CA2182693A1 - Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices - Google Patents

Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices

Info

Publication number
CA2182693A1
CA2182693A1 CA002182693A CA2182693A CA2182693A1 CA 2182693 A1 CA2182693 A1 CA 2182693A1 CA 002182693 A CA002182693 A CA 002182693A CA 2182693 A CA2182693 A CA 2182693A CA 2182693 A1 CA2182693 A1 CA 2182693A1
Authority
CA
Canada
Prior art keywords
bodies
nucleophilic
substrate
bonded
siloxane polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002182693A
Other languages
French (fr)
Other versions
CA2182693C (en
Inventor
William R. Betz
James L. Desorcie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sigma Aldrich Co LLC
Original Assignee
William R. Betz
James L. Desorcie
Supelco, Inc.
Sigma-Aldrich Co.
Sigma-Aldrich Co. Newco Inc.
Sigma-Aldrich Co. Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by William R. Betz, James L. Desorcie, Supelco, Inc., Sigma-Aldrich Co., Sigma-Aldrich Co. Newco Inc., Sigma-Aldrich Co. Llc filed Critical William R. Betz
Priority to CA002365098A priority Critical patent/CA2365098C/en
Publication of CA2182693A1 publication Critical patent/CA2182693A1/en
Application granted granted Critical
Publication of CA2182693C publication Critical patent/CA2182693C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/281—Sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J20/286—Phases chemically bonded to a substrate, e.g. to silica or to polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3206—Organic carriers, supports or substrates
    • B01J20/3208—Polymeric carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3223—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating by means of an adhesive agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3238—Inorganic material layers containing any type of zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/324—Inorganic material layers containing free carbon, e.g. activated carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3268—Macromolecular compounds
    • B01J20/327—Polymers obtained by reactions involving only carbon to carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/80—Aspects related to sorbents specially adapted for preparative, analytical or investigative chromatography
    • B01J2220/86—Sorbents applied to inner surfaces of columns or capillaries
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/50—Conditioning of the sorbent material or stationary liquid
    • G01N30/52—Physical parameters
    • G01N2030/524—Physical parameters structural properties
    • G01N2030/528—Monolithic sorbent material
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/60—Construction of the column
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
    • G01N30/02—Column chromatography
    • G01N30/60—Construction of the column
    • G01N30/6034—Construction of the column joining multiple columns
    • G01N30/6043—Construction of the column joining multiple columns in parallel

Abstract

A structure comprising bodies having a functional surface property bonded to a substrate via a siloxane polymer adhesive. The structure may comprise a novel composition comprising a siloxane polymer having carbon bodies bonded thereto by direct carbon to silicon bonds. This composition may be used to bond carbon parti-cles through a medium comprising the siloxane polymer to a vitreous, metal, plastic or other nu-cleophilic substrate. Alternatively, the bodies may comprise alumina, silicon zeolite, organic poly-mers or other nucleophilic compositions, which are bonded directly to silicon atoms of the siloxane polymer. To bond carbon or other nucleophilic bodies to the substrate, the substrate is contacted with a mixture of the bodies and a hydrosiloxane polymer. The mixture is heated to cause the poly-mer to be bonded to the nucleophilic bodies, typ-ically by C-Si, C-O-Si, Si-O-Si or Si-O-Al bonds, and to the substrate by reaction with the surface silanol or other nucleophilic groups. Chromato-graphic methods using a column comprising the novel composition are also disclosed.
CA002182693A 1994-02-04 1995-02-02 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices Expired - Lifetime CA2182693C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA002365098A CA2365098C (en) 1994-02-04 1995-02-02 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US19164494A 1994-02-04 1994-02-04
US20175294A 1994-02-25 1994-02-25
US27604894A 1994-07-15 1994-07-15
US08/283,210 1994-07-29
US08/201,752 1994-07-29
US08/283,210 US5653875A (en) 1994-02-04 1994-07-29 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices
US08/276,048 1994-07-29
US08/191,644 1994-07-29
PCT/US1995/001336 WO1995021020A1 (en) 1994-02-04 1995-02-02 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA002365098A Division CA2365098C (en) 1994-02-04 1995-02-02 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices

Publications (2)

Publication Number Publication Date
CA2182693A1 true CA2182693A1 (en) 1995-08-10
CA2182693C CA2182693C (en) 2002-04-16

Family

ID=27497896

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002182693A Expired - Lifetime CA2182693C (en) 1994-02-04 1995-02-02 Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices

Country Status (6)

Country Link
US (6) US5653875A (en)
EP (1) EP0741606A1 (en)
JP (3) JPH09511532A (en)
AU (1) AU1910695A (en)
CA (1) CA2182693C (en)
WO (1) WO1995021020A1 (en)

Families Citing this family (82)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19611132A1 (en) * 1996-03-21 1997-09-25 Joachim Dr Pohl Heterogeneous catalyst, its preparation and its use
US6306959B1 (en) 1996-05-03 2001-10-23 Warner Lambert Company Rapid purification by polymer supported quench
SE9700769D0 (en) * 1997-03-04 1997-03-04 Pharmacia Biotech Ab Matrices for separation and separation that utilize the matrices
US6010646A (en) * 1997-04-11 2000-01-04 Potters Industries, Inc. Electroconductive composition and methods for producing such composition
US6136187A (en) * 1997-12-09 2000-10-24 The Board Of Trustees Of The Leland Stanford Junior University Separation column containing porous matrix and method of packing column
US6372283B1 (en) * 1999-04-02 2002-04-16 Medtronic, Inc. Plasma process for surface modification of pyrolitic carbon
EP1126275A3 (en) * 2000-02-18 2002-12-18 The Board Of Trustees Of The Leland Stanford Junior University Fused-silicia capillaries with photopolymer components
US6875348B2 (en) * 2000-02-18 2005-04-05 The Board Of Trustees Of The Leland Stanford Junior University Separation column having a photopolymerized sol-gel component and associated methods
US6866785B2 (en) * 2001-08-13 2005-03-15 The Board Of Trustees Of The Leland Stanford Junior University Photopolymerized sol-gel column and associated methods
JP3840524B2 (en) * 2000-02-21 2006-11-01 孝雄 津田 Hollow capillary column and method for producing the same
US6946070B2 (en) * 2000-03-14 2005-09-20 Hammen Richard F Composite matrices with interstitial polymer networks
JP2001281117A (en) * 2000-03-24 2001-10-10 Millipore Corp Sample adjusting device and sample adjusting device forming method
DE10016825A1 (en) * 2000-04-07 2001-10-11 Merck Patent Gmbh Monolithic sorbents with fiber-reinforced plastic coating
JP2001321425A (en) * 2000-05-17 2001-11-20 Osaka Prefecture Adsorbent and adsorbing material for volatile organic compound or the like
JP2004526126A (en) * 2000-09-01 2004-08-26 カボット コーポレーション Chromatography and other absorption methods using modified carbon-clad metal oxide particles
DE60038059D1 (en) * 2000-12-07 2008-03-27 Sun Plastics Co Ltd MATERIAL FOR COLLECTING CHEMICAL SUBSTANCES AND METHOD FOR THE PRODUCTION THEREOF AND TUBE FOR COLLAPING CHEMICAL SUBSTANCES
US20040129141A1 (en) * 2002-03-08 2004-07-08 Abdul Malik High efficiency sol-gel gas chromatography column
WO2002072225A1 (en) * 2001-03-09 2002-09-19 University Of South Florida High efficiency sol-gel gas chromatography column
EP1414548B1 (en) * 2001-06-08 2006-08-23 Donaldson Company, Inc. Adsorption element and methods
US20050092176A1 (en) * 2001-06-08 2005-05-05 Lefei Ding Adsorptive filter element and methods
DE10231922B4 (en) * 2002-07-15 2005-10-27 Bayer Technology Services Gmbh Apparatus and method for creating a liquid barrier
US6997977B2 (en) * 2002-07-31 2006-02-14 Donaldson Company, Inc. Adsorptive duct for contaminant removal, and methods
US20040069146A1 (en) * 2002-07-31 2004-04-15 Carter Steven Alan Adsorptive duct for contaminant removal, and methods
US6923895B2 (en) * 2002-09-09 2005-08-02 Beckman Coulter, Inc. Coated capillary electrophoresis tubes and system
WO2004071615A2 (en) 2003-02-07 2004-08-26 Waters Investments Limited Polymeric solid supports for chromatography nanocolumns
GB2413508B (en) * 2003-02-10 2007-02-21 Waters Investments Ltd Siloxane-Immobilized particulate stationary phases for chromatographic separations and extractions
JP4217881B2 (en) * 2003-04-28 2009-02-04 信越化学工業株式会社 Method for forming functional coating and functional coated article
WO2005018802A2 (en) * 2003-08-25 2005-03-03 Cabot Corporation Compositions and chromatography materials for bioseparation
US20060115384A1 (en) * 2003-09-16 2006-06-01 Vici Gig Harbor Group, Inc. Pipette tip surface sorption extraction
US20060115383A1 (en) * 2003-09-16 2006-06-01 Vici Gig Harbor Group, Inc. Flow through well plate surface sorption extarction
US20060110295A1 (en) * 2003-09-16 2006-05-25 Vici Gig Harbor Group, Inc. Closed well plate surface sorption extraction
US7087437B2 (en) * 2003-09-16 2006-08-08 Vici Gig Harbor Group, Inc. Direct vial surface sorbent micro extraction device and method
WO2005052544A2 (en) * 2003-11-20 2005-06-09 Sigma-Aldrich Co. Polysilazane thermosetting polymers for use in chromatographic systems and applications
DE502004008840D1 (en) * 2003-12-09 2009-02-26 Bgb Analytik Ag SAMPLE PREPARATION DEVICE
US20050127002A1 (en) * 2003-12-12 2005-06-16 Zare Richard N. Immobilized-enzyme microreactor devices for characterization of biomolecular analytes and associated methods
US7285219B2 (en) * 2004-08-10 2007-10-23 Prime Separations, Inc. Chromatographic separation member and method
US7452412B2 (en) * 2004-08-24 2008-11-18 Midwest Research Institute, Inc. High-efficiency filter device and method for making same
DE112005002839T5 (en) * 2004-11-16 2007-12-20 Waters Investments Ltd., New Castle Apparatus for performing separations and methods of making and using the same
US20060151382A1 (en) * 2005-01-12 2006-07-13 Petrik Viktor I Contact devices with nanostructured materials
FR2884253B1 (en) * 2005-04-08 2007-06-22 Univ Lille Sciences Tech FUNCTIONALIZABLE MONOLITHIC MATERIALS
SE0502485L (en) * 2005-11-09 2007-05-10 Peter Viberg particles
US20070284308A1 (en) * 2006-06-12 2007-12-13 Zare Richard N Immobilized-enzyme microreactor devices for characterization of biomolecular analytes and associated methods
US7559981B2 (en) * 2006-07-06 2009-07-14 J.M. Huber Corporation Air filtration media comprising oxidizing agent-treated metal-doped silicon-based gel and zeolite materials
FR2903616B1 (en) * 2006-07-13 2008-10-31 Veolia Eau Cie Generale Des Ea DEVICE AND METHOD FOR CAPTURING ODOR GENERATING SUBSTANCES AND / OR GOUTS PRESENTED IN CIRCULATING WATER IN A NETWORK.
US20080199256A1 (en) * 2006-10-19 2008-08-21 R.H. Dyck, Inc. Compositions, devices, and methods for use in environmental remediation
WO2008154523A2 (en) * 2007-06-08 2008-12-18 Protein Discovery, Inc. Improved methods and devices for concentration and fractionation of analytes for chemical analysis including matrix-assisted laser desorption/ionization (maldi) mass spectrometry (ms)
JP4931244B2 (en) * 2007-11-16 2012-05-16 理研計器株式会社 Hydrogen sulfide removal filter for gas detector
US20090173146A1 (en) * 2008-01-07 2009-07-09 Matthias Pursch Temperature programmed low thermal mass fast liquid chromatography analysis system
US20090221773A1 (en) * 2008-02-28 2009-09-03 Brigham Young University Methods for direct attachment of polymers to diamond surfaces and diamond articles
US20090218276A1 (en) * 2008-02-29 2009-09-03 Brigham Young University Functionalized diamond particles and methods for preparing the same
CA2723651C (en) * 2008-05-10 2014-02-11 Brigham Young University Porous composite particulate materials, methods of making and using same, and related apparatuses
US9192915B2 (en) * 2008-05-10 2015-11-24 Brigham Young University Porous composite particulate materials, methods of making and using same, and related apparatuses
WO2010033903A1 (en) * 2008-09-22 2010-03-25 Brigham Young University Functionalized graphitic stationary phase and methods for making and using same
