CA2267177A1 - Cyanoacrylate adhesive - Google Patents
Cyanoacrylate adhesive Download PDFInfo
- Publication number
- CA2267177A1 CA2267177A1 CA002267177A CA2267177A CA2267177A1 CA 2267177 A1 CA2267177 A1 CA 2267177A1 CA 002267177 A CA002267177 A CA 002267177A CA 2267177 A CA2267177 A CA 2267177A CA 2267177 A1 CA2267177 A1 CA 2267177A1
- Authority
- CA
- Canada
- Prior art keywords
- bis
- cyanoacrylate
- adhesive
- cpds
- cyanoacrylate adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
Abstract
In order to improve the thermal stability of polycyanoacrylates, a combination of 2-cyanopentadienoic acid alkyl ester and alkylene-bis(2-pentadienoate), preferably in amounts of up to a total of 20 wt %, are added to cyanoacrylate adhesives based on monocyano-acrylic acid esters. The alkyl or alkylene group advantageously has between 2 and 4 carbon atoms.
Description
WO 98l14526 1 PCTIEP97/05183 A Cyanoacrylate Adhesive This invention relates to a cyanoacrylate adhesive containing 2-cyanopentadienoic acid ester and to its production and use.
Cyanoacrylate adhesives are one-component reactive adhesives based on monomeric 2-cyanoacrylates. They have cornered the market through extremely quick curing which, depending on the substrate, takes only a few seconds. The resulting properties satisfy many industrial requirements. However, there are special applications where they are still in need of improvement. For example depolymerization is possible at temperatures of only around 100~C, so that prolonged exposure to temperatures above 80~C should be avoided.
This problem of inadequate heat stability has been repeatedly discussed, for example in Journal of Applied Polymer Science 49, (1993), pages 1387-1394. This literature reference first of all describes the production and characterization of alkyl-2-cyano-2,4-pentadienoates and alkyl-2-cyano-2,4-hexadienoates and of bis-(2-cyano-2,4-hexadienoates) and then investigates the effect of adding 10% by weight of individual alkyl esters on the thermal stability of polycyanoacrylic acid propyl ester. The results show that heating for 1 hour to 150~C does not have an adverse effect on strength at 25~C. In the absence of such an addition, however, there is a reduction in strength to about one quarter of the original value.
There is no reference to strength at elevated temperature, nor any indication of how it can be improved.
WO 94I15907 describes cyanoacrylate adhesives with improved resistance to heat and moisture through the use of cyanoacrylate terminated linear polymers, for example polyisobutylene or polyalkyl methacrylates (see page 4, line 16 to page 5, line 7 and page 10, line 27 to page 11) line 12). There are no specific references either to the composition of the adhesives or to their adhesive properties.
The fact that an addition of biscyanoacrylates to cyanoacrylate adhesives can lead to problems, particularly in regard to storage life and curing rate, is well known. In Journal of Polymer Science: Polymer Chemistry Edition, Vol. 16, pages 2475-2507 (1978), Carl J. Buck describes a mixture of isobutyl cyanoacrylate and bis-(2-cyanoacrylates).
N,N-dimethyl-p-toluidine (DMPT) is required to initiate the polymerization reaction. A composition of 90% by weight of methyl cyanoacrylate and 10% by weight of octanediol bis-cyanoacrylate takes one day to cure at 38~C (see page 2504, last paragraph, and page 2505).
Against the background of this prior art, the problem addressed by the present invention was to provide a cyanoacrylate adhesive which would show increased heat resistance for substantially the same storage behavior and acceptable cure times.
The solution provided by the present invention is defined in the claims and is essentially distinguished by the fact that, in addition to at least one typical monocyanoacrylate, the cyanoacrylate adhesive containing 2-cyanopentadienoic acid alkyl ester (CPDS-alkyl) also contains an effective quantity of at least one alkylene bis-(2-cyanopentadienoate) (bis-CPD).
