CN103805074A - Nano palygorskite-modified flame-retardant adhesive - Google Patents
Nano palygorskite-modified flame-retardant adhesive Download PDFInfo
- Publication number
- CN103805074A CN103805074A CN201410057022.1A CN201410057022A CN103805074A CN 103805074 A CN103805074 A CN 103805074A CN 201410057022 A CN201410057022 A CN 201410057022A CN 103805074 A CN103805074 A CN 103805074A
- Authority
- CN
- China
- Prior art keywords
- parts
- sizing agent
- modification
- retardant
- palygorskite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a nano palygorskite-modified flame-retardant adhesive which consists of the following raw materials in parts by weight: 100-150 parts of styrene, 50-80 parts of ethyl methacrylate, 10-15 parts of pentaerythritol, 5-8 parts of furan resin, 10-15 parts of epoxypropane butyl ether, 10-15 parts of chloroprene rubber, 1-3 parts of boron powder, 5-10 parts of bisphenol A epoxy resin, 5-8 parts of epoxidized soybean oil, 15-20 parts of nano palygorskite, 8-10 parts of nano feldspar powder, 2-4 parts of titanium dioxide, 2-3 parts of chlorinated paraffin, 1-3 parts of glass powder, 2-3 parts of magnesium oxide, 15-20 parts of flame-retardant polyether polyol, 5-8 parts of lignin, 3-5 parts of amination triazine salt, 0.5-0.8 part of dibutyltin dilaurate, 0.3-0.5 part of phosphoric acid, 1-2 parts of antioxidant 1076, 2-3 parts of anti-aging agent MB, 1-2 parts of accelerant CBS, 3-5 parts of titanate coupling agent and 3-5 parts of modified tree ash. The adhesive disclosed by the invention has the advantages of excellent adhesion, flame retardance, smoke suppression, low toxicity, good storage stability and the like.
Description
Technical field
The present invention relates to sizing agent technical field, relate in particular to a kind of fire-retardant sizing agent of nanometer palygorskite modification.
Background technology
Along with building high stratification, automotive light weight technology, high-newization of electrical equipment, furniture are superior, the development of industrial large-sizedization, sizing agent has obtained application increasingly widely in modern industry field and daily life, but most of sizing agents are more inflammable, exist fire hazard, simultaneously, when sizing agent burning, also can produce smog and poison gas, environment and the person are all impacted.Existing market is in great demand for fire-retardant sizing agent, and for the research in this field or little, sizing agent belongs to macromolecular compound, meets the general condition of superpolymer burning, if without fire-retardant finish, just cannot use some special dimension.Therefore, research and development have fire-retardant, press down cigarette, low toxicity or nontoxic sizing agent has become one of focus direction of development of new sizing agent.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of very strong adhesiveproperties, fire-retardant that has is provided
Property, press down the fire-retardant sizing agent of the nanometer palygorskite modification of cigarette, low toxicity, excellent storage stability.
The present invention adopts following technical scheme to achieve these goals:
A kind of fire-retardant sizing agent of nanometer palygorskite modification, raw material by following weight part forms: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, tetramethylolmethane 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, chloroprene rubber 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, epoxy soybean oil 5-8 part, nanometer palygorskite 15-20 part, nanometer Feldspar Powder 8-10 part, titanium dioxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 parts, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification trees ashes 3-5 part.
Described flame retardant polyether polyol is one or both of halogenated polyether polyvalent alcohol, phenol polyvalent alcohol.
Described modification trees ashes are prepared by following methods: first use 10-15% salt acid soak trees ashes 3-5h, then use deionized water washes clean, soak 3-5h with 10-13% sodium hydroxide solution again, extremely neutral with deionized water wash, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 2-4%, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min is stirred 1-3h, pulverizes and grinds to form ultrafine powder.
The preparation method of the fire-retardant sizing agent of described nanometer palygorskite modification, comprises the following steps:
(1) add reactor to be heated to 100-120 ℃ vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio, high-speed stirring 1-2h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, packing.
Compared with the prior art, beneficial effect of the present invention is as follows:
The present invention, by adding nanometer palygorskite and flame retardant polyether polyol in sizing agent, adjusts formula, significantly improves flame retardant properties, the smoke suppressing of sizing agent, trees ashes is carried out to modification simultaneously, improves sizing agent group
The dispersing uniformity dividing, obviously improves the bonding strength of sizing agent, and obviously improves the package stability of sizing agent.Sizing agent of the present invention has very strong cementability, flame retardant resistance, presses down the advantages such as cigarette, low toxicity, excellent storage stability.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment:
A kind of fire-retardant sizing agent of nanometer palygorskite modification, raw material by following weight part forms: 130 parts of vinylbenzene, 70 parts of β-dimethyl-aminoethylmethacrylates, 10 parts of tetramethylolmethanes, 6 parts of furane resin, 12 parts of epoxy propane butyl ethers, 12 parts of chloroprene rubbers, 2 parts, boron powder, 8 parts of bisphenol A epoxide resins, 7 parts of epoxy soybean oils, 20 parts of nanometer palygorskites, 8 parts of nanometer Feldspar Powders, 2 parts of titanium dioxides, 2 parts of clorafins, 2 parts, glass powder, 2 parts, magnesium oxide, 15 parts of halogenated polyether polyvalent alcohols, 7 parts, xylogen, 4 parts of amination triazine salt, 0.6 part of dibutyl tin laurate, 0.4 part of phosphoric acid, 1,076 2 parts of antioxidants, 2 parts of antioxidant MBs, 2 parts of accelerator CBSs, 4 parts of titanate coupling agents, 5 parts, modification trees ashes.
Wherein, described modification trees ashes are prepared by following methods: first use 15% salt acid soak trees ashes 4h, then use deionized water washes clean, soak 4h with 13% sodium hydroxide solution again,, dry to neutral with deionized water wash, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 3%, 2% peregal, 3% tributyl citrate, 1500 revs/min are stirred 2h at a high speed, pulverize and grind to form ultrafine powder.
The preparation method of the fire-retardant sizing agent of described nanometer palygorskite modification, comprises the following steps:
(1) add reactor to be heated to 120 ℃, high-speed stirring 1h vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio;
(2) other material is mixed with reactant in step (1), stir 50min, be cooled to normal temperature, obtain finished product, packing.
After sizing agent in the embodiment of the present invention solidifies, it is carried out to heat analysis, the temperature that starts to decompose is 292.05 ℃.
Claims (4)
1. the fire-retardant sizing agent of a nanometer palygorskite modification, it is characterized in that: the raw material by following weight part forms: vinylbenzene 100-150 part, β-dimethyl-aminoethylmethacrylate 50-80 part, tetramethylolmethane 10-15 part, furane resin 5-8 part, epoxy propane butyl ether 10-15 part, chloroprene rubber 10-15 part, boron powder 1-3 part, bisphenol A epoxide resin 5-10 part, epoxy soybean oil 5-8 part, nanometer palygorskite 15-20 part, nanometer Feldspar Powder 8-10 part, titanium dioxide 2-4 part, clorafin 2-3 part, glass powder 1-3 part, magnesium oxide 2-3 part, flame retardant polyether polyol 15-20 part, xylogen 5-8 part, amination triazine salt 3-5 part, dibutyl tin laurate 0.5-0.8 part, phosphoric acid 0.3-0.5 part, antioxidant 1076 1-2 parts, antioxidant MB 2-3 part, accelerator CBS 1-2 part, titanate coupling agent 3-5 part, modification trees ashes 3-5 part.
2. the fire-retardant sizing agent of nanometer palygorskite modification according to claim 1, is characterized in that: described flame retardant polyether polyol is one or both of halogenated polyether polyvalent alcohol, phenol polyvalent alcohol.
3. the fire-retardant sizing agent of nanometer palygorskite modification according to claim 1, it is characterized in that: described modification trees ashes are prepared by following methods: first use 10-15% salt acid soak trees ashes 3-5h, then use deionized water washes clean, soak 3-5h with 10-13% sodium hydroxide solution again, extremely neutral with deionized water wash, dry, add and be equivalent to the wooden sodium sulfonate of trees ashes weight 2-4%, the peregal of 1-3%, the tributyl citrate of 2-4%, high speed 1300-1500 rev/min is stirred 1-3h, pulverizes and grinds to form ultrafine powder.
4. a preparation method for the fire-retardant sizing agent of nanometer palygorskite modification as claimed in claim 1, is characterized in that: comprise the following steps:
(1) add reactor to be heated to 100-120 ℃ vinylbenzene, β-dimethyl-aminoethylmethacrylate, tetramethylolmethane, furane resin, epoxy propane butyl ether, chloroprene rubber, bisphenol A epoxide resin, flame retardant polyether polyol, dibutyl tin laurate, phosphoric acid by above-mentioned weight ratio, high-speed stirring 1-2h;
(2) other material is mixed with reactant in step (1), stir 30-50min, be cooled to normal temperature, obtain finished product, packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057022.1A CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057022.1A CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103805074A true CN103805074A (en) | 2014-05-21 |
| CN103805074B CN103805074B (en) | 2015-06-10 |
Family
ID=50702480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410057022.1A Expired - Fee Related CN103805074B (en) | 2014-02-20 | 2014-02-20 | Nano palygorskite-modified flame-retardant adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103805074B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315527A (en) * | 2015-11-23 | 2016-02-10 | 苏州盖德精细材料有限公司 | Neoprene-based UL yellow adhesive and preparation method thereof |
| CN106751502A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of neo-epoxy resin composition |
| CN107739577A (en) * | 2017-11-17 | 2018-02-27 | 刘青 | A kind of anti-flammability adhesive |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997709A (en) * | 1988-11-07 | 1991-03-05 | The Kendall Company | Novel adhesives and tapes including same |
| CN101298509A (en) * | 2008-06-18 | 2008-11-05 | 西北师范大学 | Nanometer grade paligorskite-flame retardant epoxide resin composite material |
| JP2008274274A (en) * | 2001-01-10 | 2008-11-13 | Hitachi Chem Co Ltd | Thermosetting resin composition and prepreg using it, laminate sheet for wiring board, and printed wiring board |
| CN102533161A (en) * | 2011-12-19 | 2012-07-04 | 庄晓曦 | Flame-retarding pressure-sensitive adhesive and preparation method thereof |
| CN102965036A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-wollastonite modified adhesive for packaging |
| CN102977799A (en) * | 2012-11-15 | 2013-03-20 | 合肥帝奥木业有限公司 | Preparing method of high-strength woodworking adhesives |
| CN103013389A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special bonding agent containing rice hull ash for surface composite woven shell fabric of automotive upholstery |
| CN103265917A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing nano attapulgite for packaging and preparation method thereof |
-
2014
- 2014-02-20 CN CN201410057022.1A patent/CN103805074B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4997709A (en) * | 1988-11-07 | 1991-03-05 | The Kendall Company | Novel adhesives and tapes including same |
| JP2008274274A (en) * | 2001-01-10 | 2008-11-13 | Hitachi Chem Co Ltd | Thermosetting resin composition and prepreg using it, laminate sheet for wiring board, and printed wiring board |
| CN101298509A (en) * | 2008-06-18 | 2008-11-05 | 西北师范大学 | Nanometer grade paligorskite-flame retardant epoxide resin composite material |
| CN102533161A (en) * | 2011-12-19 | 2012-07-04 | 庄晓曦 | Flame-retarding pressure-sensitive adhesive and preparation method thereof |
| CN102965036A (en) * | 2012-11-02 | 2013-03-13 | 铜陵祥云消防科技有限责任公司 | Nano-wollastonite modified adhesive for packaging |
| CN102977799A (en) * | 2012-11-15 | 2013-03-20 | 合肥帝奥木业有限公司 | Preparing method of high-strength woodworking adhesives |
| CN103013389A (en) * | 2012-11-22 | 2013-04-03 | 芜湖众力部件有限公司 | Special bonding agent containing rice hull ash for surface composite woven shell fabric of automotive upholstery |
| CN103265917A (en) * | 2013-04-07 | 2013-08-28 | 青阳县华鼎包装有限公司 | Adhesive containing nano attapulgite for packaging and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315527A (en) * | 2015-11-23 | 2016-02-10 | 苏州盖德精细材料有限公司 | Neoprene-based UL yellow adhesive and preparation method thereof |
| CN106751502A (en) * | 2016-12-06 | 2017-05-31 | 佛山市高明区生产力促进中心 | A kind of neo-epoxy resin composition |
| CN107739577A (en) * | 2017-11-17 | 2018-02-27 | 刘青 | A kind of anti-flammability adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103805074B (en) | 2015-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101280142B (en) | Preparation method of environment-friendly aqueous nanometer fireproof flame-retardant coating | |
| CN102181166B (en) | High-efficiency flame retardant wood plastics composite and preparation method thereof | |
| CN102875932B (en) | A kind of PVC power pipe material and preparation method thereof | |
| CN103805074B (en) | Nano palygorskite-modified flame-retardant adhesive | |
| CN104194171A (en) | Flame-retardant cold-resistant impact-resistant rubber cable sheath and preparation method thereof | |
| CN103820035B (en) | Flame retardant adhesive containing modified kaolin | |
| CN101638503B (en) | Environment-friendly composite flame retardant weatherproof ABS | |
| CN104356565A (en) | Aluminophosphate molecular sieve flame retardant and preparation method thereof | |
| CN103554917A (en) | Composite flame retardant | |
| CN103131304B (en) | A kind of powder coating containing modified carbide slag | |
| CN113493624B (en) | Biomass flame retardant, water-based flame retardant coating, and preparation method and application thereof | |
| CN103788678B (en) | Composite flame retardant containing modified nano bentonite | |
| CN107955155B (en) | Nitrogen-boron structure type flame-retardant polyether polyol and preparation method and application thereof | |
| CN106868916A (en) | A kind of environmental-protection flame-retardant cardboard and preparation method thereof | |
| CN103773393B (en) | Composite type flame retardant containing modified zeolite powder | |
| CN103012948B (en) | Flame-retardant mineral paper and preparation method thereof | |
| CN104262875A (en) | Intumescent flame-retardant cable material taking plant-based active carbon as synergist and preparation method thereof | |
| CN104292525B (en) | A kind of flame retardant rubber and preparation method thereof | |
| CN108997615B (en) | Piperazine modified lignin/aluminum hydroxide double-coated red phosphorus flame retardant and application thereof in EVA | |
| CN106280564A (en) | A kind of preparation method of surface modified superfine magnesium hydroxide | |
| CN106084950A (en) | A kind of aluminum alloy doors and windows flame-proof antibiotic coating | |
| CN104312056A (en) | Organic acid and rare earth composite heat stabilizer for PVC (polyvinyl chloride) | |
| CN103710872A (en) | Nonwoven cloth sound absorbing cotton containing wood sawdust | |
| CN103205177A (en) | Preparation method for powder coating containing dibutyl phthalate | |
| CN102558652A (en) | Method for preparing fireproof aluminum-plastic composite board core by utilizing brucite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161221 Address after: 542899 Hezhou the Guangxi Zhuang Autonomous Region Electronic Science and technology park is run on the road No. 1 Patentee after: Guangxi Huizhi Productivity Promotion Center Co. Ltd. Address before: 244100 Tongling Jinqiao Industrial Park, Tongling, Anhui Patentee before: Tongling Xiangyun Fire-fighting Technology Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190416 Address after: 518055 Dong 401-404, No. 5, Honghualing Industrial Zone, Taoyuan Street, Nanshan District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Meizhi Electric Industry Co., Ltd. Address before: 542899 No. 1 Zhengrun Avenue, Hezhou Electronic Science and Technology Park, Guangxi Zhuang Autonomous Region Patentee before: Guangxi Huizhi Productivity Promotion Center Co. Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150610 Termination date: 20200220 |