CA2344170A1 - Bridged metal complexes - Google Patents

Bridged metal complexes Download PDF

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Publication number
CA2344170A1
CA2344170A1 CA002344170A CA2344170A CA2344170A1 CA 2344170 A1 CA2344170 A1 CA 2344170A1 CA 002344170 A CA002344170 A CA 002344170A CA 2344170 A CA2344170 A CA 2344170A CA 2344170 A1 CA2344170 A1 CA 2344170A1
Authority
CA
Canada
Prior art keywords
metal complexes
group
bridged metal
bridged
boron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002344170A
Other languages
French (fr)
Other versions
CA2344170C (en
Inventor
Arthur J. Ashe, Iii
David D. Devore
Xinggao Fang
D. Patrick Green
Kevin A. Frazier
Jasson T. Patton
Francis J. Timmers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
University of Michigan
Original Assignee
The Dow Chemical Company
Arthur J. Ashe, Iii
David D. Devore
Xinggao Fang
D. Patrick Green
Kevin A. Frazier
Jasson T. Patton
Francis J. Timmers
The Regents Of The University Of Michigan
D. Patrick Green
Arthur J. Ashe, Iii
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company, Arthur J. Ashe, Iii, David D. Devore, Xinggao Fang, D. Patrick Green, Kevin A. Frazier, Jasson T. Patton, Francis J. Timmers, The Regents Of The University Of Michigan, D. Patrick Green, Arthur J. Ashe, Iii filed Critical The Dow Chemical Company
Publication of CA2344170A1 publication Critical patent/CA2344170A1/en
Application granted granted Critical
Publication of CA2344170C publication Critical patent/CA2344170C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/10—Heteroatom-substituted bridge, i.e. Cp or analog where the bridge linking the two Cps or analogs is substituted by at least one group that contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/12—Long bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is composed of at least two atoms which are not part of a cycle and which are not an ethylene bridge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Abstract

A Group 4 transition metal complex containing a boron or aluminum bridging group containing a nitrogen containing electron donating group, especially an amido group.
CA002344170A 1998-10-08 1999-09-08 Bridged metal complexes Expired - Fee Related CA2344170C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10351198P 1998-10-08 1998-10-08
US60/103,511 1998-10-08
US38399699A 1999-08-26 1999-08-26
US09/383,996 1999-08-26
PCT/US1999/020538 WO2000020426A1 (en) 1998-10-08 1999-09-08 Bridged metal complexes

Publications (2)

Publication Number Publication Date
CA2344170A1 true CA2344170A1 (en) 2000-04-13
CA2344170C CA2344170C (en) 2009-02-24

Family

ID=26800547

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002344170A Expired - Fee Related CA2344170C (en) 1998-10-08 1999-09-08 Bridged metal complexes

Country Status (18)

Country Link
US (2) US6376406B1 (en)
EP (1) EP1119575B1 (en)
JP (1) JP2002526548A (en)
KR (1) KR100628614B1 (en)
CN (1) CN1192033C (en)
AR (1) AR023334A1 (en)
AT (1) ATE248849T1 (en)
AU (1) AU774455B2 (en)
BR (1) BR9914771A (en)
CA (1) CA2344170C (en)
DE (1) DE69911041T2 (en)
ES (1) ES2205876T3 (en)
HU (1) HUP0104654A3 (en)
ID (1) ID29854A (en)
NO (1) NO994875L (en)
PL (1) PL347324A1 (en)
TW (1) TW523519B (en)
WO (1) WO2000020426A1 (en)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6489261B1 (en) * 1997-12-01 2002-12-03 Dsm N.V. Catalyst composition comprising a reduced transition metal complex and a cocatalyst
US6500949B2 (en) * 1998-10-08 2002-12-31 Dow Global Technologies Inc. Bridged metal complexes
DE19858016A1 (en) 1998-12-16 2000-06-21 Basf Ag New metallocene complexes
CN1357012A (en) * 1999-04-20 2002-07-03 英国石油化学品有限公司 Delayed activity supported olefin polymerization, catalyst compsns. and method for making and using same
JP4819279B2 (en) * 2000-03-14 2011-11-24 電気化学工業株式会社 Transition metal catalyst component for polymerization and method for producing polymer using the same
US6891004B2 (en) 2000-03-14 2005-05-10 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, and method for producing a polymer by means thereof
WO2002008303A1 (en) 2000-07-20 2002-01-31 The Dow Chemical Company Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom
US20020072577A1 (en) * 2000-10-04 2002-06-13 The Dow Chemical Company Supported catalyst compositions
EP1328533A1 (en) * 2000-10-24 2003-07-23 Dow Global Technologies Inc. Bridged ylide group containing metal complexes
US6544918B1 (en) * 2001-07-17 2003-04-08 Equistar Chemicals, Lp Olefin polymerization catalysts containing chelating dianionic ligands
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
EP1428840A4 (en) * 2001-08-07 2005-04-06 Denki Kagaku Kogyo Kk Process for producing polymer
DE10158656A1 (en) 2001-11-30 2003-06-26 Basell Polyolefine Gmbh Organo transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for making polyolefins
US6703338B2 (en) * 2002-06-28 2004-03-09 Univation Technologies, Llc Polymerization catalyst activators, method of preparing, and their use in polymerization processes
EP1495038B1 (en) * 2002-04-12 2008-07-23 Dow Global Technologies Inc. Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
US20060089253A1 (en) 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
JP2005536566A (en) 2002-08-22 2005-12-02 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング Monocyclopentadienyl complex
ATE446304T1 (en) * 2004-01-28 2009-11-15 Idemitsu Kosan Co TRANSITION METAL COMPOUND AND CATALYST FOR OLEFIN POLYMERIZATION
EP1763542B1 (en) 2004-06-16 2011-04-06 Dow Global Technologies Inc. Technique for selecting polymerization modifiers
US8461264B2 (en) 2008-04-15 2013-06-11 Denki Kagaku Kogyo Kabushiki Kaisha Thermoplastic resin composition
EP2336205A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
EP2336204A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand
US20110206857A1 (en) * 2010-02-25 2011-08-25 Applied Materials, Inc. Ultra low dielectric materials using hybrid precursors containing silicon with organic functional groups by plasma-enhanced chemical vapor deposition
ES2665432T3 (en) * 2013-11-19 2018-04-25 Chevron Phillips Chemical Company Lp Catalyst systems containing cyclopentadienyl fluorenyl metallocene compounds with boron bridge with an alkenyl substituent
JP6622186B2 (en) 2014-04-03 2019-12-18 デンカ株式会社 Cross copolymer and resin composition
CN106715450B (en) * 2014-09-10 2019-10-22 Sabic环球技术有限责任公司 The 2- indenyl metallocene complex of boron bridging for olefinic polymerization
DE112016004386T5 (en) 2015-09-28 2018-06-07 Denka Company Limited Cross-copolymers and method of preparation thereof
EP3436486B1 (en) * 2016-03-31 2020-08-05 Dow Global Technologies LLC Olefin polymerization catalyst systems and methods of use thereof
KR20210076701A (en) 2019-12-16 2021-06-24 현대자동차주식회사 EPDM for fuel cell and manufacturing method thereof
CN111449414A (en) 2020-03-31 2020-07-28 浙江捷昌线性驱动科技股份有限公司 Multifunctional hand controller for height-adjustable furniture

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
JP3423378B2 (en) * 1993-11-12 2003-07-07 三井化学株式会社 Novel transition metal compound, olefin polymerization catalyst component comprising the transition metal compound, olefin polymerization catalyst containing the olefin polymerization catalyst component, and olefin polymerization method
US5707913A (en) * 1994-06-15 1998-01-13 Basf Aktiengesellschaft Amidinato catalyst systems for the polymerization of olefins
AU688674B2 (en) * 1995-03-08 1998-03-12 Shell Internationale Research Maatschappij B.V. Bridged bis-amido group 4 metal compounds in a catalyst composition
DE19539650A1 (en) * 1995-10-25 1997-04-30 Studiengesellschaft Kohle Mbh Zirconocenes and hafnocenes with borylated cyclopentadienyl ligands and the process for their preparation
DE19616523A1 (en) * 1996-04-25 1997-11-06 Basf Ag Polymerization catalysts with beta-diketiminate ligands
DE19622271A1 (en) * 1996-06-03 1997-12-04 Basf Ag Chiral connections
DE19624581C2 (en) * 1996-06-20 1999-02-04 Targor Gmbh Transition metal compound and a process for their preparation, and their use
DE19709486A1 (en) * 1997-03-07 1998-09-10 Studiengesellschaft Kohle Mbh Processes and catalysts for the stereospecific polymerization of olefins with chiral half-sandwich metallocene catalysts
US5777120A (en) * 1997-03-14 1998-07-07 University Of Iowa Research Foundation Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts
UA57864C2 (en) * 1998-10-08 2003-07-15 Бп Кемікалз Лімітед A PROCESS FOR POLYMERIZATION OF OLEFINS USING bridging metal complexes

Also Published As

Publication number Publication date
KR100628614B1 (en) 2006-09-26
CA2344170C (en) 2009-02-24
KR20010085884A (en) 2001-09-07
ATE248849T1 (en) 2003-09-15
NO994875D0 (en) 1999-10-07
CN1192033C (en) 2005-03-09
BR9914771A (en) 2001-07-03
EP1119575A1 (en) 2001-08-01
ID29854A (en) 2001-10-18
DE69911041D1 (en) 2003-10-09
AU5706099A (en) 2000-04-26
NO994875L (en) 2000-04-10
CN1322208A (en) 2001-11-14
US6376406B1 (en) 2002-04-23
AR023334A1 (en) 2002-09-04
ES2205876T3 (en) 2004-05-01
EP1119575B1 (en) 2003-09-03
AU774455B2 (en) 2004-06-24
WO2000020426A1 (en) 2000-04-13
DE69911041T2 (en) 2004-07-08
HUP0104654A3 (en) 2003-08-28
JP2002526548A (en) 2002-08-20
PL347324A1 (en) 2002-03-25
HUP0104654A2 (en) 2002-03-28
US6284905B1 (en) 2001-09-04
TW523519B (en) 2003-03-11

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