CN103897614A - Non-asphalt-based rubber film - Google Patents

Non-asphalt-based rubber film Download PDF

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Publication number
CN103897614A
CN103897614A CN201410159708.1A CN201410159708A CN103897614A CN 103897614 A CN103897614 A CN 103897614A CN 201410159708 A CN201410159708 A CN 201410159708A CN 103897614 A CN103897614 A CN 103897614A
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China
Prior art keywords
styrene
glued membrane
sis
block copolymer
styrene block
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Granted
Application number
CN201410159708.1A
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Chinese (zh)
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CN103897614B (en
Inventor
刘晖
周为民
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Guangdong Psylic Waterproof Material Co ltd
China Railway Siyuan Survey and Design Group Co Ltd
Original Assignee
GUANGDONG PSYLIC WATERPROOF MATERIAL Co Ltd
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Application filed by GUANGDONG PSYLIC WATERPROOF MATERIAL Co Ltd filed Critical GUANGDONG PSYLIC WATERPROOF MATERIAL Co Ltd
Priority to CN201410159708.1A priority Critical patent/CN103897614B/en
Publication of CN103897614A publication Critical patent/CN103897614A/en
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Publication of CN103897614B publication Critical patent/CN103897614B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention belongs to flexible materials for roof coverings and particularly relates to a non-asphalt-based rubber film. The invention aims providing a non-asphalt-based waterproof coiled material. In order to achieve the aim, the technical scheme provided by the invention is as follows: the non-asphalt-based rubber film contains the following ingredients in percentage by weight: 4-10% of styrene-butadiene-styrene block copolymer (SBS), 4-10% of styrene-isoprene-styrene block copolymer (SIS), 2-5% of ethylene-vinyl-acetate copolymer (EVA), 1-3% of polypropylene (PP), 10-20% of tackifying resin, 20-40% of filler and 25-45% of rubber oil. The non-asphalt-based rubber film has the beneficial effects that the non-asphalt-based rubber film is safe, environmental-friendly and pollution-free; the binding power is stronger; the stability is better, and the service life is prolonged; the waterproof effect is relatively good.

