CA2130911A1 - Electrolytic Cell for Generating Sterilization Solutions Having Increased Ozone Content - Google Patents
Electrolytic Cell for Generating Sterilization Solutions Having Increased Ozone ContentInfo
- Publication number
- CA2130911A1 CA2130911A1 CA 2130911 CA2130911A CA2130911A1 CA 2130911 A1 CA2130911 A1 CA 2130911A1 CA 2130911 CA2130911 CA 2130911 CA 2130911 A CA2130911 A CA 2130911A CA 2130911 A1 CA2130911 A1 CA 2130911A1
- Authority
- CA
- Canada
- Prior art keywords
- cell
- electrolytic cell
- ozone
- ozone content
- increased ozone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46109—Electrodes
- C02F2001/46133—Electrodes characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4611—Fluid flow
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46125—Electrical variables
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4612—Controlling or monitoring
- C02F2201/46145—Fluid flow
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/46—Apparatus for electrochemical processes
- C02F2201/461—Electrolysis apparatus
- C02F2201/46105—Details relating to the electrolytic devices
- C02F2201/4618—Supplying or removing reactants or electrolyte
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/782—Ozone generators
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/02—Fluid flow conditions
- C02F2301/022—Laminar
Abstract
An electrolytic cell (10) for generating a mixed oxidant that is rich in ozone is disclosed. The cell disassociates a brine solu-tion to generate ozone and chlorine based oxidants. The improved cell design allows the ratio of ozone to the other oxidants to be optimized, thereby providing a more efficient sterilization solution. The ozone production is adjusted by adjusting the residence time of the brine solution in the cell and the orientation of the cell.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US857,731 | 1992-03-26 | ||
US07/857,731 US5316740A (en) | 1992-03-26 | 1992-03-26 | Electrolytic cell for generating sterilization solutions having increased ozone content |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2130911A1 true CA2130911A1 (en) | 1993-09-30 |
CA2130911C CA2130911C (en) | 1999-03-30 |
Family
ID=25326629
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002130911A Expired - Fee Related CA2130911C (en) | 1992-03-26 | 1993-03-04 | Electrolytic cell for generating sterilization solutions having increased ozone content |
Country Status (19)
Country | Link |
---|---|
US (3) | US5316740A (en) |
EP (1) | EP0632746B1 (en) |
JP (1) | JP3051175B2 (en) |
KR (1) | KR100220363B1 (en) |
AR (1) | AR247765A1 (en) |
AT (1) | ATE192944T1 (en) |
AU (1) | AU667525B2 (en) |
BR (1) | BR9306134A (en) |
CA (1) | CA2130911C (en) |
DE (1) | DE69328676T2 (en) |
FI (1) | FI944424A0 (en) |
HU (1) | HU218057B (en) |
IL (1) | IL104989A0 (en) |
MX (1) | MX9301712A (en) |
MY (1) | MY109908A (en) |
NO (1) | NO943412L (en) |
RU (1) | RU2123069C1 (en) |
TW (1) | TW210327B (en) |
WO (1) | WO1993018854A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006047876A1 (en) * | 2004-11-02 | 2006-05-11 | Hy-Drive Technologies Ltd. | Electrolysis cell electrolyte pumping system |
US7651602B2 (en) | 2002-08-28 | 2010-01-26 | Fatpower, Inc. | Electrolyzer |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5447630A (en) * | 1993-04-28 | 1995-09-05 | Rummler; John M. | Materials treatment process and apparatus |
US5972196A (en) | 1995-06-07 | 1999-10-26 | Lynntech, Inc. | Electrochemical production of ozone and hydrogen peroxide |
CA2104355C (en) * | 1993-08-18 | 1997-06-17 | Ion I. Inculet | Method and apparatus for ozone generation and treatment of water |
US5507932A (en) * | 1994-08-26 | 1996-04-16 | Schlumberger Technology Corporation | Apparatus for electrolyzing fluids |
