CN103443342B - Multi-layer gasket for heat-insulated and sound insulation molding - Google Patents

Multi-layer gasket for heat-insulated and sound insulation molding Download PDF

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Publication number
CN103443342B
CN103443342B CN201280014690.5A CN201280014690A CN103443342B CN 103443342 B CN103443342 B CN 103443342B CN 201280014690 A CN201280014690 A CN 201280014690A CN 103443342 B CN103443342 B CN 103443342B
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China
Prior art keywords
layer
gasket according
polyamide
heat
fiber
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CN201280014690.5A
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Chinese (zh)
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CN103443342A (en
Inventor
托马斯·布尔金
皮埃尔·达尼罗
菲利普·戈达诺
斯蒂芬·柯尼希鲍尔
文策尔·克劳泽
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Autoneum Management AG
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Autoneum Management AG
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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/04—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam
    • B29C35/049—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam using steam or damp
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/026—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers and with one or more layers of pure plastics material, e.g. foam layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28—Shaping operations therefor
    • B29C70/40—Shaping or impregnating by compression not applied
    • B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/465—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating by melting a solid material, e.g. sheets, powders of fibres
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    • B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
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    • B29D99/0021—Producing wall or panel-like structures, e.g. for hulls, fuselages, or buildings provided with plain or filled structures, e.g. cores, placed between two or more plates or sheets, e.g. in a matrix
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    • B60R13/011—Liners for load platforms or load compartments for internal load compartments, e.g. car trunks
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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Abstract

A kind of multi-layer gasket for heat-insulated and sound insulation steam under pressure molding, first layer and at least one second layer including forming enhancement layer, the enhancement layer is made up of the blend fabric of the polyamide substrate material and reinforcing fibre of powder or fiber or sheet form, the second layer is selected from open cell foam layer, or heat-reflecting layer, or the second enhancement layer that the blend fabric of the polyamide substrate material and reinforcing fibre by powder or fiber or sheet form is made, wherein, due to steam under pressure molding, all layers are laminated, and all available blend fabric are cured to form porous enhancement layer.

Description

Multi-layer gasket for heat-insulated and sound insulation molding
Technical field
The present invention relates to a kind of multi-layer gasket for heat-insulated and sound insulation molding, particularly for the engine of motor vehicles Cabin, and multi-layer gasket are used as the use of automotive trim parts.
Background technology
Acoustics and heat pad applied to vehicle is well known in the art.In order to provide sound attenuating, this A little pads often rely on sound absorption and transmission loss, and sound absorption absorbs the ability of incident acoustic wave, and transmission loss is the incident sound of reflection The ability of ripple.These pads also rely on heat shielding performance, with prevent or reduce from various thermals source (engine, gearbox and Gas extraction system) heat transmission to vehicle passenger compartment.This pad is used for example as particularly for the engine compartment area of vehicle Hood, so as to decay closer to the sound of the engine of its sound source.
In the enging cabin including car and the motor vehicles of commercial car, the sound-insulating member of sound absorber form is more and more Ground is used to reduce the noise of engine.In general, these sound absorbers are designed to mechanograph, to reduce the outer of vehicle Portion's noise and interior noise.The mechanograph can be made up of fabric (such as cotton) or polyurethane foam, and generally have be up to about 160 DEG C heat endurance.
In some regions, such as discharge manifold, hot air reflow area or in engine environment, mechanograph can suffer from high heat Load.Therefore, these mechanographs are often partially or even wholly laminated with aluminium foil to be used as heat reflector, to protect bottom Non-woven.Generally, aluminium foil is sufficiently thick to be used as carrier layer so that the mechanical performance of part is self-supporting.Sound-absorbing material is protected Hold as discrete material and thickness carrys out the acoustic characteristic of optimization component as far as possible.Such as DE8700919 discloses such a aluminium lamination, It has the foam for being used to isolate purpose for being glued onto inner side.Other examples are the pines by being clamped between two metal foil layers Scattered fiber material cushion is made, and thus metal level has structure carrier characteristic.
In recent years, it instead of typical heat shielding decorative element with being combined heat liner part.These composite pads are general It is all formed as multilayer module.These components have been fabricated heat exposure layer and composite bed, and heat exposure layer has reflection and impermeable Function, composite bed has good thermal insulation, mechanically and structurally characteristic, and that also there are additional top layers to be used for is outer for component sometimes Table and anti-permeability performance.The pad of these types is made using injection moulding or compression forming.These compound heat pads It is impervious and weight structure member to have the disadvantage them.Although they have good hot property and structural behaviour, most Still acoustics and heat decay characteristic are lacked in the case of number.
Although existing many adhesives, adhesive fabric and bondable fibers are used for ensuring laminated piece by special exploitation for many years Each layer be fixed together, laminated pad and isolator have intrinsic risk in terms of layering and failure.It is this potential The severe working environment that risk is subjected to mainly due to pad and isolator.Pad and isolator are located near heating sources mostly And/or be designed to shield thermal source, the component thermal source of such as engine, gearbox and gas extraction system.As a result, pad and Isolator is often subjected to the temperature more than 180 DEG C, and bonding agent or adhesive are shown by force over time at such a temperature It is strong and quickly deteriorate.
In addition, the part for being directly adjacent to engine installation is likely due to vibrate and cause from the vibration that engine is transmitted Noise.The part of these vibrations is likely to form undesirable additional noise.It is related to the fatigue behaviour of pad on the other hand, shakes Dynamic frequency may have a negative impact to the bulk life time of pad.
