CA2163087A1 - Method for Synthesis of High Capacity LiXMn2O4 Secondary Battery Electrode Compounds - Google Patents

Method for Synthesis of High Capacity LiXMn2O4 Secondary Battery Electrode Compounds

Info

Publication number
CA2163087A1
CA2163087A1 CA2163087A CA2163087A CA2163087A1 CA 2163087 A1 CA2163087 A1 CA 2163087A1 CA 2163087 A CA2163087 A CA 2163087A CA 2163087 A CA2163087 A CA 2163087A CA 2163087 A1 CA2163087 A1 CA 2163087A1
Authority
CA
Canada
Prior art keywords
lixmn2o4
secondary battery
high capacity
lithium
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2163087A
Other languages
French (fr)
Other versions
CA2163087C (en
Inventor
Jean-Marie Tarascon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Iconectiv LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2163087A1 publication Critical patent/CA2163087A1/en
Application granted granted Critical
Publication of CA2163087C publication Critical patent/CA2163087C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Lithium intercalation compounds suitable for use in high capacity secondary battery electrodes (44) are prepared by reacting together at a temper-ature in the range of about 800 to 900 °C lithium and manganese compounds in a stoichiometric ratio resulting in an LixMn2O4 compound wherein x is within the range of about 1.00 to 1.10. The result-ing compound is annealed at a temperature in excess of about 800 °C and cooled to at least about 500 °C
at a rate of less than about 10 °C per hour before being finally cooled to ambient working tempera-ture. Intercalation electrodes (44) comprising these lithiated compounds used in secondary batter-ies to yield stable, extended capacities in excess of 110 AHr/Kg. Lithium metal foil (42) used as the negative electrode, an electrolyte separator (43), a positive electrode (44) and electrically conductive contacts (46 and 48) form a complete cell.
CA002163087A 1993-05-19 1994-04-28 Method for synthesis of high capacity lixmn2o4 secondary battery electrode compounds Expired - Fee Related CA2163087C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/064,247 US5425932A (en) 1993-05-19 1993-05-19 Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
US064,247 1993-05-19
PCT/US1994/004776 WO1994026666A1 (en) 1993-05-19 1994-04-28 METHOD FOR SYNTHESIS OF HIGH CAPACITY LixMn2O4 SECONDARY BATTERY ELECTRODE COMPOUNDS

Publications (2)

Publication Number Publication Date
CA2163087A1 true CA2163087A1 (en) 1994-11-24
CA2163087C CA2163087C (en) 1999-06-08

Family

ID=22054597

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002163087A Expired - Fee Related CA2163087C (en) 1993-05-19 1994-04-28 Method for synthesis of high capacity lixmn2o4 secondary battery electrode compounds

Country Status (8)

Country Link
US (1) US5425932A (en)
EP (1) EP0701535B1 (en)
JP (1) JP3164583B2 (en)
CA (1) CA2163087C (en)
DE (1) DE69415011T2 (en)
DK (1) DK0701535T3 (en)
ES (1) ES2127392T3 (en)
WO (1) WO1994026666A1 (en)

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US5792442A (en) * 1995-12-05 1998-08-11 Fmc Corporation Highly homogeneous spinel Li1+X Mn2-X O4 intercalation compounds and method for preparing same
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Also Published As

Publication number Publication date
JPH08509098A (en) 1996-09-24
US5425932A (en) 1995-06-20
EP0701535A1 (en) 1996-03-20
EP0701535A4 (en) 1996-04-17
DE69415011T2 (en) 1999-08-12
ES2127392T3 (en) 1999-04-16
DK0701535T3 (en) 1999-08-30
EP0701535B1 (en) 1998-12-02
JP3164583B2 (en) 2001-05-08
WO1994026666A1 (en) 1994-11-24
CA2163087C (en) 1999-06-08
DE69415011D1 (en) 1999-01-14

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Effective date: 20030428