the following characteristics;
, Gauge in inches .0087 Basis weight, lbs./480 ft. 21.3 Basis weight, grms./dcm 2.17 Density, lbs./ft3 61.2 Tensile~ psi (1) Machine direction 1102 (2) Cross direction 709 % compression, 5000 psi 52 % initial recovery 59 The compressibility and recovery of the sheet material were measured in accordance with ASTM designation F36-66 (1973).
The gasket material was then tested in accordance with ASTM designation F39-59(1974) at 150C for 5 hours in No. 3 oil. The results of the tests were as follows:
% gauge change -1.75 % weight increase +21 % compression 5000 psi 51 /O initial recovery 30 % tensile change (1) Machine direction ~3.9 (2) Cross direction +15 Example 1 was repeated using the identical composi-tion thereof except that the process was carried out to produce a number of desired thicknesses. Table I reports the test results of the gasketing material obtained in accordance with Examples 2 - 9.
~ -16-1 1588~ 1 . o u~ o o ~ ul ~~n ~ ~d' ~ ~ ~n o In 1`1~ ~ + +
U~
~0~ ~ O 1` 0 ~ O ~ ' '' ~ n t~ + + ~_I+ +
O O O~ ~~ u~ ~ D ~ ~ I`
~ ~ + + ~,1+ +
OD ~ `' _I 0 ~ ~ D O
o1` - ~o ~ ) ~~1 ~N_I ~J
d' d'~O~1 ~d' + + ~ + +
ul O ~ O ~ a~
~ ~ + + ~ + + :, H
:' . ' ~ ~N ~n d' . .~J~ ~ d' E~l O ~D~D N ~ 0 ~ 0r~ Nd'~ ~
ID ~r` r`~ ~ + + ~, N + +
Na~
~1 1~ t~ N
O N ~D 00 N N O N N ~r O
+ + ~~+ +
~I` ~~D~I d'01` 0 d' 0 O ~ I 0 1~1~ ~--1N a~1~ r-l N
~, O :`:
U) .,1 ,_~
N ~
~I N U~ Q, O ~ O g ~ O ~ O ~' 0 ~ ~ ~ O ~ 1 C O~1 rl ~
o u ~ ~ ~q o ~ a~ ~ o U rl ~ ~ U-~l ^ Orla~~ o~ ~ ~
O~ ~ U
3 3 :~ ~ rl uq ~1 rl tJI a) S h ,1 -I rl u~
~ 1 U O ~ U O
X~ u u ~ 3 U~ U
m m ~ E~ ~ ~ E~ ~ ~ ~ ~ ~
Surprisingly, there was an increase in tensile strength after testing the gasket material in oil at high temperature where in normal gasketing materials there is a decrease in strength. Further, the material substantially maintains its compressibility after the oil emersion test which makes it ideal for high temperature gasketing material.
Further, tests have been run which show that the gasketing material is excellent in marine applications and in high temperature automotive applications.
In another application for the heat resistant material of the present invention it has been found to demonstrate insulating characteristics when used as a heat shield and the like in isolating high temperature components from necessarily low temperature operating components in automobiles. Thus, in an automobile, it is an excellent material to provide a heat shield between a catalytic converter which operates at extremely high temperatures to isolate it from the frame and body portions and appurtenant components in the undercarriage of an automobile. Further~ it is useful in the firewall of an automobile to isolate the engine compartment from the passenger compartment.
Thus, although the invention has been described with reference to specific processes and specific materials, it is only to be limited so far as is set forth in the accompanying claims.
;~
~ 1 U O ~ U O
X~ u u ~ 3 U~ U
m m ~ E~ ~ ~ E~ ~ ~ ~ ~ ~
Surprisingly, there was an increase in tensile strength after testing the gasket material in oil at high temperature where in normal gasketing materials there is a decrease in strength. Further, the material substantially maintains its compressibility after the oil emersion test which makes it ideal for high temperature gasketing material.
