CA2057355A1 - Hydrosonically embedded soft thin film materials and process for forming said materials - Google Patents
Hydrosonically embedded soft thin film materials and process for forming said materialsInfo
- Publication number
- CA2057355A1 CA2057355A1 CA 2057355 CA2057355A CA2057355A1 CA 2057355 A1 CA2057355 A1 CA 2057355A1 CA 2057355 CA2057355 CA 2057355 CA 2057355 A CA2057355 A CA 2057355A CA 2057355 A1 CA2057355 A1 CA 2057355A1
- Authority
- CA
- Canada
- Prior art keywords
- film material
- soft film
- fibers
- thin soft
- thin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000463 material Substances 0.000 title claims abstract description 192
- 238000000034 method Methods 0.000 title claims abstract description 41
- 230000008569 process Effects 0.000 title abstract description 21
- 239000010409 thin film Substances 0.000 title description 9
- 239000000835 fiber Substances 0.000 claims abstract description 76
- -1 polyethylenes Polymers 0.000 claims description 33
- 239000004698 Polyethylene Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 29
- 229920000573 polyethylene Polymers 0.000 claims description 29
- 239000012530 fluid Substances 0.000 claims description 24
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 18
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 229920000098 polyolefin Polymers 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 6
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 6
- 210000002268 wool Anatomy 0.000 claims description 6
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 5
- 239000010935 stainless steel Substances 0.000 claims description 5
- 229920000914 Metallic fiber Polymers 0.000 claims description 4
- 229920001131 Pulp (paper) Polymers 0.000 claims description 4
- 229920000297 Rayon Polymers 0.000 claims description 4
- 229910003460 diamond Inorganic materials 0.000 claims description 4
- 239000010432 diamond Substances 0.000 claims description 4
- 239000002964 rayon Substances 0.000 claims description 4
- 150000003673 urethanes Chemical class 0.000 claims description 4
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 235000010443 alginic acid Nutrition 0.000 claims description 3
- 229920000615 alginic acid Polymers 0.000 claims description 3
- 235000010418 carrageenan Nutrition 0.000 claims description 3
- 229920001525 carrageenan Polymers 0.000 claims description 3
- 229940113118 carrageenan Drugs 0.000 claims description 3
- 239000000679 carrageenan Substances 0.000 claims description 3
- 229960004592 isopropanol Drugs 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 3
- 239000010408 film Substances 0.000 description 116
- 230000007723 transport mechanism Effects 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 8
- 230000007246 mechanism Effects 0.000 description 6
- 230000009471 action Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000007779 soft material Substances 0.000 description 5
- 239000007822 coupling agent Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000012858 resilient material Substances 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009659 non-destructive testing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
- B29C35/0261—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using ultrasonic or sonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B26—HAND CUTTING TOOLS; CUTTING; SEVERING
- B26F—PERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
- B26F1/00—Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
- B26F1/26—Perforating by non-mechanical means, e.g. by fluid jet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
- B29C70/64—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler influencing the surface characteristics of the material, e.g. by concentrating near the surface or by incorporating in the surface by force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0253—Polyolefin fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/067—Wood fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/103—Metal fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2310/00—Treatment by energy or chemical effects
- B32B2310/028—Treatment by energy or chemical effects using vibration, e.g. sonic or ultrasonic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/902—High modulus filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24273—Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
- Y10T428/24322—Composite web or sheet
- Y10T428/24331—Composite web or sheet including nonapertured component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/253—Cellulosic [e.g., wood, paper, cork, rayon, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
Abstract
ABSTRACT OF THE DISCLOSURE
A thin soft film material having fibers and/or particulates embedded therein is disclosed. A process for effecting such embedding utilizing hydrosonics is also disclosed.
A thin soft film material having fibers and/or particulates embedded therein is disclosed. A process for effecting such embedding utilizing hydrosonics is also disclosed.
Description
2~73~
RELAT~:D APPLICATIONS
This application is one of a group of applications which are being filed on the same date. It should be noted that this group of applications includes U.S~ patent application serial number 07/769~050entitled "Hydrosonically Microapertured Thin Thermose~ Sheet Materials" in the names of Lee K. Jameson and Bernard Cohen; U.S. patent application serial number 07!769.047 entitled "Hydrosonically Microapertured Thin Thermoplastic Sheet Materials" in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application serial number 07t768,782 entitled "Pressure Ssnsitive Valve System and Process For Forming Said System" in the names of Lee K.
Jameson and Bernard Cohen; U.S. patent application serial number 07/768 494 entitled " Hydrosonically Embedded Soft Thin Film Materials and Process For Forming Said Materials" in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application number 07/7~8 788 ent:itled l'Hydrosonically Microapertured Thin Naturally Occurring Polymeric Sheet Materials and Method of ~aking the Same" in the names of Lee K. Jameson and Bernard Cohen; uOsO patent application serial number 07/769 048 entitled "~ydrosonically Microapertured Thin Metallic Sheet Materials'l in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application serial number 07t769 045 entitled "Process For Hydrosonically Microaperkuring Thin Sheet Materialsl' in ths names of Lee K.
Jameson and Bernard Cohen; and U.S. patent application serial .
' :,.. ,: ,. ..
: : ' ' .
, - ` - 21~73~5 number 07/767.727 entitled "Process For ~ydrosonically Area -Thinning Thin Sheet Materials" in the names of Bernard Cohen and Lee K. Jameson. All of these applications are hereby incorporated by reference.
FIELD OF THE INVENTION
The field of the present invention encompasses film materials having fibers and/or particulates embedded therein.
ACKGROUND OF THE INVENTION
Ultrasonics is basically ths science of the effects of sound vibrations beyond the limit of audible frequencies.
Ultrasonics has been used in a wide variety of applications.
For example, ultrasonics has been used for (1) dust, smoke and mist precipitation; (2) preparation of colloidal dispersions;
RELAT~:D APPLICATIONS
This application is one of a group of applications which are being filed on the same date. It should be noted that this group of applications includes U.S~ patent application serial number 07/769~050entitled "Hydrosonically Microapertured Thin Thermose~ Sheet Materials" in the names of Lee K. Jameson and Bernard Cohen; U.S. patent application serial number 07!769.047 entitled "Hydrosonically Microapertured Thin Thermoplastic Sheet Materials" in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application serial number 07t768,782 entitled "Pressure Ssnsitive Valve System and Process For Forming Said System" in the names of Lee K.
Jameson and Bernard Cohen; U.S. patent application serial number 07/768 494 entitled " Hydrosonically Embedded Soft Thin Film Materials and Process For Forming Said Materials" in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application number 07/7~8 788 ent:itled l'Hydrosonically Microapertured Thin Naturally Occurring Polymeric Sheet Materials and Method of ~aking the Same" in the names of Lee K. Jameson and Bernard Cohen; uOsO patent application serial number 07/769 048 entitled "~ydrosonically Microapertured Thin Metallic Sheet Materials'l in the names of Bernard Cohen and Lee K. Jameson; U.S. patent application serial number 07t769 045 entitled "Process For Hydrosonically Microaperkuring Thin Sheet Materialsl' in ths names of Lee K.
Jameson and Bernard Cohen; and U.S. patent application serial .
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, - ` - 21~73~5 number 07/767.727 entitled "Process For ~ydrosonically Area -Thinning Thin Sheet Materials" in the names of Bernard Cohen and Lee K. Jameson. All of these applications are hereby incorporated by reference.
FIELD OF THE INVENTION
The field of the present invention encompasses film materials having fibers and/or particulates embedded therein.
ACKGROUND OF THE INVENTION
Ultrasonics is basically ths science of the effects of sound vibrations beyond the limit of audible frequencies.
Ultrasonics has been used in a wide variety of applications.
For example, ultrasonics has been used for (1) dust, smoke and mist precipitation; (2) preparation of colloidal dispersions;
(3) cleaning of metal parts and fabrics; (4) friction welding;
(5) the formation of catalysts; (6) the degassing and solidification of molten metals; (7) the extraction of flavor oils in brewing; (8) electroplating; (9) drilling hard materials; (10~ fluxless soldering and (10~ nondestructive testing such as in diagnostic medicine.
The object of high power ultrasonic applications is to bring about some permanent physical change in the material treated. This process requires the flow of vibratory power per unit of area or volume. Depending on the application, the power density may range ~rom less than a watt to thousands - :, . - . . .
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~7~
of watts per square centimeter. Although the original ultrasonic power devices operated at radio frequencies, today most operate at 20-69 kHz.
The piezoelectric sandwich-type transducer driven by an electronic power supply ha~ emerged as the most common source of ultrasonic power. The overall efficiency of such equipment (net acoustic power per electric-line power) is typically greater than 70%. The maximum power from a conventional transducer is inversely proportional to the square of the frequency. Some applications, such as cleaning, may have many transducers working into a common load.
Other, more particular areas where ultrasonic vibratory force has been utilized are in the areas of thin nonwoven webs and thin films. For example, ultrasonic for~e has been use to bond or weld nonwoven webs. See, for example, U.S. patent numbers 3,575,752 to Carpenter, 3,660,186 to Saqer et al., 3,966,519 to Mi~chell et al. and 4,695,454 to Sayov _z et al.
which disclose the use of ultrasonics to bond or weld nonwoven webs. U.S. patent number 3,488,240 to Roberts, describes the use of ultrasonics to bond or weld thi~ films such as oriented polyesters.
Ultrasonic force has also been utilized to aperture nonwoven webs. See, for example, U.S. patent nu~bers 3,949,127 to Ostermeler et al. and 3,966,519 to Mitchell et al.~
Lastly, ultrasonic force has been used to aperture thin film material. See, for example, U. S. patent number 3,756,880 to Graczyk~
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Other methods for the aperturing of thin film have been developed. For example, U.S. patent number 4,~15,714 to Doualas discusses the aperturing of a thin film by first abrading the ~`ilm, which is in filled and unoriented form, and then subjecting t~e film to corona discharge traatment.
One of the difficulties and obsiacles in the use of ultrasonic force in the formation of apertures in materials i5 the fact that control of the amount of force which is applied was difficult. This lack of control generally resulted in the limitation of ultrasonic force to form large apertures as opposed to small microapertures. Such an application is discussed in U.K. patent application number 2,124,134 to Blair. One of the possible reasons that ultrasonics has not found satisfactory acceptance in the area of microaperture 40rmation is ~hat the amount of vibrational energy required to form an aperture ofken resulted in a melt-through of the film.
As has previously been stated, those in the art had recognized that ultrasonics could be utilized to form apertures in nonwoven webs. See, U.S. patent to itche~l~ et al.. Additionally, the Mitchell et al~ patent discloses that the amount of ultrasonic energy being subjected to a nonwoven web could be controlled by applying enough of a fluid to the area at which the ultrasonic energy was being applied to the nonwoven web so that the fluid was present in uncombin~d form.
Importantly, the Mitchell, et al. patent states that the fluid is moved by the action of the ultrasonic force within the nonwoven web to cause aperture formation in the web by fiber : . ~, ~73~
rearrangemen~ and entanglement. The Mitchell et al. patent also states that, in its broadest aspects, since these effects are obtained primarily throu~h physical movement o~ fibers, the method of their invention may be utilized to bond or increase the strength of a wide variety of fibrous webs.
While the discovery disclosed in the Mitchell et al.
patent, no doubt, was an important contribution to the art, it clearly did not addr~ss the possibility of embedding solid materials such as fibers and particulates into thin soft film materials. This fact is clear because the Mitchell et al.
patent clearly states the belief that the mechanism o~
aperture formation depended upon fiber rearrangement within a web material. Of course, thin soPt film materials do not have fibers and thus there are no intra-web fibers to be lS rearranged. Accordingly, it can be stated with conviction that the applicability of a method for embedding solid materials such as fibers and particulates into a thin soft film material by the application of ultrasonic enerqy in conjunction with a fluid at ~he poin~ of application of the ultrasonic energy to the thin nonfibrous elastomeric sheet material was not contemplated by the Mitchell et al. patent. Moreover, the relevance of the Mitchell et al. patent to such an application is ques~ionable because the patent is directed toward aperture formation as opposed to e~bedding materials into a thin soft film material.
