CA2267457C - Multi-layer magnetic tag - Google Patents

Multi-layer magnetic tag Download PDF

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Publication number
CA2267457C
CA2267457C CA002267457A CA2267457A CA2267457C CA 2267457 C CA2267457 C CA 2267457C CA 002267457 A CA002267457 A CA 002267457A CA 2267457 A CA2267457 A CA 2267457A CA 2267457 C CA2267457 C CA 2267457C
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Prior art keywords
magnetic
tag
magnetic material
pattern
regions
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CA002267457A
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CA2267457A1 (en
Inventor
Michael David Crossfield
Mark England
Andrew Nicholas Dames
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Flying Null Ltd
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Flying Null Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01VGEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS
    • G01V15/00Tags attached to, or associated with, an object, in order to enable detection of the object

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  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Geophysics (AREA)
  • Burglar Alarm Systems (AREA)
  • Credit Cards Or The Like (AREA)
  • Hard Magnetic Materials (AREA)
  • Magnetic Record Carriers (AREA)
  • Soft Magnetic Materials (AREA)
  • Inspection Of Paper Currency And Valuable Securities (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

A magnetic marker or tag is disclosed which comprises (a) a first magnetic material characterised by high permeability, low coercivity and a non-linear B-H characteristic; and (b) a second magnetic material whic h is capable of being permanently magnetised, said first and second magnetic materials being superimposed one on the other and advantageously being substantially coterminous. The second magnetic material is preferably of medium coercivity. Selected regions of sa id second magnetic material can carry magnetisation such as to magnetically divide the first magnetic material into a series of magnetically discrete zones, the length of said magnetically discrete zones and/or the lengths of said magnetised regions ("gaps") of said second materi al constituting elements of a code.

Description

Background To The Invention This invention relates to magnetic tags and, more particularly but not e~clusa.vely, is c°ancerned with tags which can be encoded with dat:.a.
In previous patent applications, notably in WOg6:31?90, l0 published November ?, ?000, and WU~7~74338, published April 16, 2002, we have described x:emate .identif:ication tags which may be interrogated using alternating and/or static magnetic fields. In response to interrogation the tags emit magnetic signals which nuay be detected in suitable receiving equipment.. Such tags have manor applications i_n area;s such as art:a.c~.e identificat: ion, security and access control.
Certain of the tags described in W'U5631790 contain elements of high. permeability, law cae:rcivit:y, "raft"
magnetic alloy in the farm of a strip, ware or thin film, overlaid with a medium coercivity magnetic layer. The magnetic signal or "signature°'' gexx.erated by the high permeability element in respoxase to interrogation is determined by the magnetisation pattern stored in the medium coercivity "coding" layer, and the characteristics of the high permeability element.
In practical implementations tag coding can far example be carried out during tag manufacture by contact- or near contact-recording the appropriate magnetic pattern onto a continuous coding layer using an array of permanent magnets . This method is pa.rticu=Lady suitable for producing many tags with the same c~ade.
Another method, which is Suitable far manufacturing tags whose code will never require change, is to place suitably-magnetised pieces of coc3~.ng material at appropriate positions on the high permeability material.
Yet another method is to place un-magnetised pieces of medium coercivity material in an appropriate pattern using e.g. a thermal transfer process, and then to bulk-magnetise the entire structure.
A very convenient arrangement uses a magnetic recording head of the type well-known for recording information onto magnetic tape. With this arrangement, tags manufactured with a uniform un-magnetised coding layer can have patterns individually coded at the point--of-issue. This is extremely us~:fu1 for applications such as airline baggage tagging, 'where individual tag details (passenger name etc.) are not known in advance of issue.
W09704338 discloses a magnetic marker or tag, which comprises (a) a first magnetic material characterised by high permeability, low caercivity and a non-linear B-H characteristic; and (b) a secor~.d magnetic material which is capable of being permanently magnetised, characterised in that said second magnetic material is magnetised with a non-uniform field pattern.
US 5,643,686 (D1) discloses the use of a fixed permanent magnetic pattern for identifying a magnetic recording medium. With th3.s system, a high degree of security against forgery ~.s Qbtained. The magnetic medium comprises a non-magnet~.c: substrate which supports at least two magnetic:; layers one of which contains dispersed magnetic particles having a coercivity of 4000 oersted or less and has a non-rewritable fixed signal recorded i.n~o the layers. This is achieved by magnetically orienting the dispex:sed particles during manufacture of the layered material while the particle ~ispexsiorz is still wet. The orienting magnetic field is active unt.a~l the layer has become solid, whereupon the dispersed particles have acquired the desired non-erasable magnetic pattern.
EP 0353040-A (D2) discloses the application of t:he so~-called "Watermark"-type magnetic material to a soft magnetic EAS (electronic arta.cle surveillance) t:ag. The "Watermark" material comprises magnet,:i.c particles orientated into alternating ,~.irections differing in phase by 90 degrees within adjacent; regions. In s.ts initial state, the "Watermark" material, although structured during manufacture, is urxmagr~etised. ~t thus has no effect upon the soft magnetic materia:~ in the EAS tag, and the tag can be detected by conventional a.c.
interrogation ( a . g . as ccammo:raly used ;~t det.ect ion gates in stores) . To prevent detect:ian o:~ t~xe tag, i.t is wiped, at the point ~of sale, with a permaneni~ magnet. This causes alternate regions of the "Watermark" layer to become magnetised; these regions then exert a uniform magnetic bias which magnetically clamps adjacent: regions of the soft magnetic: material., thereby magnetically dividing the material into regions too small to generate an alarm signal when interrogated by an a.c:. detection system. There is no magnetic pattern within the magnetised regions - just; a uniform magnetisation.
3o Brief Description of the.Draw~
FIG. 1 shows an example of a recorded pattern tc>
magnetically partition a strip tag into active segments.
FIG. 2 shows an example of a. practical pattern with improved definition of ends of material segment:>.
FIG. 3 is an alternative to the pattern of FTC. 2 with reduced field variation.

