CA2003873C - Heat-resistant exhaust manifold and method of preparing same - Google Patents

Heat-resistant exhaust manifold and method of preparing same

Info

Publication number
CA2003873C
CA2003873C CA002003873A CA2003873A CA2003873C CA 2003873 C CA2003873 C CA 2003873C CA 002003873 A CA002003873 A CA 002003873A CA 2003873 A CA2003873 A CA 2003873A CA 2003873 C CA2003873 C CA 2003873C
Authority
CA
Canada
Prior art keywords
manifold
heat
compound
section
exhaust manifold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002003873A
Other languages
French (fr)
Other versions
CA2003873A1 (en
Inventor
Frederick F. Cyb
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2003873A1 publication Critical patent/CA2003873A1/en
Application granted granted Critical
Publication of CA2003873C publication Critical patent/CA2003873C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K31/00Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups
    • B23K31/02Processes relevant to this subclass, specially adapted for particular articles or purposes, but not covered by only one of the preceding main groups relating to soldering or welding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/18Construction facilitating manufacture, assembly, or disassembly
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/16Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
    • B05B7/22Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc
    • B05B7/222Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc using an arc
    • B05B7/226Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed electrically, magnetically or electromagnetically, e.g. by arc using an arc the material being originally a particulate material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/32Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/08Other arrangements or adaptations of exhaust conduits
    • F01N13/10Other arrangements or adaptations of exhaust conduits of exhaust manifolds
    • F01N13/102Other arrangements or adaptations of exhaust conduits of exhaust manifolds having thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/16Selection of particular materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/18Construction facilitating manufacture, assembly, or disassembly
    • F01N13/1888Construction facilitating manufacture, assembly, or disassembly the housing of the assembly consisting of two or more parts, e.g. two half-shells
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/14Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2310/00Selection of sound absorbing or insulating material
    • F01N2310/06Porous ceramics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/20Methods or apparatus for fitting, inserting or repairing different elements by mechanical joints, e.g. by deforming housing, tube, baffle plate or parts thereof
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/22Methods or apparatus for fitting, inserting or repairing different elements by welding or brazing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2470/00Structure or shape of gas passages, pipes or tubes
    • F01N2470/16Plurality of inlet tubes, e.g. discharging into different chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2510/00Surface coverings
    • F01N2510/02Surface coverings for thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2530/00Selection of materials for tubes, chambers or housings
    • F01N2530/26Multi-layered walls

Abstract

A method of lining an exhaust manifold is disclosed, including applying a thin layer of a heat-resistant compound to the interior of an exhaust manifold. The manifold may be in two or more sections where the compound is applied and the sections may subsequently be joined together to form the manifold. The compound may contain zirconium or may be a ceramic material.

Description

2(~03873 -Our Reference: GYB-100-A PATENT
HEAT-RESISTANT EXHAUST MANIFOLD AND MET~OD OF PREPARING SAME
BACKGROUND 0~ TH~ INVENTION
1. Field of the Invention The present invention relste~ to heat-resistant exhau~t manifolds and method~ of preparing such manifold~. More particularly, the present invention relates to a method of lining an exhaust manifold with a heat-re~istant compound containing zirconium, a ceramic material, or both, and a heat-re~i~tant manifold which i~ the product of the described proces~.
2. Prior Art In the automotive indu~try, it has long been recognized that heat generated by the combu~tion process emanating from the exhaust manifold~ into the engine compartment of a vehicle is a problem. Not only doe~ such heat degrade the various components in the engine compartment which are not heat resi~tant, but the heat al~o cau~es the exhaust manifold~ them~elve~ to become brittle and deteriorate. The problem is exacerbated in today's smaller engine compartment~ since car~ are being "down-sized", especially when a high-performance engine is packed tightly into such a ~mall engine compartment, e.g., a turbocharged or ) supercharged engine. Heat 108~ from exhaust manifolds is not limited to such high-performance engines, however.
Many varied type~ of heat shields and insulation have been employed in the prior attempts to alleviate this problem.
Ongoing effort~ continue to channel the maximum po~ible amount of heat which has been 8enerated in the combustion chambers, 2()0~873 _ from the exhaust ports of the cylinder heads out into and through the exhaust system, minimizing the amount which is released in the engine compartment.
Another rea~on for wishing to channel the maximum amount of heat possible through the exhaust system i9 that by retaining heat in the exhaust ~ystem, "light off" of the catalytic converter may be achieved sooner if more heat is conveyed directlg to the converter. This promotes greater fuel efficiency as well as lowered exhaust emis~ions, which are both high priorities in today's market.
SUMMARY OF THE INVENTION
The present invention provides a method of lining an exhaust manifold, compri~ing the steps of:
(a) applying a thin layer of a heat-re~istant compound i to the interior of an exhaust manifold to form a liner therein;
and ~ b) bonding the compound to the inner wall of the manifold.
The manifold may be in two or more sections when the compound i~ applied thereto, and the parts may be welded or otherwise joined to~ether after the compound has been bonded to the manifold. The compound may be applied in a molten state and may be bonded to the manifold by the application of heat thereto. The compound may be a ceramic material, may contain zirconium, or may contain both of these. The application of the compound and the heat binding may be performed substantially simultaneously. The surfaoe to be coated may be treated to roughen the ~urface before the compound is applied, and in one embodiment the compound is applied in a layer about 10 to about 15 thousands of an inch in thickne~s.

20038~3 The present invention also encompasses a heat-resistant manifold which is prepared by the process of the pre~ent invention. Further detail regarding preferred embodiments of the present invention may be found in the detailed des,cription section. Throughout the following description and in the drawings, identical reference numbers are used to refer to the same or a similar component shown in multiple figures of the drawings, in which:
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is an exploded perspective view of of an exhaust manifold in accordance with the present invention;
FIG. 2 is a cross-sectional view of the lower section of the manifold of FIG. 1; taken along the line 2-2;
FIG. 3 is a view similsr to FIG. 2 showing a heat-resistant compound being applied to the interior of the manifold;
FIG. 4 is a cross-sectional view of a section of the assembled manifold showing a liner formed of heat-resistant material on the inside thereof.
FIG. 5 is a cross-sectional view of the head of a plasma-arc spray gun, partially cut away.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring to FIG. 1, four sections of an exhaust manifold body are illustrated, along with additional components of the manifold. The additional components shown are a first flange 38 for the attachment of an exhau~t pipe, and a machined plate 39 having holes therein for attachment to a cylinder head of an automotive engine, and may be added to this manifold body , ;i _ 2()03~
once the hest resistant compound has been bonded thereto snd the component part~ have been joined together. The additional components msy be attached to the manifold body by laser welding, tig welding, or other suitable method. Additional plates similar to 39 would be used to complete the manifold of FIG. 1.
The manifold illustrated in FIG. 1 compri~es a pair of upper sections 10, 12 including a first section 10 of a manifold which is a first sheet metal shell. The manifold of FIG. 1 also includes a pair of lower sections 11, 13 of a manifold including a second section 11 which is a ~econd sheet metal shell. The first and second sections 10, 11 are alignable as may be seen in FIG. 1.
As shown in FIG. 2, the second section 11 has a ridge 14 formed on each side of the ~hell 11 for joining the ~ections 10, 11 together as will be described herein.
Referring to FI~. 3, a metal spraying gun 15 is illustrated in cross-section, applying a thin heat-resistant layer to the inside of the shell 11 forming a liner 16 on the inside thereof. In a metal spraying application a suitable fuel mixture, ~uch a~ hydrogen, acetylene, or acetylene and oxygen i8 fed into a fuel inlet 20 of the metal-spraying gun 15 from a fuel ~ource (not shown). Air i~ fed into an air port 18 of the gun 15 , and mixes with the fuel at the outlet 28 of the gun.
The fuel is ignited to form 8 flame front 30 at the outlet of the gun.
Drive air is applied to a drive air port 22 and passe~ through a drive air conduit 24 to force a compound in the form of a powder out from a reservoir 32 and into a powder ~ 0~.~873 `--.
conduit 26 nnd thence into the gun 15. The compound 34 is ~prayed outwardly from the gun in a conioal pattern and is bonded to the inside of the sheet metsl shell 11 to form a first liner 16 on the inside thereof.
The interior surface 9 of the sheet metal shell 11 may be roughened beforehand to promote bonding to the surface 9, RUCh 8S by sandblasting, machining, or other appropriate method. Alternatively, any appropriate adhesive may be applied to the inner surface 11 of the sheet metal shell to promote bonding of the compound 34 to the inside surface 9 cf the sheet metal shell 11.
As seen in FIG. 5, an alternate means of applying the compound 34 to the sheet metal shells i~ plasma-aro sprsying. .,-In plasms-arc spraying, a 8as such as nitrogen or argon is fed into a plasma spray gun at a gas inlet 47 and passed between two electrodes 40, 41 where it is ionized by a continuous high voltage arc 42 passing between the electrodes. This ionizes the gas and forms it into a plasma capable of attaining temperatures of 20,0000F or more. The electrodes 40, 41 are normally liquid cooled by cooling ports 46, 44 to prolong their life. A
powder 34 which is used to form the heat-resi~tant liner 16 i8 fed into the gun 48 at a powder inlet 43 and enters the plasma downstresm of the src 42 hhere it is melted by the plasms and is caught up therein and sprayed from the outlet 45 of the gun 48 snd applied to the inside of the manifold sections 10, 11, 12, 13. P1asma-arc spraying is relatively well known and understood in the art.
The compound 34 which i8 used to form the liner may contain zirconium, may be a metallic alloy or a ceramic material or may'be a powdered glassy compound such as zircon. These rY.

2.()03~3~

compounds are used because of their known heat-resistant properties. The liner 16 may be bonded to the interior 9 of the sheet metal shell 11 by the application of heat thereto. While the thickness of the liner 16 i8 not critical to the present invention, a thickness of about .010 inches to about .015 inches has been found to be helpful in promoting heat-resistance in the finished manifold. Each of the remaining sections 10, 12 and 13 of the manifold is treated in a similar fashion, snd the gun 15 or 48 is used to spray a thin layer of the heat-resistant compound 34 on the insides thereof, which is bonded to the shell~ 10, 12, 13 to form similar liners.
Referring to FIG. 4, a cross-sectional view of part of the assembled manifold is illustrated with the upper section 10 joined to the lower ~ection 12. The rib 14 of the lower section 11 is bent in a die (not shown) in two operations and is clamped around the ridges 19 of the sheet metal shell 10 and may be welded thereto as at 36 to insure that exhaust gas will not leak out of the manifold at the seams proximate the ridges 14. The ridges 14 thus provide a means for securing the first section 10 to the second section 12 in the aligned configuration.
Alternative methods of joining the two sections 10, 11 may be used, as will be appreciated by those skilled in the art. The third and fourth sections 12, 13 are joined together in a similar fashion. The plates 38 and 39 sre added on as shown in FIG. 1 and three additional plstes ~imilar to 39 would be used to complete the manifold of FIG. 1.
The foregoing description i8 intended to be illustrative, and not restrictive. Many modifications of the present invention will occur to those skilled in the art. All f~ Z()(~3873 such modifications within the scope of the sppended claims are intended to be within the scope and spirit of the present invention.
Having, thus, described the invention, what i~ claimed is:

_ . 7 ~r ~

Claims (11)

1. A method of lining an exhaust manifold, comprising the steps of:
(a) applying a heat-resistant compound to form a first liner on the inside of a first sheet-metal shell, the first shell comprising a first section of an exhaust manifold;
(b) bonding the first liner to the first shell;
(c) applying a heat-resistant compound to form a second liner on the inside of a second sheet-metal shell, the second shell comprising a second section of the exhaust manifold and being alignable with the first section;
(d) bonding the second liner to the second shell;
and then (e) joining the first and second shells together in an aligned configuration to form an exhaust manifold or a portion thereof.
2. The method of Claim 1, wherein the compound is applied in a molten condition and is allowed to solidify in the shells.
3. The method of Claim 2, wherein the compound is applied by plasma-arc spraying.
4. The method of Claim 1, wherein the liners comprise a ceramic material.
5. The method of Claim 1, wherein the liners comprise zirconium.
6. The method of Claim 1, wherein the steps are performed substantially simultaneously.
7. The method of Claim 1, further comprising the step of roughening the interiors of the shells prior to applying the compound.
8. A heat-resistant exhaust manifold which is a product of the method of Claim 1.
9. The manifold of Claim 8, wherein the liners comprise zirconium.
10. The manifold of Claim 8, wherein the liners comprise a ceramic material.
11. A heat-resistant exhaust manifold, comprising:
(a) a first section of a manifold body formed in a sheet metal shell;
(b) a second section of a manifold body formed in a sheet metal shell and being alignable with the first section;
(c) a thin liner for each of the first and second sections, the liners bonded to the respective sections; and (d) means for securing the first section to the second section in an aligned configuration.
CA002003873A 1988-11-25 1989-11-24 Heat-resistant exhaust manifold and method of preparing same Expired - Fee Related CA2003873C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US275,949 1988-11-25
US07/275,949 US4930678A (en) 1988-11-25 1988-11-25 Heat-resistant exhaust manifold and method of preparing same

Publications (2)

Publication Number Publication Date
CA2003873A1 CA2003873A1 (en) 1990-05-25
CA2003873C true CA2003873C (en) 1995-03-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA002003873A Expired - Fee Related CA2003873C (en) 1988-11-25 1989-11-24 Heat-resistant exhaust manifold and method of preparing same

Country Status (6)

Country Link
US (1) US4930678A (en)
EP (1) EP0414832A1 (en)
JP (1) JPH03504879A (en)
KR (1) KR900701461A (en)
CA (1) CA2003873C (en)
WO (1) WO1990006207A1 (en)

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Also Published As

Publication number Publication date
EP0414832A1 (en) 1991-03-06
WO1990006207A1 (en) 1990-06-14
CA2003873A1 (en) 1990-05-25
US4930678A (en) 1990-06-05
KR900701461A (en) 1990-12-03
JPH03504879A (en) 1991-10-24

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