CA2293603C - Uv-stabilizers for siloxane systems - Google Patents
Uv-stabilizers for siloxane systems Download PDFInfo
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- CA2293603C CA2293603C CA002293603A CA2293603A CA2293603C CA 2293603 C CA2293603 C CA 2293603C CA 002293603 A CA002293603 A CA 002293603A CA 2293603 A CA2293603 A CA 2293603A CA 2293603 C CA2293603 C CA 2293603C
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Abstract
The invention relates to a non-volatile UV-stabilizing mixture for siloxane paint systems, containing hydrolizable silanes which in turn contain hydroxybenztriazols and epoxide groups. The resulting UV- stabilized paint systems are particularly suitable for use as anti-UV coatings for thermoplastics, especially aromatic polycarbonates.</SD OAB>
Description
UV stabilisers for siloxane systems The present invention relates to non-volatile UV-stabilising mixtures for siloxane lacquer systems, which mixtures have certain hydroxybenzotriazoles as the UV-stabilising active structure and which are thus particularly suitable for the UV-stabilisation of thermoplastics, in particular of aromatic polycarbonates.
Materials are frequently protected from the harmful influences of the environment by providing them with a protective surface. Siloxane-based lacquers have proved particularly suitable for this purpose, inter alia providing the materials with a scratch-resistant surface.
These lacquers may contain so-called UV-stabilising substances in order to protect the lacquer itself and the underlying material, the so-called substrate, from harmful UV radiation. Apart from providing long-term UV protection, one requirement placed upon these substances is, inter alia, that they are not volatile so that they remain homogeneously distributed within the lacquer layer and do not escape from the lacquer layer either during curing or during subsequent use of the laquer.
The UV-stabilising substances must furthermore not decompose rapidly, must be durably homogeneously miscible with the ?ac;quers and the lacquer containing the UV-stabilising substances should be transparent.
US 4 278 804 and US 4 051 161 relate to UV-stabilising active substances and lacquers containing them. The substances disclosed therein, however, exhibit the disadvantage that they provide inadequate UV protection, they decompose too rapidly and/or the siloxane system containing the stabilisers has a yellow tinge.
US 5 438 142 furthermore discloses the UV-stabilising active substance, 1-(3'-(benzotriazol-2"-yl)-4'-hydroxyphenyl)-1,1-bis(4-hydroxyphenyl)ethane. This active substance, however, exhibits the disadvantage that it is not durably miscible with siloxane-based lacquers.
Materials are frequently protected from the harmful influences of the environment by providing them with a protective surface. Siloxane-based lacquers have proved particularly suitable for this purpose, inter alia providing the materials with a scratch-resistant surface.
These lacquers may contain so-called UV-stabilising substances in order to protect the lacquer itself and the underlying material, the so-called substrate, from harmful UV radiation. Apart from providing long-term UV protection, one requirement placed upon these substances is, inter alia, that they are not volatile so that they remain homogeneously distributed within the lacquer layer and do not escape from the lacquer layer either during curing or during subsequent use of the laquer.
The UV-stabilising substances must furthermore not decompose rapidly, must be durably homogeneously miscible with the ?ac;quers and the lacquer containing the UV-stabilising substances should be transparent.
US 4 278 804 and US 4 051 161 relate to UV-stabilising active substances and lacquers containing them. The substances disclosed therein, however, exhibit the disadvantage that they provide inadequate UV protection, they decompose too rapidly and/or the siloxane system containing the stabilisers has a yellow tinge.
US 5 438 142 furthermore discloses the UV-stabilising active substance, 1-(3'-(benzotriazol-2"-yl)-4'-hydroxyphenyl)-1,1-bis(4-hydroxyphenyl)ethane. This active substance, however, exhibits the disadvantage that it is not durably miscible with siloxane-based lacquers.
The object thus arises of providing a UV-stabiliser system which does not exhibit the above-stated disadvantages.
This object is achieved according to the invention by the provision of UV-stabilising mixtures containing hydroxybenzotriazoles of the general formula (1) below and hydrolysable silanes containing epoxy groups.
'-HO
/ N R
I , N
2/ N~, R3 - OC - OR
R~: H, CI-C i g alkyl, C5-C6 cycloalkyl, C6-C I2 aryl, R2: H, halogen, preferably Cl or CI-C 12 alkyl, R': a single bond, CI -C1Z alkylene, C5-C6 cycloalkylene or phenylene, R4: H, alkali metal, ammonium, alkaline earth metal, CI -C12 alkyl, -C-alkyl, C6-C12 aryl, -C-aryl.
The present invention furthermore provides UV-stabilising mixtures having a molar ratio of epoxy groups of the silane to the hydroxybenzotriazole of the general formula (1) which is greater than 1.4, preferably greater than 2, particularly preferably greater than 8. The molar ratio of epoxy units of the silane to the hydroxybenzotriazole of the general fornula (1) should not, however, exceed 100:1.
The mixtures according to the invention are suitable for the UV-stabilisation of siloxane systems, in particular of scratch- and abrasion-resistant siloxane coating The mixtures according to the invention are suitable for the UV-stabilisation of siloxane systems, in particular of scratch- and abrasion-resistant siloxane coating materials. Such UV-stabilised coating materials, preferably lacquers, may be used for coating materials of all kinds, such as for example wood, textiles, paper, stone articles, but preferably for coating plastics, metals, glass and ceramics, particularly preferably for coating thermoplastics and very particularly preferably for coating polycarbonates.
The hydroxybenzotriazoles used for the non-volatile, UV-stabilising mixtures according to the invention are compounds of the general formula (1).
Preferred compounds of the formula (1) are:
HO
N
CH2CH,-CO2H
t-!O HO
' N / ~ ' Ct : N/ -CH,CH,-CO,H CH2CH_ -COZH
HO H H
HO
N
O:N \N[:DZN 25 / / N
CH2CH2CO2H CH~CH,CH,CO~H
HO HO CH.,CH,CH,CO.,H
~
' / - \ N/ -CoZH CH3 - ------- --The compounds of the formula (1) are either known from the literature or obtainable using processes known from the literature, for example in accordance with the reaction scheme disclosed on page 7 of EP-0 057 160.
Silanes containing epoxy groups are generally taken to mean compounds which, on the one hand, possess at least one epoxy ring and simultaneously have groups which form silanol structures under hydrolysing conditions.
Epoxysilanes as are preferably used according to the invention are described, for example in US 2 946 701. They are compounds of the formulae (2) or (3):
O
H2C CH(R5)m Si(OR6)3 2 O
D CH2 CH2- Si(ORs)3 (3) R5 is a divalent hydrocarbon residue having at most 9 carbon atoms or a divalent residue having at most 9 carbon atoms consisting of C, H and 0 atoms, wherein the 0 atom is present as an ether bond residue.
R5 is preferably -CH2OCH2CH2CH2-.
R6 is an aliphatic hydrocarbon residue having at most 4 carbon atoms, an acyl residue having at most 4 carbon atoms or a residue of the formula (CH2CH2O)nZ, in which n is at least 1 and Z means on aliphatic hydrocarbon residue having at most 4 carbon atoms;
m is0orl.
This object is achieved according to the invention by the provision of UV-stabilising mixtures containing hydroxybenzotriazoles of the general formula (1) below and hydrolysable silanes containing epoxy groups.
'-HO
/ N R
I , N
2/ N~, R3 - OC - OR
R~: H, CI-C i g alkyl, C5-C6 cycloalkyl, C6-C I2 aryl, R2: H, halogen, preferably Cl or CI-C 12 alkyl, R': a single bond, CI -C1Z alkylene, C5-C6 cycloalkylene or phenylene, R4: H, alkali metal, ammonium, alkaline earth metal, CI -C12 alkyl, -C-alkyl, C6-C12 aryl, -C-aryl.
The present invention furthermore provides UV-stabilising mixtures having a molar ratio of epoxy groups of the silane to the hydroxybenzotriazole of the general formula (1) which is greater than 1.4, preferably greater than 2, particularly preferably greater than 8. The molar ratio of epoxy units of the silane to the hydroxybenzotriazole of the general fornula (1) should not, however, exceed 100:1.
The mixtures according to the invention are suitable for the UV-stabilisation of siloxane systems, in particular of scratch- and abrasion-resistant siloxane coating The mixtures according to the invention are suitable for the UV-stabilisation of siloxane systems, in particular of scratch- and abrasion-resistant siloxane coating materials. Such UV-stabilised coating materials, preferably lacquers, may be used for coating materials of all kinds, such as for example wood, textiles, paper, stone articles, but preferably for coating plastics, metals, glass and ceramics, particularly preferably for coating thermoplastics and very particularly preferably for coating polycarbonates.
The hydroxybenzotriazoles used for the non-volatile, UV-stabilising mixtures according to the invention are compounds of the general formula (1).
Preferred compounds of the formula (1) are:
HO
N
CH2CH,-CO2H
t-!O HO
' N / ~ ' Ct : N/ -CH,CH,-CO,H CH2CH_ -COZH
HO H H
HO
N
O:N \N[:DZN 25 / / N
CH2CH2CO2H CH~CH,CH,CO~H
HO HO CH.,CH,CH,CO.,H
~
' / - \ N/ -CoZH CH3 - ------- --The compounds of the formula (1) are either known from the literature or obtainable using processes known from the literature, for example in accordance with the reaction scheme disclosed on page 7 of EP-0 057 160.
Silanes containing epoxy groups are generally taken to mean compounds which, on the one hand, possess at least one epoxy ring and simultaneously have groups which form silanol structures under hydrolysing conditions.
Epoxysilanes as are preferably used according to the invention are described, for example in US 2 946 701. They are compounds of the formulae (2) or (3):
O
H2C CH(R5)m Si(OR6)3 2 O
D CH2 CH2- Si(ORs)3 (3) R5 is a divalent hydrocarbon residue having at most 9 carbon atoms or a divalent residue having at most 9 carbon atoms consisting of C, H and 0 atoms, wherein the 0 atom is present as an ether bond residue.
R5 is preferably -CH2OCH2CH2CH2-.
R6 is an aliphatic hydrocarbon residue having at most 4 carbon atoms, an acyl residue having at most 4 carbon atoms or a residue of the formula (CH2CH2O)nZ, in which n is at least 1 and Z means on aliphatic hydrocarbon residue having at most 4 carbon atoms;
m is0orl.
Production of these epoxysilanes is also described in US 2 946 701.
Particularly preferred epoxysilanes are those compounds in which R6 is methyl. They are commercially available, inter alia from the companies Union Carbide and Huls AG
as:
A- 187* or Dynasilan Glymo* 3-glycidyloxypropyltrimethoxysilane A-186* 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane.
Production of the UV-stabilising mixtures The UV-stabilising components are produced by homogeneously mixing compounds of the general formula (1) with the hydrolysable silanes containing epoxy groups and heating this mixture. Heating should be performed for at least 30 minutes at at least 90 C. The temperature should preferably be above 120 C during heating. It has proved particularly favourable to use a mixing ratio at which stoichiometrically more epoxy groups are present than the -R3-CO-OR4_ groups of the hydroxybenzotriazole of the general formula 1. The molar ratio of epoxy units of the saline to the hydroxy-benzotriazole of the general formula (1) should thus be greater than 1.4, preferably greater than 2, particularly preferably greater than 8.
The UV-stabilising components need not necessarily be produced separately so that they may subsequently be added to the siloxane system to be stabilised, but may also be synthesised in situ as a sub-stage during synthesis of the siloxane systems/siloxane coating materials.
Siloxane systems/siloxane coating materials The siloxane systems are substantially thermally curing systems which preferably crosslink by a condensation reaction to yield -Si-O-Si- linkages. Other crosslinking mechanisims may proceed in parallel. Such systems are described, for example, in *trade-mark US 3 790 527, 3 865 755, 3 887 514, 4 243 720, 4 278 804, 4 680 232, 4 006 271, 4 476 281, in DE-A 4 011 045, 4 122 743, 4 020 316, 3 917 535, 3 706 714, 3 407 087, 3 836 815, 2 914 427, 3 135 241, 3 134 777, 3 100 532, 3 151 350, in DE-A 3 005 541, 3 014 411, 2 834 606, 2 947 879, 3 016 021, 2 914 427 and 4 338 361.
The present invention accordingly also provides siloxane systems UV-stabilised according to the invention.
Preferably used siloxane systems are those containing particulate material selected from among oxides, oxide hydrates, nitrides and carbides of Si, Al, Sb, Ce and B and of transition metals, preferably Ti, Fe and Zr, and having a particle size in the range from 1 to 100 nm, preferably from 2 to 50 nm.
The UV-stabilising mixture according to the invention should be added to the siloxane system in such a quantity, relative to the solids content of the siloxane system, that the proportion of hydroxybenzotriazole, relative to the solids content of the siloxane system, is 0.3 to 20, preferably 3 to 15, particularly preferably 5 to 10 wt.%.
Reference is made to DE-A 2 914 427 and DE-A 4 338 361 with regard to the production of siloxane-based scratch-resistant coating systems and components thereof.
Substrates, materials The siloxane systems provided with the UV-stabilising mixture according to the invention may be used as bulk materials and as coating materials. There are no restrictions as to the substrate materials which may be selected for coating.
These UV-stabilised coating materials are preferably suitable for coating wood, textiles, paper, stone articles, metals, glass, ceramics and plastics and in particular for coating thermoplastics, as are for example described in Becker/Braun Kunststoffhandbuch, Carl Hanser Verlag, Munich, Vienna, 1972. They are very particularly suitable for coating transparent thermoplastics, preferably polycarbonates.
Conventional coating processes are used for coating purposes, for example dipping, flooding, pouring, spinning, spraying or brushing.
