CA2016371C - Method for manufacturing fibre-reinforced material - Google Patents
Method for manufacturing fibre-reinforced materialInfo
- Publication number
- CA2016371C CA2016371C CA002016371A CA2016371A CA2016371C CA 2016371 C CA2016371 C CA 2016371C CA 002016371 A CA002016371 A CA 002016371A CA 2016371 A CA2016371 A CA 2016371A CA 2016371 C CA2016371 C CA 2016371C
- Authority
- CA
- Canada
- Prior art keywords
- fibre
- resin
- web
- impregnation
- molten resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
- B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
- B29B15/10—Coating or impregnating independently of the moulding or shaping step
- B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
- B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
Abstract
A method for impregnating fibre bundles with molten or liquid resin in manufacturing a fibre-reinforced material, which material comprises one or more fibre bundles, wherein each fibre is surrounded by matrix resin, by impregnating a continuous web of one or more fibre bundles with molten or liquid resin and solidifying the resin by cooling or chemical reaction. During the impregnation the molten or liquid resin material is made subject to shear forces by bringing it between two closely nearby surfaces which are in moving relationship into each other.
Description
METHOD FOR MANUFACTURING ~ 3 FIBRE-R~lNFORCED MA~ERIAL
Reference may be made to Applicant's two commonly-assigned and related ~pplications filed simultaneously herewith, 2,016,369 and 2,016,370.
The present invention concerns a method for manufacturing a fibre-reinforced material. Specifically the present invention concerns a method for manufacturing fibre-reinforced material, which is formed by a reinforcing fibre bundle or bundles bonded with a matrix forming resin material in such a way that the individual fibres are surrounded by resin material.
The main problem in the manufacture of products of this kind is the high viscosity of some matrix forming materials. Because the individual fibres in the fibre bundles are very tightly near each other, it is thereby difficult for the resin material to penetrate into the bundle to surround all individual fibres. However such penetration is necessary in view of the desired properties of the product, such as strength, stiffness, chemical resistance etc.
Many methods have been tried to solve the problem. In one solution fibre bundles are transferred through a so-called cross-head die, in which molten or liquid resin is penetrated into the fibre bundles moving through the die. In the so-called powder method a web of fibre bundles is transferred through a bed of thermoplastic resin particles, whereby the web of fibre bundles carries along resin particles, which at a later state are melted. There are also solvent A
CA 020l637l lsg8-ll-02 methods in which fibre bundles are impregnated with resins dissolved in a liquid medium.
The cross-head die method has proven to be ineffective in the impregnation of fibre bundles with thermoplastic resin because all individual fibres will not be surrounded by resin material.
Powder methods have been proven to necessitate a multiplicity of processing stages which are difficult to synchronize, are expensive to purchase and operate while damaging the reinforcement. In solvent methods a drying process is required, which is expensive, causes environmental problems, is time-consuming and limits the production rate. Furthermore the quality of the product is low due to voids left after the removal of solvents.
SUNMARY OF TnE l~.v~r..lON
The present invention provides a method and apparatus for impregnating reinforcing fibres in the form of fibre bundles so that individual fibres are surrounded by bonding resin. The invention is based on the known phenomena that some pseudoplastic materials being subjected to shear stresses experience a decrease in viscosity. This phenomena, known as shear thinning, is common for various emulsions, dispersions, suspensions and other materials including melts of thermoplastic resins and solutions of thermoset resins. The amount of this shear thinning can be altered with the level of shear stress applied to the material. At low stresses a small degree of thinning is achieved, but at intermediate shear stresses the degree of shear thinning increases dramatically, while at very high shear stresses the degree of thinning reverts to low levels as the material approaches minimum viscosity.
A typical range of viscosity for thermoplastic resin materials is 102-106 PaS and for thermoset resin solutions 100-5000 PaS. In the impregnation of reinforcing fibres a range of ~6~71 ~ .
,. ~...
~, ~ -~ 10 PaS is ideal, a common magnitude is 102 PaS and in some cases ~~- 103 PaS can be acceptable. Typical shear rate ranges for polymer ~ metals and solutions are 10 1-106 l/S and the range of maximum . , ~ ,~ - :
response can be 10~-104 l/S.
