CA1283929C - Oligomerization of ethylene in methanol and water - Google Patents
Oligomerization of ethylene in methanol and waterInfo
- Publication number
- CA1283929C CA1283929C CA000543761A CA543761A CA1283929C CA 1283929 C CA1283929 C CA 1283929C CA 000543761 A CA000543761 A CA 000543761A CA 543761 A CA543761 A CA 543761A CA 1283929 C CA1283929 C CA 1283929C
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- ethylene
- water
- methanol
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- phosphorus
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/226—Sulfur, e.g. thiocarbamates
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/2247—At least one oxygen and one phosphorous atom present as complexing atoms in an at least bidentate or bridging ligand
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
ABSTRACT OF THE DISCLOSURE
A process for oligomerizing ethylene using a nickel ylide catalyst substituted with a sulfonato group wherein the oligomerization is carried out in the presence of methanol and water.
A process for oligomerizing ethylene using a nickel ylide catalyst substituted with a sulfonato group wherein the oligomerization is carried out in the presence of methanol and water.
Description
~ ~83~9 OLIGOMERIZATION OF ETHYLENE IN METHANOL AND WATER
ReEerence is made to Applicants' following ~.S.
Patents:
U.S. Paten-t No. 4,293,502, Nickel Ylides, issued October 6, 1981;
0 U S. Patent No. 4,293,727, Process for Oligomerization of Ethylene, issued October 6, 1981;
U.S. Patent No. 4,310,716, Process for Oligomeri2ation of Ethylene in Methanol, issued January 12, 1982;
U.S. Patent No. 4,377,528, Group V~ Salts and Process for Preparing Same, issued March 22, 1983;
U.S. Patent No. 4,377,529, SulEonated Group VA Ylides and Process for Preparing Same, issued March 22, 1983;
U.S. Patent No. 4,382,153, Process for Oligomerization of Ethylene in Methanol, issued ~ay 3, 1983; and ~0 UOS. Patent No. 4,529,554, Process for the Preparation of Nickel Ylides Containing Ylide Ligands with a Sulfonated ; Group V Component, issued July 16, 1985.
FIELD OF THE INVENTION
.. . . .__ The present invention relates to the use of 25; nickel ylides to oligomerize ethylene in a solvent medium containing methanol.
DESCRIPTION OF THE PRIOR ART
It is well known in the art to use a variety of catalysts to oligomerize ethylene to higher molecular weight olefins. The term "oligomerize" has been employed, and is employed herein to describe the conversion of lower oIefins such as ethylene to olefinic products of higher molecular weight, e.g., to dimer, trimer, tetramer and the like. The reaction rate and product distribution obtained are highly dependent on the exact catalyst composition and the reaction conditions employed. Two such general classes of catalysts are the "Ziegler" types consisting of aluminum trialkyls and the "Ziegler-Natta" types consist-ing of aluminum alkyls or alkyl halides and titanium halides. ~lajor disadvantages of aluminum alkyl catalysts : . .:
:.
12B~929 are their highly reactive and pyrophoric nature and the fact that they must be used at relatively high temperatures, e.g., 200C to 275C and pressures, e.g., 2000 to 4000 psig.
Although much milder reaction conditions are used when the aluminum alkyls are used in conjunction with titanium halides, product quality and ease of catalyst separation from products of both of these prior art types of catalysts are not as high as desired.
An article by W. Keim, F. H. Kowaldt, R. Goddard and CO Kruger entitled "Novel Coordination of (Benzoylmethylene) triphenylphosphorane in a Nickel Oligomeriæation Catalyst", in Agnew. Chem. Int. Ed. Engl. (1978) No. 6, page 466, discloses that a nickel ylide having the structure:
PH p 2 CH
\ Nl ~ 1 Ph3P O Jc Ph , converts ethylene into alpha olefins or polyethylene.
SUMMARY OF THE INVENTION
According to the present invention, a process is provided for oligomerizing ethylene to normal alpha olefins, ~ that is, straight chain alpha olefins, which process comprises ;20 reacting ethylene in a methanol water mixture containing 0.5 to ~20 wt % water under oligomerization conditions in contact with a nickel ylide defined by the following formula:
Rl / R2 R3 / ~ ~ 7 :
R57E M _C _R8 . . . ,, - :
~28392g 01 _3_ wherein Rl~ R2~ R3~ R4, Rs, ~6~ R7 and R8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about 1 to about 24 carbon atoms, aryl radicals having from about 6 to about 20 carbon atoms, alkenyl radicals having from about 2 to about 30 carbon atoms, cycloalkyl radicals having -from about 3 to about 40 carbon a-toms, aralkyl and alkaryl radicals having from about 6 to about 40 carbon atoms, halogen radicals, hydroxyl, alkoxy and aryloxy groups, and hydrocarbyl groups carrying halogen, hydroxyl, alkoxy or aryloxy groups, provided that at least one of each Rl to R8 radicals is a sulfonato group or an alkyl, aryl, alkenyl, lS cycloalkyl, aralkyl or alkaryl carrying a sulfonato group, M is sulfur or oxygen, E is phosphorus, arsenic, antimony or nitrogen and F is phosphorus, arsenic or antimony, to obtain a reaction product containing (A) a methanol-water phase having dissolved therein said nickel ylide and (B) an alpha olefin phase and then separating said phases from each other to recover said alpha olefin phase.
Preferred amounts of water used in the process of the present invention are between 2 and lS wt % more preferably between ~ and 13 wt ~. The weight percent water is calculated as a percent of the combined methanol and water which is Eed to the reaction zone in the oligo-merization process of the present invention.
Among other factors, the present invention is based on our finding that the addition of`water to the reaction zone does not ruin the catalyst or its activity, particularly when the wt ~ water is controlled to below about 20 wt % of the combined methanol-water solvent. In addition, we have found that the water has an unexpectedly ; ~ marked affect in improving the phase separation of the catalyst-rich phase from the product olefin-rich phase.
Also we have found that the inclusion of water in the reaction zone results in a surprising increase in the purity of the alpha olein product, and in a shift in product distribution toward lighter alpha olefin product~
.
~8~g~9 Typically, ln the process of the present lnventlon, the ethylene, methanol, water and nickel yllde catalyst are ed to a reactlon æone or a reactor, such as a contlnuous stirred tank reactor, wherein the oligomerization reaction is controlled by reaction conditions such as temperature, pressure, residence time and catalyst concentratlon. The reaction effluent is passed to a separation ~one wherein a methanol-water catalyst phase is separa~ed for recycle to the reaction zone, also ethylene is separated for recycle, and produc~ alpha oleflns are separa~ed. The separation may be carried out in two steps. First, a gas~liquid separation wherein recycle ethylene gas is removed. In a second step, the liquid from the first step may be passed to a liquid/liquid separator where a methanol, water and catalyst phase are separated as a lower liquld phase for recycle to the reaction zone and an organic liquid phase is separated as a top or Iighter phase. The organic phase, consisting of minor amounts -~
of ethylene, but mainly of the product normal alpha olefins, i~ -preferabIy passed to a recovery zone to recover additional ~ethylene for recycle to the reaction zone and to recover the product normal alpha olefins. The product alpha olefins will typically be primarily in the C4 to C30 range, but may range fro= C~ to as high as C10O.
; Th~ aatalysts used in the reaction zone are ~he nickel ylides as set orth in our prior patents, particularly includln~ U.S. Pa~ent No. 4,310,716 and U.S. Patent No.
4,293,502. The same catalysts whlch are preferred ln those cited patents are preferred herein. Likewlse, preferred catalyst preparation procedures including methods of including ~30 a sul~onate group ln the catalyst, and preferred reaction : : ' .'' -P~
-12839~9 61936-1768 conditlons such as temperatures, pres~ures, catalyst concentration and residence time, are as described in ~he cited patent~, especially U.S. Patent No. 4,310,716 and U.S. Patent No. 4,293,502.
Such preferred reaction conditions include a temperature between 20C and 100C, oligomerization ,, :
:-:
::
.: . ... - ., : .
reaction zone residence time between 10 minutes and 24 hours, and pressures between 10 and 3000 psig, more preferably between 100 and 2000 psig.
BRIEF DESCRIPTION OF THE DRAWING
The drawing is a graph showing the effect of 10 wt water on product C14 alpha olefin.
ÆXAMPLES
Ethylene oligomerization reactions were carried out using a sulfonated nickel ylide (SUNY) catalyst. The SUNY
10catalyst used was Compound 9 of U.S. Patent No. 4,310,716 which has the following structure~
~ P/ - C - SO~Na+
Ph / ~ ¦
Ph ~ ~ ~ C Ph Ph-: ~ P~
The SUNY catalyst was prepared in accordance with the Example III preparation of U.S. Patent No. 4,310,716.
Results for experiments at various water levels are set forth in Table I below.
The experiments were performed using freshly prepared solutions of SUNY catalyst in methanol or a methanol/water mix-ture. Dilution of a 1000 ppm water standard in methanol orgravimetric mixing of anhydrous methanol in distilled water gave the desired mixtures. The nominal concentra~ion of SUNY
catalyst was 2.5 x 10-3 gram moles per liter of the methan-ol or methanol-water mixture.
Ethylene was chemically scrubbed to remove oxygen using a copper on alumina catalyst~adsorbent giving less than 1 ppm oxygen content in the feed ethylene.
~;~
~ .
~33~2~
- Sa- 61936-1768 The experiments used the same reaction conditions, namely SO~C, 500 psig and 2 hours residence time. Results for runs at various amounts of water in methanol are given in Table I below.
.
.
: ~ ~
.
-.
, . . . .
. -, ~ . . . ..
.
Table I
-Catalyst 05Example No. Water, ppm Activity 6 105944 4~34 Table I shows that water was found not to ruin the catalyst activity when the water is used in amounts up to about 10.5~ water. Our further data indicates the catalyst activity would likely not drop off too steeply up to water concentrations of about 20 wt %. The Activity column in Table I relates to moles of ethylene reacted per moles of SUNY catalyst in the reaction zone.
Table II below is a summary of data on product distribution by weight percent from runs including those in Table I. The Table II data illustrates a large shift i~n product distribution, toward lighter oligomers, which we discovered occurred using water in the reaction system.
Table II
25 ~ ~
; Example Water, No. % C6 C8 C10 C12 C14 C16C18 C20+
: ~ ~
7 ~Oa 15.18 18.39 16.5313.54 10.29 7.67 5.28 13.12 8 5b~ 18.70 19.75 17.1713.21 9.75 6.94 4.72 9.76 30~ 9 10C 24.26 23.35 18.2512.48 8.40 5.26 3.0~ 4.96 ` Runs were also made with oxygen injected into the reaction zone. We discovered that, unlike water, oxygen was ruinous to the catalyst activity even at low ~
a Mean distribution found in the product alpha olefin (AO) layers from 15 ppm water experiments.
b Mean distribution found in the AO layers from Examples 3 and 4.
c; Mean distribution found in the AO layers from Examples 5 and 6.
: ~ :
.
,. . .
. . . : , - . . -.
.
~L28392~3 01 ~7~
p~m levels. The oxygen ppm amounts are based on the parts by weight of ethylene fed to the reaction zone. The data 05 from several runs where oxygen was injected are summarized in Table III below.
Table III
Catalyst Example No. Oxygent ppm Activity <1 8124 In our initial work, careful measures were taken to exclude water from the reaction zone, suGh as the pur-chase of anhydrous methanol and the distillation of themethanol in the presence of sodium -to reduce water to a very low level. After we discovered that water was not ruinous to catalyst activity, we explored other variables, such as the effect of pressure. We found surprisingly clean separation of unreacted ethylene from product alpha olefin, even at pressures as high as 500 psig. Table IV
below lists results of these runs in Examples 21, 22,` 23 ~, and 24. The catalyst solution consisted of the SUNY cata-lyst (at a concentration of 2.5 x 10-3 gram moles per liter of methanol-water solution fed to the reaction zonej, methanol and water~
~ :
.
:, :
. ~ .
: : - - . . . , .
: . .
.
~Z~33929 TABLE IV
Exam~le No. 21 22 23 24 Run Conditions . .
Reactor Temperature, C50 50 50 40 Reactor Pressure, psig700 600 600 700 Separator Pressure, psig 25 200 500 500-300 Catalyst Concentration, Gm/L
Initial Charge 2.0 2.0 200 2.0 -Continuous Addition - - - 20.0 Water Content of Catalyst 10.0 10.0 10.0 10.0 Solution, Wt ~
Experimental Results Overall Length of Run t ~r 21 16 16 40 Catalyst Productivity,836 N/A N/A1127-770 Gm Product/Gm Catalyst Product Purity, Wt ~ 94.4 91.1 91.6 92.7-94.6 Alpha-C14 Product Distribution,0.49 0.71 0.56 0.42-0.31 Epsilon Referring in more detail now to the drawing (graph), the ordinate or "Y" axis relates to product purity, in particular C14 linear alpha olefin purity. Impurities in the alpha olefin include branch chain olefins and internal (as opposed to alpha) olefins. The abscissa or "X" axis relates to the product distribution or "epsilon" value. Epsilon is a measure of the extent of reaction and is effectively a ratio of ~30 the chain termination rate to the growth rate. It is directly :
d~ , : . . ': ' . ~ ' ':. ' . , ~339;~9 - 8a- 61936-1758 related to the mole fraction, X, of a given carbon number olefin by the following equation:
Xr =~ ( 1 )r~1, r~ 2, where r is the number of ethylene units.
