CA2423657A1 - Highly durable hydrophobic coatings and methods - Google Patents
Highly durable hydrophobic coatings and methods Download PDFInfo
- Publication number
- CA2423657A1 CA2423657A1 CA002423657A CA2423657A CA2423657A1 CA 2423657 A1 CA2423657 A1 CA 2423657A1 CA 002423657 A CA002423657 A CA 002423657A CA 2423657 A CA2423657 A CA 2423657A CA 2423657 A1 CA2423657 A1 CA 2423657A1
- Authority
- CA
- Canada
- Prior art keywords
- silicon oxide
- anchor layer
- cross
- layer
- oxide anchor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
- B05D1/185—Processes for applying liquids or other fluent materials performed by dipping applying monomolecular layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/60—Deposition of organic layers from vapour phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Abstract
Substrates have a hydrophobic surface coating comprised of the reaction products of a chlorosilyl group containing compound and an alkylsilane. Most preferably the substrate is glass. In one embodiment, highly durable hydrophobic coatings may be formed by forming a silicon oxide anchor layer or hybrid organo-silicon oxide anchor layer from a humidified reaction product of silicon tetrachloride or trichloromethylsilane, followed by the vapor-deposition of a chloroalkylsilane. Such a silicon oxide anchor layer will advantageously have a root mean square surface roughness of less than about 6.0 nm and a low haze value of less than about 3.0 %. Another embodiment includes the simultaneous humidified vapor deposition of a chlorosilyl group containing compound and a chloroalkylsilane. In preferred embodiments, the simultaneous vapor deposition onto a glass substrate of silicon tetrachloride and dimethyldichlorosilane results in a hydrophobic coating comprised of cross-linked polydimethylsiloxane, which may then be capped with a fluoroalkylsilane. The cross-linked polydimethylsiloxane layer may be formed on the surface of the glass substrate, or a silicon oxide anchor layer may be deposited under the cross-linked polydimethylsiloxane layer.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US23633500P | 2000-09-29 | 2000-09-29 | |
US60/236,335 | 2000-09-29 | ||
US09/921,303 | 2001-08-03 | ||
US09/921,303 US6743516B2 (en) | 2000-09-29 | 2001-08-03 | Highly durable hydrophobic coatings and methods |
PCT/US2001/026691 WO2002028956A1 (en) | 2000-09-29 | 2001-08-28 | Highly durable hydrophobic coatings and methods |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2423657A1 true CA2423657A1 (en) | 2002-04-11 |
CA2423657C CA2423657C (en) | 2008-11-18 |
Family
ID=26929682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2423657 Expired - Fee Related CA2423657C (en) | 2000-09-29 | 2001-08-28 | Highly durable hydrophobic coatings and methods |
Country Status (8)
Country | Link |
---|---|
US (1) | US6743516B2 (en) |
EP (1) | EP1328579B1 (en) |
AT (1) | ATE549302T1 (en) |
AU (1) | AU2001286812A1 (en) |
CA (1) | CA2423657C (en) |
ES (1) | ES2384374T3 (en) |
PL (1) | PL200431B1 (en) |
WO (1) | WO2002028956A1 (en) |
Families Citing this family (65)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2378082B (en) * | 2001-07-26 | 2005-03-09 | Kh Technology Corp | Improvements in loudspeakers |
US20030161949A1 (en) * | 2002-02-28 | 2003-08-28 | The Regents Of The University Of California | Vapor deposition of dihalodialklysilanes |
EP1607748B1 (en) * | 2003-03-24 | 2013-05-15 | Sony Corporation | Nucleic acid extracting kit, and nucleic acid extracting method |
US20080073512A1 (en) * | 2003-06-06 | 2008-03-27 | Waters Investments Limited | Methods, compositions and devices for performing ionization desorption on silicon derivatives |
WO2004113456A2 (en) | 2003-06-23 | 2004-12-29 | University Of Zurich | Superhydrophobic coating |
US20050271893A1 (en) * | 2004-06-04 | 2005-12-08 | Applied Microstructures, Inc. | Controlled vapor deposition of multilayered coatings adhered by an oxide layer |
US20040261703A1 (en) | 2003-06-27 | 2004-12-30 | Jeffrey D. Chinn | Apparatus and method for controlled application of reactive vapors to produce thin films and coatings |
US7638167B2 (en) * | 2004-06-04 | 2009-12-29 | Applied Microstructures, Inc. | Controlled deposition of silicon-containing coatings adhered by an oxide layer |
US9725805B2 (en) * | 2003-06-27 | 2017-08-08 | Spts Technologies Limited | Apparatus and method for controlled application of reactive vapors to produce thin films and coatings |
US7138186B2 (en) * | 2004-02-05 | 2006-11-21 | Guardian Industries Corp. | Hydrophobic coatings and methods |
FR2866643B1 (en) * | 2004-02-24 | 2006-05-26 | Saint Gobain | SUBSTRATE, ESPECIALLY GLASS, WITH A HYDROPHOBIC SURFACE, WITH IMPROVED DURABILITY OF HYDROPHOBIC PROPERTIES |
US7742322B2 (en) | 2005-01-07 | 2010-06-22 | Invisage Technologies, Inc. | Electronic and optoelectronic devices with quantum dot films |
US7746681B2 (en) | 2005-01-07 | 2010-06-29 | Invisage Technologies, Inc. | Methods of making quantum dot films |
US7773404B2 (en) | 2005-01-07 | 2010-08-10 | Invisage Technologies, Inc. | Quantum dot optical devices with enhanced gain and sensitivity and methods of making same |
WO2005101530A1 (en) | 2004-04-19 | 2005-10-27 | Edward Sargent | Optically-regulated optical emission using colloidal quantum dot nanocrystals |
US7695775B2 (en) * | 2004-06-04 | 2010-04-13 | Applied Microstructures, Inc. | Controlled vapor deposition of biocompatible coatings over surface-treated substrates |
WO2005121397A2 (en) * | 2004-06-04 | 2005-12-22 | Applied Microstructures, Inc. | Controlled vapor deposition of multilayered coatings adhered by an oxide layer |
US7879396B2 (en) * | 2004-06-04 | 2011-02-01 | Applied Microstructures, Inc. | High aspect ratio performance coatings for biological microfluidics |
US20060251795A1 (en) * | 2005-05-05 | 2006-11-09 | Boris Kobrin | Controlled vapor deposition of biocompatible coatings for medical devices |
US20060029732A1 (en) * | 2004-08-04 | 2006-02-09 | Boris Kobrin | Vapor deposited functional organic coatings |
US8088440B2 (en) * | 2004-11-24 | 2012-01-03 | Guardian Industries Corp. | Hydrophobic coating including underlayer(s) deposited via flame pyrolysis |
CA2519608A1 (en) | 2005-01-07 | 2006-07-07 | Edward Sargent | Quantum dot-polymer nanocomposite photodetectors and photovoltaics |
US20070079965A1 (en) * | 2005-10-06 | 2007-04-12 | Halliburton Energy Services, Inc. | Methods for enhancing aqueous fluid recovery form subterranean formations |
US8067258B2 (en) | 2006-06-05 | 2011-11-29 | Applied Microstructures, Inc. | Protective thin films for use during fabrication of semiconductors, MEMS, and microstructures |
US8435719B2 (en) * | 2006-08-08 | 2013-05-07 | International Business Machines Corporation | Tunable contact angle process for immersionlithography topcoats and photoresists |
