CA2233629A1 - S-eb-s block copolymer/oil aqueous dispersion and its use in forming articles - Google Patents
S-eb-s block copolymer/oil aqueous dispersion and its use in forming articlesInfo
- Publication number
- CA2233629A1 CA2233629A1 CA002233629A CA2233629A CA2233629A1 CA 2233629 A1 CA2233629 A1 CA 2233629A1 CA 002233629 A CA002233629 A CA 002233629A CA 2233629 A CA2233629 A CA 2233629A CA 2233629 A1 CA2233629 A1 CA 2233629A1
- Authority
- CA
- Canada
- Prior art keywords
- block copolymer
- dispersion
- aqueous dispersion
- film
- forming articles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
Abstract
A dispersion has particles dispersed in a continuous aqueous dispersion medium. The particles, preferably no more than about 2 micrometers in size, are formed of a mixture of styrene/ethylene/butylene-styrene (S-EB-S) block copolymer having end blocks each with a weight average molecular weight of more than about 15,000 Daltons and an oil such as a mineral oil. The dispersion medium is a mixture of water and a surfactant. Articles are prepared by dipping a form into the dispersion and withdrawing the form to leave a film of the dispersion on the form. The water is evaporated from the film, leaving a coherent extensible film on the form.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US695,612 | 1991-05-03 | ||
US08/695,612 US5900452A (en) | 1996-08-12 | 1996-08-12 | S-EB-S block copolymer/oil aqueous dispersion and its use in forming articles |
US904,839 | 1997-08-01 | ||
US08/904,839 US6288159B1 (en) | 1996-08-12 | 1997-08-01 | S-EB-S block copolymer/oil aqueous dispersion and its use in forming articles |
PCT/US1997/013926 WO1998006774A1 (en) | 1996-08-12 | 1997-08-11 | S-eb-s block copolymer/oil aqueous dispersion and its use in forming articles |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2233629A1 true CA2233629A1 (en) | 1998-02-19 |
CA2233629C CA2233629C (en) | 2006-06-13 |
Family
ID=24793732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002233629A Expired - Fee Related CA2233629C (en) | 1996-08-12 | 1997-08-11 | S-eb-s block copolymer/oil aqueous dispersion and its use in forming articles |
Country Status (8)
Country | Link |
---|---|
US (3) | US5900452A (en) |
EP (1) | EP0859807B1 (en) |
JP (1) | JP4296244B2 (en) |
AU (1) | AU719068B2 (en) |
CA (1) | CA2233629C (en) |
DE (1) | DE69731275T2 (en) |
WO (1) | WO1998006774A1 (en) |
ZA (1) | ZA977133B (en) |
Families Citing this family (42)
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US5900452A (en) | 1996-08-12 | 1999-05-04 | Tactyl Technologies, Inc. | S-EB-S block copolymer/oil aqueous dispersion and its use in forming articles |
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US20020155309A1 (en) * | 2001-02-21 | 2002-10-24 | Zhixin Li | Mold release and anti-blocking coating for powder-free natural or synthetic rubber articles |
US20030118761A1 (en) * | 2001-12-21 | 2003-06-26 | Kimberly-Clark Worldwide, Inc. | Elastomeric articles having improved chemical resistance |
US20030226191A1 (en) * | 2002-06-03 | 2003-12-11 | Kimberly-Clark Worldwide, Inc. | Elastomeric gloves having improved gripping characteristics |
US7455863B2 (en) * | 2002-11-07 | 2008-11-25 | Smarthealth, Inc. | Flexible elastomer articles and methods of manufacturing |
US7585526B2 (en) | 2002-11-07 | 2009-09-08 | Smarthealth, Inc. | Flexible elastomer articles and methods of manufacturing |
US6772443B2 (en) | 2002-12-30 | 2004-08-10 | Kimberly-Clark Worldwide, Inc. | Breathable elastomeric glove |
US20040231028A1 (en) * | 2003-05-22 | 2004-11-25 | Kimberly-Clark Worldwide, Inc. | Readily donned elastomeric article |
US7052642B2 (en) * | 2003-06-11 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Composition for forming an elastomeric article |
US6972148B2 (en) * | 2003-06-23 | 2005-12-06 | Kimberly-Clark Worldwide, Inc. | Glove having improved donning characteristics |
US7776368B2 (en) * | 2003-08-13 | 2010-08-17 | Smarthealth, Inc. | Gloves containing dry powdered aloe and method of manufacturing |
US20050127552A1 (en) * | 2003-12-11 | 2005-06-16 | Kimberly-Clark Worldwide, Inc. | Method for forming an elastomeric article |
US20050132466A1 (en) * | 2003-12-11 | 2005-06-23 | Kimberly-Clark Worldwide, Inc. | Elastomeric glove coating |
US7399608B2 (en) * | 2003-12-16 | 2008-07-15 | Kimberly-Clark Worldwide, Inc. | Microbial detection and quantification |
US7282349B2 (en) * | 2003-12-16 | 2007-10-16 | Kimberly-Clark Worldwide, Inc. | Solvatochromatic bacterial detection |
US7300770B2 (en) * | 2004-12-16 | 2007-11-27 | Kimberly-Clark Worldwide, Inc. | Detection of microbe contamination on elastomeric articles |
US7159246B2 (en) * | 2003-12-17 | 2007-01-09 | Kimberly-Clark Worldwide, Inc. | Glove with high tactile portion |
US20060093767A1 (en) * | 2004-11-01 | 2006-05-04 | Kimberly-Clark Worldwide, Inc. | Flexible coated article and method of making the same |
US7265192B2 (en) * | 2004-11-30 | 2007-09-04 | Kimberly-Clark Worldwide, Inc. | Breathable elastomeric article |
US7552501B2 (en) * | 2005-04-29 | 2009-06-30 | Kimberly-Clark Worldwide, Inc. | Finger wipe with improved seam structure |
US7902288B2 (en) * | 2005-05-31 | 2011-03-08 | 3M Innovative Properties Company | Sealant materials containing diblock copolymers and methods of making thereof |
US7469427B2 (en) * | 2005-06-30 | 2008-12-30 | Kimberly-Clark Worldwide, Inc. | Stretchable and permeable non-woven protective gloves |
MY147739A (en) * | 2005-07-20 | 2013-01-15 | Diptech Pte Ltd | Elastomeric films and gloves |
US20070048356A1 (en) * | 2005-08-31 | 2007-03-01 | Schorr Phillip A | Antimicrobial treatment of nonwoven materials for infection control |
US20070048344A1 (en) * | 2005-08-31 | 2007-03-01 | Ali Yahiaoui | Antimicrobial composition |
US20070048358A1 (en) * | 2005-08-31 | 2007-03-01 | Schorr Phillip A | Antimicrobial substrates |
US20070048345A1 (en) * | 2005-08-31 | 2007-03-01 | Kimberly-Clark Worldwide, Inc. | Antimicrobial composition |
US20070083980A1 (en) * | 2005-09-16 | 2007-04-19 | Kimberly-Clark Worldwide, Inc. | Polymer-coated protective garment |
US7727513B2 (en) * | 2005-12-15 | 2010-06-01 | Kimberly-Clark Worldwide, Inc. | Method for screening for bacterial conjunctivitis |
US20080054408A1 (en) * | 2006-08-31 | 2008-03-06 | Kimberly-Clark Worldwide, Inc. | Conduction through a flexible substrate in an article |
US20080057693A1 (en) * | 2006-08-31 | 2008-03-06 | Kimberly-Clark Worldwide, Inc. | Electrical conductivity bridge in a conductive multilayer article |
US20080057534A1 (en) * | 2006-08-31 | 2008-03-06 | Kimberly-Clark Worldwide, Inc. | Microbe-sensitive indicators and use of the same |
US7504550B2 (en) * | 2006-08-31 | 2009-03-17 | Kimberly-Clark Worldwide, Inc. | Conductive porous materials |
JP2009073816A (en) * | 2007-09-24 | 2009-04-09 | Rohm & Haas Co | Steam stripping of polymer dispersion for improving stability of biocide |
US20090142275A1 (en) * | 2007-11-29 | 2009-06-04 | Kimberly-Clark Worldwide, Inc. | Wound Suture Capable of Identifying the Presence of Bacteria |
US20090143516A1 (en) * | 2007-11-30 | 2009-06-04 | Macdonald John Gavin | Thermochromic responsive elastic polymer substrate |
ES2410368T3 (en) | 2008-07-16 | 2013-07-01 | Trüb Emulsions Chemie Ag | Procedure for solvent-free production of thermoplastic dispersions |
CN102227493A (en) * | 2008-10-07 | 2011-10-26 | 3M创新有限公司 | Composition, method of making same, and use thereof |
WO2010088713A1 (en) | 2009-02-05 | 2010-08-12 | Diptech Pte Limited | Production of elastomeric films |
EP2665381B1 (en) | 2011-01-18 | 2019-10-16 | Church & Dwight Co., Inc. | Method for producing a low modulus elastomeric article |
WO2018194904A1 (en) | 2017-04-16 | 2018-10-25 | Plamthottam Sebastian S | Dip formable solutions and dispersions and articles made therefrom |
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-
1996
- 1996-08-12 US US08/695,612 patent/US5900452A/en not_active Expired - Lifetime
-
1997
- 1997-08-01 US US08/904,839 patent/US6288159B1/en not_active Expired - Lifetime
- 1997-08-11 EP EP97937155A patent/EP0859807B1/en not_active Expired - Lifetime
- 1997-08-11 WO PCT/US1997/013926 patent/WO1998006774A1/en active IP Right Grant
- 1997-08-11 AU AU39735/97A patent/AU719068B2/en not_active Ceased
- 1997-08-11 ZA ZA9707133A patent/ZA977133B/en unknown
- 1997-08-11 DE DE69731275T patent/DE69731275T2/en not_active Expired - Lifetime
- 1997-08-11 CA CA002233629A patent/CA2233629C/en not_active Expired - Fee Related
- 1997-08-11 JP JP50986798A patent/JP4296244B2/en not_active Expired - Lifetime
-
2001
- 2001-09-11 US US09/951,227 patent/US6414083B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP4296244B2 (en) | 2009-07-15 |
EP0859807A1 (en) | 1998-08-26 |
EP0859807B1 (en) | 2004-10-20 |
US6288159B1 (en) | 2001-09-11 |
US6414083B2 (en) | 2002-07-02 |
DE69731275D1 (en) | 2004-11-25 |
US5900452A (en) | 1999-05-04 |
EP0859807A4 (en) | 1999-06-23 |
ZA977133B (en) | 1998-05-11 |
JP2002514232A (en) | 2002-05-14 |
AU719068B2 (en) | 2000-05-04 |
WO1998006774A1 (en) | 1998-02-19 |
CA2233629C (en) | 2006-06-13 |
DE69731275T2 (en) | 2006-03-16 |
AU3973597A (en) | 1998-03-06 |
US20020007002A1 (en) | 2002-01-17 |
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