CN102533207B - PVC/PA6 (polyvinyl chloride/polyamide 6) binder - Google Patents
PVC/PA6 (polyvinyl chloride/polyamide 6) binder Download PDFInfo
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- CN102533207B CN102533207B CN201110457508.0A CN201110457508A CN102533207B CN 102533207 B CN102533207 B CN 102533207B CN 201110457508 A CN201110457508 A CN 201110457508A CN 102533207 B CN102533207 B CN 102533207B
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Abstract
The invention relates to the technical field of a polymer material, in particular to a binder used for bonding a PVC (polyvinyl chloride) material and a PA6 (polyamide 6) material and bonding a nylon 6 and the PVC. The binder comprises raw materials of the following weight portions: 40-60 portions of nylon-6, 40-60 portions of acrylonitrile-butadiene-styrene copolymer, 5-10 portions of styrene-maleic anhydride copolymer and 1-5 portion(s) of SAN (styrene-acrylonitrile)-polybutadiene rubber base. Two insoluble raw materials, the nylon 6 and the PVC, can be blended, the binder has sufficient strength to replace a steel roller, and the effect of using plastics to replace steel can be achieved. Therefore, the invention has the advantages that energy can be saved, the cost can be reduced, and the roller has high strength, high wear resistance and long service life.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to a kind of binding agent for bond PVC material and PA6 material.
Background technology
PVC is polyvinyl chloride (Poly vinyl chloride, PVC), is a kind of polymeric material of vinyl, and its material is a kind of amorphism material.PVC material has noninflammability, high strength and good geometrical stability, and oxygenant, reductive agent and strong acid are had to very strong resistibility.Therefore PVC has a wide range of applications, but PVC material is changed by summer and winter temperature, easily produces the phenomenons such as fragile.
Nylon (Nylon), Chinese name polymeric amide, English name Polyamide (be called for short PA), be on molecular backbone chain, contain recurring amide radical group-[NHCO]-thermoplastic resin general name.Its name is determined by the concrete carbonatoms of synthon, as: PA-6, PA-66, PA-1010, PA-610 etc.Wherein nylon 6 has superior over-all properties, comprises physical strength, rigidity, toughness, mechanical shock absorption and wear resistance, and has good electrical isolation capabilities and chemical resistant properties.
Therefore can consider the outside surface parcel one deck nylon at PVC material, make both advantages, can't significantly improve material cost, but because nylon 6 is incompatible with PVC, the binding agent that both bondings can not got up in prior art.
Summary of the invention
The object of the invention is to propose a kind of PVC/PA6 binding agent, nylon 6 can be bonded together with PVC.
The object of the present invention is achieved like this, and PVC/PA6 binding agent comprises the raw material of following weight part:
Nylon-6 40-60 part;
Acrylonitrile-butadiene-styrene copolymer 40-60 part;
Styrene maleic anhydride copolymer 5-10 part;
SAN-polybutadiene rubber base 1-5 part.
Further, described nylon-6 is comprised of PA6-1030B and PA6-1013B.
Further, described acrylonitrile-butadiene-styrene copolymer is ABS-PD50S.
Further, described styrene maleic anhydride copolymer is SMA308.
Further, also comprise oxidation inhibitor 1-3 part.
Further, described oxidation inhibitor is 1010 oxidation inhibitor or 168 oxidation inhibitor.
Further, also comprise lubricant 1-3 part.
Further, described lubricant is EBS lubricant.
Further, the raw material by following weight part forms:
45 parts of PA6-1030B;
5 parts of PA6-1013B;
50 parts of ABS-PD50S;
7 parts of SMA308;
3 parts, SAN-polybutadiene rubber base;
1010/168 2 parts of antioxidants;
1.5 parts of EBS lubricants.
The present invention compared with prior art, has following technological merit: the present invention can make two kinds of immiscible raw material nylon 6 and PVC indissoluble, and its intensity can, for steel rider, accomplish to mould the effect of Dai Gang.So both saved the energy, reduced costs, and can make again carrying roller there is the advantages such as high strength, high-wearing feature, long service life.
Specific embodiments:
PVC/PA6 binding agent, comprises the raw material of following weight part:
Nylon-6 40-60 part;
Acrylonitrile-butadiene-styrene copolymer 40-60 part;
Styrene maleic anhydride copolymer 5-10 part;
SAN-polyhutadiene matrix or ABS301 1-5 part;
Oxidation inhibitor 1-3 part;
Lubricant 1-3 part.
Described nylon-6 can be selected PA6-1030B, PA6-1013B, PA6-1040, PA66-7024B, PA66PA-101, PA6-1011FB etc..
Described acrylonitrile-butadiene-styrene copolymer, i.e. ABS, optional model is ABS-PD50S, ABS PA-747S, ABSPA-709, ABS GPX2800 etc..
Described styrene maleic anhydride copolymer is selected SMA308, SMA700 etc..
Described oxidation inhibitor is selected 1010 oxidation inhibitor or 168 oxidation inhibitor, 1076 antioxidants.
Described lubricant selects EBS lubricant as EBS-P130, EBS-P200, EBS-P400.
Embodiment 1
40 parts of PA6-1030B;
45 parts of ABS-PD50S;
5 parts of SMA308;
4 parts, SAN-polybutadiene rubber base;
168 2.5 parts, oxidation inhibitor;
1 part of lubricant.
Embodiment 2
45 parts of PA6-1030B; 5 parts of PA6-1013B;
50 parts of ABS-PD50S;
7 parts of SMA308;
3 parts, SAN-polybutadiene rubber base;
1010/168 2 parts of antioxidants;
1.5 parts of EBS lubricants.
Embodiment 3
50 parts of PA6-1030B;
10 parts of PA6-1013B;
60 parts of ABS-PD50S;
8 parts of SMA308;
5 parts, SAN-polybutadiene rubber base;
1010 1 part of antioxidant;
2 parts of EBS lubricants.
Embodiment 4
48 parts of PA6-1030B;
8 parts of PA6-1013B;
40 parts of ABS-PD50S;
5 parts of SMA308;
1 part of ABS301;
3 parts of EBS lubricants.
Embodiment 5
46 parts of PA6-1030B;
4 parts of PA6-1013B;
55 parts of ABS-PD50S;
10 parts of SMA308;
4 parts, SAN-polybutadiene rubber base;
168 1 part of antioxidant.
Performance formula test result
Claims (1)
1.PVC/PA6 binding agent, is characterized in that: the raw material by following weight part forms:
48 parts of PA6-1030B;
8 parts of PA6-1013B;
40 parts of ABS-PD50S;
5 parts of SMA308;
1 part of ABS301;
3 parts of EBS lubricants.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110457508.0A CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110457508.0A CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102533207A CN102533207A (en) | 2012-07-04 |
| CN102533207B true CN102533207B (en) | 2014-01-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110457508.0A Active CN102533207B (en) | 2011-12-31 | 2011-12-31 | PVC/PA6 (polyvinyl chloride/polyamide 6) binder |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102533207B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4157319A (en) * | 1974-11-29 | 1979-06-05 | The Goodyear Tire & Rubber Company | Adhesive composition and butadiene, styrene, acrylonitrile copolymer therefor |
| CN1854184A (en) * | 2005-04-29 | 2006-11-01 | 上海日之升新技术发展有限公司 | Nylon and ABS alloy material for improving impact and heat-resisting performances |
| CN101735604A (en) * | 2009-12-25 | 2010-06-16 | 杭州鸿雁电器有限公司 | Montmorillonoid modified Pa6/ABS alloy material and preparation method thereof |
-
2011
- 2011-12-31 CN CN201110457508.0A patent/CN102533207B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4157319A (en) * | 1974-11-29 | 1979-06-05 | The Goodyear Tire & Rubber Company | Adhesive composition and butadiene, styrene, acrylonitrile copolymer therefor |
| CN1854184A (en) * | 2005-04-29 | 2006-11-01 | 上海日之升新技术发展有限公司 | Nylon and ABS alloy material for improving impact and heat-resisting performances |
| CN101735604A (en) * | 2009-12-25 | 2010-06-16 | 杭州鸿雁电器有限公司 | Montmorillonoid modified Pa6/ABS alloy material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102533207A (en) | 2012-07-04 |
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