~28~929 01 ~9~
The graph shows the data points, in terms of C14 alpha olefin product purity and product distribution, for 05 a number of oligomerization runs made with the above-described SUNY catalyst both with no water (only methanol as a solvent) in the reaction zone and with 10% water in the methanol solvent. As can be noted from the graph, approximately 2~ greater C14 alpha olefin product purity lU was achieved with 10% water versus that achieved without water in the methanol. Thus the runs represented by three data points at .57 epsilon can be considered. These runs were made at essentially identical conditions except that the run indicated by X had 10% water in the methanol solvent whereas the two runs indicated by the dots had no water in the methanol. The X data point shows about 90.8 purity for the C14 alpha olefin whereas the dot data points show about 87.5 to 88% purity for the Cl~ alpha olefin. The run conditions for the various epsilon values shown on the graph were varied similar to the conditions shown in Examples 21 through 24, except that for the runs indicated by dots, no water was included in the methanol.
, ,: ~
~ ~ 35~
.
,. .
'
ReEerence is made to Applicants' following ~.S.
Patents:
U.S. Paten-t No. 4,293,502, Nickel Ylides, issued October 6, 1981;
0 U S. Patent No. 4,293,727, Process for Oligomerization of Ethylene, issued October 6, 1981;
U.S. Patent No. 4,310,716, Process for Oligomeri2ation of Ethylene in Methanol, issued January 12, 1982;
U.S. Patent No. 4,377,528, Group V~ Salts and Process for Preparing Same, issued March 22, 1983;
U.S. Patent No. 4,377,529, SulEonated Group VA Ylides and Process for Preparing Same, issued March 22, 1983;
U.S. Patent No. 4,382,153, Process for Oligomerization of Ethylene in Methanol, issued ~ay 3, 1983; and ~0 UOS. Patent No. 4,529,554, Process for the Preparation of Nickel Ylides Containing Ylide Ligands with a Sulfonated ; Group V Component, issued July 16, 1985.
FIELD OF THE INVENTION
.. . . .__ The present invention relates to the use of 25; nickel ylides to oligomerize ethylene in a solvent medium containing methanol.
DESCRIPTION OF THE PRIOR ART
It is well known in the art to use a variety of catalysts to oligomerize ethylene to higher molecular weight olefins. The term "oligomerize" has been employed, and is employed herein to describe the conversion of lower oIefins such as ethylene to olefinic products of higher molecular weight, e.g., to dimer, trimer, tetramer and the like. The reaction rate and product distribution obtained are highly dependent on the exact catalyst composition and the reaction conditions employed. Two such general classes of catalysts are the "Ziegler" types consisting of aluminum trialkyls and the "Ziegler-Natta" types consist-ing of aluminum alkyls or alkyl halides and titanium halides. ~lajor disadvantages of aluminum alkyl catalysts : . .:
:.
12B~929 are their highly reactive and pyrophoric nature and the fact that they must be used at relatively high temperatures, e.g., 200C to 275C and pressures, e.g., 2000 to 4000 psig.
Although much milder reaction conditions are used when the aluminum alkyls are used in conjunction with titanium halides, product quality and ease of catalyst separation from products of both of these prior art types of catalysts are not as high as desired.
An article by W. Keim, F. H. Kowaldt, R. Goddard and CO Kruger entitled "Novel Coordination of (Benzoylmethylene) triphenylphosphorane in a Nickel Oligomeriæation Catalyst", in Agnew. Chem. Int. Ed. Engl. (1978) No. 6, page 466, discloses that a nickel ylide having the structure:
PH p 2 CH
\ Nl ~ 1 Ph3P O Jc Ph , converts ethylene into alpha olefins or polyethylene.
SUMMARY OF THE INVENTION
According to the present invention, a process is provided for oligomerizing ethylene to normal alpha olefins, ~ that is, straight chain alpha olefins, which process comprises ;20 reacting ethylene in a methanol water mixture containing 0.5 to ~20 wt % water under oligomerization conditions in contact with a nickel ylide defined by the following formula:
Rl / R2 R3 / ~ ~ 7 :
R57E M _C _R8 . . . ,, - :
~28392g 01 _3_ wherein Rl~ R2~ R3~ R4, Rs, ~6~ R7 and R8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about 1 to about 24 carbon atoms, aryl radicals having from about 6 to about 20 carbon atoms, alkenyl radicals having from about 2 to about 30 carbon atoms, cycloalkyl radicals having -from about 3 to about 40 carbon a-toms, aralkyl and alkaryl radicals having from about 6 to about 40 carbon atoms, halogen radicals, hydroxyl, alkoxy and aryloxy groups, and hydrocarbyl groups carrying halogen, hydroxyl, alkoxy or aryloxy groups, provided that at least one of each Rl to R8 radicals is a sulfonato group or an alkyl, aryl, alkenyl, lS cycloalkyl, aralkyl or alkaryl carrying a sulfonato group, M is sulfur or oxygen, E is phosphorus, arsenic, antimony or nitrogen and F is phosphorus, arsenic or antimony, to obtain a reaction product containing (A) a methanol-water phase having dissolved therein said nickel ylide and (B) an alpha olefin phase and then separating said phases from each other to recover said alpha olefin phase.
Preferred amounts of water used in the process of the present invention are between 2 and lS wt % more preferably between ~ and 13 wt ~. The weight percent water is calculated as a percent of the combined methanol and water which is Eed to the reaction zone in the oligo-merization process of the present invention.
Among other factors, the present invention is based on our finding that the addition of`water to the reaction zone does not ruin the catalyst or its activity, particularly when the wt ~ water is controlled to below about 20 wt % of the combined methanol-water solvent. In addition, we have found that the water has an unexpectedly ; ~ marked affect in improving the phase separation of the catalyst-rich phase from the product olefin-rich phase.
Also we have found that the inclusion of water in the reaction zone results in a surprising increase in the purity of the alpha olein product, and in a shift in product distribution toward lighter alpha olefin product~
.
~8~g~9 Typically, ln the process of the present lnventlon, the ethylene, methanol, water and nickel yllde catalyst are ed to a reactlon æone or a reactor, such as a contlnuous stirred tank reactor, wherein the oligomerization reaction is controlled by reaction conditions such as temperature, pressure, residence time and catalyst concentratlon. The reaction effluent is passed to a separation ~one wherein a methanol-water catalyst phase is separa~ed for recycle to the reaction zone, also ethylene is separated for recycle, and produc~ alpha oleflns are separa~ed. The separation may be carried out in two steps. First, a gas~liquid separation wherein recycle ethylene gas is removed. In a second step, the liquid from the first step may be passed to a liquid/liquid separator where a methanol, water and catalyst phase are separated as a lower liquld phase for recycle to the reaction zone and an organic liquid phase is separated as a top or Iighter phase. The organic phase, consisting of minor amounts -~
of ethylene, but mainly of the product normal alpha olefins, i~ -preferabIy passed to a recovery zone to recover additional ~ethylene for recycle to the reaction zone and to recover the product normal alpha olefins. The product alpha olefins will typically be primarily in the C4 to C30 range, but may range fro= C~ to as high as C10O.
; Th~ aatalysts used in the reaction zone are ~he nickel ylides as set orth in our prior patents, particularly includln~ U.S. Pa~ent No. 4,310,716 and U.S. Patent No.
4,293,502. The same catalysts whlch are preferred ln those cited patents are preferred herein. Likewlse, preferred catalyst preparation procedures including methods of including ~30 a sul~onate group ln the catalyst, and preferred reaction : : ' .'' -P~
-12839~9 61936-1768 conditlons such as temperatures, pres~ures, catalyst concentration and residence time, are as described in ~he cited patent~, especially U.S. Patent No. 4,310,716 and U.S. Patent No. 4,293,502.
Such preferred reaction conditions include a temperature between 20C and 100C, oligomerization ,, :
:-:
::
.: . ... - ., : .
reaction zone residence time between 10 minutes and 24 hours, and pressures between 10 and 3000 psig, more preferably between 100 and 2000 psig.
BRIEF DESCRIPTION OF THE DRAWING
The drawing is a graph showing the effect of 10 wt water on product C14 alpha olefin.
ÆXAMPLES
Ethylene oligomerization reactions were carried out using a sulfonated nickel ylide (SUNY) catalyst. The SUNY
10catalyst used was Compound 9 of U.S. Patent No. 4,310,716 which has the following structure~
~ P/ - C - SO~Na+
Ph / ~ ¦
Ph ~ ~ ~ C Ph Ph-: ~ P~
The SUNY catalyst was prepared in accordance with the Example III preparation of U.S. Patent No. 4,310,716.
Results for experiments at various water levels are set forth in Table I below.
The experiments were performed using freshly prepared solutions of SUNY catalyst in methanol or a methanol/water mix-ture. Dilution of a 1000 ppm water standard in methanol orgravimetric mixing of anhydrous methanol in distilled water gave the desired mixtures. The nominal concentra~ion of SUNY
catalyst was 2.5 x 10-3 gram moles per liter of the methan-ol or methanol-water mixture.
Ethylene was chemically scrubbed to remove oxygen using a copper on alumina catalyst~adsorbent giving less than 1 ppm oxygen content in the feed ethylene.
~;~
~ .
~33~2~
- Sa- 61936-1768 The experiments used the same reaction conditions, namely SO~C, 500 psig and 2 hours residence time. Results for runs at various amounts of water in methanol are given in Table I below.
