CA2122409A1 - Alcools alpha-acetyleniques a longue chaine comme inhibiteurs de reaction d'hydrosilylation, et leur application pour la preparation de compositions silicones durcissables stables - Google Patents

Alcools alpha-acetyleniques a longue chaine comme inhibiteurs de reaction d'hydrosilylation, et leur application pour la preparation de compositions silicones durcissables stables

Info

Publication number
CA2122409A1
CA2122409A1 CA2122409A CA2122409A CA2122409A1 CA 2122409 A1 CA2122409 A1 CA 2122409A1 CA 2122409 A CA2122409 A CA 2122409A CA 2122409 A CA2122409 A CA 2122409A CA 2122409 A1 CA2122409 A1 CA 2122409A1
Authority
CA
Canada
Prior art keywords
hydrosilylation
alcohol
compositions
functions
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2122409A
Other languages
English (en)
Other versions
CA2122409C (fr
Inventor
Jean-Marc Frances
Robert-Stuart Dordick
Andre Soldat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Elkem Silicones France SAS
Original Assignee
Jean-Marc Frances
Robert-Stuart Dordick
Andre Soldat
Rhone-Poulenc Chimie
Rhodia Chimie
Bluestar Silicones France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jean-Marc Frances, Robert-Stuart Dordick, Andre Soldat, Rhone-Poulenc Chimie, Rhodia Chimie, Bluestar Silicones France filed Critical Jean-Marc Frances
Publication of CA2122409A1 publication Critical patent/CA2122409A1/fr
Application granted granted Critical
Publication of CA2122409C publication Critical patent/CA2122409C/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/12—Polysiloxanes containing silicon bound to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/70—Siloxanes defined by use of the MDTQ nomenclature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/80—Siloxanes having aromatic substituents, e.g. phenyl side groups

Abstract

La présente invention concerne un alcool alpha-acétylénique à longue chaîne comme inhibiteur de réaction d'hydrosilylation, son utilisation, son application pour la préparation de compositions silicones durcissables stables, son composant et son procédé pour l'obtention d'articles non adhérents. L'alcool acétylénique inhibiteur de réaction d'hydrosilylation, a pour formule:
R-(R')C(OH)-C~CH (I) dans laquelle R est un radical alkyle linéaire ou ramifié, ou un radical phényle, R' est H ou R, les radicaux R, R' et l'atome de carbone situé en .alpha. de la triple liaison pouvant éventuellement former un cycle, le nombre total d'atomes de carbone contenu dans R et R' étant d'au moins 9. L'alcool de l'invention est utilisé comme inhibiteur d'hydrosilylation dans des compositions durcissables à base d'une huile de base silicone à fonctions alcényle et/ou d'une résine modulateur d'adhérence à fonctions SiAlcényle, éventuellement d'une résine modulateur d'adhérence à
fonctions SiH, d'un agent de réticulation silicone à
fonctions SiH et d'un catalyseur d'hydrosilylation.
CA002122409A 1993-04-29 1994-04-28 Alcools alpha-acetyleniques a longue chaine comme inhibiteurs de reaction d'hydrosilylation, et leur application pour la preparation de compositions silicones durcissables stables Expired - Fee Related CA2122409C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9305130 1993-04-29
FR9305130A FR2704553B1 (fr) 1993-04-30 1993-04-30 Alcools alpha-acétyléniques à longue chaîne comme inhibiteurs de réaction d'hydrosilylation, et leur application pour la préparation de compositions silicones durcissables stables.

Publications (2)

Publication Number Publication Date
CA2122409A1 true CA2122409A1 (fr) 1994-10-30
CA2122409C CA2122409C (fr) 2000-06-20

Family

ID=9446606

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002122409A Expired - Fee Related CA2122409C (fr) 1993-04-29 1994-04-28 Alcools alpha-acetyleniques a longue chaine comme inhibiteurs de reaction d'hydrosilylation, et leur application pour la preparation de compositions silicones durcissables stables

Country Status (14)

Country Link
US (1) US5629387A (fr)
EP (1) EP0622420B1 (fr)
JP (1) JP2665881B2 (fr)
AT (1) ATE225383T1 (fr)
BR (1) BR9401604A (fr)
CA (1) CA2122409C (fr)
DE (1) DE69431456T2 (fr)
DK (1) DK0622420T3 (fr)
ES (1) ES2180566T3 (fr)
FI (1) FI941964A (fr)
FR (1) FR2704553B1 (fr)
MX (1) MX191230B (fr)
NO (1) NO305841B1 (fr)
PT (1) PT622420E (fr)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4436817A1 (de) * 1994-10-14 1996-04-18 Wacker Chemie Gmbh Organopolysiloxanharzlösungen, Verfahren zu deren Herstellung sowie deren Verwendung in Beschichtungsmassen
DE19541451A1 (de) 1995-11-07 1997-05-15 Wacker Chemie Gmbh Vernetzbare Zusammensetzungen
US6191247B1 (en) * 1996-04-10 2001-02-20 The Yokohama Rubber Co., Ltd. Polysiloxane composition having superior storage stability and rubber composition containing same
US6805912B2 (en) * 1997-03-21 2004-10-19 Jean-Paul Benayoun Process and device for coating a support using a crosslinkable silicone composition
FR2760981B1 (fr) * 1997-03-21 1999-06-04 Rhodia Chimie Sa Procede et dispositif d'enduction d'un support en vue de lui conferer des proprietes anti-adherentes, au moyen d'une composition silicone reticulable
US6395338B1 (en) * 1999-03-19 2002-05-28 Rhodia Chimie Process and device for coating a support using a crosslinkable silicone composition
DE19723669A1 (de) * 1997-06-05 1998-12-10 Wacker Chemie Gmbh Vernetzbare Zusammensetzungen
JP3568148B2 (ja) * 1997-09-12 2004-09-22 信越化学工業株式会社 オルガノポリシロキサン組成物
US6093256A (en) 1997-11-14 2000-07-25 Fort James Corp Embossing roll cleaning method
GB9912653D0 (en) * 1999-05-28 1999-07-28 Dow Corning Sa Organosilicon composition
US20050165194A1 (en) 2001-11-20 2005-07-28 Rhodia Chimie Crosslinking agent for a silicone composition which can be crosslinked at low temperature based on a hydrogenated silicone oil comprising Si-H units at the chain end and in the chain
FR2832414B1 (fr) * 2001-11-20 2004-01-30 Rhodia Chimie Sa Reticulant pour composition silicone reticulable a basse temperature a base d'une huile silicone hydrogenee comprenant des motifs si-h en bout de chaine et dans la chaine
FR2833963B1 (fr) * 2001-12-21 2004-03-12 Rhodia Chimie Sa RETICULANT POUR UNE COMPOSITION SILICONE RETICULABLE AVEC DE BAS TAUX DE PLATINE, A BASE D'UNE HUILE SILICONE HYDROGENEE COMPORTANT DES MOTIFS Si-H EN BOUT DE CHAINE ET DANS LA CHAINE
JP3865639B2 (ja) * 2002-01-28 2007-01-10 信越化学工業株式会社 半導体封止用シリコーン組成物および半導体装置
US20050003216A1 (en) * 2003-06-30 2005-01-06 Jean-Marc Frances Microparticle containing silicone release coatings having improved anti-block and release properties
JP4471361B2 (ja) * 2004-06-07 2010-06-02 信越化学工業株式会社 新規なフロロアルキル基含有アセチレンアルコールおよびその製造方法
US7067688B2 (en) 2004-11-09 2006-06-27 Shin-Etsu Chemical Co., Ltd. Acetylene alcohol and method for preparing the same
FR2879612B1 (fr) * 2004-12-21 2007-05-04 Rhodia Chimie Sa Composition elastomere silicone, adhesive, monocomposante et reticulable par polyaddition
US7750106B2 (en) * 2005-12-21 2010-07-06 Avon Products, Inc. Cosmetic compositions having in-situ hydrosilylation cross-linking
JP2008138013A (ja) * 2006-11-07 2008-06-19 Mitsui Chemicals Inc 低揮発性ゴム組成物
US8133478B2 (en) 2007-05-09 2012-03-13 Avon Products Inc. Cosmetic nanocomposites based on in-situ cross-linked POSS materials
US8263055B2 (en) * 2007-08-01 2012-09-11 Avon Products, Inc. Long lasting and waterproof lash extension composition
US8729170B2 (en) * 2008-12-30 2014-05-20 Bluestar Silicones France Sas Coating compositions and textile fabrics coated therewith
JP5343911B2 (ja) * 2010-04-09 2013-11-13 信越化学工業株式会社 無溶剤型シリコーン粘着剤用離型剤組成物及び剥離シート
BR112013005289A2 (pt) 2010-09-06 2020-09-29 Bluestar Silicones France rolo compressível, rolo de espuma de silicone, processo de fabricação e uso
CN103180392B (zh) 2010-09-06 2016-07-06 蓝星有机硅法国公司 用于弹性体泡沫材料的有机硅组合物
US20130052356A1 (en) * 2011-08-31 2013-02-28 Wacker Chemical Corporation Paper Coating Compositions For Grease and Water Resistance
US9498409B2 (en) 2014-12-16 2016-11-22 Momentive Performance Materials Inc. Cosmetic skin covering sheets and their method of preparation
US9801805B2 (en) 2014-12-16 2017-10-31 Momentive Performance Materials Inc. Personal care composition comprising silicone network
US9839602B2 (en) 2014-12-16 2017-12-12 Momentive Performance Materials Inc. Personal care compositions containing crosslinked silicone polymer networks and their method of preparation
US9744119B2 (en) 2014-12-16 2017-08-29 Momentive Performance Materials Inc. Cosmetic composition and method of preparation
US20160166494A1 (en) 2014-12-16 2016-06-16 Momentive Performance Materials Inc. Cosmetic composition and method of preparation
US9986743B2 (en) * 2016-03-18 2018-06-05 Wacker Chemie Ag Baking paper coated with a silicone-containing emulsion
CN111032604B (zh) * 2017-10-19 2020-10-30 美国陶氏有机硅公司 含有可用作氢化硅烷化反应抑制剂的2-取代的-1-炔基-1-环己醇的聚有机硅氧烷组合物
KR102648018B1 (ko) 2017-11-15 2024-03-18 신에쓰 가가꾸 고교 가부시끼가이샤 오르가노폴리실록산 조성물
CN112074931A (zh) 2018-05-01 2020-12-11 日产化学株式会社 包含耐热性阻聚剂的含有聚硅氧烷的临时粘接剂
CN113166624B (zh) 2018-11-16 2024-01-19 日产化学株式会社 红外线剥离用粘接剂组合物、层叠体、层叠体的制造方法以及剥离方法
US20220002591A1 (en) 2018-11-16 2022-01-06 Nissan Chemical Corporation Laminate peeling method, laminate, and laminate production method
KR20210096144A (ko) 2018-11-28 2021-08-04 닛산 가가쿠 가부시키가이샤 접착제 조성물, 적층체 및 적층체의 제조 방법, 그리고 반도체 형성 기판을 박화하는 방법

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1528464A (fr) * 1966-06-23 1968-06-07 Dow Corning Compositions d'organopolysiloxanes durcissables à une partie composante
NL129346C (fr) * 1966-06-23
US4024091A (en) * 1975-07-14 1977-05-17 Dow Corning Corporation Spongeable silicone gum stock
DE2654893A1 (de) * 1976-12-03 1978-06-15 Wacker Chemie Gmbh Verfahren zum herstellen von klebrige stoffe abweisenden ueberzuegen
JPS61136572A (ja) * 1984-12-06 1986-06-24 Nitto Electric Ind Co Ltd 剥離性処理層
FR2633303B1 (fr) * 1988-06-23 1990-10-05 Rhone Poulenc Chimie Emulsions aqueuses de silicones polycondensation catalysees par un monochelate d'etain
US5082894A (en) * 1990-03-19 1992-01-21 Dow Corning Corporation Storage stable one-part organosiloxane compositions
JPH0826168B2 (ja) * 1991-01-29 1996-03-13 信越化学工業株式会社 発泡性シリコーンゴム組成物及びシリコーンゴムスポンジ
US5214074A (en) * 1991-01-29 1993-05-25 Shin-Etsu Chemical Co., Ltd. Foamable silicone rubber composition and silicone rubber sponge
US5270425A (en) * 1992-11-23 1993-12-14 Dow Corning Corporation One-part curable organosiloxane compositions

Also Published As

Publication number Publication date
NO941533L (no) 1994-10-31
NO941533D0 (fr) 1994-04-27
JP2665881B2 (ja) 1997-10-22
DK0622420T3 (da) 2002-10-28
FI941964A0 (fi) 1994-04-28
FR2704553A1 (fr) 1994-11-04
CA2122409C (fr) 2000-06-20
US5629387A (en) 1997-05-13
JPH06329917A (ja) 1994-11-29
ES2180566T3 (es) 2003-02-16
ATE225383T1 (de) 2002-10-15
NO305841B1 (no) 1999-08-02
PT622420E (pt) 2003-02-28
EP0622420A1 (fr) 1994-11-02
MX191230B (es) 1999-02-12
EP0622420B1 (fr) 2002-10-02
BR9401604A (pt) 1994-12-27
FR2704553B1 (fr) 1995-06-09
DE69431456D1 (de) 2002-11-07
FI941964A (fi) 1994-10-31
DE69431456T2 (de) 2003-06-18

Similar Documents

Publication Publication Date Title
CA2122409A1 (fr) Alcools alpha-acetyleniques a longue chaine comme inhibiteurs de reaction d'hydrosilylation, et leur application pour la preparation de compositions silicones durcissables stables
DE68905170T2 (de) Akyloxyalkylierte polyorganosiloxane enthaltende rasierzusammensetzung fuer die haut und verfahren zu ihrer herstellung.
KR850006700A (ko) 감압성 접착제 박리피복용 조성물
AU584428B2 (en) (Meth) -Acrylic acid esters and the use thereof
KR950000836A (ko) 실라시클로헥산화합물, 그의 제조방법 및 이것을 함유하는 액정조성물
BR9608276A (pt) Organossilicone com um grupo funcional carboxila
ATE211902T1 (de) Kosmetische zusammensetzungen enthaltend ein filmbildendes polymer
KR910002879A (ko) 유기실란 화합물
CA2242015A1 (fr) Nouveaux derives chromeniques, leur procede de preparation et les compositions pharmaceutiques qui les contiennent
HUP0004110A2 (hu) Vizes emulzióban vinil-dimetikon/dimetikon kopolimert és sürítőszert tartalmazó kozmetikai készítmény és alkalmazása
EP0509922A3 (fr) Composition et procédé mettant en oeuvre des silicones thiols pour la protection de la couleur de fibres kératiniques teintes
KR890014443A (ko) 신규한 치환 나프타렌 화합물 및 동 화합물을 함유하는 액정조성물
HUP0004111A2 (hu) Vinil-dimetikon/dimetikon kopolimert és kationos felületaktív anyagot tartalmazó kozmetikai készítmény és alkalmazása
ES2009941A6 (es) Barniz para unas anhidro y dispositivo para su presentacion.
KR950000837A (ko) 실라시클로헥산화합물, 그의 제조방법 및 이것을 함유하는 액정조성물
FR2636946A1 (fr) ((diarylmethoxy)alcoyl)-1 pyrrolidines et piperidines, procedes de preparation et medicaments les contenant
FR2703682B1 (fr) Procédé de préparation de (méth)acrylate(s) d'alkylimidazolidone.
FR2436779A1 (fr) Derives de pyrrolidine-2 methanol utilisables comme medicaments
CA2201162A1 (fr) Esters phosphoriques d'alkyl ou d'acyl dianhydro-1,4:3,6-d-glucitol, procede de preparation et utilisations
BR9712784A (pt) Composições detergentes lìquidas de baixa espumação compreendendo supressor de espuma de silicone e éster de ácido graxo
FR2413439A1 (fr) Compositions d'organopolysiloxanes durcissables
KR950017930A (ko) 실라시클로헥산화합물, 그 제조방법 및 이것을 함유하는 액정조성물
DK0434560T3 (da) Hidtil ukendte substituerede aminosyrederivater, fremgangsmåde til fremstilling heraf og farmaceutiske midler indeholdende dem
EP0894529A3 (fr) Composition catalytique à base d'un complexe de platine contenant un organosiloxane fonctionnalisé par une longue chaíne alkyle et son procédé de préparation
BR9811238A (pt) Solução de hidrocarboneto de um composto dialquilmagnésio tendo reduzida viscosidade

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed