CA2344170A1 - Bridged metal complexes - Google Patents

Bridged metal complexes Download PDF

Info

Publication number
CA2344170A1
CA2344170A1 CA002344170A CA2344170A CA2344170A1 CA 2344170 A1 CA2344170 A1 CA 2344170A1 CA 002344170 A CA002344170 A CA 002344170A CA 2344170 A CA2344170 A CA 2344170A CA 2344170 A1 CA2344170 A1 CA 2344170A1
Authority
CA
Canada
Prior art keywords
metal complexes
group
bridged metal
bridged
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002344170A
Other languages
French (fr)
Other versions
CA2344170C (en
Inventor
Arthur J. Ashe, Iii
David D. Devore
Xinggao Fang
D. Patrick Green
Kevin A. Frazier
Jasson T. Patton
Francis J. Timmers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
University of Michigan
Original Assignee
The Dow Chemical Company
Arthur J. Ashe, Iii
David D. Devore
Xinggao Fang
D. Patrick Green
Kevin A. Frazier
Jasson T. Patton
Francis J. Timmers
The Regents Of The University Of Michigan
D. Patrick Green
Arthur J. Ashe, Iii
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company, Arthur J. Ashe, Iii, David D. Devore, Xinggao Fang, D. Patrick Green, Kevin A. Frazier, Jasson T. Patton, Francis J. Timmers, The Regents Of The University Of Michigan, D. Patrick Green, Arthur J. Ashe, Iii filed Critical The Dow Chemical Company
Publication of CA2344170A1 publication Critical patent/CA2344170A1/en
Application granted granted Critical
Publication of CA2344170C publication Critical patent/CA2344170C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/12—Long bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is composed of at least two atoms which are not part of a cycle and which are not an ethylene bridge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

A Group 4 transition metal complex containing a boron or aluminum bridging group containing a nitrogen containing electron donating group, especially an amido group.
CA002344170A 1998-10-08 1999-09-08 Bridged metal complexes Expired - Fee Related CA2344170C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10351198P 1998-10-08 1998-10-08
US60/103,511 1998-10-08
US38399699A 1999-08-26 1999-08-26
US09/383,996 1999-08-26
PCT/US1999/020538 WO2000020426A1 (en) 1998-10-08 1999-09-08 Bridged metal complexes

Publications (2)

Publication Number Publication Date
CA2344170A1 true CA2344170A1 (en) 2000-04-13
CA2344170C CA2344170C (en) 2009-02-24

Family

ID=26800547

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002344170A Expired - Fee Related CA2344170C (en) 1998-10-08 1999-09-08 Bridged metal complexes

Country Status (18)

Country Link
US (2) US6376406B1 (en)
EP (1) EP1119575B1 (en)
JP (1) JP2002526548A (en)
KR (1) KR100628614B1 (en)
CN (1) CN1192033C (en)
AR (1) AR023334A1 (en)
AT (1) ATE248849T1 (en)
AU (1) AU774455B2 (en)
BR (1) BR9914771A (en)
CA (1) CA2344170C (en)
DE (1) DE69911041T2 (en)
ES (1) ES2205876T3 (en)
HU (1) HUP0104654A3 (en)
ID (1) ID29854A (en)
NO (1) NO994875L (en)
PL (1) PL347324A1 (en)
TW (1) TW523519B (en)
WO (1) WO2000020426A1 (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6489261B1 (en) * 1997-12-01 2002-12-03 Dsm N.V. Catalyst composition comprising a reduced transition metal complex and a cocatalyst
US6500949B2 (en) * 1998-10-08 2002-12-31 Dow Global Technologies Inc. Bridged metal complexes
DE19858016A1 (en) 1998-12-16 2000-06-21 Basf Ag New metallocene complexes
EP1230279A2 (en) * 1999-04-20 2002-08-14 BP Chemicals Limited Delayed activity supported olefin polymerization catalyst compositions and method for making and using the same
DE60128990T2 (en) * 2000-03-14 2008-02-28 Denki Kagaku Kogyo K.K. TRANSITION METAL CALCULATOR COMPONENTS FOR POLYMERIZATION AND METHOD FOR POLYMER MANUFACTURING USE THEREOF
US6891004B2 (en) 2000-03-14 2005-05-10 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, and method for producing a polymer by means thereof
US6627573B2 (en) 2000-07-20 2003-09-30 The Dow Chemical Company Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
WO2002028921A1 (en) * 2000-10-04 2002-04-11 The Dow Chemical Company Supported catalyst compositions
AU2001290910A1 (en) * 2000-10-24 2002-05-06 Dow Global Technologies Inc. Bridged ylide group containing metal complexes
US6544918B1 (en) * 2001-07-17 2003-04-08 Equistar Chemicals, Lp Olefin polymerization catalysts containing chelating dianionic ligands
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
EP1428840A4 (en) * 2001-08-07 2005-04-06 Denki Kagaku Kogyo Kk Process for producing polymer
DE10158656A1 (en) * 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organo transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for making polyolefins
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
WO2003087114A1 (en) * 2002-04-12 2003-10-23 Dow Global Technologies Inc. Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US20060089253A1 (en) 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
JP2005536566A (en) * 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング Monocyclopentadienyl complex
DE602005017243D1 (en) * 2004-01-28 2009-12-03 Idemitsu Kosan Co INPOLYMERISIERUNG
WO2006007094A2 (en) 2004-06-16 2006-01-19 Dow Global Technologies Inc. Technique for selecting polymerization modifiers
EP2270091B1 (en) 2008-04-15 2014-07-30 Denki Kagaku Kogyo Kabushiki Kaisha Thermoplastic resin composition
EP2336205A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
EP2336204A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand
US20110206857A1 (en) * 2010-02-25 2011-08-25 Applied Materials, Inc. Ultra low dielectric materials using hybrid precursors containing silicon with organic functional groups by plasma-enhanced chemical vapor deposition
EP3071609B1 (en) * 2013-11-19 2018-01-31 Chevron Phillips Chemical Company LP Catalyst systems containing boron-bridged cyclopentadienyl-fluorenyl metallocene compounds with an alkenyl substituent
US10125207B2 (en) 2014-04-03 2018-11-13 Denka Company Limited Cross-copolymer, and resin composition
US10005858B2 (en) * 2014-09-10 2018-06-26 Sabic Global Technologies B.V. Boron-bridged 2-indenyl metallocene complexes for olefin polymerization
KR20180061227A (en) 2015-09-28 2018-06-07 덴카 주식회사 Cross-copolymer and method for producing the same
CN108884196B (en) * 2016-03-31 2021-06-18 陶氏环球技术有限责任公司 Olefin polymerization catalyst system and method of using same
KR20210076701A (en) 2019-12-16 2021-06-24 현대자동차주식회사 EPDM for fuel cell and manufacturing method thereof
CN111449414A (en) 2020-03-31 2020-07-28 浙江捷昌线性驱动科技股份有限公司 Multifunctional hand controller for height-adjustable furniture

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
JP3423378B2 (en) * 1993-11-12 2003-07-07 三井化学株式会社 Novel transition metal compound, olefin polymerization catalyst component comprising the transition metal compound, olefin polymerization catalyst containing the olefin polymerization catalyst component, and olefin polymerization method
US5707913A (en) * 1994-06-15 1998-01-13 Basf Aktiengesellschaft Amidinato catalyst systems for the polymerization of olefins
DE69600841T2 (en) * 1995-03-08 1999-03-18 Shell Int Research BRIDGED TO AMIDO COMPOUNDS OF A GROUP IV METAL IN A CATALYTIC COMPOSITION
DE19539650A1 (en) * 1995-10-25 1997-04-30 Studiengesellschaft Kohle Mbh Zirconocenes and hafnocenes with borylated cyclopentadienyl ligands and the process for their preparation
DE19616523A1 (en) * 1996-04-25 1997-11-06 Basf Ag Polymerization catalysts with beta-diketiminate ligands
DE19622271A1 (en) * 1996-06-03 1997-12-04 Basf Ag Chiral connections
DE19624581C2 (en) * 1996-06-20 1999-02-04 Targor Gmbh Transition metal compound and a process for their preparation, and their use
DE19709486A1 (en) * 1997-03-07 1998-09-10 Studiengesellschaft Kohle Mbh Processes and catalysts for the stereospecific polymerization of olefins with chiral half-sandwich metallocene catalysts
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
UA57864C2 (en) * 1998-10-08 2003-07-15 Бп Кемікалз Лімітед A PROCESS FOR POLYMERIZATION OF OLEFINS USING bridging metal complexes

Also Published As

Publication number Publication date
AR023334A1 (en) 2002-09-04
PL347324A1 (en) 2002-03-25
CA2344170C (en) 2009-02-24
TW523519B (en) 2003-03-11
ID29854A (en) 2001-10-18
AU774455B2 (en) 2004-06-24
ES2205876T3 (en) 2004-05-01
HUP0104654A3 (en) 2003-08-28
EP1119575A1 (en) 2001-08-01
EP1119575B1 (en) 2003-09-03
WO2000020426A1 (en) 2000-04-13
BR9914771A (en) 2001-07-03
KR20010085884A (en) 2001-09-07
DE69911041D1 (en) 2003-10-09
ATE248849T1 (en) 2003-09-15
HUP0104654A2 (en) 2002-03-28
US6376406B1 (en) 2002-04-23
KR100628614B1 (en) 2006-09-26
NO994875L (en) 2000-04-10
DE69911041T2 (en) 2004-07-08
JP2002526548A (en) 2002-08-20
NO994875D0 (en) 1999-10-07
CN1322208A (en) 2001-11-14
AU5706099A (en) 2000-04-26
US6284905B1 (en) 2001-09-04
CN1192033C (en) 2005-03-09

Similar Documents

Publication Publication Date Title
CA2344170A1 (en) Bridged metal complexes
WO2000020462A3 (en) Bridged metal complexes for gas phase polymerizations
AU1773901A (en) Substituted group 4 metal complexes, catalysts and olefin polymerization process
EP0629631A3 (en) Novel transition metal compound, and polymerization catalyst containing it.
CA2330450A1 (en) Microbicide for detergents
AU3038797A (en) Novel group iv metal complexes
EP0629632A3 (en) Novel transition metal compound for use as a polymerization catalyst.
WO1999064047A8 (en) Novel antiviral compounds
AU1103100A (en) Catalyst ligands, catalytic metal complexes and processes using same
ZA996443B (en) A nitrogen oxide storage catalyst.
EP0648519A3 (en) Evaporator flask for a rotary evaporator.
AU4900999A (en) Press, especially a continuous press
HK1022795A1 (en) An architecture for multi-sector base stations.
AU4932999A (en) Mu-oxobismetallocene complexes, catalyst for olefin polymerization containing the same, and polymerization method
ZA9710797B (en) High coating weight iron phosphating, compositions therefor, and use of the coating formed as a lubricant carrier.
ZA988B (en) 3-aminocarbonyl-/3-aminothiocarbonyl-substituted 2-benzoylcyclohexane-1,3-diones.
MY135908A (en) Bridged metal complexes
AU9154398A (en) Catalysts based on fulvene metal complexes
AU8533898A (en) Attachment for an industrial truck, and an industrial truck
AU1146899A (en) Load-carrying crane, especially a container-carrying crane
ZA200006725B (en) Novel furylphosphines and organometallic complexes containing them.
AU8637798A (en) Novel transition metal complexes
AU4614699A (en) Water-soluble transition metal complexes
AU1988200A (en) Metal complexes useful as polymerization catalyst
ZA996246B (en) Bridged metal complexes for gas phase polymerizations.

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20140909