CN102482802B - Biluminescent colored fibers - Google Patents
Biluminescent colored fibers Download PDFInfo
- Publication number
- CN102482802B CN102482802B CN201080035727.3A CN201080035727A CN102482802B CN 102482802 B CN102482802 B CN 102482802B CN 201080035727 A CN201080035727 A CN 201080035727A CN 102482802 B CN102482802 B CN 102482802B
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- China
- Prior art keywords
- subregion
- colored fibre
- thin slice
- luminescent substance
- fibre
- Prior art date
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/30—Luminescent or fluorescent substances, e.g. for optical bleaching
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
Abstract
The invention relates to fluorescent colored fibers which are labeled with a first luminescent substance and which consist at least to some extent of an adhesive, to a film comprising colored fibers and to a document having said colored fibers. The invention further relates to methods for producing fluorescent colored fibers, to a method for producing a film having fluorescent colored fibers and to a method for producing a document having fluorescent colored fibers. The invention provides a particularly forgery-proof and easy-to-produce security feature for documents of value and security documents.
Description
Technical field
The present invention relates to a kind of fluorescence colored fibre, described fluorescence colored fibre has been labeled the first luminescent substance and has been made up of adhesive at least to a certain extent, relates to the thin slice that includes color fibre and relates to the file with described colored fibre.The invention still further relates to the method manufacturing fluorescence colored fibre, the method for the method of the thin slice of fabricated ribbon fluorescence colored fibre and the file of fabricated ribbon fluorescence colored fibre.
Prior art
There is known from prior art the method that manufactures luminous colored fibre and introduce them, especially they being incorporated into the method in paper in the manufacture process of paper.
There is known the method for dyeing organic fiber from DE 41 33 977 A1, its dope dyeing (spin dyeing) being different from prior art is that it uses the aqueous solution of cationic polymer and then uses the water slurry of pigment to dye a small amount of fiber.In the case of any possible, the particle size for the particle dyeed should < 10 μm.
There is known from DE 37 19 48 A and manufacture the method that the ring of light produces colored fibre.Be embedded into the paper in it by dry colored fibre, these colored fibres make paper stamp color, thus the ring of light is formed in around colored fibre, can be easy to like this remove fiber.
There is known the safety paper of band colored fibre from EP 1 268 935 B1, different luminous colored fibres is embedded into, and object is encoded in the different subregions of paper.Luminescent substance can be introduced in colored fibre or only be applied on their surface.The characteristics of luminescence is such as the die-away time of emission wavelength or luminous rays.
A shortcoming of this prior art is that the types of patterns introduced is very limited.Strip pattern is only disclosed in EP 1 268 935B1.In addition, the method manufacturing this safety paper can not for the manufacture of the file based on plastics, because colored fibre loosely to be arranged on hard frosting therefore by Arbitrary distribution and can not the pattern of replication application.
The safety paper of the colored fibre with at least one type is there is known from DE 103 24 630 A1, for the manufacture of the marketable securities be made up of safety paper (valuable document), such as banknote.Colored fibre comprises the luminescent substance with the peculiar characteristics of luminescence.These colored fibres can be designed to bicomponent fiber, wherein form core sheath structure.If sheath part is low molten material and preferably have advantage especially by being melting in the temperature range of 95 to 150 DEG C.These fibers demonstrate bondingly better in subregion, and wherein colored fibre is added in the manufacture process of paper.The Production Example of colored fibre as melt spinning (melt spinning) can be used, wet spinning (wet spinning), or dry spinning (dry spinning) technique and realizing.Colored fibre has special geometric format and information can be coded on this geometric format.But shortcoming is that the inspection of this fiber needs technology auxiliary and time-consuming.Such as, the form of colored fibre can be seen under an optical microscope.But this process is unsuitable for quick test, such as, in point of sale.
the problem of prior art and object of the present invention
For the colored fibre of prior art, Problems existing is that these can be copied easily via press-in fluorochrome.For this reason, adulterator uses fuel on forging document, print the image of the fiber of arbitrarily distribution.These counterfeits can be detected, but very hard, such as, by means of microscope.
Be introduce based in the file of plastics according to another problem of the colored fibre of prior art, be especially introduced through laminated plastic thin slice and in the file that manufactures.Use known method, laminated fiber to be sown on one of them thin slice and therefore to be produced random pattern.But compared with paper manufacture, the problem done like this is that fiber does not bond on thin slice, by any way because they do not carry out laminated.Like this, we can know that the manufactured factory of a large amount of fibers carries out distributing and therefore privately may manufacture the other products that should not comprise any colored fibre or should comprise different fiber.
Based on this, the object of this invention is to provide a kind of colored fibre, it is easy to inspection, easy to implement and structure, and integrated to be especially integrated in plastic document simple.
Summary of the invention
These objects by fluorescence colored fibre according to claim 1, according to claim 13 include color fibre thin slice, according to claim 18ly comprise the file of fluorescence colored fibre, the manufacture method according to the manufacture method of the fluorescence colored fibre of claim 21 and 23, the thin slice of band fluorescence colored fibre according to claim 25, and to be achieved according to the manufacture method of the file of the band fluorescence colored fibre of claim 31.Dependent claims has set forth the preferred embodiments of the present invention.
According to the present invention, above-mentioned purpose is achieved by following: colored fibre comprises at least two kinds of luminescent substances and adhesive.
Fluorescence colored fibre according to the present invention has the first and second luminescent substances.First luminescent substance launches the first utilizing emitted light under the first incentive condition and the second luminescent substance launches the second utilizing emitted light under the second incentive condition.In this configuration, the first and second incentive conditions are different, and the first and second radiative spectrum are different.In addition, colored fibre is made up of adhesive at least partly.
An advantage according to fluorescence colored fibre of the present invention is owing to there is adhesive so be more easily integrated in the file based on plastics, and can distinguish so enhance the security of opposing forgery due to the utilizing emitted light color of launching under the first and second incentive conditions.In addition, adhesive makes the connection between colored fibre and file not disconnect, thus therefore can not can not be forged and forge document from file removing according to fluorescence colored fibre of the present invention.
In a preferred embodiment of colored fibre, they have at least one first subregion and at least one second subregion.Described subregion by perpendicular to described fiber direction and be preferably parallel to disposed adjacent one another.Such as, a sub regions forms half, a left side for fiber and another forms right half, or one of them subregion surrounds another subregion, and such as, the core in cable is surrounded by insulating barrier.At least one first subregion described is made up of adhesive.At least one first subregion described and/or at least one second subregion described have been labeled the first luminescent substance and at least one first subregion described and/or at least one second subregion described have been labeled the second luminescent substance.The advantage of two sub regions is that the space that can realize different light-emitting zone is separated, and this is easy to carry out optical check.Therefore, two kinds of luminescent substances may reside in identical and/or different subregions.
Here hereinafter, the first subregion is understood to region, and it is preferably manufactured from the same material but is spatially separated from each other.For second and may exist the 3rd and other subregion be also like this.Therefore, all first subregions preferably have identical material behavior, and this makes them very clearly be different from all second and other subregion.Such as, the colored fibre made by spinning can be made up of at least two kinds of fibers, and they are separated from one another but be woven into inside each other.The yarn be manufactured from the same material is seen as identical subregion, such as, as the first subregion.
In the preferred embodiment of colored fibre, comprise the light of wave-length coverage from 380 to 300nm for encouraging described first incentive condition of described first luminescent substance.Particularly, described first luminescent substance can by UV-A and UV-B ray, and wavelength is 365nm and 316nm particularly, excitation.For the suitable selection of the material of near surface or the introducing of colored fibre, can also to go directly 200nm, especially 254nm by means of wavelength, UV-C ray excitation.
In another preferred embodiment of colored fibre, comprise the light of wave-length coverage from 320 to 300nm for encouraging described second incentive condition of described second luminescent substance.Particularly, described second luminescent substance can not can only be used UV-B ray excitation by UV-A ray, can not can only use the ray excitation of wavelength 316nm particularly by the ray excitation of wavelength 365nm.
In another preferred embodiment of colored fibre, the other subregion that at least one first subregion described surrounds at least one second subregion described and also may exist.Such as, at least one second subregion described forms core and at least one first subregion described around core as sheath, and such as, the line in cable is surrounded by insulating barrier.
In another preferred embodiment of colored fibre, at least one first subregion described comprises described first luminescent substance and at least one second subregion described comprises described second luminescent substance.
In another preferred embodiment of colored fibre, at least one first subregion described comprises described first luminescent substance and at least one second subregion described comprises the first and second luminescent substances.
In another preferred embodiment of colored fibre, they have at least one the 3rd subregion in addition, and at least one second subregion wherein said and at least one the 3rd subregion described are surrounded by least one first subregion described.In this configuration, described at least one second and at least one the 3rd subregion described can location adjacent one another are or disposed adjacent one another or be spaced apart from each other arrange and can be separated from each other by least one first subregion described.
Such as, at least one second subregion described and at least one the 3rd subregion described can be enclosed in the sheath be made up of at least one first subregion described as two cores, compared with having the line of two cables.Therefore automatically recognize and can imagine multiple second and/or the 3rd and the other subregion that also may exist.If we design that the second subregion is A and the 3rd subregion is B, so, such as, pattern ABA or pattern ABAB may be there is for the single bar in colored fibre, wherein, these three or four sub regions are all surrounded by first subregion be made up of adhesive.
In another preferred embodiment of colored fibre, at least one first subregion described of colored fibre or colored fibre is made up of adhesive.Adhesive can be hot-melt adhesive or reactive adhesive.Such as, hot-melt adhesive has from 50 to 200 DEG C, preferably from 80 to 120 DEG C, softening point temperature.Reactive adhesive is such as acrylates adhesive.Adhesive does not preferably at room temperature have viscosity.Like this, at room temperature carry out colored fibre in the process that processes can separate well each other.
In another preferred embodiment of colored fibre, luminescent substance is inorganic pigment.Particularly, these luminescent substances can be rear-earth-doped oxides, oxinate, sulfide, oxysulfide, phosphate, or vanadate.Element europium, gadolinium, terbium, dysprosium, holmium, erbium, and thulium is particularly useful for rear-earth-doped (rare-earth doping).Such as, we can mention the pigment LUMILUX that can obtain from Honeywell
cD740 (redness) and CD702 (green).Best color is that particle size is less than or equal to 10 μm, is preferably less than or equal to 8 μm, those, and be particularly preferably be less than or equal to those of 6 μm.Inorganic pigment has the temperature stability of the softening point temperature higher than used polymer.