In the context of the invention, "typical monocyanoacrylates" are understood to be compounds corresponding to the following general formula:
H2C = C(CN)-CO-O-R (I) where R is an alkyl, alkenyl, cycloalkyl, aryl, alkoxyalkyl, aralkyl or haloalkyl group, more especially a methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, pentyl, hexyl, allyl, methallyl, crotyl, propargyl) cyclohexyl, benzyl, phenyl, cresyl, 2-chloroethyl, 3-chloropropyl, 2-chlorobutyl, trifluoroethyl, 2-methoxyethyl, 3-methoxybutyl and 2-ethoxyethyl group. The cyanoacrylates mentioned above are known to the expert on adhesives, cf.
Ullmann's Encyclopaedia of Industrial Chemistry, Vol. A1, page 240, Verlag Chemie Weinheim (1985) and US-PS 3,254,111 and US-PS
3,654,340. Preferred monomers are the allyl) methoxyethyl, ethoxyethyl, methyl, ethyl, propyl, isopropyl or butyl esters of 2-cyanoacrylic acid. The monocyanoacrylates represent the largest percentage by weight of polymerizable monomers in the adhesive.
The abbreviation "bis-CPDs" is understood to apply to compounds corresponding to the following general formula:
[CH2 = CH - CH = C(CN)-CO-O]2R' (II) where R' is a branched or unbranched difunctional alkylene radical containing 2 to 18 and more particularly 2 to 4 carbon atoms which may also contain hetero atoms, such as halogens and oxygen. However, R' is preferably a pure hydrocarbon. It is important that the bis-CPDs should be particularly pure. This requirement is satisfied, for example, by the following production and purification methods. Basically, the cyano-pentadienoates may be obtained by the Gerber method (A.H. Gerber, US-PS 3,316,227 (1967)). However, the compounds are obtained in greater purity if, in contrast to the method mentioned above, the reaction mixture is taken up in 4 to 5 times the volume of ca. 5% hydrochloric acid and the precipitate formed is recrystallized from petroleum ether after filtration and drying in air. After drying in a high vacuum, the yields are generally of the order of 50 to 70%. The adhesive formulations prepared with a product obtained in this way are distinguished by greater reactivity, i.e. faster setting times, and also by better stability in storage.
In addition, the required CPDS-alkyl/bis-CPD mixture can be obtained by a one-pot synthesis, i.e. by simultaneous reaction of the corresponding cyanoacetates in one and the same batch.
The abbreviation "CPDS-alkyl" is understood to apply to compounds corresponding to the following general formula:
CH2 = CH - CH = C(CN) - CO - O - R2 (III) where R2 is a branched or unbranched monofunctional alkyl radical containing 1 to 10 carbon atoms and more particularly 1 to 4 carbon atoms which may also contain hetero atoms, such as halogens and oxygen.
However, R2 is preferably a pure hydrocarbon. It is important that the CPDS-alkyls should be particularly pure. This requirement is satisfied, for example, by the production and purification method described above.
The bis-CPDs and CPDS-alkyls in pure form can be stored in light for about 4 weeks at room temperature without significantly discoloring or undergoing changes in their melting points. In a refrigerator) i.e. at T
<10~C/darkness, they can be stored for at least 6 months. However, they can presumably be stored for much longer.
The compounds are stable to extremely weak bases and nucleo-philes, for example water. In the presence of medium-strong to strong bases, for example amine bases, phosphanes, lyes, they undergo spontaneous polymerization similarly to the cyanoacrylates.
The 2-cyanopentadienoates (CPDS-alkyl and bis-CPD) should preferably be added in a quantity of up to 25% by weight and more preferably in a quantity of 1 to 15% by weight, based on the total weight of the adhesive formulation.
The ratio by weight of CPDS-alkyl to bis-CPD can vary within wide limits, although it should preferably be in the range from 4 to 0.25:1 and more preferably in the range from 2 to 0.5:1.
The adhesive may contain additives, for example plasticizers, thickeners, stabilizers, primers, dyes etc. The adhesive preferably contains stabilizers such as, for example, hydroquinone and sulfur dioxide.
The adhesive is prepared in the usual way by mixing the components, preferably by dissolving the respective additives at room temperature.
In all the cases investigated, the stability of the new adhesives in storage exceeded 3 months at room temperature or 3 days at 60~C.