.
.
: ~ ~
.
-.
, . . . .
. -, ~ . . . ..
.
Table I
-Catalyst 05Example No. Water, ppm Activity 6 105944 4~34 Table I shows that water was found not to ruin the catalyst activity when the water is used in amounts up to about 10.5~ water. Our further data indicates the catalyst activity would likely not drop off too steeply up to water concentrations of about 20 wt %. The Activity column in Table I relates to moles of ethylene reacted per moles of SUNY catalyst in the reaction zone.
Table II below is a summary of data on product distribution by weight percent from runs including those in Table I. The Table II data illustrates a large shift i~n product distribution, toward lighter oligomers, which we discovered occurred using water in the reaction system.
Table II
25 ~ ~
; Example Water, No. % C6 C8 C10 C12 C14 C16C18 C20+
: ~ ~
7 ~Oa 15.18 18.39 16.5313.54 10.29 7.67 5.28 13.12 8 5b~ 18.70 19.75 17.1713.21 9.75 6.94 4.72 9.76 30~ 9 10C 24.26 23.35 18.2512.48 8.40 5.26 3.0~ 4.96 ` Runs were also made with oxygen injected into the reaction zone. We discovered that, unlike water, oxygen was ruinous to the catalyst activity even at low ~
a Mean distribution found in the product alpha olefin (AO) layers from 15 ppm water experiments.
b Mean distribution found in the AO layers from Examples 3 and 4.
c; Mean distribution found in the AO layers from Examples 5 and 6.
: ~ :
.
,. . .
. . . : , - . . -.
.
~L28392~3 01 ~7~
p~m levels. The oxygen ppm amounts are based on the parts by weight of ethylene fed to the reaction zone. The data 05 from several runs where oxygen was injected are summarized in Table III below.
Table III
Catalyst Example No. Oxygent ppm Activity <1 8124 In our initial work, careful measures were taken to exclude water from the reaction zone, suGh as the pur-chase of anhydrous methanol and the distillation of themethanol in the presence of sodium -to reduce water to a very low level. After we discovered that water was not ruinous to catalyst activity, we explored other variables, such as the effect of pressure. We found surprisingly clean separation of unreacted ethylene from product alpha olefin, even at pressures as high as 500 psig. Table IV
below lists results of these runs in Examples 21, 22,` 23 ~, and 24. The catalyst solution consisted of the SUNY cata-lyst (at a concentration of 2.5 x 10-3 gram moles per liter of methanol-water solution fed to the reaction zonej, methanol and water~
~ :
.
:, :
. ~ .
: : - - . . . , .
: . .
.
~Z~33929 TABLE IV
Exam~le No. 21 22 23 24 Run Conditions . .
Reactor Temperature, C50 50 50 40 Reactor Pressure, psig700 600 600 700 Separator Pressure, psig 25 200 500 500-300 Catalyst Concentration, Gm/L
Initial Charge 2.0 2.0 200 2.0 -Continuous Addition - - - 20.0 Water Content of Catalyst 10.0 10.0 10.0 10.0 Solution, Wt ~
Experimental Results Overall Length of Run t ~r 21 16 16 40 Catalyst Productivity,836 N/A N/A1127-770 Gm Product/Gm Catalyst Product Purity, Wt ~ 94.4 91.1 91.6 92.7-94.6 Alpha-C14 Product Distribution,0.49 0.71 0.56 0.42-0.31 Epsilon Referring in more detail now to the drawing (graph), the ordinate or "Y" axis relates to product purity, in particular C14 linear alpha olefin purity. Impurities in the alpha olefin include branch chain olefins and internal (as opposed to alpha) olefins. The abscissa or "X" axis relates to the product distribution or "epsilon" value. Epsilon is a measure of the extent of reaction and is effectively a ratio of ~30 the chain termination rate to the growth rate. It is directly :
d~ , : . . ': ' . ~ ' ':. ' . , ~339;~9 - 8a- 61936-1758 related to the mole fraction, X, of a given carbon number olefin by the following equation:
Xr =~ ( 1 )r~1, r~ 2, where r is the number of ethylene units.
~28~929 01 ~9~
The graph shows the data points, in terms of C14 alpha olefin product purity and product distribution, for 05 a number of oligomerization runs made with the above-described SUNY catalyst both with no water (only methanol as a solvent) in the reaction zone and with 10% water in the methanol solvent. As can be noted from the graph, approximately 2~ greater C14 alpha olefin product purity lU was achieved with 10% water versus that achieved without water in the methanol. Thus the runs represented by three data points at .57 epsilon can be considered. These runs were made at essentially identical conditions except that the run indicated by X had 10% water in the methanol solvent whereas the two runs indicated by the dots had no water in the methanol. The X data point shows about 90.8 purity for the C14 alpha olefin whereas the dot data points show about 87.5 to 88% purity for the Cl~ alpha olefin. The run conditions for the various epsilon values shown on the graph were varied similar to the conditions shown in Examples 21 through 24, except that for the runs indicated by dots, no water was included in the methanol.
