CA1177594A - Golf ball - Google Patents
Golf ballInfo
- Publication number
- CA1177594A CA1177594A CA000354810A CA354810A CA1177594A CA 1177594 A CA1177594 A CA 1177594A CA 000354810 A CA000354810 A CA 000354810A CA 354810 A CA354810 A CA 354810A CA 1177594 A CA1177594 A CA 1177594A
- Authority
- CA
- Canada
- Prior art keywords
- golf ball
- polyester
- diisocyanate
- range
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/0023—Covers
- A63B37/0029—Physical properties
- A63B37/0036—Melt flow rate [MFR]
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/005—Cores
- A63B37/0051—Materials other than polybutadienes; Constructional details
- A63B37/0052—Liquid cores
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B37/00—Solid balls; Rigid hollow balls; Marbles
- A63B37/0003—Golf balls
- A63B37/007—Characteristics of the ball as a whole
- A63B37/0072—Characteristics of the ball as a whole with a specified number of layers
- A63B37/0075—Three piece balls, i.e. cover, intermediate layer and core
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
- C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S273/00—Amusement devices: games
- Y10S273/08—Urethane
Abstract
ABSTRACT OF THE DISCLOSURE
Golf balls are provided having a thermoplastic polyesterurethane cover comprising the reaction product of a polyester having a molecular weight from about 800 to 1500 reacted with para-phenylene dlisocyanate or 1,4-cyclohexane diisocyanate, which is thereafter molded around a golf ball core.
Golf balls are provided having a thermoplastic polyesterurethane cover comprising the reaction product of a polyester having a molecular weight from about 800 to 1500 reacted with para-phenylene dlisocyanate or 1,4-cyclohexane diisocyanate, which is thereafter molded around a golf ball core.
Description
~ 7 7~ P~
~ 1 --IMPROVED GOLF BALL
BACKGROUND OF _TI~E INVENTION
Naturally occuring balata is the standard for golf ball covers and is the standard in processabillty and properties for substitutes therefor. Unfortunately balata is expensive, difficult to obtain and since it occurs naturally, it presents problems in lack of uni-formity from batch to batch. Many substitutes Eor balata have been proposed for golf ball covers. Among 10 them has been the polyesterurethane described in U.S.
Patent 3,034,791 wherein a golf ball cover is described that is the reaction product of 1 mol of polytetra-methyleneether glycol r 2 mols of an isomeric mixture of toluene-2,4-diisocyanate, and about 25 percent of 15 toluene 2,6-diisocyanate, with 16 weight parts of 4,4'-methylene-bis(2-chloroanaline) as a curing or cross-linking agent. This material, patented in 1962 r has several disadvantages. First r the curing agent is a toxic material. Second r as taught in the Patent r the 20 handling time for the reaction product of the diiso-cyanate-polytetramethyleneether glycol is critical and results in handling problems in processing. The patent teaches that when short aging times are usedr the golf ball cover stock may have poor golf ball core centering 25 and thread show-through. When long aging times are involved, cover penetration of the stocks into thread interstices is limited, resulting in poor cover adhes-ion, uneven compression, and the like. Improved mater-ials for go]f ball covers are an objective of this 30 invention.
SUM~AR~ OF THE INVENTION
Improved golf balls and covers therefor are obtained when said cover comprises the reaction product of a polyester glycol of aliphatic glycols containing 2 to 8 carbon atoms and aliphatic dicarboxylic acids 7t7 r i ~ ~ ~
containlng 4 to 8 carbon atoms, and havlny a molecular weight of about 800 to 1500, reacted with about a molar equivalent, ie 0.96 to 1.02 mols of para~phen~lene diisocyanate or cyclohexane diisocyanate in the sub-` 5 stantial absence of curing or crosslinking agents to result in a thermo-plastic, readily moldable gol~ ball cover stock.
DETAI~ED_DESCRIPTION
- i The polyesters are readily prepared from aliphatic glycols containing 2 to 8 carbon atoms, in-cluding for example ethanediol, butanediol-1,4, hexane-diol-1,6, and the like. The aliphatic dicarboxylic acids contain 4 to 8 carbon atoms including for example adipic, pimelic and suberic acids. Preferred polyesters are obtained from glycols and acids containing 4 to 6 carbon atoms, a prefered acid is adipic acid. The polyesters have molecular weights in the range of about 800 to 1500, usually about 850 to 1100 Golf ball cover stock with polyesters of about 2000 molecular weight normally do not have optimum physical properties.
The diisocyanates used are para-phenylene diisocyanate and 1,4-cyclohexane diisocyanate. Hexa-methylene diisocyanate is not satisfactory, nor are the toluene diisocyanates. Improved golf ball cover stocks are obtained with polyurethanes from diphenylmethane-p,p'-diisocyanate, but such materials do not provide the optlmum balance of desired properties as do para-phenylene diisocyanate and 1,4-cyclohexane diisocyanate.
