CN106223120A - A kind of heat sublimation transfer printing paper coating process - Google Patents

A kind of heat sublimation transfer printing paper coating process Download PDF

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Publication number
CN106223120A
CN106223120A CN201610693773.1A CN201610693773A CN106223120A CN 106223120 A CN106223120 A CN 106223120A CN 201610693773 A CN201610693773 A CN 201610693773A CN 106223120 A CN106223120 A CN 106223120A
Authority
CN
China
Prior art keywords
coating
heat sublimation
paper
controls
viscosity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610693773.1A
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Chinese (zh)
Inventor
李双晓
童树华
华飞果
杨宗建
王励稼
江鹏盛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG JINZE PAPER TECHNOLOGY Co Ltd
Original Assignee
ZHEJIANG JINZE PAPER TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG JINZE PAPER TECHNOLOGY Co Ltd filed Critical ZHEJIANG JINZE PAPER TECHNOLOGY Co Ltd
Priority to CN201610693773.1A priority Critical patent/CN106223120A/en
Publication of CN106223120A publication Critical patent/CN106223120A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00—Methods of beating or refining; Beaters of the Hollander type
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D21H21/20—Wet strength agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form

Abstract

The present invention relates to the coating process of a kind of heat sublimation transfer printing paper, this technique is with one or more in porous inorganic filling materials, cationic polymer, High hydrophilous resin, low-viscosity starch, polyvinyl alcohol with low degree of polymerization as base material at the heat sublimation former recto of transfer coated paper, through drying together after painting bottom coating；With one or more in high viscosity starch, polyvinyl alcohol, carboxymethyl cellulose Starch Sodium, sodium carboxymethyl cellulose as base material on the priming coat of the heat sublimation former recto of transfer coated paper, coated face coating Hou Jing bis-road is dried；At the back side of heat sublimation transfer coated paper body paper, with one or more in the macromolecular materials such as polyvinyl alcohol, polyacrylamide, poly(ethylene oxide) as base material, coating back coating Hou Jing bis-road is dried；Rolling after drawn, press polish, composite membrane.Use the present invention, meet general print speed and be dried requirement, it is adaptable to high, medium and low quality heat sublimation transfer ink, and transfer effect can be improved.