CN101585666B (en) * 2009-06-22 2011-08-31 浙江新康药用玻璃有限公司 Inner surface coating technique of medicinal glass bottle
JP2011141271A (en) * 2009-12-08 2011-07-21 Yokogawa Electric Corp Column for gas chromatograph, and method for manufacturing the same
US20110210056A1 (en) * 2010-02-26 2011-09-01 Brigham Young University Gas phase approach to in-situ/ex-situ functionalization of porous graphitic carbon via radical-generated molecules
US8323747B2 (en) * 2010-06-25 2012-12-04 Uop Llc Zeolite containing wash coats for adsorber heat exchangers and temperature controlled adsorbers
AU2011329063A1 (en) 2010-11-17 2013-06-13 Brigham Young University Sonication for improved particle size distribution of core-shell particles
TW201228701A (en) * 2011-01-14 2012-07-16 Univ Chung Yuan Christian Stationary phase composition for chromatographic separation, and preparation method thereof
DE102012014335A1 (en) * 2012-07-19 2014-01-23 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Dispersion, process for coating counterstocks with this dispersion and use of the dispersion
US9075068B2 (en) 2012-08-31 2015-07-07 Agilent Technologies, Inc. Integrated particle trap for capillary plot columns
CA2859256A1 (en) * 2013-08-13 2015-02-13 William Marsh Rice University Nucleophilic porous carbon materials for co2 and h2s capture
WO2016094820A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Adsorbent for heteroatom species removal and uses thereof
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
WO2016094830A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Methods of separating aromatic compounds from lube base stockes
WO2016094861A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
US10022700B2 (en) 2014-12-12 2018-07-17 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
US10047304B2 (en) 2014-12-12 2018-08-14 Exxonmobil Research And Engineering Company Aromatic hydrogenation catalysts and uses thereof
US10207249B2 (en) 2014-12-12 2019-02-19 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
EP3230409A1 (en) 2014-12-12 2017-10-18 ExxonMobil Research and Engineering Company Organosilica materials and uses thereof
US10351639B2 (en) 2014-12-12 2019-07-16 Exxonmobil Research And Engineering Company Organosilica materials for use as adsorbents for oxygenate removal
CN107001859B (en) 2014-12-12 2019-04-05 埃克森美孚研究工程公司 Use the coating method and application thereof of organic silica (organosilica) material
WO2016094803A1 (en) 2014-12-12 2016-06-16 Exxonmobil Research And Engineering Company Membrane fabrication methods using organosilica materials and uses thereof
ITUB20152857A1 (en) * 2015-08-04 2017-02-04 Ettore Guerriero Analytical system based on carbon fibers
JP2019523746A (en) 2016-06-10 2019-08-29 エクソンモービル リサーチ アンド エンジニアリング カンパニーＥｘｘｏｎ Ｒｅｓｅａｒｃｈ Ａｎｄ Ｅｎｇｉｎｅｅｒｉｎｇ Ｃｏｍｐａｎｙ Organosilica material, process for its production and use thereof
EP3468712A1 (en) 2016-06-10 2019-04-17 Exxonmobil Research And Engineering Company Organosilica polymer catalysts and methods of making the same
US10179839B2 (en) 2016-11-18 2019-01-15 Exxonmobil Research And Engineering Company Sulfur terminated organosilica materials and uses thereof
JP6993421B2 (en) * 2017-03-14 2022-01-13 ダウ シリコーンズ コーポレーション A method for removing organosilicon components in a mixture using a sorbent copolymer, and an apparatus for carrying out the method.
EP3672723B1 (en) 2017-08-24 2023-10-18 Sigma-Aldrich Co. LLC Method for making improved hlb copolymers
WO2019069158A1 (en) * 2017-10-02 2019-04-11 Ali Reza Ghiasvand Modified cotton fabric for solid-phase extraction and fabrication method
CN111511465B (en) 2017-12-21 2023-06-06 埃克森美孚科技工程公司 Method for producing organic silicon dioxide material and use thereof
CN111771123A (en) * 2018-02-23 2020-10-13 西尔科特克公司 Liquid chromatography technique