The molar ratio of diisocyanate to polyester is from about 0.96 to about 1.02 mols of diisocyanate per mol of polyester, preferably about 0.98 to about 1.0 mols of diisocyanate per mol of polyester.
The melting temperature of the resulting polyesterurethane is important to obtaining satisfactory j 35 results in improved golf ball covers, and must be greater than 70C up to about 110C, preferably the ..
. -- 3 ~
"
. melting point of the polyester urethane is in the xange of about 75 to 100C. measured by a differential scanning calorimeter. A paxticularly useul range is 80 . to 90C. The desired polyesterurethanes also have a i 5 melt index in the range of about 15 to 50.
.: : The use of chain extenders in ma~ing the poly-. urethanes is not desired. For example, when small amounts of butanediol~l,4 are mixed with a polyester . before reaction with the diisocyanate, or thereafter ' ! 10 when an excess of diisocyanate is used.with the poly-ester, the addition results in polyurethanes -that do not have the desired balance of properties to provide good ~ golf ball covers. Similarly, the use of curing or crosslinking agents is not desired because of the . 15 resulting handling difficulties in the plant, both in . compounding and hold-up before molding, and since a thermoplastic polyurethane is then not obtained.
. These polyesterurethanes may be used to make . both 2 piece and 3 piece golf balls by any of the .: 20 techniques now being used and well known in the golf ball art. The covers from the defined polyesterure-thanes may be injection molded or compression molded, . and in either case provide satisfactory golf balls having a satisfactory balance of good physical prop-erties. In compression molding, for example, two sepa-. rate pieces of the polyester urethanes are formed and then placed in a mold around the golf ball core attemperatures normally greater than about 250F to about 300F for about 5 minutes and allowed to cool down in the mold. 275 to 280 F is the usual operating range.
In a typical preparation of a polyesterure-thane useful as a golf ball cover, 450 weight-parts of poly(tetramethylene adipate) glycol having a number average molecular weight of 957 and an acid number of 1.1 was heated to 104C. While stirring, -the molten polyester, 73.7 parts of p-phenylene diisocyanate was '7 ~
added. At this point compounding additives such as titanium dioxide and other pigments, processing aids as wax and molding aids such as fatty acid esters of dihydric alcohols may be added if desired. It is an advantage of these polyester urethanes that such aids are not necessary and in this example are not added.
The resulting mixture was stirred for three minutes to 180C. The polymer was poured onto a tray and allowed to cool. After one week, this polyesterurethane had a i 10 melt index of 18.3 determined according to ASTM n-1238, Procedure A, at a barrel temperature of 175C, a 6 minute preheat, and a 2,160 piston load.
Samples of this polyester urethane were com pression molded into half-shells and cooled. Thereafter the half-shells were positioned in a mold on either side of a golf ball core comprising a solid center and a rubber thread winding, and molded at 280F for 5 minutes and cooled in the mold. The resulting golf--balls were found, as compared to balata covered three piece balls, to have equivalent and comparable compression, initial velocity, cut resistance, uniformity and paintability.
An important advant.age of the defined polyesterurethanes in painting is that no chemical pre-treatmerlt of the surface, or use of a primer was required to obtain satisfactory adhesion of the paint. The balls had satisfactory driving characteristics. This balance of ` desirable physical properties indicates excellent and uniform adhesion to the rubber threads of the golf ball cores. Balls were cut and it was found tha~ there was excellent physical adhesion of the rubber threads to the inner surface of the defined polyesterurethane golf ball cover. If the adhesion to the rubber winding is not good, durability is harmed, the cover will dis-tort and the balls tend -to be "ou-t of round" and have an unde--35 sirable loss of compression. It is one of the advan-tages of the polyester urethanes of this invention that .
~ ~ O' f ~ f~
excellent and uniform adhesion to the rubber winding is , obtained without noticeable degradation or des-truc-tion of these rubber windings.
-Three piece golf balls, as is well known in ! 5 the art, normally comprise solid or liquid centers, rubber thread windings and a co~er. The polyester-urethanes of this invention are particularly useful in a three piece ball. The two piece ball normally comprises a solid core and a cover. Such core is normally a i10 vulcanized rubber core. The polyesterurethanes of this ` invention provide satisfactory 2 piece golf balls and to demonstrate this the polyesterurethane described above is injection molded over a solid cured rubber core. The resulting ball is satisfactory.
In addition to the excellent adhesion to the core obtained with the defined polyesterurethanes, and paintability, these advantages were obtained using substantially the polyesterurethanes as is in a thermo-plastic state without the necessity for adding the usual ~20 compounding ingredients, although they may be used if desired, titanium dioxide for example, and without a curing o c~osslinking ageAt.