As is discussed in the related applications, disclosed above, the applicants of the present invention have been conducting a considerable amount of research in the area of ; . , .
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application o~ ultrasonics. As a result of thesP
investigations, some surprising discoveries have been made.
DEFINITIONS
As use.d herein the term "soft material", refers to any material that is capable of having fibers or particulates embedded therein by hydrosonic processing. Examples o~ soft materials include, without limitation, certain thermoplastic film materials and certain materials derived from natural materials. Some experimentation is necessary because if the material is too hard fibers and/or particulates cannot ~e embedded therein. Conversely, if the material is too elastic fibers and particulates cannot be embedded because, it is believed, they bounce of~ of the material during hydrosonic processing~
As used herein the te~m "soft film material" refers to a generally nonporou~ film formed from a material that ran be arranged in generally planar configuration which. This term is also intended to include multilayer materials which include, as a surface layer thereof, at least one such soPt film material as a layer thereof.
As used herein the term "thin soft film material" refers to a soft film material having an average thicknesæ yenerally of less than about ten (10) mils. Average thickness is determined by randomly selecting five (5) locations on a given film material, measuring the thickness of the film material ': ~' ' ',. "~ , , ;
~ , 3 ~ ~
at each location to the nearest 0.1 mil, and averaging the five values ~sum of the five values divided by five).
As used herein the term "mesh count" refers to the num~er which is the product of the number o~ wires in a wire mesh screen in both the machine (MD) and cross-machine (CD) directions in a given unit axea. For exampl~, a wir~ mesh screen having 100 wires per inch in the machine direction and 100 wires par inch in the cross machine direction would have a mesh count of 10,000 per square inch. As a result of the interweaving of these wires, raised areas are present on both sides of the mesh screen. The number of raised areas on one side of such a wire mesh screen is generally one-half of the mesh count.
As used herein the term "aperture" refers to a generally linear hole or passageway. Aperture is to be distinguished from and does not include holes or passageways having the greatly tortuous path or passageways found in membranes.
As used herein the term "microaperture'~ refers to an aperture which has an area of less than about 100,000 square micrometers. The area of the microaperture is to be measured at the narrow~st point in the linear passageway or hole.
As used herein the ~erm "ultrasonic vibrations" refers to vibrations having a frequency of at least about 20,000 cycles per second. The frequency of th~ ultrasonic vibrations may range from about 20,000 to about 400,000 cycles per second.
As used herein the term "hydrosonics" re~ers to th2 application of ultrasonic vibrations to a material where the , ' '' ~, . ' 2~3~
area of such application is has had a liquid applied thereto to the extent that the liquid is present in sufficient quantity to generally fill the gap between the tip of the ultrasonic horn and the surface of the material.
O~JECTS QF THE INVENTION
Accordingly, it is a general object of the present invention to provide a thin so~t film material which has fibers and/or particulates embedded therein.
It is another general object of the present invention to provide a process for embedding fibers and~or particulates in thin soft film materials.
Still further objects and the broad scope of applicability of the present invention will become apparent to those o~
skill in the art from the details given hereinafter. However, it should be understood that the detai.led description of the presently preferred embodiments of the present invention is given only by way of illustration because various changes and modi~ications well within the spirit and scope of the invention w}ll become apparent to those o~ skill in the art in view of this detailed description.
SUMM~RY OF THE I~VENTION
As is revealed in detail in the referenced related applications, we have discovered that thin sheet materials may be microapertured if they are subjected to hydrosonic g ": ., , , : ~: ~ , . , ::
2~73~5 treat~ent against an anvil where the anvil is a pattern anvil having a pattern of raised arPas that have a hei~ht which is greater than the thickness of the thin sheet material to be apertured. While conducting the experiments discuss~d in detail in the referenced related applications, some experiments were conducted to detarmine whethar the presence of solids in the fluid would affect the microaperturing process. ~uch to our surprise, not only was the microaperturing process generally not affected, but we discovered that the hydrosonic force actually embedded the fihers and particulates which we had added to the coupling fluid to act as impurities into the sheet material wAile the sheet material was still apertured.
In additional experiments it was determined that, if the pattern anvil was removed and an anvil having a planar surface was substituted for the pattern anvil, the thin sheet material would no longer be microapertured but would still have the fib~rs and/or particulates embedded therein.
Accordingly, we have developed a thin soft film material having fibers and~or particulates embedded therein. The fibers to be embedded may be of any type which is able to withstand hydrosonic treatment. For example, the fibers to be embedded may be selected from the group including metallic fibers such as are found in steel wool: naturally occurring fibers ~uch as, for example, wood pulp fibers, cotton fibers and wool fibers; and synthetic fibers such as polyolefin fibers, rayon fibers and nylon fibers. The particulates to be embedded may be o~ any type which is able to withstand hydrosonic , ;, ' ` ,:: ,:~
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, 2~1~73~5 treatment. For example, the particuLat~s may be selected from the group including calcium carbonate, silicon carbide, diamond or activated charcoal. In some embodiments both fibers and particulates may be embedded into tha thin soft film material.
In some embodiments the thin soft film material may be formed from the group of materials selected from the group including soft polypxcpylenes, soft polyethylenes, so~t urethanes, soft alginates or carrageenanO
As was stated above, in some embodiments the thin soft film which is embedded with fibers and/or particulates may alæo be microapertured so that it defines at least about 1,000 microapertures p~r square inch. For example, the thin soft film material which is embedded with fibers and/or parti¢ulates may also be microapertured so that it defines at least about 5,000 microapertures per square inoh. More particularly, the thin soft film material which is embedded with fibers and/or particulates may al~so be microapertured so that it defines at least about 20,000 microapertures per s~uare inch. Even more particularly, the thin soft film material which is embedded with fibers and/or particulates may also be microapertured so that it defines at least about 90,000 microapertures per square inch. Yet even mor~
particularly, the thin soft film material which is embedded with fibers and/or particulates may also b~ microapertured so that it defines at least about 160,000 microapertures per square inch.
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In accordance with the definition o~ l'thin" sof~ film material, the average thickness oP the thin soft film material is les6 than about ten mils. Additionally, the average thickness of the thin soft film material is at least about 0.25 mil. For example, the avera~e thickne~s of the thin soft ~ilm material may range from at least about 0.25 mil to about 5 mil~. More particularly, the average thickness o~ the film material may range from at least about 0.25 mil to about 2 mils. Even more particularly, the average thickness of the film material may range from at least about 0.5 mil to about 1 mil.
The invention also is directed to a method for embedding fibers and/or particulates, or both, in a thin soft film material. The proces~ includes the steps of (a) placing the thin soft ~ilm material on an anvil means; (b~ conveying the thin so~t film matexial, while placed on the anvil means, through an area where a mixture of a fluid and fibers and/or particulate~, or both, is applied to the thin soft film ma~erial; and (c~ subjecting the thin soft film material to a sufficient amount of ultrasonic vibrations in the area where the fluid and fibers andtor particulates, or both, are applied to the thin soft film material to embed the fibers, particula~es or both into the thin soft film material.
The ~luid may be selected from the group including one or more of water, mineral oil, a chlorinated hydrocarbon, ethylene glycol or a solution o~ S0 volume percent water and 50 volume percent 2 propanol. For example, the chlorinated - 2~7~
hydrocarbon may be selected form the group including 1,1,1 trichloroethane or carbon tetrachloride.
In some embodiments it may be desirable for the embedding to be confined to a predesignated area or areas of the soft thin film. This result may be obtained where only a portion of the soft thin film is subjected to ultrasonic vibrations.
Where it is desired only to embed the fibers, paxticulates or both into the thin soft film material, the anvil means may be selected from the group including a smooth, nonpatterned, lo stainless steel shim material or a smooth, non pattsrned roller coated with a resilient material.
Where it is desired to both embed fibers, particulates, or both, into the thin soft film material and to microaperture the thin soft film material, the anvil means should be a pattern an~il me~hanism having a pattern of raised areas.
Figure I is a schematic representat:ion of apparatus which utilizes ultrasonic vibrations to embed fibers and/or particulates in thin soft film materials.
Figure II is a cross sectional view of the transport mechanism for transporting the thin soft film material to the area where it is subjected to ultrasonic vihrations~
Figure III is a detailed view of the area where the thin soft film material is subjected to ultrasonic vibrations. The area i5 designated by the dotted circle in Figure I.
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Figure IV is a photomicrograph of a 0.5 mil thick thin soft ~ilm of polyethylene which has had southern softwood fibers embedded therein in accordance with the present invention. The photomicxograph is accompanied by a scale where each unit represen~s ten microns (micrometers).
Figure V is a photomicrograph of a 0.5 mil thick thin soft f ilm of polyethylene which has been microapertured and has had southern so~twood fibers embedded therein in accordance with the present invention. The photomicrograph is accompanied by a scale where each unit represents ten microns (~icrometers).
Figur~ VI is a photomicrograph of a 0.5 mil thick thin soft film of polye~hylene which has been microapertured and has had calcium carbonate particulates embedded therein in accordance with ~he present invention. The photomicrograph is accompanied by a scale where each unit represents ten microns (micrometers~. -Figure VII is a photomicrograph O:e a 0.5 mil thick thin soft film of polyethylene which has b~een microapertured and has had silicon carbide particulates embedded therein in accordance with the present invention. The photomiarograph is accompanied by a scale where each unit represents ten microns (micrometers).
DETAILED DE5CRIPTION OF THE_INVENTION
Turning now to the Figures where like re~erence numerals represent like structure and, in particular to Figura I which ' ' '.' , ~, , . .
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2~7~
is a schematic representation of an apparatus which can carry out the method of the present invention, it can be seen that the apparatus is generally represented by the reference numeral 10. In operation, a supply roll 12 of a thin soft film material 14 into which fibers, particulates, or both are to be embedded is ~upplied. As has been previously stated, the term ~hin sof~ film material refers to film materials which have an average thickness of about ten (10) mils or less.
Additionally, generally speaking the average thickness of the thin soft film material 1~ will be at least about 0.25 mil.
For example, the average thickness of the thin soft film 14 material may range fxom about O.Z5 mil to about 5 mils. More particularly, the average thickn~ss of the thin soft film material 14 may range from about 0.25 mil to about 2 mils.
Even more specifically, the average thickness of the thin soft film material 14 may range from about 0.5 mil to about 1 mil.
The thin soft film material 14 may be formed ~rom any suitable material meeting the definit:ion of soft contained herein. For example, the thin soft film material may be formed from soft materials such as soft polyolefins such as, for example, soft polypropylenes or soft polyethylenes; soft urethanes or soft alginlates such as carrageenan.
The thin soft film material 14 is transported to a first nip 16 formed by a first transport roll 18 and a first nip roller 20 by the action of an endless transport mechanism 22 which moves in the direction indicated by the arrow 24. The transport mechanism 22 is driven by the rotation of the ~irst transport roller 18 in conjunction with a second transport : :
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2~573~
roller 26 which, in turn, are drivPn by a con~entional power source, not shown.
Figure II is 2 cross sectional view of the tran~port mechanism 22 taken along lines A-A in Figure I. Figure II
disclose~ that the transport mechanism 22 includes a heavy duty transport wire mesh screen 28 usually having a mesh count of less than a~out 400 (i.e. less than a 20 wires per inch MD
by 20 wire per inch CD mesh screen if machine direction (MD) and cross machine direction (CD) wire count is the same).
Heavy duty mesh wire screens of this type may be made from a variety of materials such as, for example, plastic~, nylons or polyeæters, and are readily available to those in the art.
Located above and attached to the transport screen 28 is an endless flat shim plate 30. The shim plate 30 d~sirably is formed from stainless steel. However, those of skill in the art will readily recognize that other materials may be utilized.
From the first nip 16 the thin soft film material 14 is transported by the transport mechanism 22 over a tension roll 36 to an area 38 (defined in Figure I by the dotted lined circle) where the thin soft film material 14 is subjected to ultrasonic vibrations.
The assembly for subjecting the thin soft film material 14 to the ultrasonic vibrations is conventional and is generally designated at 40. The assembly 40 includes a power supply 42 which, through a power control 44, supplies power to a piezoelectric transducer 46. As is well known in the art, the piezoelectric transducer 46 transforms electrical energy ;. . :: :
., " .. ..
20~73~
into mechanical movement as a result of the transducer's vibrating in response to an input of electrical energy. The vibrations crea~ed by the piezoel~ctric transducer 46 are transferred, in conventional manner, to a mechanical movement booster or ~mplifier 48. As is well known in the art, the mechanical movement booster 48 may be designed to increase the amplitude of the vibrations (mechanical movement) by a known factor depending upon the configuration of the booster 48c In further conventional manner, the mechanical movement (vibrational energy~ is transferred from the mechanical movement booster 48 to a conventional knife edge ultrasonic horn 50. It should be realized that other types of ultrasonic horns S0 could be utilized. For example, a rotary type ultrasonic horn could be used. The ultrasonic horn 50 may be designed to ef~ect yet another boost or increase in the amplitude of the mechanical movement (vibrations) which is to be applied to the thin soft film material 14. Lastly, the assembly includes an actuator 52 which includes a pneumatic cylinder, not shown. The actuator 52 provides a mechanism for raising and lowering the assembly 40 so that the tip 54 of the ul~rasonic horn 50 can apply tension to the transpor~
mechanism 22 upon the assembly 40 being lowered. It has been found that it i5 necessary to have som~ degree of tension applied to the tran~port mechanism 22 upon the lowering of the assembly for proper application of vibrational energy to the thin soft film material 14 to embed solid materials such as fibers, particulates, or both into the thin soft film material 14. one desirable aspect of this tensioned arrangement is that ;
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the need to desig~ a finely tolerancefl gap between th~ tip 54 o~ the horn 50 and the shim plate 30.
Figure III i~ a schematic representatisn of the area 38 where the ultra~onic vihrations are applied to the thin soft film material 14. As can be seen in Figura III, the transport mechanism 22 forms an angle 56 with the tip 54 of the ultrasonic horn 50. While some embedding will occur if the angle 56 is a~ great as 45 degrees, it has been found that it is desirable for the angle 56 to range from about 5 degrees to about 15 degrees. For example, the angle 56 may range from about 7 to about 13 degrees. More particularly, the anglr 56 may range ~rom abou~ g to about 11 degrees.
Figure III also illustrates that the transport mechanism 22 is supported from below by the first tension roll 36 and a second tension roll 58. Positioned somewhat prior to th~ tip 54 of the ultrasonic horn 50 is a spray nozzle 60 which is configured to apply a mixture of a fluid and the fibers, particulates, etc. 62 which are to be embedded into the surface of the thin soft film material 14 just prior to the sheet material 14 being subjected to ultraconic ~ibrations by the tip 54 of the ultrasonic horn 50. The fluid portion of the mixture 62 desirably may be selected from the group including one or more of water, mineral oil, a chlorinated hydrocarbon, ethylene glycol or a solution of 5Q volume percent water and 50 volume percent 2 propanol. For example, in some embodiments the chlorinated hydrocarbon may be selected from the group including 1,1,1 trichloroethane or carbon tetrachloride. The fibers and/or particulate6 or both which may be utilized in ' 2~73~
the ~ixture 62 may be any type of fibers having sufficient rigidity to allow there being embedded into the thin soft film material 14. For example, the fibers may be selected ~rom the group including metallic fibers such as are found in steel wool; naturally occurring fibers such as, for example, wood pulp fibers, cotton fibers and wool fibers; and synthetic fibers such as polyolefin fibers, rayon fibers and nylon fibers. The particulates ~o be embedded may be of any type which is able to withstand hydrosonic treatment. For example, the particula~es may be selected from the group including calcium carbonate, silicon carbide, diamond or activated charcoal.
It should be noted that the wedge-shaped area 64 formed by the tip 54 of the ultrasonic horn 50 and the transport mechanism 22 should be subjected to a sufficient amount of the mixture 62 for the fluid to act as both a heat sink and a coupling agent for the most desirable results.
Positioned below the transport mechanism 22 in the area where the tip 54 of the ultrasonic horn 50 is located is a mixt~re collection tank 66. (See F:Lgure I.3 The mixture collection tank 66 serves to collect mixture 62 which has heen applied to the surface of the thin soft film material 14 and which has been driven through the transport mechanism 22 or over the edges of the transport mechanism 22 by the action of the vibrations of the tip 54 of the ultrasonic horn 50.
Mixture 62 which is collected in the collection tank 66 is transported by tubing 68 to a mixture holding tank 70.
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Figure I illustrates that the mixture holding tank 70 con~ains a pump 72 which, by way of additional tubing 74, supplies ~he mi~ture 62 to the mixture spray nozzle 60.
Accordingly, the mixture 62 may be re-cycled for a con-siderable period of time.
While the mechanism of action may not be fully understood and the present application should not be bound to any particular theory or mechanism of action, it is believed that the presence of the fluid portion of the mixture 62 in the wedge-shaped area 64 durinq operation of the ultrasonic hcrn 50 accomplishes two separate and distinct functions. First~
the presence o~ the fluid portion allows the fluid to act as a heat sink which allows the ultrasonic vibrations to be applied to the thin soft film material 14 without the thin soft film material 14 being alterecl or destroyed as by melting. Secondly, the presence of the fluid portion of the mixture 62 in the wedge-shaped area 64 allows the fluid to act as a coupling agent in the application of the vibrations from the ultrasonic horn 50 to the thin soft film material 14.
It has heen discovered that the action of the ultrasonic horn 50 on the fibers, particulates, or both, in the mixture 62 embeds them in the soft film material 14.
If it is desired to provide a soft thin film material 14 which is both embedded with fibers, particulates, both, etc., this may b~ accomplished in accordance with the teachings of our other above-referenced applications. To accomplish this, it is necessary to locate above and attach to the shim plate 30 a fine mesh wire pattern screen 32 usually having a mesh count of at lea t about 2,000 (i.e. at least about 45 wires per inch MD by 45 wires per inch CD mesh screen if MD and CD
wire count is ths same3. Fine mesh wire screens of this type are readily available to those in the art. The fine mesh wire screen 32 has raised areas or knuckles 34 which preform the function of a pattern anvil as will be discussed later.
As the thin soft film material 14 is subjected to the hydrosonic forces, the microapertures are punched through the thin soft film material 14 in the pattern of the raised areas or knuckles 34 of the fine mesh wire pattern screen 32.
Generally, the number of microapertures produced will be equal to the number of raised areas or knuckles 34 on the upper surface o~ the fine mesh wire screen 32. That is, the number of microapertures will generally be one-half the mesh count o~ a given area of pattern screen 32. For example, if the pattern screen 32 is 100 wires p~r inch MD by 100 wires per inch CD, the total number of knuckles or raised areas 34 on one side of the pattern wire, per square inch, 32 will be lU0 times 100 divided by 2. This equals 5,000 microap~rtures per square inch. For a 200 wires per inch by 200 wires per inch m~sh pattern screen 32 the calculation yields 20,000 microapertures per square inch. Depending somewhat on the thickness of the thin soft film material 14, at a mesh count of about 90,0oO (300 wires per inch MD by 300 wires per inch CD) the wires are so thin as to allow the knuckles 34 on both sides to microaperture the thin soft film material 14 if sufficient force is applied. Thus, a 300 wires per inch MD by 300 wires per inch CD mesh screen yields 90,000 microapertures .
' ~7~5 per square inch; for a ~00 wires per inch MD by 400 wires per inch CD mesh--160,000 microapertures per square inch. o~
course the MD and CD wire count of the wire mesh screen does not have to be the same.
It should al~o be noted that the number of microapertures formed may also vary with the number of ultrasonic vibrations to which the thin soft film material 14 is subjected per unit area for a given period of time. This factor may be varied in a number of ways. For example, the number and size of the microapertures will vary somewhat with the line speed of the thin soft film material 14 as it passes underneath the tip 54 of the ultrasonic horn 50. Generally speaking, as line speed increases, first the size of the microapertures decreases and then the number of microapert~lres decreases. As the number of microapertures decreases the less the pattern of microapertures resembles the pattern o~ raised areas 34 on the pattern screen 32. The range of linle speeds that usually yields microapertures varies with the soft material utilized to form the thin soft film material 1~ and the material used as the fluid in the mixture 62. For polyethylene having a thickness of about 0.5 mil, typical line speeds which usually yield microapertures for a variety of fluids range from about 7 to about 25 feet per minute. For example, if water is the fluid in the mixture and the film material is a polyethylene, typical line speeds which usually yield microapertures range from about 7 to about 23 Peet per minute. It is believed that, to some extent, ~he variations in the number of microapertures formed and the size of the microapertures occurs due to the . :,:, : :
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minute variations in the height o* the raised areas or knuckles 34 of the fine mesh pattern screen 32. It should be noted that the fine mesh pattern screens used to date have been obtained ~rom conventional everyday sources such as a hardware store. It is also helieved that if a pattern screen 32 could be created where all oP the raised areas 34 of the screen 32 were of exactly the same height these variatio~s would only occur in unifor~ fashion with variations of line speed.
As was stated above, the area or size of each of the microapertures formed will also vary with the parameters discussed above. The area of the microapertures will also vary with the area of the raised areas of the pattern anvil such as tns knuckles 34 on the fine mesh wire screen 32. It is believad that the type of soft material used in forming the thin so~t film material 14 will also vary the area of the microapertures formed if all other parameters are maintained the same. For example, the softer the thin soft film material 14, the easier it is to push the thin soft film material 14 through the raised areas of the *ine mesh pattern screen 32.
Because the raised areas (knuckles) on the fine mesh screen are generally pyramidal in shape, the deeper the raised area penetrates the thin soft film material 14, the larger the microaperture. Of course, the height of the raised areas must be greater than the thickness of the thin sheet material 14 for microapertures to be formed and the degree o~ excess necessary may vary with the type of soft film material 14 to be microapertured. Generally speaking, the more stretchable .
the material, the greater the height of the raised a~eas 34 must excPed the thickness of the thin so~t ~ilm material 14.
In some embodiments it may be necessary to subject the thin soft film ma~erial 14 to multiple passes through the apparatus 10 in order to microaperture the thin sheet material 14. In such situations the thin sheet material 14 will initially only be thinned in the pattern of the pattern anvil's raised areas9 However, two or more passes through the apparatus 10, with the thin soft film material 14 being aligned in the same configuration with respect to the pattern anvil, yields microapertures. Essentially what is happening in these situations is that the thin sot film material 14 is --repeatedly thinned by repeated application of ultrasonic vibrational force until such time as microapertures are formed. Al~ernatively, the fine mesh wire diameter size may be increased with the consequent decrease in mesh count.
Increasing the wire diameter size of the fine mesh screen 32 increases the llkelihood that microapertures will be formed.
0~ course, if it is desired to provide a thin soft film material 14 which has fibers, particulates, or both embedded therein and also having thinned areas or microareas, the amount o~ ultrasonic energy may need to be adjusted downwardly so that thinning and not microaperturing occurs. For more details on ~he details of th~ thinned area process, reference should be made to our referenced U.S. patent application serial number ~ entitled "Process For Hydrosonically Area Thinning Thin Sheet Materials" which has been incorporated herein by reference in its entirety.
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Another feature of the present invention is the fact that the microapertures or thinned areas or microareas can be formed in a predesignated area or areas of th~ thin soft film material 14. This can be accomplished in a number of ways. For example, the thin soft film material 14 may be subjected to ultrasonic vibrations only at certain areas of the thin soft film material 14. Alternatively, the entire thin soft ~ilm material 14 could be subjected to ultrasonic vibrations with the pattern anvil having raised areas 34 only at certain locations and otherwise being flat. Accordingly, the thin soft film material 14 would be microapertured only in those areas which corresponded ~o areas on the pattern anvil having raised areas.
It should also be noted that some limitation exists in the number of microapertures which can be formed in a given thin soft film material 14 on a single application of vibrational energy, i.e. a single pass through thP apparatus 10 if a wire mesh screen is used as the pattern anvil. This follows from the fact that, as was s~at~d above~ the height of the raised areas 34 must exceed the thickness of the thin soft film material 14 in conjunction with the fact that, generally as the mesh count increases the height of the raised areas or knuckles decreases. In such situations, if the number o~
microapertures dasired per unit area is greater than the number which can be formed in one pass through the apparatus, multiple passes are necessary with the alignment of the thin soft film material 14 with respect to the raised ares ~eing altered or shifted slightly on each pass.
' 2~73~
Generally speaking the area of ea~h of the microapertures is greater than about ten square micrometers. That is the area of each o~ the microapertures of each of the may ranye from at least about 10 square micrometers to ahout lO0,000 square microme~ers~ For example, the area o~ each o~ the microapertures may generally range from at least about 10 square micrometers to about 10,000 square micrometers. More particularly, the area of each of the micrsapertures may generally range from at least about 10 square micrometers to about l,000 square micrometers. Even more particularly, the area of each of the microapertures may generally range from at least about 10 square micrometers to about 100 square micrometers.
A number of important observations about the process may now be made. For example, it should be understood that the presence o~ the fluid portion of the mixture 62 is highly important to the pxesent inventive process which uses the fluid as a coupling agent~ Because a coupling agent is present, the fibers, particulates or both are embedded into the thin soft film material 14. Additionally, the presence of the shim plate 30 or its squivalent is necessary in order to provide an anvil mechani~m against which the thin soft film material 14 may be worked, that is apertured, by the action of the tip 54 of the ultrasonic horn 50. Because the vibrating tip 54 of the ultra~onic horn 50 is acting in a hammer and anvil manner when operated in conjunction with the heavy duty wire mesh screen 28/shim plate 30/fine wire mesh 32 combination, it should be readily recognized that a certain . ' ~,,~, 2~73~
degree of ~ension must be placed upon the transport mechanism 22 by the downward displacement of the ultrasonic horn 50. If there is little or no tension placed upon the transport mechanism 22, the shim plate 30 cannot preform its function as an anvil and microaperturing generally does not occur.
Because both the shim plate 30 and the fine mesh pattern wire 32 form the resistance that the ultrasonic horn 50 works against, they are collectively referred herein as a pattern anvil combina~ion. It should be easily recognized by those in the ar~ that the function of the pattern anvil can be accomplished by other arrangements than the heavy duty wire mesh screen 28/shim plate 30/fine mesh screen 32 combination.
For ~xample, the pattern anvil could be a flat plate with raised portions acting to direct the microaperturing force of the ultrasonic horn 50. Alternatively, the pattern anvil could be a cylindrical roller having raised areas. If the pattern anvil is a cylindrical roller, it is de~sirable for the pattern anvil to be wrapped or coated with or made from a resilient material. Where the pattern anvil is a mesh screen the resiliency is provided by the fact that the screen is unsupported directly below the point of application of ultrasonic vibrations to the mesh screen.
Th~ invention will now be discussed with regard to specific examples which will aid those of skill in the art in a full and complete understanding thereof.
EXAMPLE I
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A sheet of 0.5 mil thick polyethylene film having the trade designation S/~ 702 obtained from the Edison Company of Plainfield, New Jersey, and was cut into a length of about 11 inches and a width of about 8.5 inche~. The sample was subjected to hydrosonic treatment in accordance with the presenk invention.
A model 1120 power supply obtained from the Branson Company of Danbury, Connecticut, was utilized. This power supply, which ha th~ capacity to deliver 1,300 watts of electrical energy, was used to convert 115 volt, 60 cycle electrical energy to 20 kilohertz alternating current. A
Branson type J4 power level control, which has the ability to regulate the ultimate output of the model 1120 power supply from 0 to 100%, wa~ connected to the model 1120 power supply.
In this example, the power level control was set at 100%. The actual amount o~ power con~umed was indicated by a Branson modal A410A wattmeter. This amount waC; about 1 r 100 watts.
The output of the power supply was fed to a model 402 piezoelectric ultrasonic transducer obtained from the Branson Company. The transducer conYerts the electrical energy to mechanical movement. At 100% power the amount of mechanical movement o~ the ~ransducer is about 0.8 micrometers.
The piezoelectric transducer wa~ connected to a mechanical movement booster sectiGn obt~ined from the Branson Company.
The booster is a solid titanium metal shaft with a length equal to one-half wave length of the 20 kilohertz resonant ~requency. Boosters can be machined so that the amount of mechanical movement at their output end is increased or ,, ~
2~73~
decreased as compared to the amount of movemenk of the transducer. In this example the booster increased the amount of movement and has a gain ratio of about 1:2.5. That is, the amount of mechanical movement at the output end of the booster is about 2~5 times the amount of movement of the transducer.
The output end of the booster was connected to an ultrasonic horn obtained from the Branson Company. The horn in this example is made of titanium with a working face of about 9 inches by about 1/2 inch. The leading and trailing edges of the working face of the horn are each curved on a radius of about 1/8 inch. The horn step area is exponential in shape and yields about a two~fold increase in the mechanical movement of the booster. That is, the horn step area has about a 1:2 gain ratio. The combined increase, by the booster and the horn step arsa, in the original mechanical movement created by the transducer yields a mechanical movement of abou~ 4.0 micrometers.
The forming table arrangement included a small forming table which was utilized to transport and support the polyethylene film which is to have fiber embedded in it. The forming table included two 2-inch diameter idler rollers which were spaced about 12 inches apart on the surface of the forming table. A transport mesh belt e~circles the two idler rollers so that a continuous conveying or transport surface is created. The transport mesh belt is a square weave 20 x 20 mesh web of 0.020 inch diameter plastic filaments. The belt is about 10 inches wide and is raised above the surface of the forming table.
, ~73~5 The transducer/booster/horn assembly, hereinafter the assembly, is secured in a Branson series 400 actuator. When pswer is switched on to the transducer, the actuator, by means of a pneumatic cylinder with a piston area of about 4.4 square inches, lowers the assembly so that the output end of the horn contacts the sheet of polyethylene film which is to have fibers embedded therein. The actuator also raises the assembly so that the output end of the hoxn is removed from contact with the sheet of polyethylene film when power is switched off.
The assembly is positioned so that the output end of the horn is adapted so that it may be lowered to contact the transport mesh belt between the two idler rollers. An 8-inch wide 0.005-inch thick stainless steel shim stock having a length of about 60 inches was placed on the plastic mesh transport belt ~o provide an anvil mechanism. The sheet of polyethylene film which was to have fibers embedded therein was then fastened onto the metal shim using masking tape.
The forming table arrangement also included a mixture circulating sys~em. The circulating system includes a mixture reservoir tan~, a mixture circulating pump which may conveniently be located within the tank, associated tubing for transporting the mixture from the tank to a slotted boom which is designed to direct a curtain of mixtur2 into the juncture of the output end of the horn and sheet of polyethylene film which is to have fibers embedded ther~in. In operation, the assembly was positioned so that the output end of the horn was at an angle of from about 10 to 15 degrees to the sheet of , `'~','"' ' `
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polyethylene film. Accordingly, a wedye shaped chamber was fo~med between the output end of the ho.n and the sheet of polyethylene film. It is into this wedge shaped chamber that the mixture, in this axample a slurry of water and southern softwood obtained from the Kimberly-Clark Corporation Company under the trade designation CR54 was directed by the slotted boom. The slurry was prepared by placing the pulp into a British Disintegrator for about 3,000 revolutions~ The slurry was maintained a~ room temperature.
It should be noted that the actuator was positioned at a height to insure that, when the assembly is lowered, the downward movement of the output end of the horn is stoppPd by the tension of the transport mesh before the actuator reaches the limit of its stroke. In this example, actuating pressure was adjusted to 12 pounds per squaxe inch as re~d on a pressure gauge which is attached to the pneumatic cylinder of the actuator. This adjustment results in a total downward force of 52.8 pounds. (12 psi times 4.4 square inches of piston area equals 52.8 pounds of force.) The sequence of operation was (l) the mixture pump was switched on and the area wh re th output end of the horn was to contact the polyethylene film was flooded with the mixture;
(2) the transport mesh conveyor system was switched on and the polyethylene film started moving at 5 feet per minute; and (3) power to the assembly was supplied and the assembly was lowered so that the output end of the horn contacted the polyethylene film while the film continued to pass under the output end of the horn until the end of the sample was -3l-,, , ,, :
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reached. The reading on the A410A wattmeter during the process is an indication of the energy required to maintain maximum mechanical movement at the output end of the horn while working against the combined mass of the mixture, the polyethylene ~ilm, the shim stQck, and the transport wire.
This example yielded a polyethylene film having fibers embedded therein.
Figure IV is a photomicrograph of the polyethylene film processed by Example I having fibers embedded therein.
EXAMPLE II
The process of Example I was repeated with the exception that a 250 mesh wire was placed on top of the shim. The power utilized was about 1,200 watts. The results of this experiment were generally the same as those of Example I with the exception that the polyethylene ~ilm was both embedded with fibers and microapertured.
Figure V is a photomicrograph of the polyethylene film of Example II having fibers embedded therein.
EXAMPLE III
The process of Example II was repeated with the exception that the mixture was a mixture of water and calcium carbonate.
About 127.6 rams of calcium carbonate was mixed with about 23 kilograms of water. The calcium carhonate was obtained from the Aldrich Chemical Company of Milwaukee, Wisconsin and was a crystalline material o~ cubic shape and approximately 8 : : .
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microns in size. The watts utilized was read as about 800. The line speed of the polyethylene film was 7 feet per minute and the ac~ua~ing pressure was about 8 pounds per square inch. The results of ~his experiment were generally the same as those of Example II. The size of the microapertures was about 5 micrometers by 10 micrometers.
Figure VI is a photomicrograph of the polyethylene film of Example III having particulates e~bedded therein.
EXAMPLE IV
The process of Example III was repeated except that about 26~.1 grams of calcium carbonate was used.
The results of this experiment were generally ~he same as those of Example III.
EXAMPLE V
The process of Example III was repeated except that about 125.5 grams of 280 mesh, irregular shape silicon carbide obtained ~rom the supreme Felt & Abrasive co~ o~ Melrose, Illinois was substituted for the calcium carbonate. The silicon carbide had an apprsximate size of eight microns.
The results of this experiment were generally the same as those of Example III.
Figure VII is a photomicrograph of the polyethylene film of Example VII having silicon carbide embedded therein.
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EXAMPLE ~I
The process of Example V was repeated with the exception that about 151.1 grams of silicon carbide was used~ The results of this experiment were generally the same as those of Example V.
Figure VII is a photomicrograph of polyethylene film of having silicon carbide particulates embedded therein in accordance wi~h Example V.
The uses to which the thin soft film material having fibers, particulates or other solids embedded may be put are numerous. For example, the material may be utilized as abrasive clo~hs such as sandpaper. Alternatively, the material could provide a cotton-like film sheet for use as an outer cover for a diaper. The process of manufacturing many plastic materials could b~ modified by the teachings of the present invention so that their coefficient of friction was increased and they are less slippery.
It is to be understood that variations and modifications of the present invention may be made without departing from the scope of the invention. For example, in some embodiments the use o~ multiple ultrasonic horns aligned abreast or sequentially may be desirable. It is also to be understood that the scope of the present invention is not to be interpreted as limited to the specific embodiments disclosed herein, but only in accordance with the appended claims when read in ligh~ o~ the foregoing disclosure.
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(5) the formation of catalysts; (6) the degassing and solidification of molten metals; (7) the extraction of flavor oils in brewing; (8) electroplating; (9) drilling hard materials; (10~ fluxless soldering and (10~ nondestructive testing such as in diagnostic medicine.
The object of high power ultrasonic applications is to bring about some permanent physical change in the material treated. This process requires the flow of vibratory power per unit of area or volume. Depending on the application, the power density may range ~rom less than a watt to thousands - :, . - . . .
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of watts per square centimeter. Although the original ultrasonic power devices operated at radio frequencies, today most operate at 20-69 kHz.
The piezoelectric sandwich-type transducer driven by an electronic power supply ha~ emerged as the most common source of ultrasonic power. The overall efficiency of such equipment (net acoustic power per electric-line power) is typically greater than 70%. The maximum power from a conventional transducer is inversely proportional to the square of the frequency. Some applications, such as cleaning, may have many transducers working into a common load.
Other, more particular areas where ultrasonic vibratory force has been utilized are in the areas of thin nonwoven webs and thin films. For example, ultrasonic for~e has been use to bond or weld nonwoven webs. See, for example, U.S. patent numbers 3,575,752 to Carpenter, 3,660,186 to Saqer et al., 3,966,519 to Mi~chell et al. and 4,695,454 to Sayov _z et al.
which disclose the use of ultrasonics to bond or weld nonwoven webs. U.S. patent number 3,488,240 to Roberts, describes the use of ultrasonics to bond or weld thi~ films such as oriented polyesters.
Ultrasonic force has also been utilized to aperture nonwoven webs. See, for example, U.S. patent nu~bers 3,949,127 to Ostermeler et al. and 3,966,519 to Mitchell et al.~
Lastly, ultrasonic force has been used to aperture thin film material. See, for example, U. S. patent number 3,756,880 to Graczyk~
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Other methods for the aperturing of thin film have been developed. For example, U.S. patent number 4,~15,714 to Doualas discusses the aperturing of a thin film by first abrading the ~`ilm, which is in filled and unoriented form, and then subjecting t~e film to corona discharge traatment.
One of the difficulties and obsiacles in the use of ultrasonic force in the formation of apertures in materials i5 the fact that control of the amount of force which is applied was difficult. This lack of control generally resulted in the limitation of ultrasonic force to form large apertures as opposed to small microapertures. Such an application is discussed in U.K. patent application number 2,124,134 to Blair. One of the possible reasons that ultrasonics has not found satisfactory acceptance in the area of microaperture 40rmation is ~hat the amount of vibrational energy required to form an aperture ofken resulted in a melt-through of the film.
As has previously been stated, those in the art had recognized that ultrasonics could be utilized to form apertures in nonwoven webs. See, U.S. patent to itche~l~ et al.. Additionally, the Mitchell et al~ patent discloses that the amount of ultrasonic energy being subjected to a nonwoven web could be controlled by applying enough of a fluid to the area at which the ultrasonic energy was being applied to the nonwoven web so that the fluid was present in uncombin~d form.
Importantly, the Mitchell, et al. patent states that the fluid is moved by the action of the ultrasonic force within the nonwoven web to cause aperture formation in the web by fiber : . ~, ~73~
rearrangemen~ and entanglement. The Mitchell et al. patent also states that, in its broadest aspects, since these effects are obtained primarily throu~h physical movement o~ fibers, the method of their invention may be utilized to bond or increase the strength of a wide variety of fibrous webs.
While the discovery disclosed in the Mitchell et al.
patent, no doubt, was an important contribution to the art, it clearly did not addr~ss the possibility of embedding solid materials such as fibers and particulates into thin soft film materials. This fact is clear because the Mitchell et al.
patent clearly states the belief that the mechanism o~
aperture formation depended upon fiber rearrangement within a web material. Of course, thin soPt film materials do not have fibers and thus there are no intra-web fibers to be lS rearranged. Accordingly, it can be stated with conviction that the applicability of a method for embedding solid materials such as fibers and particulates into a thin soft film material by the application of ultrasonic enerqy in conjunction with a fluid at ~he poin~ of application of the ultrasonic energy to the thin nonfibrous elastomeric sheet material was not contemplated by the Mitchell et al. patent. Moreover, the relevance of the Mitchell et al. patent to such an application is ques~ionable because the patent is directed toward aperture formation as opposed to e~bedding materials into a thin soft film material.
As is discussed in the related applications, disclosed above, the applicants of the present invention have been conducting a considerable amount of research in the area of ; . , .
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application o~ ultrasonics. As a result of thesP
investigations, some surprising discoveries have been made.
DEFINITIONS
As use.d herein the term "soft material", refers to any material that is capable of having fibers or particulates embedded therein by hydrosonic processing. Examples o~ soft materials include, without limitation, certain thermoplastic film materials and certain materials derived from natural materials. Some experimentation is necessary because if the material is too hard fibers and/or particulates cannot ~e embedded therein. Conversely, if the material is too elastic fibers and particulates cannot be embedded because, it is believed, they bounce of~ of the material during hydrosonic processing~
As used herein the te~m "soft film material" refers to a generally nonporou~ film formed from a material that ran be arranged in generally planar configuration which. This term is also intended to include multilayer materials which include, as a surface layer thereof, at least one such soPt film material as a layer thereof.
As used herein the term "thin soft film material" refers to a soft film material having an average thicknesæ yenerally of less than about ten (10) mils. Average thickness is determined by randomly selecting five (5) locations on a given film material, measuring the thickness of the film material ': ~' ' ',. "~ , , ;
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at each location to the nearest 0.1 mil, and averaging the five values ~sum of the five values divided by five).
As used herein the term "mesh count" refers to the num~er which is the product of the number o~ wires in a wire mesh screen in both the machine (MD) and cross-machine (CD) directions in a given unit axea. For exampl~, a wir~ mesh screen having 100 wires per inch in the machine direction and 100 wires par inch in the cross machine direction would have a mesh count of 10,000 per square inch. As a result of the interweaving of these wires, raised areas are present on both sides of the mesh screen. The number of raised areas on one side of such a wire mesh screen is generally one-half of the mesh count.
As used herein the term "aperture" refers to a generally linear hole or passageway. Aperture is to be distinguished from and does not include holes or passageways having the greatly tortuous path or passageways found in membranes.
As used herein the term "microaperture'~ refers to an aperture which has an area of less than about 100,000 square micrometers. The area of the microaperture is to be measured at the narrow~st point in the linear passageway or hole.
As used herein the ~erm "ultrasonic vibrations" refers to vibrations having a frequency of at least about 20,000 cycles per second. The frequency of th~ ultrasonic vibrations may range from about 20,000 to about 400,000 cycles per second.
As used herein the term "hydrosonics" re~ers to th2 application of ultrasonic vibrations to a material where the , ' '' ~, . ' 2~3~
area of such application is has had a liquid applied thereto to the extent that the liquid is present in sufficient quantity to generally fill the gap between the tip of the ultrasonic horn and the surface of the material.
O~JECTS QF THE INVENTION
Accordingly, it is a general object of the present invention to provide a thin so~t film material which has fibers and/or particulates embedded therein.
It is another general object of the present invention to provide a process for embedding fibers and~or particulates in thin soft film materials.
Still further objects and the broad scope of applicability of the present invention will become apparent to those o~
skill in the art from the details given hereinafter. However, it should be understood that the detai.led description of the presently preferred embodiments of the present invention is given only by way of illustration because various changes and modi~ications well within the spirit and scope of the invention w}ll become apparent to those o~ skill in the art in view of this detailed description.
SUMM~RY OF THE I~VENTION
As is revealed in detail in the referenced related applications, we have discovered that thin sheet materials may be microapertured if they are subjected to hydrosonic g ": ., , , : ~: ~ , . , ::
2~73~5 treat~ent against an anvil where the anvil is a pattern anvil having a pattern of raised arPas that have a hei~ht which is greater than the thickness of the thin sheet material to be apertured. While conducting the experiments discuss~d in detail in the referenced related applications, some experiments were conducted to detarmine whethar the presence of solids in the fluid would affect the microaperturing process. ~uch to our surprise, not only was the microaperturing process generally not affected, but we discovered that the hydrosonic force actually embedded the fihers and particulates which we had added to the coupling fluid to act as impurities into the sheet material wAile the sheet material was still apertured.
In additional experiments it was determined that, if the pattern anvil was removed and an anvil having a planar surface was substituted for the pattern anvil, the thin sheet material would no longer be microapertured but would still have the fib~rs and/or particulates embedded therein.
Accordingly, we have developed a thin soft film material having fibers and~or particulates embedded therein. The fibers to be embedded may be of any type which is able to withstand hydrosonic treatment. For example, the fibers to be embedded may be selected from the group including metallic fibers such as are found in steel wool: naturally occurring fibers ~uch as, for example, wood pulp fibers, cotton fibers and wool fibers; and synthetic fibers such as polyolefin fibers, rayon fibers and nylon fibers. The particulates to be embedded may be o~ any type which is able to withstand hydrosonic , ;, ' ` ,:: ,:~
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, 2~1~73~5 treatment. For example, the particuLat~s may be selected from the group including calcium carbonate, silicon carbide, diamond or activated charcoal. In some embodiments both fibers and particulates may be embedded into tha thin soft film material.
In some embodiments the thin soft film material may be formed from the group of materials selected from the group including soft polypxcpylenes, soft polyethylenes, so~t urethanes, soft alginates or carrageenanO
As was stated above, in some embodiments the thin soft film which is embedded with fibers and/or particulates may alæo be microapertured so that it defines at least about 1,000 microapertures p~r square inch. For example, the thin soft film material which is embedded with fibers and/or parti¢ulates may also be microapertured so that it defines at least about 5,000 microapertures per square inoh. More particularly, the thin soft film material which is embedded with fibers and/or particulates may al~so be microapertured so that it defines at least about 20,000 microapertures per s~uare inch. Even more particularly, the thin soft film material which is embedded with fibers and/or particulates may also be microapertured so that it defines at least about 90,000 microapertures per square inch. Yet even mor~
particularly, the thin soft film material which is embedded with fibers and/or particulates may also b~ microapertured so that it defines at least about 160,000 microapertures per square inch.
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In accordance with the definition o~ l'thin" sof~ film material, the average thickness oP the thin soft film material is les6 than about ten mils. Additionally, the average thickness of the thin soft film material is at least about 0.25 mil. For example, the avera~e thickne~s of the thin soft ~ilm material may range from at least about 0.25 mil to about 5 mil~. More particularly, the average thickness o~ the film material may range from at least about 0.25 mil to about 2 mils. Even more particularly, the average thickness of the film material may range from at least about 0.5 mil to about 1 mil.
The invention also is directed to a method for embedding fibers and/or particulates, or both, in a thin soft film material. The proces~ includes the steps of (a) placing the thin soft ~ilm material on an anvil means; (b~ conveying the thin so~t film matexial, while placed on the anvil means, through an area where a mixture of a fluid and fibers and/or particulate~, or both, is applied to the thin soft film ma~erial; and (c~ subjecting the thin soft film material to a sufficient amount of ultrasonic vibrations in the area where the fluid and fibers andtor particulates, or both, are applied to the thin soft film material to embed the fibers, particula~es or both into the thin soft film material.
The ~luid may be selected from the group including one or more of water, mineral oil, a chlorinated hydrocarbon, ethylene glycol or a solution o~ S0 volume percent water and 50 volume percent 2 propanol. For example, the chlorinated - 2~7~
hydrocarbon may be selected form the group including 1,1,1 trichloroethane or carbon tetrachloride.