, ,: ~
~ ~ 35~
.
,. .
'
Claims (28)
1. A process for oligomerizing ethylene to normal alpha olefins and recovering said olefins from the reac-tion product which comprises reacting ethylene in a methanol-water mixture containing 0.5 to 20 wt % water under oligomerization conditions in contact with a nickel ylide defined by the following formula:
wherein R1, R2, R3, R4, R5, R6, R7 and R8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about 1 to about 24 carbon atoms, aryl radicals having from about 6 to about 20 carbon atoms, alkenyl radicals having from about 2 to about 30 carbon atoms, cycloalkyl radicals having from about 3 to about 40 carbon atoms, aralkyl and alkaryl radicals having from about 6 to about 40 carbon atoms, halogen radicals, hydroxyl, alkoxy and aryloxy groups, and hydrocarbyl groups carrying halogen, hydroxyl, alkoxy or aryloxy groups, provided that at least one of each R1 to R8 radicals is a sulfonato group or an alkyl, aryl, alkenyl, cycloalkyl, aralkyl or alkaryl carrying a sulfonato group, M is sulfur or oxygen, E is phosphorus, arsenic, antimony or nitrogen and F is phosphorus, arsenic or antimony, to obtain a reaction product containing (A) a methanol-water phase having dissolved therein said nickel ylide and (B) an alpha olefin phase and then separating said phases from each other to recover said alpha olefin phase.
wherein R1, R2, R3, R4, R5, R6, R7 and R8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about 1 to about 24 carbon atoms, aryl radicals having from about 6 to about 20 carbon atoms, alkenyl radicals having from about 2 to about 30 carbon atoms, cycloalkyl radicals having from about 3 to about 40 carbon atoms, aralkyl and alkaryl radicals having from about 6 to about 40 carbon atoms, halogen radicals, hydroxyl, alkoxy and aryloxy groups, and hydrocarbyl groups carrying halogen, hydroxyl, alkoxy or aryloxy groups, provided that at least one of each R1 to R8 radicals is a sulfonato group or an alkyl, aryl, alkenyl, cycloalkyl, aralkyl or alkaryl carrying a sulfonato group, M is sulfur or oxygen, E is phosphorus, arsenic, antimony or nitrogen and F is phosphorus, arsenic or antimony, to obtain a reaction product containing (A) a methanol-water phase having dissolved therein said nickel ylide and (B) an alpha olefin phase and then separating said phases from each other to recover said alpha olefin phase.
2. A process as defined in Claim 1 wherein the percent water is 2 to 15.
3. A process a defined in Claim 1 wherein the per-cent water is 7 to 13.
4. A process a defined in Claim 1 wherein the sulfonato group is in R4, R5 and/or R6 and at least one of R4, R5 and R6 is aryl.
5. A process as defined in Claim 1 wherein the sulfonato group is in R1, R2 and or R3.
6. A process as defined in Claim 1 wherein R7 com-prises a sulfonato group.
7. A process as defined in Claim 1 wherein E and F
are both phosphorus and M is oxygen.
are both phosphorus and M is oxygen.
8. A process as defined in Claim 4 wherein E and F
are both phosphorus and M is oxygen.
are both phosphorus and M is oxygen.
9. A process as defined in Claim 5 wherein E and F
are both phosphorus and M is oxygen.
are both phosphorus and M is oxygen.
10. A process as defined in Claim 6 wherein E and F
are both phosphorus and M is oxygen.
are both phosphorus and M is oxygen.
11. A process as defined in Claim 8 wherein each of R4, R5, and R6 is phenyl, one of which is substituted with a sulfonato group.
12. A process as defined in Claim 11 wherein each of R1, R2, R3 and R8 is phenyl and R7 is hydrogen,
13. A process as defined in Claim 9 wherein each of R1, R2 and R3 is phenyl, one of which is substituted with a sulfonato group,
14. A process as defined in Claim 13 wherein each of R4, R5, R6 and R8 is phenyl and R7 is hydrogen.
15. A process as defined in Claim 10 wherein each of R1, R2, R3, R4, R5, R6 and R8 is phenyl and R7 is a sulfonato group.