Description

A kind of heat sublimation transfer printing paper coating process
Technical field
The present invention relates to a kind of heat sublimation transfer printing paper coating process, be particularly suitable for the heat sublimation of high-speed printer Transfer printing paper coating process.
Background technology
Thermal dye sublimation transfer printing technology refer to utilize ink-jet printer or laser printer by thermal dye sublimation transfer printing ink with word or The form of pattern prints on thermal dye sublimation transfer printing paper work surface, and reusable heat transfer interpreter is in certain transition temperature, hot pressing time and warm Transferring the pattern onto the process of carrying object under pressure pressure, carrying object is usually various cloth, and material mostly is chinlon, terylene Deng.Its concrete grammar is that designer first designs different decorative patterns or pattern according to the requirement that client is concrete, and recycling colour is beaten Print machine automatic color-matching system, by deployed heat sublimation ink print thermal dye sublimation transfer printing paper after coating, treats ink setting After, then will treat that printed fabrics is put in heat transfer machine, at a temperature of 200～240 DEG C together with fitting tightly with thermal dye sublimation transfer printing paper Pressing 20-30s can be successfully by decorative pattern or pattern transfer paper predetermined fabric.This technology is because of simple to operate, and usage range is wide, Variation, individual requirement can be met again simultaneously, thus quickly grow, have been widely used dress ornament, case and bag, porcelain, electronics product Hundreds of commodity such as product.But, along with developing rapidly of this technology, Printing ink producing business, in order to reduce environmental pollution, reduces and produces Cost, constantly releases water fever sublimation transfer ink, and aqueous ink is high because of moisture, and osmosis is strong, can reduce ink dries Dry speed, damages hot transfer effect.Additionally, along with the continuous progress of technology, large colour printer is by original single shower nozzle Develop into present many shower nozzles isochronous printing.Print speed also has original 10～15m/h, brings up to 18 commonly used now ～25m/h, the fastest print speed can reach 45m/h.More and more higher for heat sublimation transfer printing ink moisture content, color Color printer operating speed is increasingly faster, and this just requires, and heat sublimation transfer coated paper intensity is high, deflection is big, water absorption is strong, transfer Effective.
Summary of the invention
It is an object of the invention to provide ink setting speed fast, hot transfer effect is good, meets flying print, quick-drying The coating process of a kind of heat sublimation transfer printing paper required.
The present invention adopts the technical scheme that: the coating process of a kind of heat sublimation transfer printing paper, it is characterised in that its bag Include following steps: A, at the heat sublimation former recto of transfer coated paper, with porous inorganic filling materials, cationic polymer, high water suction One or more in resin, low-viscosity starch, polyvinyl alcohol with low degree of polymerization are base material, through drying together after painting bottom coating, Wherein the sizing material concentration of priming coat controls in the range of 10%～20%, and viscosity controls at 100s～150s, and spread controls 24～g/m2；B, on the priming coat of the heat sublimation former recto of transfer coated paper, with high viscosity starch, polyvinyl alcohol, carboxylic first One or more in base cellulose starch sodium, sodium carboxymethyl cellulose are base material, and coated face coating Hou Jing bis-road is dried, wherein The sizing material concentration of finishing coat controls in the range of 10%～20%, and viscosity controls at 90s～120s, and spread controls 3～5g/ m2；C, at the back side of heat sublimation transfer coated paper body paper, with macromolecule materials such as polyvinyl alcohol, polyacrylamide, poly(ethylene oxide) One or more in material are base material, and coating back coating Hou Jing bis-road is dried, wherein the compound viscosity of back coating control 5%～ In the range of 10%, viscosity controls at 30s～50s, spread 0.5～2g/m2；After D, drawn, press polish, composite membrane, rolling is i.e. Can.
Use the present invention, one be produce heat sublimation transfer coated paper can meet the most general print speed be 18～ The requirement to ink setting speed of the 25m/h printer, with full width quantity of ink printing amount 300g/m during printing2Meter, for high-quality Heat sublimation transfer ink, in the time of 5s～15s, ink is the most essentially dry, completely without drying；For ordinary quality Heat sublimation transfer ink, in the time of 30s～45s, ink is the most essentially dry, it may not be necessary to drying plant；For ultralow Quality heat sublimation transfer ink, in the time of 70s～90s, ink is the most essentially dry.Two is due to topcoating macromolecular material There is extraordinary swellability and certain polarity, film property, therefore print procedure can be sent out with polar functional group in ink Raw cross-linking reaction, stops granules of pigments migration in paper in ink, improves transfer effect.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.It comprises the steps:
One, with needlebush, leaf wood mixed slurry as raw material, wet strength agent addition is the 2%～5% of oven dry stock, and AKD neutral and alkali is executed Glue, by strengthening needlebush ratio, the mode improving beating degree produces the heat sublimation that water resistant is good, intensity is good, tightness is high, deflection is good Transfer coated paper body paper.
Two, at the heat sublimation former recto of transfer coated paper, with porous inorganic filling materials, cationic polymer, super absorbent resin One or more in fat, low-viscosity starch, polyvinyl alcohol with low degree of polymerization are base material, through drying together after painting bottom coating, its Middle sizing material concentration controls in the range of 10%～20%, and viscosity controls at 100s～150s, and spread controls 2～4g/m2。
Three, on the priming coat of the heat sublimation former recto of transfer coated paper, with high viscosity starch, polyvinyl alcohol, carboxylic One or more in methylcellulose Starch Sodium, sodium carboxymethyl cellulose are base material, and coated face coating Hou Jing bis-road is dried, its Middle sizing material concentration controls in the range of 10%～20%, and viscosity is slightly less than primary coat, controls at 90s～120s, and spread controls 3 ～5g/m2, scraper for coating, adjust scraper angle and edge height, it is to avoid occur that scraper silking affects coating quality.
Four, do not avoid single spreading to cause heat sublimation to be coated with the unidirectional Texturized severity of paper, affect the follow-up printing of page Flatness, therefore use the technique of back side applying glue, with in the macromolecular materials such as polyvinyl alcohol, polyacrylamide, poly(ethylene oxide) One or more are base material, dry in backsize back coating Hou Jing bis-road of heat sublimation transfer coated paper body paper, wherein sizing material Viscosity controls in the range of 5%～10%, and viscosity controls at 30s～50s, spread 0.5～2g/m2.For reaching Anti-curling Effect, back side applying glue spread must be uniform, therefore viscosity and sizing material concentration can not be excessive, and sizing material levelability necessarily to be got well.
Six, rolling after drawn, press polish, composite membrane.