-
~ 1 --IMPROVED GOLF BALL
BACKGROUND OF _TI~E INVENTION
Naturally occuring balata is the standard for golf ball covers and is the standard in processabillty and properties for substitutes therefor. Unfortunately balata is expensive, difficult to obtain and since it occurs naturally, it presents problems in lack of uni-formity from batch to batch. Many substitutes Eor balata have been proposed for golf ball covers. Among 10 them has been the polyesterurethane described in U.S.
Patent 3,034,791 wherein a golf ball cover is described that is the reaction product of 1 mol of polytetra-methyleneether glycol r 2 mols of an isomeric mixture of toluene-2,4-diisocyanate, and about 25 percent of 15 toluene 2,6-diisocyanate, with 16 weight parts of 4,4'-methylene-bis(2-chloroanaline) as a curing or cross-linking agent. This material, patented in 1962 r has several disadvantages. First r the curing agent is a toxic material. Second r as taught in the Patent r the 20 handling time for the reaction product of the diiso-cyanate-polytetramethyleneether glycol is critical and results in handling problems in processing. The patent teaches that when short aging times are usedr the golf ball cover stock may have poor golf ball core centering 25 and thread show-through. When long aging times are involved, cover penetration of the stocks into thread interstices is limited, resulting in poor cover adhes-ion, uneven compression, and the like. Improved mater-ials for go]f ball covers are an objective of this 30 invention.
SUM~AR~ OF THE INVENTION
Improved golf balls and covers therefor are obtained when said cover comprises the reaction product of a polyester glycol of aliphatic glycols containing 2 to 8 carbon atoms and aliphatic dicarboxylic acids 7t7 r i ~ ~ ~
containlng 4 to 8 carbon atoms, and havlny a molecular weight of about 800 to 1500, reacted with about a molar equivalent, ie 0.96 to 1.02 mols of para~phen~lene diisocyanate or cyclohexane diisocyanate in the sub-` 5 stantial absence of curing or crosslinking agents to result in a thermo-plastic, readily moldable gol~ ball cover stock.
DETAI~ED_DESCRIPTION
- i The polyesters are readily prepared from aliphatic glycols containing 2 to 8 carbon atoms, in-cluding for example ethanediol, butanediol-1,4, hexane-diol-1,6, and the like. The aliphatic dicarboxylic acids contain 4 to 8 carbon atoms including for example adipic, pimelic and suberic acids. Preferred polyesters are obtained from glycols and acids containing 4 to 6 carbon atoms, a prefered acid is adipic acid. The polyesters have molecular weights in the range of about 800 to 1500, usually about 850 to 1100 Golf ball cover stock with polyesters of about 2000 molecular weight normally do not have optimum physical properties.
The diisocyanates used are para-phenylene diisocyanate and 1,4-cyclohexane diisocyanate. Hexa-methylene diisocyanate is not satisfactory, nor are the toluene diisocyanates. Improved golf ball cover stocks are obtained with polyurethanes from diphenylmethane-p,p'-diisocyanate, but such materials do not provide the optlmum balance of desired properties as do para-phenylene diisocyanate and 1,4-cyclohexane diisocyanate.
The molar ratio of diisocyanate to polyester is from about 0.96 to about 1.02 mols of diisocyanate per mol of polyester, preferably about 0.98 to about 1.0 mols of diisocyanate per mol of polyester.
The melting temperature of the resulting polyesterurethane is important to obtaining satisfactory j 35 results in improved golf ball covers, and must be greater than 70C up to about 110C, preferably the ..
. -- 3 ~
"
. melting point of the polyester urethane is in the xange of about 75 to 100C. measured by a differential scanning calorimeter. A paxticularly useul range is 80 . to 90C. The desired polyesterurethanes also have a i 5 melt index in the range of about 15 to 50.
.: : The use of chain extenders in ma~ing the poly-. urethanes is not desired. For example, when small amounts of butanediol~l,4 are mixed with a polyester . before reaction with the diisocyanate, or thereafter ' ! 10 when an excess of diisocyanate is used.with the poly-ester, the addition results in polyurethanes -that do not have the desired balance of properties to provide good ~ golf ball covers. Similarly, the use of curing or crosslinking agents is not desired because of the . 15 resulting handling difficulties in the plant, both in . compounding and hold-up before molding, and since a thermoplastic polyurethane is then not obtained.
. These polyesterurethanes may be used to make . both 2 piece and 3 piece golf balls by any of the .: 20 techniques now being used and well known in the golf ball art. The covers from the defined polyesterure-thanes may be injection molded or compression molded, . and in either case provide satisfactory golf balls having a satisfactory balance of good physical prop-erties. In compression molding, for example, two sepa-. rate pieces of the polyester urethanes are formed and then placed in a mold around the golf ball core attemperatures normally greater than about 250F to about 300F for about 5 minutes and allowed to cool down in the mold. 275 to 280 F is the usual operating range.
