CA2207544C - Epdm, hnbr and butyl rubber compositions containing carbon black products - Google Patents

Epdm, hnbr and butyl rubber compositions containing carbon black products Download PDF

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CA2207544C
CA2207544C CA002207544A CA2207544A CA2207544C CA 2207544 C CA2207544 C CA 2207544C CA 002207544 A CA002207544 A CA 002207544A CA 2207544 A CA2207544 A CA 2207544A CA 2207544 C CA2207544 C CA 2207544C
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carbon black
rubber
epdm
hnbr
rubber composition
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CA2207544A1 (en
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James A. Belmont
Thomas F. Reed
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Cabot Corp
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Cabot Corp
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44—Carbon
    • C09C1/48—Carbon black
    • C09C1/56—Treatment of carbon black ; Purification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Sealing Material Composition (AREA)
  • Tires In General (AREA)

Abstract

A rubber composition prepared by the process comprising mixing 100 parts by weight of a rubber selected from EPDM, HNBR, and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group. The organic group has the formula -Ar-S n-Ar'- in which Ar and Ar' are arylene groups or -Ar-S n-Ar" in which Ar is an arylene group, Ar" is an aryl group and n is 1 to 8.

Description

EPDM, HNBR AND BUTYL RUBBER COMPOSITIONS
n CONTAINING CARBON BhACK PRODUCTS
BACKGROUND OF THE INVENTION
Field of the Invention The present invention relates to the use of carbon black products in EPDM, HNBR, and butyl rubber compositions to provide increased modulus and increased bound rubber as well as other valuable properties.
Discussion of Related Art.
EPDM, HNBR, and butyl rubber are well known rubber compositons used in a wide variety of industrial and consumer products. See McGraw-Hill Encyclopedia of Science & Technology, pp. 761-763 (McGraw-Hill, 1982). EPDM is a copolymer of ethylene-propylene-diene monomers. HNBR is a partially hydrogenated copolymer made from the copolymerization of acrylonitrile and butadiene. Butyl rubber is a copolymer of isobutylene and isoprene.
EPDM, HNBR, and butyl rubber compositions are used in a wide variety of products. These products include, for example, automotive parts, gaskets, cable and wire coatings, mechanical rubber products, cover strips for the sidewalls of tires, innertubes for tires, safety bumpers, fabric coatings, electrical wire insulation, hoses, mechanical rubber goods, and sealants for ponds or reservoirs.
One characteristic of EPDM, HNBR, and butyl rubber is their low levels of unsaturation. The low level of unsaturation in EPDM, HNBR, and butyl rubber limits the effectiveness of reinforcing agents in rubber compositions made from these rubbers. This is particularly true when compared with the use of reinforcing agents in diene rubbers which have high degrees of unsaturation. Butyl rubber, for example, is generally a polybutylene with 0.5-4.5% of a diolefin, normally 3% isoprene. The small amount of diolefin in butyl rubber provides unsaturation for reinforcement and crosslinking.
Carbon blacks have been utilized as pigments, fillers, and/or reinforcing agents in the compounding and preparation of rubber compositions. The properties of the carbon black are important factors in determining various performance properties of the rubber composition containing the carbon black. See, for example, U.S. Pat. No.
5,236,992.
It would be desirable to develop a carbon black product which would impart desirable properties to EPDM, HNBR, and butyl rubber compositions containing the carbon black product.
SUMMARY OF THE INVENTION
Accordingly, the present invention provides new rubber compositions prepared by the process comprising mixing 100 parts by weight of a rubber selected from EPDM, HNBR, and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group of the formula: -Ar-(S)n-Ar'- in which Ar and Ar' are arylene groups and n is 1 to 8, preferably 2 to 4.
In another embodiment, the invention provides a rubber composition prepared by the process comprising mixing 100 parts by weight of a rubber selected from EPDM, HNBR, butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group of the formula: -Ar-(S)n Ar" in which Ar is an arylene group, Ar" is an aryl group and n is 1 to 8, preferably 2 to 4.
The rubber compositions of the invention show increased modulus and increased bound rubber compared to that of the corresponding carbon blacks without the attached organic groups. Other features of the present invention will become apparent from the following detailed description of the invention and the claims.
DOCSM'rL: I 88028011 DETAILED DESCRIPTION OF THE INVENTION
The present invention relates to a rubber composition prepared by the process comprising mixing 100 parts by weight of a rubber selected from EPDM, HNBR, and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group. The organic groups have the general formula -Ar-(S)"-Ar'- in which Ar and Ar' are arylene groups or the general formula -Ar-(S)"-Ar" in which Ar is an arylene group and Ar" is an aryl group. In each of the general formulas the integer n varies from 1 to 8, preferably 2 to 4.
The carbon black product is prepared by reacting a carbon black with a diazonium salt corresponding to the organic group in a liquid reaction medium to attach at least one organic group to the surface of the carbon black. According to the invention, a diazonium salt is an organic compound having one or more diazonium groups. The diazonium salt can be conveniently prepared using means known in the art from a primary amine corresponding to the organic group, for example, Hz N-Ar-(S)" -Ar'-NHz or Hz N-Ar-(S)" -Ar". Preferred reaction media include water, any medium containing water, and any medium containing alcohol. These carbon black products and various methods for their preparation are described in U.S. 5851280 entitled "Reaction of Carbon Black with Diazonium Salts, Resultant Carbon Black Products and Their Uses".
Preparation of such carbon black products are also shown in the Examples below.
These carbon black products having organic groups of the formula: -Ar-(S)"-Ar'-or -Ar-(S)"-Ar" are particularly useful in EPDM, HNBR, and butyl rubber compositions.
In these organic groups Ar and Ar' are independently arylene groups, Ar" is an aryl and n is 1 to 8. Preferred arylene groups include phenylene groups, particularly p-phenylene groups. Preferred aryl groups include phenyl and naphthyl.
~ocsM~r~: isHOZSOn WO 96!18674 PCT/IB95/01154 The number of sulfurs present defined by n preferably r ranges from 2 to 4. A particularly preferred organic group is bis-pares- ( C6H4 ) -SZ- ( C6H4 ) - .
The above carbon black products may be mixed with EPDM, HNBR, or butyl rubbers by normal means known in the art, for example by milling. The rubber compositions containing the carbon black products can be cured using conventional sulfur-based or peroxide systems. Other conventionally used additives may be added to the rubber compositions of this invention.
Generally, amounts of~the carbon black product ranging from about 10 to about 300 parts by weight can be used for each 100 parts by weight of the rubber in order to impart a significant degree of reinforcement. It is, however, preferred to use amounts varying from about 50 to about 200 parts by weight of carbon black product per 100 parts by weight of the rubber and especially preferred is the utilization of from about 70 to about 150 parts of carbon black product per 100 parts of the rubber.
The presence of the carbon black products discussed above improves the physical characteristics of the rubber compositions of the invention as compared with the corresponding untreated carbon blacks. Incorporating the carbon black products into the rubber compositions increases the modulus and bound rubber properties of the rubber compositions.
The following examples are intended to illustrate, not limit, this invention.
ASTM test procedures were used to evaluate the rubber compositions of the invention shown in the Examples below. , Iodine number was measured using ASTM D-1510. DBPA was measured using ASTM D-2414. Tensile elongation and modulus were measured using ASTM D-412. Shore A hardness was measured using ASTM D-2240-86. Viscosity was measured using a MPT viscometer at 100oC and 100s-1 with Z/D = 16/1 in the capillary.
Tan b was measured with a Rheometrics Dynamic Spectrometer Model RDS-2 at a constant frequency of 10 Hz, ~at room temperature, and in the shear mode of strain.
Strain sweeps were run from 0.088 to 10~ DSA. Measurements were taken at five points per decade and the maximum Tan b was reported.
Bound rubber was determined as follows: A 0.5 g sample of an uncured rubber composition containing a rubber and a known amount of a carbon black was placed in a wire cage and submerged in a solvent. After standing for one day, the sample was placed in fresh solvent, and allowed to stand for three additional days at room temperature. The sample was then removed, dried in an oven, and weighed.
The weight of the carbon black was subtracted from weight of the sample before and after the solvent treatment to give a value for the amount of rubber in each sample. The weight of the sample after the solvent treatment, adjusted for the weight of the carbon black and other insoluble ingredients in the composition, represents the amount of insoluble rubber remaining. Bound rubber was expressed as the percentage of the weight of insoluble rubber in the sample after standing in the solvent versus the amount of rubber in the original sample.
Example 1 Preparation of a carbon black product This example describes the preparation of a carbon black product for use in the present invention.
Concentrated HC1 (2.62g) was diluted with 30 g and added to a stirring mixture of 1.5 g p-aminophenyl disulfide in 100 g of water. The resulting solution was cooled in an ice bath and a cold solution of 0.95 g NaN02 in 40 g of water was added with stirring. 4-Diazophenyl disulfide is formed. The solution was added to a suspension of 150 g of pelleted carbon black (iodine number of 19 mg~g and a DBPA
of 95 ml/100g) in 1200 mZ of water at about 14°C with stirring. Bubbles were released. After stirring for 2 1/4 hours, the product was filtered, washed with 800 mL of ethanol, washed with 2L of water, and dried at 125oC. This process produced a carbon black product having dithiodi(4,1-phenylene) groups attached to the carbon black.
Example 2 Reference carboy black A reference carbon black was prepared by washing 158 g of the unreacted carbon black of Example 1 with 800 mL of ethanol, about 2 L of water, and subsequently drying in an oven at 125oC.
Example 3 Preparation of a carbon black product This example describes the preparation of a carbon black product for use in the present invention.
Concentrated HC1 (5.70 g) was diluted with 30 g of water and added to a stirring mixture of 3.50 g p-aminophenyl disulfide in 100 g of water. The resulting solution was cooled in an ice bath and a cold solution of 2.11 g NaN02 in 50 g of water was added with stirring. 4-Diazophenyl disulfide is formed. The solution was added to a suspension of 250 g of pelleted carbon black (iodine number of 36 mg/g and a DBPA of 122 ml/100g) in 1500 mL of water at about 14°C with stirring. Bubbles were released. After stirring for 2 hours, the product was filtered, washed with 1.1 L of ethanol, washed with 3 L of water, and dried at 125°C. A sample of the carbon black product that was extracted overnight with tetrahydrofuran (THF) and dried contained 1.32 sulfur, compared to 0.99 for the unreacted ~.
carbon black. Therefore, the product contained 0.05 mmol/g of dithiodi(4,1-phenylene) groups.

_ 7 _ Example 4 Reference carbon black A reference carbon black was prepared by washing 250 g of the unreacted carbon black of Example 3 with 1.1 L of ethanol, about 3 L of water, and subsequently drying in an oven at 125oC.
Example 5 Use of a carbon black product 9.n EPDM
This example illustrates the use of the carbon black product of Example 1, the washed carbon black reference of Example 2 and the unwashed carbon black reference from Example 1 in EPDM. VISTALON 5600 EPDM (81.4 g) (VISTALON
is a registered trademark of Exxon Chemical Americas, Houston, TX) was milled in a Brabender mixer for one minute at an initial temperature of 45oC at 77 rpm. A paraffinic oil ASTM D-2226, type 104B, (122.1 g) was added and mixed for one minute. The carbon black (122.1 g) was added and mixed for 2 1/2 minutes. Zinc oxide (4.07 g) and 0.81 g of stearic acid were added and mixed for two minutes.
Tetramethyl thiuram disulfide (2.2 g), 2.2 g of zinc dibutyldithiocarbamate, 2.2 g of zinc dimethyldithiocarbamate, 0.41 g of sulfur and 1.38 g of 4,4'dithiodimorpholine were added and mixed for an additional two minutes. Bound rubber was determined using toluene as the solvent at room temperature. The table below shows that the carbon black product of Example 1 is useful in EPDM and increases modulus and bound rubber.

3 ~ Sample TensileElongationModulusModulusHardnessViscosityBound MPa ~ 100 3008 Sh A Pa-s Rubber ~

MPa MPa g Ex. 1 10.9 553 1.62 5.96 47 2120 8.8 Ref. 12.4 731 1.26 3.75 46 2130 5.8 Ex. 2 Ref. 11.9 679 1.38 4.16 46 2080 7.1 , Unwashed Example 6 Use of a carbon black product in EPDM
This example illustrates the use of the carbon black product of Example 3, the washed carbon black reference of Example 4 and the unwashed carbon black reference from Example 3 in EPDM. VISTAZON 5600 EPDM (81.4 g) was milled in a Brabender mixer for one minute at an initial temperature of 60oC at 50 rpm. A paraffinic oil ASTM D-2226, type 104B, .(122.1 g) was added and mixed for one minute. The carbon black (122.1 g) was added and mixed for 2 1/2 minutes. Zinc oxide (4.07 g) and 0.81 g of stearic acid were added and mixed for two minutes. Tetramethyl thiuram disulfide (2.2 g), 2.2 g of zinc dibutyldithiocarbamate, 2.2 g of zinc dimethyldithiocarbamate, 0.41 g of sulfur and 1.38 g of 4,4'dithiodimorpholine were added and mixed for an additional two minutes. Bound rubber was determined using toluene as solvent at room temperature. The table below shows that the carbon black product of Example 3 is useful in EPDM and increases modulus and bound rubber.
r 2 5 Sample TensileElongationModulusModulusHardnessViscosityBound MPa 8 100 300 Sh A Pa-s Rubber 'k MPa MPa 'k Ex. 3 10.0 364 2.93 8.61 63 2260 44.8 Ref. 10.6 467 2.63 7.14 62 2230 39.6 Ex. 4 f Ref. 9.8 941 2.63 7.13 62 2150 39.8 3 ~ Unwashed c Example 7 Use of a carbon black product in butyl rubber 35 This example illustrates the use of the carbon black g product of Example 3, the washed carbon black reference of Example 4 and the unwashed carbon black reference from Example 3 in butyl rubber. Butyl rubber 301 (181.1g) was milled in a Brabender mixer at 40 rpm for 30 seconds at an initial temperature of 30oC. A paraffinic oil ASTM D-2226, type 104B, (21.7 g) and the carbon black (135.9 g) were added and mixed for two minutes. Zn0 (9.1 g) and sulfur (2.7 g) were added and milling was continued for 3 1/2 minutes. Tetramethyl thiuram disulfide (3.6 g) and mercaptobenzothiazole (1.8 g) were added and mixed for an additional 1 1/2 minutes. Bound rubber was determined using cyclohexane as solvent at room temperature. The table below shows that the carbon black product of Example 3 is useful in butyl rubber, increases modulus and bound rubber, and decreases hysteresis as shown by higher rebound and lower Tan 8.
Sample TensileElonga-Modu-Modu- Hard- ReboundTan Visco-Bound MPa tion lus lus ness 9 $ sity Rubber 1009 3008 Sh Pa-s A

MPa MPa Ex. 11.7 470 3.49 9.43 74 13.2 0.29 5020 7.54 2 0 Ref. 10.6 528 2.97 7.58 70 12.2 0.35 4880 3.54 Ex.

Ref. 10.2 520 2.94 7.51 71 12.1 0.37 4850 4.42 Unwash-ed Example 8 Preparation of a carbon black product This example illustrates the preparation of a carbon black product useful in the rubber compositions of the present invention. A carbon black with an iodine number of 120 mg/g and a DBPA of 125 m1/100 g was used. A cold solution of 2.65 g concentrated HC1 and 30 g water was added to a mixture of 2.85 g 4-aminophenyl phenyl disulfide in 50 g water that was stirring in an ice bath. A cold solution of 1.04 g NaN02 in 30 g of water was added over a period of l0 minutes. 4-Diazophenyl phenyl disulfide chloride was formed. The diazonium suspension was added to a suspension of 122 g carbon black in about 800 g water that was stirring at 15°C. Bubbles were released. After stirring for about two hours, the carbon black product was filtered off, washed with isopropanol, washed with water, and dried in an oven at about 125°C. A sample of the carbon black product that had been subjected to Soxhlet extraction overnight with THF and dried had a sulfur content of 1.32, compared to 1.08 for the untreated carbon black.
Therefore, the carbon black product had 0.038 mmol/g of attached phenyldithiophenylene groups. This carbon black product may be incorporated into a rubber composition of the invention in accordance the examples above.
Example 9 Use of a carbon black product in HNBR
Following generally the procedures of Examples 5-7, a carbon black product such as shown in Examples 1-4 and 8 may be incorporated into HNBR to form a rubber composition of the invention.

Claims (12)

Claims:
1. A rubber composition prepared by a process comprising mixing 100 parts by weight of rubber selected from EPDM, HNBR and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group of the formula:
-Ar-Sn-Ar'-in which Ar and Ar' are arylene groups and n is 1 to 8.
2. A rubber composition of claim 1, wherein n is 2 to 4.
3. A rubber composition of claim 1 or 2, wherein the process further comprises curing the mixture of the rubber and the carbon black product.
4. A rubber composition of claim 1, 2 or 3, wherein Ar and Ar' are p-phenylene.
5. A rubber composition of claim 4, wherein n is 2.
6. A rubber composition of claim 1, 2, 3, 4 or 5, wherein the rubber is EPDM.
7. A rubber composition prepared by a process comprising mixing 100 parts by weight of rubber selected from EPDM, HNBR and butyl rubber, and 10 to 300 parts by weight of a carbon black product having an attached organic group of the formula:
-Ar-Sn-Ar"
in which Ar is an arylene group, Ar" is an aryl group and n is 1 to 8.
8. A rubber composition of claim 7 wherein n is 2 to 4.
9. A rubber composition of claim 7 or 8, wherein the process further comprises curing the mixture of the rubber and the carbon black product.
10. A rubber composition of claim 7, 8 or 9, wherein Ar is phenylene and Ar"
is phenyl.
11. A rubber composition of claim 10, wherein n is 2.
12. A rubber composition of claim 7, 8, 9, 10 or 11, wherein the rubber is EPDM.
CA002207544A 1994-12-15 1995-12-14 Epdm, hnbr and butyl rubber compositions containing carbon black products Expired - Fee Related CA2207544C (en)

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US08/356,459 US5559169A (en) 1994-12-15 1994-12-15 EPDM, HNBR and Butyl rubber compositions containing carbon black products
US08/356,459 1994-12-15
PCT/IB1995/001154 WO1996018674A1 (en) 1994-12-15 1995-12-14 Epdm, hnbr and butyl rubber compositions containing carbon black products

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JP (1) JP3672926B2 (en)
KR (1) KR100379729B1 (en)
AR (1) AR000351A1 (en)
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IN (1) IN192665B (en)
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CA2882515C (en) 2012-08-31 2016-10-18 Soucy Techno Inc. Rubber compositions reinforced with fibers and nanometric filamentary structures, and uses thereof
US20140120339A1 (en) 2012-10-31 2014-05-01 Cabot Corporation Porous carbon monoliths templated by pickering emulsions
US9840611B2 (en) 2013-10-18 2017-12-12 Soucy Techno Inc. Rubber compositions and uses thereof
US9663640B2 (en) 2013-12-19 2017-05-30 Soucy Techno Inc. Rubber compositions and uses thereof
CN105440378A (en) * 2015-06-10 2016-03-30 国网山东省电力公司临沂供电公司 Insulating material for power distribution system
CN105367859A (en) * 2015-08-16 2016-03-02 国网山东省电力公司临沂供电公司 High-temperature-resistant and dampproof cable for industry
JP6682248B2 (en) * 2015-11-30 2020-04-15 株式会社ブリヂストン Rubber composition
US10204715B2 (en) * 2016-03-31 2019-02-12 Schlumberger Technology Corporation Submersible power cable
US20200070579A1 (en) 2018-09-04 2020-03-05 The Goodyear Tire & Rubber Company Pneumatic tire
KR20230008121A (en) 2020-04-20 2023-01-13 비욘드 로투스 엘엘씨 Elastomer composition with carbon nanostructured filler

Family Cites Families (136)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2121535A (en) * 1934-09-22 1938-06-21 Cabot Godfrey L Inc Granular product and method of preparing the same
US2156591A (en) * 1936-06-29 1939-05-02 Sealco By Products Company Manufacture of carburized silica
US2502254A (en) * 1945-12-07 1950-03-28 Ici Ltd Manufacture of pigments
US2514236A (en) * 1948-03-12 1950-07-04 Ici Ltd Manufacture of pigments
DE957755C (en) * 1949-06-08 1957-01-17 W. R. Grace a Co., New York, N. Y. (V. St. A.) Process for the production of a silica gel suitable as a matting agent for paints or the like
US2833736A (en) * 1953-07-20 1958-05-06 Western Union Telegraph Co Aqueous graphite-polyvinyl alcohol ink composition
US3011902A (en) * 1954-05-27 1961-12-05 Cabot Corp Process of manufacturing carbon black pellets for inks
GB862018A (en) 1957-01-16 1961-03-01 Etude Des Ind Du Petrole Au Po Water-dispersible carbon black and production thereof
FR1164786A (en) 1957-01-16 1958-10-14 Etude Des Ind Du Petrole Au Po Water soluble carbon black and its preparation
US3043708A (en) * 1958-07-22 1962-07-10 Dunlop Rubber Co Modified carbon black
GB910309A (en) * 1958-07-22 1962-11-14 Dunlop Rubber Co Rubber compositions
FR1215895A (en) 1958-11-21 1960-04-21 Etude Des Ind Du Petrole Au Po Modified carbon black, its preparation and applications
FR1224131A (en) 1959-01-16 1960-06-22 Etude Des Ind Du Petrole Au Po Modified soluble carbon blacks, their preparation and applications
US3335020A (en) * 1964-03-02 1967-08-08 Huber Corp J M Modified carbon blacks
US3674670A (en) * 1964-12-04 1972-07-04 Ppg Industries Inc Coating method
US3479300A (en) * 1965-10-22 1969-11-18 Cabot Corp Carbonaceous products
UST860001I4 (en) * 1966-12-22 1969-03-18 Defensive publication
US3528840A (en) * 1967-11-15 1970-09-15 Huber Corp J M Sulfonated carbon black
US3607813A (en) * 1969-09-05 1971-09-21 Union Carbide Corp Printing ink compositions
US3876603A (en) * 1970-06-22 1975-04-08 Ppg Industries Inc Method of encapsulating pigments in organic dispersions of polymers
US3686111A (en) * 1970-06-22 1972-08-22 Ppg Industries Inc Non-aqueous polymeric pseudo-dispersion
US4014844A (en) * 1970-06-26 1977-03-29 Agence Nationale De Valorisation De La Recherche (Anvar) Process for grafting polymers on carbon black through free radical mechanism
US3846141A (en) * 1970-12-07 1974-11-05 Dick Co Ab Jet printing ink composition
GB1506464A (en) * 1974-05-29 1978-04-05 Degussa Aqueous carbon black preparation
US4003751A (en) * 1974-09-05 1977-01-18 Union Carbide Corporation Coating and ink compositions
JPS51137506A (en) * 1975-05-22 1976-11-27 Konishiroku Photo Ind Composition of ink for ink jet recording
US4014833A (en) * 1975-11-28 1977-03-29 Owens-Illinois, Inc. Aqueous printing ink with polyethylene oxide
US4061830A (en) * 1975-12-23 1977-12-06 Ppg Industries, Inc. Selective solar energy receiver and method for its production
US4204871A (en) * 1978-04-04 1980-05-27 Sun Chemical Corporation Printing inks containing nucleated organic pigments
US4204876A (en) * 1978-07-17 1980-05-27 M. Hamburger & Sons, Inc. Cement coloring composition and method of producing same
JPS5682859A (en) * 1979-12-11 1981-07-06 Sakura Color Prod Corp Ink composition
US4290072A (en) * 1980-01-28 1981-09-15 American Can Company Opaque jet ink printing method and composition
JPS56128362A (en) 1980-03-05 1981-10-07 Toho Beslon Co Production of carbon fiber
US4293394A (en) * 1980-03-31 1981-10-06 Ppg Industries, Inc. Electrolytically producing chlorine using a solid polymer electrolyte-cathode unit
DE3115532A1 (en) * 1980-04-17 1982-01-28 Canon K.K., Tokyo INK-JET RECORDING METHOD AND RECORDING INK FOR RECORDING ON AN IMAGE RECEIVER
US4478905A (en) * 1980-04-21 1984-10-23 Ppg Industries, Inc. Spandrel product with silicate coating
US4476270A (en) * 1980-06-06 1984-10-09 E. I. Du Pont De Nemours And Company Process for making high solids acrylic dispersion lacquer
US4328041A (en) * 1980-06-09 1982-05-04 Milliken Research Corporation Comminuted inorganic materials
DE3039527C2 (en) 1980-10-20 1984-02-02 Chemische Werke Brockhues AG, 6229 Walluf Colorants for cementitious objects
EP0098338B1 (en) * 1982-07-09 1988-04-20 Battelle Memorial Institute Low viscosity stable aqueous dispersion of graft carbon black