The coating is applied to film thicknesses of, for example, 2 to 200 m, preferably of 2 to 30 m and particularly preferably of 5 to 15 m. The substrate may optionally be primed with a coupling agent or primer coat before application of the coating.
The lacquers are preferably cured at temperatures of >90 C.
For the purposes of the present invention, thermoplastic, aromatic polycarbonates include both homopolycarbonates and copolycarbonates; the polycarbonates may, in a known manner, be linear or branched.
A proportion, up to 80 mol %, preferably of 20 mol % to 50 mol %, of the carbonate groups in the suitable polycarbonates may be replaced by aromatic dicarboxylic acid ester groups. Such polycarbonates, which contain both acid residues of carbonic acid and acid residues of aromatic dicarboxylic acids incorporated in the molecular chain, are more accurately termed aromatic polyester carbonates. They are to be subsumed within the superordinate term of thermoplastic, aromatic polycarbonates.
Details of the production of polycarbonates have been described in hundreds of patents over the past approx. 40 years. Reference is made, merely by way of example, to "Schnell, Chemistry & Physics of Polycarbonates", Polymer Reviews, volume 9, Interscience Publishers, New York, London, Sydney 1964, to D.C.
Prevorsek, B.T. Debona & Y. Kesten, Corporate Research Center, Allied Chemical Corporation, Morristown, New Jersey 07960, "Synthesis of poly(ester carbonate) copolymers" in Journal of Polymer Science, Polymer Chemistry edition, volume 19, - ----- ------ - ----75-90 (1980), to D. Freitag, U. Grigo, P.R. Miiller, N. Nouvertne', Bayer AG, "Polycarbonates" in Encyclopedia of Polymer Science & Engineering, volume 11, second edition, 1988, pages 648-718 and finally to Dr. U. Grigo, Dr. K.
Kircher &
Dr. P.R. Miiller "Polycarbonate" in Becker/Braun, Kunststoff-Handbuch, volume 3/1, Polycarbonate, Polyacetale, Polyester, Celluloseester, Carl Hanser Verlag, Munich, Vienna, 1992, pages 117-299.
The thermoplastic polycarbonates have average molecular weights M,õ
(determined by measuring relative viscosity at 25 C in CH2C12 at a concentration of 0.5 g per 100 ml of CHZC12) of 12000 to 400000, preferably of 18000 to 80000 and in particular of 22000 to 60000.
The present invention accordingly also provides coated materials, preferably polycarbonate and particularly preferably polycarbonate provided with a scratch-resistant coating.
Particularly preferred epoxysilanes are those compounds in which R6 is methyl. They are commercially available, inter alia from the companies Union Carbide and Huls AG
as:
A- 187* or Dynasilan Glymo* 3-glycidyloxypropyltrimethoxysilane A-186* 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane.
Production of the UV-stabilising mixtures The UV-stabilising components are produced by homogeneously mixing compounds of the general formula (1) with the hydrolysable silanes containing epoxy groups and heating this mixture. Heating should be performed for at least 30 minutes at at least 90 C. The temperature should preferably be above 120 C during heating. It has proved particularly favourable to use a mixing ratio at which stoichiometrically more epoxy groups are present than the -R3-CO-OR4_ groups of the hydroxybenzotriazole of the general formula 1. The molar ratio of epoxy units of the saline to the hydroxy-benzotriazole of the general formula (1) should thus be greater than 1.4, preferably greater than 2, particularly preferably greater than 8.
The UV-stabilising components need not necessarily be produced separately so that they may subsequently be added to the siloxane system to be stabilised, but may also be synthesised in situ as a sub-stage during synthesis of the siloxane systems/siloxane coating materials.
Siloxane systems/siloxane coating materials The siloxane systems are substantially thermally curing systems which preferably crosslink by a condensation reaction to yield -Si-O-Si- linkages. Other crosslinking mechanisims may proceed in parallel. Such systems are described, for example, in *trade-mark US 3 790 527, 3 865 755, 3 887 514, 4 243 720, 4 278 804, 4 680 232, 4 006 271, 4 476 281, in DE-A 4 011 045, 4 122 743, 4 020 316, 3 917 535, 3 706 714, 3 407 087, 3 836 815, 2 914 427, 3 135 241, 3 134 777, 3 100 532, 3 151 350, in DE-A 3 005 541, 3 014 411, 2 834 606, 2 947 879, 3 016 021, 2 914 427 and 4 338 361.
The present invention accordingly also provides siloxane systems UV-stabilised according to the invention.
Preferably used siloxane systems are those containing particulate material selected from among oxides, oxide hydrates, nitrides and carbides of Si, Al, Sb, Ce and B and of transition metals, preferably Ti, Fe and Zr, and having a particle size in the range from 1 to 100 nm, preferably from 2 to 50 nm.
The UV-stabilising mixture according to the invention should be added to the siloxane system in such a quantity, relative to the solids content of the siloxane system, that the proportion of hydroxybenzotriazole, relative to the solids content of the siloxane system, is 0.3 to 20, preferably 3 to 15, particularly preferably 5 to 10 wt.%.
Reference is made to DE-A 2 914 427 and DE-A 4 338 361 with regard to the production of siloxane-based scratch-resistant coating systems and components thereof.
Substrates, materials The siloxane systems provided with the UV-stabilising mixture according to the invention may be used as bulk materials and as coating materials. There are no restrictions as to the substrate materials which may be selected for coating.
These UV-stabilised coating materials are preferably suitable for coating wood, textiles, paper, stone articles, metals, glass, ceramics and plastics and in particular for coating thermoplastics, as are for example described in Becker/Braun Kunststoffhandbuch, Carl Hanser Verlag, Munich, Vienna, 1972. They are very particularly suitable for coating transparent thermoplastics, preferably polycarbonates.
Conventional coating processes are used for coating purposes, for example dipping, flooding, pouring, spinning, spraying or brushing.
The coating is applied to film thicknesses of, for example, 2 to 200 m, preferably of 2 to 30 m and particularly preferably of 5 to 15 m. The substrate may optionally be primed with a coupling agent or primer coat before application of the coating.
The lacquers are preferably cured at temperatures of >90 C.
For the purposes of the present invention, thermoplastic, aromatic polycarbonates include both homopolycarbonates and copolycarbonates; the polycarbonates may, in a known manner, be linear or branched.
A proportion, up to 80 mol %, preferably of 20 mol % to 50 mol %, of the carbonate groups in the suitable polycarbonates may be replaced by aromatic dicarboxylic acid ester groups. Such polycarbonates, which contain both acid residues of carbonic acid and acid residues of aromatic dicarboxylic acids incorporated in the molecular chain, are more accurately termed aromatic polyester carbonates. They are to be subsumed within the superordinate term of thermoplastic, aromatic polycarbonates.
Details of the production of polycarbonates have been described in hundreds of patents over the past approx. 40 years. Reference is made, merely by way of example, to "Schnell, Chemistry & Physics of Polycarbonates", Polymer Reviews, volume 9, Interscience Publishers, New York, London, Sydney 1964, to D.C.
Prevorsek, B.T. Debona & Y. Kesten, Corporate Research Center, Allied Chemical Corporation, Morristown, New Jersey 07960, "Synthesis of poly(ester carbonate) copolymers" in Journal of Polymer Science, Polymer Chemistry edition, volume 19, - ----- ------ - ----75-90 (1980), to D. Freitag, U. Grigo, P.R. Miiller, N. Nouvertne', Bayer AG, "Polycarbonates" in Encyclopedia of Polymer Science & Engineering, volume 11, second edition, 1988, pages 648-718 and finally to Dr. U. Grigo, Dr. K.
Kircher &
Dr. P.R. Miiller "Polycarbonate" in Becker/Braun, Kunststoff-Handbuch, volume 3/1, Polycarbonate, Polyacetale, Polyester, Celluloseester, Carl Hanser Verlag, Munich, Vienna, 1992, pages 117-299.
The thermoplastic polycarbonates have average molecular weights M,õ
(determined by measuring relative viscosity at 25 C in CH2C12 at a concentration of 0.5 g per 100 ml of CHZC12) of 12000 to 400000, preferably of 18000 to 80000 and in particular of 22000 to 60000.
The present invention accordingly also provides coated materials, preferably polycarbonate and particularly preferably polycarbonate provided with a scratch-resistant coating.
Examples Example I=
a) UV-absorbing starting materials al) 2-(2-hydroxy-3-tert.-butyl-5-(2-carboxyethyl)phenyl)benzotriazole, m.p. 195 C (produced as in EP 0 057 160, Example 1) a2) 2-(2-hydroxy-3-cyclohexyl-5(3-carboxypropyl)phenyl)benzotriazole a) 132 g (0.75 mol) of 2-cyclohexylphenol are dissolved in 800 ml of dry chlorobenzene. 200 g (1.5 mol) of A1C13 are then added at 5 to 10 C followed at 0 to 10 C by a solution of 73.5 g (0.75 mol) of maleic anhydride in 400 ml of chlorobenzene. After 12 hours at room temperature, the mixture is poured into iced water and acidified with concentrated HCI. 85 g of a powder having an m.p. of 187 to 190 C
are obtained.
B) 34.5 g (0.25 mol) of o-nitroaniline are stirred in 300 ml of water and 69 ml of concentrated HC1. A solution of 17.3 g (0.25 mol) of sodium nitrite in 155 ml of water is then added dropwise at 5 C. This solution is then added dropwise at 5 C to a solution of 68.5 g (0.25 mol) of compound a and 79.5 g (0.75 mol) of sodium carbonate in 1 litre of water. 117 g of a solid having an m.p. of 155 C are obtained.
y) 42.5 g (0.1 mol) of the azo dye B are combined with 200 ml of 2 n NaOH. 50 g of zinc powder are then added and 80 ml of 10 n NaOH
are run in within 1 hour such that the temperature remains below 45 C. The mixture is then heated to 90 C for 4 hours, filtered and the filtrate acidified with HC1.
After recrystallisation from cyclohexane, 31 g of 2-(2-hydroxy-3-cyclohexyl-5-(3-carboxypropyl)phenyl)benzotriazole are obtained as colourless crystals of an m.p. of 165 C.
b) UV-stabilising component prepared from al and 3-glvcidyloxxpropyltri-methoxxsilane (Gl tno) 50 g of al and 450 g of 3-glycidyloxypropyltrimethoxysilane are introduced into a vessel and heated to 140 to 150 C under a nitrogen atmosphere while being stirred and are maintained at this temperature for one hour.
This mixture (mixture 1) was varied as follows:
Mixture:
2 100 g al 400 g Glymo 3 150g " 350g "
4 200 g " 300 g "
5 100 g " 400 g a-(3,4-epoxycyclohexyl)ethyltrimeth-oxysilane c) Production of the siloxane coating material according to DE-A 2 914 427 (coating sol 1) a) 19.8 g of glacial acetic acid, 210 g of distilled water and 227 g of isopropanol are added to 300 g of colloidal silicic acid having an Si02 content of 30 wt.%. After thorough mixing, 900 g of methyltriethoxy-silane are added and the mixture heated to 60 C while being stirred.
The mixture is left at this temperature for 4 hours and then a further 1200 g of isopropanol are added to the mixture. Once the product has cooled to room temperature, the slightly opaque solution is filtered.
-------- - - - -- - _~.~----_ B) 340 g of isopropanol, 190 g of tetraethoxysilane and 360 g of methyltriethoxysilane are introduced into a vessel fitted with a stirrer and reflux condenser. This mixture is combined with 180 g of 0.05 n hydrochloric acid and co-hydrolysed by refluxing for five hours. The mixture is cooled to room temperature after the reaction. A solution is obtained which is a partial hydrolysate of tetraethoxysilane (5.1%, calculated as Si02) and a partial hydrolysate of methyltriethoxysilane (12.6%, calculated as CH3SiO1.5).
Before use as a coating material, the two components a) and B) are mixed together in a 1:1 ratio and dissolved in a mixture prepared from 60 parts by weight of n-butanol, 40 parts by weight of acetic acid and 20 parts by weight of toluene.
d) Production of a siloxane coating material according to DE-A 4 338 361 (coating sol H) A boehmite sol was produced by combining 12.82 g of acetic acid-stabilised (6.4 wt.% acetic acid) boehmite powder with 104.62 g of 0.1 n HCI.
Subsequent ultrasonication (20 minutes) produced a transparent, colourless solution, 24.3 g of which were combined with a mixture prepared from 118.17 g of GPTS (3-glycidyloxypropyltrimethoxysilane) and 62.50 g of TEOS (tetraethyl orthosilicate). The reaction mixture was stirred for 2 hours at room temperature and then, while being cooled with ice, combined with 18.93 g of aluminium tributoxyethanolate. The resultant clear sol was stirred for 2 hours at room temperature and then, while being cooled with ice, combined with 93.14 g of the above boehmite sol and 79.30 g of butoxyethanol.
a) UV-absorbing starting materials al) 2-(2-hydroxy-3-tert.-butyl-5-(2-carboxyethyl)phenyl)benzotriazole, m.p. 195 C (produced as in EP 0 057 160, Example 1) a2) 2-(2-hydroxy-3-cyclohexyl-5(3-carboxypropyl)phenyl)benzotriazole a) 132 g (0.75 mol) of 2-cyclohexylphenol are dissolved in 800 ml of dry chlorobenzene. 200 g (1.5 mol) of A1C13 are then added at 5 to 10 C followed at 0 to 10 C by a solution of 73.5 g (0.75 mol) of maleic anhydride in 400 ml of chlorobenzene. After 12 hours at room temperature, the mixture is poured into iced water and acidified with concentrated HCI. 85 g of a powder having an m.p. of 187 to 190 C
are obtained.
B) 34.5 g (0.25 mol) of o-nitroaniline are stirred in 300 ml of water and 69 ml of concentrated HC1. A solution of 17.3 g (0.25 mol) of sodium nitrite in 155 ml of water is then added dropwise at 5 C. This solution is then added dropwise at 5 C to a solution of 68.5 g (0.25 mol) of compound a and 79.5 g (0.75 mol) of sodium carbonate in 1 litre of water. 117 g of a solid having an m.p. of 155 C are obtained.
y) 42.5 g (0.1 mol) of the azo dye B are combined with 200 ml of 2 n NaOH. 50 g of zinc powder are then added and 80 ml of 10 n NaOH
are run in within 1 hour such that the temperature remains below 45 C. The mixture is then heated to 90 C for 4 hours, filtered and the filtrate acidified with HC1.
After recrystallisation from cyclohexane, 31 g of 2-(2-hydroxy-3-cyclohexyl-5-(3-carboxypropyl)phenyl)benzotriazole are obtained as colourless crystals of an m.p. of 165 C.
b) UV-stabilising component prepared from al and 3-glvcidyloxxpropyltri-methoxxsilane (Gl tno) 50 g of al and 450 g of 3-glycidyloxypropyltrimethoxysilane are introduced into a vessel and heated to 140 to 150 C under a nitrogen atmosphere while being stirred and are maintained at this temperature for one hour.
This mixture (mixture 1) was varied as follows:
Mixture:
2 100 g al 400 g Glymo 3 150g " 350g "
4 200 g " 300 g "
5 100 g " 400 g a-(3,4-epoxycyclohexyl)ethyltrimeth-oxysilane c) Production of the siloxane coating material according to DE-A 2 914 427 (coating sol 1) a) 19.8 g of glacial acetic acid, 210 g of distilled water and 227 g of isopropanol are added to 300 g of colloidal silicic acid having an Si02 content of 30 wt.%. After thorough mixing, 900 g of methyltriethoxy-silane are added and the mixture heated to 60 C while being stirred.
The mixture is left at this temperature for 4 hours and then a further 1200 g of isopropanol are added to the mixture. Once the product has cooled to room temperature, the slightly opaque solution is filtered.
-------- - - - -- - _~.~----_ B) 340 g of isopropanol, 190 g of tetraethoxysilane and 360 g of methyltriethoxysilane are introduced into a vessel fitted with a stirrer and reflux condenser. This mixture is combined with 180 g of 0.05 n hydrochloric acid and co-hydrolysed by refluxing for five hours. The mixture is cooled to room temperature after the reaction. A solution is obtained which is a partial hydrolysate of tetraethoxysilane (5.1%, calculated as Si02) and a partial hydrolysate of methyltriethoxysilane (12.6%, calculated as CH3SiO1.5).
Before use as a coating material, the two components a) and B) are mixed together in a 1:1 ratio and dissolved in a mixture prepared from 60 parts by weight of n-butanol, 40 parts by weight of acetic acid and 20 parts by weight of toluene.
d) Production of a siloxane coating material according to DE-A 4 338 361 (coating sol H) A boehmite sol was produced by combining 12.82 g of acetic acid-stabilised (6.4 wt.% acetic acid) boehmite powder with 104.62 g of 0.1 n HCI.
Subsequent ultrasonication (20 minutes) produced a transparent, colourless solution, 24.3 g of which were combined with a mixture prepared from 118.17 g of GPTS (3-glycidyloxypropyltrimethoxysilane) and 62.50 g of TEOS (tetraethyl orthosilicate). The reaction mixture was stirred for 2 hours at room temperature and then, while being cooled with ice, combined with 18.93 g of aluminium tributoxyethanolate. The resultant clear sol was stirred for 2 hours at room temperature and then, while being cooled with ice, combined with 93.14 g of the above boehmite sol and 79.30 g of butoxyethanol.
e) UV-stabilised coating sols I and H
A 60 g portion of the UV-stabilising mixture 2 according to the invention was added to a 1000 g portion of each of coating sols I and H. Silica glass was coated with these compositions and UV light transmission measured with a Beckmann DU 70 photometer in the wavelength range from 250 to 600 nm. The coating film was 5 m thick and absorbed >98% of the radiation of a wavelength of <350 nm critical for polycarbonate.
Coating of substrates and testing of coatingproperties Bisphenol A polycarbonate sheets (Tg = 147 C, MW 27500) of dimensions 105 x 150 x 4 mm were cleaned with isopropanol and primed by dipping in a mixture prepared from 3 wt.% of aminopropyltrimethoxysilane and 97 wt.% of ethylene glycol monobutyl ether followed by 30 minutes' heat treatment at 130 C.
The sheets were then provided with a 20 m film of one of coating sols I or II
at a dipping speed V = 100 cm/min. After flashing off for 10 minutes at room temperature, the coated sheets were dried for 1 hour at 130 C. The film thickness of the scratch-resistant lacquers was approx. 5 m after drying. Once curing was complete, the coated sheets were stored for 2 days at room temperature and then exposed to a defined quantity of UV radiation.
UV exposure testing The polycarbonate sheets were exposed to filtered xenon arc radiation with a water spray cycle to DIN 53387-1-A-X under the following test conditions:
Weathering apparatus: Xenon-WOM
Radiation intensity at 340 nm: 0.35 W/m2 (preferably) Filter combination: inner: Pyrex, outer: Pyrex Blackboard temperature: 60 C 5 C
Black standard temperature: 650C 3 C
A 60 g portion of the UV-stabilising mixture 2 according to the invention was added to a 1000 g portion of each of coating sols I and H. Silica glass was coated with these compositions and UV light transmission measured with a Beckmann DU 70 photometer in the wavelength range from 250 to 600 nm. The coating film was 5 m thick and absorbed >98% of the radiation of a wavelength of <350 nm critical for polycarbonate.
Coating of substrates and testing of coatingproperties Bisphenol A polycarbonate sheets (Tg = 147 C, MW 27500) of dimensions 105 x 150 x 4 mm were cleaned with isopropanol and primed by dipping in a mixture prepared from 3 wt.% of aminopropyltrimethoxysilane and 97 wt.% of ethylene glycol monobutyl ether followed by 30 minutes' heat treatment at 130 C.
The sheets were then provided with a 20 m film of one of coating sols I or II
at a dipping speed V = 100 cm/min. After flashing off for 10 minutes at room temperature, the coated sheets were dried for 1 hour at 130 C. The film thickness of the scratch-resistant lacquers was approx. 5 m after drying. Once curing was complete, the coated sheets were stored for 2 days at room temperature and then exposed to a defined quantity of UV radiation.
UV exposure testing The polycarbonate sheets were exposed to filtered xenon arc radiation with a water spray cycle to DIN 53387-1-A-X under the following test conditions:
Weathering apparatus: Xenon-WOM
Radiation intensity at 340 nm: 0.35 W/m2 (preferably) Filter combination: inner: Pyrex, outer: Pyrex Blackboard temperature: 60 C 5 C
Black standard temperature: 650C 3 C
Mode of operation: constant Water spray cycle: 102:18 Relative atmospheric humidity: 60-80%
Yellowing as a function of exposure time was used as the evaluation criterion for the weathering resistance of the lacquer-coated sheets. The corresponding yellowness of the sheets was determined as the Yellowness Index (Y.I.) to ASTM D 1925-70.
Y.I. values after Xenon-WOM 102:18 weatherinQ
Specimens 0 h 1000 h 2000 h 3000 h 5000 h Polycarbonate with UV-stabilised coating sol I 2.1 2.2 2.7 2.8 4.3 according to mixture 2 Polycarbonate with UV-stabilised coating sol II 2.5 2.7 3.2 3.3 4.8 according to mixture 2 Comparison Polycarbonate with coating sol I without LN 1.8 2.2 6.48' 7.681 ) stabilisation Polycarbonate with coating sol H without UV 1.9 2.6 6.3') 7 9') b) stabilisation a) Cracks, delamination of lacquer film.
b) No lacquer film remains.
Yellowing as a function of exposure time was used as the evaluation criterion for the weathering resistance of the lacquer-coated sheets. The corresponding yellowness of the sheets was determined as the Yellowness Index (Y.I.) to ASTM D 1925-70.
Y.I. values after Xenon-WOM 102:18 weatherinQ
Specimens 0 h 1000 h 2000 h 3000 h 5000 h Polycarbonate with UV-stabilised coating sol I 2.1 2.2 2.7 2.8 4.3 according to mixture 2 Polycarbonate with UV-stabilised coating sol II 2.5 2.7 3.2 3.3 4.8 according to mixture 2 Comparison Polycarbonate with coating sol I without LN 1.8 2.2 6.48' 7.681 ) stabilisation Polycarbonate with coating sol H without UV 1.9 2.6 6.3') 7 9') b) stabilisation a) Cracks, delamination of lacquer film.
b) No lacquer film remains.
Claims (14)
1. A process for producing UV-stabilizer comprising mixing and heating (A) a hydroxybenzotriazole conforming to where R1 denotes a member selected from the group consisting of H, C1-18-alkyl, C5-6-cycloalkyl and C+6-12-aryl, R2 denotes a member selected from the group consisting of H, halogen and C1-12-alkyl, R3 denotes a member selected from the group consisting of a single bond, C1-12-alkylene, C5-6-cycloalkylene and phenylene R4 is a member selected from the group consisting of H, alkali metal, ammonium, alkaline earth metal, C1-12-alkyl, -CO-alkyl, C6-12-aryl, and -CO-aryl, and (B) at least one hydrolyzable silane containing at least one epoxy group, to at least 90°C for at least 30 minutes to form a reaction product.
2. The process of Claim 1 wherein the molar ratio between the at least one epoxy group and the hydroxybenzotriazole is greater than 1.4.
3. The process of Claim 1 wherein said A) is at least one member selected from the group consisting of
4. An UV stabilizer comprising the reaction product of Claim 1.
5. A coating composition comprising a siloxane system and the UV stabilizer of Claim 4.
6. The coating composition of Claim 5 wherein siloxane system contains solids in the form of particulate material having a particle size in the range of 1 to 100 nm selected from the group consisting of oxides, oxide hydrates, nitrides and carbides of Si, Al, Sb, Ce and B and of transition metals.
7. The coating composition of Claim 6 wherein weight ratio of hydroxybenzotriazole to said solids is 0.3 to 20.
8. The coating composition of Claim 6 wherein transition metal is a member selected from the group consisting of Ti, Fe and Zr.
9. A method of producing a coated substrate comprising coating at least part of the substrate with a coating comprising the UV-stabilizer of Claim 4.
10. The method of Claim 9 wherein substrate is thermoplastic.
11. The method of Claim 10 wherein thermoplastic is polycarbonate.
12. A substrate coated according to the method of Claim 9.
13. A process for producing UV-stabilizer comprising mixing and heating (A) a hydroxybenzotriazole conforming to where R1 denotes a member selected from the group consisting of H, C1-18-alkyl, C5-6-cycloalkyl and C6-12-aryl, R2 denotes a member selected from the group consisting of H, halogen and C1-12-alkyl, R3 denotes a member selected from the group consisting of a single bond, C1-12-alkylene, C5-6-cycloalkylene and phenylene R4 is a member selected from the group consisting of H, alkali metal, ammonium, alkaline earth metal, C1-12-alkyl, -CO-alkyl, -CO-alkyl, C6-12-aryl, and -CO-aryl, and (B) at least one hydrolyzable silane conforming to formula (2) or (3) where R5 is a divalent hydrocarbon residue having at most 9 carbon atoms or a divalent residue having at most 9 carbon atoms consisting of C, H and O atoms, wherein the O atom is present as an ether bond residue and R6 is an aliphatic hydrocarbon residue having at most 4 carbon atoms, an acyl residue having at most 4 carbon atoms or a residue of the formula (CH2CH2O)n Z, in which n is at least 1 and Z means an aliphatic hydrocarbon residue having at most 4 carbon atoms;
m is 0 or 1, to at least 90°C for at least 30 minutes to form a reaction product.
m is 0 or 1, to at least 90°C for at least 30 minutes to form a reaction product.
14. The product prepared by the process of Claim 13.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19724397A DE19724397A1 (en) | 1997-06-10 | 1997-06-10 | UV stabilizers for siloxane systems |
| DE19724397.5 | 1997-06-10 | ||
| PCT/EP1998/003157 WO1998056853A1 (en) | 1997-06-10 | 1998-05-28 | Uv-stabilizers for siloxane systems |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2293603A1 CA2293603A1 (en) | 1998-12-17 |
| CA2293603C true CA2293603C (en) | 2007-07-31 |
Family
ID=7832017
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002293603A Expired - Fee Related CA2293603C (en) | 1997-06-10 | 1998-05-28 | Uv-stabilizers for siloxane systems |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6306512B1 (en) |
| EP (1) | EP0988340B1 (en) |
| JP (1) | JP4228124B2 (en) |
| KR (1) | KR100541298B1 (en) |
| CN (1) | CN1124309C (en) |
| AU (1) | AU7916398A (en) |
| BR (1) | BR9810434A (en) |
| CA (1) | CA2293603C (en) |
| DE (2) | DE19724397A1 (en) |
| DK (1) | DK0988340T3 (en) |
| ES (1) | ES2167903T3 (en) |
| ID (1) | ID23428A (en) |
| IL (1) | IL132795A0 (en) |
| TW (1) | TW459011B (en) |
| WO (1) | WO1998056853A1 (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19858998A1 (en) * | 1998-12-21 | 2000-06-29 | Bayer Ag | Coating compositions containing cerium dioxide |
| JP2001079491A (en) * | 1999-09-10 | 2001-03-27 | Koito Mfg Co Ltd | Method for forming coating film and lamp for vehicle formed by the method |
| US6620509B1 (en) | 2002-04-22 | 2003-09-16 | Mitsubishi Gas Chemical Company, Inc. | Transparent resin laminate and molded article used the same |
| US7056916B2 (en) | 2002-11-15 | 2006-06-06 | Boehringer Ingelheim Pharma Gmbh & Co. Kg | Medicaments for the treatment of chronic obstructive pulmonary disease |
| US7220742B2 (en) | 2004-05-14 | 2007-05-22 | Boehringer Ingelheim International Gmbh | Enantiomerically pure beta agonists, process for the manufacture thereof and use thereof as medicaments |
| US7642303B2 (en) * | 2004-10-15 | 2010-01-05 | Shakely Thomas L | Thermoplastic articles for packaging UV sensitive materials, processes for the articles production and use and novel UV absorbers |
| ES2712912T3 (en) | 2004-10-25 | 2019-05-16 | Igm Group B V | Functionalized nanoparticles |
| DE102006000040B4 (en) * | 2005-02-01 | 2008-04-03 | Kabushiki Kaisha Toyota Jidoshokki, Kariya | Coated element |
| JP4730886B2 (en) * | 2005-06-01 | 2011-07-20 | 信越化学工業株式会社 | UV-absorbing group-containing organopolysiloxane, method for producing the polysiloxane, and treatment agent comprising the polysiloxane |
| US8089795B2 (en) * | 2006-02-09 | 2012-01-03 | Google Inc. | Memory module with memory stack and interface with enhanced capabilities |
| CA2619402C (en) * | 2005-08-15 | 2015-02-03 | Boehringer Ingelheim International Gmbh | Method for producing betamimetics |
| EP1988138A4 (en) * | 2006-02-24 | 2010-04-21 | Idemitsu Kosan Co | Coating composition, hardened film and resin laminate |
| KR20090043591A (en) | 2006-08-24 | 2009-05-06 | 시바 홀딩 인크 | Uv-dosis indicators |
| WO2009010405A1 (en) | 2007-07-18 | 2009-01-22 | Basf Se | Laser-sensitive coating formulation |
| WO2010046285A2 (en) | 2008-10-23 | 2010-04-29 | Basf Se | Heat absorbing additives |
| WO2010049282A1 (en) | 2008-10-27 | 2010-05-06 | Basf Se | Coating composition for marking substrates |
| WO2011005631A2 (en) | 2009-07-07 | 2011-01-13 | Basf Se | Potassium cesium tungsten bronze particles |
| MX361886B (en) | 2012-05-08 | 2018-12-18 | Nicox Ophthalmics Inc | Preparations of hydrophobic therapeutic agents, methods of manufacture and use thereof. |
| CN104562660B (en) * | 2013-10-11 | 2018-06-15 | 中国石油化工股份有限公司 | Polyester fiber based on Benzotriazole Ultraviolet Stabilizer and preparation method thereof |
| CN104562302B (en) * | 2013-10-11 | 2018-05-29 | 中国石油化工股份有限公司 | A kind of anti-ultraviolet ageing polyester fiber and preparation method thereof |
| US10119039B2 (en) | 2013-10-29 | 2018-11-06 | Basf Se | Use of 2-(2-hydroxyphenyl)benzotriazole compounds as an UV absorbing agent in coatings |
| CN105802238B (en) * | 2014-12-31 | 2019-06-25 | 埃肯有机硅（上海）有限公司 | Curable polysiloxane composition |
| CN107345369A (en) * | 2017-06-26 | 2017-11-14 | 苏州威尔德工贸有限公司 | A kind of silk fabric uvioresistant coloring agent |
| EP3775021A1 (en) | 2018-04-04 | 2021-02-17 | Basf Se | Use of an ultraviolet radiation absorbing polymer composition (uvrap) as an uv absorbing agent in a coating for non-living and non-keratinous materials |
| CN111648136A (en) * | 2018-04-21 | 2020-09-11 | 湖南辰砾新材料有限公司 | Fabric soft hydrophilic finishing agent |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2946701A (en) | 1957-11-12 | 1960-07-26 | Dow Corning | Method of treating glass with epoxysilanes and their epoxy-amine adducts, and the articles made thereby |
| NL149226B (en) | 1971-06-30 | 1976-04-15 | Monsanto Co | PROCESS FOR THE PREPARATION OF CHELATE FORMING POLYCARBON ACIDS AND PROCEDURE FOR THE PREPARATION OF DETERGENTS CONTAINING THEY. |
| US3790527A (en) | 1972-07-21 | 1974-02-05 | Gen Electric | Flexible tack free silicone resins |
| US4051161A (en) | 1972-09-15 | 1977-09-27 | E. I. Du Pont De Nemours And Company | Ultraviolet screening agents and coating materials containing organosilane ester groups |
| US3887514A (en) | 1974-01-02 | 1975-06-03 | Gen Electric | Bodied organopolysiloxanes and process therefor |
| US4006271A (en) | 1976-01-28 | 1977-02-01 | Itek Corporation | Abrasion resistant coating for polycarbonate substrates |
| JPS53111336A (en) * | 1977-03-11 | 1978-09-28 | Toray Ind Inc | Coating composition |
| CA1192103A (en) | 1977-08-08 | 1985-08-20 | Nazir A. Memon | Process for applying a silicone or siloxane-based abrasion resistant coating to a polycarbonate substrate, and coated articles |
| US4243720A (en) | 1978-11-01 | 1981-01-06 | General Electric Company | Silicone coated abrasion resistant polycarbonate article |
| US4413088A (en) | 1978-11-30 | 1983-11-01 | General Electric Co. | Silicone resin coating composition especially suited for primerless adhesion to cast acrylics |
| US4476281A (en) | 1978-11-30 | 1984-10-09 | General Electric Company | Silicone resin coating composition |
| US4299746A (en) | 1978-11-30 | 1981-11-10 | General Electric Company | Silicone resin coating composition |
| US4324712A (en) | 1978-11-30 | 1982-04-13 | General Electric Company | Silicone resin coating composition |
| US4277287A (en) | 1978-11-30 | 1981-07-07 | General Electric Company | Silicone resin coating composition |
| JPS55110166A (en) | 1979-02-16 | 1980-08-25 | Ito Kogaku Kogyo Kk | Coating composition |
| DE2914427A1 (en) | 1979-04-10 | 1980-10-23 | Bayer Ag | COATING FOR THERMOPLASTICS |
| GB2047721A (en) | 1979-04-16 | 1980-12-03 | Dow Corning | Coating composition |
| US4368235A (en) | 1980-01-18 | 1983-01-11 | General Electric Co. | Silicone resin coating composition |
| US4374674A (en) | 1980-05-30 | 1983-02-22 | General Electric Co. | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4278804A (en) | 1980-05-30 | 1981-07-14 | General Electric Company | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4419405A (en) | 1981-01-15 | 1983-12-06 | General Electric Company | Ultraviolet light absorbing agents and compositions and articles containing same |
| US4853471A (en) * | 1981-01-23 | 1989-08-01 | Ciba-Geigy Corporation | 2-(2-Hydroxyphenyl)-benztriazoles, their use as UV-absorbers and their preparation |
| DE3134777A1 (en) | 1981-09-02 | 1983-03-10 | Röhm GmbH, 6100 Darmstadt | WATER-BASED COATING AGENTS ON A SILICONE RESIN BASE |
| DE3135241A1 (en) | 1981-09-05 | 1983-03-17 | Röhm GmbH, 6100 Darmstadt | WATER-BASED COATING AGENTS ON A SILICONE RESIN BASE |
| DE3151350A1 (en) | 1981-12-24 | 1983-07-07 | Bayer Ag, 5090 Leverkusen | PLASTIC MOLDED BODIES EQUIPPED WITH A 3-LAYER COVER AND A METHOD FOR PRODUCING THE EQUIPMENT |
| US4525426A (en) | 1982-04-30 | 1985-06-25 | General Electric Company | Ultraviolet light absorbing agents, method for making, compositions, and articles containing same |
| US4495360A (en) | 1982-04-30 | 1985-01-22 | General Electric Company | Ultraviolet light absorbing agents, method for making, compositions and articles containing same |
| DE3407087C3 (en) | 1984-02-27 | 1994-07-07 | Fraunhofer Ges Forschung | Process and varnish for the production of scratch-resistant coatings |
| US4587169A (en) * | 1984-08-17 | 1986-05-06 | Minnesota Mining And Manufacturing Company | Abrasion resistant coatings |
| US4624870A (en) | 1984-11-14 | 1986-11-25 | General Electric Company | Sodium free silicone resin coating compositions |
| US4680232A (en) * | 1986-01-02 | 1987-07-14 | General Electric Company | Abrasion and UV resistant coating compositions |
| DE3706714A1 (en) | 1987-03-02 | 1988-09-15 | Fraunhofer Ges Forschung | INORGANIC POLYCONDENSATES WITH BUILT-IN ORGANIC POLYMERS |
| US4957818A (en) * | 1987-08-14 | 1990-09-18 | Mitsubishi Kasei Vinyl Company | Molded synthetic resin product |
| US4859759A (en) * | 1988-04-14 | 1989-08-22 | Kimberly-Clark Corporation | Siloxane containing benzotriazolyl/tetraalkylpiperidyl substituent |
| DE3836815A1 (en) | 1988-10-28 | 1990-07-26 | Hofmann Klaus Dipl Chem | Process and composition for the production of scratch-resistant materials, especially coatings having improved elasticity and adhesion |
| DE3917535A1 (en) | 1989-05-30 | 1990-12-06 | Fraunhofer Ges Forschung | Scratch-resistant materials - prepd. by hydrolysis of silane-based mixt. with removal of volatile hydrolysis prods. before applying coating or moulding |
| DE4011045A1 (en) | 1990-04-05 | 1991-10-10 | Fraunhofer Ges Forschung | METHOD FOR COATING PLASTIC SUBSTRATES AND VARNISH FOR USE IN THIS METHOD |
| DE4020316B4 (en) | 1990-06-26 | 2004-07-08 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for the production of a lacquer and its use |
| US5371138A (en) * | 1990-07-24 | 1994-12-06 | Tru Vue, Inc. | Ultraviolet blocking polysiloxane resin and process for making the same |
| DE4122743C1 (en) | 1991-07-10 | 1992-11-26 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung Ev, 8000 Muenchen, De | |
| WO1993015063A1 (en) | 1992-02-03 | 1993-08-05 | Hoechst Celanese Corporation | Uv light stabilizing, antioxidant and colorant compounds |
| DE4338361A1 (en) | 1993-11-10 | 1995-05-11 | Inst Neue Mat Gemein Gmbh | Process for the preparation of compositions based on silanes containing epoxy groups |
| JP3524617B2 (en) * | 1995-03-13 | 2004-05-10 | 新日本石油株式会社 | UV absorbers and coating materials |
| NZ333312A (en) * | 1996-06-27 | 2000-06-23 | Nippon Mitsubishi Oil Corp | Ultraviolet absorbing material comprising an aminosilane and ultraviolet absorbing plate |
| US6001163A (en) * | 1997-04-17 | 1999-12-14 | Sdc Coatings, Inc. | Composition for providing an abrasion resistant coating on a substrate |
-
1997
- 1997-06-10 DE DE19724397A patent/DE19724397A1/en not_active Ceased
-
1998
- 1998-05-15 TW TW087107508A patent/TW459011B/en active
- 1998-05-28 DE DE59802740T patent/DE59802740D1/en not_active Expired - Fee Related
- 1998-05-28 US US09/445,113 patent/US6306512B1/en not_active Expired - Fee Related
- 1998-05-28 DK DK98929392T patent/DK0988340T3/en active
- 1998-05-28 JP JP50143499A patent/JP4228124B2/en not_active Expired - Fee Related
- 1998-05-28 KR KR1019997011582A patent/KR100541298B1/en not_active IP Right Cessation
- 1998-05-28 BR BR9810434-9A patent/BR9810434A/en not_active IP Right Cessation
- 1998-05-28 ES ES98929392T patent/ES2167903T3/en not_active Expired - Lifetime
- 1998-05-28 ID IDW991375A patent/ID23428A/en unknown
- 1998-05-28 EP EP98929392A patent/EP0988340B1/en not_active Expired - Lifetime
- 1998-05-28 CN CN98806105A patent/CN1124309C/en not_active Expired - Fee Related
- 1998-05-28 WO PCT/EP1998/003157 patent/WO1998056853A1/en active IP Right Grant
- 1998-05-28 AU AU79163/98A patent/AU7916398A/en not_active Abandoned
- 1998-05-28 IL IL13279598A patent/IL132795A0/en unknown
- 1998-05-28 CA CA002293603A patent/CA2293603C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP4228124B2 (en) | 2009-02-25 |
| AU7916398A (en) | 1998-12-30 |
| DE59802740D1 (en) | 2002-02-21 |
| DE19724397A1 (en) | 1999-01-14 |
| JP2002511894A (en) | 2002-04-16 |
| EP0988340A1 (en) | 2000-03-29 |
| KR100541298B1 (en) | 2006-01-12 |
| CN1259973A (en) | 2000-07-12 |
| CA2293603A1 (en) | 1998-12-17 |
| BR9810434A (en) | 2000-09-19 |
| EP0988340B1 (en) | 2001-11-21 |
| ES2167903T3 (en) | 2002-05-16 |
| TW459011B (en) | 2001-10-11 |
| WO1998056853A1 (en) | 1998-12-17 |
| CN1124309C (en) | 2003-10-15 |
| DK0988340T3 (en) | 2002-05-21 |
| IL132795A0 (en) | 2001-03-19 |
| US6306512B1 (en) | 2001-10-23 |
| KR20010013575A (en) | 2001-02-26 |
| US20020002262A1 (en) | 2002-01-03 |
| ID23428A (en) | 2000-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |