CA2124846A1 - Melt-stable lactide polymer composition and process for manufacture thereof - Google Patents

Melt-stable lactide polymer composition and process for manufacture thereof

Info

Publication number
CA2124846A1
CA2124846A1 CA002124846A CA2124846A CA2124846A1 CA 2124846 A1 CA2124846 A1 CA 2124846A1 CA 002124846 A CA002124846 A CA 002124846A CA 2124846 A CA2124846 A CA 2124846A CA 2124846 A1 CA2124846 A1 CA 2124846A1
Authority
CA
Canada
Prior art keywords
melt
stable
lactide
lactide polymer
polymer composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002124846A
Other languages
French (fr)
Other versions
CA2124846C (en
Inventor
Patrick R. Gruber
Jeffrey J. Kolstad
Eric S. Hall
Robin S. E. Conn
Christopher M. Ryan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cargill Inc
Original Assignee
Individual
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Filing date
Publication date
Family has litigation
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Application filed by Individual filed Critical Individual
Publication of CA2124846A1 publication Critical patent/CA2124846A1/en
Application granted granted Critical
Publication of CA2124846C publication Critical patent/CA2124846C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
    • A61L15/26—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
    • A61L31/04—Macromolecular materials
    • A61L31/06—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88—Post-polymerisation treatment
    • C08G63/90—Purification; Drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D01F6/625—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters derived from hydroxy-carboxylic acids, e.g. lactones
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/28—Polyesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00—Compositions for preparing biodegradable polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/3179—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31801—Of wax or waxy material
    • Y10T428/31804—Next to cellulosic
    • Y10T428/31808—Cellulosic is paper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31815—Of bituminous or tarry residue
    • Y10T428/31819—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31993—Of paper

Abstract

A lactide polymer composition combining compositional and purity limitations and catalyst optimization or addition of stabilizing agents resulting in a melt-stable polymer is disclosed. The melt-stable lactide polymer comprises a mixture of polylactide material having a number average molecular weight of at least about 10,000, residual lactide in concentration of less than about 2% and water in a concentration no greater than 1000 parts-per-million.
A stabilizing agent in an amount sufficient to reduce depolymerization of the lactide polymer during melt-processing or alternatively, control of catalyst level at a molar ratio of monomer to catalyst greater than 3000:1 is also included in the melt-stable composition. A process for manufacture of a melt-stable lactide polymer composition includes polymerizing a lactide mixture and adding stabilizing agents-sufficient to reduce depolymerization of the polylactide during melt-processing, followed by devolatilizing the polylactide to remove monomer and water.
CA 2124846 1992-10-02 1993-09-30 Melt-stable lactide polymer composition and process for manufacture thereof Expired - Lifetime CA2124846C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/955,690 1992-10-02
US07/955,690 US5338822A (en) 1992-10-02 1992-10-02 Melt-stable lactide polymer composition and process for manufacture thereof
PCT/US1993/009330 WO1994007949A1 (en) 1992-10-02 1993-09-30 Melt-stable lactide polymer composition and process for manufacture thereof

Publications (2)

Publication Number Publication Date
CA2124846A1 true CA2124846A1 (en) 1994-04-14
CA2124846C CA2124846C (en) 2009-05-19

Family

ID=25497211

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2124846 Expired - Lifetime CA2124846C (en) 1992-10-02 1993-09-30 Melt-stable lactide polymer composition and process for manufacture thereof

Country Status (17)

Country Link
US (15) US5338822A (en)
EP (1) EP0615532B1 (en)
JP (2) JP3436368B2 (en)
KR (3) KR100305536B1 (en)
AT (1) ATE193718T1 (en)
AU (1) AU660266B2 (en)
BR (1) BR9305657A (en)
CA (1) CA2124846C (en)
DE (1) DE69328822T2 (en)
DK (1) DK0615532T3 (en)
ES (1) ES2149217T3 (en)
FI (1) FI108142B (en)
MX (1) MX9306143A (en)
NO (1) NO309042B1 (en)
NZ (1) NZ257216A (en)
PT (1) PT615532E (en)
WO (1) WO1994007949A1 (en)

