CA2045679A1 - Process for the preparation of peroxidic perfluoropolyethers - Google Patents
Process for the preparation of peroxidic perfluoropolyethersInfo
- Publication number
- CA2045679A1 CA2045679A1 CA2045679A CA2045679A CA2045679A1 CA 2045679 A1 CA2045679 A1 CA 2045679A1 CA 2045679 A CA2045679 A CA 2045679A CA 2045679 A CA2045679 A CA 2045679A CA 2045679 A1 CA2045679 A1 CA 2045679A1
- Authority
- CA
- Canada
- Prior art keywords
- preparation
- peroxidic perfluoropolyethers
- perfluoropolyethers
- peroxidic
- perfluoroolefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010702 perfluoropolyether Substances 0.000 title abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
- C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
- C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
Abstract
A process is disclosed for preparing peroxidic perfluoropolyethers comprising perfluoroalkylenoxy units having at least two carbon atoms, characterized in that one or more perfluoroolefins, except tetrafluoroethylene used alone, are reacted with oxygen in the liquid phase at a temperature not exceeding 50.degree.C and in the presence of one or more compounds having one or more F-X bonds, in which X is selected from the group consisting of F, O and Cl.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT8920207A IT1229845B (en) | 1989-04-20 | 1989-04-20 | PROCEDURE FOR THE PREPARATION OF PEROXIDE PERFLUOROPOLYETERS. |
IT20207A/89 | 1989-04-20 | ||
PCT/EP1990/000638 WO1990012832A1 (en) | 1989-04-20 | 1990-04-20 | Process for the preparation of peroxidic perfluoropolyethers |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2045679A1 true CA2045679A1 (en) | 1990-10-21 |
CA2045679C CA2045679C (en) | 2000-08-22 |
Family
ID=11164767
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002045679A Expired - Fee Related CA2045679C (en) | 1989-04-20 | 1990-04-20 | Process for the preparation of peroxidic perfluoropolyethers |
CA002045470A Expired - Fee Related CA2045470C (en) | 1989-04-20 | 1990-04-20 | Process for preparing peroxidic perfluoropolyethers |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002045470A Expired - Fee Related CA2045470C (en) | 1989-04-20 | 1990-04-20 | Process for preparing peroxidic perfluoropolyethers |
Country Status (36)
Country | Link |
---|---|
US (2) | US5258110A (en) |
EP (4) | EP0393700B1 (en) |
JP (2) | JP3043400B2 (en) |
KR (2) | KR0167551B1 (en) |
CN (2) | CN1031063C (en) |
AR (1) | AR246747A1 (en) |
AT (2) | ATE123787T1 (en) |
AU (2) | AU633081B2 (en) |
BG (1) | BG51357A3 (en) |
BR (2) | BR9007099A (en) |
CA (2) | CA2045679C (en) |
CZ (2) | CZ282933B6 (en) |
DD (2) | DD298941A5 (en) |
DE (2) | DE69020107T2 (en) |
DK (2) | DK0393700T3 (en) |
EG (2) | EG19387A (en) |
ES (2) | ES2075898T3 (en) |
FI (2) | FI96428C (en) |
GR (2) | GR3017108T3 (en) |
HU (2) | HU209675B (en) |
IE (2) | IE68409B1 (en) |
IL (2) | IL94112A0 (en) |
IT (1) | IT1229845B (en) |