Claims (1)

1. the coating process of a heat sublimation transfer printing paper, it is characterised in that it comprises the steps: A, shifts in heat sublimation The coating former recto of paper, gathers with porous inorganic filling materials, cationic polymer, High hydrophilous resin, low-viscosity starch, low polymerization degree One or more in vinyl alcohol are base material, and through drying together after painting bottom coating, wherein the sizing material concentration of priming coat controls In the range of 10%～20%, viscosity controls at 100s～150s, and spread controls 24～g/m2；B, in heat sublimation transfer coated On the priming coat of the former recto of paper, with high viscosity starch, polyvinyl alcohol, carboxymethyl cellulose Starch Sodium, carboxymethyl cellulose One or more in sodium are base material, and coated face coating Hou Jing bis-road is dried, wherein the sizing material concentration of finishing coat control 10%～ In the range of 20%, viscosity controls at 90s～120s, and spread controls 3～5g/m2；C, at heat sublimation transfer coated paper body paper The back side, with one or more in the macromolecular materials such as polyvinyl alcohol, polyacrylamide, poly(ethylene oxide) as base material, coating Back coating Hou Jing bis-road is dried, and wherein the compound viscosity of back coating controls in the range of 5%～10%, viscosity control at 30s～ 50s, spread 0.5～2g/m2；Rolling after D, drawn, press polish, composite membrane.
CN201610693773.1A 2016-08-22 2016-08-22 A kind of heat sublimation transfer printing paper coating process Pending CN106223120A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106965585A (en) * 2017-02-16 2017-07-21 苏州吉谷新材料有限公司 Wink dry transfer paper
CN107130468A (en) * 2016-12-30 2017-09-05 山东华泰纸业股份有限公司 It is a kind of can be with the production technology of the two-sided digital heat sublimation transfer printing paper used
CN107142782A (en) * 2016-12-30 2017-09-08 山东华泰纸业股份有限公司 A kind of production method of thermal sublimation digit transfer printing
CN108677588A (en) * 2018-05-15 2018-10-19 浙江永鑫特种纸有限公司 Numerial code spray drawing thermal transfer body paper paper machine and papermaking process
CN107059470B (en) * 2016-12-30 2019-02-22 山东华泰纸业股份有限公司 A kind of coating suitable for producing digital thermal dye sublimation transfer printing paper on high speed coating machine
CN109881532A (en) * 2019-03-21 2019-06-14 武汉金华腾科技有限公司 A kind of coating machine and preparation method thereof being used to prepare digital transfer calico paper
CN109894327A (en) * 2019-03-21 2019-06-18 武汉金华腾科技有限公司 A kind of coating machine and its processing method of processing thermal sublimation digit transfer calico paper
CN109910486A (en) * 2019-03-13 2019-06-21 华邦古楼新材料有限公司 A kind of method and apparatus of high-performance thermal dye sublimation transfer printing paper manufacture
CN111171734A (en) * 2020-01-09 2020-05-19 广东荣冕服饰辅料科技有限公司 Transparent hot-melt adhesive film and injection molding silica gel pyrograph process using same
CN111851142A (en) * 2020-07-24 2020-10-30 淄博圣泉纸业有限公司 Surface treatment method for transfer printing paper