In another preferred embodiment of colored fibre, at least one second subregion described is made up of polyamide (PA) or polyamide copolymer.Particularly, we can use polyamide PA12, PA6, and PA6.6.PA6 is formed by the ring-opening polymerization (ring openingpolymerisation) of epsilon-caprolactams.PA6.6 (Nylon
) formed by dehydrating polycondensation manufacture by hexamethylene diamine (hexamethylenediamine) and adipic acid (adipic acid).Polyethylene (PE) can also be used, poly terephthalic acid second two (alcohol) ester (PET), polyvinyl chloride (PVC), cellulose and their derivative such as viscose glue (viscose) or glassine paper (cellophane).But polyamide is preferred, because this material reacts to each other minimum with the conventional laser system used in personalization of documents process.Particularly, when using PA, as required, use laser beam by documents blackening, equally in the region at colored fibre place.
Colored fibre can be selected for the form and geometry that change them.Feature is usually based on the length of colored fibre, diameter and cross-sectional form.A kind of typical length of colored fibre is positioned at the scope from 2 to 25mm, preferably about 6mm.Such as, diameter is in the scope of 20 to 150 μm and preferably from the scope of 50 to 60 μm.Cross-sectional form preferably leads circle (circle) or oval.
In addition, the present invention relates to the thin slice had in its surface according to fluorescence colored fibre of the present invention, colored fibre is by fastening by means of adhesive.Thin slice is preferably plastic tab, it is preferably made up of Merlon (PC), particularly, bisphenol A polycarbonate (bisphenol-Apolycarbonate), poly terephthalic acid second two (alcohol) ester (PET), the polyethylene terephthalate (PETG) that their derivative is such as glycol-modified, polyethylene naphtha (polyethylene naphthalate) (PEN), polyvinyl chloride (PVC), polyvinyl butyral resin (PVB), polymethyl methacrylate (PMMA), polyimides (PI), polyvinyl alcohol (PVA), polystyrene (PS), polyvinyl phenol (polyvinyl phenol) (PVP), polypropylene (PP), polyethylene (PE), thermoplastic elastomer (TPE) (TPE), especially thermoplastic polyurethane (TPU), acrylonitrile-butadiene-styrene (ABS) (ABS), Teslin
and their derivative.In addition, thin slice can be the thin slice of coextrusion (co-extruded), and can use other composite material, also comprises above-mentioned material.Thin slice also can be made of paper.
In another preferred embodiment of the thin slice of band colored fibre, colored fibre is arranged on the surface of thin slice by space structure.Such as, colored fibre is applied on thin slice with the form of bar, has the strip region of color fibre to be formed on thin slice and does not have the strip region of color fibre.In addition, the region having a color fibre such as can have shield, the form of seal or other pattern.
In another preferred embodiment of the thin slice of band colored fibre, at least two kinds of dissimilar fluorescence colored fibres are secured on the surface of thin slice.
In another preferred embodiment of the thin slice of band colored fibre, different according to dissimilar colored fibre spatial configuration of the present invention.Such as, colored fibre is applied on thin slice with the form of bar, with on thin slice formed exist the colored fibre of the first kind the first strip region and on thin slice formed there is the second strip region of the colored fibre of Second Type and do not have the Article 3 shape region of color fibre.In addition, the region of the colored fibre with certain type can be there is, such as, the form of shield or seal can be presented, and other type such as cover whole surface.
In addition, the present invention relates to the file of band according to fluorescence colored fibre of the present invention.Preferably, this file is marketable securities or insurance documentation.The example of marketable securities or insurance documentation is passport, identity card, driving license, visa, check and credit card, identity of company card (company identitycard), certificate (credential), member's status card, present buying voucher (gift andpurchase voucher), and recreation ground game money (casino playing chip), banknote, check, stamp, and stamp.Particularly, file has laminated card.The example with the file of laminated card comprises check and credit card and German driving license.
According to the present invention, manufacture and comprise according to the method for fluorescence colored fibre of the present invention: extrude by least one first spinning head at least one first subregion that at least the first polymer is formed with color fibre simultaneously, and, alternatively, meanwhile, extrude by least one second spinning head at least one second subregion that at least the second polymer is formed with color fibre simultaneously.Described at least one first polymer comprises the first luminescent substance, and described first luminescent substance launches the first utilizing emitted light under the first incentive condition.Adhesive is selected as the first polymer and/or as the second polymer.In addition, described first polymer and/or described second polymer comprise the second luminescent substance, and described second luminescent substance launches the second utilizing emitted light under the second incentive condition, and the first and second incentive conditions are not identical, and the first and second radiative spectrum are different.If only extrude a kind of first polymer so the first polymer comprise described first and second luminescent substances.If extrude the first polymer and the second polymer, so, such as, described first polymer can comprise described first luminescent substance and described second polymer can comprise described second luminescent substance, or described first polymer comprises described first luminescent substance and described second polymer comprises described first and second luminescent substances.