The method according to the invention comprises the step of impregnating fibre bundles with molten or liquid resin while manufacturing a fibre-reinforced material, which material comprises one or more fibre bundles, wherein each fibre is surrounded by matrix resin, by impregnating a continuous web of one or more fibre bundles with molten or liquid resin and solidifying said resin by cooling or chemical reaction. The method of the invention is characterized in that during said impregnation said molten or liquid resin material is made subject to shear forces by bringing it between closely proximate surfaces which are in moving relationship relative to each other.
According to an advantageous embodiment of the method according to the invention one of said surfaces is a stationary surface and the other surface is a moving surface. However, both of said surfaces can be moving surfaces as well. The essential feature in view of the invention is that said surfaces are close to each other and that they are in moving relationship relative to each other.
According to an advantageous embodiment of the method according to the invention one of the moving surfaces comprises the continuous web of a fibre bundle itself or bundles themselves to be impregnated. In this case the resin to be impregnated is led between one fibre bundle to be impregnated and the stationary or moving surface, whereat the surfaces naturally are moving in different directions to each other. This causes shear forces that are directed to the resin to be impregnated and ~I crease the viscosity of the .
:: ~
~ 3 7 ~
~'~
. ~ , :................ , ' ,, resin and facilitate the covering of the individual fibres with resin.
~ . .
According to an advantageous embodiment of the method .
according to the invention the moving surfaces are surfaces of cylindrical or annular elements, in which case one of the surface is formed by the web to be impregnated. Said surfaces can also be planar surfaces, wherein one of the surfaces can be the web to be impregnated itself or said surfaces can be formed of two discs that rotate in opposite directions and are closely proximate to each other.
With the method of the invention it is possible to manufacture any fibre reinforced material, in which the fibres are in the form of bundles. The fibres can be any kind of fibres bondable by a matrix resin. Such products are for example fibre-reinforced granules for injection molding or other processes, prepregs or preimpregnated materials for additional processes such as extrusion, filament winding, tape laying, etc.
Suitable fibres for the invention are thus glass fibres, carbon fibres and aramid fibres and thermoplastic fibres. Most common fibre materials to be used are glass fibre products in the form of bundles, which can be used as single bundles or also in the form of woven products, for example as glass fibre rovings.
Typically glass fibre bundles contain thousands of individual fibres with a diame_er of 10-17 ~m.
The resin material to be used for bonding fibre-reinforced products can be a thermoplastic resin, which is impregnated into fibre bundles as melt, or a thermosetting resin, which will be solidified after impregnation with heat or chemical reaction.
Suitable thermoplastic resins are among others olefine 2 ~ ~ ~ 3 7 1 ., , ",. . .
... .. .
homogeneous polymers and copolymers, vinyl chloride homogeneous polymers and copolymers, polyethylene terephtalate, acrylonitrile ~ homogeneous, polymers and copolymers, polyamides or copolyamides, - thermoplastic polymers or formaldehyde, polycarbonate, polysulphone ~ :, and mixtures of two or more of any of the polymers above or in general any other thermoplastics which show decreased viscosity by ;~ shearing action.
The invention concerns also an apparatus for impregnating ~- reinforcing fibres in the form of fibre bundles in manufacturing :::
fibre-reinforced material, which material comprises one or more bundles, wherein each fibre is surrounded by matrix resin. The apparatus of the invention is characterized in that it comprises means for subjecting shear forces during said impregnation into said molten or liquid resin, said means consisting of two closely nearby surfaces, between which surfaces said molten or liquid resin material is forced to flow and thus made subject to shear forces during impregnation, and means for feeding said molten or liquid resin material between said surfaces.
According to an advantageous embodiment of the apparatus according to the invention at least one of said surfaces is a moving surface.
- According to an advantageous embodiment of the apparatus according to the invention both of said surfaces are moving surfaces.
According to an advantageous embodiment of the apparatus according to the invention one of said surfaces comprises a web of a fibre bundle to be impregnated.
According to another embodiment of the apparatus according to the invention said surfaces are cylindrical or planar surfaces.
According to an advantageous embodiment of the apparatus according to the invention said means for feeding molten or liquid resin between said surfaces comprise one or more feed openings in the wall of an impregnation head, which openings have circular, rectangular or other cross-section.
According to an advantageous embodiment of the apparatus according to the invention said feed openings are one or more slits cut into the wall of an impregnation head.
According to an advantageous embodiment of the apparatus according to the invention said impregnation head is connected to the outlet of an extruder.
According to an advantageous embodiment of the apparatus according to the invention the impregnation head is curved or planar within the area of impregnation.