Further, tests have been run which show that the gasketing material is excellent in marine applications and in high temperature automotive applications.
In another application for the heat resistant material of the present invention it has been found to demonstrate insulating characteristics when used as a heat shield and the like in isolating high temperature components from necessarily low temperature operating components in automobiles. Thus, in an automobile, it is an excellent material to provide a heat shield between a catalytic converter which operates at extremely high temperatures to isolate it from the frame and body portions and appurtenant components in the undercarriage of an automobile. Further~ it is useful in the firewall of an automobile to isolate the engine compartment from the passenger compartment.
Thus, although the invention has been described with reference to specific processes and specific materials, it is only to be limited so far as is set forth in the accompanying claims.
;~
Claims (23)
1. A high temperature resistant compressible water laid sheet material having a fibrous constituent and a thickness of 0.001 to 1 inch comprising:
(a) 8 to 65 percent by weight of a binder including a crosslinkable elastomer and a silane coupling agent copolymerized within said binder at a level of at least about 2 percent by weight;
(b) a crosslinking agent for said elastomer, (c) 15 to 70 percent by weight of a inorganic particulate filler which has been chemically modified to coreact with the crosslinked elastomer, and (d) 15 to 50 percent by weight of high temperature nonasbestos staple fibers, said material capable of withstanding service temperatures of 500°F and being oil and water resistant.
(a) 8 to 65 percent by weight of a binder including a crosslinkable elastomer and a silane coupling agent copolymerized within said binder at a level of at least about 2 percent by weight;
(b) a crosslinking agent for said elastomer, (c) 15 to 70 percent by weight of a inorganic particulate filler which has been chemically modified to coreact with the crosslinked elastomer, and (d) 15 to 50 percent by weight of high temperature nonasbestos staple fibers, said material capable of withstanding service temperatures of 500°F and being oil and water resistant.
2. The material of claim 1 wherein said particulate filler is present at a level of 40 to 60 percent by weight based on the total weight of said material.
3. The material of claim 1 wherein the particulate filler is a clay.
4. The material of claim 1 wherein said particulate filler has been modified by a coupling agent.
5. The material of claim 4 wherein said coupling agent is a silane coupling agent.
6. The material of claim 5 wherein said silane coupling agent is selected from the group consisting of an amino functional silane coupling agent and a mercapto-functional silane coupling agent.
7. The material of claim 1 wherein the silane coupling agent is addition copolymerized with the elastomer.
8. The material of claim 1 having a thickness of 0.001 to 1/4 inch.
9. The material of claim 1 wherein said elastomer has acrylonitrile polymerized therein.
10. The material of claim 1 wherein said elastomer is present at a level of 8 to 35 percent by weight based on the weight of said sheet material.
11. The material of claim 1 wherein said binder includes 8 to 30 percent by weight of a crosslinkable nonelastomeric polymer.
12. The material of claim 1 including a silane coupling agent copolymerized with said elastomer.
13. The material of claim 11 including a silane coupling agent copolymerized with said non-elastomeric polymer.
14. The material of claim 1 wherein said crosslinking agent is selected from the group consisting of melamine formaldehyde resins, urea formaldehyde resins and resorcinol formaldehyde resins.
15. The material of claim 1 wherein said crosslinking agent is present at a level of 0.7-4 percent by weight based on the weight of said material.
16. The material of claim 1 wherein said high temperature staple fibers are inorganic.
17. The material of claim 1 wherein said high temperature fibers are capable of withstanding 1500°F
continuous service temperature.
continuous service temperature.
18. The material of claim 17 wherein said fibers are composed of alumina/silica fibers.
19. The material of claim 1 wherein said fibers are present at a level of 20 to 30 percent by weight.
20. The material of claim 17 including a minor amount of fibers which are capable of withstanding 900° F
but not 1500°F continuous service temperature.
but not 1500°F continuous service temperature.
