CA1223188A

CA1223188A - Disposable article constructions

Info

Publication number: CA1223188A
Application number: CA000469274A
Authority: CA
Inventors: Robert C. Schmidt, Jr.; Paul P. Puletti
Original assignee: National Starch and Chemical Corp
Current assignee: Ingredion Inc
Priority date: 1984-01-09
Filing date: 1984-12-04
Publication date: 1987-06-23
Also published as: JPS60158284A; US4526577A; AU552956B2; AU3660184A

Abstract

ABSTRACT
A hot melt pressure sensitive adhesive composition comprises 15-35% of an A-B-A block or multiblock A-B-A-B-A-B copolymer, 45-70% of a compatible tackifying resin, 5-30% of a plasticizing oil, 0-5% of a petroleum derived wax, and 0.1-2% of a stabilizer. Polymer blocks A
are non-elastomeric blocks which as homopolymers have glass transition temperatures above 20°C; polymer block B is butadiene or hydrogenated butadiene. They are used in disposable articles such as diapers to bond the polyethylene or polypropylene substrates of multi-line type construction to the tissue, non-woven polyethylene or polypropylene substrates.

Description

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DISPOSABLE ARTICLE CONSTRUCTIONS

The present invention relates to disposable articles prepared using multi-line construction and especially to multi-line disposable diaper, sanitary napkin and bed pad constructions and to hot melt adhesives useful for the assembly thereof.
While a wide range of uses for hot melt adhesive compositions are known throughout the disposable industry, it has been found that a hot melt adhesive used for bonding in a particular use or application may be completely unsuitable for other uses or applications. Thus, various hot melt adhesive cornpositions have been proposed for use in the con-struction of disposable articles. Depending upon the type of construc-; tion employed, the adhesive must possess certain physical properties.
Perhaps the most stringent properties are those required of adhesives to be used in the bonding of polyethylene films, or the like, to tissue or non-woven substrakes ln the production of articles, particularly lS diapers, sanitary napkins and bed pads, using multi-line construction techniques. This class oF disposable construction presenks unique problems for the adhesive formulator. The adhesive rnust possess a high degree of adhesion since lt is applied in the form of a number of very fine parallel longitudinal stripes -thus requiring each line of adhesive to possess exceptionally high bonding properties. The adhesive must also possess sufficient adhesive and cohesive strength to provide ' :

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- 2 - ~L~ ;3gLc~3 high bond strength values when subjected to stress so the constructions cannot be easily separated. As an additional criteria, i-t is necessary that the adhesive~ upon application, not absorb -throughout the actual disposable construction and that -the adhesive bonds not only remain secure but also be flexible even after prolonged periods of storage.
In addition to requiring heat and oxidation resistance on aging they must also possess sufficient bonding range and must be white or clear in color.
To date, only hot melt adhesives based on ethylene-vinyl acetate copolymers or on atactic polypropylene have been used for these multi-line constructions. Neither of these approaches have resulted in ad-hesives possessing all the desirable properties discussed above. Thus, the polypropylene based adhesives have adequate adhesion requirements at the sacrifice of stability and bonding range while the ethylene-vinyl acetate adhesives provide flexibility while sacrificing adhesionand bond strength. Further, in order to formulate either type into ap-hesives which have the bonding range or open time required for these applications, it has been necessary to formulate them as semipressure sensitives which consequently has further reduced their cohesive streng-th resulting in loss of bonding during storage or transport at elevated temperatures.
Wh;le the term "rnulti-line" construction is used herein to repre-sent the above-descrlbed embodlment, ;t wlll be understood that -the -terrn may also be used to lnclude articles constructecl usiny a "multi-clot" or "multi-stripe" pattern or application, i.e., any assembly re-quirin~l the use of a larcJe number of adhesive deposits, each deposit being oF a small quantity of adhesive.

3 _ ~ 3~L8 ~3 The present invention provides a disposable article of multi-line type construction which comprises at least one polye-thylene or po'ly-propylene substrate bonded to at least one tissue, non-woven polyethy-lene or polypropylene substrate using a hot melt pressure sensitive adhesive composition comprising:
a) 15 to 35% by weight of an A-B-A block or A-B-A-B-A-B multi-block copolymer, where the A polymer block is a non-elastomeric polymer block which, as a homopolymer has a glass transition temperature above 20C, and the B polymer block is butadiene or hydrogenated butadiene;
b) 45 to 70% by weight of a compatible tackifying resin;
c) 5 to 30% by weight of a plasticizing oil;
d) 0 to 5% by weight of a petroleum derived wax; and e) 0.1 to 2% by weight o-f a stabilizer.
The adhesive compositions can be applied at relatively low temp-eratures and will retain their superior bonding strength even when subjected to prolonged periods of storage. The preferred hot melt adhesives contain as the block copo'lymer a multi-block styrene-buta-diene copolymer containing at least 35 parts styrene per 100 parts co-polymer. The bu-tadiene may be partially or substantially hydrogenated.
Further, the copo'lymer may be linear or branched. Typical branched structures contain an elastomeric portion with a-t least three branches which can radiate out from a central hub or can be otherwise coupled together.
The non-elastomeric b'locks which make up 14 -to 86% by weight o-f the block copolymer may comprise homopolymers or copolymers of vinyl monomers such as vinyl arenes, vinyl pyridines, vinyl halides and vinyl carboxylates, as well as acrylic monomers such as acrylonitrile, methacrylonitrile, esters of acrylic acids, etc~ Monoviny'l aromatic ,.

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hydrocarbons include particularly those of the benzene series such as styrene, vinyl toluene, vinyl xylene~ ethyl vinyl benzene as well as dicyclic monovlnyl compounds such as vinyl naphthalene and the like.
Other non-elastomeric polymer blocks may be derived from alpha olefins, alkylene oxides, acetals, urethanes, etc. Styrene is preferred.
The elastomeric block component making up the remainder of the copolymer is butadiene, which may or may not be hydrogenated as taught, for example, in U.S. Pat~ No. 3,700,633 issued October 24, 1972 to M.M. Wald et al. This hydrogenation may be either partial or substan-tially complete. Selected conditions may be employed for examp'le tohydrogenate the elastomeric butadiene block while not so modifying the vinyl arene polymer blocks. Other conditions may be chosen to hydro-genate substantially uniFormly along the polymer chain, both the elastomeric and non-elastomeric blocks thereof being hydrogenated to practically the same extent, which may be either partial or substan-tially complete.
Typical of the rubbery block copolymers useful herein are the polystyrene-polybutadiene-polystyrene and polystyrene-poly(ethylene-butylene)-polystyrene. These copolymers may be prepared usin(J methods taught, for examp'le, in U.S. Pat. Nos. 3,239,478 issued March 8, 1966 to J. T. ~larlan; 3,427,269 issued Feb. 11, 1969 to F. C. Davis et al.;
3,700,633 issued Feb. 11, 1969 to F. C. Davis et al.; 3,753,936 issued Aug. 21, 1973 to 0. L. Marrs; an~ 3,932,327 Issued Jan. 13, 1976 -to F.
E. Naylor. A'lternatively, some may be obtained from Shell Chemical Co.
under the trademarks Kra-ton :L101, 1102, 1650, 1652 and 1657 and from Phil'lips Chemical Co. under the trademarks Solprene 418 and 423.
Most preferred for use herein are the linear A-B-A-B-A nnulti-block copolymers where the elastomeric block is butadiene and the non-elasto-. ' 3~

meric block is styrene, and the latter is present in relatively high concentrations, i.e. at levels of 35% or above. Block copolymers marketed commercially at this time which meet the above described requirements are available from Firestone under the tradename Stereon 840A (57 parts butadiene and 43 parts styrene). Blends of these high styrene containing copolymers with other compatable block copolymers may also be employed.
The tackifying resins use-ful in the adhesive compositions can be hydrocarbon resins, synthetic polyterpenes, rosin esters, natural ter-penes, and the like. More particularly, the useful tackifying resins include any compatible resins or mixtures thereof such as (1) natural and modified rosins, for example, gum rosin, wood rosin, tall-oil rosin, distilled rosin, hydrogenated rosin, dimerized rosin, and polymerized rosin; (2) glycerol and pentaerythritol esters of natural and modified rosins, for example, glycerol ester of pale wood rosin, glycerol ester of hydrogenated rosin, glycerol ester of polymerized rosin, pentaery-thritol ester of hydrogenated rosin, and phenolic-modified pentaery-thritol ester of rosin; (3) copolymers and terpolymers of natural ter-penes, e.g. styrene/terpene and alpha methyl s-tyrene/terpene; (~) poly-terpene resins havlng a sof-tening point, as determined by ASTM method E28-58T, of from about 80 to 150C; the latter polyterpene resins gen-erally resulting from the polymerization of terepene hydrocarbons, such as the blcyclic monoterpene known as pinene, in the presence of Friedel-Crafts catalysts at moderately low temperatures; also included are the hydrogenated polyterpene resins; (5) phenolic modified terpene resins and hydrogenated derivatives thereof, for example, the resin product resulting from the condensation, in an acidic mediurn, of a bicyclic ,, ', ! ' ': .' . .; ~ . . :: , - 6 - ~L~ 3~3~

