CN101580744B - Fuel additives to maintain optimum injector performance - Google Patents
Fuel additives to maintain optimum injector performance Download PDFInfo
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- CN101580744B CN101580744B CN200910141206.5A CN200910141206A CN101580744B CN 101580744 B CN101580744 B CN 101580744B CN 200910141206 A CN200910141206 A CN 200910141206A CN 101580744 B CN101580744 B CN 101580744B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/221—Organic compounds containing nitrogen compounds of uncertain formula; reaction products where mixtures of compounds are obtained
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
Abstract
The invention discloses a fuel additives to maintain optimum injector performance. A diesel fuel, diesel fuel additive concentrate and method for improving the performance of fuel injectors for a diesel engine are provided. The diesel fuel includes a major amount of middle distillate fuel; and a reaction product of a hydrocarbyl substituted dicarboxylic acid or anhydride and an amine compound or salt. The amine compound has the formula wherein R is selected from the group consisting of a hydrogen and a hydrocarbyl group containing from about 1 to about 15 carbon atoms, and R1 is selected from the group consisting of hydrogen and a hydrocarbyl group containing from about 1 to about 20 carbon atoms. The reaction product contains at least one amino triazole group and is present in the fuel in an amount sufficient to improve the performance of diesel fuel injectors.
Description
Technical field
Present disclosure relates to some diesel-fuels (diesel fuel) additive and comprises diesel-fuel and the diesel-fuel additive enriched material of this additive.Particularly, present disclosure relates to a kind of diesel-fuel additive of fuel injector (injector) performance of effective enhancing diesel motor.
Background technology
Wished to make fuel economy, power and the cornering ability optimizing of diesel-fuel power car for a long time, strengthened simultaneously and accelerate, reduce discharge and prevent temporary transient shutdown.Though it is known keeping valve and fuel injector to clean to strengthen the petrol power motor performance by the use dispersion agent, this gasoline dispersant is not necessarily effective in diesel-fuel is used.The reason of this unpredictability be diesel motor and petrol engine between how turning round many differences and the chemical differences between diesel-fuel and the gasoline.
In these years, researched and developed the disperser composition that is used for diesel-fuel.The disperser composition known in the art that is used for diesel-fuel comprises the composition that can comprise the polyalkylene succinimide, and described polyalkylene succinimide is the reaction product of polyalkylene succinyl oxide and amine.Dispersion agent is applicable to and makes cigarette ash and sludge keep being suspended in the fluid that in case still settling forms from the teeth outwards, these dispersion agents are ineffective especially for the clean surface.Therefore, the diesel fuel composition that comprises dispersion agent still produces undesirable settling on the diesel motor injector of being everlasting.Therefore, need to prevent sediment pile, keep the improved composition for " as the new " degree of cleaning in vehicle life-span.Ideally, can clean dirty fuel injector, with the same combination of performance recovery to former " as new " state, will be desirable with useful in the trial that reduces airborne exhaust emissions equally.
Summary of the invention
According to present disclosure, exemplary provides a kind of diesel-fuel, diesel-fuel additive enriched material and improves the method for the fuel injector performance of diesel motor.Diesel-fuel comprises a large amount of midbarrel fuels; With the dicarboxylic acid of alkyl replacement or the reaction product of acid anhydrides and amine compound or salt.Amine compound has following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and contain 1 alkyl to about 20 carbon atoms of having an appointment.Reaction product comprises at least one aminotriazole group and is present in the fuel with the amount that is enough to improve fuel injector performance.
Another embodiment of present disclosure provides a kind of method of improving the injector performance of diesel motor.This method comprises the fuels run diesel motor that has a large amount of fuel and a small amount of following reaction product based on a kind of, and described reaction product is derived from amine compound or its salt of following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and contain 1 alkyl to about 20 carbon atoms of having an appointment, and the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.
Present disclosure another embodiment a kind of method of fuel injector of the diesel motor that cleans burner oil is provided.This method comprises the fuels run diesel motor that has a large amount of fuel and a small amount of following reaction product based on a kind of, and described reaction product is derived from amine compound or its salt of following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and contain 1 alkyl to about 20 carbon atoms of having an appointment, and the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.
The advantage of fuel dope described herein not only can reduce directly for this additive and/or be formed at sediment yield on the diesel engine fuel injector indirectly, and this additive can also clean dirty fuel injector effectively.The minimizing settling of additive and cleaning action are demonstrated in 2007 back model year engine technologies.
Other embodiment of present disclosure and advantage will part be set forth in detailed description subsequently, and/or can learn by the enforcement of present disclosure.Should be understood that above-mentioned general remark and following detailed description only are exemplary and explanat, is not to limit present disclosure as right is come requirement.
Embodiment
The application's composition can be used for a large amount of diesel-fuels with a small amount of, and can be by amine compound or its salt of following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and contain 1 alkyl to about 20 carbon atoms of having an appointment, with the hydrocarbyl oxycarbonyl based compound prepared in reaction of following formula,
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.Do not wish to accept the constraint of opinion factor, the reaction product that it is believed that amine and hydrocarbyl oxycarbonyl based compound is aminotriazole, for example the bis-amino triazole compounds of following formula
Comprise having about 200 to about 3000 number-average molecular weights, contain 40 tautomers to about 80 carbon atoms of having an appointment.The five-ring of triazole is considered to aromatics.Aminotriazole is to oxygenant quite stable and hydrolysis extremely.Though be not certain, it is believed that this reaction product be polyalkenyl (polyalkenyl) two-3-amino-1,2, the 4-triazole.This product comprises higher nitrogen content, is the nitrogen of about 1.8wt% to about 2.9wt%.
Use as the present invention, term " hydrocarbyl group " or " alkyl " use well known to a person skilled in the art conventional meaning.Particularly, its expression group of having the carbon atom of the rest part that is directly connected to molecule and having main hydrocarbon character.The example of hydrocarbyl group comprises: (1) hydrocarbon substituent, namely aliphatic series (for example alkyl or alkenyl), alicyclic (for example cycloalkyl, cycloalkenyl group) substituting group, and aromatics-, aliphatic series-and the aromatic substituent of alicyclic replacement, and cyclic substituent, wherein this ring is finished (for example, two substituting groups form alicyclic group together) by another part of molecule; (2) hydrocarbon substituent of Qu Daiing, the substituting group that namely contains non-hydrocarbyl group, in context of the present invention, described non-hydrocarbyl group can not change main hydrocarbon substituent (for example halogen (particularly chlorine and fluorine), hydroxyl, alkoxyl group, sulfydryl, alkyl thiol, nitro, nitroso-group and alkylsulfonyl); (3) hydridization substituting group in this context, namely has main hydrocarbon character simultaneously, and contains the substituting group of non-carbon atom in the ring of being made up of carbon atom in addition or chain.Heteroatoms comprises sulphur, oxygen, nitrogen, and comprises the substituting group such as pyridyl, furyl, thienyl and imidazolyl.Usually in hydrocarbyl group, will there be two at the most in per ten carbon atoms, or as other example, have non-hydrocarbon substituent at the most; In some embodiments, in hydrocarbyl group, will there be non-hydrocarbon substituent.
As used herein, term " in a large number " is interpreted as expression with respect to the gross weight of composition, and more than or equal to 50wt%, for example about 80 to the amount of about 98wt%.In addition, as used herein, term " on a small quantity " is interpreted as expression with respect to composition total weight, is lower than the amount of 50wt%.Amine compound
The amine compound of suitable following formula
Can be selected from guanidine and aminoguanidine or its salt, wherein R and R
1As defined above.Therefore, amine compound can be selected from the inorganic salt of guanidine, for example the halogenide of guanidine, carbonate, nitrate, phosphoric acid salt and orthophosphoric acid salt.Term " guanidine " expression guanidine and guanidine derivative, for example aminoguanidine.In one embodiment, the guanidine compound for the preparation of additive is aminoguanidine bicarbonate.Aminoguanidine bicarbonate can easily obtain from commercial source, or can prepare with known manner.The hydrocarbyl oxycarbonyl based compound
The hydrocarbyl oxycarbonyl radical reaction compounds of additive can be for having any suitable compound of hydrocarbyl portion and carbonyl moiety, and can be combined the additive that forms present disclosure with amine compound.The unrestricted example of suitable hydrocarbyl oxycarbonyl based compound includes but not limited to that alkyl substituted succinyl oxide, alkyl replace the ester of succsinic acid and alkyl replacement succsinic acid.
In some respects, the hydrocarbyl oxycarbonyl based compound can be for having the polyalkylene succinyl oxide reactant of following formula:
R wherein
2Be hydrocarbyl portion, for example have about 100 polyalkenyl to about 5,000 number-average molecular weights.For example, R
2Number-average molecular weight can be for about 200 to about 3,000, as according to gpc measurement.Except as otherwise noted, molecular weight is number-average molecular weight in this manual.
R
2The polyalkenyl group can comprise the one or more polymer units that are selected from linearity or branching thiazolinyl unit.In some respects, the thiazolinyl unit can have about 2 to about 10 carbon atoms.For example, the polyalkenyl group can comprise one or more linearities or the branched polymers unit that is selected from vinyl group (ethylene radicals), propylene group (propylene radicals), butylene group (butylene radicals), amylene group (penteneradicals), hexene group (hexene radicals), octene group (octene radicals) and decene group (decene radicals).In some respects, R
2The polyalkenyl group can be for example form of homopolymer, multipolymer or terpolymer.In one aspect, the polyalkenyl group is iso-butylene (isobutylene).For example, the polyalkenyl group can be for comprising about 10 to about 60 iso-butylene groups, for example the homopolymer of about 20 polyisobutene to about 30 iso-butylene groups (polyisobutylene).Be used to form R
2The polyalkenyl compound of polyalkenyl group can be by any suitable method, and for example the conventional catalytic oligomerization of alkene forms.
On the other hand, hydrocarbyl portion R
2Can be derived from linear alpha-alkene or the acid isomer alpha-olefin by method oligomerisation of ethylene preparation as known in the art.These hydrocarbyl portions can extremely surpass 40 carbon atoms for about 8 carbon atoms.For example, this alkenyl part can be derived from linear C
18Alpha-olefin or C
20-24Mixture or the acid isomer C of alpha-olefin
16Alpha-olefin.
In some respects, the highly reactive polyisobutenes of polymer molecule with end vinylidene group (vinylidenegroup) with higher proportion can be used for forming R
2Group.In one embodiment, at least about 60%, for example about 70% to about 90% polyisobutene comprises the end olefinic double bond.In industry, have the general trend be converted into highly reactive polyisobutenes, and known highly reactive polyisobutenes for example is disclosed in US 4,152, in 499, at this its disclosure all is incorporated herein by reference.
The specific examples of hydrocarbyl oxycarbonyl based compound comprises such as dodecenyl succinic anhydride, C
16-18The compound of alkenyl succinic anhydride and polyisobutenyl (polyisobutenyl) succinyl oxide (PIBSA).In some embodiments, can to have vinylidene content be about 4% to greater than about 90% polyisobutene part to PIBSA.In some embodiments, the carbonyl number in the hydrocarbyl oxycarbonyl based compound can be about 1: 1 to about 6: 1 to the ratio of hydrocarbyl portion number.
In some respects, every mole of polyalkylene can react about one mole of maleic anhydride, and therefore final polyalkenyl succinic anhydrides has each polyalkylene substituting group, and about 0.8 to about 1 succinic anhydride group.In other side, succinic anhydride group can be for about 0.5 to about 3.5 to the weight ratio of alkylidene group, and for example about 1 to about 1.1.
The hydrocarbyl oxycarbonyl based compound can use prepared by any suitable process.The method that forms the hydrocarbyl oxycarbonyl based compound is known in the art.An example that forms the currently known methods of hydrocarbyl oxycarbonyl based compound comprises blend polyolefine and maleic anhydride.The optional catalyzer that uses, for example chlorine or superoxide, with polyolefine and maleic anhydride reactant be heated to for example about 150 ℃ to about 250 ℃ temperature.Another illustrative methods of preparation polyalkylene succinyl oxide is at US 4,234, describes in 435, at this it all is incorporated herein by reference.
Above-mentioned alkyl carbonyl and amine compound can mix under optimum conditions, so that the required product amino-triazole compound thing of present disclosure to be provided.Aspect of present disclosure, reactant compound can with about 1: 1 to about 1: 2.5 alkyl carbonyl to the mixed in molar ratio of amine together.For example, the mol ratio of reactant can be about 1: 1 to about 1: 2.2.
Under atmospheric pressure, suitable reaction temperature can be about 155 ℃ to about 200 ℃.For example, temperature of reaction can be about 160 ℃ to about 190 ℃.Can use any suitable reaction pressure, for example comprise pressure below atmospheric pressure or be higher than atmospheric pressure.But, being different from when carrying out under the normal atmosphere when being reflected at, temperature range can be with listed those be different.Reaction can be at about 1 hour to about 8 hours, carries out to about 6 hours time period in preferred about 2 hours.
Aspect some of the application, the application's dispersion agent product can be used in combination with the diesel-fuel soluble carrier.This carrier can be all kinds, for example liquid or solid, for example wax.The example of liquid vehicle includes but not limited to mineral oil and oxidation products, liquid poly-alkoxylation ether (also claiming polyalkylene glycol or polyalkylene ether) for example, liquid poly-alkoxylation phenol, liquid poly-alkoxylation ester, liquid poly-alkoxylation amine and composition thereof.The example of oxidation products carrier is found in people such as Henly on May 19th, 1998 disclosed US 5,752,989, this wherein the explanation of carrier all be incorporated herein by reference.Other example of oxidation products carrier is included in people such as Colucci in the aryl poly-alkoxylation thing (polyalkoxylate) that the alkyl described on July 17th, the 2003 disclosed US 2003/0131527 replaces, and at this its explanation all is incorporated herein by reference.
In other side, the application's composition can not comprise carrier.For example, the application's some compositions can not comprise mineral oil or oxidation products, for example above-mentioned those oxidation productss.
One or more other optional compound may reside in the fuel composition of disclosed embodiment.For example, fuel can comprise cetane number improver, sanitas, cold flow promotor (CFPP additive), pour point reducer, solvent, emulsion splitter, slip additive, friction modifiers, amine stabiliser, ignition dope, dispersion agent, oxidation inhibitor, thermo-stabilizer, conductivity promotor, metal passivator, labeling dye, organic nitrates ignition accelerator, Huan Mao (cyclomatic) manganese tricarbonyl compound of convention amount etc.In some respects, composition described herein can comprise about 10wt% or still less, or in other side, about 5wt% or one or more above-mentioned additives still less are based on the gross weight of multifunctional additive for lubricating oils.Similarly, fuel can comprise the conventional fuel blend components of appropriate amount, for example methyl alcohol, ethanol, dialkyl ether etc.
Aspect some of disclosed embodiment, can use to comprise aliphatic series or alicyclic nitric ether and comprise the organic nitrates ignition accelerator of about 12 carbon at the most, wherein aliphatic series or alicyclic group are saturated.The example of operable organic nitrates ignition accelerator is methyl nitrate, ethyl nitrate, propyl nitrate, isopropyl nitrate, the nitric acid allyl ester, the nitric acid butyl ester, isobutyl nitrate, the secondary butyl ester of nitric acid, the nitric acid tert-butyl ester, amyl nitrate, isoamyl nitrate, nitric acid 2-amyl group ester, nitric acid 3-base pentyl ester, the own ester of nitric acid, the nitric acid heptyl ester, nitric acid 2-heptyl ester, n-octyl nitrate, isooctyl ester nitrate, nitric acid 2-ethylhexyl, nitric acid ester in the ninth of the ten Heavenly Stems, decyl nitrate, nitric acid undecyl ester, the nitric acid dodecyl ester, nitric acid ring pentyl ester, cyclohexyl nitrate, nitric acid methyl cyclohexane ester, nitric acid cyclo-dodecyl ester, nitric acid 2-ethoxy ethyl ester, nitric acid 2-(2-ethoxy ethoxy) ethyl ester, nitric acid tetrahydrofuran ester etc.Also can use this type of mixtures of material.
The example that can be used for the suitable optional metals passivator of the application's composition is disclosed among the disclosed US 4,482,357 on November 13rd, 1984, at this its disclosure all is incorporated herein by reference.This metal passivator comprises for example salicylidene-o-amino-phenol, Disalicylidene ethylene diamine, two salicylidene trimethylene diamine and N, N '-two salicylidenes-1.
Suitable optional ring luxuriant (cyclomatic) manganese tricarbonyl compound that can be used for the application's composition comprises for example cyclopentadienyl tricarbonyl manganese, methyl cyclopentadienyl tricarbonyl manganese, indenyl manganese tricarbonyl and ethyl cyclopentadienyl tricarbonyl manganese.Other example of the suitable luxuriant manganese tricarbonyl compound of ring is disclosed among the US 3,015,668 that disclosed US on November 19th, 1996 on January 2nd, 5,575,823 and 1962 announced, all is incorporated herein by reference in this disclosure with both.
When preparing the application's fuel composition, additive can be to be enough to reduce or suppress the amount use that the settling in the diesel motor forms.In some respects, fuel can contain a spot of control or reduce engine deposits formation, for example the above-mentioned bis-amino triazole compounds of the formation of the injector deposits in the diesel motor.For example, the application's diesel-fuel can contain every Kg fuel, and about 5mg is to the bis-amino triazole compounds of about 200mg, every Kg fuel for example, and about 20mg is the bis-amino triazole compounds of about 120mg extremely, based on the activeconstituents basis.In every respect, when using carrier, fuel composition can contain every Kg fuel, and about 1mg is to the carrier of about 100mg, every Kg fuel for example, and about 5mg is the dispersion agent of about 50mg extremely, based on the activeconstituents basis.Described activeconstituents basis does not comprise (i) unreacted components, for example along with produce and use follow and remain in the weight of the polyalkylene compound in the product, if (ii) have, in bis-amino triazole compounds forming process or afterwards, if but use carrier, before adding carrier for the preparation of the weight of one or more solvents of bis-amino triazole compounds.
The application's additive comprises above-mentioned bis-amino triazole compounds and the optional additive that is used for preparation fuel of the present invention, can be respectively or amount to various subgroups and to infiltrate in the basic diesel-fuel.In some embodiments, the application's binder component can enter in the diesel-fuel when using multifunctional additive for lubricating oils in blend, because this point utilization is when adopting the form of multifunctional additive for lubricating oils, the intermiscibility and the convenience that are obtained by the combination of each composition.The use of enriched material can also reduce the blend time and reduce the possibility of blend deviation.
Therefore, in some embodiments, the application relates to a kind of diesel-fuel additive, comprises the bis-amino triazole compounds, and this compound is the reaction product of aforesaid at least a guanidine and at least a polyalkylene succinyl oxide.This additive can comprise one or more above-listed supplementary components.This additive can for example be packed respectively and sell with conc forms and diesel-fuel.This additive then can be as required by client with itself and diesel-fuel blend.
The application's diesel-fuel goes for the running of stationary diesel engine (for example engine that uses in power generation assembly, the pumping plant etc.) and on-fixed diesel motor (for example being used as the engine of the primover in automobile, truck, road grading equipment, the military vehicle etc.).For example, fuel can comprise any and all midbarrel fuels, diesel-fuel, biological recyclable fuel, biofuel machine fuel, gas is to liquid (GTL) fuel, rocket engine fuel, alcohol, ether, kerosene, low-sulfur fuel, synthol is fischer-tropsch (Fischer-Tropsch) fuel for example, liquefied petroleum gas (LPG), hopper oil, coal is to liquid (CTL) fuel, biomass are to liquid (BTL) fuel, high bituminous fuel, fuel derived from coal is (natural, that purify and refinery coke), genetic engineering biofuel and crop and from its extract, and Sweet natural gas.As used herein, " biological recyclable fuel " is interpreted as representing any fuel derived from the resource that is different from oil.This resource includes but not limited to corn, maize, soybean and other crop; Herbage, for example withy broomcorn millet, awns belong to and hybridization herbage; Algae, marine alga, vegetables oil; Natural fat; With its mixture.In one aspect, biological recyclable fuel can comprise single hydroxyl alcohol, for example comprises 1 to those of about 5 carbon atoms.The unrestricted example of suitable single hydroxyl alcohol comprises methyl alcohol, ethanol, propyl alcohol, propyl carbinol, isopropylcarbinol, the trimethyl carbinol, amylalcohol and primary isoamyl alcohol.Therefore, the application's each side relates to the method for the amount of the injector deposits that reduces diesel motor, and described diesel motor has at least one combustion chamber and one or more direct fuel injectors that are connected with combustion chamber fluid.In yet another aspect, improve also and can observe in the diesel engine fuel injector indirectly.In some respects, this method comprises via the diesel motor injector, will comprise that the alkyl compression ignition fuel injection of the application's bis-amino triazole additive enters in the combustion chamber, and light this compression ignition fuel.In some respects, this method also can be included in and mix at least a above-mentioned optional supplementary component in the diesel-fuel.
In one embodiment, the application's diesel-fuel can be substantially free of, and does not for example contain conventional succinimide dispersants compound.For the application's purpose, term " is substantially free of " to be defined as injector degree of cleaning or settling is formed the concentration that does not have measurable influence basically.
In the application's other side, fuel dope can not contain or be substantially free of and is different from 1,2 of above-mentioned triazole, the 4-triazole.For example, composition can be substantially free of the triazole of formula II,
R wherein
4And R
5Be independently selected from hydrogen and alkyl, condition is R
4And R
5At least one be not hydrogen.The example of alkyl comprises C
2To C
50Linearity, branching or cyclic alkyl; C
2To C
50Linearity, branching or ring-type thiazolinyl; With replacement or unsubstituted aryl, for example phenyl, tolyl and xylyl.Embodiment
Following examples illustrate the exemplary of present disclosure.In the application's these embodiment and other part, except as otherwise noted, all umbers and percentages.Wish it only is that illustrative purposes provides these embodiment for example, but not be used for limiting scope of the present invention disclosed herein.Embodiment 1
The polybutylene-based succinyl oxide of 950 molecular weight is heated to 95 ℃.Added the slurry oil of aminoguanidine bicarbonate (AGBC) through 45 minutes.Under vacuum, with mixture heating up to 160 ℃ and remained on this temperature about 6 hours, remove water and carbonic acid gas.Filter the gained mixture.
In following examples, use conventional diesel motor fuel injector test as described below, diesel motor is carried out the injector deposits test.
Test procedure
The test procedure that uses is by people such as Graupner, " Injector deposit test formodern diesel engines ", Technische Akademie Esslingen, 5th InternationalColloquium, 12-13 day in January, 2005,3.10, p157, editor Wilfried J Bartz describes.Briefly, these rules are used modern diesel engines, focus on that fuel injector deposits forms.Test is divided into five stages: the soak time (3 to 8 hours) that prolongs a) the measurement b of engine power output) 8 hours lasting operation c), engine is stopped and cools off d therebetween) second 8 hours lasting operation e) measurement of engine power output.
For data given herein, use above five stages, but stage b), c) and d) can repeat the test procedure that multipass carries out with coupling.Equally, the stage a) and e) can omit, but useful to result's understanding to improving.With the stage a) during during the average torque in when beginning test and the stage e) difference between the average torque during end of test (EOT) report the result.Alternatively, if the stage of not carrying out above-mentioned steps a) and stage e), then can use the measurement difference between the torque at starting under full load/full speed and the final load/speed.The aborning difference of same record smog.The formation of injector deposits will have negative influence and observed amount of smoke will be increased final power output.For the state that repeats to expect in the modern diesel engines, the little metal pollutent of zinc neodecanoate form is joined fuel for running engine.In form, BAT is above-mentioned bis-amino triazole compounds.
| The running test | Fuel composition | BAT additive treating speed (ppm) by weight | Torque loss |
| 1 | Basic fuel+1ppm Zn | 0.0 | 13.73％ |
| 2 | Basic fuel+1ppm Zn+BAT | 80 | 0.84％ |
Shown in above-mentioned embodiment, the bis-amino triazole compounds does not provide torque loss substantially in the diesel-fuel of zinc that mixes.This result is surprising and exceeds unexpected fully.Therefore, it is believed that bis-amino triazole composition as described herein may be effective to keeping the fuel injector surface to be used for the diesel motor purification.
Should point out that singulative " ", " a kind of " and " being somebody's turn to do " comprise plural object as using in this specification sheets and claims, unless clearly and clearly be limited to an object.Therefore, for example " a kind of oxidation inhibitor " comprises the oxidation inhibitor that two or more are different.As used herein, term " comprises " and grammatical variants wishes it is nonrestrictive, so other similar item that can substitute or join in the Listed Items is not got rid of in the narration of project in the inventory.
For the purpose of this specification sheets and claims, except as otherwise noted, all numerical value of expression quantity, per-cent or ratio, and other numerical value that uses in specification sheets and the claim is interpreted as being modified by term " about " in all instances.Therefore, unless indicate on the contrary, the numerical parameter of enumerating in following specification sheets and claims is approximation, and it can be according to the desired properties change of attempting to be obtained by present disclosure.At least, and do not attempt to limit range applications equivalent principle to claim, each numerical parameter should be explained according to the number of the significant figure of reporting and by using the common method of rounding up at least.
Though embodiment has been described, at present not or unpredictable to replacement scheme, improvement, variation, improvement and basic equivalent can be made by applicant or other those skilled in the art.Therefore, claims submission and that may be modified intend comprising all this replacement schemes, improvement, variation, improvement and basic equivalent.Therefore, at this following embodiment is disclosed.1. 1 kinds of diesel-fuels that are used for fuel injection of scheme comprise: a large amount of midbarrel fuels; (a) dicarboxylic acid that replaces of alkyl or acid anhydrides and (b) amine compound of following formula or the reaction product of its salt
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, and R
1Be selected from hydrogen and contain 1 alkyl to about 20 carbon atoms of having an appointment, wherein said reaction product contains at least one aminotriazole group and exists to be enough to improving diesel engine amount direct and/or indirect fuel injector performance.The fuel of scheme 2. schemes 1, wherein reaction product is substantially free of succinimide dispersants.The fuel of scheme 3. schemes 1, wherein reaction product comprises the compound of following formula
And tautomer, wherein R
2For having about 200 alkyl to about 3000 number-average molecular weights.The fuel of scheme 4. schemes 1, wherein alkyl dicarboxylic acid or acid anhydrides are selected from the ester of hydrocarbyl substituted succinic acid anhydride, hydrocarbyl substituted succinic and hydrocarbyl substituted succinic.The fuel of scheme 5. schemes 4, wherein R
2For having the about 200 polyolefine groups to about 3,000 number-average molecular weights.The fuel of scheme 6. schemes 5, wherein diesel-fuel comprises the fuel for direct fuel injection.The fuel of scheme 7. schemes 6, wherein polyisobutylene group is derived from having at least 60% or the highly reactive polyisobutenes of multiterminal olefinic double bond more.The fuel of scheme 8. schemes 1, wherein (a) is about 1: 1 to about 1: 2.2 to the molar ratio of (b).The fuel of scheme 9. schemes 1, wherein amine comprises the inorganic salt of guanidine.The fuel of scheme 10. schemes 1, wherein amine comprises the salt of aminoguanidine.The fuel of scheme 11. schemes 1, wherein amine comprises aminoguanidine bicarbonate.12. 1 kinds of methods of improving the injector performance of fuel injection diesel motor of scheme, comprise based on fuel composition running diesel motor, described fuel composition comprises a large amount of fuel and a spot of following reaction product, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and containing and have an appointment 1 to the alkyl of about 20 carbon atoms and (b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.The method of scheme 13. schemes 12, wherein reaction product is substantially free of succinimide dispersants.The method of scheme 14. schemes 12, wherein R
2For having about 200 polyisobutene to about 3,000 number-average molecular weights.The method of scheme 15. schemes 12, wherein the fuel injection diesel motor comprises direct fuel injection diesel motor.The method of scheme 16. schemes 12, wherein (a) is about 1: 1 to about 2.2: 1 to the molar ratio of (b).The method of scheme 17. schemes 12, wherein amine is aminoguanidine bicarbonate.The method that 18. 1 kinds of fuel purifyings of scheme spray the fuel injector of diesel motor, comprise based on fuel composition running diesel motor, described fuel composition comprises a large amount of fuel and a spot of following reaction product, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and containing and have an appointment 1 to the alkyl of about 20 carbon atoms and (b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.The method of scheme 19. schemes 18, wherein reaction product is substantially free of succinimide dispersants.The method of scheme 20. schemes 18, wherein R
2For having the about 200 polyolefine groups to about 3,000 number-average molecular weights.The method of scheme 21. schemes 18, wherein the fuel injection diesel motor is direct fuel injection diesel motor.The method of scheme 22. schemes 18, wherein (a) is about 1: 1 to about 2.2: 1 to the molar ratio of (b).The method of scheme 23. schemes 18, wherein amine is aminoguanidine bicarbonate.24. 1 kinds of fuel additive concentrates of scheme, it is used for joining diesel-fuel to improve the fuel injector performance of diesel motor, comprises following reaction product, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and contains 1 alkyl to about 15 carbon atoms of having an appointment, R
1Be selected from hydrogen and containing and have an appointment 1 to the alkyl of about 20 carbon atoms and (b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having about 200 alkyl to about 3000 number-average molecular weights.The multifunctional additive for lubricating oils of scheme 25. schemes 24, wherein R
2For having the about 500 polyolefine groups to about 1,000 daltons number average molecular weight.The multifunctional additive for lubricating oils of scheme 26. schemes 25, wherein the polyolefine group is polyisobutylene group.The multifunctional additive for lubricating oils of scheme 27. schemes 26, wherein polyisobutylene group is derived from having at least 60% or the highly reactive polyisobutenes of multiterminal olefinic double bond more.The multifunctional additive for lubricating oils of scheme 28. schemes 24, wherein (a) is about 1: 1 to about 2.2: 1 to the molar ratio of (b).The multifunctional additive for lubricating oils of scheme 29. schemes 24, wherein amine comprises the inorganic salt of guanidine.The multifunctional additive for lubricating oils of scheme 30. schemes 24, wherein diesel motor comprises direct fuel injection diesel motor.31. 1 kinds of fuel of scheme, comprise the multifunctional additive for lubricating oils of a spot of scheme 24 and a large amount of fuel, described fuel is selected from midbarrel fuel, diesel-fuel, biological recyclable fuel, biofuel machine fuel, gas is to liquid (GTL) fuel, rocket engine fuel, alcohol, ether, kerosene, low-sulfur fuel, synthol is fischer-tropsch fuel for example, liquefied petroleum gas (LPG), hopper oil, coal is to liquid (CTL) fuel, biomass are to liquid (BTL) fuel, high bituminous fuel, (natural derived from coal, pure and refinery coke) fuel, the biofuel of genetic engineering and crop and from its extract, and Sweet natural gas.
Claims (9)
1. diesel-fuel that is used for fuel injection comprises:
A large amount of midbarrel fuels; With
(a) dicarboxylic acid that replaces of alkyl or acid anhydrides and
(b) reaction product of the amine compound of following formula or its salt
Wherein R is selected from hydrogen and the alkyl that contains 1 to 15 carbon atom, and R
1Be selected from hydrogen and contain the alkyl of 1 to 20 carbon atom, wherein said reaction product is under atmospheric pressure 155 ℃ to 200 ℃ temperature preparation, and described reaction product comprises the compound of following formula
And tautomer, wherein R
2For having the alkyl of 200 to 3000 number-average molecular weights, and described reaction product exists with the amount of every Kg fuel 5mg to 200mg, and this amount is enough to improve the performance of the direct and/or indirect fuel injector of diesel engine.
2. the fuel of claim 1, wherein said reaction product is substantially free of succinimide dispersants.
3. the fuel of claim 1, wherein (a) is 1: 1 to 1: 2.2 to the molar ratio of (b).
4. the fuel of claim 1, wherein said amine comprises aminoguanidine bicarbonate.
5. method of improving the injector performance of fuel injection diesel motor, comprise based on fuel composition running diesel motor, described fuel composition comprises the following reaction product of a large amount of fuel and every Kg fuel 5mg to 200mg, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and the alkyl that contains 1 to 15 carbon atom, R
1Be selected from hydrogen and contain 1 to 20 carbon atom alkyl and
(b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having the alkyl of 200 to 3000 number-average molecular weights, wherein said reaction product be under atmospheric pressure 155 ℃ to 200 ℃ temperature preparation and described reaction product comprise the compound of following formula
And tautomer, wherein R
2For having the alkyl of 200 to 3000 number-average molecular weights.
6. the method for claim 5, wherein R
2For having the polyisobutene of 200 to 3,000 number-average molecular weights.
7. a fuel purifying sprays the method for the fuel injector of diesel motor, comprise based on fuel composition running diesel motor, described fuel composition comprises the following reaction product of a large amount of fuel and every Kg fuel 5mg to 200mg, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and the alkyl that contains 1 to 15 carbon atom, R
1Be selected from hydrogen and contain 1 to 20 carbon atom alkyl and
(b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having the alkyl of 200 to 3000 number-average molecular weights, wherein said reaction product be under atmospheric pressure 155 ℃ to 200 ℃ temperature preparation and described reaction product comprise the compound of following formula
And tautomer, wherein R
2For having the alkyl of 200 to 3000 number-average molecular weights.
8. fuel additive concentrate, it is used for joining diesel-fuel to improve the fuel injector performance of diesel motor, comprises following reaction product, and described reaction product is derived from amine compound or its salt of (a) following formula
Wherein R is selected from hydrogen and the alkyl that contains 1 to 15 carbon atom, R
1Be selected from hydrogen and contain 1 to 20 carbon atom alkyl and
(b) the hydrocarbyl oxycarbonyl based compound of following formula
R wherein
2For having the alkyl of 200 to 3000 number-average molecular weights, wherein said reaction product is preparation and the compound that comprise following formula 155 ℃ to 200 ℃ temperature under atmospheric pressure
And tautomer, wherein R
2For having the alkyl of 200 to 3000 number-average molecular weights, and the amount of the described reaction product that comprises of wherein said multifunctional additive for lubricating oils is enough to provide the described reaction product of every Kg fuel 5mg to 200mg in described fuel.
9. the multifunctional additive for lubricating oils of claim 8, wherein polyisobutylene group is derived from having at least 60% or the highly reactive polyisobutenes of multiterminal olefinic double bond more.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/119788 | 2008-05-13 | ||
| US12/119,788 | 2008-05-13 | ||
| US12/119,788 US20100037514A1 (en) | 2008-05-13 | 2008-05-13 | Fuel additives to maintain optimum injector performance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101580744A CN101580744A (en) | 2009-11-18 |
| CN101580744B true CN101580744B (en) | 2013-08-28 |
Family
ID=40750683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910141206.5A Active CN101580744B (en) | 2008-05-13 | 2009-05-12 | Fuel additives to maintain optimum injector performance |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100037514A1 (en) |
| CN (1) | CN101580744B (en) |
| BE (1) | BE1018579A5 (en) |
| GB (1) | GB2462696B (en) |
| SG (1) | SG157285A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2480612A (en) * | 2010-05-24 | 2011-11-30 | Afton Chemical Ltd | Oxidation stabilized fuels having enhanced corrosion resistance |
| BR112013012874B1 (en) | 2010-12-02 | 2019-09-03 | Basf Se | reaction product use, and fuel composition and additive concentrate preparation processes |
| US9523057B2 (en) * | 2011-02-22 | 2016-12-20 | Afton Chemical Corporation | Fuel additives to maintain optimum injector performance |
| US8758456B2 (en) * | 2011-09-22 | 2014-06-24 | Afton Chemical Corporation | Fuel additive for improved performance of low sulfur diesel fuels |
| US8852297B2 (en) | 2011-09-22 | 2014-10-07 | Afton Chemical Corporation | Fuel additives for treating internal deposits of fuel injectors |
| BE1021686B1 (en) * | 2012-04-19 | 2016-01-08 | Afton Chemical Corportion | FUEL ADDITIVES FOR TREATING INTERNAL DEPOSITS OF FUEL INJECTORS. |
| AU2013201711B2 (en) * | 2012-04-24 | 2014-10-30 | Afton Chemical Corporation | Fuel additives for treating internal deposits of fuel injectors |
| US8894726B2 (en) * | 2012-06-13 | 2014-11-25 | Afton Chemical Corporation | Fuel additive for improved performance in fuel injected engines |
| US9340742B1 (en) | 2015-05-05 | 2016-05-17 | Afton Chemical Corporation | Fuel additive for improved injector performance |
| US11390821B2 (en) | 2019-01-31 | 2022-07-19 | Afton Chemical Corporation | Fuel additive mixture providing rapid injector clean-up in high pressure gasoline engines |
| US11873461B1 (en) | 2022-09-22 | 2024-01-16 | Afton Chemical Corporation | Extreme pressure additives with improved copper corrosion |
| US11795412B1 (en) | 2023-03-03 | 2023-10-24 | Afton Chemical Corporation | Lubricating composition for industrial gear fluids |
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Also Published As
| Publication number | Publication date |
|---|---|
| GB2462696A8 (en) | 2010-03-24 |
| GB2462696A (en) | 2010-02-24 |
| CN101580744A (en) | 2009-11-18 |
| BE1018579A5 (en) | 2011-04-05 |
| US20100037514A1 (en) | 2010-02-18 |
| SG157285A1 (en) | 2009-12-29 |
| GB2462696B (en) | 2011-05-04 |
| GB0906532D0 (en) | 2009-05-20 |
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