16. A process as defined in Claim 15 wherein said ylide is in the form of its sodium salt.
17. A process as defined in Claim 1 wherein said ethylene and said nickel ylide are contacted at a tempera-ture of from about -20°C to about 200°C for about 1 minute to 72 hours.
18. A process as defined in Claim 1 wherein said ethylene and said nickel ylide are contacted at a tempera-ture of from about 20°C to about 100°C for about 10 minutes to about 24 hours.
19, A process as defined in Claim 15 wherein said ethylene and said nickel ylide are contacted at a tempera-ture of from about -20°C to about 200°C for about 1 minute to 72 hours.
20. A process as defined in Claim 15 wherein said ethylene and said nickel ylide are contacted at a tempera-ture of from about 20°C to about 100°C for about 10 minutes to about 24 hours.
21. A process as defined in Claim 16 wherein said ethylene and said nickel ylide are contacted at a tempera-ture of from about -20°C to about 200°C for about 1 minute to 72 hours.
22. A process as defined in Claim 16 wherein said ethylene and said nickel ylide are contacted at a temperature of from about 20°C to about 100°C for about 10 minutes to about 24 hours.
23. A process as defined in Claim 1 wherein the ethylene pressure is maintained in the range of about 100 to about 2000 psig throughout the reaction.
24. A process as defined in Claim 1 wherein the ethylene pressure is maintained in the range of about 350 to about 850 psig throughout the reaction.
25. A process as defined in Claim 16 wherein the ethylene pressure is maintained in the range of about 100 to about 2000 psig throughout the reaction.
26. A process as defined in Claim 1 wherein the methanol-water phase is recycled to the reaction zone for use therein.
27. A process as defined in Claim 13 wherein the methanol-water phase is recycled to the reaction zone for use therein.
28. A process as defined in Claim 14 wherein the methanol-water phase is recycled to the reaction zone for use therein.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US900,204 | 1986-08-25 | ||
US06/900,204 US4711969A (en) | 1986-08-25 | 1986-08-25 | Oligomerization of ethylene in methanol and water |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1283929C true CA1283929C (en) | 1991-05-07 |
Family
ID=25412136
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000543761A Expired - Fee Related CA1283929C (en) | 1986-08-25 | 1987-08-05 | Oligomerization of ethylene in methanol and water |
Country Status (6)
Country | Link |
---|---|
US (1) | US4711969A (en) |
EP (1) | EP0257232B1 (en) |
JP (1) | JP2525422B2 (en) |
CA (1) | CA1283929C (en) |
DE (1) | DE3781744T2 (en) |
ES (1) | ES2052516T3 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US5744679A (en) * | 1996-12-27 | 1998-04-28 | Uop Llc | Using water concentration to control ethylene oligomerization |
FR2784110B1 (en) | 1998-10-06 | 2003-08-01 | Atochem Elf Sa | PROCESS FOR THE POLYMERIZATION OF OLEFINS IN THE PRESENCE OF WATER |
EP2196444A1 (en) | 2008-12-11 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to make alpha olefins from ethanol |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4293727A (en) * | 1980-08-18 | 1981-10-06 | Gulf Research & Development Company | Process for the oligomerization of ethylene |
US4310716A (en) * | 1980-08-18 | 1982-01-12 | Gulf Research & Development Company | Process for the oligomerization of ethylene in methanol |
US4301318A (en) * | 1980-08-18 | 1981-11-17 | Gulf Research & Development Company | Process for recovering oligomerization product |
US4382153A (en) * | 1982-04-05 | 1983-05-03 | Gulf Research & Development Company | Process for the oligomerization of ethylene in methanol |
-
1986
- 1986-08-25 US US06/900,204 patent/US4711969A/en not_active Expired - Lifetime
-
1987
- 1987-06-24 ES ES87109087T patent/ES2052516T3/en not_active Expired - Lifetime
- 1987-06-24 EP EP87109087A patent/EP0257232B1/en not_active Expired - Lifetime
- 1987-06-24 DE DE8787109087T patent/DE3781744T2/en not_active Expired - Fee Related
- 1987-08-05 CA CA000543761A patent/CA1283929C/en not_active Expired - Fee Related
- 1987-08-24 JP JP62208401A patent/JP2525422B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US4711969A (en) | 1987-12-08 |
EP0257232A3 (en) | 1989-02-15 |
JPS6366133A (en) | 1988-03-24 |
DE3781744T2 (en) | 1993-04-22 |
EP0257232A2 (en) | 1988-03-02 |
ES2052516T3 (en) | 1994-07-16 |
DE3781744D1 (en) | 1992-10-22 |
JP2525422B2 (en) | 1996-08-21 |
EP0257232B1 (en) | 1992-09-16 |
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