CN104017438A - Composite fire retardant coating - Google Patents
Composite fire retardant coating Download PDFInfo
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- CN104017438A CN104017438A CN201410249165.2A CN201410249165A CN104017438A CN 104017438 A CN104017438 A CN 104017438A CN 201410249165 A CN201410249165 A CN 201410249165A CN 104017438 A CN104017438 A CN 104017438A
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Abstract
The invention relates to composite fire retardant coating and belongs to the technical field of coating. The composite fire retardant coating comprises the following components in parts by weight: 20-40 parts of water glass, 10-40 parts of corn starch, 5-20 parts of carboxymethyl cellulose, 20-60 parts of styrene-acrylate emulsion, 5-15 parts of organic curing agent and 5-15 parts of inorganic curing agent. The obtained fire retardant coating integrates the advantages of the organic fire retardant coating and inorganic fire retardant coating, no toxic gas or smoke is produced during fire retardance, the produced silicate foamed thermal-protective coating is high in strength, impact effect of a flame heat flow can be effectively resisted, and the fire retardant property is obvious; the organic and inorganic composite fire retardant coating combines good performances of the organic fire retardant coating and the inorganic fire retardant coating, and deficiencies of the organic fire retardant coating and the inorganic fire retardant coating are made up each other; an organic matter group is introduced onto an inorganic matter molecular structure, so that properties of the organic matter group are improved; a multi-fingered mechanical mixing process is carried out, mixed dispersion liquid is obtained, and the composite fire retardant coating has good decorative function, water resistance and field spraying construction performance.
Description
Technical field
The invention belongs to technical field of coatings, specifically implement that low, the resistance to burning of a kind of toxicity, intensity are good, foam layer quality pine, thermal conductivity is little and fire-proof and thermal-insulation is effective composite coating.
Background technology
Now widely used frie retardant coating comprises organic fire-proof dilatation and inorganic fire-proof dilatation.The features such as organic expander frie retardant coating has system and has attractive coat, and sticking power is good, but easily produce smog when its back-fire relief and emit to some extent poisonous gas, cost is also higher; The frie retardant coating of inorganic fire-proof dilatation main film forming substance, its flame retardant resistance is better than organic fire prevention coating, but the physicalies such as its water tolerance are poor.
Summary of the invention
For the above-mentioned problems in the prior art, the object of the present invention is to provide that low, the resistance to burning of toxicity, intensity are good, foam layer quality pine, thermal conductivity is little and fire-proof and thermal-insulation is effective composite coating.
Described a kind of composite fire retardant coating, it is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 20-40 part, W-Gum 10-40 part, carboxymethyl cellulose 5-20 part, cinnamic acrylic ester emulsion 20-60 part, organic curing agent 5-15 part, inorganic solidification agent 5-15 part.
Described a kind of composite fire retardant coating, it is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 25-35 part, W-Gum 15-30 part, carboxymethyl cellulose 10-15 part, cinnamic acrylic ester emulsion 30-50 part, organic curing agent 8-12 part, inorganic solidification agent 8-12 part.
Described a kind of composite fire retardant coating, is characterized in that described frie retardant coating comprises the component of following parts by weight: 30 parts of water glass, 25 parts of W-Gums, 12 parts of carboxymethyl celluloses, 40 parts of cinnamic acrylic ester emulsions, 10 parts of organic curing agents, 1 part of inorganic solidification agent.
Described a kind of composite fire retardant coating, is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 25-35 part, W-Gum 15-30 part, carboxymethyl cellulose 10-15 part, cinnamic acrylic ester emulsion 30-50 part, organic curing agent 8-12 part.
Described a kind of composite fire retardant coating, it is characterized in that described organic curing agent be trolamine, oxalic dialdehyde, any one in methyl-monosilane alkyd sodium, methyl-silicone oil.
Described a kind of composite fire retardant coating, is characterized in that described inorganic solidification agent is condensed phosphoric acid sodium salt, poly-silicophosphate or Sodium Silicofluoride.
By adopting above-mentioned technology, compared with prior art, the present invention has following beneficial effect:
Composite fire retardant coating of the present invention comprises the component of following parts by weight: water glass 20-40 part, W-Gum 10-40 part, carboxymethyl cellulose 5-20 part, cinnamic acrylic ester emulsion 20-60 part, organic curing agent 5-15 part, inorganic solidification agent 5-15 part.The frie retardant coating obtaining integrates the advantage of organic fire prevention coating and inorganic fireproof coating, and the silicate foam shape thermofin intensity that does not produce poisonous gas and smog, generation when back-fire relief is high, can effectively resist fire
The shock action of flame hot-fluid, Fire resistances is more outstanding; This organic-inorganic composite frie retardant coating combines the premium properties of the two to learn from other's strong points to offset one's weaknesses.On the molecular structure of inorganics, introduce organism group, its character is improved; Multifinger mechanical mixing process, obtains mixed dispersion liquid, has good decoration functions, water resistance, in-situ spraying workability.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited in this.
Embodiment 1: a kind of composite fire retardant coating, comprise the component of following parts by weight: 20 parts of water glass, 40 parts of W-Gums, 20 parts of carboxymethyl celluloses, 60 parts of cinnamic acrylic ester emulsions, 5 parts of trolamines, 15 parts of condensed phosphoric acid sodium salts, each component mix with water routinely ratio mix.
On above-described embodiment, oxalic dialdehyde for organic curing agent, methyl-monosilane alkyd sodium, methyl-silicone oil replaces trolamine, and inorganic solidification agent replaces condensed phosphoric acid sodium salt with poly-silicophosphate or Sodium Silicofluoride, all can obtain same technique effect.
Embodiment 2: a kind of composite fire retardant coating, comprises the component of following parts by weight: 40 parts of water glass, 10 parts of W-Gums, 5 parts of carboxymethyl celluloses, 20 parts of cinnamic acrylic ester emulsions, 15 parts of oxalic dialdehydes, 5 parts of poly-phosphorus ammonium silicates.Each component mix with water routinely ratio mix.
Embodiment 3: a kind of composite fire retardant coating, comprises the component of following parts by weight: 25 parts of water glass, 15 parts of W-Gums, 10 parts of carboxymethyl celluloses, 50 parts of cinnamic acrylic ester emulsions, 12 parts of trolamines, 12 parts of Sodium Silicofluorides.
Embodiment 4: a kind of composite fire retardant coating, comprises the component of following parts by weight: 35 parts of water glass, 30 parts of W-Gums, 15 parts of carboxymethyl celluloses, 30 parts of cinnamic acrylic ester emulsions, 8 parts of oxalic dialdehydes, 8 parts of poly-phosphorus water glass.
Embodiment 5: a kind of composite fire retardant coating, comprises the component of following parts by weight: 30 parts of water glass, 25 parts of W-Gums, 12 parts of carboxymethyl celluloses, 40 parts of cinnamic acrylic ester emulsions, 10 parts of methyl-silicone oils, 10 parts of Sodium Silicofluorides.
The performance test results of the composite water-proof paint that the present invention obtains above-described embodiment 1-5 is as following table:
The performance test results of the composite water-proof paint of the embodiment of the present invention
From upper table, can obtain, composite fire retardant coating of the present invention, water tolerance is up to 89h, alkali resistance is good, and the resistance to property gone out, humidity resistance are strong, and resistance to combustion is of long duration, have that low, the resistance to burning of toxicity, intensity are good, foam layer quality pine, thermal conductivity is little and fire-proof and thermal-insulation is effective, be suitable for applying.
Claims (6)
1. a composite fire retardant coating, it is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 20-40 part, W-Gum 10-40 part, carboxymethyl cellulose 5-20 part, cinnamic acrylic ester emulsion 20-60 part, organic curing agent 5-15 part, inorganic solidification agent 5-15 part.
2. a kind of composite fire retardant coating according to claim 1, it is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 25-35 part, W-Gum 15-30 part, carboxymethyl cellulose 10-15 part, cinnamic acrylic ester emulsion 30-50 part, organic curing agent 8-12 part, inorganic solidification agent 8-12 part.
3. a kind of composite fire retardant coating according to claim 1, is characterized in that described frie retardant coating comprises the component of following parts by weight: 30 parts of water glass, 25 parts of W-Gums, 12 parts of carboxymethyl celluloses, 40 parts of cinnamic acrylic ester emulsions, 10 parts of organic curing agents, 1 part of inorganic solidification agent.
4. a kind of composite fire retardant coating according to claim 1, is characterized in that described frie retardant coating comprises the component of following parts by weight: water glass 25-35 part, W-Gum 15-30 part, carboxymethyl cellulose 10-15 part, cinnamic acrylic ester emulsion 30-50 part, organic curing agent 8-12 part.
5. a kind of composite fire retardant coating according to claim 1, it is characterized in that described organic curing agent be trolamine, oxalic dialdehyde, any one in methyl-monosilane alkyd sodium, methyl-silicone oil.
6. a kind of composite fire retardant coating according to claim 1, is characterized in that described inorganic solidification agent is condensed phosphoric acid sodium salt, poly-silicophosphate or Sodium Silicofluoride.
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CN201410249165.2A CN104017438A (en) | 2014-06-06 | 2014-06-06 | Composite fire retardant coating |
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CN201410249165.2A CN104017438A (en) | 2014-06-06 | 2014-06-06 | Composite fire retardant coating |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104671738A (en) * | 2015-02-10 | 2015-06-03 | 韩方超 | Shale diatom ooze wall material and preparation method thereof |
CN104817894A (en) * | 2015-05-05 | 2015-08-05 | 广西高农机械有限公司 | Composite fireproof coating used for agriculture machinery |
CN104817899A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Modified wear-resistant coating for weeding machines |
CN106433365A (en) * | 2016-10-11 | 2017-02-22 | 安徽卡塔门窗有限公司 | Fireproof coating for wooden door and preparation method of fireproof coating |
CN107216693A (en) * | 2017-05-19 | 2017-09-29 | 海洋化工研究院有限公司 | Inorganic expansive fireproof coating and preparation method |
US9969100B1 (en) * | 2017-08-30 | 2018-05-15 | Paul Moran | Fire retardant composition |
CN112812590A (en) * | 2020-12-30 | 2021-05-18 | 廊坊华日家具股份有限公司 | Water-based fireproof elastic coating |
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CN1544556A (en) * | 2003-11-28 | 2004-11-10 | 厦门大学 | Tunnel fireproof paint and its manufacturing technology |
CN101386719A (en) * | 2008-08-28 | 2009-03-18 | 冯守中 | Multifunctional coatings and preparation method thereof |
CN103045037A (en) * | 2012-12-14 | 2013-04-17 | 中盈长江国际新能源投资有限公司 | Water-based expandable fireproof steel structure coating and preparation method |
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2014
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US4273879A (en) * | 1978-03-31 | 1981-06-16 | Minnesota Mining And Manufacturing Company | Intumescent fire retardant composites |
CN1106851A (en) * | 1994-11-07 | 1995-08-16 | 刘小兵 | Compound insulation and fire-proof paint |
CN1544556A (en) * | 2003-11-28 | 2004-11-10 | 厦门大学 | Tunnel fireproof paint and its manufacturing technology |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104671738A (en) * | 2015-02-10 | 2015-06-03 | 韩方超 | Shale diatom ooze wall material and preparation method thereof |
CN104817899A (en) * | 2015-04-30 | 2015-08-05 | 广西高农机械有限公司 | Modified wear-resistant coating for weeding machines |
CN104817894A (en) * | 2015-05-05 | 2015-08-05 | 广西高农机械有限公司 | Composite fireproof coating used for agriculture machinery |
CN106433365A (en) * | 2016-10-11 | 2017-02-22 | 安徽卡塔门窗有限公司 | Fireproof coating for wooden door and preparation method of fireproof coating |
CN107216693A (en) * | 2017-05-19 | 2017-09-29 | 海洋化工研究院有限公司 | Inorganic expansive fireproof coating and preparation method |
US9969100B1 (en) * | 2017-08-30 | 2018-05-15 | Paul Moran | Fire retardant composition |
CN112812590A (en) * | 2020-12-30 | 2021-05-18 | 廊坊华日家具股份有限公司 | Water-based fireproof elastic coating |
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