In a typical preparation of a polyesterure-thane useful as a golf ball cover, 450 weight-parts of poly(tetramethylene adipate) glycol having a number average molecular weight of 957 and an acid number of 1.1 was heated to 104C. While stirring, -the molten polyester, 73.7 parts of p-phenylene diisocyanate was '7 ~
added. At this point compounding additives such as titanium dioxide and other pigments, processing aids as wax and molding aids such as fatty acid esters of dihydric alcohols may be added if desired. It is an advantage of these polyester urethanes that such aids are not necessary and in this example are not added.
The resulting mixture was stirred for three minutes to 180C. The polymer was poured onto a tray and allowed to cool. After one week, this polyesterurethane had a i 10 melt index of 18.3 determined according to ASTM n-1238, Procedure A, at a barrel temperature of 175C, a 6 minute preheat, and a 2,160 piston load.
Samples of this polyester urethane were com pression molded into half-shells and cooled. Thereafter the half-shells were positioned in a mold on either side of a golf ball core comprising a solid center and a rubber thread winding, and molded at 280F for 5 minutes and cooled in the mold. The resulting golf--balls were found, as compared to balata covered three piece balls, to have equivalent and comparable compression, initial velocity, cut resistance, uniformity and paintability.
An important advant.age of the defined polyesterurethanes in painting is that no chemical pre-treatmerlt of the surface, or use of a primer was required to obtain satisfactory adhesion of the paint. The balls had satisfactory driving characteristics. This balance of ` desirable physical properties indicates excellent and uniform adhesion to the rubber threads of the golf ball cores. Balls were cut and it was found tha~ there was excellent physical adhesion of the rubber threads to the inner surface of the defined polyesterurethane golf ball cover. If the adhesion to the rubber winding is not good, durability is harmed, the cover will dis-tort and the balls tend -to be "ou-t of round" and have an unde--35 sirable loss of compression. It is one of the advan-tages of the polyester urethanes of this invention that .
~ ~ O' f ~ f~
excellent and uniform adhesion to the rubber winding is , obtained without noticeable degradation or des-truc-tion of these rubber windings.
-Three piece golf balls, as is well known in ! 5 the art, normally comprise solid or liquid centers, rubber thread windings and a co~er. The polyester-urethanes of this invention are particularly useful in a three piece ball. The two piece ball normally comprises a solid core and a cover. Such core is normally a i10 vulcanized rubber core. The polyesterurethanes of this ` invention provide satisfactory 2 piece golf balls and to demonstrate this the polyesterurethane described above is injection molded over a solid cured rubber core. The resulting ball is satisfactory.
In addition to the excellent adhesion to the core obtained with the defined polyesterurethanes, and paintability, these advantages were obtained using substantially the polyesterurethanes as is in a thermo-plastic state without the necessity for adding the usual ~20 compounding ingredients, although they may be used if desired, titanium dioxide for example, and without a curing o c~osslinking ageAt.
-
Claims (6)
1. A golf ball comprising a core and a polyester-urethane cover comprising the reaction product of a poly-ester of an aliphatic diol containing 2 to 8 carbon atoms and an aliphatic dicarboxylic acid containing 4 to 8 carbon atoms, said polyester having a molecular weight of about 800 to about 1500, reacted with para-phenylene diisocyanate or 1,4-cyclohexane diisocyanate in a molar ratio of about 0.96 to 1.02 mols of diisocyanate per mol of polyester.
2. A golf ball of claim 1, wherein said glycol and acid each contain 4 to 6 carbon atoms, the polyester mole-cular weight is about 850 to 1,100, the molar ratio of di-isocyanate to polyester is 0.98 to 1.01 and the melt index of the polyesterurethane is in the range of about 15 to 50.
3. A composition of claim 2, wherein the dicarboxylic is adipic acid, the diisocyanate is paraphenylene diiso-cyanate and the molar ratio of diisocyanate to polyester is about 0.98 to 1Ø
4. A golf ball of claim 3, wherein said polyester is poly(tetramethylene adipate) having a molecular weight in the range of about 900 to 1,050 and the melt index is in the range of about 15 to 25.
5. A golf ball of claim 1, wherein said golf ball is a three piece golf ball comprising a liquid or solid center, rubber winding and said polyesterurethane as a cover therefor.