US6117285A (en) * | 1994-08-26 | 2000-09-12 | Medical Discoveries, Inc. | System for carrying out sterilization of equipment |
DE19640840C2 (en) * | 1996-10-02 | 1999-08-26 | Fresenius Medical Care De Gmbh | Method for disinfecting a dialysis machine |
DE19640839C2 (en) * | 1996-10-02 | 1999-08-26 | Fresenius Medical Care De Gmbh | Method and device for disinfecting a dialysis machine |
US6287431B1 (en) | 1997-03-21 | 2001-09-11 | Lynntech International, Ltd. | Integrated ozone generator system |
US5989407A (en) | 1997-03-31 | 1999-11-23 | Lynntech, Inc. | Generation and delivery device for ozone gas and ozone dissolved in water |
US6576096B1 (en) | 1998-01-05 | 2003-06-10 | Lynntech International, Ltd. | Generation and delivery device for ozone gas and ozone dissolved in water |
US6171551B1 (en) | 1998-02-06 | 2001-01-09 | Steris Corporation | Electrolytic synthesis of peracetic acid and other oxidants |
NZ517172A (en) | 1999-08-05 | 2003-09-26 | Steris Inc | Electrolytic synthesis of peracetic acid |
US7186334B1 (en) | 1999-09-10 | 2007-03-06 | Barnes Ronald L | Combined chlorine and ozone generator sterilization system |
EP1351893B1 (en) | 2000-12-12 | 2009-08-12 | Tersano Inc. | Device for generating and applying ozonated water |
US7048842B2 (en) * | 2001-06-22 | 2006-05-23 | The Procter & Gamble Company | Electrolysis cell for generating chlorine dioxide |
CN1243667C (en) | 2001-02-15 | 2006-03-01 | 宝洁公司 | Effective electrolysis device for generating oxidant in solution |
US7008523B2 (en) * | 2001-07-16 | 2006-03-07 | Miox Corporation | Electrolytic cell for surface and point of use disinfection |
US7005075B2 (en) * | 2001-07-16 | 2006-02-28 | Miox Corporation | Gas drive electrolytic cell |
CA2461558C (en) | 2001-10-15 | 2011-10-04 | United States Filter Corporation | Apparatus for fluid purification and methods of manufacture and use thereof |
US7083733B2 (en) * | 2003-11-13 | 2006-08-01 | Usfilter Corporation | Water treatment system and method |
US7563351B2 (en) | 2003-11-13 | 2009-07-21 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
US7846340B2 (en) | 2003-11-13 | 2010-12-07 | Siemens Water Technologies Corp. | Water treatment system and method |
US7862700B2 (en) | 2003-11-13 | 2011-01-04 | Siemens Water Technologies Holding Corp. | Water treatment system and method |
US20050103717A1 (en) | 2003-11-13 | 2005-05-19 | United States Filter Corporation | Water treatment system and method |
US8377279B2 (en) | 2003-11-13 | 2013-02-19 | Siemens Industry, Inc. | Water treatment system and method |
WO2006033762A2 (en) * | 2004-08-19 | 2006-03-30 | Miox Corporation | Scented electrolysis product |
US20060137973A1 (en) * | 2004-11-24 | 2006-06-29 | Miox Corporation | Device and method for instrument steralization |
WO2006130786A2 (en) | 2005-06-01 | 2006-12-07 | Siemens Water Technologies Holding Corp. | Water treatment system and process |
US20080067069A1 (en) | 2006-06-22 | 2008-03-20 | Siemens Water Technologies Corp. | Low scale potential water treatment |
US7744760B2 (en) | 2006-09-20 | 2010-06-29 | Siemens Water Technologies Corp. | Method and apparatus for desalination |
US20080116144A1 (en) | 2006-10-10 | 2008-05-22 | Spicer Randolph, Llc | Methods and compositions for reducing chlorine demand, decreasing disinfection by-products and controlling deposits in drinking water distribution systems |
WO2008064180A1 (en) * | 2006-11-17 | 2008-05-29 | Miox Corporation | Water purification system |
US7922890B2 (en) * | 2006-11-28 | 2011-04-12 | Miox Corporation | Low maintenance on-site generator |
ATE550641T1 (en) * | 2006-12-23 | 2012-04-15 | Miox Corp | INTERNAL FLOW CONTROL IN ELECTROLYTIC CELLS |
US20100224495A1 (en) * | 2007-08-02 | 2010-09-09 | Mcguire Dennis | Real-time processing of water for hydraulic fracture treatments using a transportable frac tank |