Another disadvantage of the prior art is to obtain the high temperature needed for resulting composite.The heating-up temperature to be reached depends on In matrix polymer.Generally, to form compound, matrix and reinforcing fibre utilize such as hot-air, contact heating or infrared ray to add The dryness such as heat heating means are heated.In order to compensate the temperature loss for example from heater to device for molding, product generally quilt It is heated to above the actual fusing point or the active temperature higher than binder resin of matrix polymer.The heating higher than fusing point of polymer Accelerate degeneration.
Had the shortcomings that using direct contact heater it is other, product must be compressed with the whole thickness of product obtain Good heat transfer.Hot-air generally more than the melting temperature of binder polymer at a temperature of use, therefore polymer by To fire damage, and infrared heating is only applicable to thin material.Energy needed for internal material is heated in thicker material can be damaged Hinder the outer surface of polymer.The method is generally only used at most 4-5mm thickness.
Using direct contact heater including the use of perforate slab froth bed in multi-layer gasket, this can cause lather collapse, Particularly the top layer of slab foam, so that it is impervious for airborne sound wave, thus deteriorates the whole of the part Body absorbs sound.
Another has the disadvantage the melting temperature for being used as matrix fiber and most of thermoplastic polymers as reinforcing fibre It is closer to each other, for example, using the polyethylene terephthalate that differential scanning calorimeter (DSC) is measured according to ISO11357-3 (PET) melting temperature be 230-260 DEG C, polyacrylic melting temperature between 140-170 DEG C, polyamide -6 (PA6.6) Melting temperature between 170-225 DEG C, and polyamide -6.6 melting temperature between 220-260 DEG C.Matrix fiber and plus Strong fiber uses thermoplastic polymer, such as PA6.6 as matrix PET as reinforcing fibre, it is necessary to which they are heated to More than the melting temperature of matrix fiber, this also results in reinforcing fibre and starts to melt or soften.This will cause structure breaking, shape Into compound closely.
Felt is widely used due to its heat-insulated and sound insulation property, particularly in automobile industry.Current trend is court To recyclable material, therefore in the past few years, thermoplastic adhesives have already taken up significant share.By such as polyester, gather The fiber that the high performance polymer such as acid amides is made is due to its mechanical performance and heat resistance rather than is subjected to concern.But it is necessary viscous Mixture constitutes their application limitations in molding 3D parts.
The fusing point of adhesive used so far is always less than the fusing point of reinforcing fibre so that the fabric of molding is shown Relatively weak performance, and limit its use in vehicle refined zone.The molded fiber fabric of these types is all uncomfortable For the high temperature exposure in enging cabin or compartment, particularly engine contact zone.Some in these adhesives are modified poly- Compound (), it has cast characteristic, because its improved structure is special to hydrolysis phenomena with copolyesters (CO-PET) as an example It is sensitive.
The technique of this felt of molding as known in the art is " cold " molding process or " heat " molding process, " cold " molding Felt is preheated by various means in technique, is then transferred into cold mould, and is compressed to obtain part shape wherein Felt is introduced in the mould of closing in shape, " heat " molding process, and heat transfer medium (such as air), which is introduced into, wherein makes bonding Agent reaches its fusing point, then discharges.Then, part is in tool interior or outside aids in cooling down (example using or without using cooling Such as referring to EP1656243A, EP1414440A and EP590112A).Only after the setting temperature of material is fully cooled to, Part can be removed from the molds and transported.
Disclosed fibre composites are generally used with reference to extra play, reflecting layer as discussed, or use foam.Can With by foam direct back foaming (back foaming) (foam-injection or foaming) by foam applications to this In fibre composites.However, generally foam is produced as slab foam and is cut into required thickness first.For adjacent fibre layer Foam stepped construction typically using hot-forming.The layer of stacking is placed between two hot plates with fusing material and obtained Multiple layers of stacking.Compression needs to be used for helping to transfer heat to the porous reinforcer of stratified material.Especially use foam One of this method of layer on open-celled structure the disadvantage is that, lather collapse and form top layer.This top layer deterioration perforate bubble The overall sound absorbing capabilities of foam.
The content of the invention
Therefore, it is an object of the invention to provide a kind of multilayer for the molding being particularly useful in the enging cabin of motor vehicles Pad, it has comparable heat-insulated and sound insulation property, but weight is lighter and is exposed to for a long time under thermic load in using region When holding structure.
The realization of the purpose is the multi-layer gasket moulded by steam according to claim 1, and passes through basis The application of this pad described in claim 17.
Included according to the multi-layer gasket that the steam under pressure of the present invention is moulded：
First layer, it forms enhancement layer, and the enhancement layer is by powder or fiber or the polyamide substrate material of sheet form The mixed goods of material and reinforcing fibre is made,
And at least one second layer, it is selected from open-celled polyurethane foam layer or heat-reflecting layer, or by powder or fibre The second enhancement layer that dimension or the polyamide substrate material of sheet form and the mixed goods of reinforcing fibre are made,
Wherein, because steam under pressure is moulded, all layers are laminated and all available mixed goods quilts Solidify to form porous enhancement layer.
It has been found that using live (open) steam molding process using polyamide as jointing material, the polyamide under steam pressure Softening and melting temperature be switched to less than the normal melt temperature according to the polyamide of dsc measurement.Know by using this Know, compared with current material, it now is possible to make part that there is higher melting temperature in use, and can be in higher temperature It is heat-staple under degree.Moreover, it has been discovered that the amount of the polyamide material used in enhancement layer is also laminated adjacent layer enough.Make us Surprisingly, such as froth bed or heat-reflecting layer layer are laminated also without additional matching glue layer.Particularly, find Mould using live (open) steam on additional froth bed and will not produce any negative effect to the acoustic characteristic of froth bed, for example, steep The melting of foam.Therefore, the favourable acoustic characteristic without top layer open celled foam of production is maintained.