In another preferred embodiment of method manufacturing fluorescence colored fibre, at least one second subregion described is surrounded by least one first subregion described.Such as, this can realize by locating spinning head by rights, and this is very familiar for a person skilled in the art.Such as, six the first spinning heads can be arranged round the second spinning head.
In another embodiment of the method in accordance with the present invention, fluorescence colored fibre is manufactured by following step, in a first step, extrude at least one second polymer by least one spinning head and form at least one second subregion simultaneously, and in second step subsequently, at least one second subregion described is surrounded by least one first subregion of the first polymer.In this example, the first polymer is adhesive.Described at least one second polymer comprises the second luminescent substance, and described second luminescent substance launches the second utilizing emitted light under the second incentive condition.In addition, described first polymer and/or described second polymer comprise the first luminescent substance, described first luminescent substance launches the first utilizing emitted light under the first incentive condition, and described first and second incentive conditions are not identical, and the first and second radiative spectrum are different.Such as, colored fibre can use known method to make in the first method step.They are surrounded with adhesive in the second step, and adhesive comprises the first luminescent substance.Surround and such as can realize by means of dip coating.
Can be cut into the length of any expection in a further step according to the colored fibre of manufacture arbitrary in said method, this operation is not carried out in the fabrication process, but colored fibre is made into the yarn of endless.The length about 6mm usually of colored fibre.
According to the present invention, the method for the manufacture of the thin slice of band fluorescence colored fibre comprises provides thin slice, thin slice is applied according to fluorescence colored fibre of the present invention and is fixed on thin slice by fluorescence colored fibre.
In another preferred embodiment of the method for the thin slice of fabricated ribbon colored fibre, colored fibre is used heating and/or UV ray to fix in place.Such as, after application fluorescence colored fibre, make thin slice below IR radiator or by roll laminator (roller laminator), to make the adhesive of colored fibre soften or become liquid, and therefore colored fibre is fixed on thin slice.Alternatively, can thin slice be put in an oven after application fluorescence colored fibre, thin slice is heated to above the temperature of the softening point temperature of adhesive but the softening point temperature lower than thin slice.Alternatively or additionally, after application fluorescence colored fibre, thin slice is made below UV radiator activate the reactive adhesive of colored fibre and therefore to realize colored fibre to fixing on thin slice.
In another preferred embodiment of method manufacturing thin slice, colored fibre is only applied at least one first subregion of thin slice.Such as, colored fibre is applied on thin slice by the form with bar.Such as, this can upper by spraying, distributions upper or suppress above and realize.Colored fibre can also such as be applied with the form of shield or seal.This above can be realized by punching press or impression.
In another preferred embodiment of method manufacturing thin slice, substituting as previous embodiment, colored fibre is applied on the whole surface of thin slice.But colored fibre is only fixed at least one first subregion of thin slice.Such as, this can by changing ray and realizing with IR or UV light local, thus the colored fibre in making only lamellated at least one first subregion described is fixed in place.The colored fibre in place that is not fixed is removed by from thin slice subsequently, such as, by upset thin slice or by blowing or sop up the colored fibre in place and realizing of not being fixed off.
In another preferred embodiment of method manufacturing thin slice, the colored fibre of two types is applied on thin slice.On at least one first subregion that the colored fibre of the first kind is applied to thin slice and the colored fibre of Second Type be applied at least one second subregion of thin slice.The colored fibre of the first and second types is different.Particularly, this two type presents dissimilar fluorescence, to utilize the visual inspection comprising UV excitation can be easy to they be identified and make a distinction.In addition, the colored fibre of the first and second types can be distinguished based on the geometry of fiber.Such as, they may have different length, form, and/or different diameters.In addition, the colored fibre of the first and second types can also know feature (forensic feature) based on adding to debating in a wherein type, such as upper conversion (up-conversion) fluorescent material, distinguish uniquely, so that this distinguishes only to observe in the laboratory of special outfit.
In another preferred embodiment of method manufacturing thin slice, at least one first subregion and at least one subregion form pattern.The example of these patterns is the shields on substrate, and wherein shield is made up of first subregion with the first color and substrate is made up of second subregion with the second color.Another example of pattern is the numeral on banknote.At least one second subregion described can comprise at least one first subregion described around or otherwise around at least one first subregion described.But at least one is first identical with at least one second subregion.Such as, if the part that the first subregion comprises the whole surface of thin slice and at least one second subregion just surface is exactly this situation, such as, with the form of shield.Such as, the first subregion can be the subset of the second subregion, is made up of the mixture of the first and second colors on the substrate of the second color to make shield.
According to the method for the file of fabricated ribbon fluorescence colored fibre of the present invention comprise by band with good grounds colored fibre of the present invention at least one thin slice and, if need, at least one other thin slice is put together and the laminated thin slice combined.
In another preferred embodiment of the method for manufacturing documentation, cut from laminate at laminated at least one file rear or be stamped to form.If laminate is multiduty will be particularly advantageous.At least two kinds of files (purposes) can be manufactured individually by multiduty laminate and form, such as, cut or be stamped to form.
