CN103253021A - Digital printing and dyeing paper used for cotton fabrics, and preparation method thereof - Google Patents
Digital printing and dyeing paper used for cotton fabrics, and preparation method thereof Download PDFInfo
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- CN103253021A CN103253021A CN201210035846XA CN201210035846A CN103253021A CN 103253021 A CN103253021 A CN 103253021A CN 201210035846X A CN201210035846X A CN 201210035846XA CN 201210035846 A CN201210035846 A CN 201210035846A CN 103253021 A CN103253021 A CN 103253021A
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Abstract
The invention discloses a digital printing and dyeing paper used for cotton fabrics. The digital printing and dyeing paper comprises a substrate and a functional material coat covered on the substrate; the functional material coat comprises a printing system, a catalytic system and an auxiliary system; the printing system comprises one or more selected from water-soluble polymers and amphiphilic polymers; the catalytic system comprises one or more selected from amide compounds, amine compounds, water-soluble metal hydroxides, weak acid salts of alkali metals, and weak acid salts of alkaline earth metals; and the auxiliary system comprises a coating agent, an antifoaming agent, an adsorbent and an antiseptic. There is no need to preprocess the fabrics when the digital printing and dyeing paper is used to chemically print and dye various cotton fabrics, so the technological cost is substantially saved; and printed and dyed products obtained through using the digital printing and dyeing paper have the advantages of brilliant color, excellent color fastness, good permeability and comfortableness, maintenance of the original application performances of the cotton fabrics, and substantial effect.
Description
Technical field
The present invention relates to a kind ofly be used to containing number printing and dyeing paper of cotton face fabric and preparation method thereof, carry out number and print and dye containing cotton face fabric, belong to field of printing and dyeing.
Background technology
The green dyeing and printing process of energy-conserving and environment-protective is just obtaining country or local government supports to promote energetically, progressively to replace traditional dyeing and finishing technology.The digital dyeing and printing process that occurs at present can be divided into following two kinds by principle: the physics method of printing and dyeing by physical bond effect combination of (1) pigment molecular and fabric (as patent: 201010119584.6,201010109026.1), (2) pigment molecular and fabric with the chemical method of printing and dyeing of chemical bond combination (as patent: 200710040431.0,200810201472.8).For the physics method of printing and dyeing, adopt the directly spray on fabric of coating ink or paint ink usually, finish fixation by simple heat cure again.This method is quite environmental protection on technology, but often color fastness is not enough, even color fastness is up to standard, continuation be full of cracks and the phenomenon of fading are also arranged, its reason is that the pigment of each friction back physical bond all can break away from fabric on a small quantity, this continue to fade make pigment and human body have long-time chronic the contact, have potential safety hazard.The process using transfer printing is also arranged, namely coat one deck PUR on printing and dyeing paper surface, during use the related hot melt adhesive layer of pattern scalded together and be bonded on the fabric, yet its finished product fabric is because existing one deck colloid feel not good, its gas permeability and comfortableness are all relatively poor, these problems have all caused its application performance to descend, therefore can not be by widespread usage.
At present, the traditional dyeing and finishing technology that the overwhelming majority contains cotton face fabric is to use the chemical method of printing and dyeing of active mill base, therefore, and may be more near practical application at the new digital dyeing and printing process that this maturation process derives.The made finished product of the chemistry method of printing and dyeing, after its loose colour was removed, the residue pigment molecular linked to each other with chemical bond with the face liber molecule, and common washing and friction all are difficult to destroy and have than high color fastness and continuation color fastness.The digital chemical method of printing and dyeing also has two kinds of straight spray and transfer printings, can make the finished product with higher dyeing quality, especially cold transfer technique, and its finished product lovely luster, color fastness is high and do not influence the original character of fabric.
Yet, the chemical printing technology of existing number all needs fabric is carried out pre-treatment (as patent: 200710037612.8), pre-treatment not only makes the technology cost increase, also cause a series of problems, be difficult to as technological factor that control, product dyeing quality stability significantly reduce, product includes the slurries material and is difficult to problems such as removal, face liber sex change, thereby influences the large-scale popularization of new technology.
