CA2451181A1 - Lithium ion secondary battery and a method for manufacturing the same - Google Patents
Lithium ion secondary battery and a method for manufacturing the same Download PDFInfo
- Publication number
- CA2451181A1 CA2451181A1 CA002451181A CA2451181A CA2451181A1 CA 2451181 A1 CA2451181 A1 CA 2451181A1 CA 002451181 A CA002451181 A CA 002451181A CA 2451181 A CA2451181 A CA 2451181A CA 2451181 A1 CA2451181 A1 CA 2451181A1
- Authority
- CA
- Canada
- Prior art keywords
- lithium ion
- secondary battery
- ion secondary
- solid electrolyte
- inorganic substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Abstract
A lithium ion secondary battery includes a positive electrode, a negative electrode and a thin film solid electrolyte including lithium ion conductive inorganic substance. The thin film solid electrolyte has thickness of 20,µm or below and is formed directly on an electrode material or materials for the positive electrode and/or the negative electrode. The thin film solid electrolyte has lithium ion conductivity of 10-6Scm-1 or over and contains lithium ion conductive inorganic substance powder in an amount of 40 weight % or over in a polymer medium. The average particle diameter of the inorganic substance powder is 0.5 µm or below .According to a method for manufacturing the lithium ion secondary battery, the thin film solid electrolyte is formed by coating the lithium ion conductive inorganic substance directly on the electrode material or materials for the positive electrode and/or the negative electrode.
Claims (20)
1. A lithium ion secondary battery comprising a positive electrode, a negative electrode and a solid electrolyte, said solid electrolyte being made in the form of a thin film comprising a lithium ion conductive inorganic substance.
2. A lithium ion secondary battery as defined in claim 1 wherein said thin film solid electrolyte has thickness of 20 µm or below
3. A lithium ion secondary battery as defined in claim 1 wherein said thin film solid electrolyte is formed directly on an electrode material or materials for the positive electrode and/or the negative electrode.
4. A lithium ion secondary battery as defined in claim 1 wherein said thin film solid electrolyte has lithium ion conductivity of 10-5Scm-1 or over.
5. A lithium ion secondary battery as defined in claim 1 wherein said thin film solid electrolyte comprises the inorganic substance in an amount of 40 weight % or over.
6. A lithium ion secondary battery as defined in claim 7 wherein said inorganic substance is a lithium ion conductive crystal.
7. A lithium ion secondary battery as defined in claim 1 wherein said inorganic substance is a lithium ion conductive glass.
8. A lithium ion secondary battery as defined in claim 1 wherein said inorganic substance is a lithium ion conductive glass-ceramic.
9. A lithium ion secondary battery as defined yn claim 1 wherein said inorganic substance is powder of the inorganic substance.
10. A lithium ion secondary battery as defined in claim 9 wherein said inorganic substance powder is powder of a lithium ion conductive glass-ceramic,
11. A lithium ion secondary battery as defined in claim 9 wherein an average particle diameter of the inorganic substance powder is 1.0 µm or below.
12. A lithium ion secondary battery as defined in claim 9 wherein said thin film solid electrolyte comprises a lithium ion conductive inorganic substance powder in a polymer medium.
13. A lithium ion secondary battery as defined in claim 9 wherein said thin film solid electrolyte comprises a lithium inorganic salt and lithium ion conductive glass-ceramic powder in a polymer medium.
14. A lithium ion secondary battery as defined in claim 3 wherein said thin film solid electrolyte is formed by direct coating on an electrode material or materials for the positive electrode and/or the negative electrode.
15. A lithium ion secondary battery as defined in claim 3 wherein said thin film solid electrolyte is formed by crystallizing an amorphous layer which is formed by direct coating on an electrode material or materials for the positive electrode and/or the negative electrode.
16. A lithium ion secondary battery as defined in claim 1 comprising a positive electrode, a negative electrode and a solid electrolyte wherein said positive and/or negative electrode comprises lithium ion conductive inorganic substance powder.
17. A lithium ion secondary battery as defined in claim 16 wherein said inorganic substance powder in the positive and/or negative electrode has an average particle diameter of 3 µm or below
18. A method for manufacturing a lithium ion secondary battery having a thin film solid electrolyte comprising a lithium ion conductive inorganic substance comprising a step of forming the thin film solid electrolyte by coating the lithium ion conductive inorganic substance directly on an electrode material or materials for the positive and/or negative electrode.
19. A method for manufacturing a lithium ion secondary battery as defined in claim 18 comprising a step of preparing slurry comprising the lithium ion conductive inorganic substance, and a step of forming the thin film solid electrolyte by coating the slurry directly on the electrode material or materials for the positive and/or negative electrode.
20. A method for manufacturing a lithium ion secondary battery as defined in claim 18 comprising a step of coating the lithium ion conductive inorganic substance directly on the electrode material or materials for the positive and/or negative electrode to form an amorphous layer, and a step of forming the thin film solid electrolyte by crystallizing the amorphous layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2698567A CA2698567A1 (en) | 2002-11-29 | 2003-11-26 | Lithium ion secondary battery and a method for manufacturing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002348532A JP4777593B2 (en) | 2002-11-29 | 2002-11-29 | Method for producing lithium ion secondary battery |
JP2002-348532 | 2002-11-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2698567A Division CA2698567A1 (en) | 2002-11-29 | 2003-11-26 | Lithium ion secondary battery and a method for manufacturing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2451181A1 true CA2451181A1 (en) | 2004-05-29 |
CA2451181C CA2451181C (en) | 2013-04-02 |
Family
ID=32290503
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2451181A Expired - Fee Related CA2451181C (en) | 2002-11-29 | 2003-11-26 | Lithium ion secondary battery and a method for manufacturing the same |
CA2698567A Abandoned CA2698567A1 (en) | 2002-11-29 | 2003-11-26 | Lithium ion secondary battery and a method for manufacturing the same |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2698567A Abandoned CA2698567A1 (en) | 2002-11-29 | 2003-11-26 | Lithium ion secondary battery and a method for manufacturing the same |
Country Status (10)
Country | Link |
---|---|
US (3) | US20040106046A1 (en) |
EP (1) | EP1424743B1 (en) |
JP (1) | JP4777593B2 (en) |
KR (1) | KR100580442B1 (en) |
CN (1) | CN1505198B (en) |
AT (1) | ATE346392T1 (en) |
CA (2) | CA2451181C (en) |
DE (1) | DE60309815T2 (en) |
HK (1) | HK1065649A1 (en) |
TW (1) | TWI265652B (en) |
Families Citing this family (107)
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- 2003-11-26 KR KR1020030084572A patent/KR100580442B1/en active IP Right Grant
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DE60309815T2 (en) | 2007-10-11 |
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CN1505198B (en) | 2012-09-26 |
JP4777593B2 (en) | 2011-09-21 |
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TW200423452A (en) | 2004-11-01 |
ATE346392T1 (en) | 2006-12-15 |
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KR20040047664A (en) | 2004-06-05 |
TWI265652B (en) | 2006-11-01 |
HK1065649A1 (en) | 2005-02-25 |
KR100580442B1 (en) | 2006-05-15 |
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