Description

A kind of non-asphaltic base glued membrane
Technical field
The invention belongs to the flexible materials for roof cladding, relate in particular to a kind of non-asphaltic base glued membrane.
Background technology
Waterproof roll is as material necessary in a kind of house decoraton, with and with the closely-related present situation of people's daily life, the quality of its quality is directly connected to the healthy of people.
Existing waterproof roll all contains pitch, and the main component of pitch be phenols, compound, anthracene, naphthalene, pyridine etc. to mucocutaneous tool pungency, be coated with 30% coal-tar pitch toluene solution and be coated with skin 3 times, part presents hyperkeratosis and chaps continue inflammation after.
Pitch and contained anthracene thereof, phenanthrene, pyridine etc. are all light poisonous substance, under action of ultraviolet radiation, can cause photochemical reaction.Due to pitch, photochemical reaction is the photochemical reaction that pitch occurs by luminous energy effect under aerobic conditions, and free radical, superoxide that reflection generates cause cell injury, therefore be a kind of non-immunity disease.
Therefore, research and development one neither comprises pitch, can meet again the coiled material of waterproof and other building performance, for being badly in need of.
Summary of the invention
Technical problem to be solved by this invention is that a kind of waterproof roll of non-asphaltic base is provided.
In order to address the above problem, technical scheme provided by the present invention is:
A kind of non-asphaltic base glued membrane, the component of described glued membrane and weight percent are: styrene butadiene-benzene second
Alkene block copolymer (SBS) 4 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 10 ~ 20%, filler 20 ~ 40%, rubber oil 25 ~ 45%.
Optionally, described glued membrane does not comprise asphaltic base.
Optionally, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymerization
Thing (SBS) 4 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 8%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 10 ~ 20%, filler 25 ~ 40%, rubber oil 29 ~ 45%.
Optionally, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymerization
Thing (SBS) 5 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 5 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 3 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 13 ~ 16%, filler 20 ~ 35%, rubber oil 25 ~ 41%.
Optionally, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymerization
Thing (SBS) 6 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 4%, polypropylene (PP) 2 ~ 3%, tackifying resin 13 ~ 20%, filler 20 ~ 29%, rubber oil 30 ~ 45%.
Optionally, described glued membrane also comprises rubber modifier and coupling agent, the weight hundred of described rubber modifier
Proportion by subtraction is 1 ~ 5%, and the weight percent of described coupling agent is 0.2 ~ 1%.
Optionally, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymerization
Thing (SBS) 4%, styrene isoprene styrene block copolymer (SIS) (SIS) 10%, ethylene-vinyl acetate copolymer (EVA) 3%, polypropylene (PP) 1%, tackifying resin 11%, filler 40%, rubber oil 25%, rubber modifier 5%, coupling agent 1%.
Optionally, described tackifying resin is at least one in carbon five resins, carbon nine resins, tackify petroleum resin, coumarone petroleum resin, terpine resin.
Optionally, described filler comprises at least one in calcium carbonate or activated rubber powder.
Beneficial effect of the present invention is: 1. safety and environmental protection is pollution-free.Pitch complicated component, and belong to dangerization
Product, in use easily make people cause a disease.2. cohesive force is stronger.Styrene-butadiene-styrene block copolymer (SBS) can improving product elasticity, be combined with tackifying resin, bond effect that can also improving product.Styrene isoprene styrene block copolymer (SIS) (SIS) snappiness of improving product better.Ethylene-vinyl acetate copolymer (EVA) can ensure that product still keeps good bond effect under hot conditions.Tackifying resin also can make product bond effect better.3. stability is better, and increase work-ing life.Pitch complicated component, impurity is many, has just used easy embrittlement, sclerosis, and work-ing life is shorter.In the present invention, owing to belonging to non-asphaltic base, so there will not be the phenomenon such as embrittlement, sclerosis, life cycle is long.Filler can improve the stability of product.When the present invention hangs under 70 DEG C of conditions, there will not be sliding phenomenon.4. waterproof effect is better.
Embodiment
For clearer, complete description content of the present invention, provide optimum embodiment to illustrate that the present invention conceives below.Certainly, the embodiment that provides is intended to illustrate design of the present invention, is not the whole of design of the present invention, more should not be considered as the limitation of design content of the present invention.Under the enlightenment of provided embodiment, any scheme of having done all belongs to protection scope of the present invention.
Embodiment 1
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 4%, styrene isoprene styrene block copolymer (SIS) (SIS) 6%, ethylene-vinyl acetate copolymer (EVA) 5%, polypropylene (PP) 1%, tackifying resin 15%, filler 40%, rubber oil 29%.
Embodiment 2
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 10%, benzene second
Alkene-isoprene-styrene block copolymer (SIS) 8%, ethylene-vinyl acetate copolymer (EVA) 2%, polypropylene (PP) 3%, tackifying resin 20%, filler 25%, rubber oil 30%.
Embodiment 3
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 6%, vinylbenzene
-isoprene-styrene block copolymer (SIS) 4%, ethylene-vinyl acetate copolymer (EVA) 4%, polypropylene (PP) 2%, tackifying resin 10%, filler 29%, rubber oil 45%.
Embodiment 4
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 8%, vinylbenzene
-isoprene-styrene block copolymer (SIS) 10%, ethylene-vinyl acetate copolymer (EVA) 3%, polypropylene (PP) 3%, tackifying resin 13%, filler 20%, rubber oil 41%.
Embodiment 5
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 10%, benzene second
Alkene-isoprene-styrene block copolymer (SIS) 10%, ethylene-vinyl acetate copolymer (EVA) 5%, polypropylene (PP) 2%, tackifying resin 18%, filler 30%, rubber oil 25%.
Embodiment 6
A kind of non-asphaltic base glued membrane, styrene-butadiene-styrene block copolymer (SBS) 5%, vinylbenzene
-isoprene-styrene block copolymer (SIS) 5%, ethylene-vinyl acetate copolymer (EVA) 4%, polypropylene (PP) 1%, tackifying resin 16%, filler 35%, rubber oil 34%.
Embodiment 7
A kind of non-asphaltic base glued membrane, the component of described glued membrane and weight percent are: styrene butadiene-benzene second
Alkene block copolymer (SBS) 6%, styrene isoprene styrene block copolymer (SIS) (SIS) 4%, ethylene-vinyl acetate copolymer (EVA) 2%, polypropylene (PP) 1.8%, tackifying resin 20%, filler 20%, rubber oil 45%, rubber modifier 1%, coupling agent 0.2%.
Embodiment 8
A kind of non-asphaltic base glued membrane, the component of described glued membrane and weight percent are: the component of described glued membrane and heavy
Amount per-cent is: styrene-butadiene-styrene block copolymer (SBS) 4%, styrene isoprene styrene block copolymer (SIS) (SIS) 10%, ethylene-vinyl acetate copolymer (EVA) 3%, polypropylene (PP) 1%, tackifying resin 11%, filler 40%, rubber oil 25%, rubber modifier 5%, coupling agent 1%.
Embodiment 9
A kind of non-asphaltic base glued membrane, the component of described glued membrane and weight percent are: the component of described glued membrane and heavy
Amount per-cent is: styrene-butadiene-styrene block copolymer (SBS) 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 5%, ethylene-vinyl acetate copolymer (EVA) 5%, polypropylene (PP) 3%, tackifying resin 10%, filler 30%, rubber oil 33%, rubber modifier 3.5%, coupling agent 0.5%.
In the above-described embodiments, tackifying resin is carbon five resins, carbon nine resins, tackify petroleum resin, ancient horse
At least one in grand petroleum resin, terpine resin; Described filler comprises at least one in calcium carbonate or activated rubber powder.

Claims (9)

1. a non-asphaltic base glued membrane, it is characterized in that, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymer (SBS) 4 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 10 ~ 20%, filler 20 ~ 40%, rubber oil 25 ~ 45%.
2. glued membrane according to claim 1, is characterized in that, described glued membrane does not comprise asphaltic base.
3. glued membrane according to claim 1, it is characterized in that, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymer (SBS) 4 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 8%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 10 ~ 20%, filler 25 ~ 40%, rubber oil 29 ~ 45%.
4. glued membrane according to claim 1, it is characterized in that, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymer (SBS) 5 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 5 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 3 ~ 5%, polypropylene (PP) 1 ~ 3%, tackifying resin 13 ~ 16%, filler 20 ~ 35%, rubber oil 25 ~ 41%.
5. glued membrane according to claim 1, it is characterized in that, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymer (SBS) 6 ~ 10%, styrene isoprene styrene block copolymer (SIS) (SIS) 4 ~ 10%, ethylene-vinyl acetate copolymer (EVA) 2 ~ 4%, polypropylene (PP) 2 ~ 3%, tackifying resin 13 ~ 20%, filler 20 ~ 29%, rubber oil 30 ~ 45%.
6. according to the glued membrane described in any one described in claim 1 to 5, it is characterized in that, described glued membrane also comprises rubber modifier and coupling agent, and the weight percent of described rubber modifier is 1 ~ 5%, and the weight percent of described coupling agent is 0.2 ~ 1%.
7. glued membrane according to claim 6, it is characterized in that, the component of described glued membrane and weight percent are: styrene-butadiene-styrene block copolymer (SBS) 4%, styrene isoprene styrene block copolymer (SIS) (SIS) 10%, ethylene-vinyl acetate copolymer (EVA) 3%, polypropylene (PP) 1%, tackifying resin 11%, filler 40%, rubber oil 25%, rubber modifier 5%, coupling agent 1%.
8. according to the glued membrane described in any one in claim 1 to 5,7, it is characterized in that, described tackifying resin is at least one in carbon five resins, carbon nine resins, tackify petroleum resin, coumarone petroleum resin, terpine resin.
9. glued membrane according to claim 8, is characterized in that, described filler comprises at least one in calcium carbonate or activated rubber powder.
CN201410159708.1A 2014-04-21 2014-04-21 A kind of non-bituminous base glued membrane Expired - Fee Related CN103897614B (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104610892A (en) * 2014-12-25 2015-05-13 湖南鑫湘环保胶业科技有限公司 Formula of environment-friendly particle hot-melt type pressure-sensitive adhesive and preparation method for adhesive
CN105017982A (en) * 2015-07-16 2015-11-04 广东禹能建材科技股份有限公司 Preparation method of non-asphalt multifunctional waterproof coiled material laminated adhesive
CN105237820A (en) * 2014-07-12 2016-01-13 卢桂才 Reaction type non-asphalt base waterproof composition
CN105269898A (en) * 2014-07-12 2016-01-27 卢桂才 Reactive non-asphaltic base wet-applied waterproofing roll
CN105295119A (en) * 2014-07-12 2016-02-03 卢桂才 Reaction type non-asphaltic base waterproof composition
CN105315510A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base waterproof composition
CN105313390A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base wet-paving waterproof coiled material
CN105315528A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base waterproof composition
CN106318258A (en) * 2015-04-27 2017-01-11 苏州斯迪克新材料科技股份有限公司 Release film with net-shaped patterns
CN106398642A (en) * 2016-08-26 2017-02-15 广西青龙化学建材有限公司 High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof
CN106633358A (en) * 2017-01-07 2017-05-10 成都市嘉洲新型防水材料有限公司 Non-asphalt-based reactive flame-retardant macromolecular waterproof roll material and preparation method thereof
CN107674607A (en) * 2017-11-15 2018-02-09 湖北蓝盾之星科技有限公司 A kind of floating bead is modified the preparation method of non-bituminous base adhesive waterproof coil
CN110003808A (en) * 2019-04-15 2019-07-12 四川卓邦安新材料科技有限公司 A kind of high-polymer self-adhesion waterproof coiled material and preparation method thereof
CN110591618A (en) * 2019-10-24 2019-12-20 江苏嘉好热熔胶股份有限公司 Hot-melt pressure-sensitive adhesive for modifying viscosity of SBS asphalt waterproof coiled material
CN114292562A (en) * 2022-01-26 2022-04-08 北京宇阳泽丽防水材料有限责任公司 Nano-grade filler modified non-asphalt waterproof material
CN115124932A (en) * 2022-06-30 2022-09-30 上海北新月皇新材料集团有限公司 High-molecular self-adhesive film waterproof roll and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
US4997709A (en) * 1988-11-07 1991-03-05 The Kendall Company Novel adhesives and tapes including same
CN101289605A (en) * 2008-06-04 2008-10-22 金尔昇 Environment protection type colourful flashing hot-melt adhesive
CN102925087A (en) * 2012-11-08 2013-02-13 无锡市万力粘合材料有限公司 Hot melt adhesive composition for sealing automobile lamp and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4997709A (en) * 1988-11-07 1991-03-05 The Kendall Company Novel adhesives and tapes including same
CN101289605A (en) * 2008-06-04 2008-10-22 金尔昇 Environment protection type colourful flashing hot-melt adhesive
CN102925087A (en) * 2012-11-08 2013-02-13 无锡市万力粘合材料有限公司 Hot melt adhesive composition for sealing automobile lamp and preparation method thereof

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237820A (en) * 2014-07-12 2016-01-13 卢桂才 Reaction type non-asphalt base waterproof composition
CN105269898A (en) * 2014-07-12 2016-01-27 卢桂才 Reactive non-asphaltic base wet-applied waterproofing roll
CN105295119A (en) * 2014-07-12 2016-02-03 卢桂才 Reaction type non-asphaltic base waterproof composition
CN105315510A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base waterproof composition
CN105313390A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base wet-paving waterproof coiled material
CN105315528A (en) * 2014-07-12 2016-02-10 卢桂才 Reaction type non-asphalt base waterproof composition
CN104610892B (en) * 2014-12-25 2016-08-17 湖南鑫湘环保胶业科技有限公司 A kind of formula of environmental protection granule thermotropic pressure sensitive glue and preparation method thereof
CN104610892A (en) * 2014-12-25 2015-05-13 湖南鑫湘环保胶业科技有限公司 Formula of environment-friendly particle hot-melt type pressure-sensitive adhesive and preparation method for adhesive
CN106318258A (en) * 2015-04-27 2017-01-11 苏州斯迪克新材料科技股份有限公司 Release film with net-shaped patterns
CN105017982B (en) * 2015-07-16 2018-09-25 广东禹能建材科技股份有限公司 A kind of preparation method of non-bituminous Multifunctional water-proof coiled material laminated adhesive
CN105017982A (en) * 2015-07-16 2015-11-04 广东禹能建材科技股份有限公司 Preparation method of non-asphalt multifunctional waterproof coiled material laminated adhesive
CN106398642A (en) * 2016-08-26 2017-02-15 广西青龙化学建材有限公司 High viscosity non-asphalt base self-adhesive glue for waterproof coiled materials and preparation method thereof
CN106633358A (en) * 2017-01-07 2017-05-10 成都市嘉洲新型防水材料有限公司 Non-asphalt-based reactive flame-retardant macromolecular waterproof roll material and preparation method thereof
CN107674607A (en) * 2017-11-15 2018-02-09 湖北蓝盾之星科技有限公司 A kind of floating bead is modified the preparation method of non-bituminous base adhesive waterproof coil
CN110003808A (en) * 2019-04-15 2019-07-12 四川卓邦安新材料科技有限公司 A kind of high-polymer self-adhesion waterproof coiled material and preparation method thereof
CN110003808B (en) * 2019-04-15 2021-12-03 四川卓邦安新材料科技有限公司 High-molecular self-adhesive waterproof coiled material and preparation method thereof
CN110591618A (en) * 2019-10-24 2019-12-20 江苏嘉好热熔胶股份有限公司 Hot-melt pressure-sensitive adhesive for modifying viscosity of SBS asphalt waterproof coiled material
CN110591618B (en) * 2019-10-24 2021-05-25 江苏嘉好热熔胶股份有限公司 Hot-melt pressure-sensitive adhesive for modifying viscosity of SBS asphalt waterproof coiled material
CN114292562A (en) * 2022-01-26 2022-04-08 北京宇阳泽丽防水材料有限责任公司 Nano-grade filler modified non-asphalt waterproof material
CN115124932A (en) * 2022-06-30 2022-09-30 上海北新月皇新材料集团有限公司 High-molecular self-adhesive film waterproof roll and preparation method thereof
CN115124932B (en) * 2022-06-30 2023-11-03 上海北新月皇新材料集团有限公司 Polymer self-adhesive film waterproof coiled material and preparation method thereof

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