CN102277239A - Natural plant aqueous cleaning agent and preparation method thereof - Google Patents

Natural plant aqueous cleaning agent and preparation method thereof Download PDF

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Publication number
CN102277239A
CN102277239A CN2011102031922A CN201110203192A CN102277239A CN 102277239 A CN102277239 A CN 102277239A CN 2011102031922 A CN2011102031922 A CN 2011102031922A CN 201110203192 A CN201110203192 A CN 201110203192A CN 102277239 A CN102277239 A CN 102277239A
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CN
China
Prior art keywords
parts
cleaning agent
thickener
clean
natural plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2011102031922A
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Chinese (zh)
Inventor
张刚
樊如
刘俊勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Liuhong Sci & Tech Dev Co Ltd
Original Assignee
Tianjin Liuhong Sci & Tech Dev Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Liuhong Sci & Tech Dev Co Ltd filed Critical Tianjin Liuhong Sci & Tech Dev Co Ltd
Priority to CN2011102031922A priority Critical patent/CN102277239A/en
Priority to PCT/CN2011/077833 priority patent/WO2013010338A1/en
Publication of CN102277239A publication Critical patent/CN102277239A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C11D3/188—Terpenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

The invention relates to a natural plant aqueous cleaning agent, which is characterized by being prepared by mixing the following components in part by weight: 5 to 15 parts of limonene, 3 to 7 parts of alkaryl ether sulfate (Disponil AES48), 10 to 15 parts of alkylphenol polyoxyethylene ether (Dispersant130), 0.5 to 1 part of associative thickener (Thickener 3820) and 62 to 81.5 parts of deionized water. The preparation method comprises the following steps of: mixing the components, stirring in a high-speed dispersion machine at the temperature of between 55 and 65 DEG C at a speed of between 700 and 900r/min for 5 to 10 minutes, and performing micro-emulsification to prepare the cleaning agent. The natural plant aqueous cleaning agent is prepared according to a reasonable formula, and is easy to prepare and low in cost; and the demixing phenomenon after emulsification is prevented effectively, and the cleaning effect is improved. During application, the cleaning agent is safe, environment-friendly, high in detersive power and safe and reliable in use and storage, and avoids damage to paint films of home appliances, glass, ceramic tile, steels and the like.

