CA2297934C - Process for manufacturing moulded articles made of plastics, cellulose or wood pulp and provided with cavities - Google Patents
Process for manufacturing moulded articles made of plastics, cellulose or wood pulp and provided with cavities Download PDFInfo
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- CA2297934C CA2297934C CA002297934A CA2297934A CA2297934C CA 2297934 C CA2297934 C CA 2297934C CA 002297934 A CA002297934 A CA 002297934A CA 2297934 A CA2297934 A CA 2297934A CA 2297934 C CA2297934 C CA 2297934C
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- gas
- mold halves
- mold
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
- B29C44/18—Filling preformed cavities
- B29C44/182—Filling flexible bags not having a particular shape
- B29C44/184—Filling flexible bags not having a particular shape and inserting the bags into preformed cavities
- B29C44/185—Starting the expansion after rupturing or dissolving the bag
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
- Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
- Y10T156/1003—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina by separating laminae between spaced secured areas [e.g., honeycomb expanding]
Abstract
Process for manufacturing molded articles made of plastics, cellulose, pulp or wood fibers with cavities (9), in particular composite parts for light-weight construction, by means of tool parts (1,2), including the following process steps:
a) a matrix layer (5) is provided at pre-selected locations with inserts (7) containing gas-creating substances or blowing agents and b) these inserts (7) are activated to create gas in tool parts (1,2) and thus expand the matrix material.
Also disclosed are gas-creating insertion elements for use in said process and made of gas-creating blowing substances enclosed in gas-proof sheaths or inserted into the matrix material (5) in order to form locally limited areas.
This process allows the production of particularly light and at the same time solid tool parts, in particular composite parts for light-weight construction.
a) a matrix layer (5) is provided at pre-selected locations with inserts (7) containing gas-creating substances or blowing agents and b) these inserts (7) are activated to create gas in tool parts (1,2) and thus expand the matrix material.
Also disclosed are gas-creating insertion elements for use in said process and made of gas-creating blowing substances enclosed in gas-proof sheaths or inserted into the matrix material (5) in order to form locally limited areas.
This process allows the production of particularly light and at the same time solid tool parts, in particular composite parts for light-weight construction.
Description
2811 December 1999 Procedure for manufacturing structured parts with cavities consisting of plastics, cellulose or wood granulate Description The invention concerns a procedure for the production of structured parts with cavities consisting of plastics, cellulose or wood granulate, in particular of light-weight construction compound parts, using molding tools. Gas-creating insertion elements are also used in the procedure.
The European patent EP 0 478 535 [B1] already contains a description o f plastic-coated parts such as pressure pads and rolls, whereas a further layer for the reduction or removal of adhesion is applied between the part and the epoxy coating in a locally limited procedure. To create cavities in the layer, the layer is filled with fluids or gas, through which the epoxy coating will arch outwards.
Consequently, the surrounding area of a roll can be deformed in a desired manner depending on order and size of the cavities.
The German patent application DE 33 24 705 Al describes a procedure for the production of a sound-absorbing lining with cavities which is made of textiles; this lining is preferably used for the construction of vehicles in order to line sound-sensible fields on the one hand and protect against airborne sound on the other hand. The lining consists of at least two mats that are made of textiles, for example reprocessed wool, that have been fabricated with a binding agent at raised temperature. A plastic part, i.e. a continuous tape, is inserted between the mats. The individual layers are then shed with needles and pressed together.
In certain areas, the mats and the continuous tape will be pressed more strongly than in others. During the pressing procedure, the plastic part will melt or create gas at the processing temperature; as a consequence, cavities are created in the areas with smaller compression. The areas with higher compression serve as bindings to stiffen the mats. Furthermore, the mats will be combined area by area by binding agents which become effective under the heat and thus the mat will be bound. The plastic parts are preferably made of polystyrol foam, e.g. of thermoformable plastics or other epoxies with low melting temperature.
The composite material described in the European patent application EP 0 679 501 Al is particularly known for its use in the production of sealing materials in automobile technology which are used for sealing cavities. This composite material consists of a cavity forming supporting material which again contains a "hot-foaming" material. Hot-foaming means that such a material (e.g.
polymerics or copolymers of ethylene and unsaturated acrylic esters) will transform at least partly when they are heating up. The temperature of the supporting material, e.g.
with polyamide plastic components, is higher than the temperature at the beginning of the foaming process. The composite material is always fabricated in pre-selected forms; afterwards the form will be placed in an installation site designed for the sealing process. For this procedure, the supporting material has to have at least one, preferably two oppositely arranged apertures, through which the foaming material will exit after the activation; the foam will consequently seal the composite material with the walls. An example for the production procedure of composite material parts would be the extrusion of hot-foaming material between two polyamid foils. The composite material parts are then punched into the pre-selected form, thus combining the two external structures.
The support material will not deform during the production process, it will only lead the foam leaking out through the cavities towards the sealing areas.
Furthermore, there is a process for reaction plastics injection molding as described in the German Disclosure DE-OS 1 926 688 which has been developed for the production of a mold part with a dense outer layer made of a polyurethane thermoset. The tool parts are used in automobile technology and household appliance industry, where big-size high-quality tool parts with thick cross sections required. The reaction plastics injection molding of foaming polyurethane thermoset takes place in a mold with core parts.
The core is formed by an elastic wrapper with a cylinder-shaped opening and is filled with a gas or a liquid.
As described in the European Patent Application EP 0 443 364 A2, there is a laminated plastic which consists of stable fixings in a foaming or honeycomb core layer made of a temperature-resistant epoxy. In the core layer, foaming inserts that have a higher density than the core layer are placed near the fixing places.
The core layer is coated with at least one layer of a fiber-reinforced temperature-resistant epoxy. Such laminated plastics are preferably used for the construction of interior parts for airplanes. An example for the incorporation of the inserts into the core layer would be the shaping of hollows into the core layer, and inserting a granular material blowing agent. The foaming granular material enters into the core layer and anchors there. Self-cutting tapped bushings can then be screwed into the insert. The blowing agents are used for foaming an epoxy in order to create a foam with high density.
The USS 4,113,909 also specifies the production of hexagonal structures of a plastomer to be used in light-weight building boards. A plate of the thermoplast is inserted between two molding boards, then heated up; afterwards the boards are drawn apart. Hereby the thermoplast form, now in heated condition, sticks to the molding boards and the drawn-apart thermoplast material forms a honeycomb structure.
The present invention aims at developing a procedure to manufacture particularly light, but at the same time solid, molding tools, in particular of light-weight construction compound parts.
This goal can be achieved through a procedure for manufacturing structured parts with cavities consisting of plastics, cellulose or wood granulate, in particular to form light-weight compound parts making use of tool parts following the features submitted under Claim 1. Useful applications of the invention are indicated in sub-claims 2 to 10. Furthermore, gas-creating insertion elements for the use of the previously mentioned procedures are indicated in sub-claims 11 to 16.
The said procedure for the production of structured parts with cavities made of plastics, cellulose or wood granulate using tool parts allows an expansion of the matrix material by inserting pre-shaped gas-creating substances in the matrix material at pre-selected places, and subsequently activat ing the insertion elements in the tool parts to produce gas, thus creating light-weight macro-cavities, which are preferably filled only with gas and the residue of the blowing agent and not with heavy foam.
The present invention extends the state of the art by offering the possibility to create several, but separately structured macro-cavities inside a matrix material without external gas conduction, which will preferably lead to a honeycomb structure formation with a homogeneous combination with the surface layers.
The said insertion elements which consist of gas-creating substances and a surrounding or solid coating, will be applicated to fiber webs in the form of circular, polygon or ring-shaped discs and implemented as single parts between at least two of the pre-fabricated layers of plastic, wood, or granulated material in double-sided films; these pre-fabricated layers are then inserted into the mold and subsequently coated by injection molding or extrusion or pressing to a homogeneous compound ready to be triggered for gas creation on the implemented inserts for lift-off in order to create the hollow structure.
A further possibility for the stationary fixing of the insertion elements would be the use of textile inserts. During the weaving process, the weaving machine pointedly places the insertion elements in the programmed pattern .
Multiple-staged weaving machines will insert the gas-creating substances in the said offset pattern in two layers. The prefabricated weavings with the included insertion elements positioned in the mold and the left cavity of the mold are filled by injected plastics. The subsequent creation of gas causes a tension of the reinforcement until the yielding point is reached. Due to the reinforcement, the compound part will be of greater solidity.
The submitted procedure makes it possible to coat light-weight structures with cavities in an economic process by inserting foils or a decor film inside the mold surfaces. These light-weight construction compound parts have a high specific strength-weight relation and are especially suited for cladding, covers and crash-proof parts in car, ship and airborne vehicle design. Using reinforced sheets of plastics or sheet steels as surface layers, high-strength structural parts are set up.
In addition to good sound and heat insulation through the cavities, the thickness of the structure walls can be held small. Three-dimensionally shaped hulls that are homogeneously bound with the matrix on the surface layers form a stable compound; furthermore, the cavities can be used to implement hollow elements including pipes and cables as single-double corrugated structures.
The presented invention differs from existing hot-foaming processes and foaming material inside hollow structures by the following features:
) The local situation of the cavities is predetermined by the situation of the insertion elements.
) The cavity size lies in the macro-area and is predetermined by the size of the insertion elements.
) The structured compound from the thin-walled encirclement of the cavities by the matrix material, as well as the combination of the bordering surface layer consists of a supporting homogenously bound matrix material.
) The design of the thickness of the matrix material walls, the form and size of the cavities, are predetermined by form and situation and the amount of blowing agent; and are arranged according to static requirements.
) The structured compound is arranged according to the direction of the form of the insertion elements and their size in accordance to the loads of the part.
The gasification and therefore the creation of cavities will preferably occur in a predetermined manner and in locally limited areas. The blowing agent substances will be activated after the local thermoplastic deformation of the pre-form and hot tack adhesion of layers or pre-formed layers in order to create the macro-cavities e.g. for a light-weight compound, web systems, isolation cavities etc.
The method for the punctual ignition of the gas-creating process of insertion elements imbedded in a matrix material of plastics, cellulose or wood granulate will preferably be applied according to the following features:
Exothermic processes:
Transgression of a certain pressure which is necessary for gasification, - by injecting (molding) additional matrix material, - by pressing and compressing a form, - Transgression of a certain temperature which is necessary for gasification, - by external additional warming such as radiation or convection, - by rubbing the particles by means of pressure or shifting, - by the friction of films and the resulting contact friction energy, microwave radiation, ultrasound, energetic radiation from outside;
Endothermic processes:
the mechanical mixing of gas- or heat-creating components using external pressure or shifting, thermal melting of substances coated by protective layers with gas or heat-creating substances with at least two components resulting in a subsequent reaction, the bursting of covers of included substances and their resulting reaction, ) the diffusion of two gas-creating substances which are separated by a porous film which, for the ignition/activation, will penetrate the film and then react Time-delayed processes:
- chemical reaction with determined delay, - attaining a certain mass by compres sion in order to trigger the gas- or heat-creating reaction;
triggering the reaction by placing additives of endotherm processing material Combination of the previously mentioned processes.
The processes of exothermic gasification are preferably combined by creating heat within the matrix material layer. The exothermic reaction softens the matrix material during the thermoforming of the matrix material. The endothermic gasification is combined with a temperature reduction which can then be used for the rapid hardening of the thermoplastics. The advantage of an endothermic gas-creating substance lies in the controlled process of gasification and the shorter cycle periods.
In addition, physical gases consisting of easily evaporating hydrocarbons (pentene to heptane KP 30 to 1000 C) can be used for the procedure. Chemical exothermic Azo-combinations, N-nitroso-combinations and sulfonyl-hydracides can also be employed at kick-off temperatures from 90 to 275 C. Suitable chemical endothermic (temperature raising) agents are NaHCO3 and Hydrocerol.
The previously mentioned substances generally start decomposing as soon as they reach a certain kick-off temperature, which corresponds to the requirements for the matrix materials, thereby creating gas. The widely-used azo-dicarbonamid can be adjusted to starting temperatures of 155-200 C by so-called kick-offs, for example Pb- and Sn stabilizers.
The blowing agent substances are produced as powders or granular materials.
They will be added to the hopper of an injection molding machine as a granular material or, for epoxy components, as liquid additives (powder). During the extruding, injection molding, and pressing processes, the gasification process is laid off by the high injection pressure.
Moreover, gas-creating insertion elements can be inserted which consist of heat-resistant explosives that release the prescribed amount of gas through electric ignition. This method is presently used for airbags in the automobile industry. For the complete explosive transition, insensitive explosives (blasting agents) require effective ignition agents (celluloseulose nitrate, Hg-fulminate, plumbum acid, argentum acid, tetracene, nitrophenol (diaodine nitrophenol), plumbum nitroresorcinate) or boosters (e.g.: glycerine nitrate, glycol di-nitrate, ammonium nitrate).
For the usage the processes of GFK, CFK, RFC, wood pulp or celluloseulose as porous and viscose matrix material, the gasification can happen within film blisters or airbag/mattress-like welded double films optionally; thus, a light-weight compound with a waver structure or honeycomb structures or an egg-crate shaped inner layer can be created.
The following figures will describe the invention in more detail:
Figure 1 A to 1 D pressing Figure 2A to 2E blow-molding Figure 3A to 3C thermoplast metal sheet compound Figure 4A to 4F reinforced fiber plastics vacuum forming or reaction processes and pressing Figure 5A to 5B injection molding with co-injection Figure 6A to 6B In-mold coating injection molding Figure 7A to 7D Injection molding with pre-forms and net insertion Figure 8A to 8D Injection molding with pre-forms insertion Figure 9A to 9C Injection molding with reflux melt and pre-form insertion Figure 10 Two-component injection Figure 1 1A to 11 B Insertion of gas-creating substances Figure 12 Coated insertion of gas-creating substances Figure 13A to 13C Textile rear injection molding Figure 14A to 14B Reinforced pre-formed inserts Figure 15A to 15C Thermoforming Figures 1A to 1 D show the procedure scheme of the process of pressing.
Between mold parts (1) and (2) (see figure 1A) of a press (which is not shown), a pre-formed insert is placed which consists of a upper left surface layer (4), a matrix layer (5) and a lower right surface layer (6). To the left of the matrix material (5), gas-creating insertion elements (7a) are arranged in a pattern. Further gas-creating insertion elem ents (7b) are arranged to the right of the matrix material (5) in an offset pattern. These layers of matrix material (5) and insertion elements (7a), (7b) can optionally be arranged multi-layered. By closing the press (see figure 1B) the compound part is grouted and the gasification of insertion elements (7) will be caused by pressure and/or temperature. After complete gasification the mold parts (1) and (2) are drawn apart, whereas the mold parts (1) and (2) are sealed against each other by means of a dipping rim (11), in order to maintain the gas pressure to lift off the matrix material (5). The part detached from the mold parts (1) and (2) (see figure 1 D) now consists of the left surface layer (4), the matrix material (5) which is now spherically thermoformed through the gas pressure, and the right surface layer (6). The residues (12) of the gas-creating element (7) remain in the cavities (9). By arranging the insertion elements (7) in rings, hexagons or octagons and correspondingly displacing the insertion elements (7) on the two sides of the matrix material (5), honeycomb-shaped intermediary layers can be created, which have separate macro-cavities (9) and are homogeneously bound to the surface layers (4) and (6). The essential economical advantage lies in the fact that this compound part is produced in one working cycle without the otherwise additionally necessary steps of binding the surface layers with the honeycomb matrix material.
Figures 2A to 2E show the scheme of the blow molding process. Such a process would be an essential application for the plastically inserted gas-creating elements (7). The pre-forms to the blow molds are either produced by injection molding (see figures 7 or 8) or they are extruded - as shown here in figures 2A and 2B. The actual blowing process is independent from the production of the pre-forms and is shown in figures 2C to 2E.
Figure 2A shows a part of a sectional view of a five-layered co-extrusion injection nozzle, that forms a rotation cylinder around an axis (22). The five processed materials consist of the upper surface layer (4), the upper gas-creating insertion elements (7a), the matrix material (5), the lower insertion elements (7b) and the lower surface layer (6). In the extrusion process, the upper (7a) and the lower (7b) gas-creating insertion elements are inserted in a pattern between the layers (4) and (6) and the matrix material (5). This is controlled by segmented subdivided slides (23) which are moving back and forth. Consequently, a tubular, continuously extruded hose (21) will be formed. In figure 2B the extruded hose (21) is shown as a sectional view. The gas-creating insertion elements (7a) are arranged in an offset pattern to the gas-creating insertion elements (7b). In the known production method for pre-forms, a part of the hose will be cut off and pressed. The pre-form (28) is inserted into the mold (29), as shown in figure 2C, and is blown to fit to the outer conture. Figure 2D shows how an initiator (30) is inserted for the stimulation of the gasification of the insertion elements (7). The gasification can be activated by means of ultraviolet light. While the materials (4), (5) and (6) are still in the thermoforming condition, the gas-creating insertion elements (7) will cause the cavities (9) and will form a multi-layer part. The multi-layer part now has a doubly corrugated (like an egg crate) inside compound with a smooth external wall. The double layer protects fro m leakage and increases the thermal insulation and the stability of the container.
Figures 3A to 3C illustrate the procedure for the production of thermoplast metal sheet compounds. A thermoplastic pre-form is inserted between an upper metal sheet (34) and a lower metal sheet (35) (see figure 3A). This pre-form consists of an upper surface layer (4), the upper gas-creating insertion elements (7a), the matrix material (5), the lower gas-creating insertion elements (7b) and the lower surface layer (6). Figure 3B shows the thermoplastic metal sheet compound which is deformed in a die press brake (not shown); this metal sheet compound then thermoplastically deforms the matrix material (5) in figure 3C after the initiation of gasification and optional endothermic heat formation through the gas pressure, thus drawing apart the mold parts (1) and (2).
Figures 4A to 4F show the schematic procedure for the RFC vacuum shaping or the fiber spraying and pressing. In the mold part (1), a lower surface layer made of fibers soaked with resin (4) is applied as a fiber reinforced plastic layer (19) by means of an extrusion head (17) that is swung (see figure 4A). Afterwards, the gas-creating insertion elements (7a) will be arranged (see figure 4B). The matrix material (5) is also inserted as a fiber reinforced plastic spraying (18) (see figure 4 C). Then the upper gas-creating insertion elements (7b) (see figure 4 D) will be arranged on top.
Finally, the upper surface layer (6) is sprayed to the matrix (5) (see figure 4E).
Mold part (1) is now shut and pressed to mold part (2). If desired, the gas that is left in between the layers can be sucked off by vacuum. The dipping rim (11) of the mold parts (1) and (2) serves as a seal. The fiber layers are grouted to inter-link the contacting areas of the layers. Gasification will be initiated by means of pressing, temperature or, for example, ultraviolet light (see figure 4 F). In figure 4G, mold part (2) will be lifted by controlled motion after homogenous gasification, and the matrix material (5) which has not yet hardened is spherically deformed by gas pressure. Figure 4H shows the compound after curing the epoxy part with upper surface layer (6), matrix material (5) and the lower surface layer (4).
In the cavities (9), the residue (12) of the gas-creating substances (7) remain.
Consequently, a light-weight construction part with cavities can easily be produced.
Figures 5A and 5B show the procedure for injection molding in the co-injection process. The co-injection nozzle in figu re 5A is schematized as a 3-layered version. (4) designates the upper surface layer, (6) is the lower surface layer. The middle nozzle injects gas-creating elements (7) as an extruded component. By means of the slide (23), the interlayer is alternately pressed between surface layers (4) and (6) . In accordance with the viscosity of layers (4), (6) and (7), a regular flow from surface layers and insertion elements (7) pours between mold part (1) and (2). Mold parts (1) and (2) are moved apart as shown in figure 5B
after the initiation of the gasification process whereas the mold parts remain gas-proof due to a dipping rim (11) in between them , so that the cavities (9) are spatially thermoforming the matrix material (5) by the internal gas pressure.
In this procedure, recycling material can be used. By the use of plastic gas-creating agents below the reaction temperature and the (exact) co-injection, optionally with an interruption cycle in the extrusion, as well as the subsequent ignition of the gas-creating process and the subsequent expanding motion of mold parts (1) and (2) when cooling down, a molded piece will be created with a double layered film and optionally with webs in between.
The figures 6A and 6B schematize the process for injection molding used in the "in mold coating" method. A material compound consisting of a film coating (46) and gas-creating insertion elements (7), that is preheated below the reaction temperature of the ignition agent, are inserted into a mold part (2) and pressed into mold part (1) while the core pull (3) is closed.
Subsequently, the matrix material (5) will be sprayed from the rear of the part to the film coating (46) with gas-creating insertion elements. The ignition agent of the gas-creating substances is now heated above ignition temperature by the injected thermoplastics; thus allowing to move mold part (1) corresponding to the desired thickness of the compound during the lift-off of the matrix material (5).
The figures 7A and 7D show the injection molding by means of a pre-form inserting procedure using a net. The insertion elements (7) of gas-creating substances are arranged in a pattern and fixed to a net (13) (see figure 7a) .
The net (13) and the elements (7) are placed between the mold parts (1) and (2) whereas a special device will preferably ensure a regular distance between the inner surface of mold parts (1) and (2) and the net (13). Figure 7C shows the melt injection. An injection nozzle (14) pours the thermoplastic into the form and, serving as matrix material (5), rinses around the gas-creating insertion parts (7) which are held at the planned distances by the net (13). Gasification (8) is activated by pressure and/or temperature (see figure 7D). After the homogenous gas creation, mold parts (1) and (2) are removed and the joints remain gas-proof by means of the dipping rim (11). Cavities (9) are created by the widening of the matrix material (5) which are surrounded by plastically deformed epoxy (15).
The gas-creating insertion elements (7) can optionally be placed in several layers with distances in between in an offset pattern, in order to create matrix materials (5) in honeycomb/egg crate shape.
Figures 8A and 8D schematize an injection molding process following the pre-form inserting procedure "pre-formed layer". An optionally preheated prefabricated pre-form consisting of a matrix material (5) is inserted between the mold parts (1) and (2). To the left and to the right of the matrix material (5), gas-creating insertion elements (7a) and (7b) are arranged in an offset pattern (see figure 8A).
Optionally, these layers can be carried out repeatedly. After closing mold parts (1) and (2) (see figure 8B), the pre-form is thermoformed adapting to the mold shape.
The mold parts (1) and (2) are opened to create a cavity for the right surface layer (6). The remaining cavity is injected with melt to have the right surface layer (6) poured into the form. The mold parts (1) and (2) are opened to create a cavity for the left surface layer (4). The injection of the left surface layer (4) is represented in figure 8C. By means of the second injection nozzle (14b), a hot melting epoxy is injected, which will activate gasification e. g. through pressure and/or temperature (see figure 8 D). After the gasification has been completed, the mold parts (1) and (2) will be moved apart, whereas the parts remain gas-proof due to dipping rim (11). The part now consists of a left surface layer (4), a matrix material (5) which is now deformed spatially by gas pressure, and a right surface layer (6).
Figures 9A and 9C show the procedure for gas melt injection molding processes.
After the insertion of the left surface layer (4) and of gas-creating insertion elements (7), the mold parts (1) and (2) are closed (see figure 9A). Figure 9B
shows the injection molding process, where the right surface layer (6) is injected above the injector nozzle (14). Gasification is initiated by the increase of temperature and/or pressurizing. Figure 9C displays the reflux of the plastic melt (39) processes through the injection nozzle (14), with cavities (9) resulting from the created gas pressure.
Figures 10 exhibit the schematic process of a two component plastics injection.
The plastic insertion of the gas-creating substances can be achieved with a two component plastics machinery by means of injection of two epoxy surface layers (4) and (6), thus creating a two-layered material flow. In accordance with the hydraulic flow principles, the formed layers (32) are injected to the cavities between the mold parts (1) and (2) and then distributed and will then form areas with gas-creating characteristics (33). The plastic material of the gas-creating insertion elements (7) is injected as one part of the two components. Both volume and distance of the insertion elements are controlled via the second component and/or distributed by the injection nozzle according to speed and volume. The mold parts (1) and (2) will be kept under pressure until all gas-creating insertion elements (7) have been activated in order to enable the subsequent creation of cavities after moving apart mold parts (1) and (2).
Figures 11A to 11 D display a process to add gas-creating insertion elements (7) to the matrix by blister injection. Mold part (1) contains several injection needles (20) which are arranged in a sliding axial position (see figure 1 1A). Matrix material (5) is injected through an injection nozzle (14) (see figure 11B) in between the mold parts (1) and (2). The injection needles (20) which are placed in mold part (1) are pushed forward to the matrix material (5) (see figure 11C). The gas-creating substances (7) are injected through these needles on to the matrix material (5) while additional volume is added to the mold by moving apart the mold parts (1) and (2) and will activate gasification by pressurizing and/or temperature (see figure 11 D). The injection needles (20) are, subsequently pulled back. After the gasification is completed, the mold parts are moved apart according to the designed thickness of the structure, whereas the form remains gas-proof due to the dipping rim (11). Cavities (9) are created wh ich are surrounded by plastically deformed epoxy (15) created by the matrix material (5). To create multiple-layered cavities, the injection needles (20) can be positioned in different axial positions.
Figure 12 schematizes the procedure for a coated blister injection with gas-creating insertion elements. Here, the injection needle consists of two concentric tubes. Inner tube (45) and external tube (42) are moved into the matrix material (5). In the first step, a ductile thermoplastic material (41) is injected into the matrix material (5) through the space (43) between external and inner tube. The gas-creating insertion element is injected into the ductile thermoplastic material (41) by the inner tube (44). The tubes (45) and (41) are then withdrawn to form a blister covered with ductile epoxy containing gas-creating substances.
Figures 13A and 13C show a textile rear injection molding procedure. Into the mold part (1), a textile (41) is inserted. By means of a spraying nozzle (40), the melt is put on as matrix material (5). On top of this melt, gas-creating insertion elements are injected and then covered with the matrix material (5) (see figure 13A). The mold parts (1) and (2) are closed while the core pull (40) is shut (figure 13 B). After the pressing of the matrix material (5) with the textile (41) and the gas-creating insertion elements (7), gasification (8) takes place. Figure 13C
displays the procedure where core pull (40) is moved apart from mold part (1) and textile (41). Cavities (9) are generated in between mold part (1) and the core pull (40).
Figures 14A and 14B illustrate the procedure employing a reinforcement layer surrounding the gas-creating insertion elements (7). Figure 14A depicts a gas-creating insertion element (7), which is reinforced by tissue threads. The first layer of reinforced fibers (36) alternately winds around insertion elements (7), placing the second layer of reinforced fibers on the other side of the insertion elements (7). Surface layers (4) and (6) can then be applied on top optionally. A two-layered gas-creating insertion layer (7a) and (7b) is represented in figure 14B. Both layers surround the matrix material (5). The first layer of reinforced fibers (36) alternately winds around the second layer of reinforced fibers (37) and the third layer of reinforced fibers (38). Surface layers (4) and (6) are applied on top optionally.
The Figures 15A to 15C show the procedure for the "thermoplastic thermoforming"
process by means of a 4-layered part with 3 layers of gas-creatin g insertions (7a) to (7c). Upper surface layer (4) and the upper matrix material (5a) surround the gas-creating upper insertion elements (7a). Between the matrix materials (5a) and (5b), the middle gas creating insertion elements (7b) are positioned. The gas-creating insertion elements (7c) are placed between matrix material (5b) and the lower surface layer (6). Through the internal gas pressure initiated by pressure or temperature and the moving apart of surface layers (4) and (6), the thermoplastic deformation of the matrix materials 5a and 5b will be initiated; as a consequence, the part shown in figure 15C will be created which shows a (highly solid) web structure of high firmness after cooling.
Item list 1 primary mold part molding 2 second mold part 29 blow mold 3 core pull 30 ignition agent 4 surface layer 32 layer of blowing agent matrix material 33 gas-creating layer 6 second surface layer 34 upper metal sheet 7 insertion elements 35 lower metal sheet 9 cavity 36 first layer of reinforced fibers 11 dipping rim 37 second layer of reinforced 12 residue of blowing agent fibers 13 net 38 third layer of reinforced 14 injection nozzle, spraying unit fibers matrix material spherically 39 reflux of plastics melting deformed 40 textile rear injection 17 injection unit/device molding 19 fiber reinforced plastic 41 surrounding plastics layer blisters injection needle 42 external injection needle 21 extruded multi-layer 43 inner injection needle hose 44 gas-creating substance 22 axis of the nozzle 45 low-melting epoxy 23 slide 46 film coating 28 pre-form for blow-
The European patent EP 0 478 535 [B1] already contains a description o f plastic-coated parts such as pressure pads and rolls, whereas a further layer for the reduction or removal of adhesion is applied between the part and the epoxy coating in a locally limited procedure. To create cavities in the layer, the layer is filled with fluids or gas, through which the epoxy coating will arch outwards.
Consequently, the surrounding area of a roll can be deformed in a desired manner depending on order and size of the cavities.
The German patent application DE 33 24 705 Al describes a procedure for the production of a sound-absorbing lining with cavities which is made of textiles; this lining is preferably used for the construction of vehicles in order to line sound-sensible fields on the one hand and protect against airborne sound on the other hand. The lining consists of at least two mats that are made of textiles, for example reprocessed wool, that have been fabricated with a binding agent at raised temperature. A plastic part, i.e. a continuous tape, is inserted between the mats. The individual layers are then shed with needles and pressed together.
In certain areas, the mats and the continuous tape will be pressed more strongly than in others. During the pressing procedure, the plastic part will melt or create gas at the processing temperature; as a consequence, cavities are created in the areas with smaller compression. The areas with higher compression serve as bindings to stiffen the mats. Furthermore, the mats will be combined area by area by binding agents which become effective under the heat and thus the mat will be bound. The plastic parts are preferably made of polystyrol foam, e.g. of thermoformable plastics or other epoxies with low melting temperature.
The composite material described in the European patent application EP 0 679 501 Al is particularly known for its use in the production of sealing materials in automobile technology which are used for sealing cavities. This composite material consists of a cavity forming supporting material which again contains a "hot-foaming" material. Hot-foaming means that such a material (e.g.
polymerics or copolymers of ethylene and unsaturated acrylic esters) will transform at least partly when they are heating up. The temperature of the supporting material, e.g.
with polyamide plastic components, is higher than the temperature at the beginning of the foaming process. The composite material is always fabricated in pre-selected forms; afterwards the form will be placed in an installation site designed for the sealing process. For this procedure, the supporting material has to have at least one, preferably two oppositely arranged apertures, through which the foaming material will exit after the activation; the foam will consequently seal the composite material with the walls. An example for the production procedure of composite material parts would be the extrusion of hot-foaming material between two polyamid foils. The composite material parts are then punched into the pre-selected form, thus combining the two external structures.
The support material will not deform during the production process, it will only lead the foam leaking out through the cavities towards the sealing areas.
Furthermore, there is a process for reaction plastics injection molding as described in the German Disclosure DE-OS 1 926 688 which has been developed for the production of a mold part with a dense outer layer made of a polyurethane thermoset. The tool parts are used in automobile technology and household appliance industry, where big-size high-quality tool parts with thick cross sections required. The reaction plastics injection molding of foaming polyurethane thermoset takes place in a mold with core parts.
The core is formed by an elastic wrapper with a cylinder-shaped opening and is filled with a gas or a liquid.
As described in the European Patent Application EP 0 443 364 A2, there is a laminated plastic which consists of stable fixings in a foaming or honeycomb core layer made of a temperature-resistant epoxy. In the core layer, foaming inserts that have a higher density than the core layer are placed near the fixing places.
The core layer is coated with at least one layer of a fiber-reinforced temperature-resistant epoxy. Such laminated plastics are preferably used for the construction of interior parts for airplanes. An example for the incorporation of the inserts into the core layer would be the shaping of hollows into the core layer, and inserting a granular material blowing agent. The foaming granular material enters into the core layer and anchors there. Self-cutting tapped bushings can then be screwed into the insert. The blowing agents are used for foaming an epoxy in order to create a foam with high density.
The USS 4,113,909 also specifies the production of hexagonal structures of a plastomer to be used in light-weight building boards. A plate of the thermoplast is inserted between two molding boards, then heated up; afterwards the boards are drawn apart. Hereby the thermoplast form, now in heated condition, sticks to the molding boards and the drawn-apart thermoplast material forms a honeycomb structure.
The present invention aims at developing a procedure to manufacture particularly light, but at the same time solid, molding tools, in particular of light-weight construction compound parts.
This goal can be achieved through a procedure for manufacturing structured parts with cavities consisting of plastics, cellulose or wood granulate, in particular to form light-weight compound parts making use of tool parts following the features submitted under Claim 1. Useful applications of the invention are indicated in sub-claims 2 to 10. Furthermore, gas-creating insertion elements for the use of the previously mentioned procedures are indicated in sub-claims 11 to 16.
The said procedure for the production of structured parts with cavities made of plastics, cellulose or wood granulate using tool parts allows an expansion of the matrix material by inserting pre-shaped gas-creating substances in the matrix material at pre-selected places, and subsequently activat ing the insertion elements in the tool parts to produce gas, thus creating light-weight macro-cavities, which are preferably filled only with gas and the residue of the blowing agent and not with heavy foam.
The present invention extends the state of the art by offering the possibility to create several, but separately structured macro-cavities inside a matrix material without external gas conduction, which will preferably lead to a honeycomb structure formation with a homogeneous combination with the surface layers.
The said insertion elements which consist of gas-creating substances and a surrounding or solid coating, will be applicated to fiber webs in the form of circular, polygon or ring-shaped discs and implemented as single parts between at least two of the pre-fabricated layers of plastic, wood, or granulated material in double-sided films; these pre-fabricated layers are then inserted into the mold and subsequently coated by injection molding or extrusion or pressing to a homogeneous compound ready to be triggered for gas creation on the implemented inserts for lift-off in order to create the hollow structure.
A further possibility for the stationary fixing of the insertion elements would be the use of textile inserts. During the weaving process, the weaving machine pointedly places the insertion elements in the programmed pattern .
Multiple-staged weaving machines will insert the gas-creating substances in the said offset pattern in two layers. The prefabricated weavings with the included insertion elements positioned in the mold and the left cavity of the mold are filled by injected plastics. The subsequent creation of gas causes a tension of the reinforcement until the yielding point is reached. Due to the reinforcement, the compound part will be of greater solidity.
The submitted procedure makes it possible to coat light-weight structures with cavities in an economic process by inserting foils or a decor film inside the mold surfaces. These light-weight construction compound parts have a high specific strength-weight relation and are especially suited for cladding, covers and crash-proof parts in car, ship and airborne vehicle design. Using reinforced sheets of plastics or sheet steels as surface layers, high-strength structural parts are set up.
In addition to good sound and heat insulation through the cavities, the thickness of the structure walls can be held small. Three-dimensionally shaped hulls that are homogeneously bound with the matrix on the surface layers form a stable compound; furthermore, the cavities can be used to implement hollow elements including pipes and cables as single-double corrugated structures.
The presented invention differs from existing hot-foaming processes and foaming material inside hollow structures by the following features:
) The local situation of the cavities is predetermined by the situation of the insertion elements.
) The cavity size lies in the macro-area and is predetermined by the size of the insertion elements.
) The structured compound from the thin-walled encirclement of the cavities by the matrix material, as well as the combination of the bordering surface layer consists of a supporting homogenously bound matrix material.
) The design of the thickness of the matrix material walls, the form and size of the cavities, are predetermined by form and situation and the amount of blowing agent; and are arranged according to static requirements.
) The structured compound is arranged according to the direction of the form of the insertion elements and their size in accordance to the loads of the part.
The gasification and therefore the creation of cavities will preferably occur in a predetermined manner and in locally limited areas. The blowing agent substances will be activated after the local thermoplastic deformation of the pre-form and hot tack adhesion of layers or pre-formed layers in order to create the macro-cavities e.g. for a light-weight compound, web systems, isolation cavities etc.
The method for the punctual ignition of the gas-creating process of insertion elements imbedded in a matrix material of plastics, cellulose or wood granulate will preferably be applied according to the following features:
Exothermic processes:
Transgression of a certain pressure which is necessary for gasification, - by injecting (molding) additional matrix material, - by pressing and compressing a form, - Transgression of a certain temperature which is necessary for gasification, - by external additional warming such as radiation or convection, - by rubbing the particles by means of pressure or shifting, - by the friction of films and the resulting contact friction energy, microwave radiation, ultrasound, energetic radiation from outside;
Endothermic processes:
the mechanical mixing of gas- or heat-creating components using external pressure or shifting, thermal melting of substances coated by protective layers with gas or heat-creating substances with at least two components resulting in a subsequent reaction, the bursting of covers of included substances and their resulting reaction, ) the diffusion of two gas-creating substances which are separated by a porous film which, for the ignition/activation, will penetrate the film and then react Time-delayed processes:
- chemical reaction with determined delay, - attaining a certain mass by compres sion in order to trigger the gas- or heat-creating reaction;
triggering the reaction by placing additives of endotherm processing material Combination of the previously mentioned processes.
The processes of exothermic gasification are preferably combined by creating heat within the matrix material layer. The exothermic reaction softens the matrix material during the thermoforming of the matrix material. The endothermic gasification is combined with a temperature reduction which can then be used for the rapid hardening of the thermoplastics. The advantage of an endothermic gas-creating substance lies in the controlled process of gasification and the shorter cycle periods.
In addition, physical gases consisting of easily evaporating hydrocarbons (pentene to heptane KP 30 to 1000 C) can be used for the procedure. Chemical exothermic Azo-combinations, N-nitroso-combinations and sulfonyl-hydracides can also be employed at kick-off temperatures from 90 to 275 C. Suitable chemical endothermic (temperature raising) agents are NaHCO3 and Hydrocerol.
The previously mentioned substances generally start decomposing as soon as they reach a certain kick-off temperature, which corresponds to the requirements for the matrix materials, thereby creating gas. The widely-used azo-dicarbonamid can be adjusted to starting temperatures of 155-200 C by so-called kick-offs, for example Pb- and Sn stabilizers.
The blowing agent substances are produced as powders or granular materials.
They will be added to the hopper of an injection molding machine as a granular material or, for epoxy components, as liquid additives (powder). During the extruding, injection molding, and pressing processes, the gasification process is laid off by the high injection pressure.
Moreover, gas-creating insertion elements can be inserted which consist of heat-resistant explosives that release the prescribed amount of gas through electric ignition. This method is presently used for airbags in the automobile industry. For the complete explosive transition, insensitive explosives (blasting agents) require effective ignition agents (celluloseulose nitrate, Hg-fulminate, plumbum acid, argentum acid, tetracene, nitrophenol (diaodine nitrophenol), plumbum nitroresorcinate) or boosters (e.g.: glycerine nitrate, glycol di-nitrate, ammonium nitrate).
For the usage the processes of GFK, CFK, RFC, wood pulp or celluloseulose as porous and viscose matrix material, the gasification can happen within film blisters or airbag/mattress-like welded double films optionally; thus, a light-weight compound with a waver structure or honeycomb structures or an egg-crate shaped inner layer can be created.
The following figures will describe the invention in more detail:
Figure 1 A to 1 D pressing Figure 2A to 2E blow-molding Figure 3A to 3C thermoplast metal sheet compound Figure 4A to 4F reinforced fiber plastics vacuum forming or reaction processes and pressing Figure 5A to 5B injection molding with co-injection Figure 6A to 6B In-mold coating injection molding Figure 7A to 7D Injection molding with pre-forms and net insertion Figure 8A to 8D Injection molding with pre-forms insertion Figure 9A to 9C Injection molding with reflux melt and pre-form insertion Figure 10 Two-component injection Figure 1 1A to 11 B Insertion of gas-creating substances Figure 12 Coated insertion of gas-creating substances Figure 13A to 13C Textile rear injection molding Figure 14A to 14B Reinforced pre-formed inserts Figure 15A to 15C Thermoforming Figures 1A to 1 D show the procedure scheme of the process of pressing.
Between mold parts (1) and (2) (see figure 1A) of a press (which is not shown), a pre-formed insert is placed which consists of a upper left surface layer (4), a matrix layer (5) and a lower right surface layer (6). To the left of the matrix material (5), gas-creating insertion elements (7a) are arranged in a pattern. Further gas-creating insertion elem ents (7b) are arranged to the right of the matrix material (5) in an offset pattern. These layers of matrix material (5) and insertion elements (7a), (7b) can optionally be arranged multi-layered. By closing the press (see figure 1B) the compound part is grouted and the gasification of insertion elements (7) will be caused by pressure and/or temperature. After complete gasification the mold parts (1) and (2) are drawn apart, whereas the mold parts (1) and (2) are sealed against each other by means of a dipping rim (11), in order to maintain the gas pressure to lift off the matrix material (5). The part detached from the mold parts (1) and (2) (see figure 1 D) now consists of the left surface layer (4), the matrix material (5) which is now spherically thermoformed through the gas pressure, and the right surface layer (6). The residues (12) of the gas-creating element (7) remain in the cavities (9). By arranging the insertion elements (7) in rings, hexagons or octagons and correspondingly displacing the insertion elements (7) on the two sides of the matrix material (5), honeycomb-shaped intermediary layers can be created, which have separate macro-cavities (9) and are homogeneously bound to the surface layers (4) and (6). The essential economical advantage lies in the fact that this compound part is produced in one working cycle without the otherwise additionally necessary steps of binding the surface layers with the honeycomb matrix material.
Figures 2A to 2E show the scheme of the blow molding process. Such a process would be an essential application for the plastically inserted gas-creating elements (7). The pre-forms to the blow molds are either produced by injection molding (see figures 7 or 8) or they are extruded - as shown here in figures 2A and 2B. The actual blowing process is independent from the production of the pre-forms and is shown in figures 2C to 2E.
Figure 2A shows a part of a sectional view of a five-layered co-extrusion injection nozzle, that forms a rotation cylinder around an axis (22). The five processed materials consist of the upper surface layer (4), the upper gas-creating insertion elements (7a), the matrix material (5), the lower insertion elements (7b) and the lower surface layer (6). In the extrusion process, the upper (7a) and the lower (7b) gas-creating insertion elements are inserted in a pattern between the layers (4) and (6) and the matrix material (5). This is controlled by segmented subdivided slides (23) which are moving back and forth. Consequently, a tubular, continuously extruded hose (21) will be formed. In figure 2B the extruded hose (21) is shown as a sectional view. The gas-creating insertion elements (7a) are arranged in an offset pattern to the gas-creating insertion elements (7b). In the known production method for pre-forms, a part of the hose will be cut off and pressed. The pre-form (28) is inserted into the mold (29), as shown in figure 2C, and is blown to fit to the outer conture. Figure 2D shows how an initiator (30) is inserted for the stimulation of the gasification of the insertion elements (7). The gasification can be activated by means of ultraviolet light. While the materials (4), (5) and (6) are still in the thermoforming condition, the gas-creating insertion elements (7) will cause the cavities (9) and will form a multi-layer part. The multi-layer part now has a doubly corrugated (like an egg crate) inside compound with a smooth external wall. The double layer protects fro m leakage and increases the thermal insulation and the stability of the container.
Figures 3A to 3C illustrate the procedure for the production of thermoplast metal sheet compounds. A thermoplastic pre-form is inserted between an upper metal sheet (34) and a lower metal sheet (35) (see figure 3A). This pre-form consists of an upper surface layer (4), the upper gas-creating insertion elements (7a), the matrix material (5), the lower gas-creating insertion elements (7b) and the lower surface layer (6). Figure 3B shows the thermoplastic metal sheet compound which is deformed in a die press brake (not shown); this metal sheet compound then thermoplastically deforms the matrix material (5) in figure 3C after the initiation of gasification and optional endothermic heat formation through the gas pressure, thus drawing apart the mold parts (1) and (2).
Figures 4A to 4F show the schematic procedure for the RFC vacuum shaping or the fiber spraying and pressing. In the mold part (1), a lower surface layer made of fibers soaked with resin (4) is applied as a fiber reinforced plastic layer (19) by means of an extrusion head (17) that is swung (see figure 4A). Afterwards, the gas-creating insertion elements (7a) will be arranged (see figure 4B). The matrix material (5) is also inserted as a fiber reinforced plastic spraying (18) (see figure 4 C). Then the upper gas-creating insertion elements (7b) (see figure 4 D) will be arranged on top.
Finally, the upper surface layer (6) is sprayed to the matrix (5) (see figure 4E).
Mold part (1) is now shut and pressed to mold part (2). If desired, the gas that is left in between the layers can be sucked off by vacuum. The dipping rim (11) of the mold parts (1) and (2) serves as a seal. The fiber layers are grouted to inter-link the contacting areas of the layers. Gasification will be initiated by means of pressing, temperature or, for example, ultraviolet light (see figure 4 F). In figure 4G, mold part (2) will be lifted by controlled motion after homogenous gasification, and the matrix material (5) which has not yet hardened is spherically deformed by gas pressure. Figure 4H shows the compound after curing the epoxy part with upper surface layer (6), matrix material (5) and the lower surface layer (4).
In the cavities (9), the residue (12) of the gas-creating substances (7) remain.
Consequently, a light-weight construction part with cavities can easily be produced.
Figures 5A and 5B show the procedure for injection molding in the co-injection process. The co-injection nozzle in figu re 5A is schematized as a 3-layered version. (4) designates the upper surface layer, (6) is the lower surface layer. The middle nozzle injects gas-creating elements (7) as an extruded component. By means of the slide (23), the interlayer is alternately pressed between surface layers (4) and (6) . In accordance with the viscosity of layers (4), (6) and (7), a regular flow from surface layers and insertion elements (7) pours between mold part (1) and (2). Mold parts (1) and (2) are moved apart as shown in figure 5B
after the initiation of the gasification process whereas the mold parts remain gas-proof due to a dipping rim (11) in between them , so that the cavities (9) are spatially thermoforming the matrix material (5) by the internal gas pressure.
In this procedure, recycling material can be used. By the use of plastic gas-creating agents below the reaction temperature and the (exact) co-injection, optionally with an interruption cycle in the extrusion, as well as the subsequent ignition of the gas-creating process and the subsequent expanding motion of mold parts (1) and (2) when cooling down, a molded piece will be created with a double layered film and optionally with webs in between.
The figures 6A and 6B schematize the process for injection molding used in the "in mold coating" method. A material compound consisting of a film coating (46) and gas-creating insertion elements (7), that is preheated below the reaction temperature of the ignition agent, are inserted into a mold part (2) and pressed into mold part (1) while the core pull (3) is closed.
Subsequently, the matrix material (5) will be sprayed from the rear of the part to the film coating (46) with gas-creating insertion elements. The ignition agent of the gas-creating substances is now heated above ignition temperature by the injected thermoplastics; thus allowing to move mold part (1) corresponding to the desired thickness of the compound during the lift-off of the matrix material (5).
The figures 7A and 7D show the injection molding by means of a pre-form inserting procedure using a net. The insertion elements (7) of gas-creating substances are arranged in a pattern and fixed to a net (13) (see figure 7a) .
The net (13) and the elements (7) are placed between the mold parts (1) and (2) whereas a special device will preferably ensure a regular distance between the inner surface of mold parts (1) and (2) and the net (13). Figure 7C shows the melt injection. An injection nozzle (14) pours the thermoplastic into the form and, serving as matrix material (5), rinses around the gas-creating insertion parts (7) which are held at the planned distances by the net (13). Gasification (8) is activated by pressure and/or temperature (see figure 7D). After the homogenous gas creation, mold parts (1) and (2) are removed and the joints remain gas-proof by means of the dipping rim (11). Cavities (9) are created by the widening of the matrix material (5) which are surrounded by plastically deformed epoxy (15).
The gas-creating insertion elements (7) can optionally be placed in several layers with distances in between in an offset pattern, in order to create matrix materials (5) in honeycomb/egg crate shape.
Figures 8A and 8D schematize an injection molding process following the pre-form inserting procedure "pre-formed layer". An optionally preheated prefabricated pre-form consisting of a matrix material (5) is inserted between the mold parts (1) and (2). To the left and to the right of the matrix material (5), gas-creating insertion elements (7a) and (7b) are arranged in an offset pattern (see figure 8A).
Optionally, these layers can be carried out repeatedly. After closing mold parts (1) and (2) (see figure 8B), the pre-form is thermoformed adapting to the mold shape.
The mold parts (1) and (2) are opened to create a cavity for the right surface layer (6). The remaining cavity is injected with melt to have the right surface layer (6) poured into the form. The mold parts (1) and (2) are opened to create a cavity for the left surface layer (4). The injection of the left surface layer (4) is represented in figure 8C. By means of the second injection nozzle (14b), a hot melting epoxy is injected, which will activate gasification e. g. through pressure and/or temperature (see figure 8 D). After the gasification has been completed, the mold parts (1) and (2) will be moved apart, whereas the parts remain gas-proof due to dipping rim (11). The part now consists of a left surface layer (4), a matrix material (5) which is now deformed spatially by gas pressure, and a right surface layer (6).
Figures 9A and 9C show the procedure for gas melt injection molding processes.
After the insertion of the left surface layer (4) and of gas-creating insertion elements (7), the mold parts (1) and (2) are closed (see figure 9A). Figure 9B
shows the injection molding process, where the right surface layer (6) is injected above the injector nozzle (14). Gasification is initiated by the increase of temperature and/or pressurizing. Figure 9C displays the reflux of the plastic melt (39) processes through the injection nozzle (14), with cavities (9) resulting from the created gas pressure.
Figures 10 exhibit the schematic process of a two component plastics injection.
The plastic insertion of the gas-creating substances can be achieved with a two component plastics machinery by means of injection of two epoxy surface layers (4) and (6), thus creating a two-layered material flow. In accordance with the hydraulic flow principles, the formed layers (32) are injected to the cavities between the mold parts (1) and (2) and then distributed and will then form areas with gas-creating characteristics (33). The plastic material of the gas-creating insertion elements (7) is injected as one part of the two components. Both volume and distance of the insertion elements are controlled via the second component and/or distributed by the injection nozzle according to speed and volume. The mold parts (1) and (2) will be kept under pressure until all gas-creating insertion elements (7) have been activated in order to enable the subsequent creation of cavities after moving apart mold parts (1) and (2).
Figures 11A to 11 D display a process to add gas-creating insertion elements (7) to the matrix by blister injection. Mold part (1) contains several injection needles (20) which are arranged in a sliding axial position (see figure 1 1A). Matrix material (5) is injected through an injection nozzle (14) (see figure 11B) in between the mold parts (1) and (2). The injection needles (20) which are placed in mold part (1) are pushed forward to the matrix material (5) (see figure 11C). The gas-creating substances (7) are injected through these needles on to the matrix material (5) while additional volume is added to the mold by moving apart the mold parts (1) and (2) and will activate gasification by pressurizing and/or temperature (see figure 11 D). The injection needles (20) are, subsequently pulled back. After the gasification is completed, the mold parts are moved apart according to the designed thickness of the structure, whereas the form remains gas-proof due to the dipping rim (11). Cavities (9) are created wh ich are surrounded by plastically deformed epoxy (15) created by the matrix material (5). To create multiple-layered cavities, the injection needles (20) can be positioned in different axial positions.
Figure 12 schematizes the procedure for a coated blister injection with gas-creating insertion elements. Here, the injection needle consists of two concentric tubes. Inner tube (45) and external tube (42) are moved into the matrix material (5). In the first step, a ductile thermoplastic material (41) is injected into the matrix material (5) through the space (43) between external and inner tube. The gas-creating insertion element is injected into the ductile thermoplastic material (41) by the inner tube (44). The tubes (45) and (41) are then withdrawn to form a blister covered with ductile epoxy containing gas-creating substances.
Figures 13A and 13C show a textile rear injection molding procedure. Into the mold part (1), a textile (41) is inserted. By means of a spraying nozzle (40), the melt is put on as matrix material (5). On top of this melt, gas-creating insertion elements are injected and then covered with the matrix material (5) (see figure 13A). The mold parts (1) and (2) are closed while the core pull (40) is shut (figure 13 B). After the pressing of the matrix material (5) with the textile (41) and the gas-creating insertion elements (7), gasification (8) takes place. Figure 13C
displays the procedure where core pull (40) is moved apart from mold part (1) and textile (41). Cavities (9) are generated in between mold part (1) and the core pull (40).
Figures 14A and 14B illustrate the procedure employing a reinforcement layer surrounding the gas-creating insertion elements (7). Figure 14A depicts a gas-creating insertion element (7), which is reinforced by tissue threads. The first layer of reinforced fibers (36) alternately winds around insertion elements (7), placing the second layer of reinforced fibers on the other side of the insertion elements (7). Surface layers (4) and (6) can then be applied on top optionally. A two-layered gas-creating insertion layer (7a) and (7b) is represented in figure 14B. Both layers surround the matrix material (5). The first layer of reinforced fibers (36) alternately winds around the second layer of reinforced fibers (37) and the third layer of reinforced fibers (38). Surface layers (4) and (6) are applied on top optionally.
The Figures 15A to 15C show the procedure for the "thermoplastic thermoforming"
process by means of a 4-layered part with 3 layers of gas-creatin g insertions (7a) to (7c). Upper surface layer (4) and the upper matrix material (5a) surround the gas-creating upper insertion elements (7a). Between the matrix materials (5a) and (5b), the middle gas creating insertion elements (7b) are positioned. The gas-creating insertion elements (7c) are placed between matrix material (5b) and the lower surface layer (6). Through the internal gas pressure initiated by pressure or temperature and the moving apart of surface layers (4) and (6), the thermoplastic deformation of the matrix materials 5a and 5b will be initiated; as a consequence, the part shown in figure 15C will be created which shows a (highly solid) web structure of high firmness after cooling.
Item list 1 primary mold part molding 2 second mold part 29 blow mold 3 core pull 30 ignition agent 4 surface layer 32 layer of blowing agent matrix material 33 gas-creating layer 6 second surface layer 34 upper metal sheet 7 insertion elements 35 lower metal sheet 9 cavity 36 first layer of reinforced fibers 11 dipping rim 37 second layer of reinforced 12 residue of blowing agent fibers 13 net 38 third layer of reinforced 14 injection nozzle, spraying unit fibers matrix material spherically 39 reflux of plastics melting deformed 40 textile rear injection 17 injection unit/device molding 19 fiber reinforced plastic 41 surrounding plastics layer blisters injection needle 42 external injection needle 21 extruded multi-layer 43 inner injection needle hose 44 gas-creating substance 22 axis of the nozzle 45 low-melting epoxy 23 slide 46 film coating 28 pre-form for blow-
Claims (8)
1. A process for manufacturing lightweight molded articles comprising the steps of:
a) providing first and second mold halves with at least one mold half movable relative to the other towards a closed position whereat a mold cavity is produced to define the external shape of the article;
b) providing a matrix layer adjacent one of said mold halves, said matrix layer selected from a molding material group consisting of plastics, cellulose, pulp and wood fiber;
c) positioning a discrete, macro sized insert at a plurality of set locations on said matrix layer, each insert containing a substance that creates gas when activated;
d) causing a molding material to be positioned between said mold halves and said insert when said mold halves have been moved into a position adjacent one another so that said inserts are in said mold halves and said molding material is between said mold halves and said inserts while said article is molded into a shape; and, e) activating said substance to create gas and moving said mold halves away from one another in a controlled manner to a set position whereat said gas can expand to form at each position of an insert an internal macro sized gas cavity whereby a configured hollow molded article is produced.
a) providing first and second mold halves with at least one mold half movable relative to the other towards a closed position whereat a mold cavity is produced to define the external shape of the article;
b) providing a matrix layer adjacent one of said mold halves, said matrix layer selected from a molding material group consisting of plastics, cellulose, pulp and wood fiber;
c) positioning a discrete, macro sized insert at a plurality of set locations on said matrix layer, each insert containing a substance that creates gas when activated;
d) causing a molding material to be positioned between said mold halves and said insert when said mold halves have been moved into a position adjacent one another so that said inserts are in said mold halves and said molding material is between said mold halves and said inserts while said article is molded into a shape; and, e) activating said substance to create gas and moving said mold halves away from one another in a controlled manner to a set position whereat said gas can expand to form at each position of an insert an internal macro sized gas cavity whereby a configured hollow molded article is produced.
2. The process of claim 1 wherein said substance is activated to produce gas by performing at least one step selected from the group consisting of i) pressurizing said insert, ii) changing the temperature of said insert;
iii) allowing a preset time to elapse;
iv) subjecting said insert to light of a set wavelength; and, v) reacting said substance with at least one chemical.
iii) allowing a preset time to elapse;
iv) subjecting said insert to light of a set wavelength; and, v) reacting said substance with at least one chemical.
3. The process of claim 2 wherein said matrix layer is a film positioned between said mold halves and said molding material is injected between said film and said mold halves with said mold halves at a set position whereupon said process sequentially i) activates said substance and ii) moves said mold halves away from one another to allow said gas cavities to form within said molded article.
4. The process of claim 2 wherein said matrix layer is a film type material to which said inserts are attached, said process further including the steps of providing said molding material as a molding material layer on each side of said matrix layer to form a sandwich; positioning said sandwich between said mold halves; moving said mold halves towards one another to press said sandwich into the configuration of said cavity while heating said mold; said pressing and heating step causing activation of said gas creating substance in said inserts; and, retracting said mold halves to allow said gas to expand within said mold halves.
5. The process of claim 2 wherein said process further including the step of providing a deformable layer on each side of said matrix layer between said mold halves so that two deformable layers exist, each deformable layer selected from the group consisting of, wood chip panels and sheet metal; heating said deformable layers and said matrix layer while pressing said deformable layers and said matrix layer into said mold cavity at an elevated temperature to cause said matrix layer to adhere to said deformable layers in an integral structure while activating said gas creating substance in said inserts whereupon said mold halves are retracted to allow said gas cavities to form by distending said matrix layer.
6. The process of claim 2 further including the steps of injecting a first layer of said molding material into one of said mold halves; causing said matrix layer to contact said first layer of molding material injected into said one mold half on one side of said matrix layer; injecting a second layer of molding material on the opposite exposed side of said matrix layer; causing said mold halves to move towards one another to press said first and second molding material layers and said matrix layer in a heated state into the configuration of said mold cavity whereupon activation of said substance occurs and thereupon moving said mold halves away from one another to allow said gas to expand and produce internal gas cavities.
7. The process according to any one of claims 3 through 6 further including the step of forming a sealed rim between that portion of the molded article positioned in one mold half and that portion of the molded article in the other mold half to form a sealed article whereby said gas remains in said gas cavities.
8. The process of claim 7 wherein said insert at said plurality of set positions results in a plurality of insets, said plurality of inserts having smaller pluralities of differently sized inserts shaped and positioned on said matrix in a regularly repeating pattern to produce said hollow configuration in patterns including egg crate and honeycombed patterns.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT128497 | 1997-07-29 | ||
| ATA1284/97 | 1997-07-29 | ||
| PCT/DE1998/002205 WO1999006200A1 (en) | 1997-07-29 | 1998-07-29 | Process for manufacturing moulded articles made of plastics, cellulose or wood pulp and provided with cavities |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2297934A1 CA2297934A1 (en) | 1999-02-11 |
| CA2297934C true CA2297934C (en) | 2007-12-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002297934A Expired - Fee Related CA2297934C (en) | 1997-07-29 | 1998-07-29 | Process for manufacturing moulded articles made of plastics, cellulose or wood pulp and provided with cavities |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6447627B1 (en) |
| EP (1) | EP1009608A1 (en) |
| JP (1) | JP2001512059A (en) |
| AU (1) | AU9337498A (en) |
| CA (1) | CA2297934C (en) |
| DE (1) | DE19881053D2 (en) |
| WO (1) | WO1999006200A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6415583B1 (en) * | 1999-02-25 | 2002-07-09 | Supracor, Inc. | Saddle pad |
| JP2002340280A (en) * | 2001-05-18 | 2002-11-27 | Jamco Corp | Vacuum insulating block |
| DE10340608A1 (en) * | 2003-08-29 | 2005-03-24 | Infineon Technologies Ag | Polymer formulation and method of making a dielectric layer |
| WO2006080833A1 (en) * | 2005-01-31 | 2006-08-03 | Fits Holding Bv | Method of manufacturing a sandwich panel and a sandwich panel as such |
| US20100178182A1 (en) * | 2009-01-09 | 2010-07-15 | Simmons Tom M | Helical bellows, pump including same and method of bellows fabrication |
| US8636484B2 (en) * | 2009-01-09 | 2014-01-28 | Tom M. Simmons | Bellows plungers having one or more helically extending features, pumps including such bellows plungers, and related methods |
| WO2011035352A1 (en) | 2009-09-24 | 2011-03-31 | Siegfried Berghammer | Insulating molded part and method for the production thereof |
| US8361266B2 (en) * | 2010-11-15 | 2013-01-29 | Colchiesqui Alexandre Viana | Layered molding process for producing three dimensional objects |
| AT516767B1 (en) * | 2015-01-22 | 2017-01-15 | Profeta Da Silva Alois | Process for producing a fiber-matrix semifinished product |
| WO2018028791A1 (en) * | 2016-08-11 | 2018-02-15 | LIEMT, Rainer | Method for producing a fibre matrix semi-finished product |
| CA3045029C (en) | 2017-04-24 | 2023-12-05 | Rigidcore Group Llc | Sheet material, mold, and methods of making and using the sheet material and mold |
| DE102018203726A1 (en) * | 2018-03-13 | 2019-09-19 | Bayerische Motoren Werke Aktiengesellschaft | Method for producing a sandwich component |
| US11325281B2 (en) | 2018-07-23 | 2022-05-10 | Ut-Battelle, Llc | Rapid manufacturing of tailored preforms |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3615972A (en) * | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US4247586A (en) * | 1979-07-16 | 1981-01-27 | Morris Rochlin | Noise reducing liner panels for vehicles |
| SE439599B (en) * | 1981-01-14 | 1985-06-24 | Kema Nord Ab | WAY TO DRY AND EXPAND IN LIQUID DISPERSED, THERMOPLASTIC MICROSPHERES CONTAINING, VOLTABLE, LIQUID JEWELERY |
| EP0135798B1 (en) | 1983-09-03 | 1989-03-15 | MASCHINENFABRIK HENNECKE GmbH | Multiple nozzle bringing together at least two free-flowing reactants for the preparation of a free-flowing reaction mixture which reacts into plastic, in particular into foamed plastic |
| US4843104A (en) * | 1987-03-19 | 1989-06-27 | Pierce & Stevens | Syntactic polymer foam compositions containing microsphere fillers |
| JPH02178012A (en) | 1988-12-29 | 1990-07-11 | Nissei Plastics Ind Co | Injection mold assembly |
| US5244613A (en) * | 1993-01-21 | 1993-09-14 | Miles Inc. | Process for the production of reinforced moldings and the resultant products |
| EP0679501A1 (en) | 1994-03-14 | 1995-11-02 | YMOS AKTIENGESELLSCHAFT Industrieprodukte | Composite material with foamable core |
| JPH106363A (en) | 1996-06-21 | 1998-01-13 | Sunstar Inc | Injection molding machine |
-
1998
- 1998-07-29 DE DE19881053T patent/DE19881053D2/en not_active Expired - Fee Related
- 1998-07-29 JP JP2000504992A patent/JP2001512059A/en not_active Ceased
- 1998-07-29 CA CA002297934A patent/CA2297934C/en not_active Expired - Fee Related
- 1998-07-29 WO PCT/DE1998/002205 patent/WO1999006200A1/en not_active Application Discontinuation
- 1998-07-29 EP EP98946251A patent/EP1009608A1/en not_active Withdrawn
- 1998-07-29 AU AU93374/98A patent/AU9337498A/en not_active Abandoned
- 1998-07-29 US US09/462,196 patent/US6447627B1/en not_active Expired - Fee Related
-
2002
- 2002-06-07 US US10/164,547 patent/US6875298B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20020157758A1 (en) | 2002-10-31 |
| DE19881053D2 (en) | 2000-07-06 |
| AU9337498A (en) | 1999-02-22 |
| US6875298B2 (en) | 2005-04-05 |
| WO1999006200A1 (en) | 1999-02-11 |
| EP1009608A1 (en) | 2000-06-21 |
| US6447627B1 (en) | 2002-09-10 |
| JP2001512059A (en) | 2001-08-21 |
| CA2297934A1 (en) | 1999-02-11 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |