CA2224462C - Method for manufacturing cobalt catalysts - Google Patents

Method for manufacturing cobalt catalysts Download PDF

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Publication number
CA2224462C
CA2224462C CA002224462A CA2224462A CA2224462C CA 2224462 C CA2224462 C CA 2224462C CA 002224462 A CA002224462 A CA 002224462A CA 2224462 A CA2224462 A CA 2224462A CA 2224462 C CA2224462 C CA 2224462C
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Prior art keywords
formula
unsubstituted
cobalt
substituted
anhydride
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CA002224462A
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French (fr)
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CA2224462A1 (en
Inventor
Christopher Mark Perkins
Mark Robert Sivik
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Procter and Gamble Co
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Procter and Gamble Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage

Abstract

A method for manufacturing cobalt complexes having the formula: [Co(NH3)5M]Ty, wherein M ligands are selected from substituted and unsubstituted C1-C30 carboxylic acids having the formulas: RC(O)O-; said method comprising reacting cobalt (II) complexes having the formula [Co(H2O)6] Ty (e.g., T is chloride) with concentrated ammonium hydroxide/ammonium chloride, followed by an oxidizing agent (e.g., peroxide), followed by carboxylic acid anhydride of the formula RC(O)O(O)CR.

Description

METHOD FOR MANUFACTURING COBALT CATALYSTS
TECHNICAL FIELD
The present invention relates to methods for manufacturing cobalt complexes having the formula:
~Co~3)5~ TY
wherein M ligand is selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula:
RC(O)O-.
These catalysts are particularly useful in bleach-containing consumer compositions, especially automatic dishwashing detergents and laundry detergents comprising bleach.
BACKGROUND OF THE INVENTION
Cobalt catalysts are well known, as are a variety of methods for manufacturing them. Most synthesis methods, however, are directed simply to methods effective for obtaining experimental quantities for academic studies.
These are described, for example, in M. L. Tobe, "Base Hydrolysis of Transition-Metal Complexes", Adv. Inorg. BioinorQ. Mech., (1983), 2, pages 1-94; J. Chem. Ed.
(1989), 66 (12), 1043-45; "The Synthesis and Characterization of Inorganic Compounds", W.L. Jolly (Prentice-Hall; 1970), pp. 461-3; Inorg. Chem.. 18, 1502 (1979); Ino~. Chem., 21, 2881-2885 (1982); Inor~. Chem., 8 2023-2025 (1979); Inorg. Synthesis, 173-176 (1960); and Journal of Physical Chemistry,, 56, 22-( 1952).
25 For use in consumer products, however, it is necessary that the cobalt catalysts be prepared in large quantities by the most cost effective manner with the highest possible purity. It has been discovered by the present invention that cobalt catalysts containing carboxylate ligands can be prepared on an industrially useful scale by the present process.
BACKGROUND ART
U.S. Patent 4,810,410, to Diakun et al, issued March 7,1989; U.S. 5,246,612, to Van Dijk et al., issued September 21, 1993; U.S. 5,244,594, to Favre et al., issued September 14, 1993; and European Patent Application, Publication No. 408,131, published January 16, 1991 by Unilever NV, see also: U.S. Patent 5,114,611, to Van Kralingen et al, issued May 19, 1992 (transition metal complex of a transition metal, such as cobalt, and a non-macro-cyclic ligand); U.S. Pat. 4,430,243, to Bragg, issued February 7, 1984 (laundry bleaching compositions comprising catalytic heavy metal
2 cations, including cobalt); Cierm,an Patent Specification 2,054,019, published October 7, 1971 by Unilever N. V. (cobalt chelant catalyst); and European Patent Application Publication No. 549,271, published June 30, 1993 by Unilever PLC (macrocyclic organic ligands in cleaning compositions).
a ~~ i Vl 1 rli'r 11 II~.IV 1 11 )IV
The present invention relates to methods for manufacturing cobalt complexes having the formula:
~C~3)SM) TY
wherein the M ligand is selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula:
RC(O~-;
said method comprising the steps of (a) reacting a cobalt (II) salt having the formula:
~Co~20)6J TY
wherein T is one or more counteranions present in s number y to obtain a charge-balanced salt (preferred T are selected from the group consisting of chloride, iodide, I3', fonmate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PF6', BF4', B(Ph)4', phosph~ phosphate, silicate, tosylate, methanesulfonate, and combinations thereof); and y is 1 or 2;