BRIBF D~8CRIPTION OF T~B DRA~ING8 The invention will be further illustrated but not limited by referring to the enclosed figures, in which Fig. 1 is an elevational view, partly in section, of an apparatus according to the invention applied for manufacturing continuously fibre-reinforced thermoplastic granules.
Fig. 2 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with each other are formed by the fibre bundle web itself and the outer surface of a cylindrical impregnation head.
Fig. 3 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with each other are formed by the fibre bundle web itself and the outer surface of a rotating impregnation head.
Fig. 4 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with ~;
:' . ..-,~
~ each other are formed by the fibre bundle web itself and the outer '~ surface of the impregnation head, which outer surface is planar within the impregnation area.
~ ig. 5 is a detailed perspective view of an impregnation head showing several feed openings heaving a round cross-section for supplying molten thermoplastic resin to the impregnation area.
Fig. 6 is a detailed perspective view of an impregnation '~ head showing one slit-like feed opening for supplying molten thermoplastic resin to the impregnation area, and Fig. 7 is a detail of an impregnation head showing two slit-like feed openings having a round cross-section and opening to opposite sides of the impregnation head for supplying molten thermoplastic resin to the impregnation area.
,,-f ~ ~k~ ENBODl~h,B OF T~ .v~h,lON
In Fig. 1 a web 10 of glass fibre bundles is supplied from a drum 11 through a preheating chamber 12 and a spreading device 13 , , ,~, , i into an impregnation head 18. In the spreading device 13 the web 10 is transported via a set of rolls 14, so that the fibre web runs in an alternating way over and under the rolls. This spreads the individual fibres in the bundles and thus facilitates the impregnation in the impregnation stage. However this spreading device 13 is not necessary and it does not form a part of the invention. The impregnation head 18 is connected to an extruder 15, into which the resin material 16 to be impregnated is fed through a hopper 17. In the extruder 15 the resin is melted and is formed to be ready to be fed to the impregnation head 18 according to the invention.
The resin impregnated web 10b or band of fibre bundles is then transferred to a cooling unit 19, where the molten resin is 20~637~
solidified by cooling. The solidifying can also take place by chemical reaction, whereat the impregnated resin may contain additives necessary for the solidifying and, in the solidifying, extra heating can naturally be used, if necessary.
From the cooling unit 19 the resin impregnated and solidified fibre bundles are then transferred to a chopper 20, which cuts the impregnated web to pieces 21 of proper length, which are ready for packing or are ready to be used for manufacture of the products. With the method the apparatus of the invention it is ~- , naturally also possible to prepare continuous fibre-reinforced products, which in that case are cut in pieces of desired lengths or are left completely uncut.
The transportation of the web 10 through the apparatus in Fig. 1 can be carried put by any suitable pulling device. A
belt-driven pulling device 22 is schematically illustrated in Fig. 1.
In Fig. 2 there is disclosed an impregnation head 30, inside which there is a feed channel 31. The resin 32 to be impregnated is pumped through this channel 31 for example from an extruder (not shown), where the thermoplastic resin to be impregnated is melted.
From the channel 31 a feed opening 33 extends to the outer surface of the annular impregnation head 30 at point 34. The web of fibre bundles lOa travels to the direction marked with arrow A past this impregnation point 34, whereby the resin is pulled between the surfaces of the web lOa and the surface 36 of the impregnation head 30 and thus made subject to shear forces, which lower its viscosity and ensure a m~ximum impregnation of the fibre bundles. The fibre bundle web impregnated with resin is marked with lOb.
Fig. 3 shows another preferred embodiment to Fig. 2 except that the impregnation head 30 is formed by a rotating annular element -. 2~1637~
.. ,i. -which rotates it in the direction of arrow B. In this embodiment of the invention the shearing action is stronger and takes place within a longer area as in the apparatus according to Fig. 2.
In the embodiments according to Figs. 2 and 3 the two elements, between which the shearing action takes place, have a cylinder-like form. In the embodiment of Fig. 4 the impregnation takes place between the planar surfaces 37 of the impregnation head ~- 30 and the surface of web 10.
- ~ In the preferred embodiments of Figs. 5 and 6 different shapes of the feed openings 33 have been disclosed. In Fig. 5 there are three openings 33 with a circular cross-section. There can be one or more openings dependent on the width of the fibre bundle web 10. In Fig. 6 there is one slit-like feed opening 33, the width of which is approximately the same as the width of the fibre bundle web -~ 10. In Fig. 7 there is disclosed an embodiment, in which there are two slit-like feed openings 33 to the opposite sides of the impregnation head 30. Of course there can be more than two slit-like feed openings. It is possible also in the embodiment of Fig. 5 to use two or more groups of feed openings 33.