terpene and a phenol; (63 aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70 to 135C.; the latter resins resulting from the polymerization of monomers consisting of pri-marily of olefins and diolefins; also included are the hydrogenated aliphatic petroleum hydrocarbon resins; (7) aromatic petroleum hydro-carbon resins and the hydrogenated derivatives thereof; and (8) ali-cyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof. Mixtures of two or more of the above-described tackifying resins may be required for some formulations.
The selection of the particular tackiFying agent is, in large part, dependent upon the specific block copolymer employed. The preferred adhesive formulations for use herein which employ the linear multi-block Stereon type copolymers provide optimum properties when tackifi-ers of modified terpene having ring and ball softening point of about 100-120C. such as Zonatac 105 are employed.
Among the applicable stabilizers or antioxidants utilized herein are included high molecular weight hindered phenols and multifunctional phenols such as sulfur and phosphorous-containing phenols. ~lindered phenols are well known to those skilled in the art and may be char-acterized as phenolic compounds which also contain sterically bulkyradicals in close proximity to the phenolic hydroxyl group thereof. In particular, tertiary butyl groups generally are substituted onto the benzene ring in at least one of the ortho positions relative to the phenolic hydroxy group. The presence of these sterically bulky substi-tu-ted radicals in the vicinity of the hydroxyl group serves to retard its stretching frequency and, correspondingly, its reactivity; this s-teric hindrance thus providing the phenolic compound with its stabil-"' .. ~'' ' :' '.:

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.. :. , :,, - 7 - ~L2~3~L~3~3 izing properties. Representative hindered phenols include: 1,3,5-trimethyl-2,4,6-tris(3,5-di-ter~-butyl-4-hy~roxybenzyl)benzene; pen-taery-thri-tyl tetrakis-3(3,5-di-tert-butyl-4-hydroxyphenyl)propionate;
n-octadecyl-3(3,5-di-tert-butyl-4-hydroxyphenyl)-propionate; 4,4'-methylenebis(2,6-tert-butylphenol); 4,4'-thiobis (6-tert-butyl~o-cresol); 2,6-di-tertbutylphenol; 6-(4-hydroxyphenoxy)-2,4-bis(n-octyl-thio)~1,3,5-triazine; di-n-octadecyl-3,5-di-tert-butyl-4-hydroxy-benzylphosphonate; 2-(n-octylthio)ethyl-3,5-di-tert-butyl-4-hydroxy-benzoate; and sorbitol hexa[3-~3,5-di-tert-butyl-4-hydroxyphenyl)-propionate].
The perFormance of these antioxidants may be further enhanced byutilizing, in conjunction therewith known synergists, for example, thiodipropionate esters and phosphites, preferably distearylthiodipro-pionate.
These stabilizers, iF used, are genera'l'ly present in amounts of about 0.1 to 1.5%, preferably 0.25 to 1.0%, by weight.
Various p'lasticizing or extending oils are also present in the composition in amounts of 5% to about 30%, preferably 5 to 25%, by weight in order to provide wetting action and/or viscosity control.
The ahove broadly includes not only the usual plasticizing oils but also con-templates the use of olefin oligomers and low molecular weigh-t polymers as well as vegetable and animal oil and their derivatives.
The petroleum derived oils which may be employecl are relatively high boiling materials containing only a minor propro-tion of aromatic hydro-carbons (preFerably less than 30% and, more particular'ly, less than 15%by weight oF the oi'l). Alternatively, the oil may be totally non-aro-matic. The oligomers may be polypropylenes, polybutenes, hydrogenated - 8 - 3L~ L~3~3 polyisoprene, hydroyenated polybutadiene, or the like having average molecular weights between 350-10~000. Vegetable and animal oils in-clude glyceryl esters of the usual fatty acids and polymerization products thereof.
Various petroleum derived waxes may also be used in amounts less than about 15% by weight of the composition in order to impart fluidity in the molten condition of the adhesive and flexibility to the set ad-hesive, and to serve as a wetting agent for bonding cellulosic fibers.
The term "petroleum derived wax" includes both paraffin and micro-crystalline waxes having melting points within the range of 54-107C
(130-225F).
as well as synthetic waxes such as low molecular weight polyethylene or Fisher-Tropsch waxes.
The adhesive compositions are prepared by blending the components in the melt at a temperature of about 130-200C. (266-392F) until a homogeneous blencl is obtained, approximately 2 hours. Various methods of blending are known to the art and any method that produces a homo-geneous blend is satisfactory.
The resultant adhesives are then used to boncl polyethylene or polypropylene substrates to tissue, non-wovens or other polyethylene or polypropylene substrates using techniques involving multiple disposi-tions of small quantities of the aclhesives accorcling to conventional "multi-line" or "multi-dot" type constructlons. Although the proce-dures used to Inanufacture these disposable constructions vary depending upon the particular manufacturer, the adhesive is generally extruded in lines (or dots) at regularly spaced in-tervals along the length of -the article. The adhesive is usually applied to the polyethylene or poly-~"

