CN100467946C - Combustion system for changing methanol into hydrogen fuel used in industrial furnace and thermal power plant. - Google Patents

Combustion system for changing methanol into hydrogen fuel used in industrial furnace and thermal power plant. Download PDF

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Publication number
CN100467946C
CN100467946C CNB2007100488087A CN200710048808A CN100467946C CN 100467946 C CN100467946 C CN 100467946C CN B2007100488087 A CNB2007100488087 A CN B2007100488087A CN 200710048808 A CN200710048808 A CN 200710048808A CN 100467946 C CN100467946 C CN 100467946C
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methyl alcohol
waste heat
hydrogen
heat
chamber
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CN101038078A (en
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王均衡
王衍衡
王官胜
陈忠
张伟民
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

The present invention discloses a burning system using hydrogen fuel changed from methanol in industrial furnace and power station. The burning system is composed of a hydrogen making burning system, a heat transfer oil heating cycle system, a furnace remaining heat smoke heating system, an air preheating system, a start system and a bypass recycle system. The heat transfer oil is heated by furnace smoke remaining heat, and makes the methanol liquid fuel vaporize. The methanol is transferred to fuel with hydrogen as main component by the hydrogen making system, the fuel is then provided to furnace to burn. The burning process will not generate dust and sulfur dioxide harmful gas, and greatly reduces the discharge amount of the carbon dioxide gas. The fuel is satisfy with the national environmental protection standard requirement and can become new type substitute energy for the industrial furnace. The system has the advantages of safety, stable running, miniaturization of equipments and reduced manufacturing cost.

Description

Industrial furnace and the thermal power station combustion system of changing methanol into hydrogen fuel
Technical field
The present invention relates to industrial flame combustion system, relate to specifically a kind ofly change methyl alcohol vaporization, catalysis, pyrolysis into the industrial furnace of hydrogen fuel or the combustion system that thermal power station uses.
Background technology
At present, the fuel that is used for industrial furnace mainly contains two classes: a class is to be fuel with diesel oil, heavy oil, natural gas and oil liquefied gas, and the problem of existence is burning cost height, and is strong to exhausted day by day oil dependence; Another kind of is to be fuel with coal, and the coal-fired contamination hazard that causes is well-known.Therefore, seek suitable alternative energy source is the target that industrial quarters is pursued always.
Hydrogen is a kind of clean energy resource of environment-friendly type, and methyl alcohol is considered to the hydrogen storage body of the most economical most convenient practicality of discovery at present.Methyl alcohol can be produced in a large number by non-petrochemical industry channel, for example produces from coal.Methyl alcohol is directly acted as a fuel, and the calorific value that produces owing to its burning is low, corrosivity is strong and emission pollution problem seriously fails to become industrial fuel.
The present general imperfection all of industrial furnace therrmodynamic system, its afterbody waste heat is owing to fail to utilize and cause energy waste and used heat to pollute, and the combustion system that methyl alcohol is become hydrogen fuel of creating the industrial furnace application is imperative.
Application number is 200610119905.9 Chinese patent, discloses " a kind of alcohol radical gasification reforming burning system that is used for industrial furnace ".This system utilizes flue gas afterbody waste heat, in order to reduce the thermal losses of flue gas, with vaporization of alcohol radical synthetic fuel or vaporization cracking after-combustion, has alleviated the corrosivity that liquid alcohol radical synthetic fuel directly burns and produces, and has improved calorific value.Its weak point: the one, utilize flue gas afterbody waste heat directly to alcohol radical synthetic fuel heating, flue gas contact because of leaking with fuel, and the stability that security, controllability, the system of equipment moved has a negative impact; The 2nd, it is big that waste heat heater volume is wanted, and causes cost to increase.
Summary of the invention
The objective of the invention is to: for industrial furnace and the user of thermal power station provide the combustion system that a kind of safety is controlled, stable, methyl alcohol become hydrogen fuel.
The objective of the invention is to be achieved through the following technical solutions:
Industrial furnace and thermal power station include hydrogen manufacturing combustion system, the heat-conducting oil heating circulatory system, stove waste heat flue gas heating system with the combustion system of changing methanol into hydrogen fuel, and be wherein said:
The hydrogen manufacturing combustion system, the methyl alcohol station, methanol feed pump, methanol fuel case, methyl alcohol measuring pump, the methanol fuel that include by the pipeline series connection carry switch valve, vaporizer, catalyst activation system, methyl alcohol catalyse pyrolysis to change hydrogen generator and burner;
The heat-conducting oil heating circulatory system comprises that the heat conduction fuel tank, filter, conduction oil circulating pump, waste heat heater, the methyl alcohol catalyse pyrolysis that link to each other in regular turn with pipeline change hydrogen generator and vaporizer;
Stove waste heat flue gas heating system comprises the waste heat acquisition port, smoke regulating valve, waste heat heater, waste heat smoke induced draught fan and the stove chimney that connect successively with pipeline;
It is characterized in that: also include air preheating system, start-up system and bypass recirculating system, wherein:
Air preheating system is connected to form by pipeline successively by combustion air acquisition port, air blast, waste heat heater, stove combustion air inlet;
Start-up system is connected to form by pipeline successively by methanol fuel case, methyl alcohol measuring pump, start-up system transfer valve, startup burner;
The bypass recirculating system is carried between the input of switch valve and the methyl alcohol measuring pump output and the pipeline that bypass valve constituted between methyl alcohol measuring pump input and the methanol fuel case output is formed by being arranged on methanol fuel in the hydrogen manufacturing combustion system;
In described hydrogen manufacturing combustion system, being arranged on burner and methyl alcohol catalyse pyrolysis in addition in regular turn changes steam-water separator and methyl alcohol preheating and the hydrogen storage device that is connected by pipeline between the hydrogen generator, and is arranged on the heat booster that is connected by pipeline between methyl alcohol catalyse pyrolysis commentaries on classics hydrogen generator and the vaporizer;
In the described heat-conducting oil heating circulatory system, also include and be arranged on the methyl alcohol catalyse pyrolysis and change the heat booster that is connected by pipeline between hydrogen generator and the vaporizer;
Be arranged on methanol fuel in the hydrogen manufacturing combustion system in addition and carry methyl alcohol leading portion transfer pipeline between the methyl alcohol input port of the output of switch valve and methyl alcohol preheating and hydrogen storage device, and be arranged on methyl alcohol back segment transfer pipeline between the methyl alcohol input port of the methyl alcohol output port of methyl alcohol preheating and hydrogen storage device and vaporizer, and connect the system's isolating valve, pipeline that starts between burner output and smoke regulating valve output pipeline.
Described hydrogen manufacturing combustion system is arranged on the spark arrester between burner and the steam-water separator in addition.
Described waste heat heater mainly is made of three chambers that are communicated with successively, i.e. the bottom waste heat flue gas that has the gas approach flue gas cooling and the air preheating chamber at heat-conducting oil heating chamber and top at combustion chamber, middle part of holding concurrently; The wherein said waste heat flue gas combustion chamber of holding concurrently is burning or waste heat flue gas supply room, and this chamber outer wall has waste heat smoke inlet pipe;
Described heat-conducting oil heating chamber for holding the chamber of conduction oil, is placed with waste heat exhaust gases passes tubulation in this chamber, and the diaphragm that the control conduction oil flows to is set, and this heat-conducting oil heating locular wall is provided with conduction oil inlet tube and following conduction oil outlet;
Described flue gas cooling and air preheating chamber, chamber for waste heat flue gas and the heat exchange of cold air tubulation, be placed with heat exchange air tubulation in this chamber, be provided with cold flue gas outlet pipe in this chamber roof, the chamber wall both sides are provided with cold air inlet duct and preheated air outlet.
Operation principle of the present invention is as follows:
At first, start-up system: open the heat conduction fuel tank and make oil circulation, the start-up system transfer valve, light the startup burner, the methyl alcohol flame burns in the waste heat heater and makes the conduction oil preheating, when the conduction oil of circulation reaches 260 ℃ at waste heat heater outlet place, the methanol fuel of opening in the hydrogen manufacturing combustion system is carried switch valve, methyl alcohol is successively by methyl alcohol preheating and hydrogen storage device, the vaporizer vaporization, heat booster heats up, changeing in the hydrogen generator catalyst by activation at the methyl alcohol catalyse pyrolysis is converted into the methyl alcohol pyrolysis and contains Hydrogen fuel, enter then in methyl alcohol preheating and the hydrogen storage device and store, when reaching the working pressure of setting, make to contain Hydrogen fuel and enter steam-water separator and isolate condensate water, light stove by burner and air blast air-supply then.
When the temperature of stove waste heat acquisition port reaches setting value, open stove waste heat flue gas heating system, close start-up system simultaneously, the stove operate as normal, heating, methyl alcohol vaporization, catalysis and the pyrolysis of circulating heat conduction oil are converted into the needed heat of hydrogen reaction process at this moment provides by the stove waste heat.
The invention has the advantages that:
1, makes the oil liquefied gas alternative fuel with methyl alcohol, not only reduced industrial furnace to the dependence of oil but also avoid the burnt gas environmental pollution;
2. because conduction oil is non-combustible material, use conduction oil as the heat carrier of waste heat flue gas and the medium of hydrogen from methyl alcohol, avoid the possibility of flue gas contact fuel, improved the stability of controllability, security and the operation of system's use, helped the miniaturization of equipment;
3. compared with prior art,, produced three kinds of effects owing in the hydrogen manufacturing combustion system, be provided with heat booster, methyl alcohol preheating and hydrogen storage device: the one, heat booster provides methanol conversion required necessary temp, has improved methanol conversion efficient; The 2nd, the utilization of methyl alcohol preheating and hydrogen storage device can effectively utilize the reaction heat heating methanol, has saved energy; The 3rd, the use of heat booster, methyl alcohol preheating and hydrogen storage device can make waste heat heater and vaporizer realize miniaturization, has reduced system's manufacturing cost;
4. owing to adopt the bypass recirculating system, guaranteed that measuring pump all operates in the scope of measuring pump characteristic curve requirement in stove starting state and production status, played the effect of adjusting and protecting measuring pump.
5. the present invention is particularly suitable for the industrial furnace use, alleviation stove fuel is too relied on oil have positive role.
6. the native system stove does not produce dust and sulfur dioxide pernicious gas owing to use hydrogen to make fuel, has significantly reduced emission of carbon-dioxide yet, can meet the environmental protection standard requirement of country fully, and is easy to utilize.
Description of drawings
Fig. 1 is the structural representation of system of the present invention
Fig. 2 is methyl alcohol preheating and hydrogen storage device vertical profile structural representation
Fig. 3 changes hydrogen generator vertical profile structural representation for the methyl alcohol catalyse pyrolysis
Fig. 4 is a waste heat heater vertical profile structural representation
Mark among the figure: 1. stove chimney, 2. waste heat smoke induced draught fan, 3. waste heat heater, 4. the stove combustion air enters the mouth, 5. air blast, 6. combustion air acquisition port, 7. smoke regulating valve, 8. waste heat acquisition port, 9. system's isolating valve,, 10. startup burner, 11. methanol fuel case, 12. bypass valve, 13. methanol feed pump, 14. methyl alcohol station, 15. methyl alcohol measuring pump, 16. start-up system transfer valve, 17. methanol fuel is carried switch valve, 18. vaporizer, 19. heat booster, 20. the methyl alcohol catalyse pyrolysis changes hydrogen generator, 21. methyl alcohol preheating and hydrogen storage device, 22. steam-water separator, 23. burner, 24. spark arrester, 25. catalyst activation system, 26. heat conduction fuel tank, 27. filter, 28. conduction oil circulating pump, carry methyl alcohol leading portion transfer pipeline between the methyl alcohol input port of switch valve output and methyl alcohol preheating and hydrogen storage device 29. be arranged on methanol fuel, 30. be arranged on the methyl alcohol back segment transfer pipeline between the methyl alcohol input port of the methyl alcohol output port of methyl alcohol preheating and hydrogen storage device and vaporizer, 31. the methyl alcohol tube channel in methyl alcohol preheating and the hydrogen storage device cavity, 32. hydrogen-containing gas storage chamber, 33. methanol inlet pipe, 34. the methyl alcohol outlet, 35. hydrogen-containing gas inlet tubes, 36. hydrogen-containing gas outlets, 37. the methyl alcohol catalyse pyrolysis changes the lumen that is installed in catalyst and methyl alcohol generation pyrolytic reaction in the hydrogen generator cavity, 38. the heat-conducting oil heating chamber, the 39. methanol gas input mouth of pipe, the 40. hydrogen-containing gas output mouth of pipe, 41. the conduction oil input mouth of pipe, 42. the conduction oil output mouth of pipe, 43. waste heat heater base have the waste heat flue gas of the gas approach combustion chamber of holding concurrently, 44. cold flue gas outlet pipes, 45. be waste heat exhaust gases passes tubulation, 46. having conduction oil advances, the heat-conducting oil heating chamber of outlet, 47. are heat exchange air tubulation, 48. is cold air inlet duct, 49. be hot gas outlet duct, 50. be diaphragm, 51. is waste heat smoke inlet pipe, 52. is the conduction oil inlet tube, 53. be the conduction oil outlet, 54. is the flue gas cooling and the air preheating chamber at top.
The specific embodiment
Industrial furnace and thermal power station include hydrogen manufacturing combustion system, the heat-conducting oil heating circulatory system, stove waste heat flue gas heating system with the combustion system of changing methanol into hydrogen fuel, and air preheating system, start-up system and bypass recirculating system are wherein said:
The hydrogen manufacturing combustion system, carry switch valve 17 by methyl alcohol station 14, methanol feed pump 13, methanol fuel case 11, methyl alcohol measuring pump 15, methanol fuel by the pipeline series connection, methyl alcohol preheating and hydrogen storage device 21, vaporizer 18, heat booster 19, catalyst activation system 25 and methyl alcohol catalyse pyrolysis change hydrogen generator 20, steam-water separator 22, spark arrester 24 and burner 23 and form;
The heat-conducting oil heating circulatory system is changeed hydrogen generator 20, heat booster 19 and vaporizer 18 by the heat conduction fuel tank 26 that links to each other in regular turn with pipeline, filter 27, conduction oil circulating pump 28, waste heat heater 3, methyl alcohol catalyse pyrolysis and is formed;
Stove waste heat flue gas heating system is formed with waste heat acquisition port 8, smoke regulating valve 7, waste heat heater 3, waste heat smoke induced draught fan 2 and stove chimney 1 that pipeline connects successively;
Air preheating system is connected to form by pipeline successively by combustion air acquisition port 6, air blast 5, waste heat heater 3, stove combustion air inlet 4:
Start-up system is by methanol fuel case 11, methyl alcohol measuring pump 15, start-up system transfer valve 16, start burner 10 and be connected to form successively by pipeline;
The bypass recirculating system is formed by being arranged on the pipeline that methanol fuel in the hydrogen manufacturing combustion system is carried between the output of the input of switch valve 17 and methyl alcohol measuring pump 15 and the bypass valve 12 between methyl alcohol measuring pump 15 inputs and methanol fuel case 11 outputs is constituted;
In the described heat-conducting oil heating circulatory system, also include and be arranged on the methyl alcohol catalyse pyrolysis and change the heat booster 19 that is connected by pipeline between hydrogen generator 20 and the vaporizer 18;
Be arranged on methanol fuel in the hydrogen manufacturing combustion system in addition and carry methyl alcohol leading portion transfer pipeline 29 between the methyl alcohol input port of switch valve 17 outputs and methyl alcohol preheating and hydrogen storage device 21, and be arranged on methyl alcohol back segment transfer pipeline 30 between the methyl alcohol input port of the methyl alcohol output port of methyl alcohol preheating and hydrogen storage device 21 and vaporizer 18, and connect system's isolating valve, 9 pipelines that start between burner 10 outputs and smoke regulating valve 7 output pipelines.
Waste heat heater 3 mainly is made of three chambers that are communicated with successively, and promptly the bottom has the hold concurrently flue gas cooling and the air preheating chamber 54 at heat-conducting oil heating chamber 46 and top at combustion chamber 43, middle part of gas approach waste heat flue gas; The wherein said waste heat flue gas combustion chamber 43 of holding concurrently is burning or waste heat flue gas supply room, and this chamber outer wall has waste heat smoke inlet pipe 51;
Described heat-conducting oil heating chamber 46, for holding the chamber of conduction oil, be placed with waste heat exhaust gases passes tubulation 45 in this chamber, and the diaphragm 50 that the control conduction oil flows to is set, these heat-conducting oil heating chamber 46 walls are provided with conduction oil inlet tube 52 and following conduction oil outlet 53;
Described flue gas cooling and air preheating chamber 54, for waste heat flue gas and cold air tubulation change ripe chamber, be placed with heat exchange air tubulation 47 in this chamber, be provided with cold flue gas outlet pipe 44 in this chamber roof, the chamber wall both sides are provided with cold air inlet duct 48 and preheated air outlet 49.
Waste heat heater 3 has the three kinds of functions in combustion chamber that heat conduction oil, air preheat and start-up system.Its thermal source can be from industrial furnace residual heat, the backheat of thermal power station's steam turbine, steam generator system and afterbody waste heat, the waste heat that produces in reaction heat that chemical engineering process produces and the nuclear energy uses.Between methyl alcohol catalyse pyrolysis commentaries on classics hydrogen generator 20 and burner 23, be provided with methyl alcohol preheating and hydrogen storage device 21, steam-water separator 22 and spark arrester 24.Methyl alcohol preheating and hydrogen storage device 21 utilize its reaction heat preheating methanol fuel to reach 160 ℃~170 ℃, make the methanol fuel vaporization faster, change hydrogen generator 20 through vaporizer 18, heat booster 19 and methyl alcohol catalyse pyrolysis, finish the continuous heating process of methanol fuel by heating heat-conducting oil.Between methyl alcohol catalyse pyrolysis commentaries on classics hydrogen generator 20 and vaporizer, be provided with heat booster 19, the methanol fuel of having vaporized is further heated, reach the desired 240 ℃ of temperature of catalyzed conversion hydrogen production reaction, can reduce the volume of vaporizer 18 and waste heat heater 3.In continuous heating process, conduction oil is the heat carrier of waste heat flue gas.The fuel metering of reforming hydrogen manufacturing combustion system is finished by methyl alcohol measuring pump 15.The purpose that is provided with of bypass recirculating system is to protect measuring pump, guarantees the safety when stove starts.
It is the same that native system is used for the occupation mode of thermal power station.

Claims (3)

1. industrial furnace and thermal power station include hydrogen manufacturing combustion system, the heat-conducting oil heating circulatory system, stove waste heat flue gas heating system with the combustion system of changing methanol into hydrogen fuel, and be wherein said:
The hydrogen manufacturing combustion system, the methyl alcohol station (14), methanol feed pump (13), methanol fuel case (11), methyl alcohol measuring pump (15), the methanol fuel that include by the pipeline series connection carry switch valve (17), vaporizer (18), catalyst activation system (25), methyl alcohol catalyse pyrolysis to change hydrogen generator (20) and burner (23);
The heat-conducting oil heating circulatory system comprises that the heat conduction fuel tank (26), filter (27), conduction oil circulating pump (28), waste heat heater (3), the methyl alcohol catalyse pyrolysis that link to each other in regular turn with pipeline change hydrogen generator (20) and vaporizer (18);
Stove waste heat flue gas heating system, comprise the waste heat acquisition port (8), smoke regulating valve (7), waste heat heater (3), waste heat smoke induced draught fan (2) and the stove chimney (1) that connect successively with pipeline, it is characterized in that: also include air preheating system, start-up system and bypass recirculating system, wherein
Air preheating system is connected to form by pipeline successively by combustion air acquisition port (6), air blast (5), waste heat heater (3), stove combustion air inlet (4);
Start-up system is connected to form by pipeline successively by methanol fuel case (11), methyl alcohol measuring pump (15), start-up system transfer valve (16), startup burner (10);
The bypass recirculating system is formed by being arranged on the pipeline that methanol fuel in the hydrogen manufacturing combustion system is carried between the input of switch valve (17) and methyl alcohol measuring pump (15) output and the bypass valve (12) between methyl alcohol measuring pump (15) input and methanol fuel case (11) output is constituted;
In described hydrogen manufacturing combustion system, being arranged on burner (23) and methyl alcohol catalyse pyrolysis in addition in regular turn changes steam-water separator (22) and methyl alcohol preheating and the hydrogen storage device (21) that is connected by pipeline between the hydrogen generator (20), and is arranged on the heat booster (19) that is connected by pipeline between methyl alcohol catalyse pyrolysis commentaries on classics hydrogen generator (20) and the vaporizer (18);
In the described heat-conducting oil heating circulatory system, also include and be arranged on the methyl alcohol catalyse pyrolysis and change the heat booster (19) that is connected by pipeline between hydrogen generator (20) and the vaporizer (18);
Be arranged on methanol fuel in the hydrogen manufacturing combustion system in addition and carry methyl alcohol leading portion transfer pipeline (29) between the methyl alcohol input port of the output of switch valve (17) and methyl alcohol preheating and hydrogen storage device (21), and be arranged on methyl alcohol back segment transfer pipeline (30) between the methyl alcohol input port of the methyl alcohol output port of methyl alcohol preheating and hydrogen storage device (21) and vaporizer (18), and connect the pipeline that starts the system's isolating valve, (9) between burner (10) output and smoke regulating valve (7) output pipeline.
2, use the combustion system of changing methanol into hydrogen fuel according to described industrial furnace of claim 1 and thermal power station, it is characterized in that: described hydrogen manufacturing combustion system is arranged on the spark arrester (24) between burner (23) and the steam-water separator (22) in addition.
3, use the combustion system of changing methanol into hydrogen fuel according to described industrial furnace of claim 1 and thermal power station, it is characterized in that: described waste heat heater (3) mainly is made of three chambers that are communicated with successively, i.e. the bottom waste heat flue gas that has the gas approach flue gas cooling and the air preheating chamber (54) at heat-conducting oil heating chamber (46) and top at combustion chamber (43), middle part of holding concurrently; Wherein:
The described waste heat flue gas combustion chamber (43) of holding concurrently is burning or waste heat flue gas supply room, and this chamber outer wall has waste heat smoke inlet pipe (51);
Described heat-conducting oil heating chamber (46), for holding the chamber of conduction oil, in this chamber, be placed with waste heat exhaust gases passes tubulation (45), and the diaphragm (50) that the control conduction oil flows to is set, heat-conducting oil heating chamber (46) wall is provided with conduction oil inlet tube (52) and following conduction oil outlet (53);
Described flue gas cooling and air preheating chamber (54), chamber for waste heat flue gas and the heat exchange of cold air tubulation, in this chamber, be placed with heat exchange air tubulation (47), be provided with cold flue gas outlet pipe (44) in this chamber roof, the chamber wall both sides are provided with cold air inlet duct (48) and preheated air outlet (49).
CNB2007100488087A 2007-04-04 2007-04-04 Combustion system for changing methanol into hydrogen fuel used in industrial furnace and thermal power plant. Expired - Fee Related CN100467946C (en)

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CNB2007100488087A CN100467946C (en) 2007-04-04 2007-04-04 Combustion system for changing methanol into hydrogen fuel used in industrial furnace and thermal power plant.

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CN101323431B (en) * 2008-07-09 2010-08-11 王衍衡 Method and apparatus system for converting methanol into hydrogen fuel by using industrial furnace residual heat
CN103900098B (en) * 2012-12-26 2016-03-30 陈彦佐 Hydrogen energy waste heat boiler combustion-supporting system
EP3392855B1 (en) * 2017-04-19 2021-10-13 Siemens Schweiz AG Method and device for configuring a smoke detector
CN107473182A (en) * 2017-04-28 2017-12-15 王海东 Conduction oil is heated by the method and device of hydrogen from methyl alcohol using solar power generation
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