CA2590169A1 - Oilwell sealant compositions comprising alkali swellable latex - Google Patents

Oilwell sealant compositions comprising alkali swellable latex Download PDF

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Publication number
CA2590169A1
CA2590169A1 CA002590169A CA2590169A CA2590169A1 CA 2590169 A1 CA2590169 A1 CA 2590169A1 CA 002590169 A CA002590169 A CA 002590169A CA 2590169 A CA2590169 A CA 2590169A CA 2590169 A1 CA2590169 A1 CA 2590169A1
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CA
Canada
Prior art keywords
sealant composition
alkali
cement
earth metal
combinations
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002590169A
Other languages
French (fr)
Other versions
CA2590169C (en
Inventor
B. Raghava Reddy
Mark R. Savery
Krishna M. Ravi
Donald L. Whitfill
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halliburton Energy Services Inc
Original Assignee
Halliburton Energy Services, Inc.
B. Raghava Reddy
Mark R. Savery
Krishna M. Ravi
Donald L. Whitfill
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halliburton Energy Services, Inc., B. Raghava Reddy, Mark R. Savery, Krishna M. Ravi, Donald L. Whitfill filed Critical Halliburton Energy Services, Inc.
Publication of CA2590169A1 publication Critical patent/CA2590169A1/en
Application granted granted Critical
Publication of CA2590169C publication Critical patent/CA2590169C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • C09K8/5045Compositions based on water or polar solvents containing inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • C09K8/506Compositions based on water or polar solvents containing organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • C09K8/506Compositions based on water or polar solvents containing organic compounds
    • C09K8/508Compositions based on water or polar solvents containing organic compounds macromolecular compounds

Abstract

Sealant compositions comprising an alkali swellable latex and a pH increasing material and methods of using the same to service a wellbore are provided. In one embodiment, the sealant composition can be used in a wellbore and includes an alkali swellable latex and a pH increasing material. The sealant composition can have a pH of from about 7 to about 14. In other embodiments, the pH increasing material includes a base-producing material. The base~producing material can include alkali and alkali earth metal carbonates, alkali and alkali earth metal bicarbonates, alkali and alkali earth metal hydroxides, alkali and alkali earth metal oxides, alkali and alkali earth metal phosphates, alkali and alkali earth metal hydrogen phosphates, alkali and alkaline earth metal sulphides, alkali and alkaline earth metal salts of silicates, alkali and alkaline earth metal salts of aluminates, water soluble or water dispersible organic amines, polymeric amine, amino alcohols, or combinations thereof.

Claims (71)

1. A method of servicing a wellbore in contact with a subterranean formation, comprising:
placing an alkali swellable latex and a pH increasing material in the wellbore to form a sealant composition.
2. The method of claim 1, wherein the sealant composition comprises a pH of from about 7 to about 14.
3. The method of claim 1, wherein the sealant composition comprises a pH of from about 8 to about 13.
4. The method of claim 1, wherein the alkali swellable latex comprises an ethylenically unsaturated monomer containing at least one carboxylic acid functional group.
5. The method of claim 4, wherein the ethylenically unsaturated monomer containing at least one carboxylic functional group is present in the sealant composition in the amount of from about 5 to about 30 % by weight of the monomers used in preparing the alkali swellable latex.
6. The method of claim 1, wherein the alkali swellable latex comprises a vinyl aromatic monomer, an ethylene, a butadiene, a vinylnitrile, an olefinically unsaturated ester of C1-C8 alcohol, or combinations thereof.
7. The method of claim 1, wherein the alkali swellable latex comprises a crosslinking agent.
8. The method of claim 7, wherein the crosslinking agents comprise vulcanizing agents, vulcanization accelerators, vulcanization retarders, defoamers, or combinations thereof.
9. The method of claim 1, wherein the alkali swellable latex comprises from about 0.1 to about 5 wt. % of a crosslinking agent by weight of monomer.
10. The method of claim 1, wherein the alkali swellable latex is prepared by emulsion polymerization.
11. The method of claim 1, wherein the pH increasing material comprises a base-producing material, a cement, or combinations thereof.
12. The method of claim 1, wherein the pH increasing material comprises a base-producing material, and wherein the base-producing material comprises alkali and alkali earth metal carbonates, alkali and alkali earth metal bicarbonates, alkali and alkali earth metal hydroxides, alkali and alkali earth metal oxides, alkali and alkali earth metal phosphates, alkali and alkali earth metal hydrogen phosphates, alkali and alkaline earth metal sulphides, alkali and alkaline earth metal salts of silicates, alkali and alkaline earth metal salts of aluminates, water soluble or water dispersible organic amines, polymeric amines, amino alcohols, or combinations thereof.
13. The method of claim 1, wherein the sealant composition comprises a thermosetting resin.
14. The method of claim 13, wherein the thermosetting resin comprises an amino resin, a phenolic resin, a furfural resin, or combinations thereof.
15. The method of claim 1, wherein the sealant composition further comprises a surfactant.
16. The method of claim 1, wherein the sealant composition further comprises a defoamer.
17. The method of claim 1, wherein the pH increasing material comprises a cement, and wherein the cement comprises a hydraulic cement.
18. The method of claim 17, wherein the hydraulic cement comprises a Portland cement, a pozzolana cement, a gypsum cement, a phosphate cement, a high alumina content cement, a silica cement, a high alkalinity cement, a magnesia cement, or combinations thereof.
19. The method of claim 17, wherein the sealant composition further comprises a surfactant.
20. The method of claim 17, further comprising reducing fluid loss from the cement.
21. The method of claim 17, further comprising increasing tensile strength, reducing elastic modulus of the cement, reducing brittleness of the cement, or combinations thereof.
22. The method of claim 1, wherein the sealant composition further comprises a fluid absorbing material, a particulate material, a superabsorber, a viscosifying agent, a non-alkali swellable latex, or combinations thereof.
23. The method of claim 1, wherein the sealant composition further comprises a fluid absorbing material, and wherein the fluid absorbing material comprises organophilic clay, water swellable clay, a water absorbing mineral, an oil absorbing mineral, or combinations thereof.
24. The method of claim 1, wherein the sealant composition further comprises particulate material, and further wherein the sealant composition comprises a first portion of particulate material having a weight mean particle size of less than about 20 microns; a second portion of particulate material having a weight mean particle size in the range of from about 25 microns to about 400 microns, and a third portion of particulate material having a weight mean particle size in the range of from about 450 microns to about 1,500 microns.
25. The method of claim 24, wherein at least about 20% by weight of the sealant composition comprises particulate material comprising resilient particles, thermoset polymer laminate particles, or combinations thereof.
26. The method of claim 1, wherein the sealant composition comprises particulate materials in an amount between about 5 and about 35% by weight of the sealant composition.
27. The method of claim 1, wherein the sealant composition comprises a superabsorber, and wherein the superabsorber comprises a crosslinked polyacrylamide; a crosslinked polyacrylate;
a crosslinked hydrolyzed polyacrylonitrile; a salt of carboxyalkyl starch; a salt of carboxyalkyl cellulose; a salt of any crosslinked carboxyalkyl polysaccharide; a crosslinked copolymer of acrylamide and acrylate monomers; a starch grafted with acrylonitrile and acrylate monomers;
a crosslinked polymer of two or more of allylsulfonate, 2-acrylamido-2-methyl-propanesulfonic acid, 3-allyloxy-2-hydroxy-1-propane-sulfonic acid, acrylamide, and acrylic acid monomers; or combinations thereof.
28. The method of claim 1, wherein the sealant composition further comprises a viscosifying agent.
29. The method of claim 1, wherein the sealant composition further comprises a non-alkali swellable latex.
30. The method of claim 1, wherein the sealant composition is positioned in the wellbore to isolate the subterranean formation from a portion of the wellbore, to support a conduit in the wellbore, to plug a void or crack in the conduit, to plug a void or crack in a cement sheath disposed in an annulus of the wellbore, to plug an opening between the cement sheath and the conduit, to mitigate a loss of aqueous or non-aqueous drilling fluids into loss circulations zones, to be used as a fluid in front of a cement slurry, or to seal an annulus between the wellbore and an expandable pipe or pipe string.
31. The method of claim 1, further comprising combining the alkali swellable latex and the pH increasing material near a loss-circulation zone, to form the sealant composition in the loss-circulation zone.
32. The method of claim 1, further comprising introducing the pH increasing material and a drilling fluid or separate inert carrier fluid into the wellbore in a separate flowpath from the alkali swellable latex.
33. The method of claim 1, further comprising introducing the pH increasing material and the alkali swellable latex to the wellbore in a flowpath.
34. The method of claim 33, further comprising encapsulating the pH increasing material.
35. A method of increasing viscosity of a sealant composition, comprising:
(A) introducing an alkali swellable latex and a pH increasing material to a wellbore;
and (B) contacting the alkali swellable latex with the pH increasing material to form the sealant composition, wherein the pH increasing material increases the viscosity of the sealant composition.
36. The method of claim 35, wherein a sufficient amount of the pH increasing material is contacted with the alkali swellable latex to increase the viscosity of the alkali swellable latex.
37. The method of claim 35, wherein a sufficient amount of the pH increasing material is contacted with the alkali swellable latex to provide the sealant composition having a pH of from about 7 to about 14.
38. The method of claim 35, wherein a sufficient amount of the pH increasing material is contacted with the alkali swellable latex to provide the sealant composition having a pH of from about 8 to about 13.
39. The method of claim 35, wherein step A) further comprises introducing the alkali swellable latex and the pH increasing material to the wellbore in separate flowpaths.
40. The method of claim 35, wherein step A) further comprises introducing the alkali swellable latex and the pH increasing material to the wellbore in a flowpath.
41. The method of claim 40, wherein the pH increasing material is encapsulated.
42. A sealant composition for use in a wellbore, comprising: an alkali swellable latex and a pH increasing material, wherein the sealant composition has a pH of from about 7 to about 14.
43. The sealant composition of claim 42, wherein the sealant composition comprises a pH
of from about 8 to about 13.
44. The sealant composition of claim 42, wherein the sealant composition comprises a pH
of from about 9 to about 13.
45. The sealant composition of claim 42, wherein the alkali swellable latex further comprises an ethylenically unsaturated monomer containing at least one carboxylic acid functional group.
46. The sealant composition of claim 45, wherein the ethylenically unsaturated monomer containing at least one carboxylic functional group is present in the sealant composition in the amount of from about 5 to about 30 % by weight of the monomers used in preparing the alkali swellable latex.
47. The sealant composition of claim 42, wherein the alkali swellable latex comprises a vinyl aromatic monomer, an ethylene, a butadiene, a vinylnitrile, an olefinically unsaturated ester of C1-C8 alcohol, or combinations thereof.
48. The sealant composition of claim 42, wherein the alkali swellable latex comprises a crosslinking agent.
49. The sealant composition of claim 48, wherein the crosslinking agents comprise vulcanizing agents, vulcanization accelerators, vulcanization retarders, defoamers, or combinations thereof.
50. The sealant composition of claim 42, wherein the alkali swellable latex comprises from about 0.1 to about 5 wt. % of a crosslinking agent by weight of monomer.
51. The sealant composition of claim 42, wherein the alkali swellable latex is prepared by emulsion polymerization.
52. The sealant composition of claim 42, wherein the pH increasing material comprises a base-producing material, a cement, or combinations thereof.
53. The sealant composition of claim 42, wherein the pH increasing material comprises a base-producing material, and wherein the base-producing material comprises alkali and alkali earth metal carbonates, alkali and alkali earth metal bicarbonates, alkali and alkali earth metal hydroxides, alkali and alkali earth metal oxides, alkali and alkali earth metal phosphates, alkali and alkali earth metal hydrogen phosphates, alkali and alkaline earth metal sulphides, alkali and alkaline earth metal salts of silicates, alkali and alkaline earth metal salts of aluminates, water soluble or water dispersible organic amines, polymeric amines, amino alcohols, or combinations thereof.
54. The sealant composition of claim 42, wherein the sealant composition comprises a thermosetting resin.
55. The sealant composition of claim 54, wherein the thermosetting resin comprises an amino resin, a phenolic resin, a furfural resin, or combinations thereof.
56. The method of claim 42, wherein the sealant composition further comprises a surfactant.
57. The method of claim 42, wherein the sealant composition further comprises a defoamer.
58. The sealant composition of claim 42, wherein the pH increasing material comprises a cement, and wherein the cement comprises a hydraulic cement.
59. The sealant composition of claim 58, wherein the hydraulic cement comprises a Portland cement, a pozzolana cement, a gypsum cement, a phosphate cement, a high alumina content cement, a silica cement, a high alkalinity cement, a magnesia cement, or combinations thereof.
60. The method of claim 42, wherein the sealant composition further comprises a surfactant.
61. The method of claim 42, further comprising reducing fluid loss from the cement.
62. The method of claim 42, further comprising increasing tensile strength, reducing elastic modulus of the cement, reducing brittleness of the cement, or combinations thereof.
63. The sealant composition of claim 42, wherein the sealant composition further comprises a fluid absorbing material, a particulate material, a superabsorber, a viscosifying agent, a non-alkali swellable latex, or combinations thereof.
64. The sealant composition of claim 42, wherein the sealant composition further comprises a fluid absorbing material, and wherein the fluid absorbing material comprises organophilic clay, water swellable clay, a water absorbing mineral, an oil absorbing mineral, or combinations thereof.
65. The sealant composition of claim 42, wherein the sealant composition further comprises particulate material, and further wherein the sealant composition comprises a first portion of particulate material having a weight mean particle size of less than about 20 microns; a second portion of particulate material having a weight mean particle size in the range of from about 25 microns to about 400 microns, and a third portion of particulate material having a weight mean particle size in the range of from about 450 microns to about 1,500 microns.
66. The sealant composition of claim 65, wherein at least about 20% by weight of the sealant composition comprises particulate material comprising resilient particles, thermoset polymer laminate particles, or combinations thereof.
67. The sealant composition of claim 42, wherein the sealant composition comprises particulate materials in an amount between about 5 and about 35% by weight of the sealant composition.
68. The sealant composition of claim 42, wherein the sealant composition comprises a superabsorber, and wherein the superabsorber comprises a crosslinked polyacrylamide; a crosslinked polyacrylate; a crosslinked hydrolyzed polyacrylonitrile; a salt of carboxyalkyl starch; a salt of carboxyalkyl cellulose; a salt of any crosslinked carboxyalkyl polysaccharide; a crosslinked copolymer of acrylamide and acrylate monomers; a starch grafted with acrylonitrile and acrylate monomers; a crosslinked polymer of two or more of allylsulfonate, 2-acrylamido-2-methyl-1-propanesulfonic acid, 3-allyloxy-2-hydroxy-1-propane-sulfonic acid, acrylamide, and acrylic acid monomers; or combinations thereof.
69. The sealant composition of claim 42, wherein the sealant composition further comprises a viscosifying agent.
70. The sealant composition of claim 42, wherein the sealant composition further comprises a non-alkali swellable latex.
71. The sealant composition of claim 42, further comprising a drilling fluid.
CA2590169A 2004-12-08 2005-11-18 Oilwell sealant compositions comprising alkali swellable latex Expired - Fee Related CA2590169C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/010,117 US7488705B2 (en) 2004-12-08 2004-12-08 Oilwell sealant compositions comprising alkali swellable latex
US11/010,117 2004-12-08
PCT/GB2005/004455 WO2006061561A1 (en) 2004-12-08 2005-11-18 Oilwell sealant compositions comprising alkali swellable latex

Publications (2)

Publication Number Publication Date
CA2590169A1 true CA2590169A1 (en) 2006-06-15
CA2590169C CA2590169C (en) 2010-08-03

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CA2590169A Expired - Fee Related CA2590169C (en) 2004-12-08 2005-11-18 Oilwell sealant compositions comprising alkali swellable latex

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US (2) US7488705B2 (en)
EP (1) EP1853680B1 (en)
BR (1) BRPI0517496A (en)
CA (1) CA2590169C (en)
DE (1) DE602005020518D1 (en)
MX (1) MX2007006891A (en)
WO (1) WO2006061561A1 (en)

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CA2590169C (en) 2010-08-03
MX2007006891A (en) 2008-01-21
US7488705B2 (en) 2009-02-10
US8383558B2 (en) 2013-02-26
EP1853680A1 (en) 2007-11-14
US20060122071A1 (en) 2006-06-08
US20090137431A1 (en) 2009-05-28
EP1853680B1 (en) 2010-04-07
WO2006061561A1 (en) 2006-06-15
BRPI0517496A (en) 2008-10-07

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