6. A golf ball of claim 1 or 5, wherein said poly-esterurethane has a melt index in the range of about 15 to 50.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US057,633 | 1979-07-16 | ||
US06/057,633 US4248432A (en) | 1979-07-16 | 1979-07-16 | Golf ball |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1177594A true CA1177594A (en) | 1984-11-06 |
Family
ID=22011824
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000354810A Expired CA1177594A (en) | 1979-07-16 | 1980-06-25 | Golf ball |
Country Status (2)
Country | Link |
---|---|
US (1) | US4248432A (en) |
CA (1) | CA1177594A (en) |
Families Citing this family (115)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4373804A (en) * | 1979-04-30 | 1983-02-15 | Diffracto Ltd. | Method and apparatus for electro-optically determining the dimension, location and attitude of objects |
US4349657A (en) * | 1981-09-28 | 1982-09-14 | The B. F. Goodrich Company | Polyurethane process |
US4442282A (en) * | 1983-06-20 | 1984-04-10 | The B. F. Goodrich Company | Polyurethane covered golf balls |
US4674751A (en) * | 1984-12-10 | 1987-06-23 | Spalding & Evenflo Companies, Inc. | Golf ball having improved playability properties |
FR2640880A1 (en) * | 1988-12-22 | 1990-06-29 | Shemsy Sa | Improved tennis ball, new pressureless structure, and process for its manufacture |
US6855073B1 (en) * | 1998-03-18 | 2005-02-15 | Callaway Golf Company | Golf ball which includes fast-chemical-reaction-produced component and method of making same |
US6506130B2 (en) | 1993-06-01 | 2003-01-14 | Spalding Sports Worldwide, Inc. | Multi layer golf ball |
US6824476B2 (en) | 1993-06-01 | 2004-11-30 | Callaway Golf Company | Multi-layer golf ball |
US6290614B1 (en) | 1998-03-18 | 2001-09-18 | Spalding Sports Worldwide, Inc. | Golf ball which includes fast-chemical-reaction-produced component and method of making same |
US6695718B2 (en) | 1993-06-01 | 2004-02-24 | The Top-Flite Golf Company | Golf ball with sulfur cured inner core component |
US6548618B2 (en) * | 1993-06-01 | 2003-04-15 | Spalding Sports Worldwide, Inc. | Golf ball having dual core and thin polyurethane cover formed by RIM |
US6287217B1 (en) | 1993-06-01 | 2001-09-11 | Spalding Sports Worldwide, Inc. | Multi-layer golf ball |
US6638185B2 (en) | 1993-06-01 | 2003-10-28 | The Top-Flite Golf Company | Multi-layer golf ball |
US7494427B2 (en) * | 2001-11-05 | 2009-02-24 | Callaway Golf Company | Multi-layer golf ball |
US6210293B1 (en) | 1993-06-01 | 2001-04-03 | Spalding Sports Worldwide, Inc. | Multi-layer golf ball |
US6663508B1 (en) | 1993-06-01 | 2003-12-16 | Callaway Golf Company | Multi-layer golf ball with reaction injection molded polyurethane component |
US6648777B2 (en) * | 1993-06-01 | 2003-11-18 | Callaway Golf Company | Multi-layer golf ball |
US5461109A (en) * | 1994-01-21 | 1995-10-24 | Guardsman Products, Inc. | Water-reducible golf ball coating |
US7015300B2 (en) * | 1995-06-07 | 2006-03-21 | Acushnet Company | Multilayered golf ball and composition |
US5929189A (en) * | 1996-04-03 | 1999-07-27 | Bridgestone Sports Co., Ltd. | Golf ball |
US5849168A (en) * | 1996-06-14 | 1998-12-15 | Acushnet Company | Method of in-mold coating golf balls |
US6251991B1 (en) | 1997-10-28 | 2001-06-26 | Bridgestone Sports Co., Ltd. | Golf ball cover stocks and golf balls |
US6716954B2 (en) | 1998-03-18 | 2004-04-06 | Callaway Golf Company | Golf ball formed from a polyisocyanate copolymer and method of making same |
US7160210B2 (en) * | 1998-03-18 | 2007-01-09 | Callaway Golf Company | Golf ball which includes fast-chemical-reaction-produced component and method of making same |
US20050049082A1 (en) * | 1998-03-18 | 2005-03-03 | Callaway Golf Company | Golf ball |
US20030176619A1 (en) * | 1998-03-18 | 2003-09-18 | Viktor Keller | Polyurethane covered golf balls |
US20050282659A1 (en) * | 1998-03-18 | 2005-12-22 | Kennedy Thomas J Iii | High compression multi-layer RIM golf balls |
CA2439715A1 (en) * | 1998-03-18 | 2002-09-26 | The Top-Flite Golf Company | Apparatus and method for making a golf ball |
US7244196B2 (en) * | 1998-03-18 | 2007-07-17 | Callaway Golf Company | Golf ball which includes fast-chemical-reaction-produced component and method of making same |
US6533566B2 (en) | 1998-03-18 | 2003-03-18 | Spalding Sports Worldwide, Inc. | Apparatus for making a golf ball |
US7320648B2 (en) * | 1998-03-18 | 2008-01-22 | Callaway Golf Company | Golf ball |
CA2341546A1 (en) | 1999-04-20 | 2000-10-26 | Pijush K. Dewanjee | Golf ball having a polyurethane cover |
US6190268B1 (en) | 1999-07-27 | 2001-02-20 | Callaway Golf Company | Golf ball having a polyurethane cover |
US6592472B2 (en) | 1999-04-20 | 2003-07-15 | Callaway Golf Company | Golf ball having a non-yellowing cover |
US6974854B2 (en) * | 1999-04-20 | 2005-12-13 | Callaway Golf Company | Golf ball having a polyurethane cover |
US6607686B2 (en) | 1999-04-20 | 2003-08-19 | Callaway Golf Company | Thermosetting polyurethane material for a golf ball |
US6390937B1 (en) | 1999-04-20 | 2002-05-21 | Callaway Golf Company | Method for verifying the concentricity of a multiple-layer golf ball |
US6117024A (en) * | 1999-04-20 | 2000-09-12 | Callaway Golf Company | Golf ball with polyurethane cover |
US6913549B2 (en) * | 1999-07-27 | 2005-07-05 | Callaway Golf Company | Golf ball with high coefficient of restitution |
US6478697B2 (en) * | 1999-07-27 | 2002-11-12 | Callaway Golf Company | Golf ball with high coefficient of restitution |
US20030199340A1 (en) * | 1999-07-27 | 2003-10-23 | Callaway Golf Company | [GOLF BALL HAVING A POLYURETHANE COVER(Corporate Docket Number PU2156 )] |
US6213892B1 (en) | 1999-07-27 | 2001-04-10 | Callaway Golf Company | Multi-layer golf ball |
US6443858B2 (en) | 1999-07-27 | 2002-09-03 | Callaway Golf Company | Golf ball with high coefficient of restitution |
US6152836A (en) * | 1999-10-06 | 2000-11-28 | Wilson Sporting Goods Co. | Golf ball with a cover which includes polyurethane rubber |
US7148266B2 (en) * | 1999-12-23 | 2006-12-12 | Callaway Golf Company | Game balls with cover containing post crosslinkable thermoplastic polyurethane and method of making same |
JP4782942B2 (en) * | 2001-05-17 | 2011-09-28 | ブリヂストンスポーツ株式会社 | Golf ball manufacturing method |
JP4823434B2 (en) * | 2001-05-17 | 2011-11-24 | ブリヂストンスポーツ株式会社 | Golf ball manufacturing method |
JP2002360740A (en) | 2001-06-04 | 2002-12-17 | Sumitomo Rubber Ind Ltd | Three-piece solid golf ball |
US6656061B2 (en) | 2001-06-05 | 2003-12-02 | Sumitomo Rubber Industries, Ltd. | Solid golf ball |
JP5142429B2 (en) * | 2001-06-25 | 2013-02-13 | ブリヂストンスポーツ株式会社 | Two piece solid golf ball |
JP4873111B2 (en) * | 2001-08-08 | 2012-02-08 | ブリヂストンスポーツ株式会社 | Golf ball material and golf ball |
US6855077B2 (en) * | 2001-12-04 | 2005-02-15 | Callaway Golf Company | Process and apparatus for producing a golf ball with deep dimples |
US7427193B2 (en) * | 2001-12-04 | 2008-09-23 | Callaway Golf Company | Method and apparatus for forming a golf ball |
US20060038321A1 (en) * | 2001-12-04 | 2006-02-23 | Callaway Golf Company | Method and apparatus for forming deep apertures in a golf ball, and golf ball |
JP4061064B2 (en) | 2001-12-17 | 2008-03-12 | Sriスポーツ株式会社 | Golf ball |
JP3911159B2 (en) * | 2001-12-26 | 2007-05-09 | Sriスポーツ株式会社 | Golf ball |
JP3957554B2 (en) * | 2002-04-22 | 2007-08-15 | Sriスポーツ株式会社 | Golf ball |
US6787626B2 (en) * | 2002-05-31 | 2004-09-07 | Callaway Golf Company | Thermosetting polyurethane material for a golf ball cover |
US6762273B2 (en) * | 2002-05-31 | 2004-07-13 | Callaway Golf Company | Thermosetting polyurethane material for a golf ball cover |
US7244802B2 (en) | 2002-05-31 | 2007-07-17 | Callaway Golf Company | Thermosetting polyurethane material for a golf ball |
US20030224876A1 (en) * | 2002-05-31 | 2003-12-04 | Callaway Golf Company | Thermosetting polyurethane material for a golf ball cover |
JP4117466B2 (en) * | 2002-11-29 | 2008-07-16 | ブリヂストンスポーツ株式会社 | Golf ball |
US6939924B2 (en) * | 2003-03-10 | 2005-09-06 | Hyun Jin Kim | Golf ball incorporating urethane composition |
US7121961B2 (en) * | 2004-04-07 | 2006-10-17 | Callaway Golf Company | Low volume cover for a golf ball |
US20060111542A1 (en) * | 2004-11-19 | 2006-05-25 | Callaway Golf Company | Polyurethane Material For a Golf Ball |
US20060111541A1 (en) * | 2004-11-19 | 2006-05-25 | Callaway Golf Company | Polyurethane material for a golf ball cover |
US20060111543A1 (en) * | 2004-11-22 | 2006-05-25 | Callaway Golf Company | Reaction injection molded polyurea material for a golf ball cover |
US7060777B1 (en) * | 2004-12-07 | 2006-06-13 | Callaway Golf Company | Polyurethane material for a golf ball cover |
US7101952B2 (en) * | 2004-12-08 | 2006-09-05 | Callaway Golf Company | Polyurethane material for a golf ball cover |
US7819761B2 (en) | 2005-01-26 | 2010-10-26 | Taylor Made Golf Company, Inc. | Golf ball having cross-core hardness differential and method for making it |
US7591740B2 (en) * | 2005-01-26 | 2009-09-22 | Callaway Golf Company | Golf ball which includes fast-chemical-reaction-produced component and method of making same |
US8177665B2 (en) * | 2005-02-01 | 2012-05-15 | Taylor Made Golf Company, Inc. | Multi-layer golf ball |
US7264560B2 (en) * | 2005-03-10 | 2007-09-04 | Callaway Golf Company | Golf ball |
US7479533B2 (en) * | 2005-05-04 | 2009-01-20 | Bridgestone Sports Co., Ltd. | Golf ball |
US7601290B2 (en) * | 2005-05-04 | 2009-10-13 | Bridgestone Sports Co., Ltd. | Method for producing golf ball |
US7874940B2 (en) * | 2005-07-13 | 2011-01-25 | Taylor Made Golf Company, Inc. | Extrusion method for making golf balls |
GB0515353D0 (en) * | 2005-07-27 | 2005-08-31 | Psimedica Ltd | Food |
US20070035063A1 (en) * | 2005-08-10 | 2007-02-15 | Lavallee Gerald A | Two-stage reaction injection molded golf ball |
US7524251B2 (en) * | 2005-08-30 | 2009-04-28 | Callaway Golf Company | Golf products produced by a stoichiometrically imbalanced RIM system |
US20070069424A1 (en) * | 2005-08-30 | 2007-03-29 | Veilleux Thomas A | Reaction injection molding assembly for manufacturing a golf ball component |
US7306529B2 (en) * | 2005-10-07 | 2007-12-11 | Callaway Golf Company | Multi-layer golf ball |
US20070135235A1 (en) * | 2005-10-13 | 2007-06-14 | Kennedy Thomas J Iii | Fast-Chemical-Reaction-Produced Golf Product Comprising a Caprolactam Polyol |
US7550535B2 (en) | 2005-11-03 | 2009-06-23 | Bridgestone Sports Co., Ltd. | Golf ball and method of manufacture |
US20070100085A1 (en) * | 2005-11-03 | 2007-05-03 | Taylor Made Golf Company, Inc. | Amide-modified polymer compositions and sports equipment made using the compositions |
JP4523912B2 (en) * | 2005-12-16 | 2010-08-11 | Sriスポーツ株式会社 | Golf ball and method for manufacturing the same |
US8030411B2 (en) | 2005-12-21 | 2011-10-04 | Taylor Made Golf Company, Inc. | Polymer compositions comprising peptizers, sports equipment comprising such compositions, and method for their manufacture |
JP4676889B2 (en) * | 2006-01-20 | 2011-04-27 | Sriスポーツ株式会社 | Golf ball |
JP4523925B2 (en) * | 2006-03-30 | 2010-08-11 | Sriスポーツ株式会社 | Golf ball |
US7964132B2 (en) * | 2006-08-22 | 2011-06-21 | Bridgestone Sports Co., Ltd. | Golf ball manufacturing method |
US8182367B2 (en) * | 2006-08-22 | 2012-05-22 | Bridgestone Sports Co., Ltd. | Golf ball |
US7879968B2 (en) * | 2006-10-17 | 2011-02-01 | Taylor Made Golf Company, Inc. | Polymer compositions and golf balls with reduced yellowing |
US8349952B2 (en) | 2006-12-28 | 2013-01-08 | Dunlop Sports Co. Ltd. | Golf ball |
JP5258262B2 (en) * | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | Golf ball |
JP5258263B2 (en) * | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | Golf ball |
JP5258265B2 (en) * | 2007-11-08 | 2013-08-07 | ダンロップスポーツ株式会社 | Golf ball |
US8211976B2 (en) | 2007-12-21 | 2012-07-03 | Taylor Made Golf Company, Inc. | Sports equipment compositions comprising a polyurethane, polyurea or prepolymer thereof and a polyfunctional modifier |
US8096899B2 (en) * | 2007-12-28 | 2012-01-17 | Taylor Made Golf Company, Inc. | Golf ball comprising isocyanate-modified composition |
JP5258363B2 (en) * | 2008-04-18 | 2013-08-07 | ダンロップスポーツ株式会社 | Golf ball |
US20100125002A1 (en) * | 2008-11-14 | 2010-05-20 | Taylor Made Golf Company, Inc. | Resin compositions incorporating modified polyisocyanate and method for their manufacture and use |
JP5182764B2 (en) * | 2009-06-30 | 2013-04-17 | 睦久 古川 | Golf ball |
US8575278B2 (en) * | 2009-12-31 | 2013-11-05 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