The new cyanoacrylate adhesive according to the invention is particularly suitable for bonds which have to satisfy stringent thermal requirements, for example the bonding of electrical and electronic components.
The invention is illustrated by the following Examples:
I. Starting Compounds and Their Preparation 1. 2-Cyanopentadienoic acid methyl ester = CPDS-Me 2. 2-Cyanopentadienoic acid ethyl ester = CPDs-Et 3. Tetramethylene-bis-(2-cyanopentadienoate) = TMBCP
Cyanoacrylate adhesives are one-component reactive adhesives based on monomeric 2-cyanoacrylates. They have cornered the market through extremely quick curing which, depending on the substrate, takes only a few seconds. The resulting properties satisfy many industrial requirements. However, there are special applications where they are still in need of improvement. For example depolymerization is possible at temperatures of only around 100~C, so that prolonged exposure to temperatures above 80~C should be avoided.
This problem of inadequate heat stability has been repeatedly discussed, for example in Journal of Applied Polymer Science 49, (1993), pages 1387-1394. This literature reference first of all describes the production and characterization of alkyl-2-cyano-2,4-pentadienoates and alkyl-2-cyano-2,4-hexadienoates and of bis-(2-cyano-2,4-hexadienoates) and then investigates the effect of adding 10% by weight of individual alkyl esters on the thermal stability of polycyanoacrylic acid propyl ester. The results show that heating for 1 hour to 150~C does not have an adverse effect on strength at 25~C. In the absence of such an addition, however, there is a reduction in strength to about one quarter of the original value.
There is no reference to strength at elevated temperature, nor any indication of how it can be improved.
WO 94I15907 describes cyanoacrylate adhesives with improved resistance to heat and moisture through the use of cyanoacrylate terminated linear polymers, for example polyisobutylene or polyalkyl methacrylates (see page 4, line 16 to page 5, line 7 and page 10, line 27 to page 11) line 12). There are no specific references either to the composition of the adhesives or to their adhesive properties.
The fact that an addition of biscyanoacrylates to cyanoacrylate adhesives can lead to problems, particularly in regard to storage life and curing rate, is well known. In Journal of Polymer Science: Polymer Chemistry Edition, Vol. 16, pages 2475-2507 (1978), Carl J. Buck describes a mixture of isobutyl cyanoacrylate and bis-(2-cyanoacrylates).
N,N-dimethyl-p-toluidine (DMPT) is required to initiate the polymerization reaction. A composition of 90% by weight of methyl cyanoacrylate and 10% by weight of octanediol bis-cyanoacrylate takes one day to cure at 38~C (see page 2504, last paragraph, and page 2505).
Against the background of this prior art, the problem addressed by the present invention was to provide a cyanoacrylate adhesive which would show increased heat resistance for substantially the same storage behavior and acceptable cure times.
The solution provided by the present invention is defined in the claims and is essentially distinguished by the fact that, in addition to at least one typical monocyanoacrylate, the cyanoacrylate adhesive containing 2-cyanopentadienoic acid alkyl ester (CPDS-alkyl) also contains an effective quantity of at least one alkylene bis-(2-cyanopentadienoate) (bis-CPD).
In the context of the invention, "typical monocyanoacrylates" are understood to be compounds corresponding to the following general formula:
H2C = C(CN)-CO-O-R (I) where R is an alkyl, alkenyl, cycloalkyl, aryl, alkoxyalkyl, aralkyl or haloalkyl group, more especially a methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, pentyl, hexyl, allyl, methallyl, crotyl, propargyl) cyclohexyl, benzyl, phenyl, cresyl, 2-chloroethyl, 3-chloropropyl, 2-chlorobutyl, trifluoroethyl, 2-methoxyethyl, 3-methoxybutyl and 2-ethoxyethyl group. The cyanoacrylates mentioned above are known to the expert on adhesives, cf.
Ullmann's Encyclopaedia of Industrial Chemistry, Vol. A1, page 240, Verlag Chemie Weinheim (1985) and US-PS 3,254,111 and US-PS
3,654,340. Preferred monomers are the allyl) methoxyethyl, ethoxyethyl, methyl, ethyl, propyl, isopropyl or butyl esters of 2-cyanoacrylic acid. The monocyanoacrylates represent the largest percentage by weight of polymerizable monomers in the adhesive.