Accompanying drawing explanation
With reference now to accompanying drawing, embodiment of the present invention is described.Accompanying drawing shows:
Fig. 1 a to g: the schematic cross-sectional view of colored fibre;
Fig. 2: the schematic diagram of the colored fibre seen from above;
Fig. 3: with the schematic cross-sectional view of the manufacture of the thin slice of colored fibre;
Fig. 4: with the schematic cross-sectional view of the manufacture of the file of colored fibre;
Fig. 5: the schematic diagram of the file with colored fibre seen from above;
Fig. 6: the schematic diagram of another file with colored fibre seen from above;
Fig. 7: the schematic cross-sectional view manufacturing the other method of the thin slice with the colored fibre attached on it.
Detailed description of the invention
The identical reference number used below represents identical element.
Fig. 1 shows the schematic cross-sectional view of colored fibre.Its size not truly display but only for clearly representing space structure relative to each other.
Fig. 1 a shows the sectional drawing of colored fibre 10, and it is made up of first subregion 11 uniquely.First subregion is made up of adhesive.Adhesive comprises the first luminescent substance and also comprises the second luminescent substance alternatively, launches to make colored fibre 10 another utilizing emitted light being different from and launching under the second incentive condition under the first incentive condition.The advantage of shown colored fibre 10 manufactures simply in a procedure of processing.Although two kinds of luminescent substances are not separated each other spatially, copy relatively simple.
Fig. 1 b shows another colored fibre 10.1, and it is made up of the first subregion 11.1 and the second subregion 12.1.First subregion 11.1 is made up of adhesive and surrounds the second subregion 12.1.Such as, adhesive is hot-melt adhesive and the second subregion is made up of polyamide.Exemplarily, the first luminescent substance to be comprised in the first subregion 11.1 and the second luminescent substance is comprised in the second subregion 12.1 alternatively.The optical identification (opticalrecognition) that the advantage of the present embodiment is a simplified, due to the first and second radiative very different intensity distribution and different spectral characteristics.In addition advantageously, due to different material behaviors, if do not destroy file and remove colored fibre 10.1 no longer possibility, because the adhesive of subregion 11.1 can be formed into the permanent combination on file from file.
Fig. 1 c shows another colored fibre 10.2, and it is made up of the first subregion 11.2, second subregion 12.2 and the 3rd subregion 13.2.Such as, the first luminescent substance can be comprised in the second subregion 12.2 that second luminescent substance is comprised in the 3rd subregion 13.2.In the present embodiment, the thickness of the first subregion 11.2 be made up of adhesive can be very thin, because it needs the combination provided between color fibre and thin slice.
Fig. 1 d shows another colored fibre 10.3, and it is made up of the first subregion 11.3, second subregion 12.3 and the 3rd subregion 13.3.The structure of this colored fibre is identical with the colored fibre in Fig. 1 c, and wherein, the second subregion 12.3 and the 3rd subregion 13.3 are by the first subregion 11.3 separately.Such as, this colored fibre can connect two kinds by means of the adhesive of formation first subregion 11.3 and forms according to the colored fibre manufacture of prior art.
Fig. 1 e shows another colored fibre 10.4, and it is made up of the first subregion 11.4, second subregion the 12.4, three subregion 13.4 and the 4th subregion 14.4.Exemplarily, the second subregion can comprise the first luminescent substance, and the 3rd subregion comprises the second luminescent substance, and the 4th subregion comprises the 3rd luminescent substance.First subregion is made up of adhesive, and colored fibre can be fixed to thin slice by it.An advantage of this colored fibre presents three kinds of different colors adjacent one another are, and this causes simple optical identification.Utilize the three kinds of colors being in a certain position can also present the major part of national flag color, thus such as, can national specific coding be carried out.
Here a particular example is the colored fibre with the first subregion 11.4, two the second subregions 12.4 and 14.4 and the 3rd subregion 13.4.Such as, described two the second subregions comprise the first luminescent substance and the 3rd subregion comprises the second luminescent substance.First subregion 11.4 is made up of adhesive.
Fig. 1 f shows another colored fibre 10.5.It has the first subregion 11.5 and two the second subregions 12.5 that are made up of adhesive.Such as, the first subregion 11.5 comprises the first luminescent substance and the second subregion comprises the second luminescent substance.The advantage with the present embodiment of multiple second subregion is the fracture of the band occurred in the manufacture process of colored fibre in the second subregion, easily, is not defect by optics cognition.Which reduce the quantity of defective work.
Fig. 1 g shows another colored fibre 10.6, and it is by the first subregion 11.6 be made up of adhesive, and two the second subregions 12.6 and two the 3rd subregions 13.6 are formed.This form represents the combination of Fig. 1 d and the colored fibre shown in Fig. 1 f, and it combines the advantage of simple and that inspection is reliable and disqualification rate is low manufacture.
Fig. 2 shows the colored fibre 10.2 according to Fig. 1 c seen from above.It has the first subregion 11.2 be made up of adhesive.Colored fibre has the second subregion 12.2 comprising the first luminescent substance and the 3rd subregion 13.2 comprising the second luminescent substance in addition.For the optical check of colored fibre, this generates the image of the light-emitting section adjacent one another are of two kinds of different colours.The typical length on average about 6mm of this colored fibre.
