CA2107783A1 - Launderable retroreflective applique - Google Patents

Launderable retroreflective applique

Info

Publication number
CA2107783A1
CA2107783A1 CA002107783A CA2107783A CA2107783A1 CA 2107783 A1 CA2107783 A1 CA 2107783A1 CA 002107783 A CA002107783 A CA 002107783A CA 2107783 A CA2107783 A CA 2107783A CA 2107783 A1 CA2107783 A1 CA 2107783A1
Authority
CA
Canada
Prior art keywords
binder layer
retroreflective applique
launderable retroreflective
launderable
applique
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002107783A
Other languages
French (fr)
Other versions
CA2107783C (en
Inventor
Wu-Shyong Li
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Wu-Shyong Li
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wu-Shyong Li, Minnesota Mining And Manufacturing Company filed Critical Wu-Shyong Li
Publication of CA2107783A1 publication Critical patent/CA2107783A1/en
Application granted granted Critical
Publication of CA2107783C publication Critical patent/CA2107783C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24421—Silicon containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y10T428/2817—Heat sealable
    • Y10T428/2826—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645—Next to addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645—Next to addition polymer from unsaturated monomers
    • Y10T428/31649—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31931—Polyene monomer-containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Abstract

Retroreflective appliques comprising a monolayer of retroreflective elements partially embedded in and protruding from the front surface of a binder layer and an optional layer of adhesive on the rear surface of the binder layer, wherein the binder layer comprises an electron-beam cured elastomer.
CA002107783A 1991-05-08 1992-03-09 Launderable retroreflective applique Expired - Fee Related CA2107783C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US69726491A 1991-05-08 1991-05-08
US07/697,264 1991-05-08
PCT/US1992/001944 WO1992019993A1 (en) 1991-05-08 1992-03-09 Launderable retroreflective applique

Publications (2)

Publication Number Publication Date
CA2107783A1 true CA2107783A1 (en) 1992-11-09
CA2107783C CA2107783C (en) 2002-05-14

Family

ID=24800466

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002107783A Expired - Fee Related CA2107783C (en) 1991-05-08 1992-03-09 Launderable retroreflective applique

Country Status (7)

Country Link
US (1) US5283101A (en)
EP (1) EP0583267B1 (en)
JP (1) JP3048062B2 (en)
CA (1) CA2107783C (en)
DE (1) DE69219465T2 (en)
ES (1) ES2101095T3 (en)
WO (1) WO1992019993A1 (en)

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US5474827A (en) * 1994-03-23 1995-12-12 Minnesota Mining And Manufacturing Company Retroreflective article and method of making the same
KR100338991B1 (en) * 1994-04-01 2002-12-26 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 Clothing with Retroreflective Appliques
TW277152B (en) * 1994-05-10 1996-06-01 Hitachi Chemical Co Ltd
CA2188141C (en) * 1994-05-12 2003-05-20 Vera L. Lightle Retroreflective article and method of making same
US5824390A (en) * 1994-07-22 1998-10-20 Nippon Carbide Kogyo Kabushiki Kaisha Method for producing retroreflective sheeting using a coupling agent
WO1996008737A1 (en) * 1994-09-16 1996-03-21 Minnesota Mining And Manufacturing Company Retroreflective article that has phenolic resin in chemical association with reflective aluminum layer
DE69507050T2 (en) 1994-11-23 1999-07-15 Minnesota Mining & Mfg RETROREFLECTIVE OBJECT WITH A POLYETHER-POLYURETHANE BOND LAYER
US5650213A (en) * 1994-11-30 1997-07-22 Reflective Technologies, Inc. Retroreflective composition
WO1996029620A1 (en) * 1995-03-23 1996-09-26 Minnesota Mining And Manufacturing Company Retroreflective applique
US5588156A (en) * 1995-06-07 1996-12-31 Diamond Safety Gear, Inc. Article of clothing having high visibility
US7289602B1 (en) 1995-06-23 2007-10-30 Science Applications International Corporation Portable, digital X-ray apparatus for producing, storing, and displaying electronic radioscopic images
US6389105B1 (en) * 1995-06-23 2002-05-14 Science Applications International Corporation Design and manufacturing approach to the implementation of a microlens-array based scintillation conversion screen
US5674605A (en) * 1995-09-15 1997-10-07 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
US5631064A (en) * 1995-09-15 1997-05-20 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
US5645938A (en) * 1995-09-15 1997-07-08 Minnesota Mining And Manufacturing Company Retroreflective article containing a polyester polyurethane binder layer
US5812317A (en) * 1995-10-26 1998-09-22 Minnesota Mining And Manufacturing Company Exposed lens retroreflective article having a polymeric intermediate layer disposed between microspheric and reflective layers
US6159537A (en) * 1997-08-01 2000-12-12 3M Innovative Properties Company Method of making a retroreflective article that has a binder layer containing an epoxy resin and silicone crosslinked polymer
CA2375420A1 (en) 1999-06-17 2000-12-28 3M Innovative Properties Company Retroreflective article having a colored layer containing reflective flakes and a dye covalently bonded to a polymer
US6878440B1 (en) 1999-07-02 2005-04-12 3M Innovative Properties Company Pressure sensitive adhesive sheet and production method thereof
DE19936464B4 (en) * 1999-08-03 2006-04-06 Lafarge Braas Gmbh Colored coating
MXPA02011021A (en) 2000-05-11 2003-03-10 Dow Chemical Co Method of making elastic articles having improved heat resistance.
US6676754B1 (en) 2000-06-30 2004-01-13 3M Innovative Properties Company Coating apparatus and methods of applying a polymer coating
US6586067B2 (en) * 2001-04-02 2003-07-01 Avery Dennison Corporation Encapsulated lens retroreflective sheeting
US20040191481A1 (en) * 2001-05-31 2004-09-30 Volker Erb Reflective sheet treated with fluorosilane
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ATE330056T1 (en) 2002-12-19 2006-07-15 Ind Bergamasca Rifrangenti S R METHOD FOR PRODUCING A PRINTED RETROREFLECTIVE MATERIAL
US20050137266A1 (en) * 2003-12-23 2005-06-23 Naiyong Jing Aqueous composition of an oligomeric fluorosilane and use thereof for surface treatment of optical elements
US7247386B2 (en) * 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
US20050188447A1 (en) * 2004-02-27 2005-09-01 Gray John W. Athletic apparel with applied indicia
US7110496B1 (en) 2004-07-21 2006-09-19 Science Applications International Corporation Portable system and method for non-intrusive radioscopic imaging
US9730429B2 (en) 2004-07-28 2017-08-15 Nite Glow Industries, Inc. Abrasion resistant omnidirectionally reflective retractable pet leash
US7204206B2 (en) * 2004-07-28 2007-04-17 Nite Glow Industries, Inc. Abrasion resistant omnidirectionally reflective pet leash
US7246477B2 (en) * 2004-07-28 2007-07-24 Nite Glow Industries, Inc. Omnidirectionally reflective horse halter
US6925965B1 (en) 2004-07-28 2005-08-09 Nite Glow Industries, Inc. Omnidirectional reflective pet leash
US7331311B2 (en) * 2004-07-28 2008-02-19 Nite Glow Industries, Inc. Abrasion resistant omnidirectionally reflective rope
US20110203533A1 (en) * 2004-07-28 2011-08-25 Marni Markell Hurwitz Flat, braided, omnidirectionally reflective collar and leash
US7549399B2 (en) * 2004-07-28 2009-06-23 Nite Glow Industries, Inc. Abrasion resistant omnidirectionally reflective retractable pet leash
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US7690331B2 (en) * 2004-07-28 2010-04-06 Nite Glow Industries, Inc Electroluminescent braided pet leash
US9247717B2 (en) 2004-07-28 2016-02-02 Nite Glow Industries, Inc. Retractable flat belt reflective pet leash
US7252396B2 (en) * 2004-11-16 2007-08-07 3M Innovative Properties Company Retroreflective article having at least one valve and method of making same
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EP2935474A1 (en) * 2012-12-20 2015-10-28 3M Innovative Properties Company Anti-soiling, abrasion resistant constructions and methods of making
CN105189590B (en) * 2013-02-21 2019-08-06 三菱化学株式会社 Crosslinking resin combination and encapsulating material
EP3060946A1 (en) 2013-10-24 2016-08-31 3M Innovative Properties Company Retroreflective articles with anti-staining properties
EP3100084B1 (en) 2014-01-31 2023-11-01 3M Innovative Properties Company Colored retroreflective articles
EP3105048B1 (en) 2014-02-13 2021-06-16 3M Innovative Properties Company Dual cure stain resistant microsphere articles
EP3137931A1 (en) 2014-04-30 2017-03-08 3M Innovative Properties Company Stain resistant retroreflective articles
US10197714B2 (en) 2014-05-09 2019-02-05 3M Innovative Properties Company Colored retroreflective articles
US10545268B2 (en) 2014-05-09 2020-01-28 3M Innovative Properties Company Retroreflective articles
CN104101924A (en) * 2014-07-25 2014-10-15 杭州星华反光材料有限公司 Preparation technique for flame-retardant reflective warning tape
US10054724B2 (en) 2014-09-10 2018-08-21 3M Innovative Properties Company Exposed lens retroreflective articles comprising a self-assembled dielectric mirror
KR20170065591A (en) 2014-09-30 2017-06-13 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Retroreflective colored articles
US10345495B2 (en) 2014-12-30 2019-07-09 3M Innovative Properties Company Stain resistant retroreflective articles
EP3436259A4 (en) 2016-03-30 2020-02-05 3M Innovative Properties Company Article featuring a predetermined pattern of randomly distributed microspheres and methods of making the same
CN106154380B (en) * 2016-08-31 2019-02-22 上海通得丽反光材料有限公司 Flame retardant type reflective membrane and preparation method thereof
WO2019003158A1 (en) 2017-06-30 2019-01-03 3M Innovative Properties Company Articles having adhesive layers including urethane acrylate polymer or acrylate copolymer
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KR20220002458A (en) * 2019-04-25 2022-01-06 쓰리엠 이노베이티브 프로퍼티즈 캄파니 A retroreflective article comprising a plurality of locally laminated layers.
WO2023203406A1 (en) 2022-04-19 2023-10-26 3M Innovative Properties Company Retroreflective article
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Also Published As

Publication number Publication date
WO1992019993A1 (en) 1992-11-12
CA2107783C (en) 2002-05-14
DE69219465T2 (en) 1997-10-09
DE69219465D1 (en) 1997-06-05
EP0583267B1 (en) 1997-05-02
US5283101A (en) 1994-02-01
JPH06507253A (en) 1994-08-11
JP3048062B2 (en) 2000-06-05
ES2101095T3 (en) 1997-07-01
EP0583267A1 (en) 1994-02-23

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