3a Summary of The yven~~~~
The present application relates to magnetic tags whose construction i.s such treat, bar means ca f: relatively simple magnetic recording, it is possible to generate recorded patterns in parts of the tag which are such as _4_ ......

to isolate areas of a tag (made from a continuous layer " "
"

of soft magnetic material) such that the areas behave magnetically as if they were physically separate. It .. ..

also describes how data may be encoded into such a tag ," ", ~

using variations in size and/or spacing of the isolated " "

regions.
......

More particularly, according to one aspect of the present invention, there is provided a magnetic marker or tag which comprises (a) a first magnetic material characterised by high permeability, low coercivity and ....

n-linear H-H characteristic; and (b) a second n o . .
a magnetic material which is capable of being permanently magnetised by conventional magnetic recording techniques, said first and second magnetic materials being superimposed one on the other, wherein selected regions of said second magnetic material are magnetised to carry magnetisation in the form of an erasable pattern of repeatedly reversing polarity, said magnetisation being such as to couple magnetically with contiguous regions of said first magnetic material [such] so as to magnetically divide the first magnetic material into a series of magnetically discrete zones, the length of said magnetically discrete zones and/or _ the lengths of said magnetised regions ("gaps") of said second material constituting elements of a code.

Unlike D1, the tags of this invention are designed to adopt a coding scheme which requires the magnetisation of regions of the second magnetic material. It is inconceivable to incorporate such magnetisation into the material during the manufacture of the tag; this would render the manufacture so costly as to make the process unviable. In contrast to D1, therefore, the second magnetic material used in a tag of this invention is capable of being permanently magnetised by lf.r1 .'.~ :H: __.
...

-5- ......

conventional magnetic recording techniques, and is ""' preferably a conventional magnetic recording medium.

The magnetic pattern applied to the material is thus .. ..

erasable and is therefore remote from the non- "' rewritable magnetic security code which is the essence ~

of the dislcosure in Dl.

......

Similarly, tags of the present invention differ essentially from those of D2 in that they do not possess a pre-formed distribution of magnetic particles ..
into alternating zones whose alignment differs in phase . .
....

by 90 degrees. Such a pre-formed orientation results .. .
. .

in a binary response when the material is wiped .. .

longitudinally with a permanent magnet; each zone is either magnetised or not by this action. Consequently it is not possible, with such a medium, to incorporate an erasable pattern of repeatedly reversing polarity over any chosen length of the material.

These distinctions are to be expected given that D1 and D2 are directed towards the enhancement of security whereas the present invention is concerned with tags which can be magnetically coded to carry information.
Advantageously, the two magnetic materials are substantially coterminous. Such a tag can be encoded with information by magnetising selected regions of the second magnetic material; the magnetised regions nullify the properties of the first magnetic material with which they are in contact, thereby effectively dividing the soft (first) magnetic material into a series of magnetically discrete zones even though in physical terms the material is continuous. For convenience, magnetised regions of the second magnetic material are referred to herein as "gaps" since they serve to synthesise magnetic gaps in the first magnetic w:.:!~ "' .E : , ...

v ~T s 6- ......
.

.
material with which they are in contact. ' Preferably, the second magnetic material is a material : .

.. ..

of medium coercivity-. ""

....

As will be explained below, the preferred nature of the ' magnetisation depends upon the physical size of the ;" ", gap . ....

....

The magnetically discrete zones of said first magnetic ' ..
material ("active regions") and the lengths of said . .

magnetised regions ("gaps") of said second material .. .
.

.
constituting elements of a code can be thought of as ' ' ' .. .

"magnetic codons" since they are used in the invention to generate coded information in the tag. A suitable encryption key is required for writing and/or reading the information; this is preferably as simple as .

event be achieved by possible, and can in any conventional means. A simple encryption system is described, by way of example, later in this document.

In one embodiment, the lengths of the magnetically discrete zones in said first magnetic material ("active regions") are constant whereas the lengths of the I 25 magnetised regions ("gaps") of said second material are varied to provide encoding of data. Other arrangements - e.g. using different lengths for the active regions as well as, or instead of, different lengths for the gaps - may be adopted if desired.

The invention is thus able to provide magnetically recorded patterns on a tag made from a layer of soft magnetic material overlaid by a layer of medium coercivity magnetic material.
Numerous materials are commercially available which can AMENDC~J ~u.~~ r -~._ be satisfactorily be used in this invention. Far example, one suitable material for use as the first, soft magnetic material is the thin-film material.
supplied by IST of Belgium under the trade name "Atalante". This is a sputtered amorphous alloy with a thickness of about 1 urn supported on a PET backing.
The film has a typical intrinsic permeability of 105 and a low frequency coercivity of a few A/m.
Suitable coding materials - i.e. rciaterials for use as the second magnetic material - are finely-divided ferromagnetic oxides with coercivities in the range 100 to 6000 oerste.d. Suitable materia~l.s are available commercially from many suppliers, e.g. HASF (Germany), Kurtz (Germany) and TDK (;Japan), and are generally used for the manufacture of magnetic recording media.
The simplest format of mufti-bit tag (also termed label) capable of being read by a Flying Null reader as described in W09631790 consists of an array of physically separate pieces of magnetic material, th.e information being encoded by the sizes of the metal elements and/or the Qaps between them.
In such a design the minimum length of element which can be reliably detected i.s determined by the details of the reader, the intrinsic properties of the magnetic material, and the shape of the e.Lement. For example, for simple labels made from Atalante film thin, the critical length of 3 mm w~.de material for detectj.on in a 2nd harmonic detector of the type described in GB
9506909.2 is currently around 5 mm. lengths of half this dimension produce negligible output. This arises from the shape factor of the element, which reduces the extrinsic permeability of the material from about 105 for an element of infinite :Length, to around 5000 far a . ., .. " . .,u.~ N",~ , easily achieve spatial resolutions of a few Vim, and thus by using such heads it is also easy to sharply define the end conditions on the inactive segments by adjusting the phase of the recorded signal. This <;ar~ be useful in defining precise spatial end points of blocks. For example a sinusoidal bias pattern can be set to start and end at the 90 degree phase points of the sine wave, rather than zero phase, giving very rapid rise of field at the start and Enc. of the segment: which is intended to be inactive. Tt is also simple to ~>rogramme patterns where the residual bias over the active regions caused by the fields from the ends of the magnetised. region are either of uniform polarity, or reverse in polarity from one end to the other.
According to an aspect of the present invention, there is provided a magnetic marker or tag which comprises (a) a first magnetic material having higtu permeability, low coercivity and a non-linear B-H characteristic; and (b) a second magnetic material which is capable of being permanently magnetised by conventional magnetic recording techniques, said first and second magnetic materials being superimposed one on the other selected regions of said second magnetic material being magnetised to carry magnetisation in the form of an erasable pattern of repeatedly reversing polarity, said magnetisation being such as to couple magnetically with contiguous regions of said first magnetic material so as to magnetically divide the first magnetic material into a series of magnetically discrete zones, at least one of the length of said magnetically discrete zones and the lengths of said magnetised regions ("gaps") constituting elements of a code.

