CA2488335A1 - Sunscreen compositions - Google Patents

Sunscreen compositions Download PDF

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Publication number
CA2488335A1
CA2488335A1 CA002488335A CA2488335A CA2488335A1 CA 2488335 A1 CA2488335 A1 CA 2488335A1 CA 002488335 A CA002488335 A CA 002488335A CA 2488335 A CA2488335 A CA 2488335A CA 2488335 A1 CA2488335 A1 CA 2488335A1
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Prior art keywords
composition
acrylates
present
amount
agent
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Granted
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CA002488335A
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French (fr)
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CA2488335C (en
Inventor
Olga V. Dueva
James P. Sanogueira
Barbara Donovan
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Sun Pharmaceuticals Corp
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Individual
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Publication of CA2488335A1 publication Critical patent/CA2488335A1/en
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Publication of CA2488335C publication Critical patent/CA2488335C/en
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Expired - Fee Related legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/51—Chelating agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/524—Preservatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Abstract

The present invention is directed to a cosmetic composition that has an amount of at least two rheology-modifying agents such that the viscosity of the composition remains stable over a broad temperature range. The compositions of the present invention may also include at least one of the following additional components: sunscreen agent, SPF booster, secondary emulsifier, emollient, moisturizer, humectant, film former/waterproofing agent, bio-active (functional) ingredient, pH adjuster/chelating agent, preservative, fragrance, effect pigment, color additive, or any combinations thereof.

Claims (67)

1. A cosmetic composition having a stable viscosity comprising a first rheological modifying agent and a second rheological modifying agent present in a concentration ratio of about 1:10 to about 10:1, respectively.
2. The composition of claim 1, wherein said concentration ratio is about 1:5 to about 5:1.
3. The composition of claim 1, wherein said concentration ratio is about 1:2 to about 2:1.
4. The composition of claim 1, wherein said first rheological modifying agent is one or more agents selected from the group consisting of polymeric emulsifier, thickening agent, synthetic gum, natural gum, synthetic polymer, natural polymer, polysaccharide thickening agent, stabilizer, associative thickener, anionic associative rheology modifier, nonionic associative rheology modifier, oil-thickening agent, and any combinations thereof.
5. The composition of claim 1, wherein said first rheological modifying agent is one or more polymeric emulsifiers.
6. The composition of claim 5, wherein said one or more polymeric emulsifiers is selected from the group consisting of acrylates crosspolymer, acrylates/C10-30 alkylacrylate crosspolymer, acrylates/vinyl isodecanoate crosspolymer, polyacrylic acid, sodium polymethacrylate, sodium polyacrylate, polyacrylates, and any combinations thereof.
7. The composition of claim 1, wherein said second rheological modifying agent is one or more agents selected from the group consisting of polymeric emulsifier, thickening agent, synthetic gum, natural gum, synthetic polymer, natural polymer, polysaccharide thickening agent, stabilizer, associative thickener, anionic associative rheology modifier, nonionic associative rheology modifier, oil-thickening agent, and any combinations thereof.
8. The composition of claim 1, wherein said second rheological modifying agent is one or more thickening agents.
9. The composition of claim 8, wherein said one or more thickening agents is selected from the group consisting of stabilizer, synthetic gum, natural gum, synthetic polymer, natural polymer, polysaccharide thickening agent, associative thickener, anionic associative rheology modifier, nonionic associative rheology modifier, oil-thickening agent, acrylates/C10-30 alkylacrylate crosspolymer, acrylates/aminoacrylates/C10-30 alkyl PEG-20 itaconate copolymer, acrylates copolymer, acrylates/steareth-20 methacrylate copolymer, acrylates/beheneth-25 methacrylate copolymer, PEG-150/decyl alcohol/SMDI copolymer, PVP, PVM/MA decadiene crosspolymer, carbomer, PEG crosspolymer, acrylates/palmeth-25 acrylates copolymer, polysaccharide, polyacrylate, polyether-1, sodium magnesium silicate, sodium carbomer, sodium polyacrylate, sodium polymethacrylate, sodium polyacryloyldimethyl taurate, sodium acryloyldimethyl taurate copolymer, sodium carragenan, sodium carboxymethyl dextran, hydroxyethylcellulose, hydroxypropyl cyclodextran, bentonites, trihydroxystearin, aluminum-magnesium hydroxide stearate, xanthan gum, and any combinations thereof.
10. The composition of claim 1, wherein said first rheological modifying agent is present in an amount about 0.01 wt.% to about 10 wt.% of the total weight of the composition.
11. The composition of claim 1, wherein said first rheological modifying agent is present in an amount about 0.1 wt.% to about 5 wt.% of the total weight of the composition.
12. The composition of claim 1, wherein said second rheological modifying agent is present in an amount about 0.01 wt.% to about 10 wt.%
of the total weight of the composition.
13. The composition of claim 1, wherein said second rheological modifying agent is present in an amount about 0.1 wt.% to about 5 wt.% of the total weight of the composition.
14. The composition of claim 1, further comprising one or more sunscreen agents.
15. The composition of claim 14, wherein said one or more sunscreen agents are selected from the group consisting of para-aminobenzoic acid, butyl methoxydibenzoylmethane, benzophenone-1, benzophenone-2, benzophenone-3, benzophenone-4, benzophenone-6, benzophenone-8, benzophenone-12, bis-ethylhexyloxyphenol methoxyphenyl triazine, methoxycinnamate, ethyl dihydroxypropyl-PABA, glyceryl PABA, homosalate, methyl anthranilate, octocrylene, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate, PABA, 2-phenylbenzimidazole-5-sulphonic acid, triethanolamine salicylate, 3-(4-methylbenzylidene)-camphor, red petrolatum, zinc oxide, titanium dioxide, 3-(4-methylbenzyldine)boran-2-one(methylbenzindinecamphor), benzotriazole, octyl triazone, phenylbenzimidazole-5-sulfonic acid, methylene bis-benzotrizolyl tetramethylbutyl phenol, and any combinations thereof.
16. The composition of claim 14, wherein said one or more sunscreen agents is present in an amount about 1 wt.% to about 40 wt.% of the total weight of the composition.
17. The composition of claim 14, wherein said one or more sunscreen agents are present in an amount about 2 wt.% to about 35 wt.% to achieve a SPF of about 2 to about 50.
18 18. The composition of claim 14, wherein said one or more sunscreen agents is present in an amount about 4 wt.% to about 20 wt.% to achieve a SPF value of about 4 to about 30.
19. The composition of claim 1, further comprising one or more diluents.
20. The composition of claim 19, wherein said one or more diluents is selected from the group consisting of water, glycols, and any combinations thereof.
21. The composition of claim 19, wherein said one or more diluents is present in an amount about 40 wt.% to about 90 wt.%, of the total weight of the composition.
22. The composition of claim 19, wherein said one or more diluents is present in an amount about 50 wt.% to about 80 wt.%, of the total weight of the composition.
23. The composition of claim 1, further comprising one or more secondary emulsifiers selected from the group consisting of cetyl alcohol, cetearyl alcohol, oleth-10, diethylhexyl esters, sorbitan oleate, sorbitan sesquioleate, sorbitan isostearate, sorbitan trioleate, PEG-20 almond glycerides, polyglyceryl-3-diisostearate, polyglycerol esters of oleic/isostearic acid, polyglyceryl-6 hexaricinolate, polyglyceryl-4-oleate, polygylceryl-4 oleate/PEG-8 propylene glycol cocoate, sodium glyceryl oleate phosphate, hydrogenated vegetable glycerides phosphate, and any combinations thereof.
24. The composition of claim 23, wherein said secondary emulsifier is present in an amount about 0.01 wt.% to about 5 wt.% of the total weight of the composition.
25. The composition of claim 1, further comprising one or more emollients.
26. The composition of claim 25, wherein said one or more emollients is selected from the group consisting of cocoglyceride, cyclomethicone, dimethicone, dicapryl maleate, caprylic/capric triglyceride, isopropyl myristate, octyl stearate, isostearyl linoleate, lanolin oil, coconut oil, cocoa butter, olive oil, avocado oil, aloe extracts, jojoba oil, castor oil, fatty acid, oleic acid, stearic acid, fatty alcohol, cetyl alcohol, hexadecyl alcohol, diisopropyl adipate, hydroxybenzoate esters, benzoic acid esters of C9-C15 alcohols, isononyl iso-nonanoate, alkanes, mineral oil, silicone, dimethyl polysiloxane, ether, polyoxypropylene butyl ether, polyoxypropylene cetyl ether, C12-C15 alkyl benzoate, and any combinations thereof.
27. The composition of claim 25, wherein said one or more emollients is present in an amount about 0.1 wt.% to about 30 wt.% of the total weight of the composition.
28. The composition of claim 1, further comprising one or more pH
adjusters.
29. The composition of claim 28, wherein said one or more pH adjusters are selected from the group consisting of sodium hydroxide, triethanolamine, EDTA salts, and any combinations thereof.
30. The composition of claim 1, wherein said composition has a pH
about 3 to about 9.
31. The composition of claim 1, further comprising one or more humectants selected from the group consisting of glycerin, pentylene glycol, hexylene glycol, propylene glycol, butylene glycol, sorbitol, PEG-4, and any combinations thereof.
32. The composition of claim 31, wherein said one or more humectants is present in an amount about 0.1 wt.% to about 15 wt.% of the total weight of the composition.
33. The composition of claim 1, further comprising one or more SPF
boosters selected from the group consisting of styrene/acrylates copolymer, sodium bentonite, highly purified white sodium bentonite, montmorillonite, hydrogel, and any combinations thereof.
34. The composition of claim 1, further comprising one or more film former/waterproofing agents selected from the group consisting of acrylates/acrylamide copolymer, acrylates copolymer, acrylates/C12-22 alkylmethacrylate copolymer, polyethylene, wax, VP/dimethiconylacrylate/polycarbamyl polyglycol ester, butylated PVP, PVP/hexadecene copolymer, octadecene/MA copolymer, PVP/eicosene copolymer, tricontanyl PVP, Brassica Campestris/Aleuritis Fordi Oil copolymer, decamethyl cyclopentasiloxane (and) trimethylsiloxysilicate, and any combinations thereof.
35. The composition of claim 1, further comprising an acrylates/C12-22 alkylmethacrylate copolymer.
36. The composition of claim 34, wherein said one or more film formers/waterproofing agents is present in an amount about 0.1 wt.% to about 5 wt.% of the total weight of the composition.
37. The composition of claim 35, wherein said acrylates/C12-22 alkylmethacrylate copolymer is present in an amount about 1 wt.% to about 3 wt.% of the total weight of the composition.
38. The composition of claim 1, further comprising one or more preservatives selected from the group consisting of diazolidinyl urea, iodopropynyl butylcarbamate, chloromethylisotiazolinone, methylisothiazolinone, vitamin E and its derivatives, vitamin E acetate, vitamin C, butylated hydroxytoluene, butylparaben, ethylparaben, methylparaben, propylparaben, isobutylparaben, phenoxyethanol, and any combinations thereof.
39. The composition of claim 1, further comprising a preservative comprising a combination of phenoxyethanol, methylparaben, ethylparaben, propylparaben, isobutylparaben and butylparaben.
40. The composition of claim 38, wherein said one or more preservatives is present in an amount about 0.01 wt.% to about 2 wt.% of the total weight of the composition.
41. The composition of claim 30, wherein said preservative is present in an amount about 0.5 wt.% to about 1.5 wt.% of the total weight of the composition.
42. The composition of claim 1, further comprising one or more additives selected from the group consisting of plant extract, fruit extract, vegetable extract, algae extract, sugar, polysaccharide, lipid, protein, peptide, aminoacid, aminoacid derivative, absorbent, salicylic acid, alpha hydroxy acid, beta hydroxy acid, oil soluble vitamin, water soluble vitamin, vitamin A, vitamin A derivative, vitamin C, vitamin C derivative, vitamin E, vitamin E
derivative, and any combinations thereof.
43. A sunscreen composition comprising:
about 1 wt.% to about 20 wt.% of sunscreen agent; and a synergistic combination of a first rheological modifying agent and a second rheological modifying agent, wherein said composition has a stable viscosity over a temperature range of about 20°C to about 70°C.
44. The composition of claim 43, wherein said sunscreen agent is selected from the group consisting of para-aminobenzoic acid, butyl methoxydibenzoylmethane, benzophenone-1, benzophenone-2, benzophenone-3, benzophenone-4, benzophenone-6, benzophenone-8, benzophenone-12, bis-ethylhexyloxyphenol methoxyphenyl triazine, methoxycinnamate, ethyl dihydroxypropyl-PABA, glyceryl PABA, homosalate, methyl anthranilate, octocrylene, octyl dimethyl PABA, octyl methoxycinnamate, octyl salicylate, PABA, 2-phenylbenzimidazole-5-sulphonic acid, triethanolamine salicylate, 3-(4-methylbenzylidene)-camphor, red petrolatum, zinc oxide, titanium dioxide, 3-(4-methylbenzyldine)boran-2-one(methylbenzindinecamphor), benzotriazole, octyl triazone, phenylbenzimidazole-5-sulfonic acid, methylene bis-benzotrizolyl tetramethylbutyl phenol, and any combinations thereof.
45. The composition of claim 43, wherein said first rheological modifying agent is one or more agents selected from the group consisting of polymeric emulsifier, thickening agent, synthetic gum, natural gum, synthetic polymer, natural polymer, polysaccharide thickening agent, stabilizer, associative thickener, anionic associative rheology modifier, nonionic associative rheology modifier, oil-thickening agent, and any combinations thereof.
46. The composition of claim 43, wherein said second rheological modifying agent is one or more agents selected from the group consisting of polymeric emulsifier, thickening agent, synthetic gum, natural gum, synthetic polymer, natural polymer, polysaccharide thickening agent, stabilizer, associative thickener, anionic associative rheology modifier, nonionic associative rheology modifier, oil-thickening agent, and any combinations thereof.
47. The composition of claim 43, wherein said first rheological modifying agent is present in an amount about 0.01 wt.% to about 10 wt.% of the total weight of the composition.
48. The composition of claim 43, wherein said second rheological modifying agent is present in an amount about 0.01 wt.% to about 10 wt.%

of the total weight of the composition.
49. The composition of claim 43, wherein said first rheological agent and said second rheological agent are present in concentration ratio about 1:10 to about 10:1, respectively.
50. The composition of claim 43, further comprising about 1 wt.% to about 2 wt.% acrylates/C12-22 alkylmethacrylate copolymer.
51. The composition of claim 43, further comprising pentylene glycol.
52. A photoprotective composition comprising:
about 2 wt.% to about 12 wt.% of sunscreen agent having octinoxate and octocrylene; and a synergistic combination of carbomer and acrylates/C10-30 alkyl acrylate crosspolymer, wherein said composition has a stable viscosity over a temperature range of about 20°C to about 70°C.
53. The composition of claim 52, wherein said composition has an SPF
of at least about 15.
54. The composition of claim 52, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are each present in an amount about 0.1 wt.% to about 0.5 wt.%.
55. The composition of claim 52, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are present in a concentration ratio of about 1:2 to about 2:1, respectively.
56. A photoprotective composition comprising:
about 1 wt.% to about 8 wt.% of sunscreen agent having octinoxate and octisalate; and a synergistic combination of carbomer and acrylates/C10-30 alkyl acrylate crosspolymer, wherein said composition has a stable viscosity over a temperature range of about 20°C to about 70°C.
57. The composition of claim 56, wherein said composition has an SPF
of at least about 8.
58. The composition of claim 56, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are each present in an amount about 0.1 wt.% to about 0.5 wt.%.
59. The composition of claim 56, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are present in a concentration ratio of about 1:2 to about 2:1, respectively.
60. A photoprotective composition comprising:
about 1 wt.% to about 4 wt.% of sunscreen agent having octinoxate and octisalate; and a synergistic combination of carbomer and acrylates/C10-30 alkyl acrylate crosspolymer, wherein said composition has a stable viscosity over a temperature range of about 20°C to about 70°C.
61. The composition of claim 60, wherein said composition has an SPF
of at least about 4.
62. The composition of claim 60, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are each present in an amount about 0.1 wt.% to about 0.5 wt.%.
63. The composition of claim 60, wherein said carbomer and said acrylates/C10-30 alkyl acrylate crosspolymer are present in a concentration ratio of about 1:2 to about 2:1, respectively.
64. A photoprotective composition comprising:
about 1.5 wt.% to about 20 wt.% of sunscreen agent having avobenzone, octinoxate, octisalate and oxybenzone; and a synergistic combination of first rheological modifying agent having carbomer and xanthan gum and a second rheological modifying agent having acrylates/C10-30 alkyl acrylate crosspolymer, wherein said composition has a stable viscosity over a temperature range of about 20°C to about 70°C.
65. The composition of claim 64, wherein said composition has a SPF of at least about 30.
66. The composition of claim 64, wherein said first rheological modifying agent and said second rheological modifying agent are each present in an amount about 0.1 wt.% to about 0.5 wt.%.
67. The composition of claim 64, wherein said first rheological modifying agent and said second rheological modifying agent are present in a concentration ratio of about 1:2 to about 2:1, respectively.
CA2488335A 2002-06-06 2003-06-04 Sunscreen compositions Expired - Fee Related CA2488335C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US38631702P 2002-06-06 2002-06-06
US60/386,317 2002-06-06
US10/448,745 2003-05-29
US10/448,745 US7108860B2 (en) 2002-06-06 2003-05-29 Sunscreen compositions
PCT/US2003/017570 WO2003103615A1 (en) 2002-06-06 2003-06-04 Sunscreen compositions

Publications (2)

Publication Number Publication Date
CA2488335A1 true CA2488335A1 (en) 2003-12-18
CA2488335C CA2488335C (en) 2011-05-24

Family

ID=29739901

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2488335A Expired - Fee Related CA2488335C (en) 2002-06-06 2003-06-04 Sunscreen compositions

Country Status (6)

Country Link
US (1) US7108860B2 (en)
AU (1) AU2003237369B2 (en)
CA (1) CA2488335C (en)
GB (1) GB2407268B (en)
MX (1) MXPA04012201A (en)
WO (1) WO2003103615A1 (en)

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