US8674023B2 (en) * | 2009-12-31 | 2014-03-18 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
US20110159991A1 (en) * | 2009-12-31 | 2011-06-30 | Taylor Made Golf Company, Inc. | Golf ball composition |
US8629228B2 (en) | 2009-12-31 | 2014-01-14 | Taylor Made Golf Company, Inc. | Ionomer compositions for golf balls |
US8193296B2 (en) | 2010-06-30 | 2012-06-05 | Nike, Inc. | Golf balls including crosslinked thermoplastic polyurethane |
US9119990B2 (en) | 2011-04-20 | 2015-09-01 | Nike, Inc. | Polymer coating to cross-link underlying cover |
US9101796B2 (en) | 2012-01-03 | 2015-08-11 | Nike, Inc. | Golf ball having an over-indexed thermoplastic polyurethane elastomer cover and having a soft feeling when hit |
US8980155B2 (en) | 2012-01-03 | 2015-03-17 | Nike, Inc. | Over-indexed thermoplastic polyurethane elastomer, method of making, and articles comprising the elastomer |
US8987405B2 (en) | 2012-01-03 | 2015-03-24 | Nike, Inc. | Golf ball having an over-indexed thermoplastic polyurethane elastomer cover and having a soft feeling when hit |
US8906508B2 (en) | 2012-05-30 | 2014-12-09 | Nike, Inc. | Method of toughening thermoplastic polyurethane and articles comprising toughened thermoplastic polyurethane |
US9682283B2 (en) | 2014-06-27 | 2017-06-20 | Bridgestone Sports Co., Ltd. | Golf ball and method of manufacture |
US9545543B2 (en) | 2014-06-27 | 2017-01-17 | Bridgestone Sports Co., Ltd. | Golf ball manufacturing method |
US10479859B2 (en) | 2017-10-18 | 2019-11-19 | Talaco Holdings, LLC | Aromatic polyester polyether polyols, polyurethanes made therefrom and building materials comprising same |
US11578165B2 (en) * | 2019-01-21 | 2023-02-14 | Talaco Holdings, LLC | Methods of making foams exhibiting desired properties from aromatic polyester polyether polyols derived from polyethylene terephthalates and foams made therefrom |
US11779814B2 (en) | 2020-08-26 | 2023-10-10 | Volvik Inc. | Polyurethane golf ball |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE831772C (en) * | 1952-11-18 | 1952-02-18 | Bayer Ag | Process for the production of high molecular weight crosslinked plastics |
US2861981A (en) * | 1954-02-05 | 1958-11-25 | Nat Distillers Chem Corp | Polyesters and isocyanate reaction products thereof |
US3034791A (en) * | 1960-04-26 | 1962-05-15 | Du Pont | Polyurethane golf ball covers |
US3979126A (en) * | 1971-01-27 | 1976-09-07 | Acushnet Company | Ball and process and composition of matter for production thereof |
-
1979
- 1979-07-16 US US06/057,633 patent/US4248432A/en not_active Expired - Lifetime
-
1980
- 1980-06-25 CA CA000354810A patent/CA1177594A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
US4248432A (en) | 1981-02-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA1177594A (en) | Golf ball | |
US4442282A (en) | Polyurethane covered golf balls | |
US3358052A (en) | Polyurethane composition containing 0.2 to 5% polyolefin or polystyrene | |
US6511388B1 (en) | Golf ball with polyurethane cover | |
US6729975B2 (en) | Golf ball | |
US6939924B2 (en) | Golf ball incorporating urethane composition | |
US6924337B2 (en) | Golf balls incorporating urethane compositions and methods for making them | |
US6683152B2 (en) | Polyurethane golf club inserts | |
CN101130136B (en) | Golf ball | |
US7794641B2 (en) | Method for producing golf ball | |
GB2376897A (en) | Scuff resistant golf ball | |
US20070072701A1 (en) | Golf ball | |
WO1996040378A1 (en) | Golf ball covers | |
GB2376898A (en) | Process for producing a scuff resistant golf ball | |
US6660824B2 (en) | Golf ball | |
JP2005000662A (en) | Golf ball incorporating styrenic block copolymer and urethane | |
JP2002336380A (en) | Golf ball | |
JP2002336381A (en) | Golf ball | |
EP1589053A1 (en) | Thermoplastic polyurethane and use thereof | |
US7479533B2 (en) | Golf ball | |
US6593443B2 (en) | Wound-core golf ball | |
US6503157B2 (en) | Golf ball and process for manufacturing the same | |
JP4073246B2 (en) | Polyurethane ionomer and method for producing the same | |
US4051111A (en) | Injection moldable polyurethanes | |
JP2520343B2 (en) | Transmission belt |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |