CN102092985B - Treatment method for modifying money printing ink waste liquid into cement or concrete admixture - Google Patents
Treatment method for modifying money printing ink waste liquid into cement or concrete admixture Download PDFInfo
- Publication number
- CN102092985B CN102092985B CN2011100055994A CN201110005599A CN102092985B CN 102092985 B CN102092985 B CN 102092985B CN 2011100055994 A CN2011100055994 A CN 2011100055994A CN 201110005599 A CN201110005599 A CN 201110005599A CN 102092985 B CN102092985 B CN 102092985B
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- China
- Prior art keywords
- waste liquid
- printing ink
- cement
- concrete admixture
- ink waste
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0046—Premixtures of ingredients characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention belongs to the field of money printing ink waste liquid modification and utilization, and particularly relates to a treatment method for modifying money printing ink waste liquid into cement or concrete admixture. At present, the money printing ink waste liquid is treated by mainly adopting flocculation, separation, refining, reproduction or direct burning and the like at home, but the methods have complex processes, more equipment and high treatment cost. In order to fulfill the purposes, the invention adopts the technical scheme that: the treatment method for modifying the money printing ink waste liquid into the cement or concrete admixture is characterized by comprising the following steps of: weighing raw materials for later use according to a proportion, mixing the raw materials, fully stirring the mixture for 3 to 4 hours in a container, and reacting the mixture at the temperature of between 10 and 20 DEG C to obtain an admixture finished product. The method is environmentally-friendly, and has zero emission and higher economic benefit.
Description
Technical background
The invention belongs to the waste liquid modified field that utilizes of banknote printing ink, be specifically related to the treatment process of the waste liquid modified one-tenth cement of a kind of banknote printing ink, concrete admixture.
Background technology
The waste liquid that the banknote printing ink waste liquid is produced when being the intaglio printing press production of seal paper money factory because of it has serious destruction to forbid external discharging to environment, must be dealt carefully with waste liquid.At present, both at home and abroad seal paper money liquid waste disposal is mainly adopted: flocculation, separate, refine, produce again or directly Fan burn etc., but these method complex process, equipment is many, processing cost is high.
Summary of the invention
In order to overcome the defective of prior art, the purpose of this invention is to provide the treatment process of the waste liquid modified one-tenth cement of a kind of technology banknote printing ink simple, with low cost, concrete admixture.
To achieve these goals, the technical scheme of the present invention's employing is:
The treatment process of the waste liquid modified one-tenth cement of a kind of banknote printing ink, concrete admixture, its special character is: its process step is following:
1, takes by weighing trolamine, 2.5-20 weight part tri-isopropanolamine, the 3.5-30 weight part xylogen of banknote printing ink waste liquid that raw material is the 30-70 weight part, 10-30 weight part, the sodium sulfate or the calcium sulfate of 4.1-10 weight part; 5.1-10 the inorganic salt of weight part; 0.5-10 the organosilicon of weight part
2, above-mentioned raw materials is mixed,
3, said mixture was fully stirred 3-4 hour in container, temperature of reaction is 10-20 ℃,
4, obtain the admixture finished product.
With respect to prior art; Advantage of the present invention is: the present invention is turned waste into wealth through to the waste liquid modified one-tenth cement of banknote printing ink, concrete admixture, realizes the waste liquid complete utilization; There is not the secondary recycling waste material when producing cement, concrete admixture yet; Pollution-free, zero release, and the cement, the concrete admixture cost that utilize the printing ink waste liquid to produce are lower, and economic benefit is higher.
Description of drawings
Fig. 1 is a schema of the present invention.
Embodiment
Below in conjunction with accompanying drawing and specific embodiment the present invention is further specified.
Embodiment 1:
1, takes by weighing trolamine, 2.5 weight part tri-isopropanolamines, the 3.5 weight part xylogen of banknote printing ink waste liquid that raw material is 30 weight parts, 10 weight parts, the sodium sulfate or the calcium sulfate of 4.1 weight parts, the inorganic salt of 5.1 weight parts, the organosilicon of 0.5 weight part;
2, above-mentioned raw materials is mixed;
3, said mixture was fully stirred 3 hours in container, temperature of reaction is 10 ℃;
4, obtain the admixture finished product;
After the above-mentioned steps operation, finally be formed with the non-stimulated smell brown liquid of a certain amount of throw out and suspended substance.
Product is carried out technical index determining, and pH value is 7, solid content is 20%.
Utilize cement, the concrete admixture of the waste liquid modified one-tenth of banknote printing ink to oppose than test with Shandong one well-known cement, the concrete admixture that adds grinding agent company, test is carried out on 3.2 * 13m machine in certain cement mill, and experimental result data is following:
Embodiment 2:
1, takes by weighing trolamine, 20 weight part tri-isopropanolamines, the 30 weight part xylogen of banknote printing ink waste liquid that raw material is 70 weight parts, 30 weight parts, the sodium sulfate or the calcium sulfate of 10 weight parts, the inorganic salt of 10 weight parts, the organosilicon of 10 weight parts;
2, above-mentioned raw materials is mixed;
3, said mixture was fully stirred 4 hours in container, temperature of reaction is 20 ℃;
4, obtain the admixture finished product.
After the above-mentioned steps operation, finally be formed with the non-stimulated smell brown liquid of a certain amount of throw out and suspended substance.
Product is carried out technical index determining, and pH value is 13, solid content is 40%.
Seal paper money waste liquid cement cement, concrete admixture are opposed than test with Shandong one well-known cement, the concrete admixture that adds grinding agent company, and test is carried out on 3.2 * 13m machine in certain cement mill, and experimental result data is following:
。
Embodiment 3:
1, takes by weighing trolamine, 12 weight part tri-isopropanolamines, the 15 weight part xylogen of banknote printing ink waste liquid that raw material is 55 weight parts, 20 weight parts, the sodium sulfate or the calcium sulfate of 7 weight parts, the inorganic salt of 7.5 weight parts, the organosilicon of 5.5 weight parts;
2, above-mentioned raw materials is mixed;
3, said mixture was fully stirred 3.5 hours in container, temperature of reaction is 15 ℃;
4, obtain the admixture finished product.
After the above-mentioned steps operation, finally be formed with the non-stimulated smell brown liquid of a certain amount of throw out and suspended substance.
Product is carried out technical index determining, and pH value is 9, solid content is 60%.
Seal paper money waste liquid cement cement, concrete admixture are opposed than test with Shandong one well-known cement, the concrete admixture that adds grinding agent company, and test is carried out on 3.2 * 13m machine in certain cement mill, and experimental result data is following:
Cement, concrete cement, concrete admixture are building materials industry products commonly used; Has the yield and quality of raising, energy-saving and cost-reducing; Improve the effect of cement and the relevant performance of mixed earth; The product that a series of difference in functionalitys are arranged, this cement, concrete admixture product mainly are that material is composite forms by alcohols, alcamines tensio-active agent and inorganic salts etc.
After deliberation; Seal paper money waste liquid mainly is to be become to be grouped into by printing ink, Viscotrol C, sodium hydroxide and water etc.; Wherein printing ink content is up to 10 ~ 20%; The printing ink staple is an organic surface active agent, and like pure and mild hydramine material, these compositions match with cement and concrete cement, concrete admixture basal component.Sodium hydroxide is within the specific limits to the hydration reaction of cement, and improving strength of cement has promoter action.
Claims (2)
1. the treatment process of the waste liquid modified one-tenth cement of banknote printing ink, concrete admixture, it is characterized in that: its process step is following:
1) takes by weighing trolamine, 2.5-20 weight part tri-isopropanolamine, the 3.5-30 weight part xylogen of banknote printing ink waste liquid that raw material is the 30-70 weight part, 10-30 weight part, the sodium sulfate or the calcium sulfate of 4.1-10 weight part; 5.1-10 the inorganic salt of weight part; 0.5-10 the organosilicon of weight part
2) above-mentioned raw materials is mixed,
3) said mixture was fully stirred 3-4 hour in container, temperature of reaction is 10-20 ℃,
4) obtain the admixture finished product.
2. the treatment process of the waste liquid modified one-tenth cement of banknote printing ink according to claim 1, concrete admixture; It is characterized in that: wherein the banknote printing ink waste liquid is that 55 weight parts, trolamine are that 20 weight parts, xylogen are that 15 weight parts, sodium sulfate or calcium sulfate are that 7 weight parts, inorganic salt are that 7.5 weight parts, organosilicon are 5.5 weight parts; Reaction times is 3.5 hours, and temperature of reaction is 15 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100055994A CN102092985B (en) | 2011-01-12 | 2011-01-12 | Treatment method for modifying money printing ink waste liquid into cement or concrete admixture |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100055994A CN102092985B (en) | 2011-01-12 | 2011-01-12 | Treatment method for modifying money printing ink waste liquid into cement or concrete admixture |
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| CN102092985A CN102092985A (en) | 2011-06-15 |
| CN102092985B true CN102092985B (en) | 2012-12-05 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102491676A (en) * | 2011-12-14 | 2012-06-13 | 天津达尔科技有限公司 | Concrete synergist and preparation method for same |
| CN106883479B (en) * | 2017-04-11 | 2018-11-20 | 南昌印钞有限公司 | A kind of rubber and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6165262A (en) * | 1998-01-20 | 2000-12-26 | Nippon Shokubai Co., Ltd. | Cement additive and cement composition using same |
| WO2003091180A1 (en) * | 2002-04-25 | 2003-11-06 | Nippon Shokubai Co., Ltd. | Cement admixture and production method thereof |
| CN1982254A (en) * | 2005-12-15 | 2007-06-20 | 苏泽彬 | Antiseptic concrete air-tight agent composition and its production |
| CN101289293A (en) * | 2008-06-13 | 2008-10-22 | 北京工业大学 | Polycarboxylic acids anti-freeze agent for cement concrete and method for preparing same |
| CN101508534A (en) * | 2009-04-09 | 2009-08-19 | 宜兴市燎原化工有限公司 | Concrete deicing chemical containing thiocyanate |
| CN101693605A (en) * | 2009-10-12 | 2010-04-14 | 东阿东昌天汇科技有限公司 | Composite high-efficient liquid cement grinding aid |
| CN101693606A (en) * | 2009-10-12 | 2010-04-14 | 东阿东昌天汇科技有限公司 | Composite high-efficient environment-friendly powdery cement grinding aid |
-
2011
- 2011-01-12 CN CN2011100055994A patent/CN102092985B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6165262A (en) * | 1998-01-20 | 2000-12-26 | Nippon Shokubai Co., Ltd. | Cement additive and cement composition using same |
| WO2003091180A1 (en) * | 2002-04-25 | 2003-11-06 | Nippon Shokubai Co., Ltd. | Cement admixture and production method thereof |
| CN1982254A (en) * | 2005-12-15 | 2007-06-20 | 苏泽彬 | Antiseptic concrete air-tight agent composition and its production |
| CN101289293A (en) * | 2008-06-13 | 2008-10-22 | 北京工业大学 | Polycarboxylic acids anti-freeze agent for cement concrete and method for preparing same |
| CN101508534A (en) * | 2009-04-09 | 2009-08-19 | 宜兴市燎原化工有限公司 | Concrete deicing chemical containing thiocyanate |
| CN101693605A (en) * | 2009-10-12 | 2010-04-14 | 东阿东昌天汇科技有限公司 | Composite high-efficient liquid cement grinding aid |
| CN101693606A (en) * | 2009-10-12 | 2010-04-14 | 东阿东昌天汇科技有限公司 | Composite high-efficient environment-friendly powdery cement grinding aid |
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| CN102092985A (en) | 2011-06-15 |
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