CA2444844A1 - Medical devices having durable and lubricious polymeric coating - Google Patents
Medical devices having durable and lubricious polymeric coating Download PDFInfo
- Publication number
- CA2444844A1 CA2444844A1 CA002444844A CA2444844A CA2444844A1 CA 2444844 A1 CA2444844 A1 CA 2444844A1 CA 002444844 A CA002444844 A CA 002444844A CA 2444844 A CA2444844 A CA 2444844A CA 2444844 A1 CA2444844 A1 CA 2444844A1
- Authority
- CA
- Canada
- Prior art keywords
- medical device
- silicone
- polymer
- coating
- polydimethylsiloxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract 10
- 238000000576 coating method Methods 0.000 title claims abstract 10
- -1 polydimethylsiloxane Polymers 0.000 claims abstract 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract 11
- 229920001600 hydrophobic polymer Polymers 0.000 claims abstract 9
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract 7
- 229920005573 silicon-containing polymer Polymers 0.000 claims abstract 5
- 239000000203 mixture Substances 0.000 claims abstract 4
- 239000004743 Polypropylene Substances 0.000 claims abstract 3
- 229920001155 polypropylene Polymers 0.000 claims abstract 3
- 229920001169 thermoplastic Polymers 0.000 claims 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 239000004698 Polyethylene Substances 0.000 claims 2
- 229920001610 polycaprolactone Polymers 0.000 claims 2
- 239000004632 polycaprolactone Substances 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 230000009969 flowable effect Effects 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/04—Surgical instruments, devices or methods, e.g. tourniquets for suturing wounds; Holders or packages for needles or suture materials
- A61B17/06—Needles ; Sutures; Needle-suture combinations; Holders or packages for needles or suture materials
- A61B17/06066—Needles, e.g. needle tip configurations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/08—Materials for coatings
- A61L31/10—Macromolecular materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/32—Surgical cutting instruments
- A61B17/3209—Incision instruments
- A61B17/3211—Surgical scalpels, knives; Accessories therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/08—Materials for coatings
- A61L29/085—Macromolecular materials
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/14—Materials characterised by their function or physical properties, e.g. lubricating compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2420/00—Materials or methods for coatings medical devices
- A61L2420/06—Coatings containing a mixture of two or more compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Abstract
A medical device having a contact surface exposed repeatedly to bodily tissue is disclosed. The contact surface is coated with a silicone polymer and one or more non-silicone hydrophobic polymers. The preferred medical device is a surgical needle, and the preferred coating is a polydimethylsiloxane and polypropylene wax hydrocarbon mixture. The incorporation of the non-silicone hydrophobic polymer increases the durability of the coating on the device without sacrificing lubricity.
Claims (17)
1. A medical device having a contact surface exposed repeatedly to bodily tissue, the contact surface being coated with an effective amount of a coating comprising a silicone polymer and a non-silicone hydrophobic polymer.
2. The medical device of claim 1 wherein the coating comprises a mixture of the silicone polymer and the non-silicone hydrophobic polymer.
3. The medical device of claim 1 wherein the coating comprises an inner layer of the non-silicone hydrophobic polymer and an outer layer of the silicone polymer.
4. The medical device of claim 1 wherein the silicone polymer is a polysiloxane.
5. The medical device of claim 4 wherein the polysiloxane is a polyalkylsiloxane.
6. The medical device of claim 5 wherein the polyalkylsiloxane is a polydimethylsiloxane.
7. The medical device of claim 6 wherein the non-silicone hydrophobic polymer has a critical surface tension of less than about 50 mN/m.
8. The medical device of claim 7 wherein the non-silicone hydrophobic polymer is a thermoplastic polymer.
9. The medical device of claim 8 wherein the thermoplastic polymer is flowable at less than about 210 C.
10. The medical device of claim 9 wherein the coating has about 40 to about 86 weight percent of the polydimethylsiloxane and about 14 to about 60 weight percent of the thermoplastic polymer.
11. The medical device of claim 10 wherein the coating has about 44 to about 66 weight percent of the polydimethylsiloxane and about 34 to about 56 weight percent of the thermoplastic polymer.
12. The medical device of claim 11 wherein the medical device is a surgical needle.
13. The medical device of claim 12 wherein the polydimethylsiloxane is hydroxy terminated.
14. The medical device of claim 13 wherein the thermoplastic polymer is polyethylene, polypropylene or polycaprolactone.
15. The medical device of claim 2 wherein the coating comprises a mixture of an hydroxy terminated polydimethylsiloxane and a non-silicone hydrophobic polymer selected from the group consisting of polyethylene, polypropylene and polycaprolactone.
16. The medical device of claim 15 wherein the coating mixture has about 44 to about 66 weight percent of the hydroxy terminated polydimethylsiloxane and about 34 to about 56 weight percent of the non-silicone hydrophobic polymer.
17. The medical device of claim 16 wherein the medical device is a surgical needle.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41805402P | 2002-10-11 | 2002-10-11 | |
| US60/418,054 | 2002-10-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2444844A1 true CA2444844A1 (en) | 2004-04-11 |
| CA2444844C CA2444844C (en) | 2012-04-03 |
Family
ID=32030983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2444844A Expired - Lifetime CA2444844C (en) | 2002-10-11 | 2003-10-10 | Medical devices having durable and lubricious polymeric coating |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7041088B2 (en) |
| EP (1) | EP1407792B1 (en) |
| JP (1) | JP4937493B2 (en) |
| AU (1) | AU2003252885B2 (en) |
| CA (1) | CA2444844C (en) |
| DE (1) | DE60314580T2 (en) |
| ES (1) | ES2287421T3 (en) |
Families Citing this family (606)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050226993A1 (en) * | 2000-10-03 | 2005-10-13 | Nawrocki Jesse G | Medical devices having durable and lubricious polymeric coating |
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2003
- 2003-10-03 US US10/678,560 patent/US7041088B2/en active Active
- 2003-10-09 AU AU2003252885A patent/AU2003252885B2/en not_active Expired
- 2003-10-10 JP JP2003352653A patent/JP4937493B2/en not_active Expired - Lifetime
- 2003-10-10 CA CA2444844A patent/CA2444844C/en not_active Expired - Lifetime
- 2003-10-10 EP EP20030256398 patent/EP1407792B1/en not_active Expired - Lifetime
- 2003-10-10 ES ES03256398T patent/ES2287421T3/en not_active Expired - Lifetime
- 2003-10-10 DE DE2003614580 patent/DE60314580T2/en not_active Expired - Lifetime
-
2013
- 2013-03-13 US US13/801,579 patent/US20130202779A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1407792B1 (en) | 2007-06-27 |
| EP1407792A1 (en) | 2004-04-14 |
| US20130202779A1 (en) | 2013-08-08 |
| ES2287421T3 (en) | 2007-12-16 |
| CA2444844C (en) | 2012-04-03 |
| US7041088B2 (en) | 2006-05-09 |
| JP4937493B2 (en) | 2012-05-23 |
| AU2003252885B2 (en) | 2008-08-21 |
| US20040071988A1 (en) | 2004-04-15 |
| AU2003252885A1 (en) | 2004-04-29 |
| DE60314580T2 (en) | 2008-03-06 |
| JP2004167220A (en) | 2004-06-17 |
| DE60314580D1 (en) | 2007-08-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20231010 |