8a Examples of suitable patterns for t:he inactive regions of multi-bit data tags are indicated in the Figures below.
In all cases the patterns include "guard bands" at each end. These inactive regions ensure trAat th.e active regions in a tag structure are all in similar local magnetic environments, improving consistency of segment lengths as measured by the reader system.
Exemplary Coding Schemes for Multi-bit Flying Null Tags Tags constructed as described above are capable of being encoded with informatian using a variety of schemes. One of the simplest is described in one of our earlier applications. This uses the presence of an. active region to denote a digital "1", and an inactive region to denote a digital "0", the spacing between regions being constant along the tag. Since inactive regions are, by definition, not detected by the tag reader it is also necessary to add active regions at both ends of the tag, to indicate to the reader when the data has started and ended. This enables the C~
poles of the pattern are separated by, at most, half the minimum active length for the soft:, magnetic material.
This ensures that the regions of m~atex:-ial overlaid by the pattern are magnetically segregated into lengths incapable of gerierat:ing a significant signal by virtue of their low effe~ct.ive permeability.
For labels made as desruribed above and using 3 mm wide strips of Atalante film overlaid with a medium coercivity recording layer, the minimum ;~.engtl:~.for an active segment is typically 5 mm. To ~:ender regiozrs of any length inactive the spatial wavelength of the recorded pattern therefore needs to be less than a~caunc~. 5 mm, and preferably less than 2.5 mm.
For labels made from vacuurrmc;hmelt~e t:ype 6025 amorphous strip 1 mm wide and :l5l.rm t;.hic:~c the minimum effective active element length in a reader :ducr~. as described in PCT Publication No. 1~0~6/3~"x~a0 around 10 mm, and the spatial wavelength of the recorded pattern needs to be less than 10 mm, and preferably le:~s t:.han 5 mm, for good attenuation of signals from t:he unc er~ying region.
Such magnetisation patterns can be created using closely-spaced. arrays of narrow permanent 2x~agr~ets . Another technique is to deposit the recorc~~ng layer in segments which are narrower and more c:l.osel4~~ solaced than the critical dimensions described above, ~.nd then to magnetise them uniformly in those x4eg~ons of the tag which are required to be inactive. bet another alternative is to use a conventional contact magnetic recording process of the type wide:~y used for recording information onto magnetic' tape. Suc:wh processes can easily achieve spatial resolutions of a tew lam, and thus by using such heads it is also easy tc:o sraarply define the end conditions on the inactive segr~ent:s by ~,.. CA 02267457 1999-03-29 1. _ -10- ......
.

.

adjusting the phase of the recorded signal. This can ....:.

be useful in defining precise spatial end points of blocs. For example a sinusoidal bias pattern can be ; , ;

.. ..
set to start and end at the 90 degree phase points of ....

the sine wave, rather than zero phase, giving very rapid rise of field at the start and end of the segment which is intended to be inactive. It is also simple to programme patterns where the residual bias over the " "

active regions caused by the fields from the ends of '" "' the magnetised region are either of uniform polarity, ..
or reverse in polarity from one end to the other.
. .

....

.. .

. .
Examples of suitable patterns for the inactive regions .. .

of multi-bit data tags are indicated in the Figures below. In all cases the patterns include "guard bands"

at each end. These inactive regions ensure that the active regions in a tag structure are all in similar local magnetic environments, improving consistency of segment lengths as measured by the reader system.

Exemplary Coding Schemes for Multi-bit Flying Null Tans Tags constructed as described above are capable of being encoded with information using a variety of schemes. One of the simplest is described in one of our earlier applications. This uses the presence of an active region to denote a digital "1", and an inactive region to denote a digital "0", the spacing between regions being constant along the tag. Since inactive regions are, by definition, not detected by the tag reader it is also necessary to add active regions at both ends of the tag, to indicate to the reader when the data has started and ended. This enables the storage of a character by using a binary representation. For example, a decimal "6" could be represented by 11101, 110 being the binary ~:.w " .; _ , . , -11- ......

representation of 6, and the leading and trailing "1"s :

indicating the start and end of the data. This scheme is very easy to apply, and particularly suitable for ; , ;

tags with only a few bits data capacity. For higher ....

data capacity tags, however, this scheme is less attractive. A particular drawback is that as data words get longer, the codes can contain long runs of ......

successive "0"s, and this causes problems in decoding. " "

These problems include deciding when the end of a tag '" "' has been reached, and in accommodating signal width variations caused by variations in tag speed with ..
. .

. .
motion relative to the reader.

. .
. .
.. .

Robust coding schemes for high capacity tags are those which do not generate long runs of successive "0"s and have inherent embedded tag speed information. It is also very convenient from an implementation viewpoint if tags of a given data capacity are all the same physical length.
A general approach which enables coding schemes which can meet all these criteria is based on encoding information by varying the lengths of the inactive regions (gaps) between fixed length active regions.
A practical example of one such coding scheme will now be described. In this scheme a character block is made up from 4 active regions and 3 inactive regions. The active regions are all of constant length, and the first and last are fixed in position. The positions of the middle two active regions are variable, and are defined by a scheme which assigns one of four possible lengths to each of the three inactive regions in the block, with the constraint that the total physical length of the block remains constant. A typical set of gap sizes is 1.5, 3.5, 5.5 and 7.5 mm, using 5 mm -12- ......
.
active regions, with the constraint that three gaps ~~~~:~
defining a character sum to 12.5 mm. This gives twelve possible variations, which can be related to characters ; , , . ~ ~ .
as follows: " "
....

GAP1 GAP2 GAP3 CHARACTER " " "

....

_ 1 3.5 7.5 0 . ....

1.5 5.5 5.5 1 ..
. . .

1.5 7.5 3.5 2 .. .

. .
3.5 1.5 7.5 3 . .
.. .

3.5 3.5 5.5 7.5 3.5 1.5 5 5.5 5.5 1.5 6 3.5 7.5 1.5 ~.5 1.5 3.5 5.5 3.5 3.5 3.5 5.5 3.5 #

5.5 1.5 5.5 The characters 0-4, when read in the reverse direction, correspond to the characters 5-9, while the * and #
symbols are palindromes. Using this coding scheme, the reading direction of the tag can conveniently be determined by using the * or # as start or stop characters. For greater code security, a checksum character in modulo-5 format can be placed centrally in a number containing an even number of characters. This gives information both on the direction (because ,; ,. ;
::, , ,r CA 02267457 1999-03-29 _,_ -13- ......

..

reverse values will read as 5-9) and the integrity of .~..:.

the data.

. .

Information on the speed of the tag can be extracted by the tag reading apparatus by timing the occurrences of '" "' every third active region. These regions occur at ' character block spacings, and are preferably uniformly ......

spaced every 27.5 mm along the tag. ....

.,..

Of course, other values of gaps sizes and active element lengths may be used, and the same principles can be applied to schemes with different numbers of " "
.. .

gaps and gap size steps. For example, a simple extension to the scheme described is to create a fifth step size option of 9.5 mm. Still using a block containing 3 inactive regions, but now extended in total length from 27.5 mm to 29.5 mm, it can readily be shown that 18 unique characters (including 2 palindromes) can be coded. This extended scheme provides increased data capacity for a given overall tag length compared to the simpler scheme, at the expense of requiring data to be converted to a hexadecimal rather than decimal format.

It is also possible to use variations in the lengths of active elements instead of in the gap sizes to encode data in a generally analogous way, though this has to take account of the constraints on the minimum length for an active element discussed earlier. A coding arrangement which uses a combination of varying gap sizes and varying active region lengths is potentially efficient in terms of minimising overall tag length for a given data capacity.

a:.:

Claims (13)

WHAT IS CLAIMED IS:
1. A magnetic marker or tag which comprises (a) a first magnetic material having high permeability, low coercivity and a non-linear B-H characteristic; and (b) a second magnetic material which is capable of being permanently magnetised by conventional magnetic recording techniques, said first and second magnetic materials being superimposed on each other, selected regions of said second magnetic material being magnetised to carry magnetisation in the form of an erasable pattern of repeatedly reversing polarity, said magnetisation being such as to couple magnetically with contiguous regions of said first magnetic material so as to magnetically divide the first magnetic material into a series of magnetically discrete zone's, at least one of the length of said magnetically discrete zones and the lengths of said magnetised regions ("gaps") constituting elements of a code.
2. A tag as claimed in claim 1, wherein the two magnetic materials are substantially coterminous.
3. A tag as claimed in claim 1, wherein said second magnetic material comprises one or more finely divided ferromagnetic oxides.
4. A tag as claimed in claim 3, wherein the second magnetic material is a material with a coercivity in the range 100 to 6000 oersted.
5. A tag as claimed in claim 1, wherein the pattern of magnetisation applied to said second magnetic material is such that (i) the lengths of the magnetically discrete zones in said first magnetic material ("active regions") are constant and (ii) the lengths of said magnetised regions ("gaps") of said second material are varied to provide encoding of data.
6. A tag as claimed in claim 4, wherein the magnetisation of said second magnetic material (in said "gaps") is uniform when the length of a given "gap" is small in relation to the minimum length of an "active region" capable of being detected when the tag is read.
7. A tag as claimed in claim 4, wherein when the length, 1g, of a given "gap" is one of the same order larger than the minimum length, L a, of an "active region" capable of being detected when the tag is read, the magnetisation of said second magnetic material (in said "gaps") comprises a pattern of repeatedly reversing polarity, the spatial frequency of said pattern being such that the North and South poles thereof are spaced apart by a distance, d, which is less than L a.
8. A tag as claimed in claim 7, wherein the distance d is less than L a/2.
9. A tag as claimed in claim 7, wherein the magnetisation of said second magnetic material (in said "gaps") comprises a pattern of repeatedly reversing polarity in the form of a sine wave which begins and ends at a 90 degree phase point in the wave.
10. A tag as claimed in claim 1, wherein raid second magnetic material is in the form of commercially available magnetic recording tape.
11. A method of encoding data in a magnetic tag of the type claimed in claim 1, the method comprising recording a magnetic pattern in selected regions of said second magnetic material, said magnetic pattern being in the form of an erasable pattern of repeatedly reversing polarity, said magnetisation being such as to couple magnetically with contiguous regions of said first magnetic material to magnetically divide the first magnetic material into a series of magnetically discrete zones, at least one of the length of said magnetically discrete zones and the lengths of said magnetised regions ("gaps") of said second material comprising elements of a code.
12. A method according to claim 11, wherein said magnetic pattern is recorded using a magnetic recording head.
13. A method according to claim 11, wherein said magnetic pattern is recorded using an array of closely spaced, parallel permanent magnets.
CA002267457A 1996-09-27 1997-09-29 Multi-layer magnetic tag Expired - Fee Related CA2267457C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9620190.0A GB9620190D0 (en) 1996-09-27 1996-09-27 Improved methods for coding magnetic tags
GB9620190.0 1996-09-27
PCT/GB1997/002690 WO1998013708A1 (en) 1996-09-27 1997-09-29 Multi-layer magnetic tag

Publications (2)

Publication Number Publication Date
CA2267457A1 CA2267457A1 (en) 1998-04-02
CA2267457C true CA2267457C (en) 2004-05-25

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US (1) US6204766B1 (en)
EP (1) EP0928430B1 (en)
JP (1) JP3646142B2 (en)
KR (1) KR100473428B1 (en)
CN (1) CN1149406C (en)
AT (1) ATE230495T1 (en)
AU (1) AU717142B2 (en)
BR (1) BR9712147A (en)
CA (1) CA2267457C (en)
DE (1) DE69718181T2 (en)
ES (1) ES2187823T3 (en)
GB (1) GB9620190D0 (en)
RU (1) RU2183846C2 (en)
WO (1) WO1998013708A1 (en)

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EP0928430A1 (en) 1999-07-14
KR100473428B1 (en) 2005-03-07
WO1998013708A1 (en) 1998-04-02
CN1149406C (en) 2004-05-12
KR20000048703A (en) 2000-07-25
BR9712147A (en) 2001-12-04
ATE230495T1 (en) 2003-01-15
RU2183846C2 (en) 2002-06-20
JP3646142B2 (en) 2005-05-11
CN1235677A (en) 1999-11-17
EP0928430B1 (en) 2003-01-02
JP2001501005A (en) 2001-01-23
ES2187823T3 (en) 2003-06-16
DE69718181T2 (en) 2003-05-15
GB9620190D0 (en) 1996-11-13
AU717142B2 (en) 2000-03-16
CA2267457A1 (en) 1998-04-02
US6204766B1 (en) 2001-03-20
AU4562997A (en) 1998-04-17
DE69718181D1 (en) 2003-02-06

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