CA2499951A1 - Multiple catalyst system for olefin polymerization and polymers produced therefrom - Google Patents

Multiple catalyst system for olefin polymerization and polymers produced therefrom Download PDF

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CA2499951A1
CA2499951A1 CA 2499951 CA2499951A CA2499951A1 CA 2499951 A1 CA2499951 A1 CA 2499951A1 CA 2499951 CA2499951 CA 2499951 CA 2499951 A CA2499951 A CA 2499951A CA 2499951 A1 CA2499951 A1 CA 2499951A1
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indenyl
butyl
iso
2zirconium
dimethyl
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CA2499951C (en
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Peijun Jiang
Armenag Dekmezian
Jo Ann M. Canich
Charles L. Sims
Ramin Abhari
Cesar A. Garcia-Franco
David R. Johnsrud
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ExxonMobil Chemical Patents Inc
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Abstract

This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g') of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less and to a continuous process to produce a branched olefin polymer comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100~C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.

Claims (82)

1. A polymer comprising at least 50 mol% of one or more C3 to C40 olefins where the polymers has:

a) a Dot T-Peel of 1 Newton or more on Kraft paper; and b) a branching index (g') of 0.98 or less measured at the Mz of the polymer;
c) an Mw of 100,000 or less.
d) A heat of fusion of 1 to 70 J/g.
2. The polymer of claim 1 wherein the branching index (g') is 0.95 or less measured at the Mz of the polymer.
3. The polymer of claim 1 wherein the Mw is 100 to 60,000.
4. The polymer of claim 1 which is a homopolypropylene or a copolymer of propylene and up to 5 mole% ethylene said polymer having:
a) an isotactic run length of 1 to 30, and b) a r dyad percentage of greater than 20%.
5. The polymer of claim of claim 1 wherein the heat of fusion is from 1 to 50 J/g.
6. The polymer of claim 1 or 2 wherein the polymer comprises lass than 15 mole % of ethylene.
7. The polymer of any of the above claims wherein the polymer has a melt viscosity of 7000 mPa.cndot.sec or less at 190°C.
8. The polymer of any of the above claims wherein the polymer has a melt viscosity of 5000 mPa.cndot. or less at 190°C.
9. The polymer of any of the above claims wherein the polymer has a melt viscosity of 3000 mPa.cndot.sec or less at 190°C.
10. The polymer of any of the above claims wherein the polymer has a melt viscosity of between 500 and 3000 mPa.cndot.sec at 190°C.
11. The polymer of any of the above claims wherein the polymer has a Tg of 0°C or less.
12. The polymer of any of the above claims wherein the polymer has a Tg of 10°C or less.
13. The polymer of any of the above claims wherein the composition has a branching index (g) of 0.90 or less measured at the Mz of the polymer.
14. The polymer of any of the above claims wherein the polymer has an Mw of 50,000 or less and a branching index of 0.7 or less.
15. The polymer of any of the above claims wherein the molecular weight distribution of the polymer is bi- or multi-modal.
16. The polymer of any of the above claims wherein the polymer has an amorphous content of at least 50%.
17. The polymer of any of the above claims wherein the polymer has a peak melting point between 60 and 190°C.
18. The polymer of any of the above claims wherein the polymer has a molecular weight distribution (Mw/Mn) of at least 5.
19. The polymer of any of the above claims wherein the polymer has a crystallinity of at least 30%.
20. The polymer of any of the above claims wherein the polymer has 20 wt.%
or more of hexane room temperature soluble fraction and 50 wt % or less of Soxhlet heptane insolubles.
21. The polymer of any of the above claims wherein the polymer comprises less than 3.0 mole % ethylene.
22. The polymer of any of the above claims where the polymer comprises diolefin.
23. The polymer of any of the above claims where the polymer comprises diolefin selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene,cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
24. The polymer of any of the above claims where the polymer has an Mz/Mn of 2 to 200.
25. The polymer of any of the above claims wherein the polymer has an Mz of 15,000 to 500,000.
26. The polymer of any of the above claims wherein the polymer has a SAFT
of 50 to 150°C.
27. The polymer of any of the above claims wherein the polymer has a Shore A hardness of 95 or less.
28. The polymer of any of the above claims wherein the polymer has a set time of 5 seconds or less.
29. The polymer of any of the claims 1-17 and 19-28 wherein the polymer has an Mw/Mn of 2 to 75.
30. The polymer of any of the above claims wherein the polymer has a tensile strength at break of 0.5 MPa or more.
31. The polymer of any of the above claims wherein the polymer has a melt index of 900 dg/min or more.
32. The polymer of any of the above claims wherein the polymer is a homopolymer of propylene and or a copolymer of propylene and one or more of butene, pentene, hexene, octene, nonene, and decene, wherein the copolymer comprises less than 10 mole% ethylene, and wherein the homopolymer or copolymer has a Dot T-Peel of 3 or more Newtons; a viscosity of 7,000 mPasec/sec or less at 190 ° C; a branching index (g') of 0.85 or less measured at the Mz of the polymer; and an Mw of 100,000 or less.
33. The polymer of any of the above claims wherein the polymer comprises propylene, from 0 to 5 mol% ethylene, from 0 to 40 mol% of a C5 to C12 olefin, and 0 to 10 mol% of a diene.
34. The polymer of any of the above claims where the polymer comprises less than 1 mole% of ethylene and where the polymer has at least 2 mol%
(CH2)2 units.
35. The polymer of claim 34 wherein the polymer has at least 4 mol% (CH2)2 units.
36. The polymer of claim 34 wherein the polymer has at least 8 mol%!(CH2)2 units.
37. The polymer of claim 34 wherein the polymer has at least 15 mol%(CH2)2 units.
38. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 2 + X
mol% (CH2)2 units, where X is the mole % ethylene.
39. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 4 + X
mol% (CH2)2 units.
40. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 10 + X
mol% (CH2)2 units.
41. The polymer any of claims 1 to 33 where the polymer comprises between 1 and 10 mole % of ethylene and where the polymer has at least 15 + X
mol% (CH2)2 units.
42. The polymer any of claims 1 to 41 where the polymer has a Dot T-Peel of 5 Newton or more.
43. The polymer any of claims 1 to 42 where the polymer has a Dot T-Peel of between 10 and 2000 Newtons.
44. The polymer any of claims 1 to 43 wherein the polymer has a Dot T-Peel of between 15 and 1000 Newtons.
45. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 3 mol% (CH2)2 units.
46. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 6 mol % (CH2)2 units.
47. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 10 mol % (CH2)2 units.
48. The polymer any of claims 1 to 43 wherein the polymer has an amorphous component which contains at least 15 mol % (CH2)2 units.
49. The polymer of claim 109 where the amorphous component contains at least 20 mol % (CH2)2 units.
50. A composition comprising the polymer of any of claims 1 to 49 and one or hydrocarbon resins selected from the group consisting of aliphatic hydrocarbon resins, aromatic modified aliphatic hydrocarbon resins, hydrogenated polycyclopentadiene resins, polycyclopentadiene resins, gum rosins, gum rosin esters, wood rosins, wood rosin esters, tall oil rosins, tall oil rosins esters, polyterpenes, aromatic modified polyterpenes, terpene phenolics, aromatic modified hydrogenated polycyclopentadiene resins, hydrogenated aliphatic resin, hydrogenated aliphatic aromatic resins, hydrogenated terpenes and modified terpenes, and hydrogenated rosin esters.
51. The composition of claim 50 further wherein the hydrocarbon resin is present at 1 weight % to about 80 weight %.
52. The composition of claim 50 further wherein the hydrocarbon resin is present at less than 5% hydrocarbon resin.
53. A pallet comprising the polymer of any of claims 1 to 49.
54. A pellet comprising the composition of any of claims 50 to 52.
55. A continuous process to produce polymer of any of claims 1 to 49 comprising:
1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 15% or less under selected polymerization conditions;
2) selecting a second catalyst component capable of producing Polymer having an Mw of 100,000 or less and a crystallinity of 50% or more at the selected polymerization conditions;
3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins; and, 4) at a temperature of greater than 105°C;
5) at a residence time of 120 minutes or less;
5) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
56. The process of claim 55 wherein the first catalyst component comprises a stereospecific metallocene catalyst compound.
57. The process of claim 55 wherein the first catalyst component comprises a non-stereospecific metallocene catalyst compound.
58. The process of claim 55, 56 or 57 wherein the second catalyst component comprises a stereospecific metallocene catalyst compound,
59. The process of claim 55 wherein the first catalyst component comprises one or more of dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(tetrametltylcyclopentadienyl)(t-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(s-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dichloride, diethylsilyl(tetramethylcyclogentadienyl)(1-adamantylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dichloride, methylene(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(tetramethylcyalopentadienyl}(oyclododecylarxzxdo) titaniwn dimetltyl, ditnethylsilyl(tetramethylcyclopentadienyl)(exo-2-norborr~ylamida}
titanium dimethyl, dimetlxylsiiyl(tetrarnethyleyelcpentadienyl)(cycloltexyl-atnido) titaaiuxn dimethyl, dirr~ethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dime'thylsilyi(2,5-dimetlaylcyclapentadienyl)(Gyclododeeylamido} titanium dichloride, dimethylsilyl(2,S-dimethylcycloperatadienyl)(exo-2-norhozxiylaznido) titanium dichlozide, dimethyl~iayl(2,5-dimethylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2,5-diraetltylcyclopentadiex~yl)(1-adamarltylamido) titaniu~rn dichloride, dimethylsilyl(3,4-dimethyleyclopentadienyl)(cyclododeaylamxdo) titanium dichloride, dirnethylsilyl(3,4-dixnethylcyclopentadienyl}(exo-2-noxbornylamido) titanium dichl4zide, dimEthylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamida) titanium dichloride, dimethylsilyl(3,4-dimethylcyclopentadiez~yl)(1-adamazatylamido) titanitun dichloride, disnethylsilyl(2-ethyl-S-methyleyclopentadiertyl}(cyclododacylamido)titanivrn dichloride, dimethylsilyl(2-ethyl-5-rnethyloyclopentadienyl)(exo-2-narbornyi~nido) titanium dichloride, dimethylsilyl(2-ethyl-5-methylcyclapentadienyl~(cyclohexylamido) titanium diehlpride, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclododecylamido)titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dichloride, dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dichloride, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(t-butylamido) titanium dimethyl, dimethylsilyl(tatramethylcyclopentadienyl)(s-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(n-butylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, diethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclododecyl-amido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(exo-Z-norbomylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, methylene(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(cyclohexyl-amido) titanium dimethyl, dimethylsilyl(tetramethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2,5S-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2,S-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2,5-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3,4-dimethylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclododecylamido)titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-5-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl){cyclododecylamido)titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(3-ethyl-4-methylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(exo-2-norbomylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-ethyl-3-hexyl-5-methyl-4-octylcyclopentadienyl)(1-adamantylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclododecylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(cyclohexylamido) titanium dimethyl, dimethylsilyl(2-tetrahydroindenyl)(1-adamantylamido) titanium dimethyl, and dimethylsilyl(2-tetrahydroindenyl)(exo-2-norbomylamido) titanium dimethyl.
60. The process of claim 55 wherein the second catalyst component comprises one or more of the racemic versions of:
dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) zirconium dimethyl, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dichloride, dimethylsilyl (2-methyl-4-phenylindenyl) hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dimethyl, dimethylsilyl bis(indenyl)hafnium dichloride, dimethylsilyl bis(indenyl)ziconium dimethyl, dimethylsilyl bis(indenyl)zirconium dichloride, the racemic isomers of:
dimethylsilanediylbis(2-methyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dichloride;
dimethylsilanediylbis(indenyl)metal dimethyl;
dimethylsilanediylbis(tetrahydroindenyl)metal dichloride;
dimethylsilanediylbis(tetrahydroindenyl)metal dimethyl;
dimethylsilanediylbis(indenyl)metal diethyl; and dibenzylsilanediylbis(indenyl)metal dimethyl;
wherein the metal can be chosen from Zr, Hf, or Ti.
61. The process of any of claims 55 to 60 wherein the activator comprises an alumoxane.
62. The process of any of claims 55 to 61 wherein the activator comprises an ionizing compound.
63. The process of any of claims 55 to 62 wherein the activator comprises a non-coordinating anion.
64. The process of any of claims 55 to 60 wherein the activator comprises one or more of methylalumoxane, trimethylammonium tetraphenylborate, triethylammonium tetraphenylborate, tripropylammonium tetraphenylborate, tri(n-butyl)ammonium tetraphenylborate, tri(t-butyl)ammonium tetraphenylborate, N,N-dimethylanilinium tetraphenylborate, N,N-diethylaniliniurn tetraphenylborate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetraphenylborate, trimethylammonium tetrakis(pentafluorophenyl)borate, triethylammonium tetrakis(pentafluorophenyl)borate, tripropylammonium tetrakis(pentafluorophenyl)borate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, tri(sec-butyl)ammonium tetrakis(pentafluorophenyl) borate, N,N-dimethylanilinium tetrakis(pentafluorophenyl) borate, N,N-diethylanilinium tetrakis(pentafluorophenyl) borate, N,N-dimethyl-(2,4,6-trimethylanilinium) tetrakis(pentafluorophenyl) borate, trimethylammonium tetrakis-(2,3,4,6-tetrafluorophenylborate, triethylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, tripropylammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, tri(n-butyl)ammonium tetrakis-(2,3,4,6-tetrafluoro phenyl) borate, dimethyl(t-butyl)ammonium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, N,N-dimethylanilinium tetrakis.(2,3,4,6-tetrafluorophenyl) borate, N,N-diethylanilinium tetrakis-(2,3,4,6-tetrafluorophenyl) borate, and N,N-dimethyl-(2,4,6-trimethylanilinium)tetrakis-(2,3,4,6-tetrafluorophenyl) borate;
di-(i-propyl)ammonium tetrakis(pentafluorophenyl) borate;
dicyclohexylammonium tetrakis(pentafluorophenyl) borate;
triphenylphosphonium tetrakis(pentafluorophenyl) borate;
tri(o-tolyl)phosphonium tetrakis(pentafluorophenyl) borate; and tri(2,6-dimethylphenyl)phosphonium tetrakis(pentafluorophenyl) borate.
65. The process of any of claims 55 to 64 wherein the first catalyst component as capable of polymerizing macromonomers having reactive termini; and the second component is capable of producing macromonomers having reactive termini.
66. The process of any of claims 55 to 65 further comprising diolefin.
67. The process of any of claims 55 to 65 further comprising one or more C4 to C40 dienes.
68. The process of any of claims 55 to 65 further comprising diene selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
69. The process of any of claims 55 to 65 further comprising one or more dienes selected from the group consisting of 1,6-heptadiene, 1,7-octadiene, 1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene, 1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, etnylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, or combinations thereof.
70. The process of any of claims 55 to 69 wherein the reaction zone is a gas phase reactor.
71. The process of any of claims 55 to 69 wherein the reaction zone is a solution phase reactor.
72. The process of any of claims 55 to 69 wherein the reaction zone is a slurry phase reactor.
73. The process of any of claims 55 to 69 wherein the reaction zone is a solution phase reactor.
74. The process of any of claims 55 to 73 where the catalysts comprise one or more of the following combinations (where Me equals methyl, Ph equals phenyl, Et equals ethyl, Cp equals cyclopentadienyl, 3,8-di-t-BuFlu equals 3,8-di-tert-butylfluorenyl, 2-Me-4-PhInd equals 2-methyl-4-phenylindenyl, 2-MeInd equals 2-methylindenyl, c-C12H23 equals cyclododecyl, Me4C5 equals tetramethylcyclopentadienyl, H4Ind equals tetrahydroindenyl, and Ind equals indenyl):
(1) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(2) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator, (2a) Me2Si(Me4C5)(N-c-C12H13)TiMe2 and rac-Me2Si(2-Me-4 PhInd)2ZrMe2 activated with N,N-dimethylanillinium tetrakis(pentafluorophenyl)boron and or triphenylcarbonium tetrakis(pentafluorophenyl)boron;

(3) Me2Si(Me4C5)(N-c-C12H23)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;

(4) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;

(4a) Me2Si(Me4C5)(N-c-C12H23)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;

(5) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;

(6) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;

(6a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;

(7) Me2Si(Me4C5)(N-1-adamantyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;

(8) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;

(8a) Me2Si(Me4C5)(N-1-adamantyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(9) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(10) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-Phind)2ZrMe2 activated with a non-coordinating anion activator;
(10a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(11) Me2Si(Me4C5)(N-t-butyl)TiCl2 and rac-Me2Si(2-MeInd) activated with an alumoxane;
(12) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated With a nan-coordinating anion activator;
(12a) Me2Si(Me4C5)(N-t-butyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and ar triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(13) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(14) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(14a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(15) Me2Si(Me4C5)(N-exo-norbornyl)TiCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(16) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(16a) Me2Si(Me4C5)(N-exo-norbornyl)TiMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(17) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(18) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(18a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(19) (p-Et3Siph)2C(Cp)(3,8-di-t-BuFlu)HfCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(20) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;

Page 25a (20a) (p-Et3SiPh)2C(Cp)(3,8-di-t-BuFlu)HfMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(21) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(H4Ind)2ZrCl2 activated with an alumoxane;
(22) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;
(22a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(23) meso-CH2CH2(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(24) meso-CH2CH2(Ind2)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(24a) meso-CH2CH2(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(25) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(He4Ind)2ZrCl2 activated with an alumoxane;
(26) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with a non-coordinating anion activator;

(26a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(H4Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(27) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(28) meso-Me2Si(Ind)2ZrMe1 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(28a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(29) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(30) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(30a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(31) meso-Me2Si(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(32) meso-Me2Si(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;

(32a) meso-Me2Si(2-MeInd)2ZrMe2 sand rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(33) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(34) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(34a) mesa-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(35) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-Me2Si(2-MeInd)2ZrCl2 activated with an alumoxane;
(36) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(36a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-Me2Si(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium;
tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(37) meso-Me2Si(2-Me-4-PhInd)2ZrCl2 and rac-Me2Si(2-ME-4-PhInd)2ZrCl2 activated with an alumoxane;
(38) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;

(38a) meso-Me2Si(2-Me-4-PhInd)2ZrMe2 and rac-Me2Si(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(39) meso-CH2CH2(2-Me-4-PhInd)2ZrCl2 and rac-CH2CH2(2-Me-4-PhInd)2ZrCl2 activated with an alumoxane;
(40) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with a non-coordinating anion activator;
(40a) meso-CH2CH2(2-Me-4-PhInd)2ZrMe2 and rac-CH2CH2(2-Me-4-PhInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(41) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(2-MePhInd)2ZrCl2 activated with an alumoxane;
(42) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with a non-coordinating anion activator;
(42a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(2-MeInd)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(43) meso-CH2CH2(Ind)2ZrCl2 and rac-CH3CH2(Ind)2ZrGl2 activated with an alumoxane;

(44) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(44a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2H2(Ind)2ZrMe2 activated with N,N'-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(45) meso-Me2Si(Ind)2ZrCl2 and rac-Me2Si(Ind)2ZrCl2 activated with an alumoxane;
(46) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with a non-coordinating anion activator;
(46a) meso-Me2Si(Ind)2ZrMe2 and rac-Me2Si(Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(47) meso-CH2CH2(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(48) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(48a) meso-CH2CH2(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(49) meso-Me2Si(Ind)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;

(50) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(50a) meso-Me2Si(Ind)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(51) meso-CH2CH2(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 (4,7-Me2Ind = 4,7-dimethylindenyl) activated with an alumoxane;
(52) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(52a) meso-CH2CH2(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
(53) meso-Me2-Si(2-MeInd)2ZrCl2 and rac-CH2CH2(4,7-Me2Ind)2ZrCl2 activated with an alumoxane;
(54) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with a non-coordinating anion activator;
(54a) meso-Me2Si(2-MeInd)2ZrMe2 and rac-CH2CH2(4,7-Me2Ind)2ZrMe2 activated with such as N,N-dimethylanilinium tetrakis(pentaflourophenyl)boron and or triphenylcarbonium tetrakis(pentaflourophenyl)boron;
75. The process of any of claims 55 to 74 wherein the second catalyst component comprises one or more of:
dimethylsiladiyl(2-methyl, 4-(3',5',di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl{2-iso-propyl, 4-[3',5'-di-tbutylphenyl]2indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
dimethylsiladlyl(2-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3'5'-di-tbutylphenyl]indenyl)2zirconium dichloride;

9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium, dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;

dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso butyl, 4-[3',5'-di..tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;

9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
4-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;

dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',3'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2hafnium dichloride;

9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluorendiyl{2-iso-propyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dichloride;
9-silafluotendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;

dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;

dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl) 2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis- trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2hafnium dimethyl;

dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylsiladiyl(2-iso-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;

9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;

dimethylsiladiyl(2-isobutyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) 2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3';5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;

9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-propyl, 4-(3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;

dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-iso-butyl, 4-(3',3'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'_di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-methyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;

9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylpbenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyi]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;

dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-sec-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl}2hafnium dimethyl;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-ethyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-propyl, 4.-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;

9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dichloride;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2hafnium dimethyl;
dimethylsiladiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-his-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di- iso propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

dimethylsiladiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylsiladiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3 butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-(3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9.silafluorendiyl(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

9-silafluorendiyl(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl))2 .eta.4-1,4-diphenyl-1,3-butadiene;
9-silafluorendiyl(2-tert-butyl, 4-[3',5'-di-phenylphenyl)indenyl))2 .eta.4-1,4-biphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylanaidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;

dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride, dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride:

dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-tert butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
dimethylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4 1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane{2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4.
diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
dimethylamidoborane(2-methyl, 4-(3',5'-di-tbutylphenyl]indenyl)2 zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;

dimethylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;

dimethylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
dimethylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;

diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl)indenyl)2zirconium dichloride;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-n propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;

diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenylindenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2.eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl)indenyl)2 .eta.4-1, 4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2-zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;

diisopropylamidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborarane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)zirconium dimethyl;
diisopropylamidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-n-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;

diisopropylamidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
diisopropylamidoborane(2-tert-butyl, 4-[3,5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl(2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-(3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-bis-trifluoromethylphenyl)indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;

bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-(3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dichloride;

bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis{trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl}2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5' bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;

bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl) .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl(2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4- 1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2 .eta.4-1,4-diphenyl-1,3-butadiene;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5' -di-phenylphenyl]indenyl)2 .eta.4-1,4.diphenyl-1,3-butadiene;

bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3,5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-tbutylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-bis-trifluoromethylphenyl)indenyl)2 zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-bis-trifluoromethylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;

bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-iso-propylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-methyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-ethyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-propyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-n-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-iso-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl;
bis(trimethylsilyl)amidoborane(2-sec-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl; or bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl.
76. The process of any of claims 55 to 75 wherein the second catalyst component comprises one or more of bis(trimethylsilyl)amidoborane(2-tert-butyl, 4-[3',5'-di-phenylphenyl]indenyl)2zirconium dimethyl.
77. A continuous process to prepare an adhesive comprising:
1) ~combining monomer, solvent, catalyst and activator in a reactor system, 2) ~withdrawing polymer solution from the reactor system, 3) ~removing at least 10% solvent from the polymer solution, 4) ~quenching the reaction, 5)~devolatilizing the polymer solution to form molten polymer, 6) ~combining the molten polymer and one or more additives in a static mixer, 7) ~removing the polymer combination from the static mixer, and 8) ~pelletizing or drumming the polymer combination.
78. A continuous process in accordance with claim 55 to produce a branched olefin polymer comprising wherein:
1) ~the first catalyst component is capable of producing a polymer having an Mw of 80,000 or less and a crystallinity of 5% or less under selected polymerization conditions;
2) ~the second catalyst component capable of producing polymer having an Mw of 80,000 or less and a crystallinity of 20% or more at the selected polymerization conditions;
3) ~contacting the catalyst components in the presence of one or more activators with propylene and one or more C4 to C20 olefins, and, optionally one or more C4 to C20 diolefins;
4) ~at a temperature of greater than 100°C;
5) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 20:1;
6) ~wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer.
79. The process of claim 78 wherein:

a) ~the olefins comprise propylene and one or more of butane, pentane, hexene, heptene, octane; nonene, decene, dodecene; and b) ~the temperature is greater than 110°C; and c) ~the residence time is 60 to 120 minutes; and d) ~the ratio of the first catalyst to the second catalyst is from 1:1 to 1:10.
80. ~The process of claim 78 or 79 wherein the diolefin is present and is selected from the group consisting of 1,6-heptadiene, 1,7-octadiene,1,8-nonadiene, 1,9-decadiene, 1,10-undecadiene,1,11-dodecadiene, 1,12-tridecadiene, 1,13-tetradecadiene, cyclopentadiene, vinylnorbornene, norbornadiene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, polybutadienes having an Mw less than 1000 g/mol, butadiene, pentadiene, hexadiene, pentadecadiene, hexadecadiene, heptadecadiene, octadecadiene, nonadecadiene, icosadiene, heneicosadiene, docosadiene, tricosadiene, tetracosadiene, pentacosadiene, hexacosadiene, heptacosadiene, octacosadiene, nonacosadiene, triacontadiene, cyclopentadiene, vinylnorbornene, norbornediene, ethylidene norbornene, divinylbenzene, dicyclopentadiene, or combinations thereof.
81. ~The process of claim 78, 79 or 80 wherein the olefin comprises propylene and one or more of butane, pentene, hexene, heptene, octene, nonene, decene, dodecene, 4-methyl-pentene-1, 3-methyl pentene-1, and 3,5,5-trimethyl-hexane-1.
82, ~A continuous process to make an adhesive comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions;
2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 ar less and a crystallinity of 20% or more at the selected polymerization conditions;

3) ~contacting, in a solvent and in a reaction zone under the selected polymerization conditions, the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins;
4) ~at a temperature of greater than 100°C;
5)~at a residence time of 120 minutes or less;
6) ~wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1;
7) ~wherein the activity of the catalyst components is at least 50 kilograms of polymer per gram of the catalyst compounds; and wherein at least 80% of the olefins are converted to polymer;
8) ~withdrawing polymer solution from the reaction zone;
9) ~removing at least 10% solvent from the polymer solution;
10) ~quenching the reaction;
11) ~devolatilizing the polymer solution to form molten polymer;
12) ~combining the molten polymer and one or more additives in a static mixer;
13) ~removing the polymer combination from the static mixer; and 14) ~pelletizing or drumming the polymer combination.
CA 2499951 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom Expired - Fee Related CA2499951C (en)

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