The abbreviation "bis-CPDs" is understood to apply to compounds corresponding to the following general formula:
[CH2 = CH - CH = C(CN)-CO-O]2R' (II) where R' is a branched or unbranched difunctional alkylene radical containing 2 to 18 and more particularly 2 to 4 carbon atoms which may also contain hetero atoms, such as halogens and oxygen. However, R' is preferably a pure hydrocarbon. It is important that the bis-CPDs should be particularly pure. This requirement is satisfied, for example, by the following production and purification methods. Basically, the cyano-pentadienoates may be obtained by the Gerber method (A.H. Gerber, US-PS 3,316,227 (1967)). However, the compounds are obtained in greater purity if, in contrast to the method mentioned above, the reaction mixture is taken up in 4 to 5 times the volume of ca. 5% hydrochloric acid and the precipitate formed is recrystallized from petroleum ether after filtration and drying in air. After drying in a high vacuum, the yields are generally of the order of 50 to 70%. The adhesive formulations prepared with a product obtained in this way are distinguished by greater reactivity, i.e. faster setting times, and also by better stability in storage.
In addition, the required CPDS-alkyl/bis-CPD mixture can be obtained by a one-pot synthesis, i.e. by simultaneous reaction of the corresponding cyanoacetates in one and the same batch.
The abbreviation "CPDS-alkyl" is understood to apply to compounds corresponding to the following general formula:
CH2 = CH - CH = C(CN) - CO - O - R2 (III) where R2 is a branched or unbranched monofunctional alkyl radical containing 1 to 10 carbon atoms and more particularly 1 to 4 carbon atoms which may also contain hetero atoms, such as halogens and oxygen.
However, R2 is preferably a pure hydrocarbon. It is important that the CPDS-alkyls should be particularly pure. This requirement is satisfied, for example, by the production and purification method described above.
The bis-CPDs and CPDS-alkyls in pure form can be stored in light for about 4 weeks at room temperature without significantly discoloring or undergoing changes in their melting points. In a refrigerator) i.e. at T
<10~C/darkness, they can be stored for at least 6 months. However, they can presumably be stored for much longer.
The compounds are stable to extremely weak bases and nucleo-philes, for example water. In the presence of medium-strong to strong bases, for example amine bases, phosphanes, lyes, they undergo spontaneous polymerization similarly to the cyanoacrylates.
The 2-cyanopentadienoates (CPDS-alkyl and bis-CPD) should preferably be added in a quantity of up to 25% by weight and more preferably in a quantity of 1 to 15% by weight, based on the total weight of the adhesive formulation.
The ratio by weight of CPDS-alkyl to bis-CPD can vary within wide limits, although it should preferably be in the range from 4 to 0.25:1 and more preferably in the range from 2 to 0.5:1.
The adhesive may contain additives, for example plasticizers, thickeners, stabilizers, primers, dyes etc. The adhesive preferably contains stabilizers such as, for example, hydroquinone and sulfur dioxide.
The adhesive is prepared in the usual way by mixing the components, preferably by dissolving the respective additives at room temperature.
In all the cases investigated, the stability of the new adhesives in storage exceeded 3 months at room temperature or 3 days at 60~C.
The new cyanoacrylate adhesive according to the invention is particularly suitable for bonds which have to satisfy stringent thermal requirements, for example the bonding of electrical and electronic components.
The invention is illustrated by the following Examples:
I. Starting Compounds and Their Preparation 1. 2-Cyanopentadienoic acid methyl ester = CPDS-Me 2. 2-Cyanopentadienoic acid ethyl ester = CPDs-Et 3. Tetramethylene-bis-(2-cyanopentadienoate) = TMBCP
4. Ethylene-bis-(2-cyanopentadienoate) = bis=CPD
5. Ethyl cyanoacrylate 6. Isopropyl cyanoacrylate Comonomers 1 to 4 were prepared by the method described above.
The comonomers were characterized by CHN analysis, IR spectro-scopy and'H-NMR.