Families Citing this family (445)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6740731B2 (en) * 1988-08-08 2004-05-25 Cargill Dow Polymers Llc Degradation control of environmentally degradable disposable materials
US5444113A (en) * 1988-08-08 1995-08-22 Ecopol, Llc End use applications of biodegradable polymers
US6005068A (en) * 1992-10-02 1999-12-21 Cargill Incorporated Melt-stable amorphous lactide polymer film and process for manufacture thereof
DE69322155T2 (en) * 1992-10-02 1999-08-19 Cargill Inc PAPER WITH A COATING FROM MELT-STABLE POLYMER AND ITS METHOD FOR THE PRODUCTION THEREOF
PT615555E (en) 1992-10-02 2001-09-28 Cargill Inc LACTIDO POLYMER FABRIC STABILIZED IN THE FUSED DUCK STATE AND PROCESS FOR PREPARATION
US5338822A (en) * 1992-10-02 1994-08-16 Cargill, Incorporated Melt-stable lactide polymer composition and process for manufacture thereof
US5359026A (en) * 1993-07-30 1994-10-25 Cargill, Incorporated Poly(lactide) copolymer and process for manufacture thereof
US5645964A (en) 1993-08-05 1997-07-08 Kimberly-Clark Corporation Digital information recording media and method of using same
US6017471A (en) 1993-08-05 2000-01-25 Kimberly-Clark Worldwide, Inc. Colorants and colorant modifiers
US5865471A (en) 1993-08-05 1999-02-02 Kimberly-Clark Worldwide, Inc. Photo-erasable data processing forms
US5773182A (en) 1993-08-05 1998-06-30 Kimberly-Clark Worldwide, Inc. Method of light stabilizing a colorant
US5721287A (en) 1993-08-05 1998-02-24 Kimberly-Clark Worldwide, Inc. Method of mutating a colorant by irradiation
US6211383B1 (en) 1993-08-05 2001-04-03 Kimberly-Clark Worldwide, Inc. Nohr-McDonald elimination reaction
US5733693A (en) 1993-08-05 1998-03-31 Kimberly-Clark Worldwide, Inc. Method for improving the readability of data processing forms
US6017661A (en) 1994-11-09 2000-01-25 Kimberly-Clark Corporation Temporary marking using photoerasable colorants
US5681380A (en) 1995-06-05 1997-10-28 Kimberly-Clark Worldwide, Inc. Ink for ink jet printers
SG54295A1 (en) * 1993-12-20 1998-11-16 Procter & Gamble Ph-modified polymer compositions with enhanced biodegradability
FI99125C (en) * 1993-12-31 1997-10-10 Neste Oy Polylaktidsammansättning
JPH07205278A (en) * 1994-01-11 1995-08-08 Mitsubishi Plastics Ind Ltd Production of stretched film of polylactic acid polymer
JP3330712B2 (en) * 1994-01-11 2002-09-30 三菱樹脂株式会社 Method for producing polylactic acid-based film
DE69509927T2 (en) * 1994-01-21 2000-01-27 Shimadzu Corp Method of producing polylactic acid
US5639466A (en) * 1994-02-24 1997-06-17 Chronopol, Inc. Method for packaging foodstuffs
JP3328418B2 (en) * 1994-03-28 2002-09-24 三菱樹脂株式会社 Heat-shrinkable polylactic acid film
US6071979A (en) 1994-06-30 2000-06-06 Kimberly-Clark Worldwide, Inc. Photoreactor composition method of generating a reactive species and applications therefor
US6242057B1 (en) 1994-06-30 2001-06-05 Kimberly-Clark Worldwide, Inc. Photoreactor composition and applications therefor
US5685754A (en) 1994-06-30 1997-11-11 Kimberly-Clark Corporation Method of generating a reactive species and polymer coating applications therefor
US6008268A (en) 1994-10-21 1999-12-28 Kimberly-Clark Worldwide, Inc. Photoreactor composition, method of generating a reactive species, and applications therefor
JP2688330B2 (en) * 1994-10-25 1997-12-10 株式会社日本触媒 Polyester resin composition
JP3022226B2 (en) * 1994-12-08 2000-03-15 大伸化学株式会社 Catalytic method in electroless plating
US5714573A (en) 1995-01-19 1998-02-03 Cargill, Incorporated Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof
US5786132A (en) 1995-06-05 1998-07-28 Kimberly-Clark Corporation Pre-dyes, mutable dye compositions, and methods of developing a color
CA2219450A1 (en) 1995-06-05 1996-12-12 Ronald Sinclair Nohr Novel pre-dyes
ES2161357T3 (en) 1995-06-28 2001-12-01 Kimberly Clark Co STABILIZING COLORING COMPOSITION.
US5675022A (en) * 1995-08-23 1997-10-07 Union Carbide Chemicals & Plastics Technology Corporation Recovery of dioxanone by melt crystallization
JPH09157513A (en) * 1995-08-23 1997-06-17 Union Carbide Chem & Plast Technol Corp Stabilized dioxanone polymer
JP3482748B2 (en) * 1995-09-11 2004-01-06 大日本インキ化学工業株式会社 Method for producing lactic acid-based polyester
US5866634A (en) * 1995-09-25 1999-02-02 Shin-Etsu Chemical Co., Ltd Biodegradable polymer compositions and shrink films
US5849374A (en) * 1995-09-28 1998-12-15 Cargill, Incorporated Compostable multilayer structures, methods for manufacture, and articles prepared therefrom
US5849401A (en) * 1995-09-28 1998-12-15 Cargill, Incorporated Compostable multilayer structures, methods for manufacture, and articles prepared therefrom
US5686540A (en) * 1995-09-29 1997-11-11 Dainippon Ink And Chemicals, Inc. Process for the preparation of lactic acid-based polyester
US6099628A (en) 1996-03-29 2000-08-08 Kimberly-Clark Worldwide, Inc. Colorant stabilizers
US5782963A (en) 1996-03-29 1998-07-21 Kimberly-Clark Worldwide, Inc. Colorant stabilizers
SK102397A3 (en) 1995-11-28 1998-02-04 Kimberly Clark Co Colorant stabilizers
US5855655A (en) 1996-03-29 1999-01-05 Kimberly-Clark Worldwide, Inc. Colorant stabilizers
US5891229A (en) 1996-03-29 1999-04-06 Kimberly-Clark Worldwide, Inc. Colorant stabilizers
EP0909280B1 (en) * 1996-06-26 2000-08-23 Ciba SC Holding AG Decomposing polymers using nor-hals compounds
US5895587A (en) * 1997-01-21 1999-04-20 Cryovac, Inc. Cook-in package and method of making same
US5851937A (en) * 1997-03-27 1998-12-22 Clopay Plastic Products Company, Inc. Cloth-like totally biodegradable and/or compostable composites and method of manufacture
PT977912E (en) 1997-05-02 2005-02-28 Cargill Inc DEGRADABLE POLYMER FIBERS; PREPARATION; PRODUCT; AND METHODS OF USE
US6183814B1 (en) 1997-05-23 2001-02-06 Cargill, Incorporated Coating grade polylactide and coated paper, preparation and uses thereof, and articles prepared therefrom
FI980086A (en) 1997-05-28 1998-11-29 Enso Oyj Coated paperboard, its method of manufacture and containers and packaging made from it
EP0994650B1 (en) 1997-06-30 2004-02-25 Monsanto Technology LLC Microparticles containing agricultural active ingredients
US6524379B2 (en) 1997-08-15 2003-02-25 Kimberly-Clark Worldwide, Inc. Colorants, colorant stabilizers, ink compositions, and improved methods of making the same
US6089009A (en) 1997-08-28 2000-07-18 Belmont Textile Machinery Co., Inc. Fluid-jet false-twisting method and product
US6475759B1 (en) * 1997-10-14 2002-11-05 Cargill, Inc. Low PH lactic acid fermentation
US6229046B1 (en) 1997-10-14 2001-05-08 Cargill, Incorported Lactic acid processing methods arrangements and products
US6201068B1 (en) 1997-10-31 2001-03-13 Kimberly-Clark Worldwide, Inc. Biodegradable polylactide nonwovens with improved fluid management properties
US6268434B1 (en) 1997-10-31 2001-07-31 Kimberly Clark Worldwide, Inc. Biodegradable polylactide nonwovens with improved fluid management properties
US6309988B1 (en) 1997-12-22 2001-10-30 Kimberly-Clark Worldwide, Inc. Biodisintegratable nonwovens with improved fluid management properties
US6306782B1 (en) 1997-12-22 2001-10-23 Kimberly-Clark Worldwide, Inc. Disposable absorbent product having biodisintegratable nonwovens with improved fluid management properties
US6544455B1 (en) 1997-12-22 2003-04-08 Kimberly-Clark Worldwide, Inc. Methods for making a biodegradable thermoplastic composition
US6372850B2 (en) 1997-12-31 2002-04-16 Kimberly-Clark Worldwide, Inc. Melt processable poly (ethylene oxide) fibers
US6164011A (en) * 1998-02-02 2000-12-26 Cascades Multi-Pro Inc. Biodegradable and biocompatible agricultural mulch and method of preparing same
US6114495A (en) 1998-04-01 2000-09-05 Cargill Incorporated Lactic acid residue containing polymer composition and product having improved stability, and method for preparation and use thereof
DE69928101T2 (en) * 1998-05-28 2006-08-10 Gunze Limited, Ayabe LACTID BLOWN BONE FIXING DEVICE
SK1542000A3 (en) 1998-06-03 2001-11-06 Kimberly Clark Co Neonanoplasts produced by microemulsion technology and inks for ink jet printing
KR20010022593A (en) 1998-06-03 2001-03-26 로날드 디. 맥크레이 Novel Photoinitiators and Applications Therefor
US6228157B1 (en) 1998-07-20 2001-05-08 Ronald S. Nohr Ink jet ink compositions
JP2987580B1 (en) * 1998-08-07 1999-12-06 西川ゴム工業株式会社 Biodegradable resin and method for producing the same
US6197860B1 (en) 1998-08-31 2001-03-06 Kimberly-Clark Worldwide, Inc. Biodegradable nonwovens with improved fluid management properties
US6194483B1 (en) 1998-08-31 2001-02-27 Kimberly-Clark Worldwide, Inc. Disposable articles having biodegradable nonwovens with improved fluid management properties
JP2000095898A (en) * 1998-09-24 2000-04-04 Jsr Corp Biodegradable material modifier, and biodegradable material composition using the same
JP2003533548A (en) 1998-09-28 2003-11-11 キンバリー クラーク ワールドワイド インコーポレイテッド Chelates containing quinoid groups as photopolymerization initiators
US20030199218A1 (en) * 1998-10-23 2003-10-23 Mueller Louann S. Ream wrap comprising PLA resin
US20030129431A1 (en) * 1998-10-23 2003-07-10 Michael R. Nowak Composite wrap material
US6672001B1 (en) * 1998-11-17 2004-01-06 Board Of Regents Of University Of Nebraska Method for mulching an agricultural soil bed using a biodegradable protein material, and a mulched agricultural crop growing plot produced thereby
US6123811A (en) * 1998-12-14 2000-09-26 Ethicon, Inc. Method of manufacturing aqueous paper pulp for water soluble packages
DE60002294T2 (en) 1999-01-19 2003-10-30 Kimberly Clark Co DYES, COLOR STABILIZERS, INK COMPOSITIONS AND METHOD FOR THE PRODUCTION THEREOF
US6331056B1 (en) 1999-02-25 2001-12-18 Kimberly-Clark Worldwide, Inc. Printing apparatus and applications therefor
US6342065B1 (en) * 1999-03-17 2002-01-29 Poly-Med, Inc. High strength fibers of L-lactide copolymers ε-caprolactone and trimethylene carbonate and absorbable medical constructs thereof
