CA2495019A1 - Plasticized polyolefin compositions - Google Patents
Plasticized polyolefin compositions Download PDFInfo
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- CA2495019A1 CA2495019A1 CA002495019A CA2495019A CA2495019A1 CA 2495019 A1 CA2495019 A1 CA 2495019A1 CA 002495019 A CA002495019 A CA 002495019A CA 2495019 A CA2495019 A CA 2495019A CA 2495019 A1 CA2495019 A1 CA 2495019A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
Abstract
A plasticized polyolefin composition comprising one or more polyolefins and one or more non-functionalized plasticizers where the non-functionalized plasticizer comprises C20 to C1500 paraffins having a Kinematic viscosity of 10 cSt or more at 100°C, a viscosity index of 120 or more and a specific gravity of from 0.700 to 0.860, and where the polyolefin has a crystallinity of 5 to 80 %, and wherein elastomers are substantially absent from the composition, and ethylene homopolymers and copolymers having an Mw of from 500 to 10,000 are present at less than 0.5 wt% (based upon the weight of the polyolefin, ethylene polymer and non-functionalized plasticizer) and wherein the polyolefin is polypropylene having an Mw of 50,000 to 2,000,000 g/mol.
Claims (78)
1. A plasticized polyolefin composition comprising one or more polyolefins and one of more non-functionalized plasticizers where the non-functionalized plasticizers have a kinematic viscosity ("KV") of 2 cSt or less at 100 °C.
2. The composition of claim 1wherein the non-functionalized plasticizer comprises at least 50 weight%, of C6 to C100 isoparaffins.
3. The composition of claim 1 wherein the non-functionalized plasticizer comprises at least 50 weight% of C5 to C25 n-paraffins having less than 0.1 % aromatics.
4. The composition of claim 1 wherein the non-functionalized plasticizer comprises at least 50 weight% of a dearomaticized aliphatic hydrocarbon comprising a mixture of normal paraffins, isoparaffins and cycloparaffins.
5. The composition of claim 1 wherein the non-functionalized plasticizer comprises at least 50 weight% of a dearomaticized aliphatic hydrocarbon comprising a mixture of C4 to C25 normal paraffins, C4 to C25 isoparaffins and C4 to C25 cycloparaffins.
6. A plasticized polyolefin composition comprising one or more, polyolefins and one of more non-functionalized plasticizers where the non-functionalized plasticizes comprises C20 to C1500 paraffins having a Kinematic viscosity of 10 cSt or more at 100 °C and a viscosity index of 120 or more.
7. A plasticized polyolefin composition comprising one or more polyolefins and one of more non-functionalized plasticizers where the non-functionalized plasticizer comprises oligomers of C5 to C14 olefins having a Kinematic viscosity of 10 cSt or more at 100 °C and a viscosity index of 120 or more.
8. A plasticized polypropylene compositions comprising polypropylene and one or more non-functionalized plasticizers where the non-functionalized plasticizer comprises oligomers of C6 to C14 olefins having viscosity index of 120 or more, provided that when the plasticized composition comprises between 4 and 10 weight % of polyalphaolefin that is a hydrogenated, highly branched dimes of an alpha olefin having 8-12 carbon atoms, the composition does not comprises between 18 and 25 weight percent of a linear low density polyethylene having a density of 0.912 to 0.935 g/cc.
9. A plasticized polypropylene compositions comprising polypropylene and one or more non-functionalized plasticizers where the non-functionalized plasticizer comprises oligomers of C6 to C14 olefins having viscosity index of 120 or more, provided that when the composition does not comprises an impact copolymer of polypropylene and 40-50 weight% of an ethylene propylene rubber or provided that the composition does not comprise a random copolymer of propylene and ethylene.
10. The composition of any of claims 6 to 9 wherein the non-functionalized plasticizer comprises an oligomer of decene having a carbon number of 40-200.
11. The composition of any of claims 6 to 10 wherein the non-functionalized plasticizer comprises oligomers of 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, 1-decene, 1-undodecene and or 1-dodecene.
12. The composition of any of claims 6 to 11 wherein the non-functionalized plasticizer comprises oligomers of decene having a carbon number of 200 to 1500.
13. The composition of any of claims 6 to 12 wherein the non-functionalized plasticizer has a kinematic viscosity of 10 cSt at 100 °C.
14. The composition of any of claims 6 to 13 wherein the non-functionalized plasticizer has a VI of 130 or more.
15. A plasticized polyolefin composition comprising a polyolefin and a non-functionalized plasticizer where the plasticizer comprises a mineral oil having a saturates levels of 90% or more, sulfur contents of 0.03 % or less, and VI of 120 or more.
16. A plasticized polyolefin composition comprising a polyolefin and a non-functionalized plasticizer where the plasticizer comprises a mixture of branched and normal paraffins having from 6 to 50 carbon atoms and a ratio of branch paraffin to n-paraffin ratio ranging from 0.5:1 to 9:1.
17. The composition of claim 16 where the mixture comprises greater than 50 wt% mono-methyl species.
18. The composition of claim 16 or 17 where the plasticizer comprises a mixture of branched and normal paraffins having from 10 to 16 carbon atoms and a ratio of branch paraffin to n-paraffin ratio ranging from 1:1 to 4:1.
19. A plasticized polyolefin composition comprising one or more polyolefins and one or more non-functionalized plasticizers where the non-functionalized plasticizer comprises a linear or branched paraffinic hydrocarbon composition having a number average molecular weight of 500 to 20,000, having less than 10 % sidechains having 4 or more carbons, and having at least 1 or 2 carbon branches present at 15 weight % or more, and where the NFP comprises less than 2 weight % cyclic paraffins.
20. A plasticized polyolefin composition comprising one or more polyolefins and one or more non-functionalized plasticizers where the non-functionalized plasticizer has an Mn of 15,000 and an Mw of 60,000 or less and comprises: 1) a copolymer of a C4 raffinate; 2) a poly(n-butene);
or 3) a copolymer of at least isobutylene derived units, 1-butene derived units, and 2-butene derived units.
or 3) a copolymer of at least isobutylene derived units, 1-butene derived units, and 2-butene derived units.
21. The composition according to any of the above claims where the plasticized composition decreases less than 1 % in weight when stored at 70 °C for 312 hours in a dry oven.
22. The composition according to any of the above claims where the non-functionalized plasticizer comprises 0.1 weight % or less of functional groups selected from hydroxide, aryls and substituted aryls, halogens, alkoxys, carboxylates, esters, carbon unsaturation, acrylates, oxygen, nitrogen, and carboxyl, based upon the weight of the NFP.
23. The composition according to any of the above claims where the non-functionalized plasticizer has a glass transition temperature (Tg) that cannot be determined or if it can be determined then the Tg is less than 30°C.
24. The composition according to any of the above claims where the non-functionalized plasticizer has a distillation range having a difference between the upper temperature and the lower temperature of 20 °C or less.
25. The composition according to any of the above claims where the non-functionalized plasticizer has an initial boiling point greater than 110 °C.
26. The composition according to any of the above claims where the non-functionalized plasticizer has a pour point of -15 °C or less.
27. The composition according to any of the above claims where the non-functionalized plasticizer has a specific gravity of less than 0.86.
28. The composition according to any of the above claims where the non-functionalized plasticizer has a specific gravity from 0.70 to 0.86.
29. The composition according to any of the above claims where the non-functionalized plasticizer has a final boiling point of from 115°C to 500°C.
30. The composition according to any of the above claims where the non-functionalized plasticizer has a weight average molecular weight between 2,000 and 100 g/mol.
31. The composition according to any of the above claims where the non-functionalized plasticizer has a flash point of -30 to 350°C.
32. The composition according to any of the above claims where the non-functionalized plasticizer has a dielectric constant at 20°C of less than 3Ø
33. The composition according to any of the above claims where the non functionalized plasticizer has a density of from 0.70 to 0.83 g/cm3.
34. The composition according to any of the above claims where the non-functionalized plasticizer has a viscosity of from 0.5 to 20 cSt at 25°C.
35. The composition according to any of the above claims where the non-functionalized plasticizer has a carbon number of from 6 to 150.
36. The composition according to any of the above claims where the non-functionalized plasticizer has a carbon number of from 7 to 100.
37. The composition according to any of the above claims where the non-functionalized plasticizer has a carbon number of from 10 to 30.
38. The composition according to any of the above claims where the non-functionalized plasticizer has a carbon number of from 12 to 25.
39. The composition according to any of the above claims where the plasticized composition has a single glass transition temperature that is below that of the polyolefin itself.
40. The composition according to any of the above claims characterized in that the T g of the plasticized composition is at least 4 °C lower than that of the neat polyolefin.
41. The composition according to any of the above claims characterized in that the T g of the plasticized composition is at least 10 °C lower than that of the neat polyolefin.
42. The composition according to any of the above claims characterized in that the T g of the plasticized composition is at least 15 °C lower than that of the neat polyolefin.
43. The composition according to any claims 30, 31 or 32 characterized in that the peak melting temperature of the neat polyolefin is within 1 to 4°C
of the plasticized polyolefin.
of the plasticized polyolefin.
44. The composition according to any claims 30, 31, 32 or 33 characterized in that the crystallization temperature of the neat polyolefin is within 1 to 4°C
of the plasticized polyolefin.
of the plasticized polyolefin.
45. The composition according to any of the above claims where the polyolefin comprises polypropylene.
46. The composition of any of the above claims where the polyolefin comprises isotactic polypropylene.
47. The composition of any of the above claims where the polyolefin comprises syndiotactic polypropylene.
48. The composition of any of the above claims where the polyolefin comprises highly isotactic polypropylene,
49. The composition of any of the above claims where the polyolefin comprises polybutene.
50. The composition of any of the above claims where the polyolefin comprises an impact copolymer.
51. The composition of any of the above claims where the polyolefin further comprises an elastomer.
52. The composition of any of the above claims where the polyolefin further comprises a plastomer.
53. The composition of any of the above claims where the polyolefin has an Mw of 30,000 to 1,000,000 g/mol.
54. The composition of any of the above claims where the polyolefin has an, Mw/Mn of 1,6 to 10.
55. The composition of any of the above claims where the polyolefin has a melting point (second melt) of 30 to 185 °C.
56. The composition of any of the above claims where the polyolefin has a crystallinity of 5 to 80%.
57. The composition of any of the above claims where the polyolefin has a heat of fusion between 20 to 150 J/g.
58. The composition of any of the above claims where the polyolefin has a Gardner impact strength, tested on 0.125 inch disk at 23°C of 20 in-lb to 1000 in-lb,
59, The composition of any of the above claims where the polyolefin has a 1%
secant flexural modulus of from 100 Mpa to 2300 MPa .
secant flexural modulus of from 100 Mpa to 2300 MPa .
60. The composition of any of the above claims where the polyolefin has a melt flow rate from 0.3 to 500 dg/min.
61. The composition of any of the above claims where the polyolefin comprises a copolymer of propylene and from 0.5 to 30 weight % of one or more comonomers selected from the group consisting of ethylene, butene, pentene, hexene, heptene, octene, nonene, decene, dodecene, 4-methyl-pentene-1, 3-methyl pentene-1, 5-ethyl-1-nonene, and 3,5,5-trimethyl-hexene-1.
62. The composition of any of the above claims wherein the polyolefin comprises propylene, from 0 to 5 weight % of a diene, and from 2 wt% to 25 wt% ethylene, based on the total weight of the polymer and has a narrow compositional distribution; a melting point (Tm) of from 25°C to 120°C; a heat of fusion of from 50 J/g to 3 J/g; an Mw/Mn of from 1.5 to 5; and a melt index (MI) of less than 20 dg/min.
63. The polymer of claim 62 where the polyolefin has a tacticity index of 4 to 12.
64. The composition of any of the above claims where the polyolefin is present at 50 to 99.99 weight %, based upon the weight of the polyolefin and the non-functionalized plasticizer.
65. The composition of any of the above claims where non-functionalized plasticizer is present at 0.5 to 35 weight %, based upon the weight of the polyolefin and the non-functionalized plasticizer.
66. The composition of any of the above claims where non-functionalized plasticizer is present at 1 to 15 weight %, based upon the weight of the polyolefin and the non-functionalized plasticizer.
67. The composition of any of claims 1 to 68, wherein the polyolefin is a propylene impact copolymer or blend comprising from 40% to 95% by weight of a Component A and from 5% to 60% by weight of a Component B based on the total weight of copolymer; wherein Component A
comprises propylene homopolymer or copolymer, the copolymer comprising 10% or less by weight ethylene, butene, hexene or octene comonomer; and wherein Component B comprises propylene copolymer, wherein the copolymer comprises from 5% to 70% by weight ethylene, butene, hexene and/or octene comonomer, and from 95% to 30% by weight propylene.
comprises propylene homopolymer or copolymer, the copolymer comprising 10% or less by weight ethylene, butene, hexene or octene comonomer; and wherein Component B comprises propylene copolymer, wherein the copolymer comprises from 5% to 70% by weight ethylene, butene, hexene and/or octene comonomer, and from 95% to 30% by weight propylene.
68. The composition of claim 67 wherein the refractive index of Component A
and the refractive index of Component B are within 10 % of each other, and, optionally the refractive index of the non-functionalized plasticizer is within 20 % of Component A, Component B or both.
and the refractive index of Component B are within 10 % of each other, and, optionally the refractive index of the non-functionalized plasticizer is within 20 % of Component A, Component B or both.
69. The composition of any of the above claims wherein polyethylene having a weight average molecular weight of from 500 to 10,000 is substantially absent and or wherein phthalates, adipates, trimellitate esters, and polyesters are substantially absent.
70. The composition of any of the above claims wherein the polyolefin comprises segments that are isotactic.
71. An article of manufacture comprising the composition of any of the above claims.
72. The article of manufacture of claim 71 where the article is selected from the group consisting of: cookware, storage ware, furniture, automotive components, boat components, toys, sportswear, medical devices, medical devices, sterilization containers, nonwoven fibers, nonwoven fabrics, drapes, gowns, filters, hygiene products, diapers, films, oriented films, sheets, tubes, pipes, films, sheets, fibers, woven fabrics, tubes, pipes, sporting equipment, tubing, pipes, wire jacketing, cable jacketing, agricultural films, geomembranes, bumpers, grills, trim parts, dashboards, instrument panels, exterior door components, hood components, spoiler, wind screen, hub caps, mirror housing, body panel, protective side molding, crates, containers, packaging, labware, office floor mats, instrumentation sample holders, sample windows; liquid storage containers, bags, pouches, bottles for storage and IV infusion of blood or solutions; packaging material for any medical device or drugs including unit-dose, blister pack, bubble pack, adhesives, shoe soles, gaskets, bellows, elastic fibers, and sealants.
73 A method to make an article of manufacture comprising subjecting the composition of any of claims 1 to70 one or more of: injection molding, compression molding, transfer molding, casting, extruding, thermoforming, blow molding, spunbonding, meltblowing, laminating, pultrusion, fiber spinning, draw reduction, rotational molding, spinbonding, melt spinning, melt blowing; or combinations thereof.
74. A non-woven article comprising the composition of any of claims 1 to 70.
75. A method to make a non-woven article comprising melt blowing, spunbonding, film aperturing, and or staple fiber carding the composition of any of claims 1 to 70.
76. A method to make a non-woven fabric comprising extruding of fibers comprising the composition of any of claim 1 to 70 through a spinneret, drawing the fibers using high velocity air, laying the drawn fibers on an endless belt to form a web, and bonding the fibers to one another.
77. A method to make a plasticized polyolefin comprising polymerizing the polyolefin in a solution process and introducing a non-functional plasticizer that is soluble in the solvent medium into the polymer solution prior to removing the solvent.
78. A method to make a plasticized polyolefin comprising polymerizing the polyolefin in a bulk process and introducing a non-functional plasticizer that is soluble in the bulk medium into the polymer solution prior to removing the solvent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA 2675730 CA2675730C (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
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US40266502P | 2002-08-12 | 2002-08-12 | |
US60/402,665 | 2002-08-12 | ||
USPCT/US2003/024667 | 2003-08-04 | ||
US10/634,351 | 2003-08-04 | ||
US10/634,351 US7632887B2 (en) | 2002-08-12 | 2003-08-04 | Plasticized polyolefin compositions |
PCT/US2003/024667 WO2004014997A2 (en) | 2002-08-12 | 2003-08-04 | Plasticized polyolefin compositions |
PCT/US2003/025149 WO2004014998A2 (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA 2675730 Division CA2675730C (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2495019A1 true CA2495019A1 (en) | 2004-02-19 |
CA2495019C CA2495019C (en) | 2011-10-04 |
Family
ID=31715879
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2492839A Expired - Fee Related CA2492839C (en) | 2002-08-12 | 2003-08-04 | Plasticized polyolefin compositions |
CA 2675730 Expired - Fee Related CA2675730C (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
CA2495019A Expired - Fee Related CA2495019C (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2492839A Expired - Fee Related CA2492839C (en) | 2002-08-12 | 2003-08-04 | Plasticized polyolefin compositions |
CA 2675730 Expired - Fee Related CA2675730C (en) | 2002-08-12 | 2003-08-12 | Plasticized polyolefin compositions |
Country Status (10)
Country | Link |
---|---|
US (6) | US7632887B2 (en) |
EP (3) | EP1530611B1 (en) |
JP (2) | JP2005535748A (en) |
KR (1) | KR101008786B1 (en) |
CN (1) | CN100345896C (en) |
AU (3) | AU2003272213A1 (en) |
BR (2) | BR0313398A (en) |
CA (3) | CA2492839C (en) |
SG (1) | SG145599A1 (en) |
WO (2) | WO2004014997A2 (en) |
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- 2003-08-04 CN CNB038190834A patent/CN100345896C/en not_active Expired - Fee Related
- 2003-08-04 AU AU2003272213A patent/AU2003272213A1/en not_active Abandoned
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2009
- 2009-06-11 AU AU2009202306A patent/AU2009202306B2/en not_active Ceased
- 2009-10-19 US US12/581,334 patent/US8217112B2/en active Active
-
2010
- 2010-01-25 US US12/693,287 patent/US8211968B2/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113912941A (en) * | 2021-10-26 | 2022-01-11 | 金发科技股份有限公司 | Polypropylene composite material and preparation method and application thereof |
CN113912941B (en) * | 2021-10-26 | 2023-07-18 | 金发科技股份有限公司 | Polypropylene composite material and preparation method and application thereof |
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