CA2130009A1 - Olefin Polymerization Catalyst and Process for Preparing Polypropylene and Propylene Block Copolymer - Google Patents
Olefin Polymerization Catalyst and Process for Preparing Polypropylene and Propylene Block CopolymerInfo
- Publication number
- CA2130009A1 CA2130009A1 CA2130009A CA2130009A CA2130009A1 CA 2130009 A1 CA2130009 A1 CA 2130009A1 CA 2130009 A CA2130009 A CA 2130009A CA 2130009 A CA2130009 A CA 2130009A CA 2130009 A1 CA2130009 A1 CA 2130009A1
- Authority
- CA
- Canada
- Prior art keywords
- component
- olefin polymerization
- polypropylene
- catalyst component
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
Abstract
The present invention provides olefin polymerization catalysts and processes for preparing a polypropylene and propylene block copolymer using said olefin polymerization catalysts.
The olefin polymerization catalyst (1) of the invention is formed from:
[I-1] a contact product obtained by contacting:
(A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound;
[II-1] (D) a specific polyether compound; and optionally, [III] an organometallic compound catalyst component The olefin polymerization catalyst (2) of the invention is formed from:
[I-2] a contact product obtained by contacting:
(A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound;
[II-2] (C) a specific organosilicon compound; and optionally, [III] an organometallic compound catalyst component.
The contact product [I-1] or [I-2] may be replaced by one which is obtained by prepolymerizing an olefin of 2 or more carbon atoms in the presence of the catalyst components for the contact product [I-1] or [I-2] in such a way that the amount of the prepolymer formed is 0.01 to 2,000 g based on 1 g of the solid titanium catalyst component (A).
In the processes for preparing a polypropylene according to the invention, propylene is polymerized in the presence of the above-mentioned olefin polymerization catalysts. According to the invention, highly isotactic polypropylene can be prepared.
The processes for preparing a propylene block copolymer according to the invention comprises the steps of polymerizing propylene to form a polypropylene component and copolymerizing ethylene and an .alpha.-olefin of 3 to 20 carbon atoms to form an ethylene/.alpha.-olefin copolymer component, in an optional order, in the presence of the specific polymerization catalysts.
In the propylene block copolymer obtained by the invention, the polypropylene component is highly isotactic and the rubber component has a high intrinsic viscosity [n].
The olefin polymerization catalyst (1) of the invention is formed from:
[I-1] a contact product obtained by contacting:
(A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound;
[II-1] (D) a specific polyether compound; and optionally, [III] an organometallic compound catalyst component The olefin polymerization catalyst (2) of the invention is formed from:
[I-2] a contact product obtained by contacting:
(A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compound;
[II-2] (C) a specific organosilicon compound; and optionally, [III] an organometallic compound catalyst component.
The contact product [I-1] or [I-2] may be replaced by one which is obtained by prepolymerizing an olefin of 2 or more carbon atoms in the presence of the catalyst components for the contact product [I-1] or [I-2] in such a way that the amount of the prepolymer formed is 0.01 to 2,000 g based on 1 g of the solid titanium catalyst component (A).
In the processes for preparing a polypropylene according to the invention, propylene is polymerized in the presence of the above-mentioned olefin polymerization catalysts. According to the invention, highly isotactic polypropylene can be prepared.
The processes for preparing a propylene block copolymer according to the invention comprises the steps of polymerizing propylene to form a polypropylene component and copolymerizing ethylene and an .alpha.-olefin of 3 to 20 carbon atoms to form an ethylene/.alpha.-olefin copolymer component, in an optional order, in the presence of the specific polymerization catalysts.
In the propylene block copolymer obtained by the invention, the polypropylene component is highly isotactic and the rubber component has a high intrinsic viscosity [n].
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20138993 | 1993-08-13 | ||
JP201388/1993 | 1993-08-13 | ||
JP201389/1993 | 1993-08-13 | ||
JP20138893 | 1993-08-13 | ||
JP204310/1993 | 1993-08-18 | ||
JP20431093 | 1993-08-18 | ||
JP20431193 | 1993-08-18 | ||
JP204311/1993 | 1993-08-18 | ||
JP204309/1993 | 1993-08-18 | ||
JP20430993 | 1993-08-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2130009A1 true CA2130009A1 (en) | 1995-02-14 |
CA2130009C CA2130009C (en) | 1998-09-22 |
Family
ID=27529285
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002130009A Expired - Fee Related CA2130009C (en) | 1993-08-13 | 1994-08-12 | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
Country Status (7)
Country | Link |
---|---|
US (4) | US5618886A (en) |
EP (2) | EP0854156B1 (en) |
KR (2) | KR0182339B1 (en) |
CN (7) | CN1049898C (en) |
CA (1) | CA2130009C (en) |
DE (2) | DE69432779T2 (en) |
TW (1) | TW354792B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0731114A1 (en) * | 1995-03-07 | 1996-09-11 | ENICHEM ELASTOMERI S.r.l. | Process for obtaining ethylene-propylene elastomer copolymers with a high purity and controlled molecular weight distribution |
Families Citing this family (66)
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TW354792B (en) | 1993-08-13 | 1999-03-21 | Mitsui Petrochemical Ind | Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer |
CA2162946C (en) * | 1994-11-21 | 2004-01-06 | Kazuyuki Watanabe | Propylene block copolymer and process for producing the same |
DE19545499A1 (en) * | 1995-12-06 | 1997-06-12 | Basf Ag | Improved statistical propylene copolymers |
IT1282691B1 (en) * | 1996-02-27 | 1998-03-31 | Montell North America Inc | PROCESS FOR THE PREPARATION OF RANDOM PROPYLENE COPOLYMERS AND PRODUCTS SO OBTAINED |
US5859143A (en) * | 1996-04-18 | 1999-01-12 | Mitsubishi Chemical Corporation | Process for continuously producing propylene-based block copolymer |
US6403708B2 (en) | 1996-05-27 | 2002-06-11 | Mitsui Chemicals Inc | Crystalline polypropylenes, process for preparing thereof, polypropylene compositions, and thermoformed products |
KR100289227B1 (en) * | 1996-05-27 | 2001-05-02 | 나까니시 히로유끼 | Crystalline polypropylene, a process for producing the same, a polypropylene composition, |
JP3358441B2 (en) * | 1996-06-04 | 2002-12-16 | 住友化学工業株式会社 | Polypropylene block copolymer |
JP3688078B2 (en) * | 1996-11-20 | 2005-08-24 | 三井化学株式会社 | Olefin polymerization catalyst, prepolymerization catalyst, olefin polymerization method |
CN1116315C (en) | 1997-05-30 | 2003-07-30 | 株式会社宏大化纤 | Polypropylene resin composition and injection-molded article |
JPH1112316A (en) * | 1997-06-26 | 1999-01-19 | Toho Titanium Co Ltd | Solid catalyst component and catalyst for polymerizing olefins |
ES2224704T3 (en) * | 1998-11-04 | 2005-03-01 | Basell Poliolefine Italia S.P.A. | COMPONENTS AND CATALYSTS FOR POLYMERIZATION OF OLEFINS. |
SG80673A1 (en) * | 1999-02-25 | 2001-05-22 | Sumitomo Chemical Co | Catalyst component, catalyst for olefin polymerization, process for producing olefin polymer and use of organosilicon compound |
KR100546499B1 (en) * | 1999-05-27 | 2006-01-26 | 삼성토탈 주식회사 | A catalyst for ethylene homo- and co-polymerization |
KR100524293B1 (en) | 1999-05-27 | 2005-10-26 | 삼성토탈 주식회사 | A catalyst for ethylene homo- and co-polymerization |
DE60018775T2 (en) * | 1999-10-02 | 2005-08-11 | Borealis Technology Oy | SUPPORTED AND MODIFIED CATALYST FOR THE POLYMERIZATION OF OLEFINE |
US6384142B1 (en) | 2000-02-08 | 2002-05-07 | Exxonmobil Chemical Patents Inc. | Propylene impact copolymers |
EP1263764B1 (en) | 2000-02-08 | 2004-04-14 | ExxonMobil Chemical Patents Inc. | Method of preparing group 14 bridged biscyclopentadienyl ligands |
DE60134611D1 (en) * | 2000-04-24 | 2008-08-14 | Toho Titanium Co Ltd | SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION |
ES2330192T3 (en) * | 2000-05-12 | 2009-12-07 | Basell Poliolefine Italia S.R.L. | PRE-POLYMERIZED CATALYST COMPONENTS, FOR OLEFIN POLYMERIZATION. |
KR100387734B1 (en) * | 2000-06-17 | 2003-06-18 | 삼성종합화학주식회사 | Catalyst and process for polymerization of olefin |
WO2002046249A2 (en) | 2000-11-07 | 2002-06-13 | Symyx Technologies, Inc. | Methods of copolymerizing ethylene and isobutylene and polymers made thereby |
KR100389477B1 (en) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | A method for producing ethylene homo- and co-polymer |
KR100389475B1 (en) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | Preparation method of catalyst for ethylene polymeration or copolymeration |
KR100389476B1 (en) * | 2000-11-09 | 2003-06-27 | 삼성종합화학주식회사 | A method for producing ethylene homo- and co-polymer |
KR100389962B1 (en) * | 2000-11-10 | 2003-07-02 | 삼성종합화학주식회사 | Preparation method of catalyst for ethylene polymeration or copolymeration |
KR100421551B1 (en) * | 2000-12-16 | 2004-03-09 | 삼성아토피나주식회사 | Catalyst obtained by prepolymerization of polyolefin and olefin polymerization method using the same |
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-
1994
- 1994-08-11 TW TW083107329A patent/TW354792B/en active
- 1994-08-12 EP EP98105188A patent/EP0854156B1/en not_active Expired - Lifetime
- 1994-08-12 DE DE69432779T patent/DE69432779T2/en not_active Expired - Lifetime
- 1994-08-12 DE DE69429198T patent/DE69429198T2/en not_active Expired - Lifetime
- 1994-08-12 CA CA002130009A patent/CA2130009C/en not_active Expired - Fee Related
- 1994-08-12 EP EP94112641A patent/EP0641807B1/en not_active Expired - Lifetime
- 1994-08-13 CN CN94109542A patent/CN1049898C/en not_active Expired - Lifetime
- 1994-08-13 CN CNB991049896A patent/CN1169846C/en not_active Expired - Lifetime
- 1994-08-13 KR KR1019940020038A patent/KR0182339B1/en not_active IP Right Cessation
-
1996
- 1996-07-31 US US08/690,054 patent/US5618886A/en not_active Expired - Lifetime
- 1996-10-16 US US08/730,930 patent/US6271166B1/en not_active Expired - Lifetime
-
1998
- 1998-05-15 KR KR1019980017449A patent/KR0163665B1/en not_active IP Right Cessation
- 1998-06-03 US US09/089,116 patent/US6214939B1/en not_active Expired - Lifetime
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1999
- 1999-04-09 CN CN99104987A patent/CN1125831C/en not_active Expired - Lifetime
- 1999-04-09 CN CN99104993A patent/CN1132866C/en not_active Expired - Lifetime
- 1999-04-09 CN CN99104872A patent/CN1112375C/en not_active Expired - Lifetime
- 1999-04-09 CN CN99104988A patent/CN1112379C/en not_active Expired - Lifetime
- 1999-04-15 CN CN99105216A patent/CN1112376C/en not_active Expired - Lifetime
-
2001
- 2001-06-12 US US09/878,426 patent/US6537942B2/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0731114A1 (en) * | 1995-03-07 | 1996-09-11 | ENICHEM ELASTOMERI S.r.l. | Process for obtaining ethylene-propylene elastomer copolymers with a high purity and controlled molecular weight distribution |
Also Published As
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TW354792B (en) | 1999-03-21 |
US5618886A (en) | 1997-04-08 |
DE69429198D1 (en) | 2002-01-03 |
EP0641807A2 (en) | 1995-03-08 |
US6537942B2 (en) | 2003-03-25 |
CN1112379C (en) | 2003-06-25 |
EP0854156A3 (en) | 1998-08-12 |
DE69429198T2 (en) | 2002-08-14 |
CN1245813A (en) | 2000-03-01 |
CN1232829A (en) | 1999-10-27 |
EP0854156B1 (en) | 2001-11-21 |
US6271166B1 (en) | 2001-08-07 |
CN1169846C (en) | 2004-10-06 |
CN1239105A (en) | 1999-12-22 |
EP0854156A2 (en) | 1998-07-22 |
CN1132866C (en) | 2003-12-31 |
CN1231295A (en) | 1999-10-13 |
CN1231293A (en) | 1999-10-13 |
CN1049898C (en) | 2000-03-01 |
CN1231294A (en) | 1999-10-13 |
KR0182339B1 (en) | 1999-05-15 |
EP0641807B1 (en) | 2003-06-04 |
CN1125831C (en) | 2003-10-29 |
DE69432779D1 (en) | 2003-07-10 |
US20010044375A1 (en) | 2001-11-22 |
CN1112376C (en) | 2003-06-25 |
US6214939B1 (en) | 2001-04-10 |
KR0163665B1 (en) | 1999-01-15 |
CA2130009C (en) | 1998-09-22 |
KR950005850A (en) | 1995-03-20 |
EP0641807A3 (en) | 1995-04-26 |
DE69432779T2 (en) | 2004-05-13 |
CN1111643A (en) | 1995-11-15 |
CN1112375C (en) | 2003-06-25 |
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