CN102533207A - PVC/PA6 (polyvinyl chloride/polyamide 6) binder - Google Patents
PVC/PA6 (polyvinyl chloride/polyamide 6) binder Download PDFInfo
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- CN102533207A CN102533207A CN2011104575080A CN201110457508A CN102533207A CN 102533207 A CN102533207 A CN 102533207A CN 2011104575080 A CN2011104575080 A CN 2011104575080A CN 201110457508 A CN201110457508 A CN 201110457508A CN 102533207 A CN102533207 A CN 102533207A
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- pvc
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- nylon
- sticker
- binder
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Abstract
The invention relates to the technical field of a polymer material, in particular to a binder used for bonding a PVC (polyvinyl chloride) material and a PA6 (polyamide 6) material and bonding a nylon 6 and the PVC. The binder comprises raw materials of the following weight portions: 40-60 portions of nylon-6, 40-60 portions of acrylonitrile-butadiene-styrene copolymer, 5-10 portions of styrene-maleic anhydride copolymer and 1-5 portion(s) of SAN (styrene-acrylonitrile)-polybutadiene rubber base. Two insoluble raw materials, the nylon 6 and the PVC, can be blended, the binder has sufficient strength to replace a steel roller, and the effect of using plastics to replace steel can be achieved. Therefore, the invention has the advantages that energy can be saved, the cost can be reduced, and the roller has high strength, high wear resistance and long service life.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to a kind of sticker of be used to bond PVC material and PA6 material.
Background technology
PVC is that (Polyvinylchloride PVC), is a kind of polymeric material of vinyl to SE, and its material is a kind of amorphism material.The PVC material has noninflammability, HS and good geometrical stability, and oxygenant, reductive agent and strong acid are all had very strong resistibility.Therefore PVC has application widely, but the PVC material is changed by summer and winter temperature, is easy to generate phenomenons such as fragility.
Nylon (Nylon), the Chinese name polymeric amide, English name Polyamide (be called for short PA), be contain on the molecular backbone chain recurring amide radical group-[NHCO]-the thermoplastic resin general name.Its name is decided by the concrete carbonatoms of synthon, as: PA-6, PA-66, PA-1010, PA-610 etc.Wherein nylon 6 has superior over-all properties, comprises physical strength, rigidity, toughness, mechanical shock absorption property and wear resistance, and has good electrical isolation capabilities and chemical resistant properties.
Therefore can consider outside surface parcel one deck nylon, make both advantages, can't significantly improve material cost, but because nylon 6 is incompatible with PVC, the sticker that can both bondings not got up in the prior art at the PVC material.
Summary of the invention
The objective of the invention is to propose a kind of PVC/PA6 sticker, can nylon 6 be bonded together with PVC.
The objective of the invention is to realize like this, the PVC/PA6 sticker comprises the raw material of following weight part:
Nylon-6 40-60 part;
Acrylonitrile-BS 40-60 part;
Styrene maleic anhydride copolymer 5-10 part;
SAN-polybutadiene rubber base 1-5 part.
Further, said nylon-6 is made up of PA6-1030B and PA6-1013B.
Further, said acrylonitrile-BS is ABS-PD50S.
Further, said styrene maleic anhydride copolymer is SMA308.
Further, also comprise oxidation inhibitor 1-3 part.
Further, said oxidation inhibitor is 1010 oxidation inhibitor or 168 oxidation inhibitor.
Further, also comprise lubricant 1-3 part.
Further, said lubricant is the EBS lubricant.
Further, form by the raw material of following weight part:
45 parts of PA6-1030B;
5 parts of PA6-1013B;
50 parts of ABS-PD50S;
7 parts of SMA308;
3 parts in SAN-polybutadiene rubber base;
2 parts of 1010/168 inhibitors;
1.5 parts of EBS lubricants.
The present invention compared with prior art has following technological merit: the present invention can make two kinds of immiscible raw material nylon 6 and PVC fused together, and its intensity can have been accomplished to mould the effect of Dai Gang for steel rider.So both saved the energy, reduced cost, and can make carrying roller have advantages such as HS property, high-wearing feature, long service life again.
Specific embodiments:
The PVC/PA6 sticker comprises the raw material of following weight part:
Nylon-6 40-60 part;
Acrylonitrile-BS 40-60 part;
Styrene maleic anhydride copolymer 5-10 part;
SAN-polyhutadiene matrix or ABS3011-5 part;
Oxidation inhibitor 1-3 part;
Lubricant 1-3 part.
Said nylon-6 can be selected PA6-1030B, PA6-1013B, PA6-1040, PA66-7024B, PA66PA-101, PA6-1011FB etc. for use ...
Said acrylonitrile-BS, i.e. ABS, optional model be ABS-PD50S,
ABS PA-747S, ABS PA-709, ABS GPX2800 etc..
Said styrene maleic anhydride copolymer is selected SMA308, SMA700 etc. for use ...
Said oxidation inhibitor is selected 1010 oxidation inhibitor or 168 oxidation inhibitor, 1076 inhibitors for use.
Said lubricant selects for use the EBS lubricant like EBS-P130, EBS-P200, EBS-P400.
Embodiment 1
40 parts of PA6-1030B;
45 parts of ABS-PD50S;
SMA3085 part;
4 parts in SAN-polybutadiene rubber base;
2.5 parts in 168 oxidation inhibitor;
1 part of lubricant.
Embodiment 2
45 parts of PA6-1030B; 5 parts of PA6-1013B;
50 parts of ABS-PD50S;
SMA3087 part;
3 parts in SAN-polybutadiene rubber base;
2 parts of 1010/168 inhibitors;
1.5 parts of EBS lubricants.
Embodiment 3
50 parts of PA6-1030B;
10 parts of PA6-1013B;
60 parts of ABS-PD50S;
SMA3088 part;
5 parts in SAN-polybutadiene rubber base;
1 part of 1010 inhibitor;
2 parts of EBS lubricants.
Embodiment 4
48 parts of PA6-1030B;
8 parts of PA6-1013B;
40 parts of ABS-PD50S;
SMA3085 part;
3011 parts of ABS;
3 parts of EBS lubricants.
Embodiment 5
46 parts of PA6-1030B;
4 parts of PA6-1013B;
55 parts of ABS-PD50S;
SMA30810 part;
4 parts in SAN-polybutadiene rubber base;
1 part of 168 inhibitor.
The performance formula test result
Claims (9)
1.PVC/PA6 sticker is characterized in that: the raw material that comprises following weight part:
Nylon-6 40-60 part;
Acrylonitrile-BS 40-60 part;
Styrene maleic anhydride copolymer 5-10 part;
SAN-polybutadiene rubber base or ABS301 1-5 part.
2. PVC/PA6 sticker according to claim 1 is characterized in that: said nylon-6 is made up of PA6-1030B and PA6-1013B.
3. according to the PVC/PA6 sticker described in the claim 2, it is characterized in that: said acrylonitrile-BS is ABS-PD50S.
4. PVC/PA6 sticker according to claim 3 is characterized in that: said styrene maleic anhydride copolymer is SMA308.
5. PVC/PA6 sticker according to claim 4 is characterized in that: also comprise oxidation inhibitor 1-3 part.
6. PVC/PA6 sticker according to claim 5 is characterized in that: said oxidation inhibitor is 1010 oxidation inhibitor or 168 oxidation inhibitor.
7. PVC/PA6 sticker according to claim 6 is characterized in that: also comprise lubricant 1-3 part.
8. PVC/PA6 sticker according to claim 7 is characterized in that: said lubricant is the EBS lubricant.
9. according to each described PVC/PA6 sticker among the claim 1-8, it is characterized in that: by as follows
The raw material of weight part is formed:
45 parts of PA6-1030B;
5 parts of PA6-1013B;
50 parts of ABS-PD50S;
SMA3087 part;
3 parts in SAN-polybutadiene rubber base;
2 parts of 1010/168 inhibitors;
1.5 parts of EBS lubricants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110457508.0A CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110457508.0A CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102533207A true CN102533207A (en) | 2012-07-04 |
| CN102533207B CN102533207B (en) | 2014-01-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110457508.0A Active CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102533207B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4157319A (en) * | 1974-11-29 | 1979-06-05 | The Goodyear Tire & Rubber Company | Adhesive composition and butadiene, styrene, acrylonitrile copolymer therefor |
| CN1854184A (en) * | 2005-04-29 | 2006-11-01 | 上海日之升新技术发展有限公司 | Nylon and ABS alloy material for improving impact and heat-resisting performances |
| CN101735604A (en) * | 2009-12-25 | 2010-06-16 | 杭州鸿雁电器有限公司 | Montmorillonoid modified Pa6/ABS alloy material and preparation method thereof |
-
2011
- 2011-12-31 CN CN201110457508.0A patent/CN102533207B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4157319A (en) * | 1974-11-29 | 1979-06-05 | The Goodyear Tire & Rubber Company | Adhesive composition and butadiene, styrene, acrylonitrile copolymer therefor |
| CN1854184A (en) * | 2005-04-29 | 2006-11-01 | 上海日之升新技术发展有限公司 | Nylon and ABS alloy material for improving impact and heat-resisting performances |
| CN101735604A (en) * | 2009-12-25 | 2010-06-16 | 杭州鸿雁电器有限公司 | Montmorillonoid modified Pa6/ABS alloy material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102533207B (en) | 2014-01-29 |
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