Description

Natural phant water-based clean-out system and preparation method thereof
Technical field
The present invention relates to a kind of clean-out system and preparation method thereof, particularly a kind of natural phant water-based clean-out system and preparation method thereof.
Background technology
At present, on the market and the clean-out system of every profession and trade widespread usage mostly be organic raw material such as containing benzene,toluene,xylene or cyclononane, wherein benzene is high carcinogenic substance, and toluene and dimethylbenzene mainly are to influence central nervous system, respiratory tract and skin are produced hormesis to the harm of human body.Often use, can cause great injury HUMAN HEALTH.And because the toxicity of itself all can have very big potential safety hazard in production and transportation.Drawbacks such as above-mentioned raw materials ubiquity flash-point and burning-point are lower are arranged again, production unit and environment are had stricter requirement, thereby strengthen input and the production cost of implementing.On the market though some clean-out systems based on natural matter are arranged now, since unstable after the emulsification, demixing phenomenon appears easily, not only use inconvenience, and cleaning performance is not obvious; Also have some clean-out systems, be solvent type clean-out system based on natural plant raw material, though effect is better in use, clean dirt after, solvent is difficult to clean or be difficult to volatilization, causes use inconvenient.For example, people adopt above-mentioned various clean-out system to clean article such as household electrical appliances, lampblack absorber usually, often can not get preferable cleaning performance.
Therefore, provide a kind of cyclic regeneration aboundresources, technology simple, be widely used, environment friendly and pollution-free natural phant water-based clean-out system and preparation method thereof, be one of these those skilled in the art problem that should address.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point, provide a kind of cyclic regeneration aboundresources, technology simple, be widely used, environment friendly and pollution-free natural phant water-based clean-out system and preparation method thereof.
The technical solution adopted in the present invention is for achieving the above object: a kind of natural phant water-based clean-out system, it is characterized in that counting by weight, by 5～15 parts of limonene, 3～7 parts of alkyl aryl ether sulfates, 10～15 parts of alkylphenol polyoxyethylene, 0.5～1 part of associative thickener, 62～81.5 parts of deionized waters, microemulsified is formulated;
Described alkyl aryl ether sulfate is Disponil AES 48;
Described alkylphenol polyoxyethylene is Dispersant 130;
Described associative thickener is Thickener 3820.
Concrete implementation step is as follows: count by weight 5～15 parts of limonene, 3～7 parts of alkyl aryl ether sulfates, 10～15 parts of alkylphenol polyoxyethylene, 0.5～1 part of associative thickener, 62～81.5 parts of mixing of deionized water, in temperature is under 55 ℃～65 ℃ conditions, stirred 5～10 minutes with the speed of high speed dispersor at 700～900 rev/mins, microemulsified is formulated;
Described alkyl aryl ether sulfate is Disponil AES 48;
Described alkylphenol polyoxyethylene is Dispersant 130;
Described associative thickener is Thickener 3820.
Detection method and result:
Detection method: detect by company standard Q/12NK4971-2010 natural phant water-based clean-out system.
Physicochemical property: comprise not tolerant, flash-point, pH value, thermostability, cold stability, to the influence of metallic substance: soak burn into entirely and remove cadmium, to the influence of coatingsurface, extended storage stability detects the standard that reaches fully.Objectionable impurities comprises free formaldehyde, benzene,toluene,xylene, methylene dichloride, 1,2-ethylene dichloride, 1,1,2-trichloroethane, trieline, heavy metal content comprise that dissoluble lead, soluble cadmium, soluble chromium, soluble mercury etc. are well below relevant national standard.Cleaning efficiency surpasses similar clean-out system and exceeds standard.
The invention has the beneficial effects as follows: the main component of this waterborne cleaning agent is a smart distillation extraction from natural plant such as orange skin, lemon peel, Pericarpium citri sinensis, and environment-protecting asepsis is pollution-free.Other composition is the environmental protection raw material, environmental sound.Utilize micro-emulsion technology, make the pollution-free waterborne cleaning agent of environment-protecting asepsis.Main ingredient limonene wherein has stronger solvency power, and Disponil AES 48, Dispersant 130 reduce interfacial tension, Thickener 3820 stabilising systems.This clean-out system does not contain benzene,toluene,xylene, cyclononane etc. to the poisonous and hazardous material of human body, heavy metal such as yet not leaded, chromium, cadmium and mercury.Do not pollute the environment in the production process, do not have potential safety hazard.Production technique is simple, easy to operate, the production environment condition is loose, need not the supporting facility that decontaminates, and has significant use value and economic benefit.The present invention is a waterborne cleaning agent, uses, storage safe is reliable, potential safety hazards such as no combustion explosion.Adopting raw material is the recyclable regenerative resource, and the source is abundant and extensive.Reach the removing source of pollution in utilization of waste material, when turning waste into wealth, effectively implement resource integration.The present invention uses micro-emulsion technology, forms the thermodynamic stable system of appearance transparent, has avoided demixing phenomenon after the emulsification, has improved cleaning performance.This clean-out system safety and environmental protection, strong detergency, technology is simple, and cost is lower; Organic chemical industry's clean-out system of benzene class thing as an alternative cleans, decontamination, particularly uses the daily smeary of family and cleans, and effect is splendid; And to no any infringements such as the paint film of household electrical appliances, glass, ceramic tile, steel.
Embodiment
Below in conjunction with preferred embodiment, to details are as follows according to embodiment provided by the invention:
Every part of embodiment 1(is by 1 kg)
With limonene (principal constituent〉95%) 5kg, Disponil AES 48(alkyl aryl ether sulfate) 3kg, Dispersant 130(alkylphenol polyoxyethylene) 10kg, Thickener 3820(associative thickener) 1kg, deionized water 81kg mix; In temperature is under 55 ℃～65 ℃ conditions, stirs 5～10 minutes with the speed of high speed dispersor at 700～900 rev/mins, and microemulsified is mixed with natural phant water-based clean-out system routinely.
Each component content is mass percentage concentration; Disponil AES 48, Dispersant 130, Thickener 3820 are Shenzhen Haichuan Chemical Technology Co., Ltd's product.
Every part of embodiment 2(is by 1 kg)
With limonene (principal constituent〉95%) 8kg, Disponil AES 48(alkyl aryl ether sulfate) 4kg, Dispersant 130(alkylphenol polyoxyethylene) 12.5kg, Thickener 3820(associative thickener) 0.5kg, deionized water 75kg mixes; In temperature is under 55 ℃～65 ℃ conditions, stirs 5～10 minutes with the speed of high speed dispersor at 700～900 rev/mins, and microemulsified is mixed with natural phant water-based clean-out system.
Other is with embodiment 1.
Every part of embodiment 3(is by 1 kg)
With limonene (principal constituent〉95%) 15kg, Disponil AES 48(alkyl aryl ether sulfate) 7kg, Dispersant 130(alkylphenol polyoxyethylene) 15kg, Thickener 3820(associative thickener) 0.7kg, deionized water 62.3kg mix; In temperature is under 55 ℃～65 ℃ conditions, stirs 5～10 minutes with the speed of high speed dispersor at 700～900 rev/mins, and microemulsified is mixed with natural phant water-based clean-out system.
Other is with embodiment 1.
Characteristics of the present invention and purposes:
(1) the present invention adopts micro-emulsion technology, forms the thermodynamic stable system of appearance transparent, has solved the emulsification demixing phenomenon, to improve dispersion, emulsification, the soil removability of clean-out system.
(2) to adopt limonene be solvent in the present invention, effectively improves ability of cleaning greasy dirt, and environment friendly and pollution-free.
Using method:
Select clean-out system of the present invention evenly to spray or be brushed on the article that will clean, directly clean with cloth, clean with clear water, using cloth to wipe with at last to do gets final product; Cleaning performance is remarkable; Storage leave standstill do not precipitate, not stratified, can directly use, needn't shake up by restir, extremely easy to use.
Above-mentioned detailed description of this natural phant water-based clean-out system and preparation method thereof being carried out with reference to embodiment; be illustrative rather than determinate; can enumerate several embodiment according to set of dispense than qualification scope; therefore in the variation and the modification that do not break away under the general plotting of the present invention, should belong within protection scope of the present invention.

Claims (2)

1. natural phant water-based clean-out system, it is characterized in that counting by weight, by 5～15 parts of limonene, 3～7 parts of alkyl aryl ether sulfates, 10～15 parts of alkylphenol polyoxyethylene, 0.5～1 part of associative thickener, 62～81.5 parts of deionized waters, microemulsified is formulated;
Described alkyl aryl ether sulfate is Disponil AES 48;
Described alkylphenol polyoxyethylene is Dispersant 130;
Described associative thickener is Thickener 3820.
2. the preparation method of natural phant water-based clean-out system according to claim 1, it is characterized in that implementation step is as follows: count by weight with 5～15 parts of limonene, 3～7 parts of alkyl aryl ether sulfates, 10～15 parts of alkylphenol polyoxyethylene, 0.5～1 part of associative thickener, 62～81.5 parts of mixing of deionized water, in temperature is under 55 ℃～65 ℃ conditions, stirred 5～10 minutes with the speed of high speed dispersor at 700～900 rev/mins, microemulsified is formulated;
Described alkyl aryl ether sulfate is Disponil AES 48;
Described alkylphenol polyoxyethylene is Dispersant 130;
Described associative thickener is Thickener 3820.
CN2011102031922A 2011-07-20 2011-07-20 Natural plant aqueous cleaning agent and preparation method thereof Pending CN102277239A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2011102031922A CN102277239A (en) 2011-07-20 2011-07-20 Natural plant aqueous cleaning agent and preparation method thereof
PCT/CN2011/077833 WO2013010338A1 (en) 2011-07-20 2011-07-30 Natural plant water-based cleaning agent and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011102031922A CN102277239A (en) 2011-07-20 2011-07-20 Natural plant aqueous cleaning agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN102277239A true CN102277239A (en) 2011-12-14

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Country Status (2)

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CN (1) CN102277239A (en)
WO (1) WO2013010338A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103690400A (en) * 2013-12-24 2014-04-02 天津鎏虹科技发展有限公司 Natural plant type body wash and preparation method thereof
CN103789108A (en) * 2014-03-05 2014-05-14 宫翊 Gel scavenger for mucilage glue and asphalt
CN104877778A (en) * 2015-06-22 2015-09-02 天津博克尼科技发展有限公司 Preparation method for cooking utensil cleaning agent
CN106566704A (en) * 2016-09-30 2017-04-19 格林润滑科技（惠州）有限公司 Environment-friendly outer wall strong cleaning agent

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CN104674574B (en) * 2015-02-13 2016-09-07 浙江传化股份有限公司 One is deoiled level dyeing compound emulsifying agent and application thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103690400A (en) * 2013-12-24 2014-04-02 天津鎏虹科技发展有限公司 Natural plant type body wash and preparation method thereof
CN103789108A (en) * 2014-03-05 2014-05-14 宫翊 Gel scavenger for mucilage glue and asphalt
CN104877778A (en) * 2015-06-22 2015-09-02 天津博克尼科技发展有限公司 Preparation method for cooking utensil cleaning agent
CN106566704A (en) * 2016-09-30 2017-04-19 格林润滑科技（惠州）有限公司 Environment-friendly outer wall strong cleaning agent

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