MX (2) | MX174319B (en) |
NO (2) | NO178378C (en) |
NZ (2) | NZ233406A (en) |
PL (2) | PL163381B1 (en) |
PT (2) | PT93830B (en) |
RO (2) | RO110331B1 (en) |
RU (2) | RU2075486C1 (en) |
SI (2) | SI9010777B (en) |
SK (1) | SK279078B6 (en) |
UA (1) | UA26444A (en) |
WO (2) | WO1990012832A1 (en) |
YU (2) | YU77790A (en) |
ZA (2) | ZA902932B (en) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
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IT1229845B (en) * | 1989-04-20 | 1991-09-13 | Ausimont Srl | PROCEDURE FOR THE PREPARATION OF PEROXIDE PERFLUOROPOLYETERS. |
IT1241679B (en) * | 1990-03-06 | 1994-01-31 | Ausimont Spa | PERFLUOROPOLYETERS AND PROCESSES FOR THEIR PREPARATION |
IT1249319B (en) * | 1991-04-26 | 1995-02-22 | Ausimont Spa | HIGH VISCOSITY AND LOW PEROXIDE OXYGEN PERFLUOROPOLYETERS, AND PROCEDURE FOR THEIR PREPARATION |
IT1264977B1 (en) * | 1993-11-17 | 1996-10-17 | Ausimont Spa | PROCESS FOR PREPARING PERFLUOROPOLYSTERS |
IT1275972B1 (en) * | 1995-03-24 | 1997-10-24 | Ausimont Spa | DISPERSIONS OF POLYTETRAFLUOROETHYLENE IN AN ORGANIC SOLVENT AND DISPERSING AGENTS USED THEREIN |
IT1275568B (en) * | 1995-07-19 | 1997-08-07 | Ausimont Spa | PROCESS FOR THE PREPARATION OF FLUOROSSI- OR CHLOROSSI- PERFLUOROACILFLUORURI |
US5719259A (en) * | 1995-08-14 | 1998-02-17 | E. I. Du Pont De Nemours And Company | Perfluoroalkylene oxide copolymer composition containing functional groups |
IT1282627B1 (en) * | 1996-02-14 | 1998-03-31 | Ausimont Spa | PROCEDURE FOR THE PREPARATION OF PERFLUOROPOLIOSSIALKYLENES PEROXIDIC |
IT1282626B1 (en) * | 1996-02-14 | 1998-03-31 | Ausimont Spa | PEROXIDE PERFLUOROPOLYETER PREPARATION PROCESS |
EP0831110B9 (en) * | 1996-09-18 | 2005-09-07 | E.I. Du Pont De Nemours And Company | Perfluoroalkylene oxide copolymer composition containing functional groups |
IT1313597B1 (en) | 1999-08-04 | 2002-09-09 | Ausimont Spa | FLUOROPOLYEREOUS LUBRICANTS CONTAINING SULPHONYLFLUORIDE GROUPS |
US6255536B1 (en) † | 1999-12-22 | 2001-07-03 | Dyneon Llc | Fluorine containing vinyl ethers |
IT1318487B1 (en) | 2000-04-21 | 2003-08-25 | Ausimont Spa | FLUORO-ELASTOMERS. |
US7534845B2 (en) | 2000-04-21 | 2009-05-19 | Solvay Solexis S.P.A. | Fluorovinyl ethers and polymers obtainable therefrom |
IT1318488B1 (en) * | 2000-04-21 | 2003-08-25 | Ausimont Spa | FLUOROVINYLETERS AND POLYMERS THAT CAN BE OBTAINED. |
ITMI20010008A1 (en) * | 2001-01-03 | 2002-07-03 | Ausimont Spa | ADDITIVES FOR FLUOROPOLIETEREI FOR ELECTROMAGNETIC APPLICATIONS |
ITMI20010554A1 (en) | 2001-03-16 | 2002-09-16 | Ausimont Spa | ADDITIVES FOR HYDROGENATED RESINS |
ITMI20011306A1 (en) * | 2001-06-21 | 2002-12-21 | Ausimont Spa | VULCANIZABLE POLYURETHANE |
ITMI20011424A1 (en) * | 2001-07-05 | 2003-01-05 | Ausimont Spa | DISPERSIONS OF FLUORINATED POLYMERS |
EP1306417B1 (en) * | 2001-10-23 | 2012-08-01 | Solvay Specialty Polymers Italy S.p.A. | Use of fluorinated liquids for the heat exchange or as working fluids in the presence of ionizing radiations and/or irradiation with neutrons |
ITMI20020029A1 (en) * | 2002-01-10 | 2003-07-10 | Ausimont Spa | REPELLENT HYDRO-OIL COMPOSITIONS |
ITMI20020057A1 (en) * | 2002-01-15 | 2003-07-15 | Ausimont Spa | AQUEOUS COMPOSITIONS OF PERFLUOROPOLYETHER PHOSPHATES AND THEIR USE TO CONFER THE PAPER WITH OIL REPELLENCE |
ITMI20020056A1 (en) | 2002-01-15 | 2003-07-15 | Ausimont Spa | AQUEOUS COMPOSITIONS OF PERFLUOROPOLYETHER PHOSPHATES AND THEIR USE TO CONFER THE PAPER WITH OIL REPELLENCE |
ITMI20020198A1 (en) * | 2002-02-05 | 2003-08-05 | Ausimont Spa | (PER) haloethers |
ITMI20020513A1 (en) * | 2002-03-12 | 2003-09-12 | Ausimont Spa | LIQUID-LIQUID EXTRACTION OF POLAR ORGANIC SUBSTANCES FROM THEIR AQUEOUS SOLUTIONS WITH FLUORINATED EXTRACTIVE LIQUIDS |
ITMI20021228A1 (en) * | 2002-06-06 | 2003-12-09 | Ausimont Spa | COMPOSITIONS OF CROSS-LINKABLE POLYURETHANE |
ITMI20021277A1 (en) * | 2002-06-11 | 2003-12-11 | Ausimont Spa | PERFLUOROPOLYETERS INCLUDING REPETITIVE UNITS OBTAINED FROM THE OXIDATION OF PERFLUORODIOSSOLI |
ITMI20030018A1 (en) * | 2003-01-09 | 2004-07-10 | Solvay Solexis Spa | PROCEDURE FOR THE PREPARATION OF SINGLE COMPOUNDS |
ITMI20030019A1 (en) * | 2003-01-09 | 2004-07-10 | Solvay Solexis Spa | PROCEDURE FOR THE PREPARATION OF SINGLE COMPOUNDS |
WO2004087791A1 (en) * | 2003-03-31 | 2004-10-14 | Japan Science And Technology Agency | Decomposable polymer and method for producing same |
ITMI20031914A1 (en) * | 2003-10-03 | 2005-04-04 | Solvay Solexis Spa | Perfluoropolyethers. |
ITMI20031915A1 (en) * | 2003-10-03 | 2005-04-04 | Solvay Solexis Spa | PROCESS FOR THE PREPARATION OF PERFLUOROPOLIETERS. |
ITMI20040106A1 (en) * | 2004-01-27 | 2004-04-27 | Solvay Solexis Spa | POLIURETANI |
ITMI20040133A1 (en) | 2004-01-29 | 2004-04-29 | Solvay Solexis Spa | PROCESS TO PREPARE FLUOROALOGENOETERI |
ITMI20042238A1 (en) * | 2004-11-19 | 2005-02-19 | Solvay Solexis Spa | COMPOUNDS FOR FLUOROPOLIRTEREI |
ITMI20042239A1 (en) * | 2004-11-19 | 2005-02-19 | Solvay Solexis Spa | ADDITIVES FOR FLUOROPOLIETERES |
ITMI20050817A1 (en) * | 2005-05-05 | 2006-11-06 | Solvay Solexis Spa | DEALOGENATION PROCESS |
ITMI20062308A1 (en) * | 2006-11-30 | 2008-06-01 | Solvay Solexis Spa | ADDITIVES FOR HALO-POLYMERS |
WO2008065163A1 (en) * | 2006-11-30 | 2008-06-05 | Solvay Solexis S.P.A. | Fluorinated lubricants |
ITMI20062306A1 (en) * | 2006-11-30 | 2008-06-01 | Solvay Solexis Spa | FLUORINE LUBRICANTS |
EP1980583A1 (en) * | 2007-04-10 | 2008-10-15 | Solvay Solexis S.p.A. | A method for preparing carbonylic perfluoropolyethers |
JP5575637B2 (en) * | 2007-05-16 | 2014-08-20 | ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア | Fluorinated polyurethane composition |
EP2176162B1 (en) * | 2007-08-07 | 2018-02-28 | Solvay Specialty Polymers Italy S.p.A. | Modification of carbonaceous materials |
EP2100909A1 (en) | 2008-03-14 | 2009-09-16 | Solvay Solexis S.p.A. | (Per)fluorinated addition products |