Fig. 3 is with the schematic diagram of the manufacture of the thin slice of the with good grounds colored fibre of the present invention of the band shown in sectional drawing.Thin slice 30 can be obtained in first step (a).Thin slice 30 such as can be made up of PC.Then, be applied to by colored fibre (step b) on thin slice, such as, colored fibre has the first subregion 31 and the second subregion 32.First subregion 31 is formed by room temperature not having sticking hot-melt adhesive.Like this, colored fibre can be easily separated from each other and process.Preferably, the first subregion 31 comprises the first luminescent substance and the second subregion 32 comprises the second luminescent substance.In step (c) subsequently, colored fibre is fixed in place, and such as, by using IR lamp to heat up, the first subregion 31 is warmed up to the softening temperature of hot-melt adhesive by this.Like this, between colored fibre and thin slice 30, secure bond is achieved.Here schematically show the first subregion 31 for above-mentioned reasons can deform.This can be conducive to improving bonding on thin slice 30 of colored fibre.
Fig. 4 is with the schematic diagram of the manufacture method according to file of the present invention of the with good grounds colored fibre of the present invention of the band shown in sectional drawing.In first step (a), thin slice 30 according to the present invention has colored fibre, wherein colored fibre has the first subregion 31 and the second subregion 32, colored fibre is fixed on thin slice 30, thin slice 30 is by the thin slice with other, be such as two thin slices 35 and 36 here, put together in a stacked fashion.Skilled in the art will recognize that the normal configuration based on plastic document uses 3 to 15 thin slices usually.Such as, thin slice 30,35,36 is PC thin slices, and it has the glass transformation temperature (glass transition temperature) of about 148 DEG C.They are laminated flakiness under the pressure of increase and the temperature of rising, usual 170 to 210 DEG C, continues 5 to 60 minutes (step b).Monolithic card 38 is made into.Colored fibre is positioned at monolithic card 38, the first subregion 31 be wherein made up of hot-melt adhesive is deformed and is attached on file, because adhesive has glass transformation temperature lower than PC especially lower than glass transformation temperature or the fusing point of laminated temperature.Preferably, the second subregion can be designed to make the not obvious change under laminating conditions of their geometric format.Advantageously, the first subregion 31 comprises the first luminescent substance and the second subregion 32 comprises the second luminescent substance.Because the first subregion to be diffused in file so the first subregion is no longer detected as by the region of clear restriction in checkout procedure in laminated process.By the distortion of the first subregion 31, colored fibre no longer can overall remove, but only has the second subregion 32 to remove, so any trial operation obviously.
It will be apparent to one skilled in the art that obviously, thin slice 35 can be such as hologram (hologram), such as volume hologram (volume hologram) or marking (kinegram) figure.In addition, thin slice 36 can be so-called inlay, and it has chip and the antenna for contactless communication.This inlay can be made up of thermoplastic elastomers's body thermoplastic polyurethane (TPU) or TPU-PC compound.Those skilled in the art also will recognize that adhesive can be introduced into for reducing thin slice 30 and thin slice 35 and/or the laminated temperature between thin slice 30 and thin slice 36.
Fig. 5 shows the file 40 being with good grounds colored fibre 42 of the present invention with top view.Colored fibre is positioned on the subregion 41 of file 40.Subregion is such as arranged the form of slivering.The subregion of strip such as can represent code, such as bar code.This code such as represents the face amount (value) of file 40, such as banknote.It is contemplated that other form outside arranged in strips, some are alphabetical and/or digital particularly, such as, and numeral (value number) or country code.
Fig. 6 shows another file 50 being with good grounds colored fibre 53,54 of the present invention with top view.On the first subregion 51 that colored fibre 53 is placed in file 50 and colored fibre 54 be placed on the second subregion 52 of file 50.In the example shown, the second subregion 52 comprises the whole surface of file.Colored fibre 53 is different from colored fibre 54 in length in the example shown.Such as, colored fibre 53 about 5mm is long and colored fibre 54 is about 20mm.Colored fibre can also be distinguished without length, such as, based on glow color effect.First subregion 51 is shown as circle here.But, be easy to imagination first subregion 51 and present shield (coat of arms) or seal (seal), mark such as hawk, or the form of index.Be easy to recognize that multiple first subregion can represent shield or seal, mark such as hawk together in addition, or index, especially long number (multi-digit value number).
Fig. 7 is with the schematic diagram of the manufacture of the thin slice with the colored fibre be fixed thereon shown in top view.Thin slice 30 is obtained in first step (a).Thin slice 30 can be such as made up of PC.Then apply colored fibre (step b), such as, colored fibre has the first subregion 31 and the second subregion 32.First subregion 31 is formed by room temperature not having sticking hot-melt adhesive.Like this, colored fibre can be easily separated from each other and process.Preferably, the first subregion 31 comprises the first luminescent substance and the second subregion 32 comprises the second luminescent substance.Apply not recurring structure change, especially across whole surface.In step (c) below, some being fixed on thin slice of colored fibre is specified in subregion, and that is fixed structure ground occurs, to be connected with thin slice 30 in colored fibre only should be applied on thin slice 30 at them subregion.Such as by heating with IR lamp, colored fibre is fixed on thin slice, and the first subregion 31 is heated to the softening temperature of hot-melt adhesive by this.Secure bond is realized like this between colored fibre and thin slice 30.Schematically show in the drawings because the distortion of the first subregion 31 may occur this reason.This may be conducive to bonding on thin slice 30 of colored fibre.In last step (d), such as, remove revocable colored fibre by blowing off or siphon away.
Claims (14)
1. the file obtained by laminated plastic thin slice, described file comprises fluorescence colored fibre, wherein, described colored fibre has been labeled the first luminescent substance, described first luminescent substance launches the first utilizing emitted light under the first incentive condition, and described colored fibre is made up of adhesive at least partly, described colored fibre has been labeled the second luminescent substance, described second luminescent substance launches the second utilizing emitted light under the second incentive condition, first and second incentive conditions are not identical, and the first and second radiative spectrum are different, described colored fibre is fastened to the surface of described thin slice by the adhesive by means of described colored fibre, described thin slice is plastic tab, described colored fibre has at least one first subregion and at least one second subregion, subregion is disposed adjacent one another perpendicular to the direction of described fiber, at least one first subregion described is made up of adhesive, at least one first subregion described has been labeled described first luminescent substance, and at least one second subregion described has been labeled described second luminescent substance, and wherein, due to described Lamination, described first subregion is diffused in file.
2. the file obtained by laminated plastic thin slice according to claim 1, it is characterized in that, at least one second subregion described is surrounded by least one first subregion described.
3. the file obtained by laminated plastic thin slice according to claim 1 and 2, it is characterized in that, at least one second subregion described comprises described first luminescent substance in addition.
4. the file obtained by laminated plastic thin slice according to claim 1 and 2, it is characterized in that, described colored fibre also has at least one the 3rd subregion, and at least one second subregion described and at least one the 3rd subregion described are surrounded by least one first subregion described.
5. the file obtained by laminated plastic thin slice according to claim 1 and 2, it is characterized in that, described adhesive is hot-melt adhesive or reactive adhesive.
6. the file obtained by laminated plastic thin slice according to claim 1 and 2, it is characterized in that, at least one second subregion described is made up of polyamide or polyamide copolymer.
7. the file obtained by laminated plastic thin slice according to claim 1 and 2, it is characterized in that, described colored fibre is arranged on the surface of thin slice by the mode with spatial configuration.
8. the file obtained by laminated plastic thin slice according to claim 1 and 2, be is characterized in that, at least two kinds of dissimilar fluorescence colored fibres are secured on the surface of described thin slice.
9. the file obtained by laminated plastic thin slice according to claim 8, be is characterized in that, described dissimilar colored fibre spatial configuration is different.
10. a method for the file of fabricated ribbon fluorescence colored fibre, comprises the steps: A) by according to following step a)-c) at least one thin slice of manufacturing and at least one other thin slice put together:
A) provide thin slice, wherein said thin slice is plastic tab;
B) described fluorescence colored fibre is applied on described thin slice, wherein, described colored fibre has been labeled the first luminescent substance and the second luminescent substance, described first luminescent substance launches the first utilizing emitted light under the first incentive condition, described second luminescent substance launches the second utilizing emitted light under the second incentive condition, first and second incentive conditions are not identical, and the first and second radiative spectrum are different, described colored fibre is made up of adhesive at least partly, described colored fibre has at least one first subregion and at least one second subregion, subregion is disposed adjacent one another perpendicular to the direction of described fiber, and at least one first subregion described is made up of adhesive, at least one first subregion described has been labeled described first luminescent substance, and at least one second subregion described has been labeled described second luminescent substance, and
Described fluorescence colored fibre is fixed on the surface of thin slice by the adhesive c) by means of described colored fibre; And
B) the laminated thin slice be incorporated into together, makes the first subregion of described fluorescence colored fibre be diffused in file.
11. methods according to claim 10, is characterized in that, described colored fibre is used heating and/or UV ray and fixing in place.
12. methods according to claim 10 or 11, is characterized in that, at least one first subregion that described colored fibre is only applied to described thin slice is fixed in place subsequently.
13. methods according to claim 12, it is characterized in that, the described colored fibre be fixed at least one first subregion of described thin slice is the first colored fibre, and the second colored fibre is fixed at least one second subregion of described thin slice, and wherein said second colored fibre is different from described first colored fibre.
14. methods according to claim 13, is characterized in that, described second colored fibre on described first colored fibre at least one first subregion of described thin slice and at least one second subregion of described thin slice forms pattern.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009040747.2 | 2009-09-08 | ||
| DE200910040747 DE102009040747B3 (en) | 2009-09-08 | 2009-09-08 | Bililuminescent mottled fibers, a film having them, a document with these and methods for their preparation and a method for producing a document with these |
| PCT/EP2010/005332 WO2011029543A2 (en) | 2009-09-08 | 2010-08-27 | Biluminescent colored fibers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102482802A CN102482802A (en) | 2012-05-30 |
| CN102482802B true CN102482802B (en) | 2015-03-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201080035727.3A Active CN102482802B (en) | 2009-09-08 | 2010-08-27 | Biluminescent colored fibers |
Country Status (6)
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| EP (1) | EP2475811B1 (en) |
| CN (1) | CN102482802B (en) |
| AU (1) | AU2010294594B2 (en) |
| CA (1) | CA2768601C (en) |
| DE (1) | DE102009040747B3 (en) |
| WO (1) | WO2011029543A2 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012220701A1 (en) | 2012-11-13 | 2014-05-15 | Bundesdruckerei Gmbh | Security feature for a value and / or security product, the security and / or security product and method for producing the security feature |
| DE102012220703B4 (en) | 2012-11-13 | 2017-11-02 | Bundesdruckerei Gmbh | Security feature for a value and / or security product, the security and / or security product and method for producing the security feature |
| DE102013206130B4 (en) | 2013-04-08 | 2018-06-21 | Bundesdruckerei Gmbh | Multiluminescent security element and value or security document containing the same |
| US20150132575A1 (en) * | 2013-11-14 | 2015-05-14 | Honeywell International Inc. | Luminescent fibers, articles including the same, and methods of forming the same |
| DE102015212492A1 (en) | 2015-07-03 | 2017-01-05 | Bundesdruckerei Gmbh | Security or value document with a luminescent feature and method for checking the authenticity of the security or value document |
| DE102016010196A1 (en) | 2016-08-23 | 2018-03-01 | Giesecke+Devrient Currency Technology Gmbh | Security element, method of making the same and value document |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4756557A (en) * | 1984-12-21 | 1988-07-12 | G.A.O. Gesellschaft Fuer Automation Und Organisation Mbh | Security document having a security thread embedded therein and methods for producing and testing the authenticity of the security document |
| CN1412355A (en) * | 2002-10-25 | 2003-04-23 | 东华大学 | Double wave length fluorescent composite fibre, its production method and application |
| CN1763311A (en) * | 2004-10-22 | 2006-04-26 | 中国印钞造币总公司 | Composite anti-false fiber |
| CN100999881A (en) * | 2006-01-13 | 2007-07-18 | 中国印钞造币总公司 | Triple anti-forge material and triple anti-forge paper product thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE371948C (en) * | 1922-04-16 | 1923-03-19 | Hoechst Ag | Process for the production of yard-forming mottled fibers |
| DE4133977A1 (en) * | 1991-10-14 | 1993-04-15 | Cassella Ag | Dyeing of organic fibres with pigments useful as marking fibres in paper - by treating fibres with aq. cationic polymer soln. and then aq. pigment suspension |
| US5961152A (en) * | 1997-05-29 | 1999-10-05 | The Standard Register Company | Security paper having an embedded and deformed security thread and a process for making the security paper |
| DE19962790A1 (en) * | 1999-12-23 | 2001-06-28 | Giesecke & Devrient Gmbh | Security paper, for secure documents, comprises veining fibers with differing luminescent properties to discourage document forgery, and is coded according to their disposition |
| DE60101870T2 (en) * | 2000-07-11 | 2004-11-04 | Oji Paper Co., Ltd. | Counterfeit-proof recording paper and paper backing |
| US7122248B2 (en) * | 2001-02-21 | 2006-10-17 | Honeywell International Inc. | Security articles |
| DE10204870B4 (en) * | 2002-02-06 | 2018-11-15 | Infineon Technologies Ag | Method for securing counterfeiting of a value carrier, value carrier and method for checking its authenticity |
| DE10324630A1 (en) * | 2003-05-28 | 2004-12-23 | Giesecke & Devrient Gmbh | security paper |
| JP2010514950A (en) * | 2006-12-27 | 2010-05-06 | コリア ミンティング アンド セキュリティ プリンティング コープ | Functional fiber for anti-counterfeiting |
-
2009
- 2009-09-08 DE DE200910040747 patent/DE102009040747B3/en active Active
-
2010
- 2010-08-27 EP EP10754420.7A patent/EP2475811B1/en active Active
- 2010-08-27 CA CA2768601A patent/CA2768601C/en active Active
- 2010-08-27 WO PCT/EP2010/005332 patent/WO2011029543A2/en active Application Filing
- 2010-08-27 AU AU2010294594A patent/AU2010294594B2/en active Active
- 2010-08-27 CN CN201080035727.3A patent/CN102482802B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4756557A (en) * | 1984-12-21 | 1988-07-12 | G.A.O. Gesellschaft Fuer Automation Und Organisation Mbh | Security document having a security thread embedded therein and methods for producing and testing the authenticity of the security document |
| CN1412355A (en) * | 2002-10-25 | 2003-04-23 | 东华大学 | Double wave length fluorescent composite fibre, its production method and application |
| CN1763311A (en) * | 2004-10-22 | 2006-04-26 | 中国印钞造币总公司 | Composite anti-false fiber |
| CN100999881A (en) * | 2006-01-13 | 2007-07-18 | 中国印钞造币总公司 | Triple anti-forge material and triple anti-forge paper product thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2010294594B2 (en) | 2014-09-18 |
| WO2011029543A2 (en) | 2011-03-17 |
| WO2011029543A3 (en) | 2011-12-08 |
| CA2768601A1 (en) | 2011-03-17 |
| EP2475811A2 (en) | 2012-07-18 |
| CA2768601C (en) | 2016-10-25 |
| AU2010294594A1 (en) | 2012-03-01 |
| EP2475811B1 (en) | 2017-03-29 |
| CN102482802A (en) | 2012-05-30 |
| DE102009040747B3 (en) | 2011-07-21 |
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