with concentrated ammonium hydroxide and ammoroum chloride; followed by (b) reacting the product of step (a) with an oxidizing agent selected from the group consisting of oxygen, hydrogen peroxide, and mixtures thereof followed by (c) reacting the product of step (b) with a carboxylic acid anhydride of the ZS formula:
RC(O~(OxR
wherein each R is independently selected from substituted or unsubstituted C1-C30 moieties (preferably both R are the same);
(d) optionally, exchanging one T counterion with another T counterion; and (e) collecting the cobalt complex.
A11 Parts, Percentages and ratios used herein are expressed as percent weight unless otherwise specified.
3 PCT/(JS96/01086 The present invention relates to a method for manufacturing cobalt complexes having the formula:
[Co(NH3)SMJ TY
wherein the M ligands are selected from substituted and unsubstituted C1-C30 carboxylic acids having the formulas:
RC(O)O-.
This method comprises the first step of reacting a cobalt (II) salt having the formula:
[Co~2~)6~ TY
wherein T is one or more counteranions present in a number y to obtain a charge-balanced salt (preferred T are selected from the group consisting of chloride, iodide, I3-, formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PF6-, BF4-, B(Ph)4 , phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof); y is 1 or 2;
with concentrated ammonium hydroxide and ammonium chloride (preferably at least 20%, more preferably at least 25%, and typically between 28-32%
solutions of concentrated ammonium hydroxide). This step is typically conducted at room temperature; preferred temperatures are below about 90 °C, more preferably below 80 °C. Preferred is to use from about 5.0 to about 10.0 equivalents, more preferably from about 5.0 to about 5.5 equivalents, of ammonium hydroxide in a concentrated aqueous solution so as to minimize the volume of water present during the reaction.
This first step is followed by a step whereby the product of the first step is reacted with an oxidizing agent selected from the group consisting of an oxidizing source such as oxygen and, especially, hydrogen peroxide (preferably at concentrations of at least about 30% and more preferably at least about 50% by weight). This step is also typically conducted at room temperature; preferred temperatures are below about 90 °C, more preferably below 80 °C.
This reaction step is then followed by reacting the product of the previous step with a carboxylic acid anhydride of the formula:
RC(O)O(O)CR
wherein each R is independently selected from substituted or unsubstituted C1-C3p moieties. It is preferred that both R moieties are the same, but mixed anhydrides may be used as desired for the desired cobalt complex being synthesized.
Reaction conditions for this step are typically room temperature (preferred
4 temperatures are below about 90 °C, more preferably below 80 °C) for from about to about 60 minutes. Additionally, about 1.0 to about 2.0 equivalents of the ammonium carboxylate salt can be added prior to the addition of the carboxylic acid .
anhydride to facilitate synthesis of the desired cobalt complex.
5 This reaction step is then optionally followed by exchanging the T
counterion of the prepared cobalt complex with another T counterion. This may be carried out, for example, by treating the complex with an acid (e.g., HCl or HCI04), or a salt (e.g., NaPF6).
At the end of the reaction process, the mixture is optionally filtered and the 10 cobalt complex is collected. Preferred collection methods include, for example, evaporation to remove the solvent or lyophilization or precipitation (e.g., by addition of a co-solvent). The cobalt complex collected may be used as is, or further purified or modified for incorporation into the desired product or use to be made of the complex. This includes optionally washing the solid product with a suitable solvent, e.g., ethanol, to remove non-cobalt salts.
The present invention method preferably is carried out in one reaction vessel without isolation or separation of the intermediate reaction products.
However, if desired, one or more of the reaction steps may be conducted in separate reaction vessels, and may be followed or preceeded by optional separation and/or collection steps of the intermediate reaction materials. .
Preferred T are selected from the goup consisting of chloride, iodide, I3-, formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PF6 , BF4-, B(Ph)4 , phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof. Optionally, T can be protonated if more than one anionic goup exists in T, e.g., HP042-, HC03-, H2P04', etc. Further, T may be selected from the goup consisting of non-traditional inorganic anions such as anionic surfactants (e.g., linear alkylbenzene sulfonates (LAS), alkyl sulfates (AS), alkylethoxysulfonates (AES), etc.) and/or anionic polymers (e.g., polyacrylates, polymethacrylates, etc.).
Herein, R is preferably selected from the group consisting of hydrogen and C1-C3p (preferably C1-Clg) unsubstituted and substituted alkyl, C6-C30 (preferably C6-C 1 g) unsubstituted and substituted aryl, and C3-C30 (preferably CS-C 1 g) unsubstituted and substituted heteroaryl, wherein substituents are selected from the goup consisting of -NR'3, -NR'4+, -C(O)OR', -OR', -C(O)NR'2, wherein R' is selected from the group consisting of hydrogen and C1-C6 moieties. Such substituted R therefore include the moieties -(CH2)nOH and -(CH2)nNR'4+, wherein n is an integer from 1 to about 16, preferably from about 2 to about 10, and most preferably from about 2 to about 5.
5 Most preferred M are carboxylic acids having the formula above wherein R is selected from the group consisting of hydrogen, methyl, ethyl, propyl, straight or branched C4-C 12 alkyl, and benzyl. Most preferred R is methyl. The M moieties include mono-carboxylates, which are preferred, but more than one carboxylate may be present in the moiety as long as the binding to the cobalt is by only one carboxylate per moiety (in which case the other carboxylate in the M moiety may be protonated or in its salt form). Preferred carboxylic acid M moieties include formic, benzoic, octanoic, nonanoic, decanoic, dodecanoic, malonic, malefic, succinic, adipic, phthalic, 2-ethylhexanoic, naphthenoic, oleic, pahnitic, triflate, tartrate, stearic, butyric, citric, acrylic, aspartic, fumaric, lauric, linoleic, lactic, malic, and especially acetic acid. Therefore, most preferred methods use the anhydrides comprising these carboxylic acids, and preferred anhydrides are the same acids. Most preferred anhydride is acetic anhydride.
The preferred cobalt complexes prepared by the present invention are cobalt(IB) pentaamineacetate dichloride, i.e. [Co(NH3)SOAc]C12 (herein "PAC");
cobalt(IB) pentaamineacetate diacetate, i.e. [Co(NH3)SOAc](OAc)2;
[Co~3)SOAc](PF6)2~ [Co~3)SOAc](S04)~ ~d [Co(NH3)SOAc](BF4)2~
The starting cobalt(I17 complexes useful herein, the [Co(H20)6] Ty complexes, are commercially available and can be prepared by a variety of methods.
The following nonlimiting examples further illustrate the method according to the present invention.
Exam In a 1 synthesis of [Co , 3)SOAc]Cl2 (designated as "PAC") I C 2 ~6I 2 ----~ --. 4 pcZp ~ PAC
Co H O CI
Ni,CI
NH4C1 (25.0 g) is dissolved in I~OH (150 mL). [Co(H20)6]C12 (26.4 g, 0.10 mol) is added to this solution forming a slurry. H202 (30%, 40.0 mL) is slowly dripped into the solution with stirring. Acetic anhydride (30.6 g, 0.30 mol) is slowly
6 added with stirring. The solution is stirred 1 hour at RT. At this point the reaction solution can either be lyophilized to a pink powder or the solution can be rotovapped down and the resulting solid pumped on overnight at 0.05 mm. to remove residual water and NH40Ac. The excess ammonium acetate and ammonium chloride salts can also be removed by washing the solid with ethanol. Meld 35 gr., 78.1% by W-Vis spectroscopy. HPLC [according to the method of D.A. Buckingham, et al, Inora. Chem.. ~, 4567-4574 (1989)] shows all ofthe cobalt is present as [C~3)SO~lCl2.
Synthesis of [C~~~~Q~~
Ammonium hydroxide (4498.0 mL, 32.3 mol, 28%) and ammonium chloride (749.8 g, 14.0 mol) are combined in a 12 L three-necked round-bottomed flask fitted with a condenser, internal thermometer, mechanical stirrer, and addition fiumel.
Once the mixture becomes homogeneous, cobalt(I17 chloride hexahydrate ( 1500.0 g, 6.3 mol) is added in portions over 5 min forming a slurry. The reaction mixture warms to 50 °C and takes on a muddy color. H202 (429.0 g, 6.3 mol, 50%) is added over 30 min. The mixture beconms deep red and homogeneous and the tempasture raises to 60-65 °C during addition of the peroxide. Ammonium acetate (485.9 g, 6.3 mol) is then added to the mixture 30 min later. After stirring an additional 15 min, acetic anhydride (2242.5 g, 22.1 mol) is added over 1 h.
The anhydride is added so as to keep the reaction temperature below 75 °C.
The mixture is stirred for 2 h as it cools. The red miacture is filtered and the filtrate treated with isopropanol until an orango-pink solid forms. The solid is collected, washed with isopropanol, ether, and dried to give an orange-pink solid. W-vs measurements indicate the product to be 95.3% pure as [Co(NH3)SOAc]C12.

Claims (10)

WHAT IS CLAIMED IS:
1. A method for manufacturing cobalt complexes having the formula:
[Co(NH3)5M]Ty wherein the M ligand is selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula:
RC(O)O-;
said method comprising the steps of:
(a) reacting a cobalt (II) salt having the formula:
[Co(H2O)6]Ty wherein T is one or more counteranions present in a number y to obtain a charge-balanced salt; and y is 1 or 2;
with concentrated ammonium hydroxide and ammonium chloride; followed by (b) reacting the product of step (a) with an oxidizing agent selected from the group consisting of oxygen, hydrogen peroxide, and mixtures thereof followed by (c) reacting the product of step (b) with a carboxylic acid anhydride of the formula:
RC(O)O(O)CR
wherein each R is independently selected from substituted or unsubstituted C1-C30 moieties;
(d) optionally, exchanging one T counterion with another T counterion; and (e) collecting the cobalt complex.
2. The method according to Claim 1 wherein T is selected from the group consisting of chloride, iodide, I3-, formate, nitrate, nitrite, sulfate, sulfite, citrate, acetate, carbonate, bromide, PF6-, BF4-, B(Ph)4-, phosphate, phosphite, silicate, tosylate, methanesulfonate, and combinations thereof.
3. The method according to either of Claims 1-2 wherein the concentrated ammonium hydroxide is at least 25% ammonium hydroxide.
4. The method according to any of Claims 1-3 wherein each R in the anhydride is independently selected from the group consisting of hydrogen and C1-C30 unsubstituted and substituted alkyl, C6-C30 unsubstituted and substituted aryl, and C3-C30 unsubstituted and substituted heteroaryl, wherein substituents are selected from the group consisting of NR'3, NR'4+, -C(O)OR', -OR', -C(O)NR'2, wherein R' is selected from the group consisting of hydrogen and C1-C6 moieties.
5. The method according to any of Claims 1-4 wherein the M ligand is a carboxylic acid moiety selected from formic, benzoic, octanoic, nonanoic, decanoic, dodecanoic, malonic, maleic, succinic, adipic, phthalic, 2-ethylhexanoic, naphthenoic, oleic, palmitic, triflate, tartrate, stearic, butyric, citric, acrylic, aspartic, flumaric, lauric, linoleic, lactic, malic, and preferably acetic acid.
6. A method for manufacturing cobalt complexes having the formula:
[Co(NH3)5M]T y wherein the M ligand is selected from substituted and unsubstituted C1-C30 carboxylic acids having the formula:
RC(O)O-;
wherein R is selected from C1-C18 unsubstituted and substituted alkyl moieties;
said method comprising the steps of:
(a) reacting a cobalt (II) salt having the formula:
[Co(H2O)6]T y wherein T is one or more counteranions present in a number y to obtain a charge-balanced salt; and y is 1 or 2;
with concentrated ammonium hydroxide and ammonium chloride; followed by (b) reacting the product of step (a) with hydrogen peroxide; followed by (c) reacting the product of step (b) with a carboxylic acid anhydride of the formula:
RC(O)O(O)CR
wherein each R is independently selected from C1-C18 unsubstituted and substituted alkyl moieties; and (d) optionally, exchanging one T counterion with another T counterion; and (e) collecting the cobalt complex.
7. The method according to any of Claims 1-6 wherein both R in the anhydride are the same moiety selected from the group consisting of hydrogen, methyl, ethyl, propyl, straight or branched C4-C12 alkyl, and benzyl.
8. The method according to any of Claims 1-7 wherein the anhydride is acetic anhydride.
9. The method according to any of Claims 1-4 and 6 wherein each R in the anhydride is independently selected from the moieties -(CH2)n OH and -(CH2)nNR'4+, wherein n is an integer from 1 to 16, preferably from 2 to 10.
10. The method according to any of Claims 1-9 utilizing from 5.0 to 10.0 equivalents of ammonium hydroxide in a concentrated aqueous solution.
CA002224462A 1995-06-16 1996-01-25 Method for manufacturing cobalt catalysts Expired - Fee Related CA2224462C (en)

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US49118595A 1995-06-16 1995-06-16
US08/491,185 1995-06-16
US08/508,198 1995-07-27
US08/508,198 US5597936A (en) 1995-06-16 1995-07-27 Method for manufacturing cobalt catalysts
PCT/US1996/001086 WO1997000263A1 (en) 1995-06-16 1996-01-25 Method for manufacturing cobalt catalysts

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AT (1) ATE192453T1 (en)
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