US8663705B2 (en) | 2007-10-30 | 2014-03-04 | Reoxcyn Discoveries Group, Inc. | Method and apparatus for producing a stabilized antimicrobial non-toxic electrolyzed saline solution exhibiting potential as a therapeutic |
US8367120B1 (en) | 2007-10-31 | 2013-02-05 | Reoxcyn Discoveries Group, Inc. | Method and apparatus for producing a stablized antimicrobial non-toxic electrolyzed saline solution exhibiting potential as a therapeutic |
US8455010B1 (en) | 2007-10-31 | 2013-06-04 | Reoxcyn Discoveries Group, Inc | Product and method for producing an immune system supplement and performance enhancer |
EA201000905A1 (en) | 2007-11-30 | 2010-10-29 | Сименс Уотер Текнолоджиз Корп. | SYSTEMS AND METHODS FOR WATER TREATMENT |
US20090145773A1 (en) * | 2007-12-06 | 2009-06-11 | Miox Corporation | Membrane Cycle Cleaning |
US20090205972A1 (en) * | 2008-01-04 | 2009-08-20 | Miox Corporation | Electrolytic Purifier |
CA2718072A1 (en) * | 2008-03-12 | 2009-09-17 | M-I Drilling Fluids Uk Limited | Methods and systems of treating a wellbore |
WO2009143184A2 (en) * | 2008-05-19 | 2009-11-26 | Miox Corporation | Electrolytic cell with gas driven pumping |
WO2009155044A2 (en) | 2008-05-28 | 2009-12-23 | Miox Corporation | Reverse polarity cleaning and electronic flow control systems for low intervention electrolytic chemical generators |
US10005682B1 (en) | 2009-10-02 | 2018-06-26 | Tersano Inc. | Holding tank-less water ozonating system |
WO2011038489A1 (en) | 2009-10-02 | 2011-04-07 | Advantage Engineering Inc. | Holding tank-less water ozonating system |
EP2319806B1 (en) * | 2009-10-06 | 2017-04-05 | Geberit International AG | Water drain fitting comprising electrochemical cell and method for operating the same |
PL3257819T3 (en) | 2010-08-06 | 2020-06-15 | De Nora Holdings Us, Inc. | Electrolytic on-site generator |
EP2635312B1 (en) | 2010-11-02 | 2017-09-27 | Tersano Inc. | Holding tank-less water ozonating system using electrolytic decomposition of water |
SG194789A1 (en) | 2011-05-06 | 2013-12-30 | Miox Corp | Organic contaminant destruction using chlorine or mixed oxidant solution and ultraviolet light |
US8882972B2 (en) | 2011-07-19 | 2014-11-11 | Ecolab Usa Inc | Support of ion exchange membranes |
US8562810B2 (en) | 2011-07-26 | 2013-10-22 | Ecolab Usa Inc. | On site generation of alkalinity boost for ware washing applications |
US9010361B2 (en) | 2011-10-27 | 2015-04-21 | Pentair Residential Filtration, Llc | Control valve assembly |
US8671985B2 (en) | 2011-10-27 | 2014-03-18 | Pentair Residential Filtration, Llc | Control valve assembly |
US8961770B2 (en) | 2011-10-27 | 2015-02-24 | Pentair Residential Filtration, Llc | Controller and method of operation of a capacitive deionization system |
US9637397B2 (en) | 2011-10-27 | 2017-05-02 | Pentair Residential Filtration, Llc | Ion removal using a capacitive deionization system |
US9695070B2 (en) | 2011-10-27 | 2017-07-04 | Pentair Residential Filtration, Llc | Regeneration of a capacitive deionization system |
IN2014DN06912A (en) * | 2012-01-30 | 2015-05-15 | Rodney E Herrington | |
RU2494975C1 (en) * | 2012-03-19 | 2013-10-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный аграрный университет" | Device for obtaining disinfectant solution |
US9079227B2 (en) | 2013-04-08 | 2015-07-14 | Ronald L. Barnes | Sanitizing and cleaning process and apparatus |
SG11201810046TA (en) | 2014-12-09 | 2018-12-28 | Johnson Matthey Plc | Methods for the direct electrolytic production of stable, high concentration aqueous halosulfamate or halosulfonamide solutions |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4209368A (en) * | 1978-08-07 | 1980-06-24 | General Electric Company | Production of halogens by electrolysis of alkali metal halides in a cell having catalytic electrodes bonded to the surface of a porous membrane/separator |
CH653376A5 (en) * | 1982-10-27 | 1985-12-31 | Panclor Sa | ELECTROLYTIC PRODUCTION OF HYPOCHLORITE FROM SEA WATER: METHOD OF PRE-TREATMENT OF SEA WATER TO IMPROVE THE CHEMICAL-PHYSICAL CHARACTERISTICS. |
US4541989A (en) * | 1983-01-27 | 1985-09-17 | Oxytech, Inc. | Process and device for the generation of ozone via the anodic oxidation of water |
US4555323A (en) * | 1984-05-24 | 1985-11-26 | Collier Richard B | Chlorination device |
US4804449A (en) * | 1986-02-25 | 1989-02-14 | Sweeney Charles T | Electrolytic cell |
EP0243302B1 (en) * | 1986-04-17 | 1992-01-22 | Eltech Systems Corporation | An electrode with a platinum metal catalyst in surface film and its use |
US4761208A (en) * | 1986-09-29 | 1988-08-02 | Los Alamos Technical Associates, Inc. | Electrolytic method and cell for sterilizing water |
KR920003216B1 (en) * | 1990-03-03 | 1992-04-24 | Samsung Electronic | Apparatus for the production of ozone |
JP3048612B2 (en) * | 1990-09-06 | 2000-06-05 | ペルメレック電極株式会社 | Electrolytic ozone generator |
-
1992
- 1992-03-26 US US07/857,731 patent/US5316740A/en not_active Expired - Lifetime
-
1993
- 1993-03-04 WO PCT/US1993/001949 patent/WO1993018854A1/en active IP Right Grant
- 1993-03-04 JP JP5516572A patent/JP3051175B2/en not_active Expired - Fee Related
- 1993-03-04 BR BR9306134A patent/BR9306134A/en not_active IP Right Cessation
- 1993-03-04 DE DE69328676T patent/DE69328676T2/en not_active Expired - Fee Related
- 1993-03-04 AU AU37890/93A patent/AU667525B2/en not_active Ceased
- 1993-03-04 CA CA002130911A patent/CA2130911C/en not_active Expired - Fee Related
- 1993-03-04 EP EP93907201A patent/EP0632746B1/en not_active Expired - Lifetime
- 1993-03-04 RU RU94043325A patent/RU2123069C1/en active
- 1993-03-04 HU HU9402715A patent/HU218057B/en not_active IP Right Cessation
- 1993-03-04 AT AT93907201T patent/ATE192944T1/en not_active IP Right Cessation
- 1993-03-04 KR KR1019940703316A patent/KR100220363B1/en not_active IP Right Cessation
- 1993-03-09 IL IL104989A patent/IL104989A0/en unknown
- 1993-03-15 MY MYPI93000453A patent/MY109908A/en unknown
- 1993-03-20 TW TW082102086A patent/TW210327B/zh active
- 1993-03-23 AR AR93324565A patent/AR247765A1/en active
- 1993-03-26 MX MX9301712A patent/MX9301712A/en not_active IP Right Cessation
-
1994
- 1994-02-23 US US08/200,146 patent/US5385711A/en not_active Ceased
- 1994-09-14 NO NO943412A patent/NO943412L/en unknown
- 1994-09-23 FI FI944424A patent/FI944424A0/en unknown
-
1997
- 1997-01-23 US US08/787,160 patent/USRE36972E/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7651602B2 (en) | 2002-08-28 | 2010-01-26 | Fatpower, Inc. | Electrolyzer |
WO2006047876A1 (en) * | 2004-11-02 | 2006-05-11 | Hy-Drive Technologies Ltd. | Electrolysis cell electrolyte pumping system |
Also Published As
Publication number | Publication date |
---|---|
BR9306134A (en) | 1998-06-23 |
USRE36972E (en) | 2000-11-28 |
KR100220363B1 (en) | 1999-09-15 |
DE69328676T2 (en) | 2000-12-28 |
MX9301712A (en) | 1994-01-31 |
US5385711A (en) | 1995-01-31 |
ATE192944T1 (en) | 2000-06-15 |
IL104989A0 (en) | 1993-07-08 |
RU94043325A (en) | 1997-03-27 |
FI944424A (en) | 1994-09-23 |
HU9402715D0 (en) | 1995-02-28 |
MY109908A (en) | 1997-09-30 |
AR247765A1 (en) | 1995-03-31 |
JPH07505441A (en) | 1995-06-15 |
DE69328676D1 (en) | 2000-06-21 |
NO943412D0 (en) | 1994-09-14 |
JP3051175B2 (en) | 2000-06-12 |
KR950701547A (en) | 1995-04-28 |
HUT68701A (en) | 1995-07-28 |
TW210327B (en) | 1993-08-01 |
EP0632746B1 (en) | 2000-05-17 |
CA2130911C (en) | 1999-03-30 |
RU2123069C1 (en) | 1998-12-10 |
WO1993018854A1 (en) | 1993-09-30 |
NO943412L (en) | 1994-09-14 |
AU3789093A (en) | 1993-10-21 |
EP0632746A4 (en) | 1995-11-29 |
FI944424A0 (en) | 1994-09-23 |
HU218057B (en) | 2000-05-28 |
AU667525B2 (en) | 1996-03-28 |
EP0632746A1 (en) | 1995-01-11 |
US5316740A (en) | 1994-05-31 |
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