US6608170B1 (en) * 1999-03-31 2003-08-19 Cornell Research Foundation, Inc. Syndiotactic poly(lactic acid)
US6294698B1 (en) 1999-04-16 2001-09-25 Kimberly-Clark Worldwide, Inc. Photoinitiators and applications therefor
US6217630B1 (en) 1999-05-03 2001-04-17 Cargill, Incorporated Conditioned fertilizer product, method for conditioning fertilizer, and method for using conditioned fertilizer product
US6368395B1 (en) 1999-05-24 2002-04-09 Kimberly-Clark Worldwide, Inc. Subphthalocyanine colorants, ink compositions, and method of making the same
US6576246B1 (en) * 1999-05-24 2003-06-10 Seefar Technologies, Inc. Degradable animal chewing article possessing enhanced safety, durability and mouth-feel
EP1108751B1 (en) * 1999-06-25 2007-10-24 Mitsui Chemicals, Inc. Aliphatic polyester composition for masterbatch and process for producing aliphatic polyester film with the composition
KR20010086308A (en) * 2000-01-14 2001-09-10 임현덕 Injection molding composition comprising paper and method for preparing the same
US20030121630A1 (en) * 2000-04-19 2003-07-03 Zhirun Yuan Inhibition of yellowing in papers
JP4296695B2 (en) * 2000-07-19 2009-07-15 セイコーエプソン株式会社 Pulp molded product and method for producing the same
WO2002051284A2 (en) * 2000-12-26 2002-07-04 Avon Products, Inc. Applicator brushes and method for using same
JP2002210886A (en) * 2001-01-19 2002-07-31 Toray Ind Inc Softened biodegradable resin stretched film
US20040255862A1 (en) * 2001-02-26 2004-12-23 Lee Chung J. Reactor for producing reactive intermediates for low dielectric constant polymer thin films
US20050274322A1 (en) * 2001-02-26 2005-12-15 Lee Chung J Reactor for producing reactive intermediates for low dielectric constant polymer thin films
DE10113302B4 (en) * 2001-03-19 2009-09-24 Fraunhofer-Gesellschaft für die angewandte Forschung e.V. Process for the preparation of homo- and copolyesters of lactic acid
US6660211B2 (en) 2001-04-23 2003-12-09 Kimberly-Clark Worldwide, Inc. Methods of making biodegradable films having enhanced ductility and breathability
US6905759B2 (en) * 2001-04-23 2005-06-14 Kimberly Clark Worldwide, Inc. Biodegradable films having enhanced ductility and breathability
DE10127314A1 (en) * 2001-06-06 2002-12-19 Trespaphan Gmbh Biaxially stretched film, useful for the production of packaging, comprises at least one base layer of a hydroxycarboxylic acid with a different thermoplastic polymer and/or inorganic additives.
US7080688B2 (en) 2003-08-14 2006-07-25 Halliburton Energy Services, Inc. Compositions and methods for degrading filter cake
US7276466B2 (en) 2001-06-11 2007-10-02 Halliburton Energy Services, Inc. Compositions and methods for reducing the viscosity of a fluid
US7140438B2 (en) 2003-08-14 2006-11-28 Halliburton Energy Services, Inc. Orthoester compositions and methods of use in subterranean applications
US7168489B2 (en) 2001-06-11 2007-01-30 Halliburton Energy Services, Inc. Orthoester compositions and methods for reducing the viscosified treatment fluids
US6645618B2 (en) 2001-06-15 2003-11-11 3M Innovative Properties Company Aliphatic polyester microfibers, microfibrillated articles and use thereof
DE60208609T2 (en) * 2001-08-01 2007-01-11 Fuji Photo Film Co., Ltd., Minami-Ashigara Biodegradable plastic part and process for its production
US6616748B2 (en) 2001-08-03 2003-09-09 Zo Resources, Llc High performance purified natural zeolite pigment for papermaking and paper coating
ES2295384T3 (en) * 2001-08-20 2008-04-16 Cargill Dow Llc METHOD TO PRODUCE SEMICRISTALINE POLI (LACTIC ACID) ITEMS.
JP4431390B2 (en) * 2001-09-28 2010-03-10 ビーエーエスエフ ソシエタス・ヨーロピア Biodegradable sustained release crop protection formulation
AU2002344595B2 (en) * 2001-11-01 2006-06-01 Asahi Kasei Life & Living Corporation Biaxially oriented polylactic acid-based resin films
US20030091760A1 (en) * 2001-11-09 2003-05-15 Cecile Drogou Adhesive for difficult to bond substrates
AU2002352955A1 (en) * 2001-11-27 2003-06-10 Accenture Llp Context sensitive advertisement delivery framework
US7267171B2 (en) * 2002-01-08 2007-09-11 Halliburton Energy Services, Inc. Methods and compositions for stabilizing the surface of a subterranean formation
US6962200B2 (en) * 2002-01-08 2005-11-08 Halliburton Energy Services, Inc. Methods and compositions for consolidating proppant in subterranean fractures
US7216711B2 (en) * 2002-01-08 2007-05-15 Halliburton Eenrgy Services, Inc. Methods of coating resin and blending resin-coated proppant
US7343973B2 (en) * 2002-01-08 2008-03-18 Halliburton Energy Services, Inc. Methods of stabilizing surfaces of subterranean formations
JP2003240955A (en) * 2002-02-21 2003-08-27 Konica Corp Optical film, polarizing plate, optical film roll, display device using optical film and method for manufacturing optical film
JP4179585B2 (en) * 2002-03-29 2008-11-12 ユニ・チャーム株式会社 Printed biodegradable plastic film
JP4199572B2 (en) * 2002-03-29 2008-12-17 三井化学株式会社 Lactic acid resin composition
DE10216834A1 (en) * 2002-04-16 2003-11-13 Fraunhofer Ges Forschung Process for producing melt-stable homo- and copolyesters of cyclic esters and / or diesters
JP4084953B2 (en) 2002-04-18 2008-04-30 日清紡績株式会社 Biodegradable plastic composition, molded product thereof, and biodegradation rate control method
US6691780B2 (en) 2002-04-18 2004-02-17 Halliburton Energy Services, Inc. Tracking of particulate flowback in subterranean wells
US6890649B2 (en) 2002-04-26 2005-05-10 3M Innovative Properties Company Aliphatic polyester microfibers, microfibrillated articles and use thereof
US7348052B2 (en) * 2002-05-07 2008-03-25 Coating Excellence International Sandwich wrappers, fast food wrappers, and gum wrappers comprising PLA resin
BR0311452A (en) 2002-05-30 2005-03-29 Cargill Dow Llc Processes and materials for the production of lactic acid in yeast
JP2003002984A (en) * 2002-06-14 2003-01-08 Mitsubishi Plastics Ind Ltd Polylactic acid film
JP3742842B2 (en) * 2002-06-17 2006-02-08 独立行政法人産業技術総合研究所 Biodegradable polylactic acid resin composition
US7300787B2 (en) * 2002-07-05 2007-11-27 Archer-Daniels-Midland Company Lactobacillus strains and use thereof in fermentation for L-lactic acid production
TW200403300A (en) * 2002-07-11 2004-03-01 Mitsubishi Plastics Inc Biodegradable laminate sheet and molded item from biodegradable laminate sheet
US20040024102A1 (en) * 2002-07-30 2004-02-05 Hayes Richard Allen Sulfonated aliphatic-aromatic polyetherester films, coatings, and laminates
AU2003257057B2 (en) * 2002-07-31 2008-09-25 Mast Biosurgery Ag Resorbable thin membranes
DK1539101T3 (en) * 2002-07-31 2009-04-27 Alza Corp Injectable, multi-modal polymeric compositions and applications thereof
US7670545B2 (en) * 2002-08-19 2010-03-02 Natureworks Llc Method for producing semicrystalline polylactic acid articles
US6705400B1 (en) * 2002-08-28 2004-03-16 Halliburton Energy Services, Inc. Methods and compositions for forming subterranean fractures containing resilient proppant packs
CA2765185A1 (en) * 2002-09-09 2004-03-18 Sony Corporation Resin composition
US7714054B2 (en) * 2002-10-24 2010-05-11 The University Of Akron Process for making strain-hardened polymer products
JP4245333B2 (en) * 2002-11-08 2009-03-25 日清紡績株式会社 Biodegradable plastic composition, molded product thereof, and biodegradation rate control method using the same
US6984439B2 (en) * 2002-11-12 2006-01-10 Kimberly-Clark Worldwide, Inc. Responsive film with corrugated microlayers having improved properties
US7303642B2 (en) * 2002-11-12 2007-12-04 Kimberly-Clark Worldwide, Inc. Methods of making responsive film with corrugated microlayers having improved properties
US7994078B2 (en) * 2002-12-23 2011-08-09 Kimberly-Clark Worldwide, Inc. High strength nonwoven web from a biodegradable aliphatic polyester
US7700500B2 (en) * 2002-12-23 2010-04-20 Kimberly-Clark Worldwide, Inc. Durable hydrophilic treatment for a biodegradable polymeric substrate
US20040211561A1 (en) * 2003-03-06 2004-10-28 Nguyen Philip D. Methods and compositions for consolidating proppant in fractures
US7114570B2 (en) * 2003-04-07 2006-10-03 Halliburton Energy Services, Inc. Methods and compositions for stabilizing unconsolidated subterranean formations
CN1320044C (en) 2003-04-25 2007-06-06 株式会社艾迪科 Polylactic acids compsns. make-up products and prepn. process thereof
US20050009687A1 (en) * 2003-05-02 2005-01-13 Verkade John G. Titanium alkoxide catalysts for polymerization of cyclic esters and methods of polymerization
JP3889376B2 (en) * 2003-05-16 2007-03-07 松下電器産業株式会社 Battery package and manufacturing method thereof
US6978836B2 (en) * 2003-05-23 2005-12-27 Halliburton Energy Services, Inc. Methods for controlling water and particulate production
US7413010B2 (en) * 2003-06-23 2008-08-19 Halliburton Energy Services, Inc. Remediation of subterranean formations using vibrational waves and consolidating agents
US7114560B2 (en) * 2003-06-23 2006-10-03 Halliburton Energy Services, Inc. Methods for enhancing treatment fluid placement in a subterranean formation
US20050130848A1 (en) * 2003-06-27 2005-06-16 Halliburton Energy Services, Inc. Compositions and methods for improving fracture conductivity in a subterranean well
US7178596B2 (en) 2003-06-27 2007-02-20 Halliburton Energy Services, Inc. Methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7044220B2 (en) * 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Compositions and methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7032663B2 (en) 2003-06-27 2006-04-25 Halliburton Energy Services, Inc. Permeable cement and sand control methods utilizing permeable cement in subterranean well bores
US7036587B2 (en) 2003-06-27 2006-05-02 Halliburton Energy Services, Inc. Methods of diverting treating fluids in subterranean zones and degradable diverting materials
US7044224B2 (en) 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Permeable cement and methods of fracturing utilizing permeable cement in subterranean well bores
US7228904B2 (en) 2003-06-27 2007-06-12 Halliburton Energy Services, Inc. Compositions and methods for improving fracture conductivity in a subterranean well
US7021379B2 (en) * 2003-07-07 2006-04-04 Halliburton Energy Services, Inc. Methods and compositions for enhancing consolidation strength of proppant in subterranean fractures
US7104325B2 (en) * 2003-07-09 2006-09-12 Halliburton Energy Services, Inc. Methods of consolidating subterranean zones and compositions therefor
US20050028976A1 (en) * 2003-08-05 2005-02-10 Nguyen Philip D. Compositions and methods for controlling the release of chemicals placed on particulates
US8541051B2 (en) 2003-08-14 2013-09-24 Halliburton Energy Services, Inc. On-the fly coating of acid-releasing degradable material onto a particulate
US7497278B2 (en) 2003-08-14 2009-03-03 Halliburton Energy Services, Inc. Methods of degrading filter cakes in a subterranean formation
US7179952B2 (en) * 2003-08-25 2007-02-20 Kimberly-Clark Worldwide, Inc. Absorbent article formed with microlayered films
US7156194B2 (en) * 2003-08-26 2007-01-02 Halliburton Energy Services, Inc. Methods of drilling and consolidating subterranean formation particulate
US7237609B2 (en) * 2003-08-26 2007-07-03 Halliburton Energy Services, Inc. Methods for producing fluids from acidized and consolidated portions of subterranean formations
US7059406B2 (en) * 2003-08-26 2006-06-13 Halliburton Energy Services, Inc. Production-enhancing completion methods
US7017665B2 (en) * 2003-08-26 2006-03-28 Halliburton Energy Services, Inc. Strengthening near well bore subterranean formations
US6997259B2 (en) 2003-09-05 2006-02-14 Halliburton Energy Services, Inc. Methods for forming a permeable and stable mass in a subterranean formation
US7032667B2 (en) * 2003-09-10 2006-04-25 Halliburtonn Energy Services, Inc. Methods for enhancing the consolidation strength of resin coated particulates
US7021377B2 (en) * 2003-09-11 2006-04-04 Halliburton Energy Services, Inc. Methods of removing filter cake from well producing zones
US7833944B2 (en) 2003-09-17 2010-11-16 Halliburton Energy Services, Inc. Methods and compositions using crosslinked aliphatic polyesters in well bore applications
US7829507B2 (en) * 2003-09-17 2010-11-09 Halliburton Energy Services Inc. Subterranean treatment fluids comprising a degradable bridging agent and methods of treating subterranean formations
US7674753B2 (en) 2003-09-17 2010-03-09 Halliburton Energy Services, Inc. Treatment fluids and methods of forming degradable filter cakes comprising aliphatic polyester and their use in subterranean formations
US7345011B2 (en) * 2003-10-14 2008-03-18 Halliburton Energy Services, Inc. Methods for mitigating the production of water from subterranean formations
US20050089631A1 (en) * 2003-10-22 2005-04-28 Nguyen Philip D. Methods for reducing particulate density and methods of using reduced-density particulates
US20070030574A1 (en) * 2003-10-27 2007-02-08 Takayuki Watanabe Reflective film
US7063150B2 (en) * 2003-11-25 2006-06-20 Halliburton Energy Services, Inc. Methods for preparing slurries of coated particulates
US7195068B2 (en) 2003-12-15 2007-03-27 Halliburton Energy Services, Inc. Filter cake degradation compositions and methods of use in subterranean operations
US20050136155A1 (en) * 2003-12-22 2005-06-23 Jordan Joy F. Specialty beverage infusion package
US20050145385A1 (en) * 2004-01-05 2005-07-07 Nguyen Philip D. Methods of well stimulation and completion
US20070007009A1 (en) * 2004-01-05 2007-01-11 Halliburton Energy Services, Inc. Methods of well stimulation and completion
US7131493B2 (en) * 2004-01-16 2006-11-07 Halliburton Energy Services, Inc. Methods of using sealants in multilateral junctions
US7096947B2 (en) 2004-01-27 2006-08-29 Halliburton Energy Services, Inc. Fluid loss control additives for use in fracturing subterranean formations
US7036586B2 (en) 2004-01-30 2006-05-02 Halliburton Energy Services, Inc. Methods of cementing in subterranean formations using crack resistant cement compositions
US7156174B2 (en) 2004-01-30 2007-01-02 Halliburton Energy Services, Inc. Contained micro-particles for use in well bore operations
US7204312B2 (en) 2004-01-30 2007-04-17 Halliburton Energy Services, Inc. Compositions and methods for the delivery of chemical components in subterranean well bores
US7888405B2 (en) 2004-01-30 2011-02-15 E. I. Du Pont De Nemours And Company Aliphatic-aromatic polyesters, and articles made therefrom
US20050173116A1 (en) * 2004-02-10 2005-08-11 Nguyen Philip D. Resin compositions and methods of using resin compositions to control proppant flow-back
US7326659B2 (en) * 2004-02-16 2008-02-05 Conwed Plastics Llc Biodegradable netting
US7393590B2 (en) * 2004-02-27 2008-07-01 Cereplast, Inc. Biodegradable poly(lactic acid) polymer composition and films, coatings and products comprising Biodegradable poly(lactic acid) polymer compositions
US7211547B2 (en) * 2004-03-03 2007-05-01 Halliburton Energy Services, Inc. Resin compositions and methods of using such resin compositions in subterranean applications
US20050194142A1 (en) * 2004-03-05 2005-09-08 Nguyen Philip D. Compositions and methods for controlling unconsolidated particulates
US7063151B2 (en) * 2004-03-05 2006-06-20 Halliburton Energy Services, Inc. Methods of preparing and using coated particulates
US20070172651A1 (en) * 2004-03-16 2007-07-26 Takanori Miyoshi Ultrafine polyactic acid fibers and fiber structure, and process for their production
FR2867698B1 (en) 2004-03-16 2007-11-16 Beaufour Ipsen S C R A S CATALYTIC SYSTEM FOR (CO) OLIGOMERIZATION OF LACTIDE AND GLYCOLIDE
US7172022B2 (en) * 2004-03-17 2007-02-06 Halliburton Energy Services, Inc. Cement compositions containing degradable materials and methods of cementing in subterranean formations
JP4498783B2 (en) * 2004-03-17 2010-07-07 トヨタ紡織株式会社 Method for producing wooden molded body
US6962871B2 (en) * 2004-03-31 2005-11-08 Dielectric Systems, Inc. Composite polymer dielectric film
US7309395B2 (en) 2004-03-31 2007-12-18 Dielectric Systems, Inc. System for forming composite polymer dielectric film
US7094661B2 (en) * 2004-03-31 2006-08-22 Dielectric Systems, Inc. Single and dual damascene techniques utilizing composite polymer dielectric film
PL1732756T3 (en) * 2004-04-05 2011-04-29 Leucadia Inc Degradable netting
US20070078063A1 (en) * 2004-04-26 2007-04-05 Halliburton Energy Services, Inc. Subterranean treatment fluids and methods of treating subterranean formations
WO2005105908A1 (en) * 2004-04-28 2005-11-10 Keio University Method of depolymerizing polymer having ester bond in main chain and process for producing polymer having ester bond in main chain from depolymerization product
US20050250931A1 (en) * 2004-05-05 2005-11-10 Mitsubishi Plastics, Inc. Shredder dust for recycling, molding for shredder dust and a method for recovering lactide from the shredder dust as well as molding formed from the lactide
CA2569099C (en) * 2004-05-07 2011-07-12 Marc S. Theisen Composite fiber environmental filtration media containing flocculant
US20060201426A1 (en) * 2004-05-25 2006-09-14 Lee Chung J Reactor for Producing Reactive Intermediates for Transport Polymerization
US20050263283A1 (en) * 2004-05-25 2005-12-01 Nguyen Philip D Methods for stabilizing and stimulating wells in unconsolidated subterranean formations
US7541318B2 (en) * 2004-05-26 2009-06-02 Halliburton Energy Services, Inc. On-the-fly preparation of proppant and its use in subterranean operations
US7299875B2 (en) 2004-06-08 2007-11-27 Halliburton Energy Services, Inc. Methods for controlling particulate migration
US7073581B2 (en) * 2004-06-15 2006-07-11 Halliburton Energy Services, Inc. Electroconductive proppant compositions and related methods
JP2006001574A (en) * 2004-06-16 2006-01-05 Matsushita Electric Ind Co Ltd Battery package and its manufacturing method
US7144972B2 (en) * 2004-07-09 2006-12-05 E. I. Du Pont De Nemours And Company Copolyetherester compositions containing hydroxyalkanoic acids and shaped articles produced therefrom
US7193029B2 (en) * 2004-07-09 2007-03-20 E. I. Du Pont De Nemours And Company Sulfonated copolyetherester compositions from hydroxyalkanoic acids and shaped articles produced therefrom
US7358325B2 (en) * 2004-07-09 2008-04-15 E. I. Du Pont De Nemours And Company Sulfonated aromatic copolyesters containing hydroxyalkanoic acid groups and shaped articles produced therefrom
US7547665B2 (en) 2005-04-29 2009-06-16 Halliburton Energy Services, Inc. Acidic treatment fluids comprising scleroglucan and/or diutan and associated methods
US7621334B2 (en) 2005-04-29 2009-11-24 Halliburton Energy Services, Inc. Acidic treatment fluids comprising scleroglucan and/or diutan and associated methods
US7475728B2 (en) 2004-07-23 2009-01-13 Halliburton Energy Services, Inc. Treatment fluids and methods of use in subterranean formations
US8980300B2 (en) 2004-08-05 2015-03-17 Advanced Cardiovascular Systems, Inc. Plasticizers for coating compositions
US20060032633A1 (en) * 2004-08-10 2006-02-16 Nguyen Philip D Methods and compositions for carrier fluids comprising water-absorbent fibers
US20060046044A1 (en) * 2004-08-24 2006-03-02 Lee Chung J Porous composite polymer dielectric film
US8133558B2 (en) * 2004-08-30 2012-03-13 Plastics Suppliers, Inc. Polylactic acid blown film and method of manufacturing same
US20060046938A1 (en) * 2004-09-02 2006-03-02 Harris Philip C Methods and compositions for delinking crosslinked fluids
JP4640765B2 (en) 2004-09-03 2011-03-02 株式会社Ａｄｅｋａ Polylactic acid-based resin composition, molded article and method for producing the same
US7299869B2 (en) 2004-09-03 2007-11-27 Halliburton Energy Services, Inc. Carbon foam particulates and methods of using carbon foam particulates in subterranean applications
US7281580B2 (en) * 2004-09-09 2007-10-16 Halliburton Energy Services, Inc. High porosity fractures and methods of creating high porosity fractures
US7413017B2 (en) 2004-09-24 2008-08-19 Halliburton Energy Services, Inc. Methods and compositions for inducing tip screenouts in frac-packing operations
US7416767B2 (en) * 2004-09-30 2008-08-26 Graphic Packaging International, Inc. Anti-blocking coatings for PVdc-coated substrates
US7404999B2 (en) * 2004-09-30 2008-07-29 Graphic Packaging International, Inc. Anti-blocking barrier composite
US7757768B2 (en) 2004-10-08 2010-07-20 Halliburton Energy Services, Inc. Method and composition for enhancing coverage and displacement of treatment fluids into subterranean formations
US7648946B2 (en) 2004-11-17 2010-01-19 Halliburton Energy Services, Inc. Methods of degrading filter cakes in subterranean formations
US7553800B2 (en) 2004-11-17 2009-06-30 Halliburton Energy Services, Inc. In-situ filter cake degradation compositions and methods of use in subterranean formations
JP2006143932A (en) * 2004-11-22 2006-06-08 Mitsubishi Chemicals Corp Aliphatic or alicyclic polyester resin composition
US7281581B2 (en) * 2004-12-01 2007-10-16 Halliburton Energy Services, Inc. Methods of hydraulic fracturing and of propping fractures in subterranean formations
US7273099B2 (en) * 2004-12-03 2007-09-25 Halliburton Energy Services, Inc. Methods of stimulating a subterranean formation comprising multiple production intervals
US7398825B2 (en) * 2004-12-03 2008-07-15 Halliburton Energy Services, Inc. Methods of controlling sand and water production in subterranean zones
US7883740B2 (en) 2004-12-12 2011-02-08 Halliburton Energy Services, Inc. Low-quality particulates and methods of making and using improved low-quality particulates
JP4326575B2 (en) 2004-12-17 2009-09-09 デブゲン・エヌ・ブイ Nematicidal composition
US20060159918A1 (en) * 2004-12-22 2006-07-20 Fiber Innovation Technology, Inc. Biodegradable fibers exhibiting storage-stable tenacity
US7334635B2 (en) * 2005-01-14 2008-02-26 Halliburton Energy Services, Inc. Methods for fracturing subterranean wells
US8030249B2 (en) 2005-01-28 2011-10-04 Halliburton Energy Services, Inc. Methods and compositions relating to the hydrolysis of water-hydrolysable materials
US20060169182A1 (en) 2005-01-28 2006-08-03 Halliburton Energy Services, Inc. Methods and compositions relating to the hydrolysis of water-hydrolysable materials
US7267170B2 (en) 2005-01-31 2007-09-11 Halliburton Energy Services, Inc. Self-degrading fibers and associated methods of use and manufacture
US20080009423A1 (en) 2005-01-31 2008-01-10 Halliburton Energy Services, Inc. Self-degrading fibers and associated methods of use and manufacture
US7353876B2 (en) 2005-02-01 2008-04-08 Halliburton Energy Services, Inc. Self-degrading cement compositions and methods of using self-degrading cement compositions in subterranean formations
US7497258B2 (en) * 2005-02-01 2009-03-03 Halliburton Energy Services, Inc. Methods of isolating zones in subterranean formations using self-degrading cement compositions
US20060169448A1 (en) * 2005-02-01 2006-08-03 Halliburton Energy Services, Inc. Self-degrading cement compositions and methods of using self-degrading cement compositions in subterranean formations
US20070298977A1 (en) * 2005-02-02 2007-12-27 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US20060172895A1 (en) * 2005-02-02 2006-08-03 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US8598092B2 (en) 2005-02-02 2013-12-03 Halliburton Energy Services, Inc. Methods of preparing degradable materials and methods of use in subterranean formations
US20060172894A1 (en) * 2005-02-02 2006-08-03 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US7334636B2 (en) * 2005-02-08 2008-02-26 Halliburton Energy Services, Inc. Methods of creating high-porosity propped fractures using reticulated foam
US7506689B2 (en) 2005-02-22 2009-03-24 Halliburton Energy Services, Inc. Fracturing fluids comprising degradable diverting agents and methods of use in subterranean formations
US7216705B2 (en) 2005-02-22 2007-05-15 Halliburton Energy Services, Inc. Methods of placing treatment chemicals
US7318473B2 (en) * 2005-03-07 2008-01-15 Halliburton Energy Services, Inc. Methods relating to maintaining the structural integrity of deviated well bores
US7673686B2 (en) 2005-03-29 2010-03-09 Halliburton Energy Services, Inc. Method of stabilizing unconsolidated formation for sand control
US7448451B2 (en) * 2005-03-29 2008-11-11 Halliburton Energy Services, Inc. Methods for controlling migration of particulates in a subterranean formation
US20060240995A1 (en) * 2005-04-23 2006-10-26 Halliburton Energy Services, Inc. Methods of using resins in subterranean formations
JP4605084B2 (en) * 2005-04-26 2011-01-05 東レ株式会社 Polylactic acid molded products
US8778375B2 (en) * 2005-04-29 2014-07-15 Advanced Cardiovascular Systems, Inc. Amorphous poly(D,L-lactide) coating
JP5289674B2 (en) * 2005-12-12 2013-09-11 三菱樹脂株式会社 Heat-shrinkable film, heat-shrink label using the film, molded product, and container
US8470420B2 (en) * 2005-05-11 2013-06-25 Mitsubishi Plastics, Inc. Heat-shrinkable film, moldings and heat-shrinkable labels made using the heat-shrinkable film, and containers made by using the moldings or fitted with the labels
US7662753B2 (en) 2005-05-12 2010-02-16 Halliburton Energy Services, Inc. Degradable surfactants and methods for use
US7608567B2 (en) 2005-05-12 2009-10-27 Halliburton Energy Services, Inc. Degradable surfactants and methods for use
US7677315B2 (en) 2005-05-12 2010-03-16 Halliburton Energy Services, Inc. Degradable surfactants and methods for use
WO2006127698A2 (en) * 2005-05-26 2006-11-30 Gala Industries, Inc. Method and apparatus for making crystalline polymeric pellets and granules
US9032641B2 (en) 2005-05-26 2015-05-19 Gala Industries, Inc. Method and apparatus for making crystalline polymeric pellets and granules
US20060276092A1 (en) * 2005-06-01 2006-12-07 Topolkaraev Vasily A Fibers and nonwovens with improved properties
US20060275547A1 (en) * 2005-06-01 2006-12-07 Lee Chung J Vapor Phase Deposition System and Method
US7780903B2 (en) * 2005-06-01 2010-08-24 Kimberly-Clark Worldwide, Inc. Method of making fibers and nonwovens with improved properties
US20060274474A1 (en) * 2005-06-01 2006-12-07 Lee Chung J Substrate Holder
US20060276345A1 (en) * 2005-06-07 2006-12-07 Halliburton Energy Servicers, Inc. Methods controlling the degradation rate of hydrolytically degradable materials
US7318474B2 (en) 2005-07-11 2008-01-15 Halliburton Energy Services, Inc. Methods and compositions for controlling formation fines and reducing proppant flow-back
US20070014955A1 (en) * 2005-07-14 2007-01-18 Green Bay Packaging Inc. Printable polylactide film material, methods and labels made therefrom
DE102005033101A1 (en) * 2005-07-15 2007-01-25 Boehringer Ingelheim Pharma Gmbh & Co. Kg Resorbable polyether esters and their use for the manufacture of medical implants
US8394446B2 (en) 2005-07-25 2013-03-12 Abbott Cardiovascular Systems Inc. Methods of providing antioxidants to implantable medical devices
US7785647B2 (en) * 2005-07-25 2010-08-31 Advanced Cardiovascular Systems, Inc. Methods of providing antioxidants to a drug containing product
US7484564B2 (en) * 2005-08-16 2009-02-03 Halliburton Energy Services, Inc. Delayed tackifying compositions and associated methods involving controlling particulate migration
US7595280B2 (en) 2005-08-16 2009-09-29 Halliburton Energy Services, Inc. Delayed tackifying compositions and associated methods involving controlling particulate migration
US20070049888A1 (en) * 2005-08-31 2007-03-01 Soerens Dave A Absorbent core comprising a multi-microlayer film
US20070049501A1 (en) * 2005-09-01 2007-03-01 Halliburton Energy Services, Inc. Fluid-loss control pills comprising breakers that comprise orthoesters and/or poly(orthoesters) and methods of use
US7713916B2 (en) 2005-09-22 2010-05-11 Halliburton Energy Services, Inc. Orthoester-based surfactants and associated methods
US20070071963A1 (en) * 2005-09-27 2007-03-29 L&L Products, Inc. Design system
JP2009510212A (en) * 2005-09-28 2009-03-12 テート アンド ライル パブリック リミテッド カンパニー A new method for the preparation of polylactic acid
KR20080064170A (en) * 2005-10-21 2008-07-08 클렘슨 유니버시티 Composite polymeric materials from renewable resources
US7461697B2 (en) 2005-11-21 2008-12-09 Halliburton Energy Services, Inc. Methods of modifying particulate surfaces to affect acidic sites thereon
US20070114032A1 (en) * 2005-11-22 2007-05-24 Stegent Neil A Methods of consolidating unconsolidated particulates in subterranean formations
TWI370151B (en) * 2005-11-30 2012-08-11 Toray Industries Polylactic acid-based resin laminated sheet and article formed from the same
TWI411535B (en) * 2005-11-30 2013-10-11 Mitsubishi Plastics Inc Polyolefin-based heat-shrinkable film, molded article using the film, heat-shrinkable label, and container
EP1984009B1 (en) 2006-01-18 2012-10-24 Qps, Llc Pharmaceutical compositions with enhanced stability
US20070173416A1 (en) * 2006-01-20 2007-07-26 Halliburton Energy Services, Inc. Well treatment compositions for use in acidizing a well
US8613320B2 (en) 2006-02-10 2013-12-24 Halliburton Energy Services, Inc. Compositions and applications of resins in treating subterranean formations
US20080006405A1 (en) * 2006-07-06 2008-01-10 Halliburton Energy Services, Inc. Methods and compositions for enhancing proppant pack conductivity and strength
US7926591B2 (en) 2006-02-10 2011-04-19 Halliburton Energy Services, Inc. Aqueous-based emulsified consolidating agents suitable for use in drill-in applications
US7819192B2 (en) 2006-02-10 2010-10-26 Halliburton Energy Services, Inc. Consolidating agent emulsions and associated methods
US7665517B2 (en) 2006-02-15 2010-02-23 Halliburton Energy Services, Inc. Methods of cleaning sand control screens and gravel packs