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propylene backing and subsequently the combination is mated with an absorben-t inner core and -tissue or non-woven liner.
In the examples which follow, all parts and percentages are yiven and all temperatures are in degrees Celsius unless otherwise noted.
The following testing procedures were used:
End Seal Test: A polyethylene backsheet is bonded to a non-woven liner and a sample, 3 gluelines in width, cut therefrom. One end of the polyethylene is clamped into the jaws of a tensile tester held at a 180 angle and the corresponding end of the non-woven pulled similarly in the opposite direction. The force required to separate the bond is then recorded in grams. For the applications contemplated herein, it is desirable that values of a-t least about 300 9. be obtained. Such high degrees of bond strength are desired in the multiline disposable assemblies in order to prevent the separation of the substrates. Ad-hesives conventionally utilized herein have produced constructions hav-ing end seal bond values of less than 200 9. and often only about 100 9.
Adhesion Failure Temperature is a measure of the ability of the boncl to withstand an elevated temperature rising at about 2.8C (5F) every 15 minu-tes under a constant force which pulls the bond. In this test bonds 2.54 cm. by 4 mm. (1 inch by 4 mm) were formed of polyethy-lene onto Kraft paper and the -force used -to pull the bond kept cons-tan-t at 25 9. The test results are designated as Incremental Pee'l Pass/Fail values and show the transitiona'l temperature range at which bond fai'l-ure occurs. Adhesives possessing hlgh fai'lure temperatures are essen-tial for these ~isposable cons-tructions which are oFten subjected to very high temperature conditions duriny transport and/or storage.
~e_____tJ Window Test: Bonds are formecl as in the Adhesion Failure . .
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Test. The application temperature of the glue is incrementally reduced until substrate failure did not occur either with fresh bonds or -those aged 24 hours at room temperature. This minimum temperature is desig-nated the minimum bonding temperature and is an indication of the low-est application temperature which will still give a good bond. Sincethe temperature at which the hot melt adhesive is used may vary through-out the actual manufacturing operation, an adhesive with a low minimum bonding temperature will be more versatile and will result in less down time and, consequently higher production rates.
Static Time to Failure Bond Test: Adhesive (held at 163C-325F) was applied to a series oF polyethylene surfaces 1.27 cm. (0.5 in.) in width and a 3.81 cm. (1.5 in.) long and hand cornpressed onto similar size sheets of Kraft paper. The bonds were hung vertically with 50 g.
weights and maintained at 41C (105F). The time to failure was noted.
It should be noted wi-th respect to this test that the results thereof will vary from one series of tests to another and therefore comparisons can be made only between samples tested at the same time.
This test is an indication of the heat resistance oF the adhesive under temperature conditions approximating those encountered during use (wear) of the disposable construction. Long failure times are desir~
able indicating strong bonds which are particularly essential in cer-tain areas of the disposable constructions which are subjected to greater s-tress during use.
Aclhesive Stre~ : The adhesion to stainless steel and -to Mylar (polyester) film was measured by peeling the tape backing over itself 180 at a constan-t speed (by a force applied to the -free end of the tape) from a smooth steel surface or HDPE to which it has been applied ~ L2~3~l~3~3 by a fixed pressure. For the techniques used in conducting this test, see the 180 peel adhesion test PSTC-1 of the Pressure Sensitive Tape Council. This test can be performed only on adhesive formulations which are pressure sensitive and is a measure of the s-trength or ten-acity of the adhesive.
EXAMPLE I
A total of 10 parts white USP mineral oil and 0.1 part Irganox 1010 antioxidants were blended with 20 parts Stereon 840A at 163C
(325F). When the blend was homogeneous, 10 additional parts oil were added followed by 60 parts Zonatac 105 Lite, a modiFied terpene tacki-fier.
The resulting pressure sensitive ahesive (designated Adhesive A) exhibited a viscosity (Brookfield Thermosel Viscometer) oF 1355 at 163C (325F) and 8060 at 121C (250F).
A similar adhesive (designated Adhesive B) was prepared using 60 parts Arkon M-100, a Cg aromatic Feedstream, as a tackifier.
Adhesives A and B were compared with two adhesives presently em-ployed in the commercial production oF multi-line diapers, one oF which (Adhesive C) is based on a composition prepared From ethylene vinyl acetate, alpha-methyl s-tyrene and styrene and another (Adhesive D) from a resin fortiFied atactic polypropylene.
Five samples oF each of the four adhesives were then subjected to the Static Tirne to Failure Bond Test and observed at 15 minute intervals The values For each test are shown in Table I, , . . .
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Adhesive A B C (control) D (controi) 1 2.5 hr. 3.75 hr.15 min. 15 min.
2 3 hr. 4 hr. 15 min. 30 min.
3 3 hr. 7 hr. 15 min. 30 min.

