CN106098809A - A kind of preparation method of series-parallel film battery assembly - Google Patents

A kind of preparation method of series-parallel film battery assembly Download PDF

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Publication number
CN106098809A
CN106098809A CN201610693657.XA CN201610693657A CN106098809A CN 106098809 A CN106098809 A CN 106098809A CN 201610693657 A CN201610693657 A CN 201610693657A CN 106098809 A CN106098809 A CN 106098809A
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laser
battery
series
sub
parallel
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CN106098809B (en
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鄢开均
何光俊
齐鹏飞
陈金良
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Zhongshan Ruike New Energy Co Ltd
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Zhongshan Ruike New Energy Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1876Particular processes or apparatus for batch treatment of the devices
    • H01L31/188Apparatus specially adapted for automatic interconnection of solar cells in a module
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/022441Electrode arrangements specially adapted for back-contact solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/0445PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
    • H01L31/046PV modules composed of a plurality of thin film solar cells deposited on the same substrate
    • H01L31/0463PV modules composed of a plurality of thin film solar cells deposited on the same substrate characterised by special patterning methods to connect the PV cells in a module, e.g. laser cutting of the conductive or active layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • H01L31/0516Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module specially adapted for interconnection of back-contact solar cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1884Manufacture of transparent electrodes, e.g. TCO, ITO
    • H01L31/1888Manufacture of transparent electrodes, e.g. TCO, ITO methods for etching transparent electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses the preparation method of a kind of series-parallel film battery assembly, the method is mainly divided into, by laser scoring, two parts that area is identical on one piece of TCO electro-conductive glass, it is respectively series conductor part and parallel conductance part, series conductor part is used for laser grooving and scribing sub-series battery, parallel conductance part is for laser grooving and scribing sub-battery in parallel, respectively sub-to sub-series battery and parallel connection battery is coupled together with drainage strip and busbar, again series conductor part and parallel conductance part are coupled together, the series-parallel film battery assembly needed for making.The present invention is in view of the poor shortcoming of membrane uniformity after large-area coating film, in conjunction with series circuit and the feature of parallel circuit, dissolve film layer difference and be connected in series the problem that sub-battery brings, it is additionally contemplates that the optimization carrying out electrical parameter for the feature that in hull cell electrical parameter, voltage is higher or electric current is higher, it is simple to the later stage is building in power station the impact on factors such as inverter type selecting and Power Plant Design.

Description

A kind of preparation method of series-parallel film battery assembly
Technical field
The present invention relates to the technical field of thin-film solar cells, refer in particular to a kind of series-parallel film battery assembly Preparation method.
Background technology
Thin-film solar cells mainly has non-silicon-based hull cell, CIGS thin film solar energy, CdTe film battery etc. now, The material system of hull cell is each variant, but its manufacturing process is essentially identical, and basic employing three road laser incisings are divided into area Identical sub-battery, then forms series circuit by plated film, finally completes the making of cell panel by dress rosette.It is specially the One laser grooving and scribing TCO conducting film, is divided into the identical n of area (n is positive integer) individual sub-battery, then uses PECVD's or PVD Process plated film, forms PN junction;After second laser grooving and scribing, (second laser is skew first laser grooving and scribing, tool Solid offsetting amount, according to technological requirement, is usually no more than 100 μm, it is ensured that series circuit turns on, such as accompanying drawing 1);Plated film makes the most again Through the 3rd road laser grooving and scribing after back electrode film, (the 3rd road laser is skew second laser incising to the sub-battery of formation series connection Drawing, concrete side-play amount, according to technological requirement, is usually no more than 100 μm, it is ensured that series circuit turns on, such as accompanying drawing 1);Then use Drainage strip and busbar, by battery lead, form the both positive and negative polarity of battery, ready for installing rosette below;Through last part technology (last part technology includes: coating butyl rubber, covering EVA film, laminating machine laminating battery sheet packaging, installation rosette, testing package) I.e. complete technique and make the film battery assembly (the sub-battery connected mode such as accompanying drawing 2 of hull cell) obtaining being connected in series.