The multi-layer gasket moulded according to the steam under pressure of the present invention may be used as automotive trim parts, and such as enging cabin is covered Panel, the top cover for engine, side cover or bottom, food tray lid, hood, fire-proof plate, and cover at least in part outer Aeroscopic plate after instrument board, the cooler of enging cabin, the luggage carrier in automobile or luggage case load floor.
The multilayer lining moulded according to the steam of the present invention will be described in more detail with the embodiment using this material below Pad and steam molding process.
Production technology
In the method according to the invention, the reinforcing fibre of high-modulus is with forming Fypro, thin slice or powder type The matrix of material is mixed by any suitable method (such as airlaid, wet-laying, combing), to form fabric.Then Fabric is heated with less than the polymerization for using differential scanning calorimeter (DSC) to determine according to ISO11357-3 with saturated steam Molten polyamide matrix material at a temperature of the melting temperature of thing.For example, the melting temperature of the polyamide -6 (PA-6) measured with DSC Spend TmFor 220 DEG C.However, being such as 190 DEG C according to the present invention identical PA-6 under steam pressure melting temperature.
The fabric is placed in the resistance to compression mould with least one vapor permeable surface.The mould is closed simultaneously Clamp to bear internal pressure.The saturated vapor of at least 9 bar absolute pressures is applied in hot-melt adhesive.More than 20 bar absolute pressures Saturated vapor is uneconomic.Preferably, 11 to 15 bar absolute pressure scopes are a good working ranges.Polyamide it is molten The actual converted for melting temperature depends on the steam pressure produced in the cavity of steam molding product.Therefore, used pressure Selection also depends on the melting temperature of reinforcing fibre.For example, the preferred pressure using PA-6 as binder fibre is 11 to 15 bars Absolute pressure.
Common hot-air, hot plate or infrared waves are replaced by using steam, it is possible to use the hydrone in steam The fusing point of polyamide is transformed into lower temperature by influence.Influence of the water to polyamide is known and is typically considered one Individual shortcoming, many prior art describes avoid the influence or attempt to prevent the method for the influence.It is unexpectedly, exactly the influence Make it possible to the polyamide material of powder, thin slice or fibers form and other heat with the similar fusing point by dsc measurement Plasitc fibers (such as PET) are combined, and reinforcing fibre (such as PET) is maintained at into its fiber using polyamide as unique jointing material Form.It is possible to obtain the heat stabilized moulding product with loose structure now, so as to improve acoustic characteristic (as absorbed sound) With anti-air-flow, and heat conductivity.
The influence of steam is based on reversible flooding mechanism.Use small fiber diameter or the polyamide of fine particulate form, melting It is fast with curing rate, it is with short production cycle.Once steam discharges from mould, polyamide is transformed into solid state, and part can To be stripped into rigid element.Compared to the other heat for needing substantially to cool down in mould inside or outside before structure member is obtained Plastic binder, this is an advantage, and it has sufficiently rigid to what is operated.
Because the bulk temperature used now compared with not using the mode of heating of steam can be kept as lower, PET The toughness of fiber is remained intact, so as to obtain more fluffy flexible material.Moreover, it has been found that needed for PA bonding is obtained enough Final products rigidity.Because the PA matrix materials that PET maintains its toughness and melted only are bonded in crosspoint.By Void volume in fabric, the material maintains its fluffy profile.Therefore, final products are still breathable.In addition, also It was found that using glass fibre as reinforcing fibre and using polyamide as matrix, the use of steam is favourable.Due to viscous The accurate adjustment of characteristic is closed, operates required energy less in heating and cooling procedure.
In the heating process of prior art, material is heated to the fusing point of thermoplastic matrix materials.The cooling of material is Slowly, because product radiating slower convection current and due to reinforcing fibre lack elasticity and make material compress and become densification. Therefore, molten condition will continue one section of longer time.The result is that being more difficult to adjust bonding amount.In addition, during cooling, Due to the longer molten condition of adhesive matrix, material keeps soft and is therefore more difficult to handle.For larger automobile decoration The top of part, such as truck or bigger vehicle or load floor, it is especially true.
Unexpectedly, it has been found that use material according to the invention and technique, once steam is removed from material, melt Melt process immediately to stop, and material is again at solid state.This is favourable in terms of time production cycle is reduced, because Material can be immediately treated.It is in fact possible to which the melting process stopped immediately is also regulation adhesion characteristic and material porosity A kind of point-device mode.For the permeability of material, this is important.
The use of the polyamide of such as discrete form such as thin slice, powder or fiber is necessary, to ensure the discrete of reinforcing fibre Bond to obtain porous but solidification structure.Due to the discrete of reinforcing fibre but it is fully cured, high bending rigidity can be obtained And dynamic rate.When selected material preferably at least 180 DEG C above is when heat-staple, resulting material keeps it to tie Structure, particularly will not soften when long-time is exposed to high thermic load or disintegrate (sack).Due to polyamide and reinforcing fibre Solidification be based only upon pressurization saturated vapor direct processing under the influence of polyamide softening and melting, it is not necessary that by enhancement layer Compression exceedes the necessary amounts for the 3D shape for obtaining desired final products.