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1140377B (en) * 1961-10-04 1962-11-29 Bodenseewerk Perkin Elmer Co Process for the production of capillary columns for gas chromatography
NL299544A (en) * 1962-10-23
US3418152A (en) * 1966-08-01 1968-12-24 Eastman Kodak Co Method of making a chromatographic element containing a resinous binder and product produced thereby
US3514925A (en) * 1967-09-05 1970-06-02 Mine Safety Appliances Co Gas chromatography column and method of making same
US3647684A (en) * 1968-04-17 1972-03-07 Dexter Corp Adding cationic material to silicic acid sorbent chromatographic sheet for improved performance
US3822530A (en) * 1970-06-08 1974-07-09 Phillips Petroleum Co Chromatographic column packing
US3772909A (en) * 1971-08-02 1973-11-20 Varian Associates Apparatus for analyzing environmental gases
DE2225973C2 (en) * 1972-05-27 1974-07-04 Merck Patent Gmbh, 6100 Darmstadt Process for coating non-porous material with a porous silicon dioxide layer
US3808125A (en) * 1972-08-25 1974-04-30 Phillips Petroleum Co Chromatographic apparatus
DE2315904C3 (en) * 1973-03-30 1975-09-11 Istvan Prof. Dr. 6600 Saarbruecken Halasz Packed chromatographic separation column
US4063911A (en) * 1973-07-17 1977-12-20 Applied Science Laboratories, Inc. High temperature polar stationary liquid phase for gas chromatography
US4043905A (en) * 1974-08-26 1977-08-23 Indiana University Foundation Chromatographic separation columns with selectively modified active surfaces and methods for their preparations
US4169790A (en) * 1975-05-02 1979-10-02 South African Inventions Development Corporation Solid surface texture suitable for a stationary phase for chromatography
US3988919A (en) * 1975-10-07 1976-11-02 The United States Of America As Represented By The United States Energy Research And Development Administration Use of graphitized carbon beads for gas liquid chromatography
US4218359A (en) * 1976-04-07 1980-08-19 Wacker-Chemie Gmbh Organopolysiloxane compositions and a process for treating organic fibers
DE2615078C2 (en) * 1976-04-07 1983-01-27 Wacker-Chemie GmbH, 8000 München Process for the treatment of organic fibers and the organopolysiloxane compositions used therein
DE2747277C2 (en) * 1977-10-21 1982-06-09 Degussa Ag, 6000 Frankfurt Granular organosilane preparation, its manufacture and use
JPS5489691A (en) * 1977-12-24 1979-07-16 Nippon Bunko Kogyo Kk Open tube type capillary column for micro rapid liquid chromatography and production thereof
US5128494A (en) * 1985-04-26 1992-07-07 Sri International Hydridosiloxanes as precursors to ceramic products
US4293415A (en) * 1979-04-27 1981-10-06 Hewlett-Packard Company Silica chromatographic column
US4276061A (en) * 1979-07-31 1981-06-30 The Dow Chemical Company Chromatographic column packing having a bonded organosiloxane coating
US4376641A (en) * 1981-12-14 1983-03-15 The Dow Chemical Company Coated capillary chromatographic column
JPS5952754A (en) * 1982-09-21 1984-03-27 Asahi Chem Ind Co Ltd Packing material for separation column
USH896H (en) * 1983-05-31 1991-03-05 Shell Oil Company Separating column for gas chromatography
JPS6094680A (en) * 1983-10-28 1985-05-27 東レ・ダウコーニング・シリコーン株式会社 Fiber treating agent
US4509964A (en) * 1984-01-04 1985-04-09 The Foxboro Company Fused silica capillary column
DE3427923A1 (en) * 1984-07-28 1986-01-30 Merck Patent Gmbh, 6100 Darmstadt SEPARATING MATERIAL FOR THICK LAYER CHROMATOGRAPHY
SE8405826L (en) * 1984-11-20 1986-05-21 Skf Ab TRANSPORTATION DEVICE WITH MULTIPLE TRANSPORTOR Beam
FI845161A0 (en) * 1984-12-28 1984-12-28 Ksv Chemicals Oy YTBEHANDLINGSMEDEL.
US4743377A (en) * 1985-07-02 1988-05-10 Shiseido Company Ltd. Packing material for liquid chromatography
DE3524493A1 (en) * 1985-07-09 1987-01-15 Wacker Chemie Gmbh METHOD FOR PRODUCING FOAMS
US4793920A (en) * 1985-12-11 1988-12-27 Lee Scientific, Inc. Chromatography columns with cast porous plugs and methods of fabricating same
US4900779A (en) * 1986-08-27 1990-02-13 Hercules Incorporated Organosilicon polymers
JP2504005B2 (en) * 1986-11-17 1996-06-05 東ソー株式会社 Filler and its manufacturing method
US4746572A (en) * 1986-11-28 1988-05-24 E. I. Dupont De Nemours And Company Structures surface modified with bidentate silanes
US5104530A (en) * 1988-01-29 1992-04-14 Maroldo Stephen G Chromatography column with carbonaceous adsorbents from pyrolyzed polysulfonated polymers
US4839331A (en) * 1988-01-29 1989-06-13 Rohm And Haas Company Carbonaceous adsorbents from pyrolyzed polysulfonated polymers
US5094754A (en) * 1988-01-29 1992-03-10 Rohm And Haas Company Carbonaceous adsorbents from pyrolyzed polysulfonated polymers
DE3808200A1 (en) * 1988-03-11 1989-09-21 Wacker Chemie Gmbh AT ROOM TEMPERATURE TO COMPATIBLE TO PAINTABLE ELASTOMER CROSSLINKING ORGANOPOLYSILOXANES
US4909935A (en) * 1988-06-03 1990-03-20 Brigham Young University Chromatographic arylcarboxamide polysiloxanes
US4895968A (en) * 1988-10-24 1990-01-23 General Electric Company Acid equilibration method for organcpolysiloxanes having carbon-silicon-bonded aromatic organic radicals
US4966785A (en) * 1989-07-03 1990-10-30 Associated Universities, Inc. Method for making a non-extractable stationary phase of polymer within a capillary column
US5015715A (en) * 1989-08-16 1991-05-14 Puritan-Bennett Corporation Method for bonding an analyte-sensitive dye compound to an addition-cure silicone
NL8902151A (en) * 1989-08-25 1991-03-18 Philips Nv METHOD FOR MANUFACTURING A SEPARATION COLUMN AND SEPARATION COLUMN
JPH03218458A (en) * 1989-10-02 1991-09-26 Shiseido Co Ltd Column packing material and its production
JP2874297B2 (en) * 1989-12-18 1999-03-24 東ソー株式会社 Packing material for reversed phase chromatography and method for producing the same
JP2879916B2 (en) * 1990-01-17 1999-04-05 日本カーボン株式会社 Carrier for gas chromatography using aggregated carbon particles and method for producing the same
US5271833A (en) * 1990-03-22 1993-12-21 Regents Of The University Of Minnesota Polymer-coated carbon-clad inorganic oxide particles
DE4023537A1 (en) * 1990-07-25 1992-01-30 Degussa CHEMICALLY MODIFIED ROUGS WITH ORGANOSILICIUM COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
US5268442A (en) * 1990-11-13 1993-12-07 Brigham Young University Chiral copolymers with oligosiloxane spacers
US5071565A (en) * 1991-02-04 1991-12-10 Iowa State University Research Foundation, Inc. Modified resins for solid-phase extraction
CA2059398C (en) * 1991-02-07 1999-05-25 Craig G. Markell Solid phase extraction medium
DE4122263C1 (en) * 1991-07-05 1993-02-25 Degussa Ag, 6000 Frankfurt, De
IL100105A (en) * 1991-11-20 1996-01-19 Univ Bar Ilan Supported microspheres
US5308481A (en) * 1992-06-02 1994-05-03 Analytical Bio-Chemistry Laboratories, Inc. Chemically bound fullerenes to resin and silica supports and their use as stationary phases for chromatography

Also Published As

Publication number Publication date
JP2005321405A (en) 2005-11-17
WO1995021020A1 (en) 1995-08-10
EP0741606A1 (en) 1996-11-13
AU1910695A (en) 1995-08-21
US5609756A (en) 1997-03-11
JP3913760B2 (en) 2007-05-09
JP4016051B2 (en) 2007-12-05
US5653875A (en) 1997-08-05
CA2182693C (en) 2002-04-16
US5620603A (en) 1997-04-15
JPH09511532A (en) 1997-11-18
US5607580A (en) 1997-03-04
US5630937A (en) 1997-05-20
JP2006215051A (en) 2006-08-17
US5599445A (en) 1997-02-04

Similar Documents

Publication Publication Date Title
CA2182693A1 (en) Nucleophilic bodies bonded to siloxane and use thereof for separations from sample matrices
EP0839872A3 (en) Curable polymer having reactive silicon-containing functional groups
JP4230114B2 (en) Capped silicone film and method for producing the same
EP0984036A3 (en) Curable polyolefin compositions containing organosilicon compounds as adhesion additives
JP2634343B2 (en) Semiconductor wafer holding method
CA2503137A1 (en) Continuous process for producing hot melt adhesive compositions
JPS57105446A (en) Curable composition
KR940005780A (en) Surface treatment agent and its use
EP0382094A3 (en) Adhesion method
HU9701467D0 (en) Use of poly(alpha- olefines) grafted with silane as a base material of a glu or glue curable by wetinfluence
JPS6472054A (en) Chromatograph material
EP0443860B1 (en) Method for preparing liquid chromatograph packing material, and material produced thereby
WO2002008333A1 (en) Curable composition and uses thereof
JPS62240360A (en) Curable organopolysiloxane composition
KR960031509A (en) Thermosetting silicone resin
EP1179567A4 (en) Curable compositions
WO2003011984A3 (en) Weldable coating compositions having improved intercoat adhesion
BR9910037A (en) Method for bonding a window to a substrate using an adhesive composition with silane functionality
Blomberg et al. In situ synthesis of highly thermostable, non-extractable, methylsilicone gum phases for glass capillary gas chromatography
WO2000040593A3 (en) Target molecule attachment to surfaces
EP0503975A2 (en) Addition-curable silicone adhesive compositions
EP0753021A1 (en) Curable silicon-containing polyether adhesive composition
KR890008601A (en) Similar UV Curable Coating Compositions
CA2125383A1 (en) Method for bonding substrates using molten moisture reactive organosiloxane compositions
AU1377101A (en) Addition cross-linked silicon rubber mixtures

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20150202