So making laser scoring and drainage strip, the welding production of busbar of battery component, technique is relatively easy, technology Comparative maturity.But for hull cell, plated film film aspect is long-pending relatively big, and film layer ratio own is relatively thin, and the improved-type film layer having is only Having 3~5nm, if equipment performance is bad, membrane uniformity is the most poor, and technique forms sub-series battery in making, and finally gives The film assembly being connected in series.It is understood that the feature of series circuit: (1) circuit connects feature: the whole circuit of series connection is one Loop, each electrical appliance is sequentially connected, and does not has " branch point ";(2) electrical appliance work characteristics: each electrical appliance influences each other, in circuit one Individual electrical appliance does not works, and remaining electrical appliance just cannot work.(3) the current work feature of circuit: electric current has significantly " bucket Effect ", series circuit current is the most equal: IAlways=I1=I2=I3=...=InIf, i.e. in circuit certain sub-battery due to Membrane uniformity is poor or laser scoring is bad, causes open circuit, then its resistance is bigger than normal causes electric current to be decreased obviously, and draws Playing a series of problem, as product yield declines, company cost increases;For large-area hull cell, some battery components Voltage is higher, and electric current is on the low side, has plenty of low-voltage, high electric current, thus causes the bad coupling inversion when building photovoltaic plant Device, increases the technical matters such as the difficulty of design of photovoltaic power station and construction cost.(4) series circuit total voltage is equal to voltage everywhere Sum: UAlways=U1+U2+U3+……+Un;(5) the equivalent resistance of series resistance is equal to each resistance sum: RAlways=R1+R2+R3+……+ Rn。
Summary of the invention
It is an object of the invention to the shortcoming overcoming prior art with not enough, it is provided that a kind of series-parallel film battery assembly Preparation method, can be effectively improved battery component unit for electrical property parameters, particularly occur or voltage is higher, or electric current is higher Hull cell electrical parameter;Secondly can effectively solve this type of membrane uniformity poor or certain sub-battery laser groove is bad causes The problem that generated output declines, the particularly film battery assembly of large-area coating film.
For achieving the above object, technical scheme provided by the present invention is: the system of a kind of series-parallel film battery assembly Preparation Method, comprises the following steps:
1), after rectangular TCO electro-conductive glass edging being cleaned up, deliver to first laser equipment and carry out groove, first Conducting film on TCO electro-conductive glass is divided into two parts that area is identical by road laser scoring parallel short sides delineation, is respectively Series conductor part and parallel conductance part, this series conductor part is for the sub-battery of ensuing laser delineation series connection, this parallel connection Current-carrying part is for the sub-battery of ensuing laser delineation parallel connection, and divides the laser rays definition of the conducting film on TCO electro-conductive glass equally For middle bisector;Then, further according to demand, series conductor part and parallel conductance part are respectively depicted N number of area equation Conductive module, N is positive integer, finally, more each conductive module is carried out laser grooving and scribing so that each conductive module is all scored with The sub-battery block of n+1 area equation, n is positive integer;
2), after delineation first laser technology, TCO electro-conductive glass is after relevant coating process, and film layer forms thin-film electro The PN junction in pond, is then delivered to second laser equipment, the middle bisector of second laser first coincidence first laser grooving and scribing Series conductor part and parallel conductance part are separated;If series conductor part and parallel conductance part are at first laser Respectively it is separated out N number of conductive module, then also need second laser coincidence first laser grooving and scribing, form N number of module separated; Then, then second laser grooving and scribing series conductor part and the sub-battery block of parallel conductance part are carried out, wherein, in delineation series connection During the sub-battery block of current-carrying part, second laser is skew first laser grooving and scribing, and concrete side-play amount is according to technological requirement, no More than 100 μm, to ensure that series circuit turns on, and when delineating the sub-battery block of parallel conductance part, it is desirable to second laser Line must overlap with the first laser rays of sub-battery block, to ensure to separate between sub-battery block;
3) after having delineated second laser technology, hull cell plating back electrode film is after completing back electrode film making, thin Film battery technique is come the 3rd road laser equipment and is started to delineate the 3rd road laser, the same with second laser grooving and scribing, and the 3rd road swashs Series conductor part and parallel conductance part are separated by the middle bisector of light first coincidence second laser grooving and scribing;Equally, as Really series conductor part and parallel conductance part are respectively separated out N number of conductive module at first laser, then also need the 3rd road Laser coincidence second laser grooving and scribing, forms N number of module separated;, then carry out the 3rd laser grooving and scribing series conductor portion, road then Dividing and the sub-battery block of parallel conductance part, wherein, when delineating the sub-battery block of series conductor part, the 3rd road laser is inclined Moving second laser grooving and scribing, concrete side-play amount is according to technological requirement, less than 100 μm, to ensure that series circuit turns on, and is carving When drawing the sub-battery block of parallel conductance part, it is desirable to the 3rd road laser rays must overlap with the second laser rays of sub-battery block, To ensure to separate between sub-battery block;Complete sub-series battery and the laser scoring of the sub-battery of parallel connection;
4) hull cell is annealed and after testing, sorting, the technique of hull cell comes ultrasonic bond at ultrasonic welding machine Connecing drainage strip, first weld the drainage strip of series conductor part, the parallel sub-welding battery of drainage strip, each conductive module needs two Drainage strip, the welding position of two drainage strips lays respectively at the inner side being close to sweep edge regions, described in sweep edge regions and refer to that TCO conducts electricity Region, glass edge, it is 8mm that usual surrounding sweeps edge regions width;Weld the drainage strip of parallel conductance part the most again, draw Stream bar is perpendicular to sub-welding battery, and each conductive module needs two drainage strips, and the welding position of two drainage strips is point equally It is not positioned at the inner side being close to sweep edge regions;
5) pasting insulating tape, first paste the insulating tape of series conductor part, the insulating tape of series conductor part hangs down Directly paste in sub-battery, and each conductive module must be pasted;Paste the insulating tape of parallel conductance part the most again, and The insulating tape of connection current-carrying part is parallel to sub-battery and pastes, and equally, each conductive module must be pasted;Finally, then glue Patch connects series conductor part and the insulating tape of parallel conductance part;
6) paste busbar, first paste the busbar of series conductor part, from conductive module negative pole limit drainage strip during stickup On start to paste on the drainage strip of conductive module positive pole, by that analogy, until has pasted all conductive modules to this end, and remittance Stream bar must be pasted onto on insulating tape, it is impossible to contacts with battery membranes layer, it is to avoid short circuit;Next, then paste parallel conductance part Busbar, start to paste on the drainage strip of conductive module positive pole, with this during stickup from the drainage strip of conductive module negative pole limit Analogize, until has pasted all conductive modules to this end, and busbar must be pasted onto on insulating tape, it is impossible to battery membranes layer Contact, it is to avoid short circuit;Then, then the conductive module positive pole of series conductor part and the conductive module negative pole of parallel conductance part Pasting and connect, and busbar must be pasted onto on insulating tape, it is impossible to contact with battery membranes layer, it is to avoid short circuit, finally series connection is led The conductive module negative pole of electricity part and the conductive module positive pole of parallel conductance part are formed as the positive and negative electrode of whole battery component;
7) positive and negative electrode of busbar is the positive and negative electrode of battery, ready for installing rosette below;Through last part technology, Including: coating butyl rubber, covering EVA film, laminating machine laminating battery sheet packaging, installation rosette, testing package, i.e. complete technique Make the series-parallel film battery assembly obtained.
The present invention compared with prior art, has the advantage that and beneficial effect:
1, the membrane effect impact on electric power generation cell is reduced.When large-area coating film, film layer due to device structure and Technology controlling and process is unstable, and plated film membrane uniformity is poor.If using series connection and the mode being connected in parallel to make assembly, can avoid Or reduction membrane uniformity, thus reduce the internal resistance of cell, improve electric power generation cell.
2, the hot spot effect of battery can be reduced.Owing to the internal resistance of cell can generate heat in battery component power generation process, temperature liter Height, we call hot spot effect this effect.After so using series connection and being connected in parallel, battery component internal resistance can be reduced, from And reduce the hot spot effect of battery component, promote the generating efficiency of battery.
3, reduce the production cost of manufacturing enterprise and improve product yield.
4, (" dead band " refers to that first laser scoring is to the 3rd road laser incising can to effectively reduce " dead band " that laser scoring brings Region area between line).After using the mode groove connected and be connected in parallel, three road laser scorings of parallel connection part are all It is to overlap, reduces dead zone area, improve the effective area of cell power generation.
5, optimize the electrical parameter of battery component, preferably service for photovoltaic plant construction.The group that traditional technique makes Part, particularly film assembly show as or electric current is higher, or voltage is higher, are unfavorable for type selecting and the photovoltaic plant of inverter Design.Feature based on series circuit and parallel circuit uses series connection and mode in parallel to make assembly, can optimize balance electricity Electric current in the assembly of pond and voltage parameter, be preferably power plant construction service.
Accompanying drawing explanation
Fig. 1 is the laser scoring mode schematic diagram being connected in series.
Fig. 2 is the series-connection circuit schematic diagram of Fig. 1.
Fig. 3 is the laser scoring mode schematic diagram being connected in parallel.
Fig. 4 be Fig. 3 be connected in parallel circuit diagram.
Fig. 5 is to use series connection and the laser scoring schematic diagram being connected in parallel.
Fig. 6 is that Fig. 5 uses series connection and is connected in parallel circuit diagram.
Fig. 7 is the laser scoring schematic diagram of the present invention.
Fig. 8 is the schematic diagram of ultra-sonic welded drainage strip.
Fig. 9 is the schematic diagram pasting insulating tape.
Figure 10 is the schematic diagram pasting busbar.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
The preparation method of the series-parallel film battery assembly described in the present embodiment, comprises the following steps:
1), after rectangular TCO electro-conductive glass edging being cleaned up, deliver to first laser equipment and carry out groove, first Conducting film on TCO electro-conductive glass is divided into two that area is identical by road laser scoring (being called for short P1) parallel short sides delineation Point, respectively series conductor part and parallel conductance part, this series conductor part is for the son electricity of ensuing laser delineation series connection Pond (as shown in Figure 1), this parallel conductance part is for the sub-battery (as shown in Figure 3) of ensuing laser delineation parallel connection, and puts down The laser rays dividing the conducting film on TCO electro-conductive glass is defined as middle bisector, i.e. centre separator bar, as shown in Figure 7;Connect , series conductor part and parallel conductance part respectively depict further according to demand the conductive module of N number of area equation, N is just Integer, finally, then carries out laser grooving and scribing to each conductive module so that each conductive module is all scored with n+1 area equation Sub-battery block, n is positive integer.
2), after delineation first laser technology, TCO electro-conductive glass is after relevant coating process, and film layer forms thin-film electro The PN junction in pond, is then delivered to second laser equipment, in second laser (being called for short P2) first coincidence first laser grooving and scribing Between bisector series conductor part and parallel conductance part are separated;If series conductor part and parallel conductance part are One laser is respectively separated out N number of conductive module, then also need second laser coincidence first laser grooving and scribing, formed N number of every The module opened;Then, then second laser grooving and scribing series conductor part and the sub-battery block of parallel conductance part are carried out, wherein, Delineate series conductor part sub-battery block time, second laser be skew first laser grooving and scribing, concrete side-play amount according to Technological requirement, typically not greater than 100 μm, to ensure that series circuit turns on, and when delineating the sub-battery block of parallel conductance part, Require that second laser rays must overlap with the first laser rays of sub-battery block, to ensure to separate between sub-battery block.
3) after having delineated second laser technology, hull cell plating back electrode film is after completing back electrode film making, thin Film battery technique is come the 3rd road laser equipment and is started to delineate the 3rd road laser (being called for short P3), the same with second laser grooving and scribing, Series conductor part and parallel conductance part are separated by the middle bisector of the 3rd road laser first coincidence second laser grooving and scribing; Equally, if series conductor part and parallel conductance part are respectively separated out N number of conductive module at first laser, then also need 3rd road laser coincidence second laser grooving and scribing, forms N number of module separated;, then carry out the 3rd road laser grooving and scribing series connection then Current-carrying part and the sub-battery block of parallel conductance part, wherein, when delineating the sub-battery block of series conductor part, the 3rd road swashs Just skew second laser grooving and scribing, concrete side-play amount is according to technological requirement, and typically not greater than 100 μm, to ensure series circuit Conducting, and when delineating the sub-battery block of parallel conductance part, it is desirable to the 3rd road laser rays must be with the second of sub-battery block Laser rays overlaps, to ensure to separate between sub-battery block;Complete the laser scoring of sub-series battery and the sub-battery of parallel connection (as attached Shown in Fig. 5).
