CA2247703A1 - Dual reactor ethylene polymerization process - Google Patents

Dual reactor ethylene polymerization process Download PDF

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Publication number
CA2247703A1
CA2247703A1 CA002247703A CA2247703A CA2247703A1 CA 2247703 A1 CA2247703 A1 CA 2247703A1 CA 002247703 A CA002247703 A CA 002247703A CA 2247703 A CA2247703 A CA 2247703A CA 2247703 A1 CA2247703 A1 CA 2247703A1
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CA
Canada
Prior art keywords
reactor
polymerization process
dual reactor
ethylene polymerization
reactor ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002247703A
Other languages
French (fr)
Other versions
CA2247703C (en
Inventor
Isam Jaber
Stephen John Brown
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nova Chemicals Corp
Original Assignee
Nova Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002247703A priority Critical patent/CA2247703C/en
Application filed by Nova Chemicals Corp filed Critical Nova Chemicals Corp
Priority to DE69909502T priority patent/DE69909502T2/en
Priority to ES99939877T priority patent/ES2203165T3/en
Priority to JP2000574151A priority patent/JP4576049B2/en
Priority to KR1020017003603A priority patent/KR100615758B1/en
Priority to BR9913881-6A priority patent/BR9913881A/en
Priority to CNB998111627A priority patent/CN1138792C/en
Priority to AT99939877T priority patent/ATE244733T1/en
Priority to EP99939877A priority patent/EP1124864B1/en
Priority to PCT/CA1999/000790 priority patent/WO2000017244A1/en
Priority to AU54036/99A priority patent/AU5403699A/en
Priority to US09/386,098 priority patent/US6277931B1/en
Publication of CA2247703A1 publication Critical patent/CA2247703A1/en
Application granted granted Critical
Publication of CA2247703C publication Critical patent/CA2247703C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/05—Transitioning, i.e. transition from one catalyst to another with use of a deactivating agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Abstract

A dual reactor process for the solution and (co)polymerization of ethylene uses two different types of catalysts in the two reactors. A catalyst having a phosphinimine ligand is used in the first reactor. A Ziegler Natta catalyst is used in the second reactor. The process of this invention is comparatively easy to control and may be used to produce polyethylene products having a broad molecular weight distribution. Linear low density produced according to this invention is well suited for the manufacture of molded goods and plastic films.
CA002247703A 1998-09-22 1998-09-22 Dual reactor ethylene polymerization process Expired - Lifetime CA2247703C (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
CA002247703A CA2247703C (en) 1998-09-22 1998-09-22 Dual reactor ethylene polymerization process
EP99939877A EP1124864B1 (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process
JP2000574151A JP4576049B2 (en) 1998-09-22 1999-08-27 Two-stage reactor ethylene polymerization
KR1020017003603A KR100615758B1 (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process
BR9913881-6A BR9913881A (en) 1998-09-22 1999-08-27 Polymerization process of ethylene in double reactor
CNB998111627A CN1138792C (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process
DE69909502T DE69909502T2 (en) 1998-09-22 1999-08-27 MULTI-STAGE ETHYLENE POLYMERIZATION PROCESS
ES99939877T ES2203165T3 (en) 1998-09-22 1999-08-27 ETHYLENE POLYMERIZATION PROCEDURE IN A DOUBLE REACTOR.
PCT/CA1999/000790 WO2000017244A1 (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process
AU54036/99A AU5403699A (en) 1998-09-22 1999-08-27 Dual reactor ethylene polymerization process
AT99939877T ATE244733T1 (en) 1998-09-22 1999-08-27 MULTI-STEP ETHYLENE POLYMERIZATION PROCESS
US09/386,098 US6277931B1 (en) 1998-09-22 1999-08-30 Dual reactor ethylene polymerization process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CA002247703A CA2247703C (en) 1998-09-22 1998-09-22 Dual reactor ethylene polymerization process

Publications (2)

Publication Number Publication Date
CA2247703A1 true CA2247703A1 (en) 2000-03-22
CA2247703C CA2247703C (en) 2007-04-17

Family

ID=4162832

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002247703A Expired - Lifetime CA2247703C (en) 1998-09-22 1998-09-22 Dual reactor ethylene polymerization process

Country Status (12)

Country Link
US (1) US6277931B1 (en)
EP (1) EP1124864B1 (en)
JP (1) JP4576049B2 (en)
KR (1) KR100615758B1 (en)
CN (1) CN1138792C (en)
AT (1) ATE244733T1 (en)
AU (1) AU5403699A (en)
BR (1) BR9913881A (en)
CA (1) CA2247703C (en)
DE (1) DE69909502T2 (en)
ES (1) ES2203165T3 (en)
WO (1) WO2000017244A1 (en)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6372868B1 (en) 1999-12-07 2002-04-16 Univation Technologies, Llc Start up methods for multiple catalyst systems
DE60034705T2 (en) * 1999-10-22 2008-01-17 Univation Technologies, LLC, Houston METHOD FOR ACCESSING MULTI-CATALYST SYSTEMS
MY131000A (en) 2001-03-16 2007-07-31 Dow Global Technologies Inc High melt strength polymers and method of making same
CA2347410C (en) * 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
AU2003240541A1 (en) * 2002-06-04 2003-12-19 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions and method of making pipes thereof
US7323523B2 (en) * 2004-12-07 2008-01-29 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
US7064096B1 (en) * 2004-12-07 2006-06-20 Nova Chemicals (International) Sa Dual catalyst on a single support
US7321015B2 (en) * 2004-12-07 2008-01-22 Nova Chemicals (International) S.A. Adjusting polymer characteristics through process control
KR101141494B1 (en) * 2007-09-05 2012-05-03 에스케이이노베이션 주식회사 Ethylene copolymer having multiple pitch in molecular weight distribution and the method of preparing the same
ATE535555T1 (en) * 2008-01-07 2011-12-15 Borealis Tech Oy USE OF AN IMPROVED SOLID STATE VANADIUM CONTAINING ZIEGLER-NATTA CATALYST SYSTEM FOR PRODUCING ETHYLENE POLYMER COMPOSITIONS IN A MULTI-STEP PROCESS
KR101152413B1 (en) * 2008-09-12 2012-06-05 에스케이이노베이션 주식회사 Ethylene copolymer and a method of preparing the same
EP2216347A1 (en) * 2009-01-30 2010-08-11 Borealis AG A method of catalyst transitions in olefin polymerizations
EP2256158B1 (en) 2009-05-26 2014-07-02 Borealis AG Polymer composition for crosslinked articles
EP2256159A1 (en) 2009-05-26 2010-12-01 Borealis AG Polymer composition for crosslinked pipes
CA2724943A1 (en) 2010-12-10 2012-06-10 Nova Chemicals Corporation Catalyst activation in a dual reactor process
CA2739969C (en) 2011-05-11 2018-08-21 Nova Chemicals Corporation Improving reactor operability in a gas phase polymerization process
US9321859B2 (en) 2011-06-09 2016-04-26 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
CA2742454C (en) 2011-06-09 2018-06-12 Nova Chemicals Corporation Methods for controlling ethylene copolymer properties
CA2742461C (en) 2011-06-09 2018-06-12 Nova Chemicals Corporation Modified phosphinimine catalysts for olefin polymerization
US9315591B2 (en) 2011-06-09 2016-04-19 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9127106B2 (en) 2011-06-09 2015-09-08 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9127094B2 (en) 2011-06-09 2015-09-08 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9221935B2 (en) 2011-06-09 2015-12-29 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US9243092B2 (en) 2011-06-09 2016-01-26 Nova Chemicals (International) S.A. Modified phosphinimine catalysts for olefin polymerization
US8835569B2 (en) * 2011-06-30 2014-09-16 Dow Global Technologies Llc Fractional melt index polyethylene composition and films made therefrom
CA2752407C (en) 2011-09-19 2018-12-04 Nova Chemicals Corporation Polyethylene compositions and closures for bottles
US9371442B2 (en) 2011-09-19 2016-06-21 Nova Chemicals (International) S.A. Polyethylene compositions and closures made from them
CA2760264C (en) 2011-12-05 2018-08-21 Nova Chemicals Corporation Passivated supports for use with olefin polymerization catalysts
US8796408B2 (en) 2012-08-31 2014-08-05 Exxonmobil Chemical Patents Inc. Plants and processes for forming polymers
US9783663B2 (en) 2012-12-14 2017-10-10 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2798854C (en) 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
US9475927B2 (en) 2012-12-14 2016-10-25 Nova Chemicals (International) S.A. Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
CA2868640C (en) * 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
WO2016063200A1 (en) 2014-10-21 2016-04-28 Nova Chemicals (International) S.A. Continuous solution polymerization process
EP3209722A2 (en) * 2014-10-21 2017-08-30 Nova Chemicals (International) S.A. Ethylene interpolymer product with dilution index
WO2016088045A1 (en) 2014-12-05 2016-06-09 Nova Chemicals (International) S.A. Multilayer polyethylene films
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
WO2016097254A1 (en) * 2014-12-19 2016-06-23 Borealis Ag Power cable polymer composition, power cable and uses with advantageous properties
WO2016097253A1 (en) * 2014-12-19 2016-06-23 Borealis Ag Power cable polymer composition and power cable with advantageous properties
WO2016135590A1 (en) 2015-02-24 2016-09-01 Nova Chemicals (International) S.A. Bottle cap
CA2891693C (en) 2015-05-21 2022-01-11 Nova Chemicals Corporation Controlling the placement of comonomer in an ethylene copolymer
CA2892552C (en) 2015-05-26 2022-02-15 Victoria Ker Process for polymerization in a fluidized bed reactor
CA2892882C (en) 2015-05-27 2022-03-22 Nova Chemicals Corporation Ethylene/1-butene copolymers with enhanced resin processability
US9758653B2 (en) 2015-08-19 2017-09-12 Nova Chemicals (International) S.A. Polyethylene compositions, process and closures
CA2914353C (en) 2015-12-10 2023-01-24 Nova Chemicals Corp. Hot fill process with closures made from high density polyethylene compositions
CA2914354C (en) 2015-12-10 2022-11-08 Nova Chemicals Corp. Hot fill process with closures made frm bimodal polyethylene compositions
TW201800424A (en) 2016-02-18 2018-01-01 努發化工（國際）公司 Solution polymerization process
US9783664B1 (en) 2016-06-01 2017-10-10 Nova Chemicals (International) S.A. Hinged component comprising polyethylene composition
CA2957706C (en) * 2017-02-13 2020-12-15 Nova Chemicals Corporation Caps and closures
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
CA3022700A1 (en) 2017-11-27 2019-05-27 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition having good dimensional stability
CA3022996A1 (en) 2017-12-04 2019-06-04 Nova Chemicals Corporation Bottle closure assembly comprising a polyethylene composition
SG11202005754XA (en) 2017-12-26 2020-07-29 Dow Global Technologies Llc Multimodal ethylene-based polymer compositions having improved toughness
BR112020011475B1 (en) * 2017-12-26 2023-05-16 Dow Global Technologies Llc METHOD TO PRODUCE A MULTIMODAL ETHYLENE-BASED POLYMER
JP7467341B2 (en) 2017-12-26 2024-04-15 ダウ グローバル テクノロジーズ エルエルシー Process for the production of multimodal ethylene-based polymers
JP2021525290A (en) 2018-05-31 2021-09-24 ダウ グローバル テクノロジーズ エルエルシー Methods and systems for polymer production
CA3009299A1 (en) 2018-06-26 2019-12-26 Nova Chemicals Corporation Catalyst injection system for an olefin polymerization reactor
CN111057172A (en) * 2018-10-17 2020-04-24 中国石油天然气股份有限公司 Octene modified linear low density polyethylene resin, multilayer co-extrusion packaging film containing the same and preparation method thereof
CA3026095A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Polyethylene homopolymer compositions having good barrier properties
CA3026098A1 (en) 2018-12-03 2020-06-03 Nova Chemicals Corporation Narrow polyethylene homopolymer compositions having good barrier properties
BR112021011902B1 (en) 2018-12-18 2024-01-23 Nova Chemicals (International) S.A MULTI-LAYER FILMS
CA3028148A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and articles with barrier properties
CA3028157A1 (en) 2018-12-20 2020-06-20 Nova Chemicals Corporation Polyethylene copolymer compositions and their barrier properties
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
CA3032082A1 (en) 2019-01-31 2020-07-31 Nova Chemicals Corporation Polyethylene compositions and articles with good barrier properties
BR112022000360A2 (en) 2019-07-25 2022-05-10 Nova Chem Int Sa Rotomolded parts prepared from bimodal polyethylene
US11286379B2 (en) 2019-10-08 2022-03-29 Nova Chemicals (International) S.A. Flexible rotationally molded article
MX2022004229A (en) 2019-10-16 2022-05-03 Nova Chem Int Sa Use of recycled polyethylene in closures for bottles.
EP4090527A1 (en) 2020-01-17 2022-11-23 Nova Chemicals (International) S.A. Polyethylene copolymer compositions and articles with barrier properties
US20230151130A1 (en) * 2020-05-13 2023-05-18 Nova Chemicals (International) S.A. Ethylene interpolymer product and films thereof