US8202614B2 (en) | 2006-08-09 | 2012-06-19 | Luna Innovations Incorporated | Additive particles having superhydrophobic characteristics and coatings and methods of making and using the same |
US7632543B2 (en) * | 2006-12-05 | 2009-12-15 | Guardian Industries Corp. | Method of making IG window unit and forming silicon oxide based hydrophilic coating using chlorosilane vapor deposition |
KR101270164B1 (en) * | 2006-12-27 | 2013-05-31 | 삼성디스플레이 주식회사 | Nozzle plate of inkjet printhead |
US8900695B2 (en) * | 2007-02-23 | 2014-12-02 | Applied Microstructures, Inc. | Durable conformal wear-resistant carbon-doped metal oxide-comprising coating |
US20080248263A1 (en) * | 2007-04-02 | 2008-10-09 | Applied Microstructures, Inc. | Method of creating super-hydrophobic and-or super-hydrophilic surfaces on substrates, and articles created thereby |
US8236379B2 (en) * | 2007-04-02 | 2012-08-07 | Applied Microstructures, Inc. | Articles with super-hydrophobic and-or super-hydrophilic surfaces and method of formation |
US20080315459A1 (en) * | 2007-06-21 | 2008-12-25 | 3M Innovative Properties Company | Articles and methods for replication of microstructures and nanofeatures |
US20090114618A1 (en) * | 2007-06-21 | 2009-05-07 | 3M Innovative Properties Company | Method of making hierarchical articles |
US20090041986A1 (en) * | 2007-06-21 | 2009-02-12 | 3M Innovative Properties Company | Method of making hierarchical articles |
EP2180910A2 (en) | 2007-07-20 | 2010-05-05 | Medingo Ltd. | Collapsible reservoir for use with a delivery device |
ITBO20070588A1 (en) * | 2007-08-13 | 2009-02-14 | Silicon Biosystems Spa | METHOD TO BOND A SILICON LAYER TO A METHACRYLIC POLYMER SUBSTRATE |
US7891636B2 (en) * | 2007-08-27 | 2011-02-22 | 3M Innovative Properties Company | Silicone mold and use thereof |
US20090143522A1 (en) * | 2007-12-04 | 2009-06-04 | Sea-Fue Wang | Thermally Conductive Silicone Composition |
EP3539577A1 (en) * | 2008-04-17 | 2019-09-18 | Dentsply IH AB | Improved medical device with hydrophilic coating |
US20090264316A1 (en) * | 2008-04-17 | 2009-10-22 | Marshall University Research Corporation | Ultraviolet/Ozone Patterned Organosilane Surfaces |
US20100028604A1 (en) * | 2008-08-01 | 2010-02-04 | The Ohio State University | Hierarchical structures for superhydrophobic surfaces and methods of making |
FR2940966B1 (en) * | 2009-01-09 | 2011-03-04 | Saint Gobain | HYDROPHOBIC SUBSTRATE COMPRISING A PLASMA ACTIVATED SILICON OXYCARBIDE PREMIUM |
BR112012002509A2 (en) * | 2009-08-03 | 2019-09-24 | Asahi Glass Co Ltd | water repellent film forming composition, water repellent film substrate and process for its production, and article for transport equipment |
US20150064376A1 (en) * | 2009-10-27 | 2015-03-05 | Silcotek Corp. | Coated automotive article |
EP2500009A1 (en) | 2011-03-17 | 2012-09-19 | 3M Innovative Properties Company | Dental ceramic article, process of production and use thereof |
US10077207B2 (en) | 2011-11-30 | 2018-09-18 | Corning Incorporated | Optical coating method, apparatus and product |
US9957609B2 (en) | 2011-11-30 | 2018-05-01 | Corning Incorporated | Process for making of glass articles with optical and easy-to-clean coatings |
TWI564409B (en) | 2011-11-30 | 2017-01-01 | 康寧公司 | Optical coating method, apparatus and product |
US8968831B2 (en) | 2011-12-06 | 2015-03-03 | Guardian Industries Corp. | Coated articles including anti-fingerprint and/or smudge-reducing coatings, and/or methods of making the same |
CN104321393A (en) * | 2012-02-28 | 2015-01-28 | 大金工业株式会社 | Process for producing article having fluorine-containing silane-based coating |
JP6346456B2 (en) * | 2013-02-22 | 2018-06-20 | 国立研究開発法人産業技術総合研究所 | Water / oil repellent coating and method for producing the same |
KR102195254B1 (en) | 2013-12-30 | 2020-12-28 | 삼성디스플레이 주식회사 | Manufacturing method for display device |
CN107109124B (en) | 2014-10-31 | 2021-07-09 | 住友化学株式会社 | Transparent coating film |
KR102553617B1 (en) | 2014-10-31 | 2023-07-07 | 스미또모 가가꾸 가부시키가이샤 | Transparent coating film |
KR102500899B1 (en) | 2014-10-31 | 2023-02-16 | 스미또모 가가꾸 가부시키가이샤 | Water-repellant/oil-repellant coating composition |
US10400137B2 (en) | 2014-11-12 | 2019-09-03 | Sumitomo Chemical Company, Limited | Water-repellant and oil-repellant coating composition and transparent film |
EP3064339A1 (en) | 2015-03-04 | 2016-09-07 | Matthias Schittmayer-Schantl | Use of a modified glass plate as a substrate for 3d printing |
US10293372B2 (en) * | 2015-09-18 | 2019-05-21 | International Business Machines Corporation | Pre-treating polymer tubing or hose with a hydrophobic coating to reduce depletion of corrosion inhibitor |
BR112018075724B1 (en) | 2016-06-15 | 2022-04-05 | Bemis Company, Inc | Heat-seal lid with non-heat-seal layer and hydrophobic wrap |
CN110997587B (en) | 2017-05-08 | 2022-07-26 | 康宁股份有限公司 | Glass, glass-ceramic and ceramic articles having durable lubricious anti-fingerprint coatings on optical and scratch-resistant coatings and methods of making same |
US11709156B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved analytical analysis |
US11709155B2 (en) | 2017-09-18 | 2023-07-25 | Waters Technologies Corporation | Use of vapor deposition coated flow paths for improved chromatography of metal interacting analytes |
US11918936B2 (en) | 2020-01-17 | 2024-03-05 | Waters Technologies Corporation | Performance and dynamic range for oligonucleotide bioanalysis through reduction of non specific binding |
WO2023086534A1 (en) * | 2021-11-11 | 2023-05-19 | Soliyarn, Llc | System, method and composition for producing liquid repellant materials |
DE102022108150B3 (en) | 2022-04-05 | 2023-04-27 | Technische Universität Ilmenau | Process and reactor configuration for the production of oxide or oxynitride layers |
Family Cites Families (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3637416A (en) * | 1970-02-04 | 1972-01-25 | Mbt Corp | Method of treating synthetic plastic and elastomeric materials and articles produced thereby |
US3808027A (en) * | 1972-03-29 | 1974-04-30 | Du Pont | Silica surfaced films |
US4166891A (en) | 1972-04-19 | 1979-09-04 | Elliott Stanley B | Visual-type hygrometer |
DE2559259A1 (en) | 1975-12-31 | 1977-07-14 | Dynamit Nobel Ag | SILANE WITH DISCONNECTED FUNCTIONAL GROUPS AS ADHESION MEDIA |
US4263371A (en) | 1978-10-25 | 1981-04-21 | Ppg Industries, Inc. | Organotin treatment for reducing the reactivity of a glass surface |
US4301197A (en) | 1979-12-03 | 1981-11-17 | Ppg Industries, Inc. | Siloxane release surfaces on glass |
US4263350A (en) | 1979-12-31 | 1981-04-21 | Ppg Industries, Inc. | Silane release surfaces on glass |
US4274856A (en) | 1979-12-31 | 1981-06-23 | Ppg Industries, Inc. | Method for developing a release surface on a glass mold |
US4478909A (en) | 1980-10-24 | 1984-10-23 | Toray Industries, Inc. | Anti-fogging coating film |
US4420578A (en) | 1980-11-10 | 1983-12-13 | Diversey Corporation | Surface treatment of glass containers |
US4472021A (en) | 1982-12-10 | 1984-09-18 | Desoto, Inc. | Strippable radiation-cured coatings for optical fiber and method |
US4567221A (en) | 1983-03-31 | 1986-01-28 | Kuraray Co., Ltd. | Water resistant compositions |
US4539061A (en) | 1983-09-07 | 1985-09-03 | Yeda Research And Development Co., Ltd. | Process for the production of built-up films by the stepwise adsorption of individual monolayers |
US4547432A (en) | 1984-07-31 | 1985-10-15 | The United States Of America As Represented By The United States Department Of Energy | Method of bonding silver to glass and mirrors produced according to this method |
US4711820A (en) | 1986-06-17 | 1987-12-08 | Petrarch Systems Inc. | Method of siliconization of surfaces with lower alkyl silanes |
US4753827A (en) | 1986-10-03 | 1988-06-28 | Ppg Industries, Inc. | Abrasion-resistant organosiloxane/metal oxide coating |
DE3706782A1 (en) | 1987-03-03 | 1988-09-15 | Daimler Benz Ag | USE OF ORGANIC SILICON COMPOUNDS ON GLASS WINDSHIELDS TO REACH AN ANTI-FOGGING EFFECT AGAINST OILY ORGANIC SUBSTANCES |
US4838946A (en) | 1988-05-28 | 1989-06-13 | Shin-Etsu Handotai Co., Ltd. | Absorbent of chlorosilane compound |
FR2635319B1 (en) | 1988-07-20 | 1992-07-24 | Saint Gobain Vitrage | GLAZING WITH AN ANTI-FROST LAYER |
US4946903A (en) | 1989-03-27 | 1990-08-07 | The Research Foundation Of State University Of Ny | Oxyfluoropolymers having chemically reactive surface functionality and increased surface energies |
JP2710069B2 (en) | 1989-06-06 | 1998-02-10 | 日本ユニカー株式会社 | Scratching agent for glass containers |
US5328768A (en) * | 1990-04-03 | 1994-07-12 | Ppg Industries, Inc. | Durable water repellant glass surface |
US5688864A (en) | 1990-04-03 | 1997-11-18 | Ppg Industries, Inc. | Autophobic water repellent surface treatment |
US4983459A (en) | 1990-04-03 | 1991-01-08 | Ppg Industries, Inc. | Chemically reacted glass surface |
US5308705A (en) | 1990-04-03 | 1994-05-03 | Ppg Industries, Inc. | Water repellent surface treatment |
US4997684A (en) | 1990-07-19 | 1991-03-05 | Ppg Industries, Inc. | Method of using perfluoroalkylsilanes to lower the surface energy of glass |
CA2022039A1 (en) | 1990-07-26 | 1992-01-27 | Julio O. Gun | Composition for producing a monomolecular film on the surfaces of various materials |
US5300239A (en) | 1990-08-24 | 1994-04-05 | Dow Corning Toray Silicone Co., Ltd. | Water-repellent and oil-repellent treatment |
EP0484746B1 (en) | 1990-10-25 | 1996-09-18 | Matsushita Electric Industrial Co., Ltd. | Chemically adsorbed monomolecular lamination film and method of manufacturing the same |
EP0514557B1 (en) * | 1990-11-21 | 1999-02-24 | Catalysts & Chemicals Industries Co., Ltd. | Coating solution for forming transparent electrically conductive film, method of preparation thereof, electrically conductive substrate, method of preparation thereof, and display device having transparent electrically conductive substrate |
EP0492545B1 (en) | 1990-12-25 | 1998-03-25 | Matsushita Electric Industrial Co., Ltd. | Transparent substrate with monomolecular film thereon and method of manufacturing the same |
EP0864622A3 (en) * | 1991-01-23 | 2000-04-26 | Matsushita Electric Industrial Co., Ltd | Water- and oil- repellant article |
CA2059733C (en) | 1991-01-23 | 1999-10-05 | Kazufumi Ogawa | Water- and oil-repelling film and method of manufacturing the same |
EP0499977B1 (en) | 1991-02-19 | 1995-12-20 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a chemically adsorbed film |
US5266715A (en) | 1991-03-06 | 1993-11-30 | Ciba-Geigy Corporation | Glass coating with improved adhesion and weather resistance |
EP0511548B1 (en) | 1991-04-30 | 1997-07-09 | Matsushita Electric Industrial Co., Ltd. | Chemically adsorbed film and method of manufacturing the same |
FR2680583B1 (en) | 1991-08-22 | 1993-10-08 | Commissariat A Energie Atomique | MATERIAL HAVING ANTI-REFLECTIVE, HYDROPHOBIC AND ABRASION RESISTANCE PROPERTIES AND METHOD FOR DEPOSITING AN ANTI-REFLECTIVE, HYDROPHOBIC AND ABRASION RESISTANT LAYER ON A SUBSTRATE. |
JPH0597478A (en) | 1991-10-04 | 1993-04-20 | Nippon Sheet Glass Co Ltd | Water repellent glass article and its production |
US5372851A (en) | 1991-12-16 | 1994-12-13 | Matsushita Electric Industrial Co., Ltd. | Method of manufacturing a chemically adsorbed film |
US5413865A (en) | 1992-01-31 | 1995-05-09 | Central Glass Company, Limited | Water-repellent metal oxide film and method of forming same on glass substrate |
US5368892A (en) | 1992-04-10 | 1994-11-29 | Saint-Gobain Vitrage International | Non-wettable glass sheet |
US5599625A (en) | 1992-06-17 | 1997-02-04 | Research Corporation Technologies, Inc. | Products having multiple-substituted polysiloxane monolayer |
US5873931A (en) | 1992-10-06 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
US5543171A (en) | 1992-12-14 | 1996-08-06 | Shores; A. Andrew | Process of manufacturing a coated article |
US5298587A (en) | 1992-12-21 | 1994-03-29 | The Dow Chemical Company | Protective film for articles and method |
US5435839A (en) | 1992-12-24 | 1995-07-25 | Matsushita Electric Industrial Co., Ltd. | Finishing agents and method of manufacturing the same |
JP2847605B2 (en) | 1993-03-23 | 1999-01-20 | 住友重機械工業株式会社 | Slow positron beam generator |
US5635291A (en) | 1993-04-28 | 1997-06-03 | Canon Kabushiki Kaisha | Ink-jet recording medium |
US5473037A (en) | 1993-08-18 | 1995-12-05 | Shin-Etsu Chemical Co. Ltd. | Method of producing dimethylpolysiloxanes |
US5463010A (en) | 1993-11-12 | 1995-10-31 | Surface Engineering Technologies, Division Of Innerdyne, Inc. | Hydrocyclosiloxane membrane prepared by plasma polymerization process |
TW275082B (en) | 1993-12-07 | 1996-05-01 | Shinetsu Chem Ind Co | |
US5383354A (en) * | 1993-12-27 | 1995-01-24 | Motorola, Inc. | Process for measuring surface topography using atomic force microscopy |
US5596061A (en) | 1993-12-28 | 1997-01-21 | Mona Industries, Inc. | Organosilicone having a carboxyl functional group thereon |
US5665424A (en) | 1994-03-11 | 1997-09-09 | Sherman; Dan | Method for making glass articles having a permanent protective coating |
US5723172A (en) | 1994-03-11 | 1998-03-03 | Dan Sherman | Method for forming a protective coating on glass |
JPH07316546A (en) | 1994-05-23 | 1995-12-05 | Matsushita Electric Ind Co Ltd | Water-repellent surface structure and method for forming the same |
US5584917A (en) | 1994-07-04 | 1996-12-17 | Taiho Industries Co., Ltd. | Water repellent for window panes of automobiles and method of repelling water on the window panes |
EP0696627B1 (en) | 1994-08-12 | 1999-01-27 | Shin-Etsu Chemical Co., Ltd. | Water repellent composition |
BE1008724A3 (en) | 1994-09-27 | 1996-07-02 | Couttenier Andre | COMPOSITION FOR PROTECTING WATER REPELLENT AND MAKING A siliceous substrate. |
US5763091A (en) * | 1994-10-27 | 1998-06-09 | Sumitomo Metal Mining Co., Ltd. | Electroconductive substrate and method for forming the same |
CA2168529A1 (en) * | 1995-02-02 | 1996-08-03 | Tatsuichiro Kon | Transparent conductive sheet |
US5605934A (en) | 1995-03-23 | 1997-02-25 | Baxter International Inc. | Method of manufacturing and storing solutions |
JP2810979B2 (en) | 1995-09-14 | 1998-10-15 | 工業技術院長 | Surface-hydrophobic activated carbon and its production method |
US5580606A (en) | 1995-10-06 | 1996-12-03 | Singapore Institute Of Standards Etc. | Method for forming interference anti-reflective coatings by plasma surface modification |
TW422822B (en) | 1996-04-04 | 2001-02-21 | Matsushita Electric Ind Co Ltd | Contamination-resistant float glass and process for producing the same as well as cooking device using said contamination-resistant float glass |
US5691011A (en) * | 1996-06-14 | 1997-11-25 | The Dow Chemical Company | Dispersion-preventing pattern for liquid crystal display device |
DE69709800T2 (en) | 1996-08-19 | 2002-09-26 | Central Glass Co Ltd | Water-repellent glass pane and process for its manufacture |
US5841931A (en) * | 1996-11-26 | 1998-11-24 | Massachusetts Institute Of Technology | Methods of forming polycrystalline semiconductor waveguides for optoelectronic integrated circuits, and devices formed thereby |
WO1998025761A1 (en) | 1996-12-09 | 1998-06-18 | Nippon Sheet Glass Co., Ltd. | Non-fogging article and process for the production thereof |
FR2757871B1 (en) | 1996-12-27 | 1999-03-26 | Aerospatiale | WATERPROOFING COMPOSITION COMPRISING A HYDROPHOBIC AGENT AND A SOLVENT, APPLICATION FOR THE REMOVAL OF SURFACE WATER IN PARTICULAR FROM WINDSCREENS OF VEHICLES OR AIRCRAFT |
JP4447660B2 (en) | 1997-04-04 | 2010-04-07 | エボニック デグサ ゲーエムベーハー | Method for producing surface-sealed hollow glass container |
US6363749B1 (en) | 1997-04-04 | 2002-04-02 | Degussa Ag | Process for manufacturing surface-sealed hollow glass containers |
US5851674A (en) | 1997-07-30 | 1998-12-22 | Minnesota Mining And Manufacturing Company | Antisoiling coatings for antireflective surfaces and methods of preparation |
US5919296A (en) | 1998-03-30 | 1999-07-06 | Dow Corning Corporation | Storage-stable water-repellent composition for masonry materials |
US20020001676A1 (en) | 1998-11-03 | 2002-01-03 | Don Hayden | Capped silicone film and method of manufacture thereof |
US6245387B1 (en) | 1998-11-03 | 2001-06-12 | Diamon-Fusion International, Inc. | Capped silicone film and method of manufacture thereof |
-
2001
- 2001-08-03 US US09/921,303 patent/US6743516B2/en not_active Expired - Lifetime
- 2001-08-28 PL PL361891A patent/PL200431B1/en unknown
- 2001-08-28 EP EP20010966284 patent/EP1328579B1/en not_active Expired - Lifetime
- 2001-08-28 CA CA 2423657 patent/CA2423657C/en not_active Expired - Fee Related
- 2001-08-28 AT AT01966284T patent/ATE549302T1/en active
- 2001-08-28 AU AU2001286812A patent/AU2001286812A1/en not_active Abandoned
- 2001-08-28 ES ES01966284T patent/ES2384374T3/en not_active Expired - Lifetime
- 2001-08-28 WO PCT/US2001/026691 patent/WO2002028956A1/en active Application Filing
Also Published As
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US20020064663A1 (en) | 2002-05-30 |
PL200431B1 (en) | 2009-01-30 |
EP1328579A4 (en) | 2008-07-30 |
EP1328579A1 (en) | 2003-07-23 |
ATE549302T1 (en) | 2012-03-15 |
ES2384374T3 (en) | 2012-07-04 |
US6743516B2 (en) | 2004-06-01 |
EP1328579B1 (en) | 2012-03-14 |
AU2001286812A1 (en) | 2002-04-15 |
WO2002028956A1 (en) | 2002-04-11 |
CA2423657C (en) | 2008-11-18 |
PL361891A1 (en) | 2004-10-04 |
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