CA2038330A1 - Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use - Google Patents

Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use

Info

Publication number
CA2038330A1
CA2038330A1 CA002038330A CA2038330A CA2038330A1 CA 2038330 A1 CA2038330 A1 CA 2038330A1 CA 002038330 A CA002038330 A CA 002038330A CA 2038330 A CA2038330 A CA 2038330A CA 2038330 A1 CA2038330 A1 CA 2038330A1
Authority
CA
Canada
Prior art keywords
ethylene
copolymerization
alpha
olefins
impregnating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002038330A
Other languages
French (fr)
Other versions
CA2038330C (en
Inventor
Luciano Luciani
Renzo Invernizzi
Francesco Masi
Maddalena Pondrelli
Mario Polesello
Italo Borghi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedipe SpA
Original Assignee
Luciano Luciani
Renzo Invernizzi
Francesco Masi
Maddalena Pondrelli
Mario Polesello
Italo Borghi
Montedipe S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT19698A external-priority patent/IT1240611B/en
Priority claimed from IT02150390A external-priority patent/IT1243720B/en
Application filed by Luciano Luciani, Renzo Invernizzi, Francesco Masi, Maddalena Pondrelli, Mario Polesello, Italo Borghi, Montedipe S.R.L. filed Critical Luciano Luciani
Publication of CA2038330A1 publication Critical patent/CA2038330A1/en
Application granted granted Critical
Publication of CA2038330C publication Critical patent/CA2038330C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product

Abstract

A supported Ziegler-Natta catalyst active in ethylene polymerization and in the copolymerization of ethylene with alpha-olefins consists of:
(A) a cocatalyst in the form of an organometallic compound of aluminium, and (b) a solid catalyst component obtained by:
- (i) impregnating a granular solid support with a solution of a titanium alcaholate and magnesium chloride in a liquid aliphatic hydrocarbon, followed by evaporation of the hydrocarbon solvent;
- (ii) impregnating the support treated in (i) with a solution of magnesium chloride in a liquid aliphatic ester, followed by evaporation of the ester solvent; and - (iii) activating the support treated in (ii) by contact with an alkyl aluminium halide.
In a preferred embodiment, measured quantities of a silicon halide are introduced in stage (i) and/or (ii), this considerably improving catalytic activity.
In a particular embodiment, zirconium or hafnium are introduced into the solid catalyst component (B) in addition to titanium, to obtain catalysts able to produce polyethylenes with a widened molecular weight distribution.
CA002038330A 1990-03-16 1991-03-15 Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use Expired - Lifetime CA2038330C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IT19698A IT1240611B (en) 1990-03-16 1990-03-16 Supported catalyst for the polymerization of ethylene and for the copolymerization of ethylene with alpha-olefins, its preparation and its use
IT19698A/90 1990-09-18
IT02150390A IT1243720B (en) 1990-09-18 1990-09-18 Solid catalyst component for the (co)polymerisation of ethylene and process for the preparation thereof
IT21503A/90 1990-09-18

Publications (2)

Publication Number Publication Date
CA2038330A1 true CA2038330A1 (en) 1991-09-17
CA2038330C CA2038330C (en) 2002-01-15

Family

ID=26327265

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002038330A Expired - Lifetime CA2038330C (en) 1990-03-16 1991-03-15 Supported catalyst for ethylene polymerization and the copolymerization of ethylene with alpha-olefins, its preparation and use

Country Status (15)

Country Link
US (1) US5278117A (en)
EP (1) EP0446989B1 (en)
JP (1) JP3223301B2 (en)
AT (1) ATE138392T1 (en)
BR (1) BR9101045A (en)
CA (1) CA2038330C (en)
CZ (1) CZ281369B6 (en)
DE (1) DE69119628T2 (en)
DK (1) DK0446989T3 (en)
ES (1) ES2088455T3 (en)
FI (1) FI99207C (en)
GR (1) GR3020578T3 (en)
HU (1) HU212478B (en)
RU (1) RU2022971C1 (en)
SK (1) SK279445B6 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1252041B (en) * 1990-10-11 1995-05-29 Enimont Anic Srl SOLID COMPONENT OF CATALYST FOR THE (CO) POLYMERIZATION OF ETHYLENE
US5583083A (en) * 1991-12-31 1996-12-10 Neste Oy Procatalyst composition for homo- and copolymerization of alpha olefins, its preparation and its use
FI89500C (en) * 1991-12-31 1993-10-11 Neste Oy Procatalytic composition for homo- and copolymerization of alpha-olefins, its preparation and use
US5661097A (en) * 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
EP0767183B1 (en) * 1995-10-02 1998-11-18 PCD Polymere AG Supported catalyst for olefin polymerization
ES2126973T3 (en) * 1995-10-02 1999-04-01 Borealis Ag SUPPORTED CATALYST FOR THE POLYMERIZATION OF OLEFINS.
EP0771820A1 (en) * 1995-11-03 1997-05-07 Union Carbide Chemicals & Plastics Technology Corporation Supported ziegler-natta catalysts for polyolefin production
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
AU3505497A (en) 1996-07-15 1998-02-09 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
CZ34998A3 (en) * 1997-02-17 1999-08-11 Pcd Polymere Gesellschaft M. B. H. Process for preparing solid carrier for olefin polymerization catalysts
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
CN1147320C (en) 1998-11-17 2004-04-28 大正制药株式会社 Suppositories
CN1275985C (en) * 2001-11-30 2006-09-20 埃克森美孚化学专利公司 Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use
ES2657489T3 (en) * 2003-11-14 2018-03-05 Versalis S.P.A. Enhanced Solid Catalyst Component
ITMI20032206A1 (en) * 2003-11-14 2005-05-15 Polimeri Europa Spa IMPROVED CATALYST SOLID COMPONENT FOR (C0) POLYMERIZATION OF ETHYLENE AND THE CALLED USING PROCESS.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU65587A1 (en) * 1972-06-22 1973-12-27
US4192772A (en) * 1975-04-14 1980-03-11 Solvay & Cie Solid catalyst and process for the preparation thereof
DE2543181C2 (en) * 1975-09-27 1986-08-28 Basf Ag, 6700 Ludwigshafen Process for the polymerisation of ethylene or of its copolymerisation with C 3 to C 1 0 α-monoolefins
US4383095A (en) * 1979-02-16 1983-05-10 Union Carbide Corporation Process for the preparation of high density ethylene polymers in fluid bed reactor
US4359561A (en) * 1979-06-18 1982-11-16 Union Carbide Corporation High tear strength polymers
US4379758A (en) * 1980-12-24 1983-04-12 Union Carbide Corporation Catalyst composition for polymerizing ethylene
US4354009A (en) * 1981-07-30 1982-10-12 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US4370456A (en) * 1981-11-23 1983-01-25 Union Carbide Corporation Catalyst composition for copolymerizing ethylene
US4562168A (en) * 1984-05-17 1985-12-31 Phillips Petroleum Company Catalyst and olefin polymerization
IT1203330B (en) * 1987-02-06 1989-02-15 Enichem Base Spa Catalyst and catalyst component for the polymerization of ethylene or the co-polymerization of ethylene with alpha-Olefin
US5024982A (en) * 1988-12-14 1991-06-18 Phillips Petroleum Company Silica-containing olefin polymerization catalysts and process

Also Published As

Publication number Publication date
EP0446989B1 (en) 1996-05-22
DE69119628T2 (en) 1996-12-05
FI99207C (en) 1997-10-27
JPH05140220A (en) 1993-06-08
GR3020578T3 (en) 1996-10-31
RU2022971C1 (en) 1994-11-15
FI911299A0 (en) 1991-03-15
DE69119628D1 (en) 1996-06-27
EP0446989A3 (en) 1992-03-11
DK0446989T3 (en) 1996-09-16
HUT60295A (en) 1992-08-28
CS9100655A2 (en) 1991-10-15
CA2038330C (en) 2002-01-15
HU910850D0 (en) 1991-09-30
BR9101045A (en) 1991-11-05
HU212478B (en) 1996-07-29
US5278117A (en) 1994-01-11
CZ281369B6 (en) 1996-09-11
SK279445B6 (en) 1998-11-04
ES2088455T3 (en) 1996-08-16
JP3223301B2 (en) 2001-10-29
EP0446989A2 (en) 1991-09-18
ATE138392T1 (en) 1996-06-15
FI911299A (en) 1991-09-17
FI99207B (en) 1997-07-15

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed
MKEC Expiry (correction)

Effective date: 20121202