. Although the invention has been described above as applied to the impregnation of a moving fibre bundle web, it is evident that the fibre bundle web can be stationary and the impregnation head can be arranged to be movable. The function of the invention will be the same in both cases. Also, it is possible to use two or more impregnation heads according to the invention and these impregnation heads can be placed on the same or different sides of the fibre web to be impresnated.
Furthermore, it is possible to pretreat the resin to be impregnated in other ways within the scope of the methods and ~-apparatuses of the invention such that its viscosity is decreased.
Reference may be made to Applicant's two commonly-assigned and related ~pplications filed simultaneously herewith, 2,016,369 and 2,016,370.
The present invention concerns a method for manufacturing a fibre-reinforced material. Specifically the present invention concerns a method for manufacturing fibre-reinforced material, which is formed by a reinforcing fibre bundle or bundles bonded with a matrix forming resin material in such a way that the individual fibres are surrounded by resin material.
The main problem in the manufacture of products of this kind is the high viscosity of some matrix forming materials. Because the individual fibres in the fibre bundles are very tightly near each other, it is thereby difficult for the resin material to penetrate into the bundle to surround all individual fibres. However such penetration is necessary in view of the desired properties of the product, such as strength, stiffness, chemical resistance etc.
Many methods have been tried to solve the problem. In one solution fibre bundles are transferred through a so-called cross-head die, in which molten or liquid resin is penetrated into the fibre bundles moving through the die. In the so-called powder method a web of fibre bundles is transferred through a bed of thermoplastic resin particles, whereby the web of fibre bundles carries along resin particles, which at a later state are melted. There are also solvent A
CA 020l637l lsg8-ll-02 methods in which fibre bundles are impregnated with resins dissolved in a liquid medium.
The cross-head die method has proven to be ineffective in the impregnation of fibre bundles with thermoplastic resin because all individual fibres will not be surrounded by resin material.
Powder methods have been proven to necessitate a multiplicity of processing stages which are difficult to synchronize, are expensive to purchase and operate while damaging the reinforcement. In solvent methods a drying process is required, which is expensive, causes environmental problems, is time-consuming and limits the production rate. Furthermore the quality of the product is low due to voids left after the removal of solvents.
SUNMARY OF TnE l~.v~r..lON
The present invention provides a method and apparatus for impregnating reinforcing fibres in the form of fibre bundles so that individual fibres are surrounded by bonding resin. The invention is based on the known phenomena that some pseudoplastic materials being subjected to shear stresses experience a decrease in viscosity. This phenomena, known as shear thinning, is common for various emulsions, dispersions, suspensions and other materials including melts of thermoplastic resins and solutions of thermoset resins. The amount of this shear thinning can be altered with the level of shear stress applied to the material. At low stresses a small degree of thinning is achieved, but at intermediate shear stresses the degree of shear thinning increases dramatically, while at very high shear stresses the degree of thinning reverts to low levels as the material approaches minimum viscosity.
A typical range of viscosity for thermoplastic resin materials is 102-106 PaS and for thermoset resin solutions 100-5000 PaS. In the impregnation of reinforcing fibres a range of ~6~71 ~ .
,. ~...
~, ~ -~ 10 PaS is ideal, a common magnitude is 102 PaS and in some cases ~~- 103 PaS can be acceptable. Typical shear rate ranges for polymer ~ metals and solutions are 10 1-106 l/S and the range of maximum . , ~ ,~ - :
response can be 10~-104 l/S.
The method according to the invention comprises the step of impregnating fibre bundles with molten or liquid resin while manufacturing a fibre-reinforced material, which material comprises one or more fibre bundles, wherein each fibre is surrounded by matrix resin, by impregnating a continuous web of one or more fibre bundles with molten or liquid resin and solidifying said resin by cooling or chemical reaction. The method of the invention is characterized in that during said impregnation said molten or liquid resin material is made subject to shear forces by bringing it between closely proximate surfaces which are in moving relationship relative to each other.
According to an advantageous embodiment of the method according to the invention one of said surfaces is a stationary surface and the other surface is a moving surface. However, both of said surfaces can be moving surfaces as well. The essential feature in view of the invention is that said surfaces are close to each other and that they are in moving relationship relative to each other.
According to an advantageous embodiment of the method according to the invention one of the moving surfaces comprises the continuous web of a fibre bundle itself or bundles themselves to be impregnated. In this case the resin to be impregnated is led between one fibre bundle to be impregnated and the stationary or moving surface, whereat the surfaces naturally are moving in different directions to each other. This causes shear forces that are directed to the resin to be impregnated and ~I crease the viscosity of the .
:: ~
~ 3 7 ~
~'~
. ~ , :................ , ' ,, resin and facilitate the covering of the individual fibres with resin.
~ . .
According to an advantageous embodiment of the method .
according to the invention the moving surfaces are surfaces of cylindrical or annular elements, in which case one of the surface is formed by the web to be impregnated. Said surfaces can also be planar surfaces, wherein one of the surfaces can be the web to be impregnated itself or said surfaces can be formed of two discs that rotate in opposite directions and are closely proximate to each other.
With the method of the invention it is possible to manufacture any fibre reinforced material, in which the fibres are in the form of bundles. The fibres can be any kind of fibres bondable by a matrix resin. Such products are for example fibre-reinforced granules for injection molding or other processes, prepregs or preimpregnated materials for additional processes such as extrusion, filament winding, tape laying, etc.
Suitable fibres for the invention are thus glass fibres, carbon fibres and aramid fibres and thermoplastic fibres. Most common fibre materials to be used are glass fibre products in the form of bundles, which can be used as single bundles or also in the form of woven products, for example as glass fibre rovings.
Typically glass fibre bundles contain thousands of individual fibres with a diame_er of 10-17 ~m.
The resin material to be used for bonding fibre-reinforced products can be a thermoplastic resin, which is impregnated into fibre bundles as melt, or a thermosetting resin, which will be solidified after impregnation with heat or chemical reaction.
Suitable thermoplastic resins are among others olefine 2 ~ ~ ~ 3 7 1 ., , ",. . .
... .. .
homogeneous polymers and copolymers, vinyl chloride homogeneous polymers and copolymers, polyethylene terephtalate, acrylonitrile ~ homogeneous, polymers and copolymers, polyamides or copolyamides, - thermoplastic polymers or formaldehyde, polycarbonate, polysulphone ~ :, and mixtures of two or more of any of the polymers above or in general any other thermoplastics which show decreased viscosity by ;~ shearing action.
The invention concerns also an apparatus for impregnating ~- reinforcing fibres in the form of fibre bundles in manufacturing :::
fibre-reinforced material, which material comprises one or more bundles, wherein each fibre is surrounded by matrix resin. The apparatus of the invention is characterized in that it comprises means for subjecting shear forces during said impregnation into said molten or liquid resin, said means consisting of two closely nearby surfaces, between which surfaces said molten or liquid resin material is forced to flow and thus made subject to shear forces during impregnation, and means for feeding said molten or liquid resin material between said surfaces.
According to an advantageous embodiment of the apparatus according to the invention at least one of said surfaces is a moving surface.
- According to an advantageous embodiment of the apparatus according to the invention both of said surfaces are moving surfaces.
According to an advantageous embodiment of the apparatus according to the invention one of said surfaces comprises a web of a fibre bundle to be impregnated.
According to another embodiment of the apparatus according to the invention said surfaces are cylindrical or planar surfaces.
According to an advantageous embodiment of the apparatus according to the invention said means for feeding molten or liquid resin between said surfaces comprise one or more feed openings in the wall of an impregnation head, which openings have circular, rectangular or other cross-section.
According to an advantageous embodiment of the apparatus according to the invention said feed openings are one or more slits cut into the wall of an impregnation head.
According to an advantageous embodiment of the apparatus according to the invention said impregnation head is connected to the outlet of an extruder.
According to an advantageous embodiment of the apparatus according to the invention the impregnation head is curved or planar within the area of impregnation.
BRIBF D~8CRIPTION OF T~B DRA~ING8 The invention will be further illustrated but not limited by referring to the enclosed figures, in which Fig. 1 is an elevational view, partly in section, of an apparatus according to the invention applied for manufacturing continuously fibre-reinforced thermoplastic granules.
Fig. 2 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with each other are formed by the fibre bundle web itself and the outer surface of a cylindrical impregnation head.
Fig. 3 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with each other are formed by the fibre bundle web itself and the outer surface of a rotating impregnation head.
Fig. 4 is an end view of an impregnation head according to the invention, where the surfaces being in moving relationship with ~;
:' . ..-,~
~ each other are formed by the fibre bundle web itself and the outer '~ surface of the impregnation head, which outer surface is planar within the impregnation area.