II. Composition and Production of the Cyanoacr)ilate Adhesive The composition in respect of the monomers is shown in Tables 1 and 2. The addition of comonomers in % by weight is based on the final adhesive formulation.
In addition to the monomers, the adhesive contains the following additives:
1. 500 ppm hydroquinone 2. 10 ppm sulfur dioxide.
The cyanoacrylate adhesive according to the invention can be prepared from these components in the usual way. Preferably, all the components of the adhesive are dissolved at room temperature by shaking or stirring.
The adhesive has typical viscosities of about 2.2 to 4.0 mPas (at 20 t 0.1 ~C, as measured in accordance with DIN 54453). Their storage life is also within the usual limits. All the samples prepared were still liquid after storage for 3 months at room temperature.
III. Adhesive Properties 1. Contact time The contact time is the setting time on EPDM foam rubber, i.e. the period of time for which the parts to be joined have to be pressed together until material failure occurs during separation of the bond.
2. Tensile shear strength The test specimens were produced and prepared as follows:
Cleaned and sandblasted AI plates measuring 25 x 100 mm were bonded with a 12.5 mm overlap. The specimens were then stored first for 5 days in a conditioned atmosphere (20~C/65% relative air humidity) and then for 2 days at 105~C in a heating cabinet.
The tensile shear strength was measured at the indicated temperature in accordance with DIN EN 1465 (rate of advance 10 mm/min.) and is expressed in N/mm2.
The results are set out in Tables 1 and 2. The tests show that the contact time is only negligibly lengthened and, in all the cases investigated, is between 5 and 6 seconds. Both monofunctional and bifunctional additives improve tensile shear strength at elevated temperature. In the cases mentioned (see Table below), the values obtained where the compounds are used in combination are distinctly higher than might have been expected from the individual effects taken together. Accordingly) a synergistic effect may be assumed to occur in the Examples mentioned.
Table 1:
Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strengthContact time Type/proportion Type/proportionN/mm2 C secs.
y 1 CPDS-ME/0 3.6 105 Ethyl Bis-CPD/0 cyanoacrylate 2 5 6.8 5-6 3 8 6.1 5-6 4 11 5.9 5-6 W
0 6.4 5-6 6 5 10.5 5-6 7 CPDS-ME/0 1.3 130 Bis-CPD/0 8 5 2.4 9 8 1.3 11 1.8 Table 1 continued Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strengthContact time Type/proportion Type/proportionN/mm2 C secs.
y 11 0 3.1 12 5 8.1 13 CPDS-ET/0 1.3 130 Bis-CPD/0 14 0 3.2 0 W
15 CPDS-ET/ 3.1 Ethyl 5 cyanoacrylate Bis-CPD/
16 5 6.8 17 CPDS-ME/0 1.3 130 " TMBCP
18 0 2.9 19 5 2.4 20 5 4.6 Table 1 continued Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strength Contact time Type/proportion Type/proportion N/mm2 ~C Secs.
n 21 Isopropyl cyanoacrylate CPDS-ET/0 TMBCP 0 2.6 130 N
Ov 22 0 0.2 2.8 23 0 1.2 3.4 24 5 0.2 5.5 25 5 1.0 7.8 W
26 5 0 4.8
The comonomers were characterized by CHN analysis, IR spectro-scopy and'H-NMR.
II. Composition and Production of the Cyanoacr)ilate Adhesive The composition in respect of the monomers is shown in Tables 1 and 2. The addition of comonomers in % by weight is based on the final adhesive formulation.
In addition to the monomers, the adhesive contains the following additives:
1. 500 ppm hydroquinone 2. 10 ppm sulfur dioxide.
The cyanoacrylate adhesive according to the invention can be prepared from these components in the usual way. Preferably, all the components of the adhesive are dissolved at room temperature by shaking or stirring.
The adhesive has typical viscosities of about 2.2 to 4.0 mPas (at 20 t 0.1 ~C, as measured in accordance with DIN 54453). Their storage life is also within the usual limits. All the samples prepared were still liquid after storage for 3 months at room temperature.
III. Adhesive Properties 1. Contact time The contact time is the setting time on EPDM foam rubber, i.e. the period of time for which the parts to be joined have to be pressed together until material failure occurs during separation of the bond.
2. Tensile shear strength The test specimens were produced and prepared as follows:
Cleaned and sandblasted AI plates measuring 25 x 100 mm were bonded with a 12.5 mm overlap. The specimens were then stored first for 5 days in a conditioned atmosphere (20~C/65% relative air humidity) and then for 2 days at 105~C in a heating cabinet.
The tensile shear strength was measured at the indicated temperature in accordance with DIN EN 1465 (rate of advance 10 mm/min.) and is expressed in N/mm2.
The results are set out in Tables 1 and 2. The tests show that the contact time is only negligibly lengthened and, in all the cases investigated, is between 5 and 6 seconds. Both monofunctional and bifunctional additives improve tensile shear strength at elevated temperature. In the cases mentioned (see Table below), the values obtained where the compounds are used in combination are distinctly higher than might have been expected from the individual effects taken together. Accordingly) a synergistic effect may be assumed to occur in the Examples mentioned.
Table 1:
Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strengthContact time Type/proportion Type/proportionN/mm2 C secs.
y 1 CPDS-ME/0 3.6 105 Ethyl Bis-CPD/0 cyanoacrylate 2 5 6.8 5-6 3 8 6.1 5-6 4 11 5.9 5-6 W
0 6.4 5-6 6 5 10.5 5-6 7 CPDS-ME/0 1.3 130 Bis-CPD/0 8 5 2.4 9 8 1.3 11 1.8 Table 1 continued Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strengthContact time Type/proportion Type/proportionN/mm2 C secs.
y 11 0 3.1 12 5 8.1 13 CPDS-ET/0 1.3 130 Bis-CPD/0 14 0 3.2 0 W
15 CPDS-ET/ 3.1 Ethyl 5 cyanoacrylate Bis-CPD/
16 5 6.8 17 CPDS-ME/0 1.3 130 " TMBCP
18 0 2.9 19 5 2.4 20 5 4.6 Table 1 continued Tensile shear strength and contact time in dependence upon the type and composition of the monomers No. Basic monomer Monomers added Tensile shear strength Contact time Type/proportion Type/proportion N/mm2 ~C Secs.
n 21 Isopropyl cyanoacrylate CPDS-ET/0 TMBCP 0 2.6 130 N
Ov 22 0 0.2 2.8 23 0 1.2 3.4 24 5 0.2 5.5 25 5 1.0 7.8 W
26 5 0 4.8
Claims (6)
1. A cyanoacrylate adhesive based on a typical monocyanoacrylate containing 2-cyanopentadienoic acid ester, characterized by the addition of an effective quantity of at least one alkylene-bis-(2-pentadienoate).
2. A cyanoacrylate adhesive as claimed in claim 1, characterized by an alkylene group containing 2 to 18 and, more particularly, 2 to 4 carbon atoms.
3. A cyanoacrylate adhesive as claimed in claim 1, characterized by an alkyl group containing 1 to 10 and, more particularly, 1 to 4 carbon atoms.
4. A cyanoacrylate adhesive as claimed in at least one of claims 1, 2 and 3, characterized by a quantity of 2-cyanopentadienoates of up to 25%
by weight and preferably from 1 to 20% by weight, based on the total weight of the adhesive formulation.
by weight and preferably from 1 to 20% by weight, based on the total weight of the adhesive formulation.
5. A cyanoacrylate adhesive as claimed in at least one of claims 1 to 4, characterized by a ratio by weight of 2-cyanopentadienoic acid ester to alkylene-bis-(2-pentadienoate) of 4 to 0.25:1 and, more particularly, 2 to 0.5:1.