PL2319879T3 (en) * | 2008-08-15 | 2016-04-29 | Zhonghao Chenguang Res Inst Chemical Ind | A peroxidic fluoropolyether and its use in emulsion polymerization of fluorin-containing monomer |
ITMI20081900A1 (en) * | 2008-10-28 | 2010-04-29 | Solvay Solexis Spa | USE OF FLUORINATED THERMOPLASTIC POLYMERS AS ADDITIVES FOR HYDROGENATED POLYMERS |
US8557952B2 (en) | 2008-12-05 | 2013-10-15 | Solvay Solexis S.P.A. | Polyfunctional (per)fluoropolyethers |
TWI520977B (en) | 2010-04-21 | 2016-02-11 | 首威索勒希斯股份有限公司 | Fluorinated polyurethane composition |
JP6377525B2 (en) | 2011-08-04 | 2018-08-22 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Composition of ionized fluoropolymer |
JP6153171B2 (en) * | 2011-12-12 | 2017-06-28 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Curable composition |
WO2013121986A1 (en) | 2012-02-17 | 2013-08-22 | 旭硝子株式会社 | Fluorine-containing ether compound, fluorine-containing ether composition and coating fluid, and substrate having surface-treated layer and method for producing said substrate |
EP2816047B1 (en) | 2012-02-17 | 2019-05-22 | AGC Inc. | Fluorinated ether compound, fluorinated ether composition and coating liquid, and substrate having surface-treated layer and method for its production |
WO2013121985A1 (en) | 2012-02-17 | 2013-08-22 | 旭硝子株式会社 | Fluorine-containing ether compound, fluorine-containing ether composition and coating fluid, and substrate having surface-treated layer and method for producing said substrate |
US9370733B2 (en) | 2012-11-05 | 2016-06-21 | Solvay Specialty Polymers Italy S.P.A. | Process for the purification of (per) fluoropolyethers with carboxylate end groups |
CN104884502B (en) | 2012-12-11 | 2016-11-23 | 索尔维特殊聚合物意大利有限公司 | Method for alkoxide (entirely) perfluoroalkyl polyether alcohol |
JP6326063B2 (en) | 2012-12-13 | 2018-05-16 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Non-aqueous fluoropolymer composition |
JP2017523292A (en) | 2014-08-05 | 2017-08-17 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Lubricating method with alkoxylated perfluoropolyether |
JP2018505250A (en) | 2014-12-15 | 2018-02-22 | ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. | Aqueous composition comprising a fluorinated polymer |
EP3274389A1 (en) | 2015-03-26 | 2018-01-31 | Solvay Specialty Polymers Italy S.p.A. | Non-aqueous cross-linkable fluoropolymer compositions |
JP2017105945A (en) * | 2015-12-10 | 2017-06-15 | ダイキン工業株式会社 | Manufacturing method of peroxidized perfluoropolyoxyalkylene compound |
JP2017105944A (en) * | 2015-12-10 | 2017-06-15 | ダイキン工業株式会社 | Manufacturing method of peroxidized perfluoropolyoxyalkylene compound |
JP6278146B2 (en) * | 2016-07-05 | 2018-02-14 | ダイキン工業株式会社 | Process for producing fluoropolyoxyalkylene peroxide peroxide |
US10968312B2 (en) | 2016-07-20 | 2021-04-06 | Solvay Specialty Polymers Italy S.P.A. | Method for manufacturing polyalkoxylated polymers |