4) hull cell is annealed and after testing, sorting, the technique of hull cell comes ultrasonic bond at ultrasonic welding machine Connecing drainage strip, first weld the drainage strip of series conductor part, the parallel sub-welding battery of drainage strip, each conductive module needs two Drainage strip, the welding position of two drainage strips lays respectively at the inner side (as shown in Figure 8) being close to sweep edge regions, described in sweep border area Territory refers to region, TCO electro-conductive glass edge, and it is about 8mm that usual surrounding sweeps edge regions width;Weld parallel connection the most again to lead The drainage strip of electricity part, drainage strip is perpendicular to sub-welding battery, and each conductive module needs two drainage strips, two drainage strips Welding position is the inner side laying respectively at and being close to sweep edge regions equally.
5) pasting insulating tape, first paste the insulating tape of series conductor part, the insulating tape of series conductor part hangs down Directly paste in sub-battery, and each conductive module must be pasted;Paste the insulating tape of parallel conductance part the most again, and The insulating tape of connection current-carrying part is parallel to sub-battery and pastes (as shown in Figure 9), and equally, each conductive module must be pasted On;Finally, then paste and connect series conductor part and the insulating tape of parallel conductance part.
6) paste busbar, first paste the busbar of series conductor part, from conductive module negative pole limit drainage strip during stickup On start to paste on the drainage strip of conductive module positive pole, by that analogy, until has pasted all conductive modules to this end, and remittance Stream bar must be pasted onto on insulating tape, it is impossible to contacts with battery membranes layer, it is to avoid short circuit;Next, then paste parallel conductance part Busbar, start to paste on the drainage strip of conductive module positive pole, with this during stickup from the drainage strip of conductive module negative pole limit Analogize, until has pasted all conductive modules to this end, and busbar must be pasted onto on insulating tape, it is impossible to battery membranes layer Contact, it is to avoid short circuit;Then, then the conductive module positive pole of series conductor part and the conductive module negative pole of parallel conductance part Pasting and connect, and busbar must be pasted onto on insulating tape, it is impossible to contact with battery membranes layer, it is to avoid short circuit, finally series connection is led The conductive module negative pole of electricity part and the conductive module positive pole of parallel conductance part are formed as the positive and negative electrode of whole battery component (as shown in Figure 9).
7) positive and negative electrode of busbar is the positive and negative electrode of battery, ready for installing rosette below;Through last part technology, Including: coating butyl rubber, covering EVA film, laminating machine laminating battery sheet packaging, installation rosette, testing package, i.e. complete technique Make the series-parallel film battery assembly (as shown in Figure 10) obtained.
In sum, we use in technique makes and are designed as a part for son electricity in parallel at same battery component Pond, a part is sub-series battery, as shown in accompanying drawing 5 and Fig. 6.Contrast uses (such as accompanying drawing 4) in parallel and is connected in series (such as accompanying drawing 2) mode can optimize battery component unit for electrical property parameters, does not haves or voltage is higher, or the situation that electric current is higher, passes through Select well photovoltaic DC-to-AC converter after optimizing design, reduce the difficulty of design of photovoltaic power station;Sub-battery for parallel connection part can reduce The poor impact on electrical property of membrane uniformity;Parallel connection part can reduce the low-power caused owing to membrane uniformity is poor simultaneously Problem, improves power and the product yield of assembly;Parallel connection part also can reduce " dead band " caused due to laser grooving and scribing, improves electricity The utilization rate of pond generating area.The present invention only has laser grooving and scribing, drainage strip different with traditional handicraft with busbar welding in fact, its Remaining technique is the most identical.Not only will not increase cost, moreover it is possible to solve to be connected in series the problem that sub-battery brings.If hull cell serves as a contrast The end (such as TCO electropane) area is relatively big, after glass also can be bisected into two parts by us, by series conductor part and parallel connection Current-carrying part is delineated as N number of conductive module respectively, more N number of module of series conductor part and parallel conductance part is delineated There is n (n is positive integer) bar laser rays, obtain n+1 sub-battery, (ensure that intermodule area is identical when delineation is for N number of module, Then in N number of module, n+1 sub-cell area of delineation is also identical).Then will by busbar below and drainage strip Parallel conductance part and series conductor part couple together.It is understood that the feature of parallel circuit: (1) circuit connects feature: in parallel Circuit is made up of main line and some branch roads, has " branch point ". every branch road each with formation loop, main line, have several branch roads, Just there is several loop, if the membrane uniformity in certain region is poor or laser scoring causes bad in plated film, will not be to whole Individual circuit has a significant effect, IAlways=I1+I2+I3……+In;(2) electrical appliance work characteristics: in parallel circuit, in a branch road If electrical appliance does not works, the electrical appliance of other branch roads remains to work;(3) parallel circuit resistance feature: 1 ÷ RAlways=1 ÷ R1+1÷R2 +…+RnIn parallel circuit, the inverse of all-in resistance is equal to the sum reciprocal of each branch resistance;(4) parallel circuit voltage feature: UAlways =U1=U2=...=Un voltage in parallel circuit is the most equal.
Present invention mainly solves that thin-film solar cells uniformity of film in manufacturing process is poor causes transformation efficiency relatively Low problem, Improving The Quality of Products on the basis of not increasing product cost, wins the market simultaneously.Through primary Calculation, product turns Change efficiency and can promote 1%, as calculated by 100MW/ annual capacity, that 1MW that can generate electricity every year more, calculate by 4 yuan/W, 400 can be produced The profit of ten thousand yuan.
In a word, the present invention has fully taken into account the shortcoming that membrane uniformity after large-area coating film is poor, in conjunction with parallel circuit With the feature of series circuit, dissolve film layer difference and be connected in series the problem that sub-battery brings;Also can be according to hull cell Unit for electrical property parameters, solves by the present invention that voltage is higher or the feature that current sheet is high.Use this manufacturing process, by In last part technology with to be connected in series mode identical, therefore there is no difference on cost, it is most important that solve us aborning The problem being not fee from, is with a wide range of applications, and is worthy to be popularized.
Embodiment described above is only the preferred embodiments of the invention, not limits the practical range of the present invention with this, therefore The change that all shapes according to the present invention, principle are made, all should contain within the scope of the present invention.

Claims (1)

1. the preparation method of a series-parallel film battery assembly, it is characterised in that comprise the following steps:
1) after being cleaned up by rectangular TCO electro-conductive glass edging, delivering to first laser equipment and carry out groove, first swashs Conducting film on TCO electro-conductive glass is divided into two parts that area is identical by the delineation of light groove parallel short sides, is respectively series connection Current-carrying part and parallel conductance part, this series conductor part is for the sub-battery of ensuing laser delineation series connection, this parallel conductance Part delineates sub-battery in parallel for ensuing laser, and during the laser rays dividing the conducting film on TCO electro-conductive glass equally is defined as Between bisector;Then, further according to demand, series conductor part and parallel conductance part are respectively depicted the conduction of N number of area equation Module, N is positive integer, finally, more each conductive module is carried out laser grooving and scribing so that each conductive module is all scored with n+1 The sub-battery block of individual area equation, n is positive integer;
2), after delineation first laser technology, TCO electro-conductive glass is after relevant coating process, and film layer forms hull cell PN junction, is then delivered to second laser equipment, and the middle bisector of second laser first coincidence first laser grooving and scribing will string Connection current-carrying part and parallel conductance part separate;If series conductor part and parallel conductance part are the most each at first laser It is separated out N number of conductive module, then also need second laser coincidence first laser grooving and scribing, form N number of module separated;Connect , then carry out second laser grooving and scribing series conductor part and the sub-battery block of parallel conductance part, wherein, lead in delineation series connection Electricity part sub-battery block time, second laser be skew first laser grooving and scribing, concrete side-play amount, according to technological requirement, does not surpasses Cross 100 μm, to ensure that series circuit turns on, and when delineating the sub-battery block of parallel conductance part, it is desirable to second laser rays Must overlap with the first laser rays of sub-battery block, to ensure to separate between sub-battery block;
3) after having delineated second laser technology, hull cell plating back electrode film, after completing back electrode film making, thin-film electro Pool process is come the 3rd road laser equipment and is started to delineate the 3rd road laser, the same with second laser grooving and scribing, and the 3rd road laser is first Series conductor part and parallel conductance part are separated by the middle bisector of coincidence second laser grooving and scribing;Equally, if gone here and there Connection current-carrying part and parallel conductance part are respectively separated out N number of conductive module at first laser, then also need the 3rd road laser Coincidence second laser grooving and scribing, forms N number of module separated;Then, then carry out the 3rd road laser grooving and scribing series conductor part and The sub-battery block of parallel conductance part, wherein, when delineating the sub-battery block of series conductor part, the 3rd road laser is skew the Two road laser grooving and scribings, concrete side-play amount is according to technological requirement, less than 100 μm, to ensure that series circuit turns on, and in delineation also When joining the sub-battery block of current-carrying part, it is desirable to the 3rd road laser rays must overlap with the second laser rays of sub-battery block, to protect Demonstrate,prove and separate between sub-battery block;Complete sub-series battery and the laser scoring of the sub-battery of parallel connection;
4) hull cell is annealed and after testing, sorting, the technique of hull cell is come ultra-sonic welded at ultrasonic welding machine and drawn Stream bar, first welds the drainage strip of series conductor part, the parallel sub-welding battery of drainage strip, and each conductive module needs two drains Bar, the welding position of two drainage strips lays respectively at the inner side being close to sweep edge regions, described in sweep edge regions and refer to TCO electro-conductive glass Region, edge, it is 8mm that usual surrounding sweeps edge regions width;Weld the drainage strip of parallel conductance part, drainage strip the most again Being perpendicular to sub-welding battery, each conductive module needs two drainage strips, and the welding position of two drainage strips is difference position equally In being close to the inner side of sweeping edge regions;
5) pasting insulating tape, first paste the insulating tape of series conductor part, the insulating tape of series conductor part is perpendicular to Sub-battery is pasted, and each conductive module must be pasted;Pasting the insulating tape of parallel conductance part the most again, parallel connection is led The insulating tape of electricity part is parallel to sub-battery and pastes, and equally, each conductive module must be pasted;Finally, then paste even Connect series conductor part and the insulating tape of parallel conductance part;
6) paste busbar, first paste the busbar of series conductor part, open from the drainage strip of conductive module negative pole limit during stickup Begin to paste on the drainage strip of conductive module positive pole, by that analogy, until having pasted all conductive modules to this end, and busbar Must be pasted onto on insulating tape, it is impossible to contact with battery membranes layer, it is to avoid short circuit;Next, then paste the remittance of parallel conductance part Stream bar, starts to paste on the drainage strip of conductive module positive pole during stickup from the drainage strip of conductive module negative pole limit, by that analogy, Until pasted all conductive modules to this end, and busbar must be pasted onto on insulating tape, it is impossible to contact with battery membranes layer, Avoid short circuit;Then, then the conductive module positive pole of series conductor part and the conductive module negative pole of parallel conductance part paste Connect, and busbar must be pasted onto on insulating tape, it is impossible to contact with battery membranes layer, it is to avoid short circuit, last series conductor portion The conductive module negative pole divided and the conductive module positive pole of parallel conductance part are formed as the positive and negative electrode of whole battery component;
7) positive and negative electrode of busbar is the positive and negative electrode of battery, ready for installing rosette below;Through last part technology, bag Include: coating butyl rubber, covering EVA film, laminating machine laminating battery sheet packaging, installation rosette, testing package, i.e. complete technique system Make the series-parallel film battery assembly obtained.
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