CA2072476A1 - Catalysts components for polymerization of olefins - Google Patents

Catalysts components for polymerization of olefins

Info

Publication number
CA2072476A1
CA2072476A1 CA002072476A CA2072476A CA2072476A1 CA 2072476 A1 CA2072476 A1 CA 2072476A1 CA 002072476 A CA002072476 A CA 002072476A CA 2072476 A CA2072476 A CA 2072476A CA 2072476 A1 CA2072476 A1 CA 2072476A1
Authority
CA
Canada
Prior art keywords
compound
catalyst component
olefins
polymerization
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002072476A
Other languages
French (fr)
Other versions
CA2072476C (en
Inventor
Yoshio Tajima
Naoki Kataoka
Yosuke Numao
Takashi Seki
Kazuo Matsuura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Japan Polyolefins Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2072476A1 publication Critical patent/CA2072476A1/en
Application granted granted Critical
Publication of CA2072476C publication Critical patent/CA2072476C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity

Abstract

A catalyst component is disclosed for use in the homo-or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me1(OR1)pR2qX1 4-p-q, a second compound of the formula Me2(OR3)mR4nX2z-m-n and a third compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing controlled molecular weight, wide distribution thereof and other desirable qualities in the polymer product.
CA002072476A 1991-06-27 1992-06-26 Catalysts components for polymerization of olefins Expired - Fee Related CA2072476C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP3-183272 1991-06-27
JP18327291 1991-06-27
JP27667391 1991-09-27
JP3-276673 1991-09-27

Publications (2)

Publication Number Publication Date
CA2072476A1 true CA2072476A1 (en) 1992-12-28
CA2072476C CA2072476C (en) 2002-09-03

Family

ID=26501786

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002072476A Expired - Fee Related CA2072476C (en) 1991-06-27 1992-06-26 Catalysts components for polymerization of olefins

Country Status (4)

Country Link
US (3) US5451555A (en)
EP (1) EP0520816B1 (en)
CA (1) CA2072476C (en)
DE (1) DE69206694T2 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69206694T2 (en) * 1991-06-27 1996-07-04 Nippon Oil Co Ltd Catalyst components for olefin polymerization
DE69210480T2 (en) * 1991-06-27 1996-11-28 Nippon Oil Co Ltd Catalyst component for olefin polymerization
DE69224600T2 (en) * 1991-11-12 1998-08-27 Nippon Oil Co Ltd Catalyst components for olefin polymerization
CA2089591C (en) * 1992-02-21 1997-06-03 Kenji Nakacho Polyolefin resin and method for the preparation thereof
US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
AU660808B2 (en) * 1992-06-18 1995-07-06 Montell Technology Company B.V. Catalysts for the polymerization of olefins
JPH06220129A (en) * 1993-01-20 1994-08-09 Nippon Oil Co Ltd Production of high-strength and high-modulus polyethylene material
JP3344015B2 (en) * 1993-08-23 2002-11-11 住友化学工業株式会社 Ethylene-α-olefin copolymer and molded article molded from the copolymer
US5700895A (en) * 1993-08-23 1997-12-23 Sumitomo Chemical Company, Limited Ethylene-α-olefin copolymer and molded article thereof
JPH07173214A (en) * 1993-10-27 1995-07-11 Nippon Oil Co Ltd Catalyst component for olefin polymerization
WO1996013531A1 (en) * 1994-10-31 1996-05-09 W.R. Grace & Co.-Conn. Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts
NO315857B1 (en) * 1995-03-28 2003-11-03 Japan Polyolefines Co Ltd Ethylene <alpha> olefin copolymer, blend, film, laminated material, electrically insulating material and power cable containing this
US5750454A (en) * 1995-05-31 1998-05-12 Nippon Oil Co., Ltd. Catalyst composition and process for the production of olefinic polymers
US5644009A (en) * 1995-11-27 1997-07-01 Industrial Technology Research Institute Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same
US6111040A (en) * 1996-05-30 2000-08-29 Nippon Mitsubishi Oil Corporation Process for the production of olefinic polymers
US6127309A (en) * 1996-09-19 2000-10-03 Nippon Oil Co., Ltd. Catalyst for use in the alkylation of isoalkanes
US5747406A (en) * 1997-01-10 1998-05-05 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the production of olefin polymers
US6184317B1 (en) 1997-07-14 2001-02-06 The Board Of Trustees Of The Leland Stanford Jr. University Catalysts and processes for the synthesis of alternating ethylene/α-olefin copolymers, and isotactic copolymers thereof
US6054405A (en) 1997-12-29 2000-04-25 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
EP0933383A1 (en) 1998-01-29 1999-08-04 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
TW460485B (en) 1998-06-19 2001-10-21 Japan Polyolefins Co Ltd Ethylene.Α-olefin copolymer, and combinations, films and use thereof
US6100212A (en) 1998-06-30 2000-08-08 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
EP1062257A1 (en) * 1999-01-08 2000-12-27 The Board Of Trustees Of The Leland Stanford Junior University Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof
US6420298B1 (en) * 1999-08-31 2002-07-16 Exxonmobil Oil Corporation Metallocene catalyst compositions, processes for making polyolefin resins using such catalyst compositions, and products produced thereby

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DE1720785A1 (en) * 1968-02-17 1971-07-22 Hoechst Ag Process for the polymerization of alpha olefins
FR2016801A1 (en) * 1968-07-16 1970-05-15 Asahi Chemical Ind
IE40215B1 (en) * 1973-12-04 1979-04-11 Ici Ltd Olefine polymer, olefine polymerisation process and catalyst
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DE69224600T2 (en) * 1991-11-12 1998-08-27 Nippon Oil Co Ltd Catalyst components for olefin polymerization
US5644009A (en) * 1995-11-27 1997-07-01 Industrial Technology Research Institute Catalyst composition for preparing high syndiotacticity polystyrene from styrene of other arylethylene monomers and processes using the same

Also Published As

Publication number Publication date
CA2072476C (en) 2002-09-03
EP0520816A3 (en) 1993-02-03
US5451555A (en) 1995-09-19
DE69206694T2 (en) 1996-07-04
DE69206694D1 (en) 1996-01-25
EP0520816B1 (en) 1995-12-13
EP0520816A2 (en) 1992-12-30
US5594082A (en) 1997-01-14
US5824618A (en) 1998-10-20

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