DE3228723A1 (en) * 1982-07-31 1984-02-02 Basf Farben + Fasern Ag, 2000 Hamburg STORAGE-STABLE, HEAT-CURABLE MATERIAL MIXTURES MADE OF POLYISOCYANATE AND COMPOUNDS WITH REACTIVE COMPOSITIONS, METHOD FOR THE PRODUCTION AND USE THEREOF
DE3274553D1 (en) * 1982-08-09 1987-01-15 Ford Motor Co Glycidyl-hydroxy-acrylic high solids coating compositions
DE3276818D1 (en) * 1982-08-09 1987-08-27 Ford Motor Co High solids coating compositions
US4451597A (en) * 1982-11-15 1984-05-29 E. I. Du Pont De Nemours And Company High solids color coat containing alcohol soluble cellulose acetate butyrate
US4442256A (en) * 1982-12-16 1984-04-10 E. I. Du Pont De Nemours And Company Additive for alkyd resin coating compositions
US4605596A (en) * 1982-12-20 1986-08-12 E. I. Du Pont De Nemours And Company Additive for coating compositions
DE3311513A1 (en) * 1983-03-30 1984-10-04 Basf Farben + Fasern Ag, 2000 Hamburg HEAT-CURABLE COATING AGENTS AND THEIR USE
US4680204A (en) * 1983-09-06 1987-07-14 Ppg Industries, Inc. Color plus clear coating system utilizing inorganic microparticles
US4503174A (en) * 1983-09-06 1985-03-05 E. I. Du Pont De Nemours And Company Low temperature curing coating composition
US4525521A (en) * 1983-10-14 1985-06-25 E. I. Du Pont De Nemours And Company Coating composition of an acrylic polymer having amino ester groups and a glycidyl acrylic polymer
US4556427A (en) * 1983-12-12 1985-12-03 Union Camp Corporation Use of humates in printing inks
US4503175A (en) * 1983-12-19 1985-03-05 E. I. Du Pont De Nemours And Company Acrylic polyurethane coating composition
US4555535A (en) * 1984-03-07 1985-11-26 E. I. Du Pont De Nemours And Company Acrylic polyurethane coating composition
US4620994A (en) * 1984-03-30 1986-11-04 Ppg Industries, Inc. Color plus clear coating system utilizing organo-modified clay
US4620993A (en) * 1984-03-30 1986-11-04 Ppg Industries, Inc. Color plus clear coating system utilizing organo-modified clay in combination with organic polymer microparticles
FR2564489B1 (en) 1984-05-18 1986-10-10 Onera (Off Nat Aerospatiale) ELECTROCHEMICAL PROCESS FOR THE SURFACE TREATMENT OF CARBON FIBERS, FIBER TREATED BY THIS PROCESS AND COMPOSITE MATERIAL COMPRISING SUCH FIBERS
US4665128A (en) * 1984-09-17 1987-05-12 E. I. Du Pont De Nemours And Company Flexible coating compositions
US4719132A (en) * 1984-09-21 1988-01-12 Ppg Industries, Inc. Process for the preparation of multi-layered coatings and coated articles derived therefrom
US4692481A (en) * 1984-09-27 1987-09-08 E. I. Du Pont De Nemours And Company Process for matching color of paint to a colored surface
US4741780A (en) * 1985-02-11 1988-05-03 Atkinson George K Treatment of titanium dioxide and other pigments to improve dispersibility
US5026755A (en) * 1985-03-13 1991-06-25 Sun Chemical Corporation Water-based printing ink prepared from polyamide/acrylic graft copolymers
JPS61250042A (en) * 1985-04-30 1986-11-07 Bridgestone Corp Rubber composition with high wear resistance
US5008335A (en) * 1985-08-07 1991-04-16 Ppg Industries, Inc. Powder coating compositions of polyepoxides, acrylic copolymers and aliphatic or polyester dibasic acids
US4681811A (en) * 1985-08-19 1987-07-21 Ppg Industries, Inc. Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat
US4650718A (en) * 1985-08-19 1987-03-17 Ppg Industries, Inc. Color plus clear coatings employing polyepoxides and polyacid curing agents
US4883838A (en) * 1985-09-30 1989-11-28 Basf Lacke & Farben Ag Soluble acrylate copolymer containing carboxyl groups, processes for its preparation and coating agents based on the acrylate copolymer
DE3545618A1 (en) * 1985-12-21 1987-06-25 Basf Lacke & Farben WATER-DISCOVERABLE COATING AGENT FOR PRODUCING THE BASE LAYER OF A MULTILAYER COATING
US4659770A (en) * 1986-02-03 1987-04-21 E.I. Du Pont De Nemours And Company Coating composition of an amine polymer and a blocked polyisocyanate
US4764430A (en) * 1986-03-07 1988-08-16 Ppg Industries, Inc. Crosslinkable compositions containing polyepoxides and polyacid curing agents
US4727100A (en) * 1986-08-15 1988-02-23 E. I. Du Pont De Nemours And Company Coating composition containing a reactive urethane component an acrylic fatty acid drying oil resin and a metallic alkylate
DE3629470A1 (en) 1986-08-29 1988-03-10 Basf Lacke & Farben CARBOXYL GROUPS AND TERTIAL AMINO GROUPS CONTAINING POLYCONDENSATION AND / OR ADDITION PRODUCT, COATING AGENTS BASED ON THE SAME AND THEIR USE
US5319044A (en) 1986-09-10 1994-06-07 Basf Lacke + Farben Ag Branched polymer containing silyl groups, a process for the preparation thereof, coating agents based on the polymer, and the use thereof
DE3636726C1 (en) * 1986-10-29 1988-03-17 Pelikan Ag Aqueous writing fluids and a process for their preparation
US4752532A (en) * 1986-10-31 1988-06-21 E. I. Du Pont De Nemours And Company Polyester primer composition
FR2607528B1 (en) 1986-12-02 1989-03-17 Onera (Off Nat Aerospatiale) ELECTROCHEMICAL PROCESS FOR CARBON SURFACE TREATMENT; CARBON, ESPECIALLY CARBON FIBERS, TREATED BY THIS PROCESS AND COMPOSITE MATERIAL COMPRISING SUCH FIBERS
US4880857A (en) * 1986-12-17 1989-11-14 Nippon Shokubai Kagaku Kogyo Co., Ltd. Carbon black-graft polymer, method for production thereof, and use thereof
JPH068366B2 (en) * 1987-04-23 1994-02-02 株式会社ブリヂストン Rubber composition for tires
US4808656A (en) * 1987-05-04 1989-02-28 Ppg Industries, Inc. High solids coating compositions
US4840674A (en) * 1987-06-01 1989-06-20 Xerox Corporation Ink compositions
US4789400A (en) * 1987-07-10 1988-12-06 Xerox Corporation Waterfast ink jet compositions and process
US4927868A (en) * 1987-08-19 1990-05-22 Ppg Industries, Inc. High solids coating compositions containing a polyepoxide and a copolymer of an alpha-olefin and an olefinically unsaturated monoanhydride
US4798745A (en) * 1987-08-24 1989-01-17 Ppg Industries, Inc. Non-yellowing coating composition based on a hydroxy component and an anhydride component and utilization in a process of coating
US4798746A (en) * 1987-08-24 1989-01-17 Ppg Industries, Inc. Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability
US4853037A (en) * 1987-10-30 1989-08-01 Hewlett-Packard Company Low glycol inks for plain paper printing
ZA891937B (en) * 1988-04-04 1990-11-28 Ppg Industries Inc Pigment grinding vehicles containing quaternary ammonium and ternary sulfonium groups
US5017435A (en) * 1988-06-27 1991-05-21 E. I. Du Pont De Nemours And Company Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a monomeric or oligomeric anhydride component
US4908397A (en) * 1988-06-27 1990-03-13 E. I. Du Pont De Nemours And Company Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin
US4975474A (en) * 1988-06-27 1990-12-04 E. I. Du Pont De Nemours And Company Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin
US5093391A (en) * 1988-06-27 1992-03-03 E. I. Du Pont De Nemours And Company Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and an acid functional component
DE3834738A1 (en) 1988-10-12 1990-04-19 Basf Lacke & Farben METHOD FOR PRODUCING A MULTI-LAYER COATING, AQUEOUS COATING COMPOSITION, WATER-DISCOVERABLE POLYACRYLATE RESINS AND METHOD FOR PRODUCING WATER-DISCOVERABLE POLYACRYLATE RESINS
ES2063109T3 (en) 1989-01-07 1995-01-01 Canon Kk PRINTING LIQUID AND METHOD FOR PRINTING INKS OF INK USING THE SAME.
US5204404A (en) * 1989-03-21 1993-04-20 E. I. Du Pont De Nemours And Company Waterbased acrylic silane and polyurethane containing coating composition
US5066733A (en) * 1989-04-03 1991-11-19 Ppg Industries, Inc. Chip resistant coatings and methods of application
US5242751A (en) 1989-04-27 1993-09-07 Ppg Industries, Inc. Paint composites
EP0410152B1 (en) * 1989-07-24 1994-02-23 Sumitomo Chemical Company Limited Rubber composition having excellent dynamic properties
DE3924618A1 (en) 1989-07-26 1991-01-31 Basf Lacke & Farben COATING AGENTS BASED ON CARBOXYL GROUP-CONTAINING POLYMERS AND EPOXY GROUP GROUPING NETWORKS, METHOD FOR PRODUCING THE COATING AGENT AND ITS USE
US5051464A (en) * 1989-09-01 1991-09-24 E. I. Du Pont De Nemours And Company Waterborne acrylourethane pigment dispersant polymer
US5168106A (en) * 1989-09-14 1992-12-01 Cabot Corporation Carbon blacks
JP2889326B2 (en) * 1989-09-14 1999-05-10 昭和キャボット株式会社 Carbon black and rubber composition
US5064719A (en) * 1989-09-26 1991-11-12 E. I. Du Pont De Nemours And Company Coating composition of acrylic polymers containing reactive groups and an epoxy organosilane
US5184148A (en) * 1989-10-19 1993-02-02 Canon Kabushiki Kaisha Ink jet recording having an ink with carbon black
EP0425439B1 (en) * 1989-10-26 1995-08-02 Ciba-Geigy Ag Aqueous printing ink for ink-jet printing
US5076843A (en) * 1989-10-27 1991-12-31 Lexmark, International, Inc. Nonaqueous thermaljet ink compositions
US5266406A (en) 1989-11-08 1993-11-30 E. I. Du Pont De Nemours And Company Waterbased methylol (meth)acrylamide acrylic polymer and an acrylic hydrosol coating composition
US5190582A (en) * 1989-11-21 1993-03-02 Seiko Epson Corporation Ink for ink-jet printing
DE59004417D1 (en) * 1989-12-11 1994-03-10 Ciba Geigy Process for dyeing leather.
US5122552A (en) * 1989-12-12 1992-06-16 E. I. Du Pont De Nemours And Company Coating composition of polyesterurethane and multifunctional epoxy compound
CA2072567C (en) 1990-01-08 2001-10-23 Chiung-Huei Shieh Carbon blacks imparting superior treadwear/hysteresis performance
US5200164A (en) * 1990-04-04 1993-04-06 Cabot Corporation Easily dispersible carbon blacks
US5182355A (en) * 1990-04-05 1993-01-26 Ppg Industries, Inc. Polyurethane polyanhydride oligomers and method of preparation
DE4021126C2 (en) 1990-07-03 1998-01-29 Basf Lacke & Farben Paints and use of the paints for painting car bodies
DE4023537A1 (en) * 1990-07-25 1992-01-30 Degussa CHEMICALLY MODIFIED ROUGS WITH ORGANOSILICIUM COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE
US5281261A (en) 1990-08-31 1994-01-25 Xerox Corporation Ink compositions containing modified pigment particles
US5100470A (en) * 1990-10-25 1992-03-31 Hewlett-Packard Company Waterfast ink formulations for thermal ink-jet using organic amines
DE4038000A1 (en) * 1990-11-29 1992-06-04 Bayer Ag RUBBER VOLCANISATES WITH IMPROVED HYSTERESIS BEHAVIOR
US5314945A (en) 1990-12-03 1994-05-24 E. I. Du Pont De Nemours And Company Waterbased coating compositions of methylol(meth)acrylamide acrylic polymer, polyurethane and melamine crosslinking agent
US5221581A (en) 1990-12-18 1993-06-22 E. I. Du Pont De Nemours And Company Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane
US5290848A (en) 1990-12-18 1994-03-01 E. I. Du Pont De Nemours And Company Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane
US5206295A (en) 1991-02-25 1993-04-27 E. I. Du Pont De Nemours And Company Coating composition comprising an anhydride-containing polymer and a structured epoxy-containing polymer
US5286286A (en) 1991-05-16 1994-02-15 Xerox Corporation Colorless fast-drying ink compositions for printing concealed images detectable by fluorescence
US5141556A (en) * 1991-06-13 1992-08-25 E. I. Du Pont De Nemours And Company Penetrants for aqueous ink jet inks
US5114477A (en) * 1991-09-03 1992-05-19 Xerox Corporation Liquid ink compositions
US5314953A (en) 1991-10-21 1994-05-24 E. I. Du Pont De Nemours And Company Clear coating composition for clear coat/color coat finish
US5229452A (en) 1991-11-13 1993-07-20 Cabot Corporation Carbon blacks
US5236992A (en) 1991-11-18 1993-08-17 Cabot Corporation Carbon blacks and their use in rubber applications
US5173111A (en) * 1991-11-18 1992-12-22 Sun Chemical Corporation Abrasion resistant printing inks
US5232974A (en) 1991-11-25 1993-08-03 Cabot Corporation Low rolling resistance/high treadwear resistance carbon blacks
US5310778A (en) 1992-08-25 1994-05-10 E. I. Du Pont De Nemours And Company Process for preparing ink jet inks having improved properties
US5356973A (en) 1992-08-31 1994-10-18 Ppg Industries, Inc. Aqueous based coating compositions having improved metallic pigment orientation
US5334650A (en) 1992-09-29 1994-08-02 Basf Corporation Polyurethane coating composition derived from long-chain aliphatic polyol
US5324790A (en) 1992-09-29 1994-06-28 E. I. Du Pont De Nemours And Company Esterification of carboxylate containing polymers
US5272189A (en) 1992-10-19 1993-12-21 Ppg Industries, Inc. Reduced yellowing electrodepositable coating composition
US5352289A (en) 1992-12-18 1994-10-04 Cabot Corporation Low ash carbon blacks
US5302197A (en) 1992-12-30 1994-04-12 E. I. Du Pont De Nemours And Company Ink jet inks
US5401313A (en) 1993-02-10 1995-03-28 Harcros Pigments, Inc. Surface modified particles and method of making the same
US5366828A (en) 1993-11-08 1994-11-22 Struthers Ralph C Metal alloy laded carbon aerogel hydrogen hydride battery

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