In some embodiments it may be desirable for the embedding to be confined to a predesignated area or areas of the soft thin film. This result may be obtained where only a portion of the soft thin film is subjected to ultrasonic vibrations.
Where it is desired only to embed the fibers, paxticulates or both into the thin soft film material, the anvil means may be selected from the group including a smooth, nonpatterned, lo stainless steel shim material or a smooth, non pattsrned roller coated with a resilient material.
Where it is desired to both embed fibers, particulates, or both, into the thin soft film material and to microaperture the thin soft film material, the anvil means should be a pattern an~il me~hanism having a pattern of raised areas.
Figure I is a schematic representat:ion of apparatus which utilizes ultrasonic vibrations to embed fibers and/or particulates in thin soft film materials.
Figure II is a cross sectional view of the transport mechanism for transporting the thin soft film material to the area where it is subjected to ultrasonic vihrations~
Figure III is a detailed view of the area where the thin soft film material is subjected to ultrasonic vibrations. The area i5 designated by the dotted circle in Figure I.
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Figure IV is a photomicrograph of a 0.5 mil thick thin soft ~ilm of polyethylene which has had southern softwood fibers embedded therein in accordance with the present invention. The photomicxograph is accompanied by a scale where each unit represen~s ten microns (micrometers).
Figure V is a photomicrograph of a 0.5 mil thick thin soft f ilm of polyethylene which has been microapertured and has had southern so~twood fibers embedded therein in accordance with the present invention. The photomicrograph is accompanied by a scale where each unit represents ten microns (~icrometers).
Figur~ VI is a photomicrograph of a 0.5 mil thick thin soft film of polye~hylene which has been microapertured and has had calcium carbonate particulates embedded therein in accordance with ~he present invention. The photomicrograph is accompanied by a scale where each unit represents ten microns (micrometers~. -Figure VII is a photomicrograph O:e a 0.5 mil thick thin soft film of polyethylene which has b~een microapertured and has had silicon carbide particulates embedded therein in accordance with the present invention. The photomiarograph is accompanied by a scale where each unit represents ten microns (micrometers).
DETAILED DE5CRIPTION OF THE_INVENTION
Turning now to the Figures where like re~erence numerals represent like structure and, in particular to Figura I which ' ' '.' , ~, , . .
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is a schematic representation of an apparatus which can carry out the method of the present invention, it can be seen that the apparatus is generally represented by the reference numeral 10. In operation, a supply roll 12 of a thin soft film material 14 into which fibers, particulates, or both are to be embedded is ~upplied. As has been previously stated, the term ~hin sof~ film material refers to film materials which have an average thickness of about ten (10) mils or less.
Additionally, generally speaking the average thickness of the thin soft film material 1~ will be at least about 0.25 mil.
For example, the average thickness of the thin soft film 14 material may range fxom about O.Z5 mil to about 5 mils. More particularly, the average thickn~ss of the thin soft film material 14 may range from about 0.25 mil to about 2 mils.
Even more specifically, the average thickness of the thin soft film material 14 may range from about 0.5 mil to about 1 mil.
The thin soft film material 14 may be formed ~rom any suitable material meeting the definit:ion of soft contained herein. For example, the thin soft film material may be formed from soft materials such as soft polyolefins such as, for example, soft polypropylenes or soft polyethylenes; soft urethanes or soft alginlates such as carrageenan.
The thin soft film material 14 is transported to a first nip 16 formed by a first transport roll 18 and a first nip roller 20 by the action of an endless transport mechanism 22 which moves in the direction indicated by the arrow 24. The transport mechanism 22 is driven by the rotation of the ~irst transport roller 18 in conjunction with a second transport : :
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roller 26 which, in turn, are drivPn by a con~entional power source, not shown.
Figure II is 2 cross sectional view of the tran~port mechanism 22 taken along lines A-A in Figure I. Figure II
disclose~ that the transport mechanism 22 includes a heavy duty transport wire mesh screen 28 usually having a mesh count of less than a~out 400 (i.e. less than a 20 wires per inch MD
by 20 wire per inch CD mesh screen if machine direction (MD) and cross machine direction (CD) wire count is the same).
Heavy duty mesh wire screens of this type may be made from a variety of materials such as, for example, plastic~, nylons or polyeæters, and are readily available to those in the art.
Located above and attached to the transport screen 28 is an endless flat shim plate 30. The shim plate 30 d~sirably is formed from stainless steel. However, those of skill in the art will readily recognize that other materials may be utilized.
From the first nip 16 the thin soft film material 14 is transported by the transport mechanism 22 over a tension roll 36 to an area 38 (defined in Figure I by the dotted lined circle) where the thin soft film material 14 is subjected to ultrasonic vibrations.
The assembly for subjecting the thin soft film material 14 to the ultrasonic vibrations is conventional and is generally designated at 40. The assembly 40 includes a power supply 42 which, through a power control 44, supplies power to a piezoelectric transducer 46. As is well known in the art, the piezoelectric transducer 46 transforms electrical energy ;. . :: :
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into mechanical movement as a result of the transducer's vibrating in response to an input of electrical energy. The vibrations crea~ed by the piezoel~ctric transducer 46 are transferred, in conventional manner, to a mechanical movement booster or ~mplifier 48. As is well known in the art, the mechanical movement booster 48 may be designed to increase the amplitude of the vibrations (mechanical movement) by a known factor depending upon the configuration of the booster 48c In further conventional manner, the mechanical movement (vibrational energy~ is transferred from the mechanical movement booster 48 to a conventional knife edge ultrasonic horn 50. It should be realized that other types of ultrasonic horns S0 could be utilized. For example, a rotary type ultrasonic horn could be used. The ultrasonic horn 50 may be designed to ef~ect yet another boost or increase in the amplitude of the mechanical movement (vibrations) which is to be applied to the thin soft film material 14. Lastly, the assembly includes an actuator 52 which includes a pneumatic cylinder, not shown. The actuator 52 provides a mechanism for raising and lowering the assembly 40 so that the tip 54 of the ul~rasonic horn 50 can apply tension to the transpor~
mechanism 22 upon the assembly 40 being lowered. It has been found that it i5 necessary to have som~ degree of tension applied to the tran~port mechanism 22 upon the lowering of the assembly for proper application of vibrational energy to the thin soft film material 14 to embed solid materials such as fibers, particulates, or both into the thin soft film material 14. one desirable aspect of this tensioned arrangement is that ;
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the need to desig~ a finely tolerancefl gap between th~ tip 54 o~ the horn 50 and the shim plate 30.
Figure III i~ a schematic representatisn of the area 38 where the ultra~onic vihrations are applied to the thin soft film material 14. As can be seen in Figura III, the transport mechanism 22 forms an angle 56 with the tip 54 of the ultrasonic horn 50. While some embedding will occur if the angle 56 is a~ great as 45 degrees, it has been found that it is desirable for the angle 56 to range from about 5 degrees to about 15 degrees. For example, the angle 56 may range from about 7 to about 13 degrees. More particularly, the anglr 56 may range ~rom abou~ g to about 11 degrees.
Figure III also illustrates that the transport mechanism 22 is supported from below by the first tension roll 36 and a second tension roll 58. Positioned somewhat prior to th~ tip 54 of the ultrasonic horn 50 is a spray nozzle 60 which is configured to apply a mixture of a fluid and the fibers, particulates, etc. 62 which are to be embedded into the surface of the thin soft film material 14 just prior to the sheet material 14 being subjected to ultraconic ~ibrations by the tip 54 of the ultrasonic horn 50. The fluid portion of the mixture 62 desirably may be selected from the group including one or more of water, mineral oil, a chlorinated hydrocarbon, ethylene glycol or a solution of 5Q volume percent water and 50 volume percent 2 propanol. For example, in some embodiments the chlorinated hydrocarbon may be selected from the group including 1,1,1 trichloroethane or carbon tetrachloride. The fibers and/or particulate6 or both which may be utilized in ' 2~73~
the ~ixture 62 may be any type of fibers having sufficient rigidity to allow there being embedded into the thin soft film material 14. For example, the fibers may be selected ~rom the group including metallic fibers such as are found in steel wool; naturally occurring fibers such as, for example, wood pulp fibers, cotton fibers and wool fibers; and synthetic fibers such as polyolefin fibers, rayon fibers and nylon fibers. The particulates ~o be embedded may be of any type which is able to withstand hydrosonic treatment. For example, the particula~es may be selected from the group including calcium carbonate, silicon carbide, diamond or activated charcoal.
It should be noted that the wedge-shaped area 64 formed by the tip 54 of the ultrasonic horn 50 and the transport mechanism 22 should be subjected to a sufficient amount of the mixture 62 for the fluid to act as both a heat sink and a coupling agent for the most desirable results.
Positioned below the transport mechanism 22 in the area where the tip 54 of the ultrasonic horn 50 is located is a mixt~re collection tank 66. (See F:Lgure I.3 The mixture collection tank 66 serves to collect mixture 62 which has heen applied to the surface of the thin soft film material 14 and which has been driven through the transport mechanism 22 or over the edges of the transport mechanism 22 by the action of the vibrations of the tip 54 of the ultrasonic horn 50.
Mixture 62 which is collected in the collection tank 66 is transported by tubing 68 to a mixture holding tank 70.
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Figure I illustrates that the mixture holding tank 70 con~ains a pump 72 which, by way of additional tubing 74, supplies ~he mi~ture 62 to the mixture spray nozzle 60.
Accordingly, the mixture 62 may be re-cycled for a con-siderable period of time.
While the mechanism of action may not be fully understood and the present application should not be bound to any particular theory or mechanism of action, it is believed that the presence of the fluid portion of the mixture 62 in the wedge-shaped area 64 durinq operation of the ultrasonic hcrn 50 accomplishes two separate and distinct functions. First~
the presence o~ the fluid portion allows the fluid to act as a heat sink which allows the ultrasonic vibrations to be applied to the thin soft film material 14 without the thin soft film material 14 being alterecl or destroyed as by melting. Secondly, the presence of the fluid portion of the mixture 62 in the wedge-shaped area 64 allows the fluid to act as a coupling agent in the application of the vibrations from the ultrasonic horn 50 to the thin soft film material 14.
It has heen discovered that the action of the ultrasonic horn 50 on the fibers, particulates, or both, in the mixture 62 embeds them in the soft film material 14.
If it is desired to provide a soft thin film material 14 which is both embedded with fibers, particulates, both, etc., this may b~ accomplished in accordance with the teachings of our other above-referenced applications. To accomplish this, it is necessary to locate above and attach to the shim plate 30 a fine mesh wire pattern screen 32 usually having a mesh count of at lea t about 2,000 (i.e. at least about 45 wires per inch MD by 45 wires per inch CD mesh screen if MD and CD
wire count is ths same3. Fine mesh wire screens of this type are readily available to those in the art. The fine mesh wire screen 32 has raised areas or knuckles 34 which preform the function of a pattern anvil as will be discussed later.
As the thin soft film material 14 is subjected to the hydrosonic forces, the microapertures are punched through the thin soft film material 14 in the pattern of the raised areas or knuckles 34 of the fine mesh wire pattern screen 32.
Generally, the number of microapertures produced will be equal to the number of raised areas or knuckles 34 on the upper surface o~ the fine mesh wire screen 32. That is, the number of microapertures will generally be one-half the mesh count o~ a given area of pattern screen 32. For example, if the pattern screen 32 is 100 wires p~r inch MD by 100 wires per inch CD, the total number of knuckles or raised areas 34 on one side of the pattern wire, per square inch, 32 will be lU0 times 100 divided by 2. This equals 5,000 microap~rtures per square inch. For a 200 wires per inch by 200 wires per inch m~sh pattern screen 32 the calculation yields 20,000 microapertures per square inch. Depending somewhat on the thickness of the thin soft film material 14, at a mesh count of about 90,0oO (300 wires per inch MD by 300 wires per inch CD) the wires are so thin as to allow the knuckles 34 on both sides to microaperture the thin soft film material 14 if sufficient force is applied. Thus, a 300 wires per inch MD by 300 wires per inch CD mesh screen yields 90,000 microapertures .
' ~7~5 per square inch; for a ~00 wires per inch MD by 400 wires per inch CD mesh--160,000 microapertures per square inch. o~
course the MD and CD wire count of the wire mesh screen does not have to be the same.
It should al~o be noted that the number of microapertures formed may also vary with the number of ultrasonic vibrations to which the thin soft film material 14 is subjected per unit area for a given period of time. This factor may be varied in a number of ways. For example, the number and size of the microapertures will vary somewhat with the line speed of the thin soft film material 14 as it passes underneath the tip 54 of the ultrasonic horn 50. Generally speaking, as line speed increases, first the size of the microapertures decreases and then the number of microapert~lres decreases. As the number of microapertures decreases the less the pattern of microapertures resembles the pattern o~ raised areas 34 on the pattern screen 32. The range of linle speeds that usually yields microapertures varies with the soft material utilized to form the thin soft film material 1~ and the material used as the fluid in the mixture 62. For polyethylene having a thickness of about 0.5 mil, typical line speeds which usually yield microapertures for a variety of fluids range from about 7 to about 25 feet per minute. For example, if water is the fluid in the mixture and the film material is a polyethylene, typical line speeds which usually yield microapertures range from about 7 to about 23 Peet per minute. It is believed that, to some extent, ~he variations in the number of microapertures formed and the size of the microapertures occurs due to the . :,:, : :
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minute variations in the height o* the raised areas or knuckles 34 of the fine mesh pattern screen 32. It should be noted that the fine mesh pattern screens used to date have been obtained ~rom conventional everyday sources such as a hardware store. It is also helieved that if a pattern screen 32 could be created where all oP the raised areas 34 of the screen 32 were of exactly the same height these variatio~s would only occur in unifor~ fashion with variations of line speed.
As was stated above, the area or size of each of the microapertures formed will also vary with the parameters discussed above. The area of the microapertures will also vary with the area of the raised areas of the pattern anvil such as tns knuckles 34 on the fine mesh wire screen 32. It is believad that the type of soft material used in forming the thin so~t film material 14 will also vary the area of the microapertures formed if all other parameters are maintained the same. For example, the softer the thin soft film material 14, the easier it is to push the thin soft film material 14 through the raised areas of the *ine mesh pattern screen 32.
Because the raised areas (knuckles) on the fine mesh screen are generally pyramidal in shape, the deeper the raised area penetrates the thin soft film material 14, the larger the microaperture. Of course, the height of the raised areas must be greater than the thickness of the thin sheet material 14 for microapertures to be formed and the degree o~ excess necessary may vary with the type of soft film material 14 to be microapertured. Generally speaking, the more stretchable .
the material, the greater the height of the raised a~eas 34 must excPed the thickness of the thin so~t ~ilm material 14.
In some embodiments it may be necessary to subject the thin soft film ma~erial 14 to multiple passes through the apparatus 10 in order to microaperture the thin sheet material 14. In such situations the thin sheet material 14 will initially only be thinned in the pattern of the pattern anvil's raised areas9 However, two or more passes through the apparatus 10, with the thin soft film material 14 being aligned in the same configuration with respect to the pattern anvil, yields microapertures. Essentially what is happening in these situations is that the thin sot film material 14 is --repeatedly thinned by repeated application of ultrasonic vibrational force until such time as microapertures are formed. Al~ernatively, the fine mesh wire diameter size may be increased with the consequent decrease in mesh count.
Increasing the wire diameter size of the fine mesh screen 32 increases the llkelihood that microapertures will be formed.
0~ course, if it is desired to provide a thin soft film material 14 which has fibers, particulates, or both embedded therein and also having thinned areas or microareas, the amount o~ ultrasonic energy may need to be adjusted downwardly so that thinning and not microaperturing occurs. For more details on ~he details of th~ thinned area process, reference should be made to our referenced U.S. patent application serial number ~ entitled "Process For Hydrosonically Area Thinning Thin Sheet Materials" which has been incorporated herein by reference in its entirety.
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Another feature of the present invention is the fact that the microapertures or thinned areas or microareas can be formed in a predesignated area or areas of th~ thin soft film material 14. This can be accomplished in a number of ways. For example, the thin soft film material 14 may be subjected to ultrasonic vibrations only at certain areas of the thin soft film material 14. Alternatively, the entire thin soft ~ilm material 14 could be subjected to ultrasonic vibrations with the pattern anvil having raised areas 34 only at certain locations and otherwise being flat. Accordingly, the thin soft film material 14 would be microapertured only in those areas which corresponded ~o areas on the pattern anvil having raised areas.
It should also be noted that some limitation exists in the number of microapertures which can be formed in a given thin soft film material 14 on a single application of vibrational energy, i.e. a single pass through thP apparatus 10 if a wire mesh screen is used as the pattern anvil. This follows from the fact that, as was s~at~d above~ the height of the raised areas 34 must exceed the thickness of the thin soft film material 14 in conjunction with the fact that, generally as the mesh count increases the height of the raised areas or knuckles decreases. In such situations, if the number o~
microapertures dasired per unit area is greater than the number which can be formed in one pass through the apparatus, multiple passes are necessary with the alignment of the thin soft film material 14 with respect to the raised ares ~eing altered or shifted slightly on each pass.
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Generally speaking the area of ea~h of the microapertures is greater than about ten square micrometers. That is the area of each o~ the microapertures of each of the may ranye from at least about 10 square micrometers to ahout lO0,000 square microme~ers~ For example, the area o~ each o~ the microapertures may generally range from at least about 10 square micrometers to about 10,000 square micrometers. More particularly, the area of each of the micrsapertures may generally range from at least about 10 square micrometers to about l,000 square micrometers. Even more particularly, the area of each of the microapertures may generally range from at least about 10 square micrometers to about 100 square micrometers.
A number of important observations about the process may now be made. For example, it should be understood that the presence o~ the fluid portion of the mixture 62 is highly important to the pxesent inventive process which uses the fluid as a coupling agent~ Because a coupling agent is present, the fibers, particulates or both are embedded into the thin soft film material 14. Additionally, the presence of the shim plate 30 or its squivalent is necessary in order to provide an anvil mechani~m against which the thin soft film material 14 may be worked, that is apertured, by the action of the tip 54 of the ultrasonic horn 50. Because the vibrating tip 54 of the ultra~onic horn 50 is acting in a hammer and anvil manner when operated in conjunction with the heavy duty wire mesh screen 28/shim plate 30/fine wire mesh 32 combination, it should be readily recognized that a certain . ' ~,,~, 2~73~
degree of ~ension must be placed upon the transport mechanism 22 by the downward displacement of the ultrasonic horn 50. If there is little or no tension placed upon the transport mechanism 22, the shim plate 30 cannot preform its function as an anvil and microaperturing generally does not occur.
Because both the shim plate 30 and the fine mesh pattern wire 32 form the resistance that the ultrasonic horn 50 works against, they are collectively referred herein as a pattern anvil combina~ion. It should be easily recognized by those in the ar~ that the function of the pattern anvil can be accomplished by other arrangements than the heavy duty wire mesh screen 28/shim plate 30/fine mesh screen 32 combination.
For ~xample, the pattern anvil could be a flat plate with raised portions acting to direct the microaperturing force of the ultrasonic horn 50. Alternatively, the pattern anvil could be a cylindrical roller having raised areas. If the pattern anvil is a cylindrical roller, it is de~sirable for the pattern anvil to be wrapped or coated with or made from a resilient material. Where the pattern anvil is a mesh screen the resiliency is provided by the fact that the screen is unsupported directly below the point of application of ultrasonic vibrations to the mesh screen.
Th~ invention will now be discussed with regard to specific examples which will aid those of skill in the art in a full and complete understanding thereof.
EXAMPLE I
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A sheet of 0.5 mil thick polyethylene film having the trade designation S/~ 702 obtained from the Edison Company of Plainfield, New Jersey, and was cut into a length of about 11 inches and a width of about 8.5 inche~. The sample was subjected to hydrosonic treatment in accordance with the presenk invention.
A model 1120 power supply obtained from the Branson Company of Danbury, Connecticut, was utilized. This power supply, which ha th~ capacity to deliver 1,300 watts of electrical energy, was used to convert 115 volt, 60 cycle electrical energy to 20 kilohertz alternating current. A
Branson type J4 power level control, which has the ability to regulate the ultimate output of the model 1120 power supply from 0 to 100%, wa~ connected to the model 1120 power supply.
In this example, the power level control was set at 100%. The actual amount o~ power con~umed was indicated by a Branson modal A410A wattmeter. This amount waC; about 1 r 100 watts.
The output of the power supply was fed to a model 402 piezoelectric ultrasonic transducer obtained from the Branson Company. The transducer conYerts the electrical energy to mechanical movement. At 100% power the amount of mechanical movement o~ the ~ransducer is about 0.8 micrometers.
The piezoelectric transducer wa~ connected to a mechanical movement booster sectiGn obt~ined from the Branson Company.
The booster is a solid titanium metal shaft with a length equal to one-half wave length of the 20 kilohertz resonant ~requency. Boosters can be machined so that the amount of mechanical movement at their output end is increased or ,, ~
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decreased as compared to the amount of movemenk of the transducer. In this example the booster increased the amount of movement and has a gain ratio of about 1:2.5. That is, the amount of mechanical movement at the output end of the booster is about 2~5 times the amount of movement of the transducer.
The output end of the booster was connected to an ultrasonic horn obtained from the Branson Company. The horn in this example is made of titanium with a working face of about 9 inches by about 1/2 inch. The leading and trailing edges of the working face of the horn are each curved on a radius of about 1/8 inch. The horn step area is exponential in shape and yields about a two~fold increase in the mechanical movement of the booster. That is, the horn step area has about a 1:2 gain ratio. The combined increase, by the booster and the horn step arsa, in the original mechanical movement created by the transducer yields a mechanical movement of abou~ 4.0 micrometers.
The forming table arrangement included a small forming table which was utilized to transport and support the polyethylene film which is to have fiber embedded in it. The forming table included two 2-inch diameter idler rollers which were spaced about 12 inches apart on the surface of the forming table. A transport mesh belt e~circles the two idler rollers so that a continuous conveying or transport surface is created. The transport mesh belt is a square weave 20 x 20 mesh web of 0.020 inch diameter plastic filaments. The belt is about 10 inches wide and is raised above the surface of the forming table.
, ~73~5 The transducer/booster/horn assembly, hereinafter the assembly, is secured in a Branson series 400 actuator. When pswer is switched on to the transducer, the actuator, by means of a pneumatic cylinder with a piston area of about 4.4 square inches, lowers the assembly so that the output end of the horn contacts the sheet of polyethylene film which is to have fibers embedded therein. The actuator also raises the assembly so that the output end of the hoxn is removed from contact with the sheet of polyethylene film when power is switched off.
The assembly is positioned so that the output end of the horn is adapted so that it may be lowered to contact the transport mesh belt between the two idler rollers. An 8-inch wide 0.005-inch thick stainless steel shim stock having a length of about 60 inches was placed on the plastic mesh transport belt ~o provide an anvil mechanism. The sheet of polyethylene film which was to have fibers embedded therein was then fastened onto the metal shim using masking tape.
The forming table arrangement also included a mixture circulating sys~em. The circulating system includes a mixture reservoir tan~, a mixture circulating pump which may conveniently be located within the tank, associated tubing for transporting the mixture from the tank to a slotted boom which is designed to direct a curtain of mixtur2 into the juncture of the output end of the horn and sheet of polyethylene film which is to have fibers embedded ther~in. In operation, the assembly was positioned so that the output end of the horn was at an angle of from about 10 to 15 degrees to the sheet of , `'~','"' ' `
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polyethylene film. Accordingly, a wedye shaped chamber was fo~med between the output end of the ho.n and the sheet of polyethylene film. It is into this wedge shaped chamber that the mixture, in this axample a slurry of water and southern softwood obtained from the Kimberly-Clark Corporation Company under the trade designation CR54 was directed by the slotted boom. The slurry was prepared by placing the pulp into a British Disintegrator for about 3,000 revolutions~ The slurry was maintained a~ room temperature.
It should be noted that the actuator was positioned at a height to insure that, when the assembly is lowered, the downward movement of the output end of the horn is stoppPd by the tension of the transport mesh before the actuator reaches the limit of its stroke. In this example, actuating pressure was adjusted to 12 pounds per squaxe inch as re~d on a pressure gauge which is attached to the pneumatic cylinder of the actuator. This adjustment results in a total downward force of 52.8 pounds. (12 psi times 4.4 square inches of piston area equals 52.8 pounds of force.) The sequence of operation was (l) the mixture pump was switched on and the area wh re th output end of the horn was to contact the polyethylene film was flooded with the mixture;
(2) the transport mesh conveyor system was switched on and the polyethylene film started moving at 5 feet per minute; and (3) power to the assembly was supplied and the assembly was lowered so that the output end of the horn contacted the polyethylene film while the film continued to pass under the output end of the horn until the end of the sample was -3l-,, , ,, :
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reached. The reading on the A410A wattmeter during the process is an indication of the energy required to maintain maximum mechanical movement at the output end of the horn while working against the combined mass of the mixture, the polyethylene ~ilm, the shim stQck, and the transport wire.
This example yielded a polyethylene film having fibers embedded therein.
Figure IV is a photomicrograph of the polyethylene film processed by Example I having fibers embedded therein.
EXAMPLE II
The process of Example I was repeated with the exception that a 250 mesh wire was placed on top of the shim. The power utilized was about 1,200 watts. The results of this experiment were generally the same as those of Example I with the exception that the polyethylene ~ilm was both embedded with fibers and microapertured.
Figure V is a photomicrograph of the polyethylene film of Example II having fibers embedded therein.
EXAMPLE III
The process of Example II was repeated with the exception that the mixture was a mixture of water and calcium carbonate.
About 127.6 rams of calcium carbonate was mixed with about 23 kilograms of water. The calcium carhonate was obtained from the Aldrich Chemical Company of Milwaukee, Wisconsin and was a crystalline material o~ cubic shape and approximately 8 : : .
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microns in size. The watts utilized was read as about 800. The line speed of the polyethylene film was 7 feet per minute and the ac~ua~ing pressure was about 8 pounds per square inch. The results of ~his experiment were generally the same as those of Example II. The size of the microapertures was about 5 micrometers by 10 micrometers.
Figure VI is a photomicrograph of the polyethylene film of Example III having particulates e~bedded therein.
EXAMPLE IV
The process of Example III was repeated except that about 26~.1 grams of calcium carbonate was used.
The results of this experiment were generally ~he same as those of Example III.
EXAMPLE V
The process of Example III was repeated except that about 125.5 grams of 280 mesh, irregular shape silicon carbide obtained ~rom the supreme Felt & Abrasive co~ o~ Melrose, Illinois was substituted for the calcium carbonate. The silicon carbide had an apprsximate size of eight microns.
The results of this experiment were generally the same as those of Example III.
Figure VII is a photomicrograph of the polyethylene film of Example VII having silicon carbide embedded therein.
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EXAMPLE ~I
The process of Example V was repeated with the exception that about 151.1 grams of silicon carbide was used~ The results of this experiment were generally the same as those of Example V.
Figure VII is a photomicrograph of polyethylene film of having silicon carbide particulates embedded therein in accordance wi~h Example V.
The uses to which the thin soft film material having fibers, particulates or other solids embedded may be put are numerous. For example, the material may be utilized as abrasive clo~hs such as sandpaper. Alternatively, the material could provide a cotton-like film sheet for use as an outer cover for a diaper. The process of manufacturing many plastic materials could b~ modified by the teachings of the present invention so that their coefficient of friction was increased and they are less slippery.
It is to be understood that variations and modifications of the present invention may be made without departing from the scope of the invention. For example, in some embodiments the use o~ multiple ultrasonic horns aligned abreast or sequentially may be desirable. It is also to be understood that the scope of the present invention is not to be interpreted as limited to the specific embodiments disclosed herein, but only in accordance with the appended claims when read in ligh~ o~ the foregoing disclosure.
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Claims (32)
1. A thin soft film material having a material selected from the group consisting of fibers or particulates embedded therein.
2. The thin soft film material of claim 1, wherein the embedded material consists of fibers.
3. The thin soft film material of claim 2, wherein the fibers are selected from the group consisting of metallic fibers, wood pulp fibers, cotton fibers, wool fibers, polyolefin fibers, rayon fibers or nylon fibers.
4. The thin soft film material of claim 1, wherein the embedded material consists of particulates.
5. The thin soft film material of claim 4, wherein the particulates are selected from the group consisting of calcium carbonate, silicon carbide, diamond or activated charcoal.
6. The thin soft film material of claim 1, wherein the soft film material is selected from the group consisting of soft polyolefins, soft urethanes, soft alginates or carrageenan.
7. The thin soft film material of claim 6, wherein the polyolefin is selected from the group consisting of soft polyethylenes or soft polypropylenes.
8. The thin soft film material of claim 1, wherein the soft film material also defines at least about 1,000 microapertures per square inch.
9. The thin soft film material of claim 1, wherein the soft film material also defines at least about 5,000 microapertures per square inch.
10. The thin soft film material of claim 1, wherein the soft film material also defines at least about 20,000 microapertures per square inch.
11. The thin soft film material of claim 1, wherein the soft film material also defines at least about 90,000 microapertures per square inch.
12. The thin soft film material of claim 1, wherein the soft film material also defines at least about 160,000 microapertures per square inch.
13. The thin soft film material of claim 1, wherein the average thickness of the film material is at least about 0.25 mil.
14. The thin soft film material of claim 1, wherein the average thickness of the film material is from at least about 0.25 mil to about 5 mils.
15. The thin soft film material of claim 1, wherein the average thickness of the film material is from at least about 0.25 mil to about 2 mils.
16. The thin soft film material of claim 1, wherein the average thickness of the film material is from at least about 0.5 mil to about 1 mil.
17. The thin soft film material of claim 1, wherein the embedded material is embedded only in predesignated areas of the thin soft film material.
18. A method for embedding a material selected from the group consisting of fibers or particulates in a thin soft film material comprising the steps of:
(a) placing the thin soft film material on an anvil means;
(b) conveying the thin soft film material, while placed on the anvil means, through an area where a mixture of a fluid and fibers and/or particulates is applied to the thin soft film material; and (c) subjecting the thin soft film material to a sufficient amount of ultrasonic vibrations in the area where the mixture is applied to the thin soft film material to embed the fibers and/or particulates into the thin soft film material.
(a) placing the thin soft film material on an anvil means;
(b) conveying the thin soft film material, while placed on the anvil means, through an area where a mixture of a fluid and fibers and/or particulates is applied to the thin soft film material; and (c) subjecting the thin soft film material to a sufficient amount of ultrasonic vibrations in the area where the mixture is applied to the thin soft film material to embed the fibers and/or particulates into the thin soft film material.
19. The method of claim 1, wherein the fluid is selected from the group consisting of one or more of water, mineral oil, a chlorinated hydrocarbon, ethylene glycol or a solution of 50 volume percent water and 50 volume percent 2 propanol.
20. The method of claim 19, wherein the chlorinated hydrocarbon is selected form the group consisting of 1,1,1 trichloroethane or carbon tetrachloride.
21. The method of claim 18, wherein the thin soft film material is formed from the group of materials selected from thermoplastic film materials, soft polyolefins, soft urethanes, soft alginates or carrageenan.
22. The thin soft film material of claim 21, wherein the polyolefin is selected from the group consisting of soft polyethylenes or soft polypropylenes.
23. The method of claim 18, wherein the fibers are selected from the group consisting of metallic fibers, wood pulp fibers, cotton fibers, wool fibers, polyolefin fibers, rayon fibers or nylon fibers..
24. The method of claim 18, wherein the particulates are selected from the group consisting of calcium carbonate, silicon carbide, diamond or activated charcoal.
25. The method of claim 18, wherein the anvil means is selected from the group consisting of stainless steel shim material or a stainless steel roller.
26. The method of claim 25, wherein the anvil means is a pattern anvil having a pattern of raised areas and the thin soft film material is subjected a sufficient amount of ultrasonic vibrations in the area where the fluid is applied to the thin soft film material to microaperture the thin soft film material in a pattern generally the same as the pattern of raised areas on the pattern anvil.
27. The method of claim 26, wherein the thin soft film material is microapertured, with a microaperture density of at least about 1,000 microapertures per square inch.
28. The method of claim 26, wherein the thin soft film material is microapertured, with a microaperture density of at least about 5,000 microapertures per square inch.
29. The method of claim 26, wherein the thin soft film material is microapertured, with a microaperture density of at least about 20,000 microapertures per square inch.
30. The method of claim 26, wherein the thin soft film material is microapertured, with a microaperture density of at least about 90,000 microapertures per square inch.
31. The method of claim 26, wherein the thin soft film material is microapertured, with a microaperture density of at least about 160,000 microapertures per square inch.
32. The method of claim 18, wherein the fibers and/or particulates are embedded only in predesignated areas of the thin soft film material.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US07/768,494 US5443886A (en) | 1991-09-30 | 1991-09-30 | Hydrosonically embedded soft thin film materials |
US768,494 | 1991-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2057355A1 true CA2057355A1 (en) | 1993-03-31 |
Family
ID=25082661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2057355 Abandoned CA2057355A1 (en) | 1991-09-30 | 1991-12-10 | Hydrosonically embedded soft thin film materials and process for forming said materials |
Country Status (9)
Country | Link |
---|---|
US (2) | US5443886A (en) |
EP (1) | EP0535574A1 (en) |
JP (1) | JPH07144373A (en) |
KR (1) | KR930005782A (en) |
AU (1) | AU656025B2 (en) |
CA (1) | CA2057355A1 (en) |
MX (1) | MX9205402A (en) |
TW (1) | TW210315B (en) |
ZA (1) | ZA927000B (en) |
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-
1991
- 1991-09-30 US US07/768,494 patent/US5443886A/en not_active Expired - Fee Related
- 1991-12-10 CA CA 2057355 patent/CA2057355A1/en not_active Abandoned
-
1992
- 1992-09-14 ZA ZA927000A patent/ZA927000B/en unknown
- 1992-09-16 TW TW81107308A patent/TW210315B/zh active
- 1992-09-23 MX MX9205402A patent/MX9205402A/en unknown
- 1992-09-28 EP EP19920116573 patent/EP0535574A1/en not_active Ceased
- 1992-09-29 KR KR1019920017770A patent/KR930005782A/en not_active Application Discontinuation
- 1992-09-29 AU AU26030/92A patent/AU656025B2/en not_active Ceased
- 1992-09-30 JP JP28344992A patent/JPH07144373A/en active Pending
-
1995
- 1995-01-11 US US08/371,326 patent/US5514308A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH07144373A (en) | 1995-06-06 |
ZA927000B (en) | 1993-03-18 |
US5443886A (en) | 1995-08-22 |
TW210315B (en) | 1993-08-01 |
AU656025B2 (en) | 1995-01-19 |
AU2603092A (en) | 1993-04-01 |
EP0535574A1 (en) | 1993-04-07 |
MX9205402A (en) | 1993-03-01 |
KR930005782A (en) | 1993-04-20 |
US5514308A (en) | 1996-05-07 |
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Legal Events
Date | Code | Title | Description |
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FZDE | Discontinued |