21. The material of claim 20 wherein said fibers capable of withstanding 900°F are glass microfibers.
22. The material of claim 20 wherein said fibers capable of withstanding 900°F are present at a level of up to 8 percent by weight based on the weight of said material.
23. A high temperature resistant compressible water laid sheet material having a thickness of 0.001 to 1 inch comprising:
20 to 30 percent by weight of inorganic nonasbestos stable fibers having a service temperature in excess of 1500°F;
up to 8 percent by weight of inorganic staple fibers having a service temperature greater than 900°F but not in excess of 1500°F;
20 to 30 percent by weight of a crosslinked elastomeric binder having a silane coupling agent polymerized therein at a level of at least about 2 percent by weight; and 40 to 50 percent by weight of an inorganic filler which has been modified to coreact with said elastomeric binder, said material capable of withstanding continuous service temperatures in excess of 500°F and being oil and water resistant.
20 to 30 percent by weight of inorganic nonasbestos stable fibers having a service temperature in excess of 1500°F;
up to 8 percent by weight of inorganic staple fibers having a service temperature greater than 900°F but not in excess of 1500°F;
20 to 30 percent by weight of a crosslinked elastomeric binder having a silane coupling agent polymerized therein at a level of at least about 2 percent by weight; and 40 to 50 percent by weight of an inorganic filler which has been modified to coreact with said elastomeric binder, said material capable of withstanding continuous service temperatures in excess of 500°F and being oil and water resistant.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US099,619 | 1979-12-03 | ||
US06/099,619 US4308093A (en) | 1979-12-03 | 1979-12-03 | High temperature resistant compressible sheet material for gasketing and the like |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1158811A true CA1158811A (en) | 1983-12-20 |
Family
ID=22275863
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000365914A Expired CA1158811A (en) | 1979-12-03 | 1980-12-02 | High temperature resistant compressible sheet material for gasketing and the like |
Country Status (5)
Country | Link |
---|---|
US (1) | US4308093A (en) |
JP (1) | JPS601339B2 (en) |
CA (1) | CA1158811A (en) |
DE (1) | DE3045584C2 (en) |
FR (1) | FR2471272B1 (en) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4618401A (en) * | 1982-02-02 | 1986-10-21 | Texon, Inc. | Battery separator material |
JPS58147341A (en) * | 1982-02-25 | 1983-09-02 | Nippon Pillar Packing Co Ltd | Plasticized packing |
US4389282A (en) * | 1982-08-06 | 1983-06-21 | Combustion Engineering, Inc. | Ceramic fiber board |
US4549931A (en) * | 1983-01-27 | 1985-10-29 | Corning Glass Works | Inorganic binders for articles formed from fibers |
JPS62148139U (en) * | 1986-03-14 | 1987-09-18 | ||
JPS6310940U (en) * | 1986-07-08 | 1988-01-25 | ||
JPH0643526B2 (en) * | 1987-06-11 | 1994-06-08 | 大塚化学株式会社 | Rubber composition |
DE68916967T2 (en) * | 1988-09-30 | 1994-12-15 | Arjo Wiggins Sa | Basic composition for the production of a flexible and porous sheet product consisting essentially of elastomer powder, as well as the product obtained and process for the production. |
FR2639001B1 (en) * | 1988-10-26 | 1991-04-12 | Arjomari Prioux | BASIC COMPOSITION FOR THE MANUFACTURE OF A FLEXIBLE AND POROUS SHEET PRODUCT BASED ON ELASTOMER POWDER, SHEET PRODUCT AND PROCESS FOR PREPARING THE SAME |