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CN102877360A (en) * 2012-09-05 2013-01-16 喻小琦 Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof
CN203611629U (en) * 2013-09-30 2014-05-28 戚裕 Universal type sublimation transfer paper
CN203713283U (en) * 2013-11-25 2014-07-16 中国制浆造纸研究院 High-transfer-rate quick-dry thermal sublimation transfer paper
CN105711280A (en) * 2014-12-04 2016-06-29 全斯福新材料（苏州）有限公司 Easy-to-use ink-jet heat sublimation transfer paper
CN105730120A (en) * 2014-12-08 2016-07-06 上海东升新材料有限公司 Heat transfer printing paper and preparing method thereof

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US5352503A (en) * 1992-09-21 1994-10-04 Rexham Graphics Inc. Recording paper for ink jet recording processes
CN102877360A (en) * 2012-09-05 2013-01-16 喻小琦 Coating component for heat transfer paper, heat transfer paper and manufacturing method thereof
CN203611629U (en) * 2013-09-30 2014-05-28 戚裕 Universal type sublimation transfer paper
CN203713283U (en) * 2013-11-25 2014-07-16 中国制浆造纸研究院 High-transfer-rate quick-dry thermal sublimation transfer paper
CN105711280A (en) * 2014-12-04 2016-06-29 全斯福新材料（苏州）有限公司 Easy-to-use ink-jet heat sublimation transfer paper
CN105730120A (en) * 2014-12-08 2016-07-06 上海东升新材料有限公司 Heat transfer printing paper and preparing method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107130468A (en) * 2016-12-30 2017-09-05 山东华泰纸业股份有限公司 It is a kind of can be with the production technology of the two-sided digital heat sublimation transfer printing paper used
CN107142782A (en) * 2016-12-30 2017-09-08 山东华泰纸业股份有限公司 A kind of production method of thermal sublimation digit transfer printing
CN107059470B (en) * 2016-12-30 2019-02-22 山东华泰纸业股份有限公司 A kind of coating suitable for producing digital thermal dye sublimation transfer printing paper on high speed coating machine
CN107130468B (en) * 2016-12-30 2019-06-11 山东华泰纸业股份有限公司 A kind of production technology for the digital heat sublimation transfer printing paper that two-sided can be used
CN106965585A (en) * 2017-02-16 2017-07-21 苏州吉谷新材料有限公司 Wink dry transfer paper
CN108677588A (en) * 2018-05-15 2018-10-19 浙江永鑫特种纸有限公司 Numerial code spray drawing thermal transfer body paper paper machine and papermaking process
CN109910486A (en) * 2019-03-13 2019-06-21 华邦古楼新材料有限公司 A kind of method and apparatus of high-performance thermal dye sublimation transfer printing paper manufacture
CN109881532A (en) * 2019-03-21 2019-06-14 武汉金华腾科技有限公司 A kind of coating machine and preparation method thereof being used to prepare digital transfer calico paper
CN109894327A (en) * 2019-03-21 2019-06-18 武汉金华腾科技有限公司 A kind of coating machine and its processing method of processing thermal sublimation digit transfer calico paper
CN109881532B (en) * 2019-03-21 2021-05-07 武汉金华腾科技有限公司 Coating machine for preparing digital transfer printing paper and preparation method thereof
CN111171734A (en) * 2020-01-09 2020-05-19 广东荣冕服饰辅料科技有限公司 Transparent hot-melt adhesive film and injection molding silica gel pyrograph process using same
CN111851142A (en) * 2020-07-24 2020-10-30 淄博圣泉纸业有限公司 Surface treatment method for transfer printing paper
CN111851142B (en) * 2020-07-24 2022-04-19 淄博圣泉纸业有限公司 Surface treatment method for transfer printing paper

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