Surprisingly it has been found that in identical steam molding process step by extra play be laminated to porous enhancement layer be can Can.Even find that PA matrix materials are enough firmly to bond extra play to laminating adhesive is used as, for example, combine perforate and steep Foam layer and/or heat-reflecting layer (such as aluminium foil) and/or grid cloth (scrim) layer.
Even more surprisingly it has been found that being moulded within the scope of the temperature according to the present invention using steam, foamed material Acoustical behavior does not change.In the conventional hot molding method of prior art, foam is typically to be heated to a temperature, at this At a temperature of foam soften and form outermost skin layers or even most serious is volume contraction or shrinkage.This is to the foam after molding Quality and acoustical behavior have the influence of deterioration.As can be seen that going out after molding in terms of sound absorption compared with reset condition Existing undesirable conversion.In the worst case, the conversion may be converted into overall sound absorption loss.
It is known that foam regeneration is arrived its Initial Composition by steam, therefore it is not generally used for being not intended to material degeneration The molding of part., it is surprising that the method according to the invention does not show the structure and acoustics in handled foam Qualitative any measurable influence.Because foam is typically without melting during steam cycle, the perforate knot initially obtained Structure is kept in the production process of foam.The bonding of porous enhancement layer and froth bed is entirely from polyamide adhesive agent material Molten melt drop.This is enough to obtain stable laminate adhesive.Extra advantage is, in the heat load environment of such as enging cabin In, the temperature for layering is far above the temperature of commonly used material.In addition, hot weak link be no longer adhesive in itself.
Even find, according to same principle, reflecting material directly can be laminated with porous enhancement layer.However, (particularly in aluminium foil) in the case of metal foil, the laminating surface contacted with porous enhancement layer may be anticipated with enhancement layer Pressure.
If desired, film, powder, the additional polyamide adhesive layer of thin slice or scrim layer form can be arranged in Between layers, to improve bond properties.
Porous enhancement layer
Porous enhancement layer is a kind of increased breathable compound of rigidity, the jointing material and reinforcing fibre of random arrangement It is retained in together by the substantially discontinuous drop of thermoplastic binder material in fiber crossovers position.
Material as thermoplastic binder material is the polyamide substrate of powder, thin slice or fibers form.Strengthen porous The use of Fypro is very favorable in layer, because fiber is generally better mixed, and fabric before curing This mode is kept in processing procedure.Especially, thin slice or powder can leave fabric by processing and fall between reinforcing fibre Without solidifying.
For polyamide, the mixture of all types of polyamide is all feasible, preferably CoPA (copolyamide), polyamides At least one of amine -6 (PA-6) or polyamide -6.6 (PA6.6).Expect the addition that basic polyamide ligand Fang Zhongtong is often used Agent is a part for required basic polyamide material, such as chemical compound, to realize uvioresistant, or other chemistry Thing, to increase heat endurance.
The use of polyamide adhesive fiber is most preferred, and in embodiment and preferred embodiment, however, powder End or thin slice can also be used in identical embodiment, with comparable effect.
Reinforcing fibre can be：
Mineral-based fibers, such as glass fibre, basalt fibre or carbon fiber, and/or
Staple fibre, it has the melting temperature measured according to DSC, and the temperature is higher than polyamide under steam pressure Melting temperature, such as polyester fiber, and/or
Natural fiber, such as flax, coconut or kenaf.
Especially, reinforcing fibre can be any thermoplastic polymer base material with the melting temperature according to dsc measurement Material, melting temperature of the melting temperature higher than the polyamide adhesive agent material in steam ambient.For example, such as melting temperature Staple fibre for the PET (polyethylene terephthalate) between 230-260 DEG C may be used as reinforcing fibre.The choosing of material Select the price of overall thermal stability requirement and various materials based on final products.
In addition, the mixture of the staple fibre with mineral fibres can make reinforcing fibre week, for example PET is together with GF.Make Will increase the bulkiness of final layer with such combination and acoustics enhancement layer can be defined as, more details refer to for The independent description of this layer.According to required material property, reinforcing fibre can be cutting fibre, non junction long filament or rove.
The parent material of enhancement layer is the heelpiece for the jointing material and reinforcing fibre being randomly provided, can be according in this area Known method is manufactured, for example, using airlaid or carding technology, or the direct forming after fibrous material extrusion.Institute Obtained heelpiece for example can be easier to handle by needing (needling) solidification in advance.
The ratio of polyamide adhesive material and reinforcing fibre make it that after steam treatment material keeps porous.It is preferred that polyamides The weight of amine jointing material is between 20% and 60%.
Acoustics enhancement layer
Acoustics enhancement layer is a kind of fluffy form of enhancement layer, and it has enhanced sound absorbing capabilities.Adhesive material and public affairs The adhesive material for porous enhancement layer opened is identical, but reinforcing fibre can be mineral fibres, staple fibre and/or day Any combinations or blend of right fiber, mineral fibres are, for example, glass fibre, basalt fibre or carbon fiber, staple fibre tool The melting temperature of with good grounds dsc measurement, it is higher than melting temperature of the polyamide under steam pressure, and such as polyester fiber is natural fine Dimension for example, flax, coconut or kenaf.For example, PET (poly- terephthaldehyde of the melting temperature between 230-260 DEG C Sour glycol ester) can be effectively as reinforcing fibre together with the combination of glass fibre.
As a result find, by using such fiber combinations, material maintains its bulkiness during steam molding process. It is increased sound absorption properties that not only there is material enhanced rigidity also to have.
The mineral fibres of such as glass fibre is superfine fibre, it is therefore highly preferred that for absorbing sound, but in heat treatment, they Often lose its volume and therefore lose initial sound absorbing capabilities.Surprisingly, it has been found that the artificial fibre suitably selected Dimension or natural fiber, such as polyester fiber or kenaf, their rigidity is maintained in the steam molding process of gasket material. Therefore, the material that the volume of material is kept and solidified remain it is porous so that still provide initial sound absorbing capabilities.
Preferably, about 20-40% (weight) polyamide, about 20-50% (weight) glass fibre and 20-50% (weights Amount) polyester fiber or the mixture of natural fiber will work well.
According to required material property, reinforcing fibre can be cutting fibre, non junction long filament or rove.
Heat-reflecting layer
At least one heat-reflecting layer can be used together with fiber multihole enhancement layer.At least in increased thermic load region In, can be partly or wholly covered with heat reflection coating towards the surface of thermal source, thermal source is typically that engine or power are passed The surface of the part or discharge duct or exposure of dynamic system in the sun.It should be heat-staple to reflect coating, and can reflect The infrared radiation of self-heat power or the sun, to obtain the good heat-insulated of decorative element, it is preferable that reflection coating is metal foil One kind in the yarn fabric that layer (preferably stainless steel or aluminium foil layer) or the yarn fabric or non-woven fleece or aluminum fiber aluminized are made.Heat Reflecting layer should be able at least resist steam treatment and never degenerate.
It is preferably between 20 μm and 150 μm, more preferably between 50 μm and 80 μm to reflect coating.Because enhancement layer is held The main static function of row, can use less thickness, and uniquely effect is substantially reflective thermal radiation in reflecting layer.
Reflecting coating can micropunch at least in part, although It is not necessary to all be so in all cases.It is micro- Perforating can be realized by known technology, such as acupuncture, joint-cutting, microfissure or cheesing techniques.By means of the optional of reflecting layer Perforation, the heat reflection effect of the layer is kept, but obtains the transmission of sound wave in the region so that the direction of multi-layer gasket The aluminium foil coating side of sound source keeps its acoustics activity.
Especially, reflection covering layer material be selected as it is non-porous or without perforation in the case of, hot entrance preferably should In side of the fiber decorative element not covered with reflection coating, to optimize the Steam soak into porous enhancement layer.
In the case of using reflection coating in the both sides of material, at least one layer in used multilayer should be worn It is hole and/or porous, it is sufficient to steam is flowed into fibrous layer.
Equally, layer of reflective material can be used between two enhancement layers according to the present invention.This layer be preferably perforate or Porous, still, if steam stream flows into mould from two mould half portions, rather than via only one mould half portion, paper tinsel is It is not necessary to perforating or porous.
Froth bed
As extra play, open cell foam layer can be used.Foam is preferably without skin foam (skinless foam).Even Slab foam that is continuous or discontinuously producing is most preferred, because this foam is cut into sheet after foaming and solidification, therefore Open-celled structure can be immediately adjacent to without any top layer.
Preferably, the froth bed is at least short-term heat-staple between 160 DEG C and 220 DEG C, and for example it is gathered by perforate Urethane (PUR) foam or polyester (PET) foam are made.
Polyurethane foam is made up of the addition reaction of polyisocyanates and polyalcohol.Additive is used as needed. The embodiment for the PUR foam that can be used in the pad according to the present invention is for example disclosed in EP 0937114 or EP 937109A In.
Especially, for engine compartment area or the region with increased thermic load, the use of fire retardant be it is favourable, For example handled using the fire retardant of liquid and/or solid, or include this fire retardant in the foam.Using for example in EP The foam with additional graphite disclosed in 1153067 or US 6552098 will be preferred.
Pass through in these documents especially with regard to the production technology of slab foam and all disclosures of material composition It is incorporated herein by reference.
Can be used for according to the industrial obtainable foam for preparing slab foam of the pad of the present invention is, for example, to come from Huntsmann ACOUSTIFLEX S15 (semi-rigid) or ACOUSTIFLEX F25 (flexibility), or Foampartner Flexidur 15FR+ (semi-rigid) or Rigidur 10 (semi-rigid), or the different brackets as made from Eurofoam and density Thermoflex semi-rigid foam scopes, such as Thermoflex 15, Thermoflex15MDA, Thermoflex 15MDA VW, Thermoflex 16, Thermoflex 22, and flexibility Thermoflex foams, such as T-flex 16 or T-flex 22.
Preferably, the density of foam is 8-40kg/m3Between, more preferably 12-30kg/m3Between.Because open celled foam will Increase and decayed according to the overall noise of the pad of the present invention, be about the thickness between 6-45mm for slab foam before molding, it is empty The preferred scope of air-flow dynamic resistance is 100-5000N.s/m3Between.
Astoundingly, it is found that froth bed does not change its acoustic characteristic during steam treatment, particularly in the time In condition so that foam maintains open-cell foam structure.Especially, can be with when being laminated in standard hot mould with foam The top layer seen be enclosed in using the method according to the invention when no longer it is observed that.Therefore, the acoustic characteristic of open celled foam is complete It is complete to be maintained in the pad according to the present invention.
If padded for the structure member with high mechanical load, froth bed used is selectable to improve overall Architectural characteristic, for example, by selecting harder froth bed (such as the froth bed that polyurethane or polyester are made), or pass through addition Reinforcing fibre is to froth bed.
Additional layer
Preferably, additional layer can be used.Lid attractive in appearance, or adherent layer can be such as needed to prevent the lining of stacking The wall of pad adhesion mould.Preferably, the scrim layer being made using thermoplastic fiber materials, to be given during steam is moulded Within the temperature range of it is heat-resisting.
Grid cloth is a kind of thin non-woven fabric, its thickness 0.1 between about 1mm, preferably 0.25 to 0.5mm it Between.Preferably, they have 500 to 3000N.s.m-3Between increased vapour lock (AFR), more preferably 1000 to 1500N.s.m-3Between.The area weight of scrim layer can be between 15 to 250g/m2Between, preferably 50 to 150g/m2It Between.
Grid cloth can be made up of continuous or chopped fiber or fibre blend.The fiber can be by melt-blown or spunbond technology system Into can also be mixed with natural fiber.Preferably, the material of selection is heat-staple under the exposure of prolonged thermic load.Net Lattice cloth can be made up of fiber, and for example by polyester or polyamide or the heat-staple polyacrylonitrile of oxidation, (PAN is also referred to as PANox) it is made, or is the combination of fiber, such as polyester and cellulose or polyamide and polyester.The layer can be existed with usual Processing mode needed for application region is handled, such as grease proofing, waterproof, the inflammability processing.The preferred embodiment of scrim layer can To be non-woven mesh layer of cloth that polyester fiber and viscose rayon are made.
When being used in passenger area according to the pad of the present invention, it is possible to use such as nonwoven carpet or tufted carpet are alternative Coating.These layers can also be added after steam molding process step by using the conventional method being known in the art.
In steam molding process, polyamide web scrim layer can be for the additional of additional layer pressure not direct neighbor enhancement layer The amount of jointing material in layer and/or increase lamination area.Polyamide can also powder or thin slice form addition extra play it Before spread on the surface, or as thin bonding paper tinsel or fabric like structure.Therefore, other layers of direct neighbor enhancement layer can not also It is laminated on the multi-layer gasket according to the present invention, such as different coatings attractive in appearance, such as tufting or nonwoven carpet layer, flocking material Material or non-woven fleece covering material.
Multi-layer gasket
According to the present invention steam mould multi-layer gasket include porous enhancement layer, and selected from froth bed, reflecting layer or At least one second layer in second porous enhancement layer.
Additional layer can also be used further to improve the characteristic of the multi-layer gasket according to the present invention, such as additional foam Layer or enhancement layer or similar coating attractive in appearance or technique scrim layer.It is also contemplated that using the similar layer of different densities. For example, if the directly contact of two froth beds is used, it is possible to use Fypro grid cloth, fabric, perforated foil, powder Or the polyamide adhesive layer of sheet form.The use of polyamide as additional adhesive layer is favourable because it can with reinforcement Matrix material identical mode in layer is reacted to steam.
Porous enhancement layer has primarily formed the necessary rigidity of structure.Pad is used as self-supporting knot in most applications Structure.
In a preferred application, multi-layer gasket includes at least two selected from porous enhancement layer and the porous enhancement layer of acoustics Individual layer.Preferably, the two layers are only connected to each other at the edge of pad, or by using sept between two layers of main surface Leave hollow space.The hollow space is used as additional sound absorption region and acoustics and heat decoupling region.By using extremely A few porous enhancement layer of acoustics, can increase overall acoustical behavior.
Different types of decorative element, such as Engine encapsulation can be used in engine compartment area (encapsulation), engine head covering and it is installed to the Engine encapsulation of vehicle chassis.In addition, such as car Other components such as preceding cap packing, outer bulkhead pad and downside engine shroud and perpendicular elements along front beam can be put Put in enging cabin, to optimize the heat management of enging cabin.Especially hood liners, fire-proof plate or neighbouring automobile are sent out Cover (such as engine air cylinder cap), the engine side panel of motivation, and it is other used in (such as bag of heat exposure region in vehicle The PWTN of gear-box and gas exhaust piping is included, especially on vehicle body and PWTN and/or gas exhaust piping Heat shielding cover) pad.In addition, all types of downside body panels particularly used in engine and passenger compartment all fall Enter in the range of the use that the present invention is padded.
These and other feature of the present invention is using from as follows referring to the drawings the preferred shape to being provided as non-limiting examples The description of formula is made apparent from.
By means of accompanying drawing, the embodiment of the combination of the favourable layer of application-specific is will be given for, with furthermore The bright present invention.However, the present invention should be not constrained to these embodiments, these embodiments more mean to show according to this hair The various possibilities of bright pad.
Brief description of the drawings
Fig. 1 is the explanatory view of the steam treatment according to the present invention；
Fig. 2 schematically shows the layering of the gasket material according to the present invention.
Embodiment
Fig. 1 will be used production technology is described in more detail, Fig. 1 shows the steaming including lower mold half 2 and upper mold half 1 Vapour mould.The two half modules limit die cavity together, and semi-finished product will at least be solidified in the die cavity.The die cavity is formed as most Whole decorative element desired three dimensional shape.Nonwoven felt as semi-finished product, its have jointing material and reinforcing fibre 10 with And such as mixture of froth bed 11.Preferably, the two half-unit of mould has entrance 7 and outlet 8, and saturated vapor passes through described Entrance and exit flows into die cavity and directly contacted with to be solidified and lamination multilayer material., preferably will be partly due to using saturated vapor Mould remain it is warm, to help to form pressure and prevent steam from condensing.Because steam condensation can cause heat-energy losses, and pass through Water causes product to drench.Passage 3,4,5 and 6 shown in this figure, shows the closing heating system of half module.
Mould can have additional cutting sealing element 9 at its edge, and they can be independently moved and promoted, and And they form the pressure seal of mold periphery, that is, pass through labyrinth sealing.After die pressure sealing, semi-finished product are exposed to full And steam.Steam is used as steam under pressure, and its pressure in die cavity is about preferably at least 9 bars between 2-20 bar absolute pressures Absolute pressure, and this pressure is kept in whole solidification process in die cavity.
Process time is dominated by the steam pressure rising and release for solidification.Preferably, before compacting tool set is opened, Steam under pressure is released.Although some water are not condensed in steam treatment process, and it is kept in the pad according to the present invention In material, they will be dried after mould is opened, and this is retained in the inner core of part mainly due to remaining heat energy.Make us frightened It is that, once steam pressure is pulled away, the softening and fusing of polyamide are reversed, and part becomes solid with being surprised.Therefore, steam work Skill is not only due to that dwell for needing is of short duration but favourable, and it is also eliminated is molded in using the conventional compression of drying system Moulding part can remove any cool time required before from die cavity.
Following steps are comprised at least according to one embodiment of the manufacture method of the multi-layer gasket of the present invention：
By 20% to 60% polyamide substrate of 40% to 80% reinforcing fibre and fiber, thin slice or powder type Material is mixed, and forms the fabric of the blend；
The first blend fabric and at least one additional layer are layered in the mould being made up of two half modules, it is described attached Plus layer choosing from the second blend fabric of open cell foam layer, heat-reflecting layer or reinforcing fibre and polyamide substrate material；
With the multilayer material of pressurization saturated vapor processing stacking so that the polyamide substrate material in blend fabric is steaming Melted under steam pressure with the temperature of the melting temperature less than the polyamide substrate according to DSC, so that reinforcing fibre is bonded in into one Rise, and solidify to form the blend fabric of porous enhancement layer so that the layer of stacking is laminated.
Half module can be completely closed when starting, or can be closed in steam treatment process, so that in steam cycle During beginning and/or at the end of discharge part steam.Saturated vapour pressure ranges preferably from 9 to 20 bar absolute pressures.
At least one layer of additional scrim layer can be used to prevent stratified material from adhering to mould.Such as polyester-fiber Plain non-woven mesh layer of cloth.The multilayer material of stacking can also include other additional layers, such as blend fabric extra play, foam Layer etc..Polyamide substrate is preferably the mixing of polyamide -6 or polyamide -6.6 or copolyamide or different types of polyamide Thing.
The saturation porous multilayer pad of the molding produced according to disclosed production technology can be moulded directly as 3D shapes, For use as the decorative element of automobile, such as enging cabin cover plate, the top plate of engine, side plate or bottom plate, food tray lid, bottom are started Hood, at least partly fire-proof plate, the exterior fascia of covering, aeroscopic plate, luggage carrier or row behind the cooler of enging cabin Lee's case loads floor.
The multi-layer gasket of steam molding most advantageously can be used in the region of the increase thermic load of vehicle, such as engine, Near PWTN and exhaust, it is also possible to the decorative element of sunlight is directly exposed to after trunk area or as vehicle window, Such as luggage carrier or sunshading board.
Fig. 2 shows the embodiment of possible multi-layer gasket material.Based on the pad according to the present invention, it can select porous Enhancement layer or the porous enhancement layer of acoustics.Unlike, enhancement layer is mainly made up of polyamide substrate and reinforcing fibre.Although acoustics Enhancement layer is made up of polyamide substrate and reinforcing fibre, but reinforcing fibre is the mixture of staple fibre and mineral fibres, for example The mixture of polyester fiber and glass fibre, provides a kind of more fluffy layer after solidifying using steam cycle.
Fig. 2A shows one embodiment of porous enhancement layer 10 and open cell foam layer 11, it is preferable that heat-reflecting layer 12 can To cover at least one outer surface of pad at least in part.Likewise, scrim layer 13 can be used for the outer of covering pad Surface.Acoustics enhancement layer may replace porous enhancement layer 10 be used for need more high acoustic absorption level in the case of.
In general, enhancement layer can replace injection-molded plastic layer to be generally used in automotive trim parts, because It has comparable rigidity property.However, because its porous shows sound absorbing capabilities, this is that injection molded does not possess 's.Even sound absorption is added using additional absorbent treatment.
For the automotive trim parts used in hot environment, particularly in engine compartment area, porous enhancement layer with The combination of open cell foam layer is a selection well, because its very light and suitable most acoustical demands.
For with the decorative element used in increased thermic load region, such as direct engine installing component, using many The combination of hole enhancement layer and the porous enhancement layer of fluffy acoustics is a preferably selection.
Heat-reflecting layer can be used for especially being directed to thermal source and/or obtain the surface or part of most direct heat energy In surface.
Porous enhancement layer 10 can also combine acoustics enhancement layer 14 (Fig. 2 B).
Fig. 2 C and 2D show at least three layers of embodiment.In fig. 2 c, froth bed 11 be sandwiched in two enhancement layers 10 it Between, although used herein is the enhancement layer of standard, it is possible to use one layer of two layers of acoustics enhancement layer or a type, depending on multilayer lining Depending on the situation that pad is used.Especially, the automobile high thermal load regions of Thermal protection are needed in foam, this is a kind of option.It is preferred that Ground, can also be at least partially covered with reflecting surface (not shown) and/or scrim layer.
Fig. 2 D show the sandwich with the enhancement layer 10 being clipped between two froth beds 11 as sandwich layer.If with Passenger and/or attendant often in contact with surface in, this layout has advantage.If glass fibre is stretched from pad surfaces Go out, have unpleasant Sting results, this is most beastly.Foam meeting cover glass fiber surface, to prevent this Plant spot effect (site effect).Enhancement layer constitutes main structural behaviour, therefore, foam can be it is semirigid, even Usually used more flexible open celled foam type.

Claims (26)

1. the multi-layer gasket for heat-insulated and sound insulation steam under pressure molding, it is characterised in that first including forming enhancement layer Layer and at least one second layer, the enhancement layer is by powder or fiber or the polyamide substrate material of sheet form and strengthens fine The blend fabric of dimension is made, at least one described second layer be selected from open cell foam layer or heat-reflecting layer or by powder or fiber or The second enhancement layer that the polyamide substrate material of sheet form and the blend fabric of reinforcing fibre are made, wherein, because pressurization is steamed Vapour is moulded so that the polyamide substrate material in the blend fabric is under steam pressure with less than the polyamide-based according to DSC The temperature melting of the melting temperature of body, so that all layers are laminated, and all available blend fabric are cured To form porous enhancement layer.
2. multi-layer gasket according to claim 1, it is characterised in that also including forming enhancement layer, froth bed or heat reflection The third layer of the blend fabric of layer.
3. multi-layer gasket according to claim 1 or 2, it is characterised in that the reinforcing fibre be mineral-based fibers and/or Staple fibre and/or natural fiber.
4. multi-layer gasket according to claim 3, it is characterised in that the mineral-based fibers are glass fibre, basalt Fiber or carbon fiber, the staple fibre are polyester fiber, and with the melting temperature according to dsc measurement, it is higher than steam pressure The melting temperature of lower polyamide, the natural fiber is flax, coconut or kenaf.
5. multi-layer gasket according to claim 1 or 2, it is characterised in that at least two layers of formation are made up of blend fabric Enhancement layer, at least one of these blend fabric include the mixture of mineral-based fibers, staple fibre or natural fiber.
6. multi-layer gasket according to claim 5, it is characterised in that the mineral-based fibers are glass fibre, basalt Fiber or carbon fiber, the staple fibre are polyester fiber, and with the melting temperature according to dsc measurement, it is higher than in vapour pressure The melting temperature of polyamide under power, the natural fiber is flax, coconut or kenaf.
7. multi-layer gasket according to claim 1 or 2, it is characterised in that at least two layers are enhancement layer, these enhancement layers Only marginal portion it is laminated together so that at least 80% surface of adjacent enhancement layer is not contacted each other but by air Layer separates.
8. multi-layer gasket according to claim 1 or 2, it is characterised in that the mixture for forming the enhancement layer is 20- The polyamide of 40% weight, the polyester fiber of the glass fibre of 20-50% weight and 20-50% weight and/or natural fiber Mixture.
9. multi-layer gasket according to claim 1 or 2, it is characterised in that the open cell foam layer is no skin foam.
10. multi-layer gasket according to claim 9, it is characterised in that the open cell foam layer is slab foam.
11. multi-layer gasket according to claim 1 or 2, it is characterised in that the open cell foam layer is by polyurethane (PUR) Or polyester (PET) or fiber filled and process are made.
12. multi-layer gasket according to claim 1 or 2, it is characterised in that the open cell foam layer includes fire retardant.
13. multi-layer gasket according to claim 12, it is characterised in that the fire retardant is graphite.
14. multi-layer gasket according to claim 1 or 2, it is characterised in that the heat-reflecting layer is at infrared reflection coating The non-woven or woven textiles or wire braid or metal foil layer of reason.
15. multi-layer gasket according to claim 14, it is characterised in that the metal foil layer is aluminium foil or stainless steel foil.
16. multi-layer gasket according to claim 1 or 2, it is characterised in that the heat-reflecting layer only partially covers adjacent Layer.
17. multi-layer gasket according to claim 1 or 2, it is characterised in that the heat-reflecting layer is metal foil layer, it is extremely Partially include the through hole for being used for passing air through the metal foil layer.
18. multi-layer gasket according to claim 17, it is characterised in that the through hole is perforation, pinprick or with micro- The crack in gap.
19. multi-layer gasket according to claim 1 or 2, it is characterised in that the heat-reflecting layer is at least 20 μm to 150 μ Between m.
20. multi-layer gasket according to claim 19, it is characterised in that the heat-reflecting layer is between 50 μm to 80 μm.
21. multi-layer gasket according to claim 1 or 2, it is characterised in that the polyamide substrate material is polyamide -6 Or the mixture of polyamide -6.6 or copolyamide or these polyamide.
22. multi-layer gasket according to claim 1 or 2, it is characterised in that the area weight of the enhancement layer is 100g/m2 To 2000g/m2Between.
23. multi-layer gasket according to claim 1 or 2, it is characterised in that the gas-flow resistance of the enhancement layer be 500 to 1000N.s/m3Between.
24. multi-layer gasket according to claim 1 or 2, it is characterised in that the overall gas-flow resistance of the multi-layer gasket is 500 to 2500N.s/m3Between.
25. according to the purposes of the multi-layer gasket that any described steam under pressure is moulded in preceding claims, the multi-layer gasket As automotive trim parts.
26. the purposes of multi-layer gasket according to claim 25, it is characterised in that the automotive trim parts are engine Cabin cover plate, the top cover for engine, side cover or bottom, food tray lid, bottom hood, fire-proof plate, at least partly cover The outer instrument board of lid, the aeroscopic plate behind the cooler of enging cabin, luggage carrier or luggage case load floor.
CN201280014690.5A 2011-03-23 2012-03-12 Multi-layer gasket for heat-insulated and sound insulation molding Active CN103443342B (en)

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PCT/EP2012/054279 WO2012126763A2 (en) 2011-03-23 2012-03-12 A moulded multilayer lining for heat and sound insulation

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