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5589555A (en) * 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
US5434116A (en) 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
US5554775A (en) 1995-01-17 1996-09-10 Occidental Chemical Corporation Borabenzene based olefin polymerization catalysts
CA2188722A1 (en) * 1995-10-26 1997-04-27 George Norris Foster Process for preparing an in situ polyethylene blend
JP3629113B2 (en) * 1996-12-24 2005-03-16 三菱化学株式会社 Olefin multistage polymerization process
CA2206944C (en) * 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts

Also Published As

Publication number Publication date
ATE244733T1 (en) 2003-07-15
BR9913881A (en) 2001-07-24
AU5403699A (en) 2000-04-10
EP1124864A1 (en) 2001-08-22
WO2000017244A1 (en) 2000-03-30
CN1138792C (en) 2004-02-18
ES2203165T3 (en) 2004-04-01
DE69909502T2 (en) 2004-06-09
JP2002526573A (en) 2002-08-20
US6277931B1 (en) 2001-08-21
CN1319107A (en) 2001-10-24
DE69909502D1 (en) 2003-08-14
KR20010075250A (en) 2001-08-09
EP1124864B1 (en) 2003-07-09
KR100615758B1 (en) 2006-08-25
CA2247703C (en) 2007-04-17
JP4576049B2 (en) 2010-11-04

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