~ ig. 5 is a detailed perspective view of an impregnation head showing several feed openings heaving a round cross-section for supplying molten thermoplastic resin to the impregnation area.
Fig. 6 is a detailed perspective view of an impregnation '~ head showing one slit-like feed opening for supplying molten thermoplastic resin to the impregnation area, and Fig. 7 is a detail of an impregnation head showing two slit-like feed openings having a round cross-section and opening to opposite sides of the impregnation head for supplying molten thermoplastic resin to the impregnation area.
,,-f ~ ~k~ ENBODl~h,B OF T~ .v~h,lON
In Fig. 1 a web 10 of glass fibre bundles is supplied from a drum 11 through a preheating chamber 12 and a spreading device 13 , , ,~, , i into an impregnation head 18. In the spreading device 13 the web 10 is transported via a set of rolls 14, so that the fibre web runs in an alternating way over and under the rolls. This spreads the individual fibres in the bundles and thus facilitates the impregnation in the impregnation stage. However this spreading device 13 is not necessary and it does not form a part of the invention. The impregnation head 18 is connected to an extruder 15, into which the resin material 16 to be impregnated is fed through a hopper 17. In the extruder 15 the resin is melted and is formed to be ready to be fed to the impregnation head 18 according to the invention.
The resin impregnated web 10b or band of fibre bundles is then transferred to a cooling unit 19, where the molten resin is 20~637~
solidified by cooling. The solidifying can also take place by chemical reaction, whereat the impregnated resin may contain additives necessary for the solidifying and, in the solidifying, extra heating can naturally be used, if necessary.
From the cooling unit 19 the resin impregnated and solidified fibre bundles are then transferred to a chopper 20, which cuts the impregnated web to pieces 21 of proper length, which are ready for packing or are ready to be used for manufacture of the products. With the method the apparatus of the invention it is ~- , naturally also possible to prepare continuous fibre-reinforced products, which in that case are cut in pieces of desired lengths or are left completely uncut.
The transportation of the web 10 through the apparatus in Fig. 1 can be carried put by any suitable pulling device. A
belt-driven pulling device 22 is schematically illustrated in Fig. 1.
In Fig. 2 there is disclosed an impregnation head 30, inside which there is a feed channel 31. The resin 32 to be impregnated is pumped through this channel 31 for example from an extruder (not shown), where the thermoplastic resin to be impregnated is melted.
From the channel 31 a feed opening 33 extends to the outer surface of the annular impregnation head 30 at point 34. The web of fibre bundles lOa travels to the direction marked with arrow A past this impregnation point 34, whereby the resin is pulled between the surfaces of the web lOa and the surface 36 of the impregnation head 30 and thus made subject to shear forces, which lower its viscosity and ensure a m~ximum impregnation of the fibre bundles. The fibre bundle web impregnated with resin is marked with lOb.
Fig. 3 shows another preferred embodiment to Fig. 2 except that the impregnation head 30 is formed by a rotating annular element -. 2~1637~
.. ,i. -which rotates it in the direction of arrow B. In this embodiment of the invention the shearing action is stronger and takes place within a longer area as in the apparatus according to Fig. 2.
In the embodiments according to Figs. 2 and 3 the two elements, between which the shearing action takes place, have a cylinder-like form. In the embodiment of Fig. 4 the impregnation takes place between the planar surfaces 37 of the impregnation head ~- 30 and the surface of web 10.
- ~ In the preferred embodiments of Figs. 5 and 6 different shapes of the feed openings 33 have been disclosed. In Fig. 5 there are three openings 33 with a circular cross-section. There can be one or more openings dependent on the width of the fibre bundle web 10. In Fig. 6 there is one slit-like feed opening 33, the width of which is approximately the same as the width of the fibre bundle web -~ 10. In Fig. 7 there is disclosed an embodiment, in which there are two slit-like feed openings 33 to the opposite sides of the impregnation head 30. Of course there can be more than two slit-like feed openings. It is possible also in the embodiment of Fig. 5 to use two or more groups of feed openings 33.
. Although the invention has been described above as applied to the impregnation of a moving fibre bundle web, it is evident that the fibre bundle web can be stationary and the impregnation head can be arranged to be movable. The function of the invention will be the same in both cases. Also, it is possible to use two or more impregnation heads according to the invention and these impregnation heads can be placed on the same or different sides of the fibre web to be impresnated.
