CA2198177A1 - High-molecular-weight polypropylene having a broad molecular-weight distribution - Google Patents

High-molecular-weight polypropylene having a broad molecular-weight distribution

Info

Publication number
CA2198177A1
CA2198177A1 CA002198177A CA2198177A CA2198177A1 CA 2198177 A1 CA2198177 A1 CA 2198177A1 CA 002198177 A CA002198177 A CA 002198177A CA 2198177 A CA2198177 A CA 2198177A CA 2198177 A1 CA2198177 A1 CA 2198177A1
Authority
CA
Canada
Prior art keywords
molecular
weight
polypropylene
weight distribution
range
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002198177A
Other languages
French (fr)
Other versions
CA2198177C (en
Inventor
Volker Dolle
Eduardo Chicote Carrion
Herbert Terwyen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7786044&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2198177(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2198177A1 publication Critical patent/CA2198177A1/en
Application granted granted Critical
Publication of CA2198177C publication Critical patent/CA2198177C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00—Rigid pipes
    • F16L9/12—Rigid pipes of plastics with or without reinforcement
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Abstract

The invention relates to a high-molecular-weight copolymer comprising ethylene and propylene units which has an ethylene content in the range from 1 to 10% by weight, a melt flow rate MFR (23015) of < 5 dg/min and a molecular-weight distribution M
w/M n in the range from 6 to 20. The invention also relates to a process for the preparation of the copolymer in the presence of a catalyst, an organoaluminum compound (B) and an organosilicon compound (C), in which the polymerization is carried out in two reaction steps, where the suspension medium in the first step is simultaneously the monomer, and a polypropylene having a viscosity of from 500 to 1400 ml/g which makes up a proportion of from 20 to 80% of the total polymer is prepared in the first reaction step.
CA002198177A 1996-02-22 1997-02-21 High-molecular-weight polypropylene having a broad molecular-weight distribution Expired - Fee Related CA2198177C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19606510.0 1996-02-22
DE19606510A DE19606510A1 (en) 1996-02-22 1996-02-22 High molecular weight polypropylene with a broad molecular weight distribution

Publications (2)

Publication Number Publication Date
CA2198177A1 true CA2198177A1 (en) 1997-08-22
CA2198177C CA2198177C (en) 2006-10-31

Family

ID=7786044

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002198177A Expired - Fee Related CA2198177C (en) 1996-02-22 1997-02-21 High-molecular-weight polypropylene having a broad molecular-weight distribution

Country Status (19)

Country Link
US (1) US6362298B2 (en)
EP (1) EP0791609B2 (en)
JP (2) JPH09235328A (en)
KR (1) KR100490705B1 (en)
AR (1) AR005934A1 (en)
AT (1) ATE246210T1 (en)
AU (1) AU1472797A (en)
BR (1) BR9701045A (en)
CA (1) CA2198177C (en)
CZ (1) CZ295993B6 (en)
DE (2) DE19606510A1 (en)
ES (1) ES2205078T3 (en)
HU (1) HU218856B (en)
IL (1) IL120260A (en)
NO (1) NO970799L (en)
PL (1) PL188614B1 (en)
SK (1) SK23297A3 (en)
TR (1) TR199700145A2 (en)
ZA (1) ZA971515B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6218504B1 (en) 1997-03-07 2001-04-17 Targor Gmbh Method for deodorizing polyolefin granulates

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19758124C1 (en) 1997-12-30 1999-11-18 Borealis Ag Polypropylene tube with high strength
JPH11255980A (en) * 1998-03-09 1999-09-21 Sumitomo Chem Co Ltd Packing film
SE518553C2 (en) † 1999-06-09 2002-10-22 Borealis As Profile for windows and doors of propylene block copolymer with nucleating agents and fillers
DE60106219T2 (en) * 2001-06-27 2006-03-09 Borealis Technology Oy Propylene copolymer with random comonomer distribution and process for its preparation
US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
EP1312623A1 (en) 2001-11-14 2003-05-21 Borealis Technology Oy Pressure pipes
ES2399823T3 (en) 2004-09-02 2013-04-03 Borealis Technology Oy A polymer pipe without pressure, a composition for it, and a process for its preparation
ATE435243T1 (en) 2005-05-20 2009-07-15 Borealis Tech Oy HIGH MELTING FLOW POLYMER WITH IMPROVED RESISTANCE FOR TUBE APPLICATIONS
ATE443737T1 (en) * 2005-05-20 2009-10-15 Borealis Tech Oy POLYPROPYLENE WITH IMPROVED PROCESSABILITY FOR PRODUCING PIPES
US7514509B2 (en) * 2005-12-16 2009-04-07 Fina Technology, Inc. Catalyst compositions and methods of forming isotactic polyproyplene
WO2007130306A2 (en) * 2006-05-05 2007-11-15 Dow Global Technologies Inc. Ortho-metallated hafnium complexes of imidazole ligands
US7470759B2 (en) * 2006-07-31 2008-12-30 Fina Technology, Inc. Isotactic-atactic polypropylene and methods of making same
JP5507263B2 (en) 2007-03-07 2014-05-28 ダウ グローバル テクノロジーズ エルエルシー Immobilized supported transition metal complexes
CN102325798A (en) * 2009-02-20 2012-01-18 伊内奥斯美国公司 Broadening the molecular weight distribution of polyolefins materials made in a horizontal stirred gas phase reactor
WO2011155999A1 (en) * 2010-06-10 2011-12-15 Ineos Usa Llc Controlling h2 distribution in a horizontal stirred bed reactor
EP2722348A1 (en) 2012-10-16 2014-04-23 Basell Poliolefine Italia S.r.l. Process for the preparation of propylene random copolymers
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US9593179B2 (en) 2014-02-07 2017-03-14 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins

Family Cites Families (14)

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JPS5438389A (en) * 1977-09-01 1979-03-22 Sumitomo Chem Co Ltd Preparation of highly crystalline polyolefin
JPS59172507A (en) * 1983-03-23 1984-09-29 Mitsui Petrochem Ind Ltd Production of polypropylene
US4970280A (en) * 1987-04-01 1990-11-13 Chisso Corporation Continuous process for producing high molten viscoelastic polypropylene or ethylene-propylene copolymer
US4950720A (en) * 1988-04-29 1990-08-21 Exxon Chemical Patents Inc. Modified polypropylene, process for making and article made from the same
KR920002488B1 (en) * 1988-06-17 1992-03-26 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 Process for polymerizing olefins and polymerization catalyst therefor
JP2713595B2 (en) * 1989-03-06 1998-02-16 三井東圧化学株式会社 Continuous polymerization of propylene
DE4009169A1 (en) * 1990-03-22 1991-09-26 Hoechst Ag METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL
DE4019053A1 (en) 1990-06-15 1991-12-19 Basf Ag POLYMERISATES OF PROPYLENE WITH A WIDE MOLECULAR RATIO Q
US5218052A (en) * 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
DE59209897D1 (en) * 1991-05-27 2001-04-26 Targor Gmbh Process for the production of polyolefins with a broad molar mass distribution
BE1005792A3 (en) * 1992-05-04 1994-02-01 Solvay CATALYST SYSTEM USED FOR stereospecific polymerization OF ALPHA-OLEFINS, POLYMERIZATION PROCESS FOR THIS AND POLYMERS.
IT1260497B (en) 1992-05-29 1996-04-09 Himont Inc PROPYLENE CRYSTALLINE POLYMERS HAVING IMPROVED STATE PROCESSABILITY AND PROCESS FOR THEIR PREPARATION
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6218504B1 (en) 1997-03-07 2001-04-17 Targor Gmbh Method for deodorizing polyolefin granulates

Also Published As

Publication number Publication date
AR005934A1 (en) 1999-07-21
DE19606510A1 (en) 1997-08-28
EP0791609A2 (en) 1997-08-27
KR970061922A (en) 1997-09-12
PL318608A1 (en) 1997-09-01
AU1472797A (en) 1997-08-28
HUP9700490A3 (en) 1999-04-28
EP0791609B2 (en) 2010-12-01
PL188614B1 (en) 2005-03-31
IL120260A0 (en) 1997-06-10
ES2205078T3 (en) 2004-05-01
HUP9700490A2 (en) 1997-12-29
US6362298B2 (en) 2002-03-26
SK23297A3 (en) 1998-10-07
US20020010297A1 (en) 2002-01-24
HU9700490D0 (en) 1997-04-28
TR199700145A2 (en) 1997-09-21
HU218856B (en) 2000-12-28
NO970799D0 (en) 1997-02-21
EP0791609A3 (en) 1997-09-03
IL120260A (en) 2003-11-23
CZ295993B6 (en) 2005-12-14
CA2198177C (en) 2006-10-31
BR9701045A (en) 1998-12-15
CZ54297A3 (en) 1997-09-17
JPH09235328A (en) 1997-09-09
NO970799L (en) 1997-08-25
ATE246210T1 (en) 2003-08-15
ZA971515B (en) 1998-01-26
DE59710484D1 (en) 2003-09-04
EP0791609B1 (en) 2003-07-30
KR100490705B1 (en) 2005-08-24
JP2008156664A (en) 2008-07-10

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