US7407010B2 (en) * 2006-03-16 2008-08-05 Halliburton Energy Services, Inc. Methods of coating particulates
US20070238384A1 (en) * 2006-03-20 2007-10-11 Ming Tang Articles, operating room drapes and methods of making and using the same
US7237610B1 (en) 2006-03-30 2007-07-03 Halliburton Energy Services, Inc. Degradable particulates as friction reducers for the flow of solid particulates and associated methods of use
US7608566B2 (en) 2006-03-30 2009-10-27 Halliburton Energy Services, Inc. Degradable particulates as friction reducers for the flow of solid particulates and associated methods of use
DE202007018690U1 (en) 2006-04-14 2009-02-19 Bio-Tec Biologische Naturverpackungen Gmbh & Co.Kg Multilayer film
DE102006024568A1 (en) * 2006-05-23 2007-12-06 Huhtamaki Forchheim Zweigniederlassung Der Huhtamaki Deutschland Gmbh & Co. Kg Process for producing a biodegradable plastic film and film
US20070292691A1 (en) * 2006-06-19 2007-12-20 C.J. Multi-Tech Enterprises, Inc. Compostable reinforced paper, method of making same
US7943566B2 (en) * 2006-06-21 2011-05-17 Wausau Paper Mills, Llc Dryer sheet and methods for manufacturing and using a dryer sheet
US7500521B2 (en) * 2006-07-06 2009-03-10 Halliburton Energy Services, Inc. Methods of enhancing uniform placement of a resin in a subterranean formation
US8710172B2 (en) * 2006-07-14 2014-04-29 Kimberly-Clark Worldwide, Inc. Biodegradable aliphatic-aromatic copolyester for use in nonwoven webs
KR101297865B1 (en) * 2006-07-14 2013-08-19 킴벌리-클라크 월드와이드, 인크. Biodegradable polylactic acid for use in nonwoven webs
KR101297937B1 (en) 2006-07-14 2013-08-19 킴벌리-클라크 월드와이드, 인크. Biodegradable aliphatic polyester for use in nonwoven webs
WO2008011615A2 (en) 2006-07-20 2008-01-24 Orbusneich Medical, Inc. Bioabsorbable polymeric composition for a medical device
US8329621B2 (en) 2006-07-25 2012-12-11 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US20080026960A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US20080026959A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US20080026955A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US7678743B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7678742B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7687438B2 (en) 2006-09-20 2010-03-30 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
EP2065185A4 (en) * 2006-09-21 2014-12-24 Asahi Kasei Chemicals Corp Adhesive wrap film
US7947644B2 (en) * 2006-09-26 2011-05-24 Wausau Paper Mills, Llc Dryer sheet and methods for manufacturing and using a dryer sheet
US20080076313A1 (en) * 2006-09-26 2008-03-27 David Uitenbroek Wipe and methods for manufacturing and using a wipe
US20080076314A1 (en) * 2006-09-26 2008-03-27 John James Blanz Wipe and methods for manufacturing and using a wipe
US7455112B2 (en) 2006-09-29 2008-11-25 Halliburton Energy Services, Inc. Methods and compositions relating to the control of the rates of acid-generating compounds in acidizing operations
US8076448B2 (en) * 2006-10-11 2011-12-13 Tolmar Therapeutics, Inc. Preparation of biodegradable polyesters with low-burst properties by supercritical fluid extraction
SI2079767T1 (en) * 2006-10-11 2015-01-30 Tolmar Therapeutics, Inc. Preparation of biodegradable polyesters with low-burst properties by supercritical fluid extraction
US7385020B2 (en) 2006-10-13 2008-06-10 3M Innovative Properties Company 2-octyl (meth)acrylate adhesive composition
US7959942B2 (en) 2006-10-20 2011-06-14 Orbusneich Medical, Inc. Bioabsorbable medical device with coating
CN101631513B (en) 2006-10-20 2013-06-05 奥巴斯尼茨医学公司 Bioabsorbable polymeric composition and medical device
US7686080B2 (en) 2006-11-09 2010-03-30 Halliburton Energy Services, Inc. Acid-generating fluid loss control additives and associated methods
US20080200890A1 (en) * 2006-12-11 2008-08-21 3M Innovative Properties Company Antimicrobial disposable absorbent articles
US9555167B2 (en) 2006-12-11 2017-01-31 3M Innovative Properties Company Biocompatible antimicrobial compositions
JP2010513594A (en) * 2006-12-15 2010-04-30 キンバリー クラーク ワールドワイド インコーポレイテッド Biodegradable polyester used for fiber formation
BRPI0622175A2 (en) * 2006-12-15 2011-12-27 Kimberly Clark Co Biodegradable polylactic acids for use in fiber formation
US8220548B2 (en) 2007-01-12 2012-07-17 Halliburton Energy Services Inc. Surfactant wash treatment fluids and associated methods
US8552111B2 (en) * 2007-01-12 2013-10-08 Kittrich Corporation Environmentally friendly polymeric textile coating
US20080188154A1 (en) * 2007-02-06 2008-08-07 Jen-Coat, Inc. Film laminate
JP5493355B2 (en) * 2007-03-16 2014-05-14 東レ株式会社 Aliphatic polyester sheet and molded article comprising the same
US20080268018A1 (en) * 2007-04-30 2008-10-30 Pacetti Stephen D Method for forming crystallized therapeutic agents on a medical device
WO2008141265A1 (en) * 2007-05-16 2008-11-20 Natureworks Llc Method for stabilizing polymers containing repeating lactic acid units, and stabilized polymers so made
US8147769B1 (en) 2007-05-16 2012-04-03 Abbott Cardiovascular Systems Inc. Stent and delivery system with reduced chemical degradation
MX2010002031A (en) * 2007-08-22 2010-03-15 Kimberly Clark Co Multicomponent biodegradable filaments and nonwoven webs formed therefrom.
US20090062157A1 (en) * 2007-08-30 2009-03-05 Halliburton Energy Services, Inc. Methods and compositions related to the degradation of degradable polymers involving dehydrated salts and other associated methods
US20090112259A1 (en) * 2007-10-31 2009-04-30 Angiotech Pharmaceuticals, Inc. Recombinant expressed bioadsorbable polyhydroxyalkonate monofilament and multi-filaments self-retaining sutures
AT506038B1 (en) 2007-11-14 2015-02-15 Jungbunzlauer Austria Ag METHOD FOR THE PRODUCTION OF CYCLIC DIESTERS OF L, D AND D, L-MILKYLIC ACID
US20090148715A1 (en) * 2007-12-11 2009-06-11 Toray Plastics (America), Inc. Process to produce biaxially oriented polylactic acid film at high transverse orientation rates
CN101896649B (en) * 2007-12-13 2012-07-18 金伯利-克拉克环球有限公司 Biodegradable fibers formed from a thermoplastic composition containing polylactic acid and a polyether copolymer
AU2008347720C1 (en) * 2007-12-31 2012-01-19 Samyang Holdings Corporation Highly pure amphiphilic copolymer comprising hydrophobic block from alpha-hydroxy acid and process for the preparation thereof
US20090197780A1 (en) * 2008-02-01 2009-08-06 Weaver Jimmie D Ultrafine Grinding of Soft Materials
EP2249712B8 (en) 2008-02-21 2018-12-26 Ethicon LLC Method and apparatus for elevating retainers on self-retaining sutures
US8377116B2 (en) * 2008-03-20 2013-02-19 Abbott Cardiovascular Systems Inc. Implantable medical device coatings with improved mechanical stability
US20090247710A1 (en) * 2008-03-31 2009-10-01 Purac Biochem B.V. Method for manufacturing stable polylactide
US8006760B2 (en) 2008-04-10 2011-08-30 Halliburton Energy Services, Inc. Clean fluid systems for partial monolayer fracturing
US20100151241A1 (en) * 2008-04-14 2010-06-17 3M Innovative Properties Company 2-Octyl (Meth)acrylate Adhesive Composition
US20090263458A1 (en) * 2008-04-21 2009-10-22 Lasse Daniel Efskind Material for surgical use in traumatology
US7906464B2 (en) 2008-05-13 2011-03-15 Halliburton Energy Services, Inc. Compositions and methods for the removal of oil-based filtercakes
BRPI0822434B1 (en) * 2008-05-30 2018-05-29 Kimberly-Clark Worldwide, Inc. Nonwoven weft, absorbent article and method for forming nonwoven weft
AU2009257365A1 (en) * 2008-06-12 2009-12-17 3M Innovative Properties Company Melt blown fine fibers and methods of manufacture
US8858986B2 (en) 2008-06-12 2014-10-14 3M Innovative Properties Company Biocompatible hydrophilic compositions
US8911870B2 (en) * 2008-06-13 2014-12-16 Toray Plastics (America), Inc. Method to produce matte and opaque biaxially oriented polylactic acid film
US20090319031A1 (en) * 2008-06-19 2009-12-24 Yunbing Wang Bioabsorbable Polymeric Stent With Improved Structural And Molecular Weight Integrity
FR2932797B1 (en) * 2008-06-20 2011-07-01 Colas Sa USE OF A BIOPOLYMER BINDER IN ROAD, PARAROUTIER OR CIVIL ENGINEERED APPLICATIONS.
EP2323788B1 (en) * 2008-08-15 2014-07-30 Toray Plastics (America) , Inc. Biaxially oriented polylactic acid film with high barrier
JP5077170B2 (en) * 2008-09-22 2012-11-21 株式会社日立プラントテクノロジー Process for producing polyhydroxycarboxylic acid
US7833943B2 (en) 2008-09-26 2010-11-16 Halliburton Energy Services Inc. Microemulsifiers and methods of making and using same
CN102272193A (en) * 2008-11-07 2011-12-07 高露洁-棕榄公司 Blends of polylactic acid and thermo-plastic polymers for packaging applications
US20100120308A1 (en) * 2008-11-13 2010-05-13 Conwed Plastics Llc Oxo-biodegradable netting
US8016980B2 (en) * 2008-11-25 2011-09-13 Dixie Consumer Products Llc Paper products
US20110256338A1 (en) 2008-12-29 2011-10-20 Ausen Ronald W Films having structured surface and methods for making the same
US20100167074A1 (en) * 2008-12-30 2010-07-01 Bunnelle William L Adhesive for difficult to adhere polymer coated board stock
BE1019313A3 (en) 2009-01-12 2012-06-05 Futerro Sa CATALYTIC SYSTEMS FOR POLYMERIZATION OF CYCLIC ESTERS.
WO2010085608A1 (en) * 2009-01-23 2010-07-29 Surmodics Pharmaceuticals, Inc. Polymer mixtures comprising polymers having different non-repeating units and methods for making and using same
WO2010090496A2 (en) 2009-02-09 2010-08-12 주식회사 엘지화학 Polylactide resin and preparation method thereof
TW201031524A (en) * 2009-02-16 2010-09-01 Wei Mon Ind Co Ltd Paperboard with polylactic acid
US20100212906A1 (en) * 2009-02-20 2010-08-26 Halliburton Energy Services, Inc. Method for diversion of hydraulic fracture treatments
US7998910B2 (en) 2009-02-24 2011-08-16 Halliburton Energy Services, Inc. Treatment fluids comprising relative permeability modifiers and methods of use
EP2406245B1 (en) 2009-03-13 2014-01-08 NatureWorks LLC Recovery of lactic acid values from a meso-lactide stream
US9035076B2 (en) 2009-03-13 2015-05-19 Natureworks Llc Recovery of lactic acid values from a meso-lactide stream
EP2406246B1 (en) 2009-03-13 2018-08-15 NatureWorks LLC Methods for producing lactide with recycle of meso-lactide
JP5711211B2 (en) 2009-03-31 2015-04-30 スリーエム イノベイティブ プロパティズ カンパニー Dimensionally stable nonwoven fibrous web and methods for making and using the same
JP5340818B2 (en) * 2009-06-15 2013-11-13 ユニチカ株式会社 Acid end-capped polylactic acid and method for producing the same
US9150004B2 (en) * 2009-06-19 2015-10-06 Toray Plastics (America), Inc. Biaxially oriented polylactic acid film with improved heat seal properties
US20100330382A1 (en) * 2009-06-26 2010-12-30 Toray Plastics (America), Inc. Biaxially oriented polylactic acid film with improved moisture barrier
JP5577764B2 (en) * 2009-07-06 2014-08-27 株式会社リコー Copolymer resin composition, molded article, and method for producing copolymer resin composition
US8082992B2 (en) 2009-07-13 2011-12-27 Halliburton Energy Services, Inc. Methods of fluid-controlled geometry stimulation
US8889823B2 (en) 2009-07-21 2014-11-18 Abbott Cardiovascular Systems Inc. Method to make poly(L-lactide) stent with tunable degradation rate
US9889238B2 (en) * 2009-07-21 2018-02-13 Abbott Cardiovascular Systems Inc. Biodegradable stent with adjustable degradation rate
US20110052847A1 (en) * 2009-08-27 2011-03-03 Roberts Danny H Articles of manufacture from renewable resources
US9221213B2 (en) 2009-09-25 2015-12-29 Toray Plastics (America), Inc. Multi-layer high moisture barrier polylactic acid film
EP2480710B1 (en) 2009-09-25 2018-01-24 Toray Plastics (America) , Inc. Multi-layer high moisture barrier polylactic acid film and its method of forming
BR112012011080A2 (en) 2009-11-10 2016-07-05 3M Innovative Properties Co method for the production of polylactide films.
TWI445606B (en) * 2009-12-02 2014-07-21 Chi Mei Corp Preparation of bead-like particles of lactic acid polymers
BE1019059A3 (en) 2009-12-03 2012-02-07 Futerro Sa METHOD FOR MASS POLYMERIZATION OF LACTIDE
CN102762370B (en) 2009-12-17 2015-11-25 3M创新有限公司 Non woven fibre web of dimensionally stable and production and preparation method thereof
MX2012007090A (en) 2009-12-17 2012-07-20 3M Innovative Properties Co Dimensionally stable nonwoven fibrous webs, melt blown fine fibers, and methods of making and using the same.
RU2478107C2 (en) * 2009-12-25 2013-03-27 Государственное образовательное учреждение высшего профессионального образования Российский химико-технологический университет им. Д.И. Менделеева (РХТУ им. Д.И. Менделеева) Method of producing biodegradable polymer
EP2539496B1 (en) 2010-02-23 2016-02-10 3M Innovative Properties Company Dimensionally stable nonwoven fibrous webs and methods of making and using the same
WO2011116122A1 (en) * 2010-03-16 2011-09-22 Andersen Corporation Sustainable compositions, related methods, and members formed therefrom
US20110319509A1 (en) * 2010-03-23 2011-12-29 Polynew, Inc. Polymer composites incorporating stereocomplexation
WO2011117308A1 (en) 2010-03-24 2011-09-29 Basf Se Process for producing aqueous dispersions of thermoplastic polyesters
US8604101B2 (en) * 2010-03-24 2013-12-10 Basf Se Process for producing aqueous dispersions of thermoplastic polyesters
JP5726078B2 (en) * 2010-03-30 2015-05-27 日東電工株式会社 Polylactic acid film or sheet and method for producing the same
US9492962B2 (en) 2010-03-31 2016-11-15 Toray Plastics (America), Inc. Biaxially oriented polylactic acid film with reduced noise level and improved moisture barrier
EP2552689B1 (en) 2010-03-31 2017-10-25 Toray Plastics (America) , Inc. Biaxially oriented polyactic acid film with reduced noise level
ES2645716T5 (en) 2010-06-21 2021-06-07 Lg Chemical Ltd Exceptionally heat resistant polylactide resin and method for its production
TW201221714A (en) 2010-10-14 2012-06-01 3M Innovative Properties Co Dimensionally stable nonwoven fibrous webs and methods of making and using the same
US8461262B2 (en) 2010-12-07 2013-06-11 Kimberly-Clark Worldwide, Inc. Polylactic acid fibers
GB2524906B8 (en) 2011-04-07 2016-12-07 Virdia Ltd Lignocellulose conversion processes and products
WO2012144511A1 (en) * 2011-04-22 2012-10-26 株式会社クレハ Biodegradable aliphatic polyester particles, and process for producing same
US8709070B2 (en) 2011-05-10 2014-04-29 Abbott Cardiovascular Systems Inc. Bioabsorbable scaffold with particles providing delayed acceleration of degradation
WO2013041649A1 (en) 2011-09-23 2013-03-28 Basf Se Use of an aqueous dispersion of biodegradable polyesters
CN104395388A (en) 2012-02-17 2015-03-04 安德森公司 Polylactic acid containing building component
US9493851B2 (en) 2012-05-03 2016-11-15 Virdia, Inc. Methods for treating lignocellulosic materials
CN104672468B (en) 2012-05-03 2019-09-10 威尔迪亚公司 Method for handling ligno-cellulosic materials
FR2991230B1 (en) * 2012-05-31 2015-02-20 Ahlstroem Oy MULTILAYER COMPLEX COMPRISING A LAYER BASED ON A BIODEGRADABLE POLYMER AND A SUPPORT BASED ON CELLULOSIC FIBERS; METHOD OF MANUFACTURE AND USE
WO2014059239A1 (en) 2012-10-12 2014-04-17 3M Innovative Properties Company Multi-layer articles
EP2727950A1 (en) * 2012-11-02 2014-05-07 Rhein Chemie Rheinau GmbH Method for drying of plastics on the basis of polyester resins
FR3002537B1 (en) * 2013-02-26 2015-04-24 Ipsen Pharma NEW PROCESS FOR PURIFYING POLYESTERS
NZ706072A (en) 2013-03-08 2018-12-21 Xyleco Inc Equipment protecting enclosures
WO2014155213A2 (en) 2013-03-26 2014-10-02 Indian Institute Of Technology Madras Catalysts for poly(lactide) synthesis and uses thereof
JP2016523588A (en) 2013-05-06 2016-08-12 アボット カーディオヴァスキュラー システムズ インコーポレイテッド Hollow stent filled with therapeutic compound formulation
EP3052697A1 (en) 2013-09-30 2016-08-10 3M Innovative Properties Company Fibers and wipes with epoxidized fatty ester disposed thereon, and methods
KR20160062105A (en) 2013-09-30 2016-06-01 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Fibers, wipes, and methods
WO2015047988A1 (en) 2013-09-30 2015-04-02 3M Innovative Properties Company Compositions, wipes, and methods
KR102189677B1 (en) 2014-02-10 2020-12-11 삼성전자주식회사 Preparation method of polylactic acid, polylactic acid resin prepared therefrom, resin composition comprising the resin, and catalyst system for preparing polylactic acid
JP2015205994A (en) * 2014-04-21 2015-11-19 東洋紡株式会社 Polylactic acid base resin for thermofusion type road-marking coating material and thermofusion type road-marking coating composition
US9512338B2 (en) 2014-04-29 2016-12-06 Greif Packaging Llc Method for manufacturing an adhesive compound for use in the production of corrugated paperboard
US9675478B2 (en) 2014-06-11 2017-06-13 Abbott Cardiovascular Systems Inc. Solvent method for forming a polymer scaffolding
US9381280B2 (en) 2014-06-13 2016-07-05 Abbott Cardiovascular Systems Inc. Plasticizers for a biodegradable scaffolding and methods of forming same
WO2016077359A1 (en) 2014-11-14 2016-05-19 Schlumberger Canada Limited Well treatment
US10470378B2 (en) 2014-12-19 2019-11-12 Selfeco LLC Biodegradable horticulture container
US10716264B2 (en) 2014-12-19 2020-07-21 Selfeco LLC Biodegradable horticulture container
CN107109041B (en) * 2014-12-22 2020-10-16 3M创新有限公司 Compositions and films comprising polylactic acid polymers, polyvinyl acetate polymers and plasticizers
US10143318B2 (en) 2015-01-19 2018-12-04 Selfeco LLC Food display and service articles
USD775999S1 (en) 2015-03-16 2017-01-10 Selfeco LLC Plant pot
US9872442B2 (en) 2015-03-16 2018-01-23 Selfeco LLC Biodegradable shield for plant protection
RU2624905C2 (en) * 2015-12-21 2017-07-10 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Method for preparing catalyst for biodiversive aliphatic synthesis of complex polyesters
KR20170093028A (en) * 2016-02-04 2017-08-14 에스케이케미칼주식회사 Flexible polylactic acid resin composition comprising a water scavenger
US11066551B2 (en) 2016-05-20 2021-07-20 3M Innovative Properties Company Oriented polylactic acid polymer based film
WO2017222824A1 (en) 2016-06-21 2017-12-28 3M Innovative Properties Company Graphic articles comprising semicrystalline polylactic acid based film
FR3060454A1 (en) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin RUBBER COMPOSITION COMPRISING A POLYDIENE / POLYLACTIDE COPOLYMER
FR3060582A1 (en) 2016-12-21 2018-06-22 Compagnie Generale Des Etablissements Michelin PROCESS FOR THE PREPARATION OF POLYDIENE / POLYLACTIDE COPOLYMERS BY REACTIVE EXTRUSION
EP3406605B1 (en) 2017-05-22 2022-04-20 NatureWorks LLC Methods for producing lactide with recrystallization and recycle of meso-lactide
EP3461857A1 (en) * 2017-09-28 2019-04-03 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Surface-functionalised polymeric object and method of its production
EP3723984A4 (en) 2017-12-15 2021-08-18 3M Innovative Properties Company Textured printable nonwoven media
FR3082519B1 (en) 2018-06-19 2020-11-20 Michelin & Cie ELASTOMERIC BLEND INCLUDING PLLA AND PDLA
EP3674059A1 (en) * 2018-12-28 2020-07-01 Agrana Stärke GmbH Compound or film containing thermoplastic starch and a thermoplastic polymer
DE102019200596A1 (en) 2019-01-17 2020-07-23 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. USE OF ADDITIVE COMPOSITION FOR CONTROLLED ACCELERATED DISASSEMBLY OF CONDENSATION POLYMERS
JP2022525475A (en) * 2019-03-18 2022-05-16 ノボマー， インコーポレイテッド Membrane separation system and its applications
KR20220043074A (en) * 2019-06-03 2022-04-05 토탈 콜비온 피엘에이 비.브이. Process for preparing stabilized aliphatic polyester and composition obtained thereby
CN114616285B (en) * 2019-06-13 2023-11-07 自然工作有限责任公司 Rapidly hydrolyzed polylactide resin composition
WO2022212229A1 (en) 2021-03-31 2022-10-06 Natureworks Llc Melt-stable polylactide resin compositions containing phosphite esters
CN115491006A (en) * 2022-10-10 2022-12-20 金发科技股份有限公司 Polylactic acid composition and preparation method and application thereof

Family Cites Families (128)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA808731A (en) * 1969-03-18 A. Fouty Roger Preparation of high molecular weight polylactides
CA863673A (en) * 1971-02-16 K. Schneider Allan Absorbable suture
DE267826C (en) * 1912-12-28 1913-12-02 Chemische Werke Process for the preparation of lactide
US1095205A (en) * 1913-05-15 1914-05-05 Chemische Werke Vorm Dr Heinrich Byk Manufacture of lactid.
US1849107A (en) * 1928-05-12 1932-03-15 Celanese Corp Synthetic resin and method of making the same
US1995970A (en) * 1931-04-04 1935-03-26 Du Pont Polymeric lactide resin
US2396994A (en) * 1944-01-18 1946-03-19 Nasa Condensation products of hydroxy carboxylic acids
US2703316A (en) * 1951-06-05 1955-03-01 Du Pont Polymers of high melting lactide
US2758987A (en) * 1952-06-05 1956-08-14 Du Pont Optically active homopolymers containing but one antipodal species of an alpha-monohydroxy monocarboxylic acid
IT544701A (en) * 1953-09-26
GB808731A (en) * 1956-01-20 1959-02-11 Du Pont Preparation of platinum metal catalysts
DE1228416B (en) * 1957-03-04 1966-11-10 Boehringer Sohn Ingelheim Process for the production of polyesters
DE1083275B (en) * 1959-07-02 1960-06-15 Dynamit Nobel Ag Process for the production of lactide
US3322791A (en) * 1963-09-26 1967-05-30 Ethicon Inc Preparation of optically active lactides
GB1040168A (en) * 1963-11-08 1966-08-24 Du Pont High molecular weight polylactides and a process for their preparation
US3268487A (en) * 1963-12-23 1966-08-23 Shell Oil Co Process for polymerization of lactides
US3332791A (en) * 1964-05-12 1967-07-25 Rayonier Inc Process for producing portland cement compositions
JPS433017Y1 (en) * 1964-12-28 1968-02-07
JPS438614Y1 (en) * 1965-01-21 1968-04-16
US3531561A (en) * 1965-04-20 1970-09-29 Ethicon Inc Suture preparation
JPS432949Y1 (en) * 1965-08-26 1968-02-07
DE1543958A1 (en) * 1966-01-20 1970-02-05 Wolfen Filmfab Veb Process for the preparation of cyclic ester anhydrides of alpha-hydroxycarboxylic acids
NL6607189A (en) * 1966-05-25 1967-11-27
GB1108720A (en) * 1966-10-10 1968-04-03 Wolfen Filmfab Veb Process for the manufacture of cyclic ester anhydrides of ª‡-hydroxy-carboxylic acids
US3772420A (en) * 1968-12-23 1973-11-13 American Cyanamid Co Method for improving the in-vivo strength of polyglycolic acid
US3887699A (en) * 1969-03-24 1975-06-03 Seymour Yolles Biodegradable polymeric article for dispensing drugs
US3773919A (en) * 1969-10-23 1973-11-20 Du Pont Polylactide-drug mixtures
IT1012009B (en) * 1970-04-14 1977-03-10 Ethicon Inc PREPARATION OF HIGH MOLECULAR WEIGHT POLYLACTIDES
BE758156R (en) * 1970-05-13 1971-04-28 Ethicon Inc ABSORBABLE SUTURE ELEMENT AND ITS
US3755558A (en) * 1971-02-23 1973-08-28 Du Pont Polylactide drug mixtures for topical application atelet aggregation
US3839297A (en) * 1971-11-22 1974-10-01 Ethicon Inc Use of stannous octoate catalyst in the manufacture of l(-)lactide-glycolide copolymer sutures
US3912692A (en) * 1973-05-03 1975-10-14 American Cyanamid Co Process for polymerizing a substantially pure glycolide composition
US4045418A (en) * 1975-01-28 1977-08-30 Gulf Oil Corporation Copolymers of D,L-lactide and epsilon caprolactone
FR2439003A1 (en) * 1978-10-20 1980-05-16 Anvar NEW OSTEOSYNTHESIS PARTS, THEIR PREPARATION AND THEIR APPLICATION
US4249531A (en) * 1979-07-05 1981-02-10 Alza Corporation Bioerodible system for delivering drug manufactured from poly(carboxylic acid)
US4273920A (en) * 1979-09-12 1981-06-16 Eli Lilly And Company Polymerization process and product
US4343931A (en) * 1979-12-17 1982-08-10 Minnesota Mining And Manufacturing Company Synthetic absorbable surgical devices of poly(esteramides)
US4529792A (en) * 1979-12-17 1985-07-16 Minnesota Mining And Manufacturing Company Process for preparing synthetic absorbable poly(esteramides)
PH19942A (en) * 1980-11-18 1986-08-14 Sintex Inc Microencapsulation of water soluble polypeptides
US4343939A (en) * 1981-04-22 1982-08-10 American Cyanamid Company Glycolic acid esters and amides of bis(p-disubstitutedaminophenyl)carbinol
DE3149358A1 (en) * 1981-12-12 1983-06-16 Basf Ag, 6700 Ludwigshafen THERMOPLASTIC MOLDING
US4441496A (en) * 1982-02-08 1984-04-10 Ethicon, Inc. Copolymers of p-dioxanone and 2,5-morpholinediones and surgical devices formed therefrom having accelerated absorption characteristics
US4523591A (en) * 1982-10-22 1985-06-18 Kaplan Donald S Polymers for injection molding of absorbable surgical devices
US4643734A (en) * 1983-05-05 1987-02-17 Hexcel Corporation Lactide/caprolactone polymer, method of making the same, composites thereof, and prostheses produced therefrom
CH656884A5 (en) * 1983-08-26 1986-07-31 Sandoz Ag POLYOLESTERS, THEIR PRODUCTION AND USE.
HU194939B (en) * 1983-12-22 1988-03-28 Chinoin Gyogyszer Es Vegyeszet Process for producing alpha- beta- and gamma cyclodextrine of high yield capacity
US4611023A (en) * 1984-02-03 1986-09-09 Ciba-Geigy Corporation Di-(substituted hydroxyphenylthio) alkane and cycloalkane stabilizers and stabilized compositions
CA1236641A (en) * 1984-07-06 1988-05-10 Motoaki Tanaka Copolymer of lactic acid and glycolic acid and method for producing same
US4595713A (en) * 1985-01-22 1986-06-17 Hexcel Corporation Medical putty for tissue augmentation
JP2551756B2 (en) * 1985-05-07 1996-11-06 武田薬品工業株式会社 Polyoxycarboxylic acid ester and method for producing the same
US4727163A (en) * 1985-07-11 1988-02-23 E. I. Du Pont De Nemours And Company Process for preparing highly pure cyclic esters
GB8609537D0 (en) * 1986-04-18 1986-05-21 Ici Plc Polyesters
DE3708915C2 (en) * 1987-03-19 1996-04-04 Boehringer Ingelheim Kg Process for the preparation of lactide
DE3632103A1 (en) * 1986-09-20 1988-03-24 Boehringer Ingelheim Kg Process for the preparation of lactide
ES2030409T3 (en) * 1986-10-24 1992-11-01 Boehringer Ingelheim Kg PROCEDURE FOR PREPARING AND PURIFYING THERMOLABILE COMPOUNDS.
DE3641692A1 (en) * 1986-12-06 1988-06-09 Boehringer Ingelheim Kg CATALYST-FREE RESORBABLE HOMOPOLYMERS AND COPOLYMERS
DE3781133T2 (en) * 1986-12-19 1993-06-24 Akzo Nv MANUFACTURE OF POLYMILIC ACID AND COPOLYMERS THEREOF.
US4800219A (en) * 1986-12-22 1989-01-24 E. I. Du Pont De Nemours And Company Polylactide compositions
US4981696A (en) * 1986-12-22 1991-01-01 E. I. Du Pont De Nemours And Company Polylactide compositions
US4766182A (en) * 1986-12-22 1988-08-23 E. I. Du Pont De Nemours And Company Polylactide compositions
US4719246A (en) * 1986-12-22 1988-01-12 E. I. Du Pont De Nemours And Company Polylactide compositions
US4835293A (en) * 1987-02-24 1989-05-30 E. I. Du Pont De Nemours And Company Atmospheric pressure process for preparing pure cyclic esters
JPH02500593A (en) * 1987-06-16 1990-03-01 ベーリンガー　インゲルハイム　コマンディットゲゼルシャフト Meso-lactide and its manufacturing method
JPH0613602B2 (en) * 1987-07-14 1994-02-23 三井東圧化学株式会社 Method for producing d-l-lactic acid-glycolic acid copolymer
NL8702563A (en) * 1987-10-28 1989-05-16 Cca Biochem B V POLYMER LACTIDE, METHOD FOR PREPARING SUCH A POLYMER LACTIDE, AND A COMPOSITION CONTAINING SUCH POLYMER LACTIDE.
JP2561853B2 (en) * 1988-01-28 1996-12-11 株式会社ジェイ・エム・エス Shaped memory molded article and method of using the same
US4902515A (en) * 1988-04-28 1990-02-20 E. I. Dupont De Nemours And Company Polylactide compositions
US5444113A (en) * 1988-08-08 1995-08-22 Ecopol, Llc End use applications of biodegradable polymers
US5424346A (en) * 1988-08-08 1995-06-13 Ecopol, Llc Biodegradable replacement of crystal polystyrene
US5502158A (en) * 1988-08-08 1996-03-26 Ecopol, Llc Degradable polymer composition
US5180765A (en) * 1988-08-08 1993-01-19 Biopak Technology, Ltd. Biodegradable packaging thermoplastics from lactides
US5216050A (en) * 1988-08-08 1993-06-01 Biopak Technology, Ltd. Blends of polyactic acid
US5252642A (en) * 1989-03-01 1993-10-12 Biopak Technology, Ltd. Degradable impact modified polyactic acid
US5274127A (en) * 1990-09-18 1993-12-28 Biopak Technology, Ltd. Lactide production from dehydration of aqueous lactic acid feed
BR8907604A (en) * 1988-08-08 1991-07-30 Battelle Memorial Institute ENVIRONMENTALLY BIODEGRADABLE COMPOSITION, PROCESS TO PRODUCE THE SAME AND PROCESS TO MAKE AN ENVIRONMENTALLY BIODEGRADAVEL THERMOPLASTIC POLYMER COMPOSITION
DE3831657A1 (en) * 1988-09-17 1990-03-22 Boehringer Ingelheim Kg DEVICE FOR THE OSTEOSYNTHESIS AND METHOD FOR THE PRODUCTION THEREOF
JP2714454B2 (en) * 1988-11-07 1998-02-16 三井東圧化学株式会社 Method for producing bioabsorbable polyester
US5124023A (en) * 1988-11-28 1992-06-23 Union Oil Company Of California Continuous removal of polynuclear aromatics from hydrocarbon recycle oil
DE3917178A1 (en) * 1989-05-26 1990-11-29 Boehringer Ingelheim Kg IMPROVED METHOD FOR PRODUCING D, L-LACTID
US5149833A (en) * 1989-05-26 1992-09-22 Boehringer Ingelheim Gmbh Process for preparing D,L-Lactide
DK0405799T3 (en) * 1989-06-29 1995-08-14 Well Equip Ltd shock mechanism
AU6338590A (en) * 1989-08-08 1991-03-11 Pennsylvania Research Corporation, The Hydrodegradable polyesters
WO1991006601A1 (en) * 1989-11-02 1991-05-16 Allied-Signal Inc. Biodegradable polymeric materials and articles fabricated therefrom
JPH0623260B2 (en) * 1989-11-08 1994-03-30 工業技術院長 Microbial degradable thermoplastic resin molding and method for producing the same
WO1991013207A1 (en) * 1990-02-21 1991-09-05 Pulp And Paper Research Institute Of Canada POLY-β-HYDROXYALKANOATES FOR USE IN FIBRE CONSTRUCTS AND FILMS
US5302694A (en) * 1990-02-21 1994-04-12 Boehringer Ingelheim Gmbh Process for preparing polyesters based on hydroxycarboxylic acids
US5023349A (en) * 1990-05-08 1991-06-11 E. I. Du Pont De Nemours And Company Continuous process for rapid conversion of oligomers to cyclic esters
US5043458A (en) * 1990-05-03 1991-08-27 E. I. Du Pont De Nemours And Company One-step continuous process for preparing cyclic esters
WO1991017155A1 (en) * 1990-05-03 1991-11-14 E.I. Du Pont De Nemours And Company Improved process for the rapid production of cyclic esters
US5097005A (en) * 1990-05-11 1992-03-17 E. I. Du Pont De Nemours And Company Novel copolyesters and their use in compostable products such as disposable diapers
US5023350A (en) * 1990-05-24 1991-06-11 E. I. Du Pont De Nemours And Company Process for the purification of cyclic esters
US5138074A (en) * 1990-06-28 1992-08-11 E. I. Du Pont De Nemours And Company Continuous catalyzed vapor phase dimeric cyclic ester process
JP2744696B2 (en) * 1990-07-13 1998-04-28 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー High-yield regeneration method of lactide
AU8007591A (en) * 1990-07-16 1992-02-18 E.I. Du Pont De Nemours And Company Degradable foam materials
US5076983A (en) * 1990-07-16 1991-12-31 E. I. Du Pont De Nemours And Company Polyhydroxy acid films
EP0548284A1 (en) * 1990-09-06 1993-06-30 Biopak Technology Ltd Packaging thermoplastics from lactic acid
PT98914A (en) * 1990-09-11 1992-07-31 Du Pont METHOD FOR PREPARING POLYMERIC COMPOSITIONS AND FILMS CONTAINING POLYHYDROXY ACID AND A COMPATIBILITY AGENT
JPH06500818A (en) * 1990-09-11 1994-01-27 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Films containing polyhydroxy acids
US5332839A (en) * 1990-09-18 1994-07-26 Biopak Technology, Ltd. Catalytic production of lactide directly from lactic acid
AU8517891A (en) * 1990-09-26 1992-04-15 E.I. Du Pont De Nemours And Company Cellulosic pulp bonded by polyhydroxy acid resins
ZA918168B (en) * 1990-10-16 1993-04-14 Takeda Chemical Industries Ltd Prolonged release preparation and polymers thereof.
US5210296A (en) * 1990-11-19 1993-05-11 E. I. Du Pont De Nemours And Company Recovery of lactate esters and lactic acid from fermentation broth
US5136017A (en) * 1991-02-22 1992-08-04 Polysar Financial Services S.A. Continuous lactide polymerization
SE9100610D0 (en) * 1991-03-04 1991-03-04 Procordia Ortech Ab BIORESORBABLE MATERIAL FOR MEDICAL USE
JP3054451B2 (en) * 1991-03-11 2000-06-19 三井化学株式会社 Hydrolysable resin composition
CA2064410A1 (en) * 1991-04-01 1992-10-02 Masanobu Ajioka Degradable foam and use of same
US5132397A (en) * 1991-04-02 1992-07-21 Polysar Financial Services S.A. 4-valerolactone copolymers
US5223546A (en) * 1991-04-24 1993-06-29 Mitsui Toatsu Chemicals, Inc. High polymer network
US5340646A (en) * 1991-04-26 1994-08-23 Mitsui Toatsu Chemicals, Inc. Breathable, hydrolyzable porous film
JP3167411B2 (en) * 1991-04-26 2001-05-21 三井化学株式会社 Porous film
CA2068368A1 (en) * 1991-05-13 1992-11-14 Masanobu Ajioka Degradable laminate composition
CA2067451A1 (en) * 1991-05-24 1993-10-29 Gregory B. Kharas Polylactide blends
WO1993001521A1 (en) * 1991-07-03 1993-01-21 E.I. Du Pont De Nemours And Company Ultraviolet film/screen combinations for improved radiological evaluations
BE1005080A3 (en) * 1991-07-19 1993-04-13 Solvay Soc Anomyme Flexible film, and resilient biodegradable polymer based lactic acid may be suitable especially for making medical dressing.
TW211577B (en) * 1991-07-24 1993-08-21 Du Pont
US5296282A (en) * 1991-08-12 1994-03-22 E. I. Du Pont De Nemours And Company Degradable repellant coated articles
US5233546A (en) * 1991-08-14 1993-08-03 Hewlett-Packard Company Anti-alias filtering apparatus for frequency domain measurements
CA2067453A1 (en) * 1991-09-12 1993-10-29 Michael Castriotta Devolatilization of polylactides
EP0533314A3 (en) * 1991-09-17 1993-06-30 Novacor Chemicals (International) S.A. Biodegradable polyester compositions
US5351767A (en) * 1991-11-07 1994-10-04 Globral Marine Inc. Drill pipe handling
US5229528A (en) * 1991-11-22 1993-07-20 E. I. Du Pont De Nemours And Company Rapid depolymerization of polyhydroxy acids
US5142023A (en) * 1992-01-24 1992-08-25 Cargill, Incorporated Continuous process for manufacture of lactide polymers with controlled optical purity
US5236560A (en) * 1992-03-13 1993-08-17 E. I. Du Pont De Nemours And Company Solventless dimeric cyclic ester distillation process
US5338822A (en) * 1992-10-02 1994-08-16 Cargill, Incorporated Melt-stable lactide polymer composition and process for manufacture thereof
DE69322155T2 (en) * 1992-10-02 1999-08-19 Cargill Inc PAPER WITH A COATING FROM MELT-STABLE POLYMER AND ITS METHOD FOR THE PRODUCTION THEREOF
US5252646A (en) * 1992-10-29 1993-10-12 National Starch And Chemical Investment Holding Corporation Polylactide containing hot melt adhesive
US5202413A (en) * 1993-02-16 1993-04-13 E. I. Du Pont De Nemours And Company Alternating (ABA)N polylactide block copolymers
US5359026A (en) * 1993-07-30 1994-10-25 Cargill, Incorporated Poly(lactide) copolymer and process for manufacture thereof

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