4 3 hr. 8 hr. 15 minO 30 min.
3 hr. >8 hr. 15 min. 30 min.
As the results show, the heat resistance, as measured in terms of -the Static Time to Failure, was many fold higher for the adhesives pre-pared using the compositions of the present invention.
The adhesives prepared above were then compared with the conven~
tionally employed adhesives (including a third adhesive, adhesive E, prepared from ethylene vinyl acetate and terpene) by subjecting the adhesives to the Adhesion Failure and Operating Window tests described previously. The results are presented below:
Minimum Peel Bonding Adhesive Pass/Fail _ TemPerature C F C F
Adhesive A 57/60135/140 93 <200 Adhesive B 63/66145/150 Not tested Adhesive C 32/35 90/95 107 225 (Control) Adhesive D 41/43105/110 135 275 (Control) Adhesive E 41/43105/110 135 275 (Comparative) Again the Adhesives of the present invention gave results For superior to those obtained using -the adhesives conventionally employed for these applications.
End seal -tests were then run on a series of commercially produced multi-line diaper constructions bonded with Adhesives A, C ancl D. In the case of Aclhesive D, the comnlercial diaper was bonded with bead widths oP 0.165 cm~ (0,065 in.). Consequen-tly, for comparative purposes, D*

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is shown as indicative oF end seal values normalized to the 0.0125 in.
bead widths used in the commercial A and C constructions. Another commercially available diaper bonded with an alternate atactic polypropylene adhesive (Adhesive F) was also tested. In this case, the commercial diaper was prepared using bead widths of 0.10 cm. (0.04 in.).
For comparison F* has been normalized to a 0.0125 in. bead width.
Adhesive: A C D D* F F*
~ (control) (control) (control (comparative) (comparative normalized normalized to same to same bead width) bead width) ~8016 800 160 280 88 Bead width (in.): 0.0125 0.0125 .0625 0.0125 0.04 0.0125 (cm.): 0.0320.032 0.159 0.032 0.10 0.032 The above results show the improved end seal strength obtained using the adhesives of the present invention. Thus, while diapers can be pre-pared with other conventional adhesives, it is seen (from sample D) that acceptable strength va'lues are obtained only when subs-tantially larger amounts of adhesive are employed. The undesirable aspects o~ -the use of these wider bead widths both with respect to aesthetics ancl quantity oF
adhesive usecl are apparent.
_AMPLE II
Using the general procedure described in Examp'le I, other adhesives were prepared using various b'lock copolymers in place of the Stereon 840A. The aclhesive compositions were subjectecl to the Adhesion Failure test, Adhesive Strength Test and Static Time to Failure test.

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Static Peel Adhesive Time to Block Copolymer Pass/Fail k / Stlben/lth ~ Failure UC UF 9 cm. ~ lnear ln.)(hrs.) Adhesive A 57/60135/140 1.4 8 7 Kraton G165252/54125/130 0.9 5 >48 Kraton 1102 46/49115/120 1.3 7 8 Kraton 1107 38/43100/110 1.3 7 3 As seen from the above results, while the adhesive strength was comparable, the heat resistance of -the composition containing Kraton 1107 (a styrene-isoprene block copolymer) was substantially poorer than that obtained using the styrene-butadiene copolymers of the present in-venkion. Further, while the Kraton G1652 containing adhesive possessed some superior properties, the economic considerations involved together with the overall satisfactory properties of compositions prepared with the Stereon 840A, make these latter compositions the preFerred adhesives for use herein.

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Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE PROPERTY OR
PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. A disposable article of a multi-line type construction, which com-prises at least one polyethylene or polypropylene substrate bonded to at least one tissue, non-woven polyethylene or polypropylene substrate using a hot melt pressure sensitive adhesive composition comprising:
a) 15 to 35% by weight of an A-B-A block or an A-B-A-B-A-B multi-block copolymer, where the A polymer block is a non-elastomeric polymer block which, as a hompolymer has a glass transition temperature above 20°C, and the B polymer block is butadiene or hydrogenated butadiene;
b) 45 to 70% by weight of a compatible tackifying resin;
c) 5 to 30% by weight of a plasticizing oil;
d) 0 to 5% by weight of a petroleum derived wax; and e) 0.1 to 2% by weight of a stabilizer.

2. The disposable article of Claim 1, wherein the disposable article is selected from the group consisting of a diaper, a sanitary napkin, and a bed pad; wherein the A polymer block is styrene; and wherein the tackifying resin is any compatible resin or mixture thereof selected from the group consisting of (1) natural and modified rosins; (2) gly-cerol and pentaerythritol esters of natural and modified rosins; (3) copolymer and terpolymers of natural terpenes; (4) polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from 80 to 150°C; (5) phenolic modified terpene resins and hydrogenated deri-vatives thereof; (6) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from 70 to 135°C; (7) aromatic petro-leum hydrocarbon resins and the hydrogenated derivatives thereof; and (8) alicyclic petroleum hydrocarbon resins and the hydrogenated deriva-tives thereof.

3. The disposable article of Claim 1, wherein the multi-block copoly-mer is the A-B-A-B-A-B copolymer and wherein the A polymer block is styrene present in an amount of at least 35 parts per 100 parts of the copolymer and the B polymer block is butadiene.

4. The disposable article of Claim 3, wherein the tackifying resin is any compatible resin or mixture thereof selected from the group con-sisting of (1) natural and modified rosins; (2) glycerol and pentaery-thritol esters of natural and modified rosins; (3) copolymers and ter-polymers of natural terpenes; (4) polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from about 80 to 150°C;
(5) phenolic modified terpene resins and hydrogenated derivatives thereof; (6) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70to 135°C; (7) aromatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof; and (8) alicyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.

5. The disposable article of Claim 4, wherein the block copolymer is 43 parts styrene and 57 parts butadiene.

6. The disposable article of Claim 5, wherein the tackifying resin is the modified terpene resin having a Ring and Ball softening part of about 100-120°C or the aromatic petroleum hydrocarbon resin or hydro-genated derivative thereof.

7. The disposable article of Claim 6, wherein the article is selected from the group consisting of diapers, sanitary napkins, and bed pads.

8. The disposable article of Claim 1, wherein the article is a dis-posable diaper; and wherein the multiblock copolymer is the A-B-A-B-A-B
copolymer, where the A polymer block is styrene present in an amount of at least 35 parts per 100 parts of the copolymer the B polymer block is butadiene.

9. The disposable diaper of Claim 8, wherein the block copolymer is 43 parts styrene and 57 parts butadiene; and wherein the tackifying resin is any compatible resin or mixture thereof selected from the group con-sisting of (1) natural and modified rosins; (2) glycerol and pentaery-thritol esters of natural and modified rosins; (3) copolymers and ter-polymers of natural terpenes; (4) polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from about 80 to 150°C;
(5) phenolic modified terpene resins and hydrogenated derivatives there-of; (6) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70-135°C; (7) aromatic petroleum hydro-carbon resins and the hydrogenated derivatives thereof; and (8) alicyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.

10. The disposable article of Claim 9, wherein the tackifying resin is the modified terpene resin having a Ring and Ball softening part of about 100-120°C or the aromatic petroleum hydrocarbon resin or hydro-genated derivative thereof.