Furthermore, it is possible to pretreat the resin to be impregnated in other ways within the scope of the methods and ~-apparatuses of the invention such that its viscosity is decreased.
Claims (4)
1. In a method for impregnating fibre bundles with thermoplastic resin by impregnating a continuous web comprising one or more fibre bundles with molten thermoplastic resin and after impregnation solidifying the resin by cooling, said molten resin having a viscosity greater than that which would enable said molten resin to penetrate throughout the fibre bundles and to surround each individual fibre with said molten resin, the improvement comprising:
passing said web along a curved surface, said web being in contact with said curved surface;
feeding said molten resin onto said curved surface between said web and said curved surface, the contact area between said web and said surface being sufficiently long to cause continuous and sufficient shear action to reduce the viscosity of said molten resin to a level required to allow said molten resin to penetrate said fibre bundles and to surround each individual fibre with said molten resin.
passing said web along a curved surface, said web being in contact with said curved surface;
feeding said molten resin onto said curved surface between said web and said curved surface, the contact area between said web and said surface being sufficiently long to cause continuous and sufficient shear action to reduce the viscosity of said molten resin to a level required to allow said molten resin to penetrate said fibre bundles and to surround each individual fibre with said molten resin.
2. The method of claim 1, wherein said curved surface is a stationary surface.
3. The method of claim 1, wherein said surface is a cylindrical surface, further comprising rotating said cylindrical surface in an opposite direction to the direction of the web movement.
4. The method of claim 1, 2 or 3, wherein said thermoplastic material is selected from the group consisting of olefine homogeneous polymers and copolymers, vinyl chloride homogeneous polymers and copolymers, polyethylene terephthalate, acrylonitrate polymers and copolymers, polyamide or copolyamides, thermoplastic polymers, formaldehyde, polycarbonate, polysulphone, and mixtures of two or more of said polymers and copolymers.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI892264 | 1989-05-10 | ||
| FI892264A FI83490C (en) | 1989-05-10 | 1989-05-10 | FOERFARANDE OCH ANORDNING FOER FRAMSTAELLNING AV ETT FIBERSTAERKT MATERIAL. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2016371A1 CA2016371A1 (en) | 1990-11-10 |
| CA2016371C true CA2016371C (en) | 1999-04-06 |
Family
ID=8528398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002016371A Expired - Fee Related CA2016371C (en) | 1989-05-10 | 1990-05-09 | Method for manufacturing fibre-reinforced material |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5158806A (en) |
| EP (1) | EP0397506B1 (en) |
| AT (1) | ATE115467T1 (en) |
| CA (1) | CA2016371C (en) |
| DE (1) | DE69014983T2 (en) |
| ES (1) | ES2066129T3 (en) |
| FI (1) | FI83490C (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MY112441A (en) * | 1994-03-17 | 2001-06-30 | Shell Int Research | A process of melt impregnation |
| US6258453B1 (en) | 1996-09-19 | 2001-07-10 | Lawrence V. Montsinger | Thermoplastic composite materials made by rotational shear |
| FI108283B (en) * | 1997-01-13 | 2001-12-31 | M Real Oyj | Procedure for coating paper and cardboard |
| FI104502B (en) | 1997-09-16 | 2000-02-15 | Metsae Serla Oyj | A method of making a paper web |
| FI103417B1 (en) | 1997-09-16 | 1999-06-30 | Metsae Serla Oyj | Paper web and method of making it |
| FI105840B (en) * | 1997-09-16 | 2000-10-13 | Metsae Serla Oyj | A method for coating a web of material |
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| FI111649B (en) | 1998-05-11 | 2003-08-29 | M Real Oyj | The use of calcium carbonate is made from calcium oxalate as pigment |
| DE102004010245A1 (en) * | 2004-03-03 | 2005-09-22 | REIFENHäUSER GMBH & CO. MASCHINENFABRIK | Apparatus and method for applying liquid substances, in particular of lubricants to a nonwoven web |
| US7461438B2 (en) * | 2004-03-03 | 2008-12-09 | Reifenhaeuser Gmbh & Co. Maschinenfabrik | Apparatus and method for applying finishing agents onto a nonwoven web |
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| CN104723582A (en) * | 2015-03-27 | 2015-06-24 | 解廷秀 | Manufacture equipment for continuous fiber reinforced thermoplastic composite material and application thereof |
| EP3277473B1 (en) | 2015-04-02 | 2021-03-24 | Evonik Operations GmbH | Method for producing a fibre composite material |
| EP3150756A1 (en) * | 2015-10-01 | 2017-04-05 | LANXESS Deutschland GmbH | Method for producing a fiber matrix semifinished product |
| WO2018167671A1 (en) * | 2017-03-13 | 2018-09-20 | Sabic Global Technologies B.V. | Methods and system for producing unidirectional fiber tapes |
| KR102177348B1 (en) * | 2019-07-18 | 2020-11-11 | 순천향대학교 산학협력단 | Manufacture method for long fiber composite |
| CN112477117A (en) * | 2020-11-06 | 2021-03-12 | 西安交通大学 | Continuous fiber reinforced composite material preimpregnation 3D printing device and method |
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| GB1017563A (en) * | 1962-07-17 | 1966-01-19 | Shell Int Research | Method of, and apparatus for, impregnating strands of filaments, and strands of filaments impregnated by this method |
| GB1122021A (en) * | 1964-06-05 | 1968-07-31 | Kodak Ltd | Coating method and apparatus |
| LU51679A1 (en) * | 1966-08-01 | 1968-02-12 | ||
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| US3849174A (en) * | 1969-07-07 | 1974-11-19 | Union Carbide Corp | Calendering of laminated polymeric materials |
| US3941901A (en) * | 1974-02-15 | 1976-03-02 | Hoffmann-La Roche Inc. | Surface alignment method for liquid crystal cells and production of polarizers therefor |
| GB1508802A (en) * | 1974-05-22 | 1978-04-26 | Agfa Gevaert | Coating of viscous aqueous gelatin compositions on a continuous web support |
| US4113903A (en) * | 1977-05-27 | 1978-09-12 | Polaroid Corporation | Method of multilayer coating |
| FR2502064B1 (en) * | 1981-03-19 | 1985-06-14 | Saint Gobain Vetrotex | PROCESS FOR MANUFACTURING ARMORED PLASTIC GALBED PROFILES |
| EP0079143A3 (en) * | 1981-10-20 | 1984-11-21 | Adnovum Ag | Pseudoplastic gel transfer |
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| JPS60143866A (en) * | 1983-12-29 | 1985-07-30 | Konishiroku Photo Ind Co Ltd | Process and device for coating |
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| JPH0640990B2 (en) * | 1985-11-15 | 1994-06-01 | 富士写真フイルム株式会社 | Application method |
| US4894105A (en) * | 1986-11-07 | 1990-01-16 | Basf Aktiengesellschaft | Production of improved preimpregnated material comprising a particulate thermoplastic polymer suitable for use in the formation of substantially void-free fiber-reinforced composite article |
| US4804509A (en) * | 1986-12-17 | 1989-02-14 | Amoco Corporation | Hot-melt prepreg tow process |
| US5004643A (en) * | 1988-03-14 | 1991-04-02 | Sili-Tex, Inc. | Silicone polymer-internally coated webs |
-
1989
- 1989-05-10 FI FI892264A patent/FI83490C/en not_active IP Right Cessation
-
1990
- 1990-04-25 US US07/514,134 patent/US5158806A/en not_active Expired - Lifetime
- 1990-05-09 CA CA002016371A patent/CA2016371C/en not_active Expired - Fee Related
- 1990-05-10 ES ES90305068T patent/ES2066129T3/en not_active Expired - Lifetime
- 1990-05-10 AT AT90305068T patent/ATE115467T1/en not_active IP Right Cessation
- 1990-05-10 DE DE69014983T patent/DE69014983T2/en not_active Expired - Lifetime
- 1990-05-10 EP EP90305068A patent/EP0397506B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2066129T3 (en) | 1995-03-01 |
| ATE115467T1 (en) | 1994-12-15 |
| CA2016371A1 (en) | 1990-11-10 |
| EP0397506A3 (en) | 1991-10-02 |
| DE69014983D1 (en) | 1995-01-26 |
| DE69014983T2 (en) | 1995-05-11 |
| EP0397506B1 (en) | 1994-12-14 |
| FI83490C (en) | 1991-07-25 |
| EP0397506A2 (en) | 1990-11-14 |
| FI892264A (en) | 1990-11-11 |
| US5158806A (en) | 1992-10-27 |
| FI892264A0 (en) | 1989-05-10 |
| FI83490B (en) | 1991-04-15 |
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| EEER | Examination request | ||
| MKLA | Lapsed |