ES2099119T3 (en) * | 1990-12-05 | 1997-05-16 | Ppg Industries Inc | FIBER THERMOPLASTIC MATERIAL FORMED WET AND AQUEOUS DISPERSION FOR ITS PREPARATION. |
US5590524A (en) * | 1992-05-14 | 1997-01-07 | Soundwich, Inc. | Damped heat shield |
US5830305A (en) * | 1992-08-11 | 1998-11-03 | E. Khashoggi Industries, Llc | Methods of molding articles having an inorganically filled organic polymer matrix |
US6855404B2 (en) * | 2003-03-13 | 2005-02-15 | E. I. Du Pont De Nemours And Company | Inorganic sheet laminate |
US7585559B2 (en) | 2003-06-03 | 2009-09-08 | Intellectual Property Holdings, Llc | Foam barrier heat shield |
JP2007092904A (en) * | 2005-09-29 | 2007-04-12 | Nichias Corp | Sheet gasket and its manufacturing method |
US7799840B2 (en) | 2006-09-12 | 2010-09-21 | Intellectual Property Holdings, Llc | Thermoplastic vibrational damper with constraining layer |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB858555A (en) * | 1956-12-24 | 1961-01-11 | Columbia Southern Chem Corp | Unsaturated organo-silicon derivatives, methods for preparing same and the treatmentof siliceous pigments therewith |
US3036950A (en) * | 1959-06-22 | 1962-05-29 | Burgess Cellulose Company | Process for incorporating resins into paper |
US3109769A (en) * | 1961-07-27 | 1963-11-05 | Ray C Martin | Process for incorporating resins into paper |
US3567680A (en) * | 1968-05-03 | 1971-03-02 | Huber Corp J M | Surface modified pigments and methods for producing same and elastomers containing same |
BE754331A (en) * | 1969-08-04 | 1971-02-03 | Dow Corning | NEW MERCAPTOMETHYLALKOXYSILANES AND THEIR PREPARATION |
US3649320A (en) * | 1970-02-16 | 1972-03-14 | Du Pont | Coupling agent copolymers of amine silicates and organofunctional silanes |
US3834924A (en) * | 1972-06-08 | 1974-09-10 | Huber Corp J M | Process for manufacturing surface modified inorganic pigments |
US3847848A (en) * | 1972-12-04 | 1974-11-12 | Gen Electric | Two-part room temperature vulcanizable silicone rubber compositions |
AR207457A1 (en) * | 1974-01-10 | 1976-10-08 | Degussa | ADHESIVE RUBBER MIXTURE TO IMPROVE ADHESIVENESS OF VULCANIZABLE MIXTURES OF TEXTILES OR METALLIC FABRICS AFTER VULCANIZING |
CA1046681A (en) * | 1974-06-25 | 1979-01-16 | Union Carbide Corporation | Mercapto-silane coupler-inorganic powder mixtures |
US4048137A (en) * | 1975-11-05 | 1977-09-13 | Johns-Manville Corporation | Elastomeric materials reinforced with small diameter glass fibers |
JPS5313657A (en) * | 1976-07-26 | 1978-02-07 | Showa Electric Wire & Cable Co Ltd | Flame-retardant rubber compositions |
US4225383A (en) * | 1978-02-02 | 1980-09-30 | The Dow Chemical Company | Highly filled sheets and method of preparation thereof |
-
1979
- 1979-12-03 US US06/099,619 patent/US4308093A/en not_active Expired - Lifetime
-
1980
- 1980-12-02 JP JP55169210A patent/JPS601339B2/en not_active Expired
- 1980-12-02 CA CA000365914A patent/CA1158811A/en not_active Expired
- 1980-12-03 FR FR8025648A patent/FR2471272B1/fr not_active Expired
- 1980-12-03 DE DE3045584A patent/DE3045584C2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE3045584A1 (en) | 1981-08-13 |
US4308093A (en) | 1981-12-29 |
FR2471272B1 (en) | 1983-07-22 |
JPS5692935A (en) | 1981-07-28 |
FR2471272A1 (en) | 1981-06-19 |
DE3045584C2 (en) | 1985-11-07 |
JPS601339B2 (en) | 1985-01-14 |
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