CN107501538A (en) * | 2017-08-01 | 2017-12-22 | 巨化集团技术中心 | A kind of PFPE and preparation method thereof |
CN111201251B (en) * | 2017-09-08 | 2022-06-17 | 索尔维特殊聚合物意大利有限公司 | Process for making fluoropolymers |
CN108440748B (en) * | 2018-04-09 | 2020-06-16 | 浙江巨化技术中心有限公司 | Synthesis method of high molecular weight perfluoropolyether peroxide with acyl fluoride groups |
CN109529906B (en) * | 2018-12-25 | 2021-06-15 | 西安近代化学研究所 | Catalyst for synthesizing 1,1,2,3,3, 3-hexafluoropropyl methyl ether and preparation method thereof |
EP3757190B1 (en) * | 2019-06-26 | 2021-10-13 | Alpraaz AB | Liquid heat transfer mixture and use thereof |
CN111620972B (en) * | 2020-04-26 | 2022-07-19 | 浙江巨化技术中心有限公司 | Perfluoropolyether and preparation method thereof |
CN114507340B (en) * | 2020-11-17 | 2023-06-23 | 中昊晨光化工研究院有限公司 | Perfluoropolyether and preparation method thereof |
CN114276532A (en) * | 2021-12-29 | 2022-04-05 | 山东东岳高分子材料有限公司 | Preparation method and device of peroxide perfluoropolyether |
CN115873162A (en) * | 2022-12-01 | 2023-03-31 | 江苏梅兰化工有限公司 | Preparation device and preparation method of oligomeric fluoroether peroxide for fluororubber |
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NL148300B (en) * | 1964-01-02 | 1976-01-15 | Edison Soc | PROCESS FOR PREPARING POLYOXYPERFLUORMETHYLENES. |
NL6709067A (en) * | 1964-04-09 | 1968-01-08 | ||
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GB1217871A (en) * | 1967-02-09 | 1970-12-31 | Montedison Spa | Fluorine-containing polyethers |
US3715378A (en) * | 1967-02-09 | 1973-02-06 | Montedison Spa | Fluorinated peroxy polyether copolymers and method for preparing them from tetrafluoroethylene |
US3847978A (en) * | 1968-07-01 | 1974-11-12 | Montedison Spa | Perfluorinated linear polyethers having reactive terminal groups at both ends of the chain and process for the preparation thereof |
US3622601A (en) * | 1969-02-17 | 1971-11-23 | Monsanto Res Corp | Fluorinated epoxide |
US4384128A (en) * | 1981-04-03 | 1983-05-17 | E. I. Du Pont De Nemours And Company | Perfluoroglycidyl ethers |
US4460514A (en) | 1981-06-17 | 1984-07-17 | The United States Of America As Represented By The Secretary Of The Air Force | Method for the preparation of poly (carbonyl fluoride) oligomers |
CA1263405A (en) | 1984-05-23 | 1989-11-28 | Giantommaso Viola | Process for preparing neutral and functional perfluoropolyethers with controlled molecular weight |
IT1213071B (en) * | 1986-05-07 | 1989-12-07 | Ausimont Spa | PERFLUOROPOLYETERS FREE OF PEROXIDE OXYGEN AND CONTAINING PERFLUOROEPOXID GROUPS ARRANGED ALONG THE PERFLUOROPOLYETHER CHAIN. |
US4743300A (en) * | 1986-08-29 | 1988-05-10 | Minnesota Mining And Manufacturing Company | Polyfluoropolyethers having pendant perfluoroalkoxy groups |
JPS63137922A (en) * | 1986-11-28 | 1988-06-09 | Nippon Mektron Ltd | Novel perfluoropolyether and production thereof |
IT1218206B (en) * | 1988-04-08 | 1990-04-12 | Ausimont Spa | USE OF PERFLUOROPOLYETER EMULSIONS FOR THE PROTECTION OF STONE MATERIALS FROM ATMOSPHERIC AGENTS |
IT1218205B (en) * | 1988-04-08 | 1990-04-12 | Ausimont Spa | USE OF FLUOROPOLYETER DERIVATIVES IN THE FORM OF AQUEOUS MICROEMULSION FOR THE PROTECTION OF STONE MATERIALS FROM ATMOSPHERIC AGENTS |
IT1217452B (en) * | 1988-05-02 | 1990-03-22 | Ausimont Spa | PERFLUOROPOLYTERS CONTAINING A HALOGEN OTHER THAN FLUOR AND HAVING AN ACID-FUNCTION TERMINAL GROUP |
IT1217453B (en) * | 1988-05-02 | 1990-03-22 | Ausimont Spa | PROCEDURE FOR THE PRODUCTION OF CONTROLLED MOLECULAR WEIGHT PERFLUOROPOLES, WITH PERFLUOROALKYL OR PERFLUOROCLOROALKYL TERMINAL GROUPS |
IT1217658B (en) * | 1988-05-20 | 1990-03-30 | Ausimont Spa | PROCESS PERFECTED FOR THE PRODUCTION OF PERFLUOROPOLYETERS CONSTITUTED SUBSTANTIALLY BY PERFLUDOSSIETILENCHE AND PERFLUOROXIPROPYLENE UNITS |
IT1229845B (en) * | 1989-04-20 | 1991-09-13 | Ausimont Srl | PROCEDURE FOR THE PREPARATION OF PEROXIDE PERFLUOROPOLYETERS. |
-
1989
- 1989-04-20 IT IT8920207A patent/IT1229845B/en active
-
1990
- 1990-04-18 IL IL94112A patent/IL94112A0/en not_active IP Right Cessation
- 1990-04-18 ZA ZA902932A patent/ZA902932B/en unknown
- 1990-04-18 IL IL94113A patent/IL94113A0/en not_active IP Right Cessation
- 1990-04-18 ZA ZA902933A patent/ZA902933B/en unknown
- 1990-04-19 IE IE139790A patent/IE68409B1/en not_active IP Right Cessation
- 1990-04-19 YU YU77790A patent/YU77790A/en unknown
- 1990-04-19 SI SI9010777A patent/SI9010777B/en unknown
- 1990-04-19 MX MX020371A patent/MX174319B/en unknown
- 1990-04-19 YU YU00778/90A patent/YU77890A/en unknown
- 1990-04-19 SI SI9010778A patent/SI9010778B/en unknown
- 1990-04-19 DD DD90339895A patent/DD298941A5/en not_active IP Right Cessation
- 1990-04-19 DD DD90339896A patent/DD298942A5/en not_active IP Right Cessation
- 1990-04-19 IE IE139690A patent/IE71222B1/en not_active IP Right Cessation
- 1990-04-19 MX MX020370A patent/MX172586B/en unknown
- 1990-04-20 UA UA5001958A patent/UA26444A/en unknown
- 1990-04-20 CA CA002045679A patent/CA2045679C/en not_active Expired - Fee Related
- 1990-04-20 NZ NZ233406A patent/NZ233406A/en unknown
- 1990-04-20 CZ CS901975A patent/CZ282933B6/en not_active IP Right Cessation
- 1990-04-20 CN CN90103919A patent/CN1031063C/en not_active Expired - Fee Related
- 1990-04-20 DK DK90107532.5T patent/DK0393700T3/en active
- 1990-04-20 DE DE69020107T patent/DE69020107T2/en not_active Expired - Fee Related
- 1990-04-20 RU SU905001958A patent/RU2075486C1/en not_active IP Right Cessation
- 1990-04-20 BR BR909007099A patent/BR9007099A/en not_active Application Discontinuation
- 1990-04-20 AU AU54446/90A patent/AU633081B2/en not_active Ceased
- 1990-04-20 RO RO148415A patent/RO110331B1/en unknown
- 1990-04-20 US US07/613,495 patent/US5258110A/en not_active Expired - Lifetime
- 1990-04-20 KR KR1019900702646A patent/KR0167551B1/en not_active IP Right Cessation
- 1990-04-20 EP EP90107532A patent/EP0393700B1/en not_active Expired - Lifetime
- 1990-04-20 CZ CS901974A patent/CZ282738B6/en not_active IP Right Cessation
- 1990-04-20 AT AT90906219T patent/ATE123787T1/en not_active IP Right Cessation
- 1990-04-20 RO RO148416A patent/RO110332B1/en unknown
- 1990-04-20 AU AU54472/90A patent/AU626665B2/en not_active Ceased
- 1990-04-20 DE DE69023948T patent/DE69023948T2/en not_active Expired - Fee Related
- 1990-04-20 JP JP2506316A patent/JP3043400B2/en not_active Expired - Fee Related
- 1990-04-20 WO PCT/EP1990/000638 patent/WO1990012832A1/en active IP Right Grant
- 1990-04-20 US US07/613,483 patent/US5149842A/en not_active Expired - Lifetime
- 1990-04-20 AR AR90316671A patent/AR246747A1/en active
- 1990-04-20 KR KR1019900702647A patent/KR0167552B1/en not_active IP Right Cessation
- 1990-04-20 PT PT93830A patent/PT93830B/en not_active IP Right Cessation
- 1990-04-20 PT PT93831A patent/PT93831B/en not_active IP Right Cessation
- 1990-04-20 HU HU903455A patent/HU209675B/en not_active IP Right Cessation
- 1990-04-20 RU SU905010049A patent/RU2070558C1/en not_active IP Right Cessation
- 1990-04-20 EP EP90906217A patent/EP0424491A1/en active Pending
- 1990-04-20 DK DK90906219.2T patent/DK0427820T3/en active
- 1990-04-20 WO PCT/EP1990/000641 patent/WO1990012833A1/en active IP Right Grant
- 1990-04-20 PL PL90284870A patent/PL163381B1/en unknown
- 1990-04-20 NZ NZ233405A patent/NZ233405A/en unknown
- 1990-04-20 JP JP2506314A patent/JP3040461B2/en not_active Expired - Fee Related
- 1990-04-20 EP EP90107539A patent/EP0393705A1/en active Pending
- 1990-04-20 CA CA002045470A patent/CA2045470C/en not_active Expired - Fee Related
- 1990-04-20 EP EP90906219A patent/EP0427820B1/en not_active Expired - Lifetime
- 1990-04-20 PL PL90284868A patent/PL163380B1/en unknown
- 1990-04-20 ES ES90906219T patent/ES2075898T3/en not_active Expired - Lifetime
- 1990-04-20 BR BR909007111A patent/BR9007111A/en not_active IP Right Cessation
- 1990-04-20 SK SK1974-90A patent/SK279078B6/en unknown
- 1990-04-20 CN CN90103935A patent/CN1031064C/en not_active Expired - Lifetime
- 1990-04-20 AT AT90107532T patent/ATE131185T1/en active
- 1990-04-20 HU HU903415A patent/HU208441B/en not_active IP Right Cessation
- 1990-04-20 ES ES90107532T patent/ES2081315T3/en not_active Expired - Lifetime
- 1990-04-22 EG EG24290A patent/EG19387A/en active
- 1990-04-22 EG EG24390A patent/EG19310A/en active
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1991
- 1991-10-16 FI FI914876A patent/FI96428C/en active
- 1991-10-16 FI FI914877A patent/FI96429C/en active
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- 1991-10-18 NO NO914115A patent/NO178379C/en not_active IP Right Cessation
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1995
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- 1995-12-21 GR GR950403645T patent/GR3018513T3/en unknown
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