6. The use of the cyanoacrylate adhesives claimed in at least one of claims 1 to 5 for bonding electrical and electronic components.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19640202.6 | 1996-09-30 | ||
| DE19640202A DE19640202A1 (en) | 1996-09-30 | 1996-09-30 | Cyanoacrylate adhesive |
| PCT/EP1997/005183 WO1998014526A1 (en) | 1996-09-30 | 1997-09-22 | Cyanoacrylate adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2267177A1 true CA2267177A1 (en) | 1998-04-09 |
Family
ID=7807369
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002267177A Abandoned CA2267177A1 (en) | 1996-09-30 | 1997-09-22 | Cyanoacrylate adhesive |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6201088B1 (en) |
| EP (1) | EP0929617A1 (en) |
| JP (1) | JP2001501243A (en) |
| CA (1) | CA2267177A1 (en) |
| DE (1) | DE19640202A1 (en) |
| WO (1) | WO1998014526A1 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8044793B2 (en) * | 2001-03-01 | 2011-10-25 | Fisher-Rosemount Systems, Inc. | Integrated device alerts in a process control system |
| US20030099246A1 (en) * | 2001-11-28 | 2003-05-29 | Motorola, Inc. | Method and apparatus for self-link assessing router |
| US7454519B2 (en) * | 2002-03-22 | 2008-11-18 | Motorola, Inc. | Method for automatically allocating address prefixes |
| US9012530B2 (en) | 2010-07-30 | 2015-04-21 | Warsaw Orthopedic, Inc. | Bioadhesive for periodontal gingival and/or bone tissues |
| JP6112121B2 (en) * | 2012-12-14 | 2017-04-12 | 東亞合成株式会社 | Adhesive composition |
| EP2955904B1 (en) * | 2014-06-10 | 2016-10-19 | Siemens Aktiengesellschaft | Allocation of network addresses for network participants |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3254111A (en) | 1960-12-09 | 1966-05-31 | Eastman Kodak Co | Esters of alpha-cyanoacrylic acid and process for the manufacture thereof |
| US3316227A (en) | 1963-10-18 | 1967-04-25 | Lord Corp | Preparation of 1, 1-disubstituted diunsaturated compounds |
| US3654340A (en) | 1970-08-27 | 1972-04-04 | Minnesota Mining & Mfg | Cyanoacrylate monomer process |
| GB1415102A (en) * | 1973-11-07 | 1975-11-26 | Trofimov N N Etlis V S | Adhesives |
| JPS5647471A (en) * | 1979-09-28 | 1981-04-30 | Japan Synthetic Rubber Co Ltd | Instantaneous adhesive composition |
| US4425471A (en) * | 1981-04-23 | 1984-01-10 | Minnesota Mining & Manufacturing Company | Novel cyanoacrylate adhesive compositions and methods of bonding |
| JPS61145267A (en) * | 1984-12-19 | 1986-07-02 | Toagosei Chem Ind Co Ltd | Adhesive composition |
| JP2671528B2 (en) * | 1989-11-27 | 1997-10-29 | 東亞合成株式会社 | Instant adhesive composition |
| JPH08505383A (en) | 1993-01-11 | 1996-06-11 | ユーロタツクス・リミテツド | Process for producing 2-cyanoacrylic acid ester and use of ester produced by the process as an adhesive |
| US5386047A (en) * | 1994-03-11 | 1995-01-31 | Loctite Corporation | Di-α-cyanopentadienoate disiloxane compounds for use in adhesives |
| ES2135073T3 (en) * | 1994-06-06 | 1999-10-16 | Henkel Kgaa | PROCEDURE FOR THE OBTAINING OF BISCIANOACRYLATES. |
-
1996
- 1996-09-30 DE DE19640202A patent/DE19640202A1/en not_active Ceased
-
1997
- 1997-09-22 JP JP10516190A patent/JP2001501243A/en active Pending
- 1997-09-22 EP EP97942958A patent/EP0929617A1/en not_active Withdrawn
- 1997-09-22 WO PCT/EP1997/005183 patent/WO1998014526A1/en not_active Application Discontinuation
- 1997-09-22 CA CA002267177A patent/CA2267177A1/en not_active Abandoned
- 1997-09-22 US US09/269,654 patent/US6201088B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0929617A1 (en) | 1999-07-21 |
| DE19640202A1 (en) | 1998-04-09 |
| WO1998014526A1 (en) | 1998-04-09 |
| US6201088B1 (en) | 2001-03-13 |
| JP2001501243A (en) | 2001-01-30 |
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