Summary of the invention
The object of the invention provides a kind of be used to containing number printing and dyeing paper of cotton face fabric and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is: a kind of be used to the number printing and dyeing paper that contains cotton face fabric, and comprise base material and cover functional material coating on base material; Described functional material coating comprises prints suitable gonosome system, catalyst system and catalyzing and assistant system; The suitable gonosome of described printing system is selected from one or more in water soluble polymer and the amphipathy macromolecule; Described catalyst system and catalyzing is selected from the salt of weak acid compounds of amides compound, aminated compounds, water-soluble metal hydroxide, alkali-metal salt of weak acid compounds, alkaline-earth metal one or more; Described assistant system comprises coating agent, defoamer, adsorbent, antiseptic.
Described base material can be paper or film.The described cotton face fabric that contains can comprise and contains cotton ready-made clothes, garment piece and grey cloth etc.
In the technique scheme, the suitable gonosome of described printing system is selected from one or more in water-soluble poly alkene alcohol family macromolecule, water-soluble poly olefin acid salt family macromolecule, water-soluble poly alkene amide-type macromolecule, water soluble polyether family macromolecule, water-soluble cellulose family macromolecule, water soluble starch family macromolecule and the copolymer thereof; Described catalyst system and catalyzing is selected from niacinamide, triethanolamine, triethylamine, N, one or more in N-dimethyl amine, potash, the sodium carbonate; Coating agent in the described assistant system is selected from one or more in polyamide, polyurethane, the polyethylene; Defoamer in the described assistant system is selected from one or more in polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene glycerol ether, the ethoxylation dimethyl siloxane; Adsorbent in the described assistant system is selected from one or more in silica, calcium carbonate, sodium silicoaluminate, the titanium dioxide; Antiseptic in the described assistant system is selected from one or more in potassium sorbate, Sodium Benzoate, the imidazolone.
Preferably, described water-soluble poly alkene alcohol family macromolecule is selected from polyvinyl alcohol, POLYPROPYLENE GLYCOL or PHEMA; Described water-soluble poly olefin acid salt family macromolecule is selected from Sodium Polyacrylate, sodium polymethacrylate or poly sodium; Described water-soluble poly alkene amide-type macromolecule is polyacrylamide; Described water soluble polyether family macromolecule is selected from PEO or PPOX; Described water-soluble cellulose family macromolecule is selected from sodium carboxymethylcellulose, hydroxyethylcellulose or hydroxypropyl methylcellulose; Described water soluble starch family macromolecule is selected from starch or sodium carboxymethyl starch.
In the technique scheme, by weight, the ratio between described printing suitable gonosome system, catalyst system and catalyzing and the assistant system is 50～70: 1～10: 0～20.
In the technique scheme, described functional material coating covers the one side in base material.Be that base material has first surface and second surface, described functional material coating is covered in first surface or the second surface of described base material, perhaps is covered in first surface and the second surface of described base material simultaneously.
In the technique scheme, it is single coating structure or laminated coating structure that gonosome system, catalyst system and catalyzing and assistant system are fitted in the printing in the described functional material coating.
The present invention asks for protection a kind of preparation method be used to the number printing and dyeing paper that contains cotton face fabric simultaneously, comprises the steps: that (1) provides base material; (2) be coated with functional material at base material, form the functional material coating that covers on base material.
The present invention asks for protection a kind of using method be used to the number printing and dyeing paper that contains cotton face fabric simultaneously, comprises the steps: that (1) utilizes ink-jet printer that pattern is printed on the functional material coating in the mirror image mode, forms printed layers; (2) described printed layers is placed in the face of containing cotton face fabric, carry out hot pressing to containing cotton face fabric, make digital printing and dyeing paper and contain cotton face fabric bonding; (3) with bonding number printing and dyeing paper with contain cotton face fabric and carry out fixation, the paper of perhaps number being printed and dyed is peeled off the back fabric is carried out fixation from containing cotton face fabric; Can finish the transfer printing printing and dyeing.
In the technique scheme, described ink-jet printer ink be selected from reactive dye ink, acid dye ink, paint ink, the coating ink one or more.
In the technique scheme, the color-fixing method in the described step (3) is selected from the vapour steaming colour fixing method, leave standstill in fixation method and the thermosetting color method one or more.Wherein, vapour steaming colour fixing method step is: will be placed steam box to carry out decatize by the cotton face fabric that contains that number is printed and dyed after the paper hot pressing, and finish fixation.Leaving standstill fixation method step is: will be undertaken moisteningly by the number bonding cotton face fabric that contains of paper of printing and dyeing, and and leave standstill under moisture state, and finish fixation.Thermosetting color method step is: the cotton face fabric that contains of printed pattern is heated with baking oven, hot plate or hot-rolling, finish fixation.
Because technique scheme is used, the present invention compared with prior art has following advantage:
1, the present invention's design has obtained a kind of be used to the number printing and dyeing paper that contains cotton face fabric, use this number printing and dyeing paper that the various cotton face fabrics that contain are carried out chemistry when printing and dyeing, fabric does not need to carry out pre-treatment, thereby saved the technology cost greatly, simultaneously have bright-coloured color and luster, good color fastness, gas permeability and comfortableness preferably by its dyeing and printing products that makes, and can keep containing the original application performance of cotton face fabric, obtain significant effect.
2, the present invention designs and has used a kind of new reactive dye catalysis technique, namely uses the coating agent that catalyst is wrapped up or embedding, reaches controlled temperature sensitive release and the effect of slowly-releasing, improves the even dyeing degree; And under color fixing condition, the coating agent itself has certain cementitiousness, fabric is fully contacted with pigment molecular and improves reactivity.
3, digital printing and dyeing paper of the present invention goes for containing cotton ready-made clothes, garment piece, grey cloth etc., has the wider scope of application.
4, preparation method of the present invention and using method step are clearly demarcated, and process adjustments leeway is big, have saved cost to a great extent, are suitable for promoting the use of.
The specific embodiment
Be further described below in conjunction with the present invention of embodiment:
Embodiment one
A kind of be used to the number printing and dyeing paper that contains cotton face fabric, comprise base material and cover functional material coating on base material; Its preparation method is as follows:
(1) provides paper or film base material;
(2) be coated with functional material at described base material, form the functional material coating that is covered on this base material.
Specific as follows: configuration feature material water-based glue, contain 12% PAA and acrylamide copolymer, 2% sodium carboxymethylcellulose, 1% potash, 2% niacinamide, 2% polyethylene, 0.3% silica in this water-based system; At 100g/m
2Basic paper on coating one deck functional material, namely make the described digital printing and dyeing of the cotton face fabric paper that contains of present embodiment after the drying.
The using method of above-mentioned digital printing and dyeing paper is: loading dye ink in ink-jet printer is printed on multicolour pattern on the described functional material layer that contains the digital printing and dyeing of cotton face fabric paper of present embodiment in the mirror image mode; Then printed layers is faced textile garment piece, with temperature and the 10kg/cm of flat-bed press at 140 ℃
2Pressure under hot pressing 20 seconds; To be placed steam box by printing and dyeing paper bonding cotton garment piece again, 105 ℃ of following decatizes 15 minutes, the paper of will print and dye was then peeled off from textile garment piece, finishes to shift and prints and dyes.
Embodiment two
A kind of be used to the number printing and dyeing paper that contains cotton face fabric, comprise base material and cover functional material coating on base material; Its preparation method is as follows:
Configuration feature material water-based glue contains 12% PAA and acrylamide copolymer, 2% sodium carboxymethylcellulose, 1% potash, 2% niacinamide, 2% polyethylene, 0.3% silica in this water-based system; At 100g/m
2Basic paper on coating one deck functional material, namely make the described digital printing and dyeing of the cotton face fabric paper that contains of present embodiment after the drying.
The using method of above-mentioned digital printing and dyeing paper is: loading dye ink in ink-jet printer is printed on multicolour pattern on the described functional material layer that contains the digital printing and dyeing of cotton face fabric paper of present embodiment in the mirror image mode; Two printed printing and dyeing paper is placed on the upper and lower sides of textile ready-made clothes respectively then, makes printed layers face textile ready-made clothes, with temperature and the 10kg/cm of flat-bed press at 140 ℃
2Pressure under hot pressing 30 seconds; Again positive and negative is placed steam box by the bonding cotton garment piece of the paper of printing and dyeing, 105 ℃ of following decatizes 15 minutes, the paper of will printing and dyeing was then peeled off from textile ready-made clothes, finished and shifted printing and dyeing.The positive and negative of products obtained therefrom is all arrived pattern by printing and dyeing.
Embodiment three
A kind of be used to the number printing and dyeing paper that contains cotton face fabric, comprise base material and cover functional material coating on base material; Its preparation method is as follows:
Configuration feature material water-based glue contains 12% PAA and acrylamide copolymer, 2% sodium carboxymethylcellulose, 1% potash, 2% niacinamide, 2% polyethylene, 0.3% silica in this water-based system; At 100g/m
2Basic paper on coating one deck functional material, namely make the described digital printing and dyeing of the cotton face fabric paper that contains of present embodiment after the drying.
The using method of above-mentioned digital printing and dyeing paper is: loading dye ink in ink-jet printer is printed on multicolour pattern on the described functional material layer that contains the digital printing and dyeing of cotton face fabric paper of present embodiment in the mirror image mode; Then printed layers is faced pure cotton grey fabric, with temperature and the 15kg/cm of cylinder hot press at 140 ℃
2Linear pressure under grey cloth is carried out heat pressure adhesive; To be placed steam box by printing and dyeing paper bonding cotton grey cloth again, 105 ℃ of following decatizes 15 minutes, the paper of will print and dye was then peeled off from pure cotton grey fabric, finishes to shift and prints and dyes.
Embodiment four
A kind of be used to the number printing and dyeing paper that contains cotton face fabric, comprise base material and cover functional material coating on base material; Its preparation method is as follows:
Configuration feature material aqueous suspension contains 8% polyvinylpyrrolidone, 2% sodium carboxymethylcellulose, 1% potash, 1% triethanolamine, 3% polyethylene, 0.3% calcium carbonate, 0.1% Sodium Benzoate in this water-based system; At 90g/m
2Basic paper on coating one deck functional material, namely make the described digital printing and dyeing of the cotton face fabric paper that contains of present embodiment after the drying.
The using method of above-mentioned digital printing and dyeing paper is: loading dye ink in ink-jet printer, multicolour pattern is printed on the described functional material layer that contains the digital printing and dyeing of cotton face fabric paper of present embodiment in the mirror image mode, then printed layers is faced the cotton-polyester blend cloth, with temperature and the 10kg/cm of flat-bed press at 130 ℃
2Pressure under hot pressing 20 seconds; To be placed steam box by printing and dyeing paper bonding cotton-polyester blend cloth again, 105 ℃ of following decatizes 15 minutes, the paper of will print and dye was then peeled off from the cotton-polyester blend cloth, finishes to shift and prints and dyes.
The above only is preferred embodiment of the present invention, and in order to limit the present invention, all any modification, replacement and improvement of doing within claim of the present invention etc. all should not be included in protection scope of the present invention.
Claims (10)
1. number printing and dyeing paper that is used for containing cotton face fabric is characterized in that: comprise base material and cover functional material coating on base material; Described functional material coating comprises prints suitable gonosome system, catalyst system and catalyzing and assistant system; The suitable gonosome of described printing system is selected from one or more in water soluble polymer and the amphipathy macromolecule; Described catalyst system and catalyzing is selected from the salt of weak acid compounds of amides compound, aminated compounds, water-soluble metal hydroxide, alkali-metal salt of weak acid compounds, alkaline-earth metal one or more; Described assistant system comprises coating agent, defoamer, adsorbent, antiseptic.
2. according to claim 1 be used to the number printing and dyeing paper that contains cotton face fabric, it is characterized in that: the suitable gonosome of described printing system is selected from one or more in water-soluble poly alkene alcohol family macromolecule, water-soluble poly olefin acid salt family macromolecule, water-soluble poly alkene amide-type macromolecule, water soluble polyether family macromolecule, water-soluble cellulose family macromolecule, water soluble starch family macromolecule and the copolymer thereof; Described catalyst system and catalyzing is selected from niacinamide, triethanolamine, triethylamine, N, one or more in N-dimethyl amine, potash, the sodium carbonate; Coating agent in the described assistant system is selected from one or more in polyamide, polyurethane, the polyethylene; Defoamer in the described assistant system is selected from one or more in polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene glycerol ether, the ethoxylation dimethyl siloxane; Adsorbent in the described assistant system is selected from one or more in silica, calcium carbonate, sodium silicoaluminate, the titanium dioxide; Antiseptic in the described assistant system is selected from one or more in potassium sorbate, Sodium Benzoate, the imidazolone.
3. according to claim 2 be used to the number printing and dyeing paper that contains cotton face fabric, it is characterized in that: described water-soluble poly alkene alcohol family macromolecule is selected from polyvinyl alcohol, POLYPROPYLENE GLYCOL or PHEMA; Described water-soluble poly olefin acid salt family macromolecule is selected from Sodium Polyacrylate, sodium polymethacrylate or poly sodium; Described water-soluble poly alkene amide-type macromolecule is polyacrylamide; Described water soluble polyether family macromolecule is selected from PEO or PPOX; Described water-soluble cellulose family macromolecule is selected from sodium carboxymethylcellulose, hydroxyethylcellulose or hydroxypropyl methylcellulose; Described water soluble starch family macromolecule is selected from starch or sodium carboxymethyl starch.
4. according to claim 1 be used to the number printing and dyeing paper that contains cotton face fabric, it is characterized in that: by weight, the ratio between described printing suitable gonosome system, catalyst system and catalyzing and the assistant system is 50～70: 1～10: 0～20.
5. according to claim 1 be used to the number printing and dyeing paper that contains cotton face fabric, it is characterized in that: described functional material coating covers the one side in base material.
6. according to claim 1 be used to the number printing and dyeing paper that contains cotton face fabric, it is characterized in that: it is single coating structure or laminated coating structure that gonosome system, catalyst system and catalyzing and assistant system are fitted in the printing in the described functional material coating.
7. the preparation method be used to the number printing and dyeing paper that contains cotton face fabric as claimed in claim 1 is characterized in that, comprises the steps: that (1) provides base material; (2) be coated with functional material at base material, form the functional material coating that covers on base material.
8. the using method be used to the number printing and dyeing paper that contains cotton face fabric as claimed in claim 1 is characterized in that, comprises the steps: that (1) utilizes ink-jet printer that pattern is printed on the functional material coating in the mirror image mode, forms printed layers; (2) described printed layers is placed in the face of containing cotton face fabric, carry out hot pressing to containing cotton face fabric, make digital printing and dyeing paper and contain cotton face fabric bonding; (3) with bonding number printing and dyeing paper with contain cotton face fabric and carry out fixation, the paper of perhaps number being printed and dyed is peeled off the back fabric is carried out fixation from containing cotton face fabric; Can finish the transfer printing printing and dyeing.
9. using method according to claim 8, it is characterized in that: the ink of described ink-jet printer is selected from one or more in reactive dye ink, acid dye ink, paint ink, the coating ink.
10. using method according to claim 8 is characterized in that: the color-fixing method in the described step (3) is selected from the vapour steaming colour fixing method, leave standstill in fixation method and the thermosetting color method one or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210035846XA CN103253021A (en) | 2012-02-17 | 2012-02-17 | Digital printing and dyeing paper used for cotton fabrics, and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210035846XA CN103253021A (en) | 2012-02-17 | 2012-02-17 | Digital printing and dyeing paper used for cotton fabrics, and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103253021A true CN103253021A (en) | 2013-08-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210035846XA Pending CN103253021A (en) | 2012-02-17 | 2012-02-17 | Digital printing and dyeing paper used for cotton fabrics, and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110886134A (en) * | 2018-09-10 | 2020-03-17 | 安徽江南春包装科技有限公司 | Functional sublimation transfer printing paper and preparation method and application thereof |
| CN113152127A (en) * | 2021-04-20 | 2021-07-23 | 刘静 | Coating slurry for wet digital printing film and preparation method and application thereof |
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| JPH05179577A (en) * | 1991-12-27 | 1993-07-20 | Sanyo Chem Ind Ltd | Fabric for ink-jet dyeing and method for dyeing |
| CN1135973A (en) * | 1996-03-08 | 1996-11-20 | 单昶 | Method and apparatus for printing on leathers |
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Patent Citations (6)
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| US3940246A (en) * | 1971-04-26 | 1976-02-24 | Ciba-Geigy Ag | Sublimation transfer and isocyanate fixation of amino- or hydroxy-containing dyestuffs and transfer sheets therefor |
| JPH05179577A (en) * | 1991-12-27 | 1993-07-20 | Sanyo Chem Ind Ltd | Fabric for ink-jet dyeing and method for dyeing |
| CN1135973A (en) * | 1996-03-08 | 1996-11-20 | 单昶 | Method and apparatus for printing on leathers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113152127A (en) * | 2021-04-20 | 2021-07-23 | 刘静 | Coating slurry for wet digital printing film and preparation method and application thereof |
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Application publication date: 20130821 |